TW202144372A - 反應型磷酸鹽及其製造方法 - Google Patents

反應型磷酸鹽及其製造方法 Download PDF

Info

Publication number: TW202144372A
Authority: TW; Taiwan
Prior art keywords: group; formula; independently selected; compound; hydrogen
Prior art date: 2020-05-29

Application number

TW110119407A

Other languages

English (en)

Chinese (zh)

Inventor

王伊森

葉思宇

鮑Ｅ

Original Assignee

美商藍立方知識產權有限責任公司

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2020-05-29

Filing date

2021-05-28

Publication date

2021-12-01

2021-05-28 Application filed by 美商藍立方知識產權有限責任公司 filed Critical 美商藍立方知識產權有限責任公司

2021-12-01 Publication of TW202144372A publication Critical patent/TW202144372A/zh

Links

229910019142 PO4 Inorganic materials 0.000 title description 2
238000002360 preparation method Methods 0.000 title description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title 1
239000010452 phosphate Substances 0.000 title 1
150000001875 compounds Chemical class 0.000 claims description 140
229910052739 hydrogen Inorganic materials 0.000 claims description 123
239000001257 hydrogen Substances 0.000 claims description 123
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 83
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 71
125000000217 alkyl group Chemical group 0.000 claims description 61
125000003118 aryl group Chemical group 0.000 claims description 59
125000004104 aryloxy group Chemical group 0.000 claims description 55
125000003545 alkoxy group Chemical group 0.000 claims description 54
150000002431 hydrogen Chemical class 0.000 claims description 52
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 47
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 43
125000001424 substituent group Chemical group 0.000 claims description 42
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 41
239000011342 resin composition Substances 0.000 claims description 15
-1 methoxy, carboxy Chemical group 0.000 claims description 9
229920005989 resin Polymers 0.000 claims description 9
239000011347 resin Substances 0.000 claims description 9
LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 5
VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 claims description 4
150000003254 radicals Chemical class 0.000 claims 3
150000001335 aliphatic alkanes Chemical class 0.000 claims 1
239000000203 mixture Substances 0.000 abstract description 36
229910052698 phosphorus Inorganic materials 0.000 abstract description 20
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 8
239000011574 phosphorus Substances 0.000 abstract description 8
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 3
239000013032 Hydrocarbon resin Substances 0.000 abstract description 3
229920006270 hydrocarbon resin Polymers 0.000 abstract description 3
229920000642 polymer Polymers 0.000 abstract description 2
229930195735 unsaturated hydrocarbon Natural products 0.000 abstract description 2
150000003949 imides Chemical class 0.000 abstract 1
229920013636 polyphenyl ether polymer Polymers 0.000 abstract 1
229910052799 carbon Inorganic materials 0.000 description 22
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 20
239000002966 varnish Substances 0.000 description 20
238000009472 formulation Methods 0.000 description 17
239000004744 fabric Substances 0.000 description 16
239000011521 glass Substances 0.000 description 16
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 15
239000002904 solvent Substances 0.000 description 15
239000003063 flame retardant Substances 0.000 description 12
235000019439 ethyl acetate Nutrition 0.000 description 10
239000011541 reaction mixture Substances 0.000 description 10
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 10
238000003786 synthesis reaction Methods 0.000 description 10
NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
239000000945 filler Substances 0.000 description 6
239000000463 material Substances 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
238000005266 casting Methods 0.000 description 5
238000011156 evaluation Methods 0.000 description 5
238000000034 method Methods 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 4
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
APOXBWCRUPJDAC-UHFFFAOYSA-N bis(2,6-dimethylphenyl) hydrogen phosphate Chemical compound CC1=CC=CC(C)=C1OP(O)(=O)OC1=C(C)C=CC=C1C APOXBWCRUPJDAC-UHFFFAOYSA-N 0.000 description 4
239000011889 copper foil Substances 0.000 description 4
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 4
239000012467 final product Substances 0.000 description 4
239000003517 fume Substances 0.000 description 4
229920001955 polyphenylene ether Polymers 0.000 description 4
238000000935 solvent evaporation Methods 0.000 description 4
238000009423 ventilation Methods 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 3
239000012074 organic phase Substances 0.000 description 3
RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 description 3
WOCGGVRGNIEDSZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical compound C=1C=C(O)C(CC=C)=CC=1C(C)(C)C1=CC=C(O)C(CC=C)=C1 WOCGGVRGNIEDSZ-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000012043 crude product Substances 0.000 description 2
238000011068 loading method Methods 0.000 description 2
238000011417 postcuring Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
125000003944 tolyl group Chemical group 0.000 description 2
KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
241000720974 Protium Species 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
USJRLGNYCQWLPF-UHFFFAOYSA-N chlorophosphane Chemical compound ClP USJRLGNYCQWLPF-UHFFFAOYSA-N 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
229910052805 deuterium Inorganic materials 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
238000010907 mechanical stirring Methods 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000000047 product Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
- C07F9/657172—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom the ring phosphorus atom and one oxygen atom being part of a (thio)phosphinic acid ester: (X = O, S)
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
- C07F9/2404—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/2408—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic of hydroxyalkyl compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/062—Polyethers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
- C08G79/04—Phosphorus linked to oxygen or to oxygen and carbon
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D155/00—Coating compositions based on homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C09D123/00 - C09D153/00
- C09D155/005—Homopolymers or copolymers obtained by polymerisation of macromolecular compounds terminated by a carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Molecular Biology (AREA)
General Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Wood Science & Technology (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

TW110119407A 2020-05-29 2021-05-28 反應型磷酸鹽及其製造方法 TW202144372A (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
PCT/CN2020/093358 WO2021237695A1 (fr)	2020-05-29	2020-05-29	Phosphate de type réactif et procédé de préparation
WOPCT/CN2020/093358		2020-05-29

Publications (1)

Publication Number	Publication Date
TW202144372A true TW202144372A (zh)	2021-12-01

Family

ID=78745442

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW110119407A TW202144372A (zh)	2020-05-29	2021-05-28	反應型磷酸鹽及其製造方法

Country Status (3)

Country	Link
CN (1)	CN115698157A (fr)
TW (1)	TW202144372A (fr)
WO (1)	WO2021237695A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN115536693A (zh) *	2022-10-31	2022-12-30	珠海宏昌电子材料有限公司	一种含磷阻燃剂及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4062909A (en) *	1974-04-08	1977-12-13	Monsanto Company	Phosphoroamidates
JPH07278318A (ja) *	1994-04-08	1995-10-24	Asahi Chem Ind Co Ltd	難燃性ｃｄ−ｒｏｍ帰属部品
CN1188421C (zh) *	1999-06-28	2005-02-09	大八化学工业株式会社	制备缩聚磷酸酯的方法
JP2010077333A (ja) *	2008-09-29	2010-04-08	Fuji Electric Fa Components & Systems Co Ltd	難燃性樹脂組成物
EP2982732B1 (fr) *	2013-04-01	2018-04-18	Adeka Corporation	Composition d'agent ignifugeant, fibre ignifugée par traitement avec ladite composition, et procédé pour accroître la quantité de composant ignifugeant adhérant aux fibres faisant appel à ladite composition
WO2016029453A1 (fr) *	2014-08-29	2016-03-03	Blue Cube Ip Llc	Compositions ignifuges et exemptes d'halogène à faible dilatation thermique pour cartes de câblage imprimé de haute densité
CN110938234B (zh) *	2018-09-25	2021-06-08	中山台光电子材料有限公司	阻燃性化合物、其制造方法、树脂组合物及其制品

2020
- 2020-05-29 WO PCT/CN2020/093358 patent/WO2021237695A1/fr not_active Ceased
- 2020-05-29 CN CN202080101474.9A patent/CN115698157A/zh active Pending
2021
- 2021-05-28 TW TW110119407A patent/TW202144372A/zh unknown

Also Published As

Publication number	Publication date
WO2021237695A1 (fr)	2021-12-02
CN115698157A (zh)	2023-02-03

Publication	Publication Date	Title
CN109762115B (zh)	2021-10-01	一种树脂组合物及其应用
TW201524989A (zh)	2015-07-01	乙烯苄基醚化－ｄｏｐｏ化合物樹脂組合物及其製備和應用
TW201623372A (zh)	2016-07-01	聚苯醚樹脂、聚苯醚樹脂的製造方法、聚苯醚預聚物及樹脂組成物
JP2013023517A (ja)	2013-02-04	ポリフェニレンエーテル樹脂組成物、樹脂ワニス、プリプレグ、金属張積層板、及びプリント配線板
JP6487891B2 (ja)	2019-03-20	リン含有化合物およびその製造方法
TWI742643B (zh)	2021-10-11	一種樹脂組合物以及使用其的預浸片及絕緣板
TW201723020A (zh)	2017-07-01	酚芴改質的聚苯醚
JP2017088600A5 (fr)	2019-02-14
TWI887423B (zh)	2025-06-21	無鹵素的極低損耗樹脂組合物
TW202144372A (zh)	2021-12-01	反應型磷酸鹽及其製造方法
CN117486933A (zh)	2024-02-02	一种咪唑类阻燃固化剂、其制备方法及应用
TWI596155B (zh)	2017-08-21	Halogen-free thermosetting resin composition and prepreg and printed circuit laminate using the same
CN113773603B (zh)	2025-03-28	一种含磷乙烯基苯聚苯醚及其树脂组合物和应用
JP4402659B2 (ja)	2010-01-20	新規なエポキシ樹脂および非ハロゲン系難燃性エポキシ樹脂組成物
CN108219434B (zh)	2020-01-31	一种热固性树脂组合物、预浸料以及层压板
CN112480373A (zh)	2021-03-12	一种阻燃性环氧树脂组合物及其制备方法和应用
TWI776432B (zh)	2022-09-01	含磷化合物、包含其的環氧樹脂及複合層壓結構
JP7557119B2 (ja)	2024-09-27	難燃性樹脂組成物
CN114230793A (zh)	2022-03-25	改性双马来酰亚胺预聚物及制备方法、应用
JPH01223158A (ja)	1989-09-06	難燃性フェノール樹脂組成物
CN107337697A (zh)	2017-11-10	含dopo基的磷腈化合物、塑封料及复合金属基板
CN118546175B (zh)	2024-10-11	一种生物基阻燃增韧固化剂及其制备方法和应用
TWI765504B (zh)	2022-05-21	低膨脹係數低介電損耗高剛性無鹵樹脂組成物、積層板以及印刷電路板
TWI901471B (zh)	2025-10-11	樹脂組成物、包含其的預浸體以及覆金屬積層板
JP2004091748A (ja)	2004-03-25	難燃性硬化性樹脂組成物