TW202543902A - Transferring device and method for producing n security documents - Google Patents
Transferring device and method for producing n security documentsInfo
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- TW202543902A TW202543902A TW114106047A TW114106047A TW202543902A TW 202543902 A TW202543902 A TW 202543902A TW 114106047 A TW114106047 A TW 114106047A TW 114106047 A TW114106047 A TW 114106047A TW 202543902 A TW202543902 A TW 202543902A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F11/00—Rotary presses or machines having forme cylinders carrying a plurality of printing surfaces, or for performing letterpress, lithographic, or intaglio processes selectively or in combination
- B41F11/02—Rotary presses or machines having forme cylinders carrying a plurality of printing surfaces, or for performing letterpress, lithographic, or intaglio processes selectively or in combination for securities
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/20—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by magnetic fields
- B05D3/207—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by magnetic fields post-treatment by magnetic fields
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F1/00—Platen presses, i.e. presses in which printing is effected by at least one essentially-flat pressure-applying member co-operating with a flat type-bed
- B41F1/26—Details
- B41F1/38—Platens or type-beds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F13/00—Common details of rotary presses or machines
- B41F13/08—Cylinders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F13/00—Common details of rotary presses or machines
- B41F13/08—Cylinders
- B41F13/10—Forme cylinders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F13/00—Common details of rotary presses or machines
- B41F13/54—Auxiliary folding, cutting, collecting or depositing of sheets or webs
- B41F13/56—Folding or cutting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F19/00—Apparatus or machines for carrying out printing operations combined with other operations
- B41F19/002—Apparatus or machines for carrying out printing operations combined with other operations with means for applying specific material other than ink
- B41F19/005—Apparatus or machines for carrying out printing operations combined with other operations with means for applying specific material other than ink with means for applying metallic, conductive or chargeable material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F23/00—Devices for treating the surfaces of sheets, webs, or other articles in connection with printing
- B41F23/04—Devices for treating the surfaces of sheets, webs, or other articles in connection with printing by heat drying, by cooling, by applying powders
- B41F23/044—Drying sheets, e.g. between two printing stations
- B41F23/045—Drying sheets, e.g. between two printing stations by radiation
- B41F23/0453—Drying sheets, e.g. between two printing stations by radiation by ultraviolet dryers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/369—Magnetised or magnetisable materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/23—Magnetisable or magnetic paints or lacquers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F23/00—Devices for treating the surfaces of sheets, webs, or other articles in connection with printing
- B41F23/04—Devices for treating the surfaces of sheets, webs, or other articles in connection with printing by heat drying, by cooling, by applying powders
- B41F23/0403—Drying webs
- B41F23/0406—Drying webs by radiation
- B41F23/0409—Ultraviolet dryers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/01—Magnetic additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Printing Methods (AREA)
- Paints Or Removers (AREA)
Abstract
Description
本發明係關於一種用於對片狀磁性或可磁化顏料粒子進行定向的傳送裝置。本發明進一步係關於用於此傳送裝置的磁性定向單元、包含此種傳送裝置的印刷機、及用於產生N個安全文件的方法。This invention relates to a conveying device for orienting sheet-like magnetic or magnetizable pigment particles. Further, this invention relates to a magnetic orientation unit for this conveying device, a printing press including such a conveying device, and a method for generating N security documents.
此項技術中已知例如在安全文件領域中使用包含定向的磁性或可磁化顏料粒子、特別是亦光學可變的磁性或可磁化顏料粒子的油墨、組合物、塗層或層來產生安全元件。例如,US 2,570,856;US 3,676,273;US 3,791,864;US 5,630,877及US 5,364,689中揭示了包含定向的磁性或可磁化顏料粒子的塗層或層。例如WO 2002/090002 A2中已經揭示了包含定向的磁性色移顏料粒子的塗層或層,該等塗層或層產生特別吸引人的光學效應,可用於保護安全文件。In this art, it is known, for example, to use inks, compositions, coatings, or layers containing oriented magnetic or magnetizable pigment particles, particularly optically variable magnetic or magnetizable pigment particles, to create security elements in the field of secure documents. For example, coatings or layers containing oriented magnetic or magnetizable pigment particles are disclosed in US 2,570,856; US 3,676,273; US 3,791,864; US 5,630,877 and US 5,364,689. For example, WO 2002/090002 A2 discloses coatings or layers containing oriented magnetic color-shifting pigment particles that produce particularly attractive optical effects and can be used to protect secure documents.
印刷油墨或塗層中的磁性或可磁化顏料粒子允許經由以下操作產生磁感應影像、設計及/或圖案:施加對應的磁場,從而在未硬化的塗層中導致磁性或可磁化顏料粒子的局部定向,然後對塗層進行硬化。結果係固定的磁感應影像、設計或圖案(此項技術中稱為光學效應層(optical effect layer,OEL))。以此方式,可產生對偽造有很強抵抗力的磁感應圖案。所討論的安全元件只能藉由能夠使用以下兩者來產生:磁性或可磁化顏料粒子或對應的油墨,以及用於印刷該油墨及在印刷油墨中定向該顏料的特定技術。Magnetic or magnetizable pigment particles in printing inks or coatings allow for the creation of magnetically induced images, designs, and/or patterns by applying a corresponding magnetic field, thereby causing localized orientation of the magnetic or magnetizable pigment particles in the uncured coating, followed by curing the coating. The result is a fixed magnetically induced image, design, or pattern (referred to in this technique as an optical effect layer (OEL)). In this way, magnetically induced patterns with strong resistance to forgery can be produced. The security element discussed can only be generated using both: magnetic or magnetizable pigment particles or corresponding ink, and specific techniques for printing the ink and orienting the pigment within the ink.
上述光學效應層(optical effect layer,OEL)通常使用印刷機獲得,印刷機輸送印刷有OEL的基板且包括用於以下各項的區段:(a)將包含磁性或可磁化顏料粒子的油墨、組合物、塗層或層塗覆於基板上,(b)使用磁場對磁性或可磁化顏料粒子進行定向,及(c)對包含定向的磁性或可磁化顏料粒子的油墨、組合物、塗層或層進行硬化。為了使用磁場對磁性或可磁化顏料粒子進行定向,印刷機可包含傳送裝置,傳送裝置包括產生磁場並與基板一起旋轉的圓柱體,或產生磁場的平板體,基板放置於平板體上。The aforementioned optical effect layer (OEL) is typically obtained using a printing press, which transports a substrate printed with the OEL and includes sections for: (a) applying an ink, composition, coating, or layer containing magnetic or magnetizable pigment particles onto the substrate; (b) orienting the magnetic or magnetizable pigment particles using a magnetic field; and (c) curing the ink, composition, coating, or layer containing the oriented magnetic or magnetizable pigment particles. To orient the magnetic or magnetizable pigment particles using a magnetic field, the printing press may include a conveying device comprising a cylinder that generates a magnetic field and rotates with the substrate, or a flat plate that generates a magnetic field, on which the substrate is placed.
鈔票印刷(包括聚合物鈔票印刷)通常利用自動饋紙印刷機來執行。為了提高印刷的效率,一張紙張包含沿著多個行及多個列配置的多張鈔票。在印刷製程結束時,藉由在列及行之間切割紙張來獲得個別鈔票。Banknote printing (including polymer banknote printing) is typically performed using an automated feeder printing press. To improve printing efficiency, a single sheet of paper contains multiple banknotes arranged along multiple rows and columns. At the end of the printing process, individual banknotes are obtained by cutting the paper between the columns and rows.
出於安全原因及防偽能力的考慮,以及為了確保使用者對貨幣的信任及使用者毫無疑問地識別鈔票並將其與偽鈔區分開的能力,至關重要的是,所有鈔票都顯示出完全相同的外觀,而不管它們在印刷製程期間在紙張上的位置如何。換言之,希望紙張的第一個、最後一個或任何中心線或行的鈔票具有與同一紙張的所有其他鈔票及其他張紙的所有鈔票完全相同的最終外觀。For security and anti-counterfeiting reasons, and to ensure users' trust in the currency and their ability to identify and distinguish banknotes from counterfeit ones without any doubt, it is crucial that all banknotes exhibit the exact same appearance, regardless of their position on the paper during the printing process. In other words, it is desirable that the first, last, or any banknote along the center line or row of a sheet of paper has the exact same final appearance as all other banknotes on the same sheet and all banknotes on other sheets of paper.
本發明的目標係改進在同一基板上產生N個安全文件。The goal of this invention is to improve the generation of N security files on the same substrate.
根據第一態樣,提供一種傳送裝置,用於對包含在輻射可固化塗層組合物中並塗覆於基板上的片狀磁性或可磁化顏料粒子進行定向。該傳送裝置係平板式傳送裝置或圓柱形傳送裝置。該傳送裝置包含:N個相同的磁性塊,該等磁性塊沿著設置在傳送裝置的外表面上的對準線對準,該等磁性塊各自包括M個磁場產生裝置,該等磁場產生裝置各自產生對應的磁場,使得該等磁性塊各自產生塊磁場,N大於或等於二,且M大於或等於一;及設置在每兩個相鄰磁性塊之間的屏蔽元件,該屏蔽元件由至少部分地將每個磁性塊的塊磁場與其他磁性塊的塊磁場隔離的材料製成。According to the first embodiment, a conveying device is provided for orienting sheet-like magnetic or magnetizable pigment particles contained in a radiation-curable coating composition and coated on a substrate. The conveying device is either a flat-plate conveying device or a cylindrical conveying device. The transmission device comprises: N identical magnetic blocks aligned along alignment lines disposed on the outer surface of the transmission device, each magnetic block including M magnetic field generating devices that generate corresponding magnetic fields, such that each magnetic block generates a block magnetic field, where N is greater than or equal to two and M is greater than or equal to one; and a shielding element disposed between every two adjacent magnetic blocks, the shielding element being made of a material that at least partially isolates the block magnetic field of each magnetic block from the block magnetic fields of other magnetic blocks.
在沒有屏蔽元件的情況下,傳送裝置的相鄰磁場產生裝置在配置成彼此靠近的情況下可能產生重疊的磁場,這可能導致對磁性或可磁化顏料粒子進行定向的磁場沿著基板的不規則性。特別地,第1個及第N個磁性塊(位於平板式傳送裝置或「展開的」圓柱形傳送裝置的邊緣上)各自沿著對準線僅具有一個相鄰磁性塊,而第2個至第(N-1)個磁性塊(位於傳送裝置的更中心處)沿著對準線具有兩個相鄰磁性塊。由於相鄰磁性塊的數目的此差異,對磁性或可磁化顏料粒子進行定向的磁場沿著對準線各處並不相同,從而導致印刷在基板不同區段上(例如不同的鈔票或其他安全文件上)的安全特徵之間出現不良差異。Without shielding elements, adjacent magnetic field generating devices of the conveying device may generate overlapping magnetic fields when configured close to each other. This could lead to irregularities in the magnetic field that orients magnetic or magnetizable pigment particles along the substrate. Specifically, the first and Nth magnetic blocks (located on the edge of the flat conveying device or the "unfolded" cylindrical conveying device) each have only one adjacent magnetic block along the alignment line, while the second to (N-1)th magnetic blocks (located more centrally in the conveying device) have two adjacent magnetic blocks along the alignment line. Due to this difference in the number of adjacent magnetic blocks, the magnetic field that orients the magnetic or magnetizable pigment particles is not the same along the alignment line, resulting in undesirable differences in security features printed on different sections of the substrate (e.g., on different banknotes or other security documents).
屏蔽元件可允許克服此問題並防止相鄰磁性塊彼此影響。這樣,對磁性或可磁化顏料粒子進行定向的相同塊磁場沿著對準線施加至在基板上形成的每個安全文件(一個安全文件具有由一個磁性塊定向的顏料粒子)。有利地,可形成相同的安全文件。Shielding elements allow this problem to be overcome and prevent adjacent magnetic blocks from interfering with each other. In this way, the same block magnetic field, oriented to the magnetic or magnetizable pigment particles, is applied along the alignment line to each security document formed on the substrate (a security document has pigment particles oriented by one magnetic block). Advantageously, identical security documents can be formed.
傳送裝置可為印刷機的一部分,其容納用於對磁性或可磁化顏料粒子進行定向的磁性塊。傳送裝置可具有圓柱形形狀且繞軸線旋轉從而輸送基板,或者它可具有平板形狀,基板可放置至其上。The conveying device can be part of a printing press and houses a magnetic block for orienting magnetic or magnetizable pigment particles. The conveying device can be cylindrical in shape and rotate about an axis to transport a substrate, or it can be flat in shape on which the substrate can be placed.
與可被視為準一維粒子的針狀顏料粒子相反,片狀顏料粒子由於其尺寸的縱橫比較大而成為準二維粒子。片狀顏料粒子可被視為二維結構,其中尺寸X及Y大體上大於尺寸Z。片狀顏料粒子在此項技術中可稱為扁圓粒子或薄片。此類顏料粒子可被描述為具有對應於它們跨顏料粒子的最長尺寸的主軸X以及垂直於X且對應於跨顏料粒子的第二最長尺寸的第二軸Y。換言之,XY平面粗略地定義由顏料粒子的第一及第二最長尺寸形成的平面,Z尺寸被忽略。In contrast to needle-shaped pigment particles, which can be considered quasi-one-dimensional particles, plate-shaped pigment particles are quasi-two-dimensional particles due to their larger aspect ratio. Plate-shaped pigment particles can be viewed as two-dimensional structures, where dimensions X and Y are generally larger than dimension Z. In this technique, plate-shaped pigment particles may be referred to as flattened oval particles or flakes. Such pigment particles can be described as having a principal axis X corresponding to their longest dimension across the pigment particle and a second axis Y perpendicular to X and corresponding to the second longest dimension across the pigment particle. In other words, the XY plane is roughly defined by the plane formed by the first and second longest dimensions of the pigment particle, while the Z dimension is ignored.
本文所述的片狀磁性或可磁化顏料粒子由於其非球形形狀而對於入射電磁輻射具有非各向同性反射率,硬化/固化的黏合劑材料對於入射電磁輻射係至少部分透明的。如本文所使用,術語「非各向同性反射率」表示來自第一角度的入射輻射由粒子反射至特定(觀察)方向(第二角度)的比例隨粒子的定向而變,即,粒子的定向相對於第一角度的變化可導致反射至觀察方向的不同量值。The sheet-like magnetic or magnetizable pigment particles described herein exhibit anisotropic reflectivity to incident electromagnetic radiation due to their non-spherical shape, and the hardened/cured adhesive material is at least partially transparent to incident electromagnetic radiation. As used herein, the term "anisotropic reflectivity" means that the proportion of incident radiation from a first angle reflected by the particle to a specific (observational) direction (second angle) varies with the orientation of the particle; that is, a change in the particle's orientation relative to the first angle can result in different amounts of reflection to the observational direction.
片狀磁性或可磁化顏料粒子分散在塗層中,該層包含硬化的黏合劑材料,黏合劑材料固定片狀磁性或可磁化顏料粒子的定向。如本文所使用,術語「層」係指至少部分固化的塗層,其中片狀磁性或可磁化顏料粒子的定向係固定/凍結的(另一方面,術語「組合物」特別係指油墨)。黏合劑材料至少處於其硬化或固體狀態(本文中亦稱為第二狀態),對於在200 nm與2500 nm之間(即,在通常稱為「光譜」且包含電磁譜的紅外線、可見光及紫外線部分的波長範圍內)包含的波長範圍的電磁輻射係至少部分透明的。因此,在此範圍內的一些波長下,可經由黏合劑材料感知到在處於其硬化或固體狀態的黏合劑材料中包含的粒子及其與定向相關的反射率。較佳地,硬化的黏合劑材料對於在200 nm與800 nm之間包含的、更佳地在400 nm與700 nm之間包含的電磁輻射係至少部分透明的。本文中,術語「透明」表示電磁輻射穿過光學特徵中存在的一層20 μm的硬化的黏合劑材料(不包括片狀磁性或可磁化顏料粒子,但包括光學特徵中的所有其他可選組分(在存在此類組分的情況下))的透射在所關注的波長下為至少50%,更佳地至少60%,甚至更佳地至少70%。這可例如藉由根據完善的測試方法(例如DIN 5036-3 (1979-11))量測硬化的黏合劑材料(不包括片狀磁性或可磁化顏料粒子)的測試件的透射率來判定。Flaky magnetic or magnetizable pigment particles are dispersed in a coating layer comprising a hardened binder material that fixes the orientation of the flaky magnetic or magnetizable pigment particles. As used herein, the term "layer" refers to a coating layer that is at least partially cured, wherein the orientation of the flaky magnetic or magnetizable pigment particles is fixed/frozen (on the other hand, the term "composition" specifically refers to an ink). The binder material is at least in its hardened or solid state (also referred to herein as the second state) and is at least partially transparent to electromagnetic radiation in the wavelength range encompassed between 200 nm and 2500 nm (i.e., within the wavelength range commonly referred to as the "spectrum" and including the infrared, visible, and ultraviolet portions of the electromagnetic spectrum). Therefore, at certain wavelengths within this range, the particles contained in the adhesive material in its hardened or solid state and their orientation-related reflectivity can be perceived by the adhesive material. Preferably, the hardened adhesive material is at least partially transparent to electromagnetic radiation contained between 200 nm and 800 nm, more preferably between 400 nm and 700 nm. Herein, the term "transparent" means that the transmission of electromagnetic radiation through a 20 μm layer of hardened adhesive material present in the optical feature (excluding sheet-like magnetic or magnetizable pigment particles, but including all other optional components in the optical feature (where such components are present)) is at least 50% at the wavelength of interest, more preferably at least 60%, and even more preferably at least 70%. This can be determined, for example, by measuring the transmittance of a test specimen of a hardened adhesive material (excluding sheet-like magnetic or magnetizable pigment particles) according to a well-established test method (e.g., DIN 5036-3 (1979-11)).
本文所述的片狀磁性或可磁化顏料粒子被定義為由於其非球形形狀而對於入射電磁輻射具有非各向同性反射率,固化的黏合劑材料對於入射電磁輻射係至少部分透明的。如本文所使用,術語「非各向同性反射率」表示來自第一角度的入射輻射由粒子反射至特定(觀察)方向(第二角度)的比例隨粒子的定向而變,即,粒子的定向相對於第一角度的變化可導致反射至觀察方向的不同量值。較佳地,本文所述的片狀磁性或可磁化顏料粒子在約200 nm至約2500 nm、更佳地約400 nm至約700 nm的某些部分或整個波長範圍內對於入射電磁輻射具有非各向同性反射率,使得粒子定向的變化導致該粒子向某個方向的反射的變化。如熟習此項技術者已知的,本文所述的磁性或可磁化顏料粒子與習知顏料的不同之處在於,該等習知顏料粒子表現出與粒子定向無關的相同顏色及反射率,而本文所述的磁性或可磁化顏料粒子表現出取決於粒子定向的反射或顏色或兩者。The sheet-like magnetic or magnetizable pigment particles described herein are defined as having anisotropic reflectivity to incident electromagnetic radiation due to their non-spherical shape, and the cured adhesive material is at least partially transparent to incident electromagnetic radiation. As used herein, the term "anisotropic reflectivity" means that the proportion of incident radiation from a first angle reflected by the particle to a specific (observational) direction (second angle) varies with the orientation of the particle; that is, a change in the orientation of the particle relative to the first angle can result in different amounts of reflection to the observation direction. Preferably, the sheet-like magnetic or magnetizable pigment particles described herein have anisotropic reflectivity to incident electromagnetic radiation in certain portions or throughout the wavelength range of about 200 nm to about 2500 nm, more preferably about 400 nm to about 700 nm, such that a change in particle orientation results in a change in the amount of reflection of the particle in a certain direction. As will be known to those skilled in the art, the magnetic or magnetizable pigment particles described herein differ from conventional pigments in that conventional pigment particles exhibit the same color and reflectivity regardless of particle orientation, while the magnetic or magnetizable pigment particles described herein exhibit reflectivity or color, or both, depending on particle orientation.
本文所述的輻射可固化塗層組合物以及本文所述的塗層包含本文所述的片狀磁性或可磁化顏料粒子,其數量較佳為約1 wt%及約40 wt%,較佳地在約3 wt%與約35 wt%之間,更佳地在約5 wt%與約30 wt%之間,重量百分比係基於輻射可固化塗層組合物或塗層的總重量。The radiation-curable coating compositions and coatings described herein comprise the sheet-like magnetic or magnetizable pigment particles described herein, preferably in quantities of about 1 wt% and about 40 wt%, more preferably between about 3 wt% and about 35 wt%, and more preferably between about 5 wt% and about 30 wt%, the weight percentages being based on the total weight of the radiation-curable coating compositions or coatings.
本文所述的片狀磁性或可磁化顏料粒子的合適實例包括但不限於包含以下各項的顏料粒子:選自由鈷(Co)、鐵(Fe)及鎳(Ni)組成的組的磁性金屬;鐵、錳、鈷、鎳或其中兩者或更多者的混合物的磁性合金;鉻、錳、鈷、鐵、鎳或其中兩者或更多者的混合物的磁性氧化物;或其中兩者或更多者的混合物。涉及金屬、合金及氧化物的術語「磁性」係指鐵磁性或亞鐵磁性金屬、合金及氧化物。鉻、錳、鈷、鐵、鎳或其中兩者或更多者的混合物的磁性氧化物可為純氧化物或混合氧化物。磁性氧化物的實例包括但不限於鐵氧化物,諸如赤鐵礦(Fe2O3)、磁鐵礦(Fe3O4)、二氧化鉻(CrO2)、磁性鐵氧體(MFe2O4)、磁性尖晶石(MR2O4)、磁性六角鐵氧體(MFe12O19)、磁性正鐵氧體(RFeO3)、磁性石榴石M3R2(AO4)3,其中M代表二價金屬,R代表三價金屬,A代表四價金屬。Suitable examples of the sheet-like magnetic or magnetizable pigment particles described herein include, but are not limited to, pigment particles comprising: magnetic metals selected from the group consisting of cobalt (Co), iron (Fe), and nickel (Ni); magnetic alloys of iron, manganese, cobalt, nickel, or mixtures thereof; magnetic oxides of chromium, manganese, cobalt, iron, nickel, or mixtures thereof; or mixtures thereof. The term "magnetic" in relation to metals, alloys, and oxides refers to ferromagnetic or ferrimagnetic metals, alloys, and oxides. Magnetic oxides of chromium, manganese, cobalt, iron, nickel, or mixtures thereof may be pure oxides or mixed oxides. Examples of magnetic oxides include, but are not limited to , iron oxides, such as hematite ( Fe₂O₃ ), magnetite ( Fe₃O₄ ), chromium dioxide ( CrO₂ ), magnetic ferrite ( MFe₂O₄ ), magnetic spinel ( MR₂O₄ ), magnetic hexagonal ferrite ( MFe¹²O¹⁹ ), magnetic orthoferrite ( RFeO₃ ), and magnetic garnet M₃R₂ ( AO₄ ) ₃ , where M represents a divalent metal, R represents a trivalent metal, and A represents a tetravalent metal.
本文所述的片狀磁性或可磁化顏料粒子的實例包括但不限於包含由以下中之一或多者製成的磁性層M的顏料粒子:諸如鈷(Co)、鐵(Fe)或鎳(Ni)的磁性金屬;及鐵、鈷或鎳的磁性合金,其中該等磁性或可磁化顏料粒子可為包含一或多個額外層的多層結構。較佳地,一或多個額外層為:層A,其獨立地由選自由金屬氟化物(諸如氟化鎂(MgF2))、氧化矽(SiO)、二氧化矽(SiO2)、氧化鈦(TiO2)及氧化鋁(Al2O3) (更佳地為二氧化矽(SiO2))組成的組的一或多者製成;或層B,其獨立地由選自由金屬及金屬合金組成的組,較佳地選自由反射金屬及反射金屬合金組成的組,且更佳地選自由銀(Ag)、鋁(Al)、鉻(Cr)及鎳(Ni) (且還更佳地為鋁(Al))組成的組的一或多者製成;或者一或多個層A (諸如上文所述的層A)及一或多個層B(諸如上文所述的層B)之組合。作為上文所述的多層結構的片狀磁性或可磁化顏料粒子的典型實例包括但不限於A/M多層結構、A/M/A多層結構、A/M/B多層結構、A/B/M/A多層結構、A/B/M/B多層結構、A/B/M/B/A/多層結構、B/M多層結構、B/M/B多層結構、M/A/M多層結構、B/A/M/A多層結構、B/A/M/B多層結構、B/A/M/B/A/多層結構、B/A/M/A/B多層結構、B/A/B/A/M/A/B/A/B多層結構、A/B/A/B/A/M/A/B/A/B/A多層結構,其中層A、磁性層M及層B選自上文所述的層。Examples of sheet-like magnetic or magnetizable pigment particles described herein include, but are not limited to, pigment particles comprising a magnetic layer M made of one or more of the following: magnetic metals such as cobalt (Co), iron (Fe), or nickel (Ni); and magnetic alloys of iron, cobalt, or nickel, wherein such magnetic or magnetizable pigment particles may be multilayer structures comprising one or more additional layers. Preferably, one or more additional layers are: layer A, which is independently made of one or more of the group consisting of metallic fluorides (such as magnesium fluoride ( MgF2 )), silicon oxide (SiO), silicon dioxide ( SiO2 ), titanium oxide ( TiO2 ), and aluminum oxide ( Al2O3 ) (more preferably silicon dioxide ( SiO2 )); or layer B, which is independently made of one or more of the group consisting of metals and metal alloys, more preferably the group consisting of reflective metals and reflective metal alloys, and more preferably the group consisting of silver (Ag), aluminum (Al), chromium (Cr), and nickel (Ni) (and even more preferably aluminum (Al)); or one or more layers A (such as layer A as described above) and a combination of one or more layers B (such as layer B as described above). Typical examples of sheet-like magnetic or magnetizable pigment particles as multilayer structures as described above include, but are not limited to, A/M multilayer structures, A/M/A multilayer structures, A/M/B multilayer structures, A/B/M/A multilayer structures, A/B/M/B multilayer structures, A/B/M/B/A multilayer structures, B/M multilayer structures, B/M/B multilayer structures, M/A/M multilayer structures, etc. Layered structure, B/A/M/A multilayered structure, B/A/M/B multilayered structure, B/A/M/B/A/ multilayered structure, B/A/M/A/B multilayered structure, B/A/B/A/M/A/B/A/B multilayered structure, A/B/A/B/A/M/A/B/A/B/A multilayered structure, wherein layer A, magnetic layer M, and layer B are selected from the layers described above.
可固化塗層組合物可為紫外光-可見光輻射可固化塗層組合物,且可包含片狀光學可變的磁性或可磁化顏料粒子,及/或不具有光學可變性質的片狀磁性或可磁化顏料粒子。較佳地,本文所述的片狀磁性或可磁化顏料粒子的至少一部分由片狀光學可變的磁性或可磁化顏料粒子構成。除了由光學可變的磁性或可磁化顏料粒子的色移性質提供的顯性安全(這允許使用人類無輔助的感官來容易地檢測、辨識及/或辨別帶有包含本文所述的光學可變的磁性或可磁化顏料粒子的油墨、塗層組合物或塗層的物品或安全文件與其可能的偽造品)之外,光學可變的磁性或可磁化顏料粒子的光學性質亦可用作用於辨識光學特徵的機器可讀工具。因此,光學可變的磁性或可磁化顏料粒子的光學性質可同時用作鑑認過程中的隱性或半隱性安全特徵,其中對顏料粒子的光學(例如光譜)性質進行分析且因此增加防偽能力。The curable coating composition may be an ultraviolet-visible radiant curable coating composition and may contain sheet-like optically variable magnetic or magnetizable pigment particles, and/or sheet-like magnetic or magnetizable pigment particles that do not have optically variable properties. Preferably, at least a portion of the sheet-like magnetic or magnetizable pigment particles described herein are composed of sheet-like optically variable magnetic or magnetizable pigment particles. In addition to the explicit security provided by the color-shifting properties of optically variable magnetic or magnetizable pigment particles (which allows for easy detection, identification, and/or differentiation of articles or security documents containing inks, coating compositions, or coatings containing the optically variable magnetic or magnetizable pigment particles described herein, and their potential counterfeits using unassisted human senses), the optical properties of optically variable magnetic or magnetizable pigment particles can also be used to act on machine-readable tools that identify optical features. Therefore, the optical properties of optically variable magnetic or magnetizable pigment particles can simultaneously serve as implicit or semi-implicit security features in the authentication process, where the optical (e.g., spectral) properties of the pigment particles are analyzed, thus increasing the ability to prevent counterfeiting.
在塗層中使用片狀光學可變的磁性或可磁化顏料粒子來產生光學特徵提高了光學特徵作為安全特徵在安全文件應用中的重要性,因為此類材料保留給安全文件印刷工業且不可供公眾購買。The use of sheet-like, optically variable, magnetic, or magnetizable pigment particles in coatings to produce optical features enhances the importance of optical features as security features in security document applications, as such materials are reserved for the security document printing industry and are not available for public purchase.
如上所述,較佳地,片狀磁性或可磁化顏料粒子的至少一部分由片狀光學可變的磁性或可磁化顏料粒子構成。此等更佳地選自由片狀磁性薄膜干涉顏料粒子或片狀干涉塗佈式顏料粒子組成的組。As described above, preferably, at least a portion of the sheet-like magnetic or magnetizable pigment particles are composed of sheet-like optically variable magnetic or magnetizable pigment particles. More preferably, they are composed of sheet-like magnetic thin-film interference pigment particles or sheet-like interference coated pigment particles.
磁性薄膜干涉顏料粒子係熟習此項技術者已知的且例如在US 4,838,648;WO 2002/073250 A2;EP 0 686 675 B1;WO 2003/000801 A2;US 6,838,166;WO 2007/131833 A1;EP 2 402 401 B1;WO 2019/103937 A1;EP 3 587 500 A1;EP 3 587 501 A1;EP 3 587 502 A1;EP 3 587503 A1;WO 2020/006286 A1;WO 2020/131700 A1;US 2021/0101402;US 2021/038812;US 2022/0282094以及其中所引用的文件中已揭示。較佳地,磁性薄膜干涉顏料粒子包含具有五層法布立-培若多層結構的顏料粒子及/或具有六層法布立-培若多層結構的顏料粒子及/或具有七層法布里-珀羅多層結構的顏料粒子及/或具有九層法布里-珀羅多層結構的顏料粒子及/或具有十一層法布里-珀羅多層結構的顏料粒子及/或具有結合了一或多種多層法布立-培若結構的多層結構的顏料粒子。Magnetic thin-film interference pigment particles are known to those skilled in the art and are cited, for example, in US 4,838,648; WO 2002/073250 A2; EP 0 686 675 B1; WO 2003/000801 A2; US 6,838,166; WO 2007/131833 A1; EP 2 402 401 B1; WO 2019/103937 A1; EP 3 587 500 A1; EP 3 587 501 A1; EP 3 587 502 A1; EP 3 587503 A1; WO 2020/006286 A1; WO 2020/131700 A1; US 2021/0101402; US As disclosed in US 2021/038812; US 2022/0282094 and the documents referenced therein. Preferably, the magnetic thin film interference pigment particles comprise pigment particles having a five-layer Fabry-Perot multilayer structure and/or pigment particles having a six-layer Fabry-Perot multilayer structure and/or pigment particles having a seven-layer Fabry-Perot multilayer structure and/or pigment particles having a nine-layer Fabry-Perot multilayer structure and/or pigment particles having an eleven-layer Fabry-Perot multilayer structure and/or pigment particles having a multilayer structure combining one or more multilayer Fabry-Perot structures.
較佳的五層法布立-培若多層結構由吸收體/介電質/反射體/介電質/吸收體多層結構組成,其中反射體及/或吸收體亦為磁性層,較佳地,反射體及/或吸收體為:包含鎳、鐵及/或鈷的磁性層;及/或包含鎳、鐵及/或鈷的磁性合金;及/或包含鎳(Ni)、鐵(Fe)及/或鈷(Co)的磁性氧化物。A preferred five-layer Fabry-Perot multilayer structure is composed of an absorber/dielectric/reflector/dielectric/absorber multilayer structure, wherein the reflector and/or absorber are also magnetic layers. Preferably, the reflector and/or absorber are: magnetic layers containing nickel, iron and/or cobalt; and/or magnetic alloys containing nickel, iron and/or cobalt; and/or magnetic oxides containing nickel (Ni), iron (Fe) and/or cobalt (Co).
其他較佳的五層法布立-培若多層結構由介電質/反射體/磁性/反射體/介電質多層結構組成。Other superior five-layer Fabry-Perot multilayer structures consist of a dielectric/reflector/magnetic/reflector/dielectric multilayer structure.
較佳的六層法布立-培若多層結構由吸收體/介電質/反射體/磁性/介電質/吸收體多層結構組成。The preferred six-layer Fabry-Perot multilayer structure consists of an absorber/dielectric/reflector/magnetic/dielectric/absorber multilayer structure.
較佳的七層法布立-培若多層結構由吸收體/介電質/反射體/磁性/反射體/介電質/吸收體多層結構組成,諸如US 4,838,648中所揭示的多層結構。Preferred seven-layer Fabry-Perot multilayer structures consist of absorber/dielectric/reflector/magnetic/reflector/dielectric/absorber multilayer structures, such as the multilayer structures disclosed in US 4,838,648.
較佳的九層法布立-培若多層結構由介電質/吸收體/介電質/反射體/磁性/介電質/吸收體/介電質多層結構組成。A preferred nine-layer Fabry-Perot multilayer structure consists of a dielectric/absorbing/dielectric/reflector/magnetic/dielectric/absorbing/dielectric multilayer structure.
較佳的十一層法布立-培若多層結構由吸收體/介電質/吸收體/介電質/反射體/磁性/反射體/介電質/吸收體/介電質/吸收體多層結構組成。The preferred eleven-layer Fabry-Perot multilayer structure consists of an absorber/dielectric/absorber/dielectric/reflector/magnetic/reflector/dielectric/absorber/dielectric/absorber multilayer structure.
較佳地,本文所述的反射體層獨立地由選自由金屬及金屬合金組成的組,較佳地選自由反射金屬及反射金屬合金組成的組,更佳地選自由鋁(Al)、銀(Ag)、銅(Cu)、金(Au)、鉑(Pt)、錫(Sn)、鈦(Ti)、鈀(Pd)、銠(Rh)、鈮(Nb)、鉻(Cr))、鎳(Ni)及其合金組成的組,甚至更佳地選自由鋁(Al)、鉻(Cr)、鎳(Ni)及其合金(且還更佳地為鋁(Al))組成的組的一或多者製成。較佳地,介電層獨立地由選自由金屬氟化物(諸如氟化鎂(MgF2)、氟化鋁(AlF3)、氟化鈰(CeF3)、氟化鑭(LaF3)、氟化鋁鈉(例如Na3AlF6)、氟化釹(NdF3)、氟化釤(SmF3)、氟化鋇(BaF2)、氟化鈣(CaF2)、氟化鋰(LiF))以及金屬氧化物(諸如氧化矽(SiO)、二氧化矽(SiO2)、氧化鈦(TiO2)、氧化鋁(Al2O3))組成的組,更佳地選自由氟化鎂(MgF2)及二氧化矽(SiO2) (且還更佳地為氟化鎂(MgF2))組成的組的一或多者製成。較佳地,吸收體層獨立地由選自由鋁(Al)、銀(Ag)、銅(Cu)、鈀(Pd)、鉑(Pt)、鈦(Ti)、釩(V)、鐵(Fe)、錫(Sn)、鎢(W)、鉬(Mo)、銠(Rh)、鈮(Nb)、鉻(Cr)、鎳(Ni)、其金屬氧化物、其金屬硫化物、其金屬碳化物及其金屬合金組成的組,更佳地選自由鉻(Cr)、鎳(Ni)、其金屬氧化物及其金屬合金組成的組,且還更佳地選自由鉻(Cr)、鎳(Ni)及其金屬合金組成的組的一或多者製成。較佳地,磁性層包含鎳(Ni)、鐵(Fe)及/或鈷(Co);及/或包含鎳(Ni)、鐵(Fe)及/或鈷(Co)的磁性合金;及/或包含鎳(Ni)、鐵(Fe)及/或鈷(Co)的磁性氧化物。當包含七層法布立-培若結構的磁性薄膜干涉顏料粒子為較佳時,特別較佳的是,磁性薄膜干涉顏料粒子包含由Cr/MgF2/Al/M/Al/MgF2/Cr多層結構組成的七層法布立-培若吸收體/介電質/反射體/磁性/反射體/介電質/吸收體多層結構,其中M為Ni、Fe或Co。Preferably, the reflector layer described herein is independently composed of the group consisting of metals and metal alloys, more preferably of reflective metals and reflective metal alloys, even more preferably of aluminum (Al), silver (Ag), copper (Cu), gold (Au), platinum (Pt), tin (Sn), titanium (Ti), palladium (Pd), rhodium (Rh), niobium (Nb), chromium (Cr)), nickel (Ni) and their alloys, and even more preferably of one or more of aluminum (Al), chromium (Cr), nickel (Ni) and their alloys (and even more preferably aluminum (Al)). Preferably, the dielectric layer is independently composed of the group consisting of metal fluorides (such as magnesium fluoride ( MgF₂ ), aluminum fluoride ( AlF₃ ), cerium fluoride ( CeF₃ ), lanthanum fluoride ( LaF₃ ), sodium aluminum fluoride (e.g., Na₃AlF₆ ), neodymium fluoride ( NdF₃ ), tungsten fluoride ( SmF₃ ), barium fluoride ( BaF₂ ), calcium fluoride ( CaF₂ ), and lithium fluoride (LiF)) and metal oxides (such as silicon oxide (SiO), silicon dioxide ( SiO₂ ), titanium oxide ( TiO₂ ), and aluminum oxide ( Al₂O₃ )), more preferably magnesium fluoride ( MgF₂ ) and silicon dioxide ( SiO₂ ) . (More preferably magnesium fluoride ( MgF₂ )) One or more of the group consisting of magnesium fluoride. Preferably, the absorber layer is independently made of the group consisting of aluminum (Al), silver (Ag), copper (Cu), palladium (Pd), platinum (Pt), titanium (Ti), vanadium (V), iron (Fe), tin (Sn), tungsten (W), molybdenum (Mo), rhodium (Rh), niobium (Nb), chromium (Cr), nickel (Ni), their metal oxides, their metal sulfides, their metal carbides and their metal alloys, more preferably the group consisting of chromium (Cr), nickel (Ni), their metal oxides and their metal alloys, and even more preferably the group consisting of chromium (Cr), nickel (Ni) and their metal alloys. Preferably, the magnetic layer comprises nickel (Ni), iron (Fe), and/or cobalt (Co); and/or a magnetic alloy comprising nickel (Ni), iron (Fe), and/or cobalt (Co); and/or a magnetic oxide comprising nickel (Ni), iron (Fe), and/or cobalt (Co). When the magnetic thin-film interference pigment particles comprising a seven-layer Fabry-Perot structure are preferred, particularly preferred, the magnetic thin-film interference pigment particles comprise a seven-layer Fabry-Perot absorber/dielectric/reflector/magnetic/reflector/dielectric/absorber multilayer structure composed of a Cr/ MgF₂ /Al/M/Al/ MgF₂ /Cr multilayer structure, wherein M is Ni, Fe, or Co.
本文所述的基板較佳地選自由紙或其他纖維材料組成的組,諸如纖維素、含紙材料、玻璃、金屬、陶瓷、塑膠及聚合物、金屬化塑膠或聚合物、至少部分失透的塑膠或聚合物複合材料及其中兩者或更多者的混合物或組合。典型的紙、紙狀或其他纖維材料由多種纖維製成,包括但不限於蕉麻、棉、亞麻、木漿及其混紡物。如熟習此項技術者所熟知的,棉及棉/亞麻混紡物較佳地用於鈔票,而木漿通常用於非鈔票安全文件中。塑膠及聚合物的典型實例包括:聚烯烴,諸如聚乙烯(polyethylene,PE)及聚丙烯(polypropylene,PP);聚醯胺;聚酯,諸如聚(對苯二甲酸乙二醇酯) (poly(ethylene terephthalate),PET)、聚(對苯二甲酸1,4-丁二醇酯) (poly(1,4-butylene terephthalate),PBT)、聚(2,6-萘甲酸乙二醇酯) (poly(ethylene 2,6-naphthoate),PEN);及聚氯乙烯(polyvinylchloride,PVC)。紡黏烯烴纖維,諸如以商標Tyvek®進行銷售的紡黏烯烴纖維,亦可用作基板。金屬化塑膠或聚合物的典型實例包括上文所述的具有連續或不連續地設置在其表面上的金屬的塑膠或聚合物材料。金屬的典型實例包括但不限於鋁(Al)、鉻(Cr)、銅(Cu)、金(Au)、銀(Ag)、其合金以及上述金屬中之兩者或更多者的組合。上文所述的塑膠或聚合物材料的金屬化可藉由電沉積製程、高真空塗佈製程或藉由濺鍍製程來完成。失透的聚合物之開發目的係模仿用於安全文件的習知紙基基板的外觀及某些性質,且由聚合物透明基板組成,聚合物透明基板通常在其一側或兩側上用失透層進行表面處理以形成失透的聚合物基基板。複合材料的典型實例包括但不限於紙及至少一種塑膠或聚合物材料(諸如上文所述的材料)的多層結構或層壓物以及併入紙狀或纖維材料(諸如上文所述的材料)中的塑膠及/或聚合物纖維。當然,基板可包含熟習此項技術者已知的其他添加劑,諸如填充劑、上漿劑、增白劑、加工助劑、增強劑或濕強劑等。The substrates described herein are preferably selected from the group consisting of paper or other fibrous materials, such as cellulose, paper-containing materials, glass, metals, ceramics, plastics and polymers, metallized plastics or polymers, at least partially devitrifying plastic or polymer composites, and mixtures or combinations thereof. Typical paper, paper-like or other fibrous materials are made of a variety of fibers, including but not limited to abaca, cotton, flax, wood pulp, and blends thereof. As is well known to those skilled in the art, cotton and cotton/flax blends are preferably used for banknotes, while wood pulp is commonly used for non-banknote security documents. Typical examples of plastics and polymers include: polyolefins, such as polyethylene (PE) and polypropylene (PP); polyamides; polyesters, such as polyethylene terephthalate (PET), poly(1,4-butylene terephthalate) (PBT), and polyethylene (2,6-naphthoate) (PEN); and polyvinyl chloride (PVC). Spunlace fibers, such as those marketed under the trademark Tyvek®, can also be used as substrates. Typical examples of metallized plastics or polymers include the plastic or polymer materials described above that have metals disposed continuously or discontinuously on their surfaces. Typical examples of metals include, but are not limited to, aluminum (Al), chromium (Cr), copper (Cu), gold (Au), silver (Ag), alloys thereof, and combinations of two or more of the above metals. The metallization of the plastic or polymer materials described above can be accomplished by electrodeposition, high-vacuum coating, or sputtering processes. Devitrifying polymers are developed to mimic the appearance and certain properties of familiar paper-based substrates used for security documents and consist of a polymer transparent substrate, which is typically surface-treated with a devitrifying layer on one or both sides to form a devitrifying polymer-based substrate. Typical examples of composite materials include, but are not limited to, multilayer structures or laminates of paper and at least one plastic or polymeric material (such as those described above), as well as plastic and/or polymeric fibers incorporated into paper-like or fibrous materials (such as those described above). Of course, the substrate may contain other additives known to those skilled in the art, such as fillers, sizing agents, whitening agents, processing aids, reinforcing agents, or wet strength agents.
或者,且較佳地,塗層組合物的固化或硬化涉及化學反應,該化學反應不能藉由在安全文件的典型使用期間可能發生的簡單的溫度升高(例如高達80℃)來逆轉。術語「固化」或「可固化」係指包括對所塗覆的塗層組合物中的至少一種組分以使其轉變成分子量比起始物質更大的聚合物材料的方式進行化學反應、交聯或聚合的過程。較佳地,固化導致形成穩定的三維聚合物網。此種固化通常藉由以下操作引發:(i)在將塗層組合物塗覆於基板表面上之後,及(ii)在對片狀磁性或可磁化顏料粒子進行定向之後或與該定向部分同時,對塗層組合物施加外部刺激。較佳地,塗層組合物係選自由輻射可固化組合物、熱乾燥組合物、氧化乾燥組合物及其組合組成的組的油墨或塗層組合物。特別較佳的係選自由輻射可固化組合物組成的組的塗層組合物。輻射固化,特別是紫外光-可見光固化,有利地導致塗層組合物在曝露於固化輻射之後黏度瞬時增加,從而在磁性定向步驟之後防止顏料粒子的任何進一步移動且因此防止任何資訊損失。較佳地,固化藉由輻射固化(包括紫外光-可見光輻射固化)或藉由電子束輻射固化進行,更佳地藉由紫外光-可見光輻射固化進行。Alternatively, and more preferably, the curing or hardening of the coating composition involves a chemical reaction that cannot be reversed by a simple temperature increase (e.g., up to 80°C) that may occur during typical use of the safety document. The terms “curing” or “curable” refer to a process that includes a chemical reaction, crosslinking, or polymerization of at least one component of the coated coating composition to transform it into a polymeric material with a molecular weight greater than that of the starting material. Preferably, curing results in the formation of a stable three-dimensional polymer network. Such curing is typically initiated by applying an external stimulus to the coating composition after (i) the coating composition has been applied to a substrate surface, and (ii) after or simultaneously with the orientation of sheet-like magnetic or magnetizable pigment particles. Preferably, the coating composition is an ink or coating composition selected from the group consisting of radiation-curable compositions, heat-drying compositions, oxidative-drying compositions, and combinations thereof. Particularly preferred are coating compositions selected from the group consisting of radiation-curable compositions. Radiation curing, particularly ultraviolet-visible light curing, advantageously results in a momentary increase in viscosity of the coating composition after exposure to curing radiation, thereby preventing any further movement of pigment particles after the magnetic orientation step and thus preventing any information loss. Preferably, curing is carried out by radiation curing (including ultraviolet-visible light radiation curing) or by electron beam radiation curing, more preferably by ultraviolet-visible light radiation curing.
數字N及M可為自然數。N個磁性塊被配置成形成磁場產生裝置的重複圖案。N個磁性塊相同特別地意味著它們產生相同的塊磁場。它們在每個塊中所包括的磁場產生裝置方面、尺寸方面或類似方面亦可能相同。N係至少為二的整數。一個磁性塊的磁場產生裝置可藉由容納殼體容納在一起,使得每個磁性塊形成實體單元。N個磁性塊沿著傳送裝置的外表面對準特別地意味著N個磁性塊配置在傳送裝置的外表面上,例如配置在各自包含一個磁性塊的孔中。磁性塊可設置在外表面上,使得放置在面向傳送裝置的外表面的基板上之顏料粒子可感知塊磁場。N個磁性塊全部彼此等距離配置。特別地,N個磁性塊沿著對準線無縫地彼此相鄰配置。磁性塊「沿著對準線」配置可意味著它們與對準線平行對準。The numbers N and M can be natural numbers. N magnetic blocks are arranged in a repeating pattern to form a magnetic field generating device. The N magnetic blocks being identical specifically means that they generate the same block magnetic field. They may also be identical in terms of the magnetic field generating device, size, or similar aspects included in each block. N is an integer of at least two. The magnetic field generating device of a single magnetic block can be housed together by a housing, such that each magnetic block forms a physical unit. The N magnetic blocks are aligned along the outer surface of the conveying device, specifically meaning that the N magnetic blocks are arranged on the outer surface of the conveying device, for example, arranged in holes, each containing one magnetic block. The magnetic blocks can be disposed on the outer surface such that pigment particles placed on a substrate facing the outer surface of the conveying device can sense the block magnetic field. All N magnetic blocks are arranged equidistantly from each other. Specifically, N magnetic blocks are arranged adjacent to each other seamlessly along the alignment line. The magnetic blocks being arranged "along the alignment line" can mean that they are aligned parallel to the alignment line.
M係至少為一的整數。每個磁性塊包括至少一個磁場產生裝置。每個磁場產生裝置可包括永久磁鐵、電磁鐵、螺線管、通電的導線、塑性鐵氧體磁鐵、塑性鐵氧體磁鐵與永久磁鐵的組合、軟磁鐵、產生時間相關磁場的磁場產生裝置與軟磁鐵的組合、及/或產生磁場的類似裝置。較佳地,磁場產生裝置實現為永久磁鐵。每個磁性塊可用於將顏料粒子定向成在固化後以光學效應層(optical effect layer,OEL)的形式創建一個安全特徵。如本文所使用的術語「光學效應層(optical effect layer,OEL)」表示包含定向的片狀磁性或可磁化顏料粒子及黏合劑的塗層或層,其中該等片狀磁性或可磁化顏料粒子藉由磁場進行定向且其中定向的片狀磁性或可磁化顏料粒子在其定向及位置上被固定/凍結,以便形成磁感應影像。術語「安全特徵」用於表示可用於鑑認目的之影像或圖形元件。安全特徵可為顯性的及/或隱性的安全元件。每個安全特徵可包括M個安全元件,此等安全元件藉由對輻射可固化塗層組合物進行固化而創建,輻射可固化塗層組合物包含藉由M個磁場產生裝置進行定向的顏料粒子。M個安全元件中之每一者具有花紋圖案的形狀,且顯示出藉由曝露於塊磁場中所包含的磁場產生裝置而獲得的特定磁效應。M is an integer of at least one. Each magnetic block includes at least one magnetic field generating device. Each magnetic field generating device may include a permanent magnet, an electromagnetic magnet, a solenoid, a current-carrying wire, a plastic ferrite magnet, a combination of a plastic ferrite magnet and a permanent magnet, a soft magnet, a combination of a magnetic field generating device that generates a time-dependent magnetic field and a soft magnet, and/or similar devices that generate magnetic fields. Preferably, the magnetic field generating device is implemented as a permanent magnet. Each magnetic block can be used to orient pigment particles to create a security feature in the form of an optical effect layer (OEL) after curing. As used herein, "optical effect layer (OEL)" refers to a coating or layer comprising oriented sheet-like magnetic or magnetizable pigment particles and an adhesive, wherein the sheet-like magnetic or magnetizable pigment particles are oriented by a magnetic field and wherein the oriented sheet-like magnetic or magnetizable pigment particles are fixed/frozen in their orientation and position to form a magnetically induced image. The term "security feature" is used to refer to an image or graphic element that can be used for forensic purposes. Security features can be explicit and/or implicit security elements. Each security feature may include M security elements created by curing a radiocurable coating composition comprising pigment particles oriented by M magnetic field generating devices. Each of the M safety elements has a patterned shape and displays a specific magnetic effect obtained by exposure to a magnetic field generating device contained in a block of magnetic field.
至少一個屏蔽元件放置在每兩個相鄰磁性塊之間,通常在第1個磁性塊與第2個磁性塊之間,第2個磁性塊與第3個磁性塊之間,…,以及在第(N-1)個磁性塊與第N個磁性塊之間。換言之,可設置(N-1)個屏蔽元件。屏蔽元件較佳地位於對準線上。屏蔽元件特別是如下元件:其重新定向來自磁性塊(其配置在該等磁性塊之間)的磁場線,使得此等磁場線不會彼此交叉(這對應於將兩個相鄰磁性塊的塊磁場彼此完全隔離)。在一些情況下,可容忍相鄰磁性塊的塊磁場之間的輕微相互作用,這就是為什麼說屏蔽元件至少部分地將磁性塊的塊磁場與其他塊磁場隔離。At least one shielding element is placed between every two adjacent magnetic blocks, typically between the first and second magnetic blocks, between the second and third magnetic blocks, ..., and between the (N-1)th and Nth magnetic blocks. In other words, (N-1) shielding elements can be provided. The shielding elements are preferably positioned on alignment lines. The shielding elements are, in particular, elements that redirect the magnetic field lines from the magnetic blocks (which are arranged between them) so that these magnetic field lines do not cross each other (this corresponds to completely isolating the block magnetic fields of two adjacent magnetic blocks from each other). In some cases, slight interactions between the block magnetic fields of adjacent magnetic blocks can be tolerated, which is why it is said that shielding elements at least partially isolate the block magnetic field of a magnetic block from the block magnetic fields of other magnetic blocks.
根據一實施例,第一態樣的傳送裝置進一步包含N個容納殼體,用於各自容納一個磁性塊,該等容納殼體的至少一區段形成屏蔽元件。According to one embodiment, the first-state transmission device further includes N housings, each for housing a magnetic block, at least a section of the housings forming a shielding element.
容納殼體特別地包括或對應於屏蔽元件。容納殼體可包括用於容納個別磁場產生裝置的隔間。每個磁性塊由一個容納殼體容納。容納殼體可包括平行於外表面的蓋子,在傳送裝置的使用期間,該蓋子配置在基板與磁性塊之間。容納殼體的形成屏蔽元件的區段(部分(part/portion))可為容納殼體的位於兩個相鄰磁性塊之間的區段。The housing specifically includes or corresponds to a shielding element. The housing may include compartments for accommodating individual magnetic field generating devices. Each magnetic block is housed by one housing. The housing may include a cover parallel to its outer surface, which is disposed between the substrate and the magnetic block during use of the conveying device. The section (part/portion) of the housing forming the shielding element may be a section of the housing located between two adjacent magnetic blocks.
根據第一態樣的另一實施例,屏蔽元件的材料係具有大於40的相對磁導率的材料;及/或鋼,特別是S235鋼。According to another embodiment of the first state, the material of the shielding element is a material having a relative permeability greater than 40; and/or steel, especially S235 steel.
較佳地,屏蔽元件由鐵磁金屬製成。特定介質的相對磁導率係定義為特定介質的磁導率與自由空間(真空)的磁導率之比(參見Magnetic materials, Fundamentals and Applications, 2ndEd., Nicola A. Spaldin, p. 16-17, Cambridge University Press, 2011)。此處「導磁率」係指磁導率。絕對磁導率特別是基於通量密度的變化ΔB相對於磁場強度的變化ΔH。相對磁導率表示給定材料的磁效能。例如,相對磁導率為100意味著材料的磁導率係真空的磁導率的100倍(根據定義,相對磁導率為1,而真空的磁導率為4π·10^(-7) H/m)。Preferably, the shielding element is made of a ferromagnetic metal. The relative permeability of a particular medium is defined as the ratio of the permeability of the particular medium to the permeability of free space (vacuum) (see Magnetic materials, Fundamentals and Applications, 2nd Ed., Nicola A. Spaldin, pp. 16-17, Cambridge University Press, 2011). Here, "permeability" refers to magnetic permeability. Absolute permeability is specifically based on the change in flux density ΔB relative to the change in magnetic field strength ΔH. Relative permeability represents the magnetic performance of a given material. For example, a relative permeability of 100 means that the material's permeability is 100 times that of vacuum (by definition, relative permeability is 1, while the permeability of vacuum is 4π·10^(-7) H/m).
此處「鋼S235」特別係指如2005年4月的標準DIN EN 10025-2中所定義的鋼S235。Here, "Steel S235" specifically refers to steel S235 as defined in the April 2005 standard DIN EN 10025-2.
根據第一態樣的另一實施例,傳送裝置為圓柱形傳送裝置,且對準線係:圓柱形傳送裝置的橫截面的外圓周線(較佳實施例);或圓柱形傳送裝置的外表面上的側線,該側線平行於圓柱形傳送裝置的軸線。According to another embodiment of the first state, the conveying device is a cylindrical conveying device, and the alignment line is: the outer circumference of the cross section of the cylindrical conveying device (preferred embodiment); or a side line on the outer surface of the cylindrical conveying device, which is parallel to the axis of the cylindrical conveying device.
圓柱形傳送裝置特別地具有圓形底座。在圓柱形傳送裝置的情況下,對準線可為:圓柱形傳送裝置的橫截面的外圓周線,若圓柱形傳送裝置具有圓形底座,則其具有圓形形狀;或外表面的側線,該側線平行於圓柱形傳送裝置的軸線,該軸線係穿過圓柱體的中心的圓柱體旋轉軸線。側線係圓柱體的高度。對準線係N個磁性塊沿著其對準的線,對準線特別是N個磁性塊沿著其彼此足夠靠近以具有重疊的磁場(即,彼此影響)的線,因此在認為相鄰磁性塊的磁場影響在預期應用的背景下不夠小的情況下,如本文所描述的屏蔽元件及/或補償元件可變得有利。Cylindrical conveying devices are characterized by a circular base. In the case of a cylindrical conveying device, the alignment line can be: the outer circumference of the cross-section of the cylindrical conveying device, which, if the cylindrical conveying device has a circular base, then has a circular shape; or a side line of the outer surface, parallel to the axis of rotation of the cylindrical conveying device, which is the axis of rotation of the cylinder passing through its center. The side line represents the height of the cylinder. The alignment line is the line along which N magnetic blocks are aligned. In particular, the alignment line is the line along which N magnetic blocks are close enough to each other to have overlapping magnetic fields (i.e., to influence each other). Therefore, shielding elements and/or compensating elements as described herein may become advantageous when the magnetic field influence of adjacent magnetic blocks is considered not small enough in the context of the intended application.
根據第一態樣的另一實施例,傳送裝置係具有矩形形狀的平板式傳送裝置,且對準線平行於矩形平板式傳送裝置的一側。According to another embodiment of the first state, the conveying device is a rectangular flat plate conveying device, and the alignment line is parallel to one side of the rectangular flat plate conveying device.
換言之,對準線平行於傳送裝置的寬度或長度。In other words, the alignment line is parallel to the width or length of the transmission device.
在一些實施例中,磁性塊在傳送裝置上配置成陣列,這意味著沿著與上述(第一)對準線平行的第二(分別沿著第三、第四等)對準線設置一些額外的N個磁性塊。這允許用一個基板同時產生更多個安全文件。In some embodiments, the magnetic blocks are arranged in an array on the transmission device, which means that some additional N magnetic blocks are arranged along a second alignment line (along the third, fourth, etc., respectively) parallel to the aforementioned (first) alignment line. This allows more security files to be generated simultaneously using a single substrate.
根據第二態樣,提供一種傳送裝置,用於對包含在塗層組合物中並塗覆於基板上的片狀磁性或可磁化顏料粒子進行定向以便在基板上產生N個安全文件。該傳送裝置係平板式傳送裝置或圓柱形傳送裝置。該傳送裝置包含:N個相同的磁性塊,該等磁性塊沿著設置在傳送裝置的外表面上的對準線對準,該等磁性塊各自包括M個磁場產生裝置,該等磁場產生裝置各自產生對應的磁場,使得該等磁性塊各自產生塊磁場,N大於或等於二,且M大於或等於一;及補償磁性塊,該補償磁性塊沿著對準線設置在第一個磁性塊旁邊,使得N個磁性塊中的第一個配置在補償磁性塊與N個磁性塊中的第二個之間,補償磁性塊包括至少一個補償磁場產生裝置,至少一個補償磁場產生裝置提供的磁場與該等磁性塊中的一個磁性塊的至少一部分的磁場相同,該一個磁性塊包括第M個磁場產生裝置。According to a second embodiment, a conveying device is provided for orienting sheet-like magnetic or magnetizable pigment particles contained in a coating composition and coated on a substrate to generate N security documents on the substrate. The conveying device is either a flat-plate conveying device or a cylindrical conveying device. The conveying device comprises: N identical magnetic blocks aligned along alignment lines disposed on the outer surface of the conveying device; each magnetic block includes M magnetic field generating devices, each generating a corresponding magnetic field such that each magnetic block generates a block magnetic field, where N is greater than or equal to two, and M is greater than or equal to one; and a compensating magnetic block, which, along the alignment lines, generates N identical magnetic fields. A guideline is positioned next to the first magnetic block, such that the first of the N magnetic blocks is positioned between the compensating magnetic block and the second of the N magnetic blocks. The compensating magnetic block includes at least one compensating magnetic field generating device, and the magnetic field provided by the at least one compensating magnetic field generating device is the same as the magnetic field of at least a portion of the magnetic field of one of the magnetic blocks, which includes the Mth magnetic field generating device.
第二態樣的傳送裝置與第一態樣的傳送裝置大部分相同。第二態樣的傳送裝置之與第一態樣的傳送裝置的元件具有相同名稱的元件係同的,因此將不再對其進行描述以避免重複。第一及第二態樣的傳送裝置的差異在於,第二態樣的傳送裝置包括補償磁性塊而不是包括屏蔽元件。The second-state transmission device is largely the same as the first-state transmission device. The components in the second-state transmission device that share the same names as those in the first-state transmission device will not be described again to avoid repetition. The difference between the first and second-state transmission devices is that the second-state transmission device includes a compensating magnetic block instead of a shielding element.
補償磁性塊沿著對準線放置在第一個磁性塊之前,以模擬額外的磁性塊。因此,N個磁性塊中的第一個至第(N-1)個磁性塊各自沿著對準線具有兩個相鄰磁性塊,這意味著此等塊中之每一者的塊磁場受到相鄰塊的同等擾動,從而針對沿著對準線在基板上形成的第1個至第(N-1)個安全文件達成對磁場的恆定曝露。Compensating magnetic blocks are placed along the alignment line before the first magnetic block to simulate additional magnetic blocks. Therefore, the first to (N-1)th magnetic blocks of the N magnetic blocks each have two adjacent magnetic blocks along the alignment line, which means that the block magnetic field of each of these blocks is equally disturbed by the adjacent blocks, thereby achieving constant exposure to the magnetic field for the first to (N-1)th security documents formed on the substrate along the alignment line.
第一及第二實施例的傳送裝置針對減少對基板的不同安全文件上的磁性或可磁化顏料粒子進行定向的磁場之不規則性的相同問題提供了不同的解決方案。解決此相同問題的方法為:在第一態樣的傳送裝置中設置屏蔽元件,及在第二態樣的傳送裝置中設置補償磁性塊。雖然屏蔽元件允許防止相鄰磁性塊的塊磁場之間的干擾,但是補償磁性塊不執行任何屏蔽功能,而是向N個磁性塊添加額外的磁性塊,使得相鄰磁性塊之間的干擾相同。The first and second embodiments of the conveying apparatus offer different solutions to the same problem of reducing the irregularity of the magnetic field that orients magnetic or magnetizable pigment particles on different security documents of the substrate. The method for solving this same problem is to provide a shielding element in the first embodiment of the conveying apparatus and a compensating magnetic block in the second embodiment. While the shielding element allows for the prevention of interference between the block magnetic fields of adjacent magnetic blocks, the compensating magnetic block does not perform any shielding function; instead, it adds additional magnetic blocks to the N magnetic blocks, making the interference between adjacent magnetic blocks equal.
補償磁性塊可沿著對準線與其他磁性塊對準。補償磁性塊可為與N個磁性塊相同的磁性塊。或者,補償磁場產生裝置提供的磁場與磁性塊中的一個磁性塊的至少一部分的磁場相同,該一個磁性塊包括第M個磁場產生裝置。因此,補償磁性塊可為至少包括第M個磁場產生裝置的磁性塊,從而再現放置在N個磁性塊中的除第一個之外的任一個磁性塊之前的磁性塊的磁場影響。除了第M個磁場產生裝置之外,補償磁性塊可另外包括第(M-1)個磁場產生裝置,以此類推,直至其包括第一個磁場產生裝置或除第一個磁場產生裝置之外的所有磁場產生裝置。補償磁性塊的磁場產生裝置特別地以與N個磁性塊中相同的方式(相同的位置)配置。補償磁性塊與第一個磁性塊之間的距離特別地等於N個磁性塊中的兩個相鄰磁性塊之間的距離。補償磁場產生裝置亦可不同於磁性塊的磁場產生裝置,但是提供的磁場與磁性塊的磁場產生裝置中之一或多者的磁場相同。The compensating magnetic block can be aligned with other magnetic blocks along the alignment line. The compensating magnetic block can be the same magnetic block as the N magnetic blocks. Alternatively, the magnetic field provided by the compensating magnetic field generating device is the same as the magnetic field of at least a portion of the magnetic field of one of the magnetic blocks, which includes the Mth magnetic field generating device. Therefore, the compensating magnetic block can be a magnetic block that includes at least the Mth magnetic field generating device, thereby reproducing the magnetic field effect of the magnetic block placed before any of the N magnetic blocks except the first one. In addition to the Mth magnetic field generating device, the compensating magnetic block may further include the (M-1)th magnetic field generating device, and so on, until it includes the first magnetic field generating device or all magnetic field generating devices except the first magnetic field generating device. The magnetic field generating devices of the compensating magnetic block are specifically arranged in the same manner (at the same location) as in the N magnetic blocks. The distance between the compensating magnetic block and the first magnetic block is specifically equal to the distance between two adjacent magnetic blocks in the N magnetic blocks. The compensating magnetic field generating device may also be different from the magnetic field generating devices of the magnetic blocks, but the magnetic field it provides is the same as the magnetic field of one or more of the magnetic field generating devices of the magnetic blocks.
雖然在創建N個安全文件的製程中使用N個磁性塊來分別定向片狀磁性或可磁化顏料粒子,但是補償磁性塊係額外塊,其特別地不對應於N個安全文件中之一者。換言之,除補償磁性塊之外的每個磁性塊都與一個安全文件相關聯。補償磁性塊調整相鄰的第一個磁性塊的磁場,以相應地定向第1個安全文件的片狀磁性或可磁化顏料粒子。Although N magnetic blocks are used in the process of creating N security files to orient the sheet-like magnetic or magnetizable pigment particles respectively, the compensating magnetic block is an additional block that specifically does not correspond to one of the N security files. In other words, each magnetic block except the compensating magnetic block is associated with one security file. The compensating magnetic block adjusts the magnetic field of the first adjacent magnetic block to orient the sheet-like magnetic or magnetizable pigment particles of the first security file accordingly.
根據一實施例,第二態樣的傳送裝置進一步包含額外補償磁性塊,該額外補償磁性塊沿著對準線設置在第N個磁性塊旁邊,使得第N個磁性塊配置在額外補償磁性塊與第(N-1)個磁性塊之間,額外補償磁性塊包括至少一個額外補償磁場產生裝置,至少一個額外補償磁場產生裝置提供的磁場與該等磁性塊中的一個磁性塊的至少一部分的磁場相同,該一個磁性塊包括M個磁場產生裝置中的第一個。According to one embodiment, the second-state transmission device further includes an additional compensating magnetic block disposed next to the Nth magnetic block along an alignment line, such that the Nth magnetic block is positioned between the additional compensating magnetic block and the (N-1)th magnetic block. The additional compensating magnetic block includes at least one additional compensating magnetic field generating device, and the magnetic field provided by the at least one additional compensating magnetic field generating device is the same as the magnetic field of at least a portion of the magnetic field of one of the magnetic blocks, wherein the magnetic block includes the first of M magnetic field generating devices.
額外補償磁性塊設置在對準線的另一端(第N個磁性塊之後),且與上述補償磁性塊具有相同的性質並服務於相同的目的。即,額外補償磁性塊沿著對準線放置在第N個磁性塊之後並與其對準,以模擬額外磁性塊。因此,N個磁性塊中的第一個至第N個磁性塊各自沿著對準線具有兩個相鄰磁性塊,這意味著此等磁性塊中之每一者的塊磁場受到相鄰磁性塊的同等擾動,從而針對沿著對準線在基板上形成的第1個至第N個安全文件達成對磁場的恆定曝露。An additional compensating magnetic block is disposed at the other end of the alignment line (after the Nth magnetic block) and has the same properties and serves the same purpose as the aforementioned compensating magnetic block. That is, the additional compensating magnetic block is placed after and aligned with the Nth magnetic block along the alignment line to simulate the additional magnetic block. Therefore, each of the first to Nth magnetic blocks among the N magnetic blocks has two adjacent magnetic blocks along the alignment line, which means that the block magnetic field of each of these magnetic blocks is equally disturbed by the adjacent magnetic blocks, thereby achieving constant exposure of the magnetic field for the first to Nth security documents formed on the substrate along the alignment line.
額外補償磁性塊可為與N個磁性塊相同的磁性塊。或者,額外補償磁場產生裝置提供的磁場與磁性塊中的一個磁性塊的至少一部分的磁場相同,該一個磁性塊包括第1個磁場產生裝置。因此,額外補償磁性塊可為至少包括第1個磁場產生裝置的磁性塊,從而再現放置在第N個磁性塊中的除第N個磁性塊之外的任一個磁性塊或除第一個磁場產生裝置之外的所有磁場產生裝置之後的磁性塊的磁場影響。除了第1個磁場產生裝置之外,額外補償磁性塊可另外包括第2個磁場產生裝置,以此類推,直至包括第M個磁場產生裝置。額外補償磁性塊的磁場產生裝置特別地以與N個磁性塊中相同的方式(相同的位置)配置。額外補償磁性塊與第N個磁性塊之間的距離特別地等於N個磁性塊中的兩個相鄰磁性塊之間的距離。額外補償磁場產生裝置亦可不同於磁性塊的磁場產生裝置,但是提供的磁場與磁性塊的磁場產生裝置中之一或多者的磁場相同。The additional compensating magnetic block can be the same magnetic block as the N magnetic blocks. Alternatively, the magnetic field provided by the additional compensating magnetic field generating device is the same as the magnetic field of at least a portion of one of the magnetic blocks, which includes the first magnetic field generating device. Therefore, the additional compensating magnetic block can be a magnetic block that includes at least the first magnetic field generating device, thereby reproducing the magnetic field effect of any magnetic block other than the Nth magnetic block placed in the Nth magnetic block, or the magnetic blocks following all magnetic field generating devices except the first magnetic field generating device. In addition to the first magnetic field generating device, the additional compensating magnetic block can further include a second magnetic field generating device, and so on, up to including the Mth magnetic field generating device. The magnetic field generating device for the additional compensation magnetic block is specifically configured in the same manner (at the same location) as the N magnetic blocks. The distance between the additional compensation magnetic block and the Nth magnetic block is specifically equal to the distance between two adjacent magnetic blocks among the N magnetic blocks. The additional compensation magnetic field generating device may also differ from the magnetic field generating device for the magnetic blocks, but the magnetic field it provides is the same as the magnetic field of one or more of the magnetic field generating devices for the magnetic blocks.
雖然在創建N個安全文件的製程中使用N個磁性塊來分別定向片狀磁性或可磁化顏料粒子,但是補償磁性塊及額外補償磁性塊係額外塊,其特別地不對應於N個安全文件中之一者。換言之,除補償磁性塊及額外補償磁性塊之外的每個磁性塊都與一個安全文件相關聯。額外補償磁性塊調整相鄰的第N個磁性塊的磁場,以相應地定向第N個安全文件的片狀磁性或可磁化顏料粒子。Although N magnetic blocks are used in the process of creating N security files to orient the sheet-like magnetic or magnetizable pigment particles respectively, the compensating magnetic block and the additional compensating magnetic block are additional blocks, specifically not corresponding to one of the N security files. In other words, each magnetic block except for the compensating magnetic block and the additional compensating magnetic block is associated with one security file. The additional compensating magnetic block adjusts the magnetic field of the adjacent Nth magnetic block to correspondingly orient the sheet-like magnetic or magnetizable pigment particles of the Nth security file.
第二態樣的傳送裝置可進一步包含N個容納殼體,用於各自容納一個磁性塊。較佳地,在第二態樣中,N個容納殼體不包括如上所述的遮蔽元件。The second-state transmission device may further include N housings, each for housing a magnetic block. Preferably, in the second state, the N housings do not include the shielding elements described above.
根據第二態樣的另一實施例,補償磁性塊中所包含的至少一個補償磁場產生裝置提供的磁場與第M個磁場產生裝置的磁場相同,及/或額外補償磁性塊中所包含的至少一個額外補償磁場產生裝置提供的磁場與第一個磁場產生裝置的磁場相同。According to another embodiment of the second state, the magnetic field provided by at least one of the compensating magnetic field generating devices included in the compensating magnetic block is the same as the magnetic field of the Mth magnetic field generating device, and/or the magnetic field provided by at least one of the additional compensating magnetic field generating devices included in the additional compensating magnetic block is the same as the magnetic field of the first magnetic field generating device.
根據另一實施例,第二態樣的傳送裝置進一步包含:設置在每兩個相鄰磁性塊之間以及補償磁性塊與N個磁性塊中的第一個磁性塊之間的屏蔽元件,該屏蔽元件由至少部分地將每個磁性塊的塊磁場與其他磁性塊的磁場且與補償磁性塊的磁場隔離的材料製成。According to another embodiment, the second-state transmission device further includes: a shielding element disposed between every two adjacent magnetic blocks and between the compensating magnetic block and the first magnetic block among the N magnetic blocks, the shielding element being made of a material that at least partially isolates the block magnetic field of each magnetic block from the magnetic fields of the other magnetic blocks and from the magnetic field of the compensating magnetic block.
在設置了額外補償磁性塊的情況下,屏蔽元件進一步設置在額外補償磁性塊與第N個磁性塊之間。在此情況下,屏蔽元件由至少部分地將每個磁性塊的塊磁場與其他磁性塊的磁場、與補償磁性塊的磁場且與額外補償磁性塊的磁場隔離的材料製成。In the case where an additional compensating magnetic block is provided, the shielding element is further disposed between the additional compensating magnetic block and the Nth magnetic block. In this case, the shielding element is made of a material that at least partially isolates the block magnetic field of each magnetic block from the magnetic fields of other magnetic blocks, the magnetic field of the compensating magnetic block, and the magnetic field of the additional compensating magnetic block.
屏蔽元件可與針對第一態樣的傳送裝置所描述的屏蔽元件相同。針對第一態樣的傳送裝置所描述的特徵在本實施例的背景下同樣適用。本實施例係關於根據第一及第二態樣的傳送裝置的組合。將屏蔽元件解決方案與補償磁性塊解決方案相結合的優點在於,可更加確保同一基板的所有安全文件的顏料粒子以相同的方式定向,從而導致所有安全文件上的視覺特徵相同。The shielding element may be the same as the shielding element described for the conveying device of the first state sample. The features described for the conveying device of the first state sample are also applicable in the context of this embodiment. This embodiment relates to a combination of conveying devices according to the first and second states samples. The advantage of combining the shielding element solution with the compensating magnetic block solution is that it can better ensure that the pigment particles of all security documents on the same substrate are oriented in the same way, thereby resulting in identical visual features on all security documents.
根據傳送裝置的第一或第二態樣的另一實施例,每個磁性塊包括至少兩個不同的磁場產生裝置。According to another embodiment of the first or second state of the transmission device, each magnetic block includes at least two different magnetic field generating devices.
這對應於M≥2,其中兩個磁場產生裝置產生不同的磁場,從而對安全文件產生不同的磁效應。此等磁效應特別地包括提供運動視錯覺的動態效應(諸如下文描述的彼等)及提供浮雕視錯覺的3D效應(諸如下文描述的彼等)。在其他實施例中,每個磁性塊包括至少兩個相同的磁場產生裝置。This corresponds to M≥2, where the two magnetic field generating devices produce different magnetic fields, thereby producing different magnetic effects on the security document. These magnetic effects specifically include dynamic effects that provide motion illusions (such as those described below) and 3D effects that provide embossed illusions (such as those described below). In other embodiments, each magnetic block includes at least two identical magnetic field generating devices.
例如,可使用包含一或多個雕花的雕刻磁性板,一或多個雕花具有標記的形狀。如本文所使用,術語「標記」應意味著由顯著記號或標誌或圖案組成的連續及不連續的層。較佳地,一或多個標記選自由碼、符號、文數字符號、花紋圖案、幾何圖案(例如,圓形、三角形及規則或不規則多邊形)、字母、單詞、數字、徽標、圖式、肖像及其組合組成的組。碼的實例包括編碼的記號,諸如編碼的文數字資料、一維條碼、二維條碼、QR碼、資料矩陣及紅外線讀取碼。在使包含一或多個標記的OEL傾斜時,安全特徵可表現出動態運動。例如,磁場產生裝置至少包含條形偶極磁鐵及雕刻磁性板,該雕刻磁性板包含一或多個雕花,一或多個雕花具有標記的形狀。For example, an engraved magnetic plate containing one or more engravings, each engraved with a marked shape, can be used. As used herein, the term "mark" should mean a continuous or discontinuous layer consisting of a prominent mark, symbol, or pattern. Preferably, the one or more marks are selected from codes, symbols, alphanumeric characters, patterns, geometric patterns (e.g., circles, triangles, and regular or irregular polygons), letters, words, numbers, emblems, graphics, portraits, and combinations thereof. Examples of codes include encoded symbols, such as encoded alphanumeric data, one-dimensional barcodes, two-dimensional barcodes, QR codes, data matrices, and infrared readout codes. When an OEL containing one or more marks is tilted, the security feature can exhibit dynamic movement. For example, a magnetic field generating device includes at least a bar dipole magnet and an engraved magnetic plate, the engraved magnetic plate including one or more engravings, the one or more engravings having a marked shape.
上述效應可包括的動態運動為:明亮的反射條在基板繞軸線傾斜時在一方向上移動,例如在US 2005/0106367、WO 2020/160993 A1及WO 2014/198905 A2中描述的。該效應亦可包括的動態運動為:亮區及暗區的圖案在基板傾斜時移動,例如在WO 2013/167425 A1、WO 2021/083808 A1及WO 2021/083809 A1中描述的。該效應亦可包括的動態運動為:環形體在基板傾斜時移動,例如在WO 2014/108404 A2及WO 2014/108303 A2中描述的。該效應亦可包括的動態運動為:環形體具有在基板傾斜時發生變化的大小,例如在WO 2017/064052 A1、WO 2017/080698 A1及WO 2017/148789 A1中描述的。該效應亦可包括的動態運動為:一或多個環形體具有在基板傾斜時發生變化的形狀,例如在WO 2018/054819 A1中描述的。該效應亦可包括的動態運動為:月牙形在基板傾斜時移動並旋轉,例如在WO 2019/215148 A1中描述的。該效應亦可包括的動態運動為:一或多個環形體所圍繞的環形體具有在基板傾斜時發生變化的形狀及/或亮度,例如在WO 2020/193009 A1中描述的。該效應亦可包括的動態運動為:至少一個彗星狀斑點在傾斜基板時繞該旋轉中心旋轉,例如在WO 2019/038371 A1、WO 2019/038370 A1及WO 2019/038369 A1中描述的。The aforementioned effect may include dynamic movements such as: bright reflective stripes moving in one direction when the substrate is tilted around an axis, as described in, for example, US 2005/0106367, WO 2020/160993 A1, and WO 2014/198905 A2. The effect may also include dynamic movements such as: patterns in bright and dark areas moving when the substrate is tilted, as described in, for example, WO 2013/167425 A1, WO 2021/083808 A1, and WO 2021/083809 A1. The effect may also include dynamic movements such as: toroidal bodies moving when the substrate is tilted, as described in, for example, WO 2014/108404 A2 and WO 2014/108303 A2. The effect may also include dynamic movements in which the toroidal body has a size that changes when the substrate is tilted, as described in WO 2017/064052 A1, WO 2017/080698 A1 and WO 2017/148789 A1. The effect may also include dynamic movements in which one or more toroidal bodies have shapes that change when the substrate is tilted, as described in WO 2018/054819 A1. The effect may also include dynamic movements in which a crescent shape moves and rotates when the substrate is tilted, as described in WO 2019/215148 A1. The effect may also include dynamic motions such as: the rings surrounded by one or more rings having shapes and/or brightness that change when the substrate is tilted, for example, as described in WO 2020/193009 A1. The effect may also include dynamic motions such as: at least one comet-shaped spot rotating around the center of rotation when the substrate is tilted, for example, as described in WO 2019/038371 A1, WO 2019/038370 A1 and WO 2019/038369 A1.
根據第三態樣,提供一種用於第一態樣、第二態樣、或第一或第二態樣的任一實施例的傳送裝置的磁性定向單元。該磁性定向單元用於對包含在輻射可固化塗層組合物中並塗覆於基板上的片狀磁性或可磁化顏料粒子進行定向。該磁性定向單元包含:磁性塊,該磁性塊包括M個磁場產生裝置,該等磁場產生裝置各自產生對應的磁場,使得磁性塊產生塊磁場,其中M大於或等於一;及屏蔽元件及/或補償磁性塊;其中屏蔽元件設置在磁性塊旁邊,屏蔽元件由至少部分阻擋塊磁場的材料製成;及/或補償磁性塊設置在磁性塊旁邊,補償磁性塊包括至少一個補償磁場產生裝置,該至少一個補償磁場產生裝置提供的磁場與該等磁性塊中的一個磁性塊的至少一部分的磁場相同,該一個磁性塊包括第M個磁場產生裝置。According to the third state sample, a magnetic orientation unit is provided for a conveying device of the first state sample, the second state sample, or any embodiment of the first or second state sample. The magnetic orientation unit is used to orient sheet-like magnetic or magnetizable pigment particles contained in a radiation-curable coating composition and coated on a substrate. The magnetic orientation unit comprises: a magnetic block, the magnetic block including M magnetic field generating devices, each of the magnetic field generating devices generating a corresponding magnetic field, such that the magnetic block generates a block magnetic field, wherein M is greater than or equal to one; and a shielding element and/or a compensating magnetic block; wherein the shielding element is disposed next to the magnetic block, the shielding element being made of a material that at least partially blocks the block magnetic field; and/or a compensating magnetic block disposed next to the magnetic block, the compensating magnetic block including at least one compensating magnetic field generating device, the magnetic field provided by the at least one compensating magnetic field generating device being the same as the magnetic field of at least a portion of the magnetic field of one of the magnetic blocks, the one magnetic block including the Mth magnetic field generating device.
根據第三態樣的磁性定向單元對應於第一或第二態樣的傳送裝置的子部分,該子部分包括僅一個磁性塊以及屏蔽元件及/或補償磁性塊。可選地,磁性定向單元亦可包括如上文所定義的額外補償塊。與第一或第二態樣的先前描述的元件具有相同名稱的元件係相同的,因此不再對其進行描述。優點與針對第一及第二態樣所描述的優點相同。針對第一或第二態樣(或其任何實施例)所描述的所有特徵亦適用於根據第三態樣的磁性定向單元。The magnetic orientation unit according to the third state corresponds to a sub-part of the conveying device of the first or second state, the sub-part comprising only one magnetic block and a shielding element and/or a compensating magnetic block. Alternatively, the magnetic orientation unit may also include additional compensating blocks as defined above. Elements with the same names as those previously described in the first or second state are identical and therefore will not be described again. The advantages are the same as those described for the first and second states. All features described for the first or second state (or any embodiment thereof) also apply to the magnetic orientation unit according to the third state.
根據第四態樣,提供一種印刷機,其包含根據第一或第二態樣(或其任何實施例)的傳送裝置。According to the fourth specification, a printing press is provided, which includes a conveying device according to the first or second specification (or any embodiment thereof).
該印刷機用於在基板上的安全文件上以光學效應層(optical effect layer,OEL)的形式印刷安全特徵。除了傳送裝置之外,印刷機還特別包括用於將顏料粒子塗覆於基板上、輸送基板、固化包括顏料粒子的塗層組合物及/或可選地對基板進行分割的構件。針對第一或第二態樣(或其任何實施例)所描述的所有特徵亦適用於根據第四態樣的印刷機。This printing press is used to print security features on security documents on a substrate in the form of an optical effect layer (OEL). In addition to the conveying device, the printing press specifically includes components for coating pigment particles onto the substrate, conveying the substrate, curing the coating composition including the pigment particles, and/or optionally dividing the substrate. All features described for the first or second sample (or any embodiment thereof) are also applicable to the printing press according to the fourth sample.
根據第五態樣,提供一種用於產生至少N個安全文件的方法,該等安全文件各自包含一個安全特徵,該安全特徵包含至少M個安全元件(各自特別地形成一個OEL),N等於或大於二,且M大於或等於一。該方法包含:a) 較佳以紙張的形式提供基板;b) 在基板表面上塗覆包含片狀磁性或可磁化顏料粒子的輻射可固化塗層組合物,塗層組合物處於第一狀態,塗層組合物針對N個安全特徵中之每一者以M個獨立的且可選地間隔開的花紋圖案的形式塗覆,c) 將磁性或可磁化顏料粒子曝露於根據第一態樣、第二態樣或第一或第二態樣的任何實施例的傳送裝置的磁場,以便根據傳送裝置的磁性塊的塊磁場對一個安全特徵的M個所塗覆花紋圖案中之每一者的片狀磁性或可磁化顏料粒子的至少一部分進行定向;及d) 較佳與步驟c)部分同時將步驟b)的塗層組合物固化至第二狀態,以便將片狀磁性或可磁化顏料粒子固定在其所採用的位置及定向上,使得每個固化的花紋圖案形成安全元件中之一者。According to the fifth state, a method is provided for generating at least N security documents, each of which contains a security feature, the security feature containing at least M security elements (each specifically forming an OEL), where N is equal to or greater than two, and M is greater than or equal to one. The method comprises: a) providing a substrate, preferably in the form of paper; b) coating the surface of the substrate with a radiation-curable coating composition comprising sheet-like magnetic or magnetizable pigment particles, the coating composition being in a first state, the coating composition being coated with M independent and optionally spaced patterned designs for each of N security features; c) exposing the magnetic or magnetizable pigment particles to the magnetic field of a conveying device according to a first state, a second state, or any embodiment of the first or second state, so as to orient at least a portion of the sheet-like magnetic or magnetizable pigment particles of each of the M coated patterned designs of a security feature according to the bulk magnetic field of the magnetic block of the conveying device; and d) Preferably, the coating composition of step b) is cured to a second state simultaneously with step c) to fix the sheet-like magnetic or magnetizable pigment particles in their adopted positions and orientations, so that each cured pattern forms one of the safety elements.
與第一或第二態樣的先前描述的元件具有相同名稱的元件係相同的,因此不再對其進行描述。針對第一或第二態樣(或其任何實施例)所描述的所有特徵亦適用於根據第五態樣的方法。所描述的方法允許產生至少N個安全文件,特別是N個安全文件。此等係在同一基板上產生的,然後可對其進行分割(特別是使用單獨的機器)以獲得個別安全文件。可同時產生至少N個安全文件。Elements having the same name as those previously described in the first or second aspect are identical and therefore will not be described again. All features described for the first or second aspect (or any embodiment thereof) also apply to the method according to the fifth aspect. The described method allows the generation of at least N security files, specifically N security files. These are generated on the same substrate and can then be divided (specifically using separate machines) to obtain individual security files. At least N security files can be generated simultaneously.
本文所述的塗覆步驟b)較佳藉由印刷製程進行,印刷製程較佳地選自由絲網印刷、輪轉凹版印刷、柔版印刷及凹版印刷(在此項技術中亦稱為雕刻銅板印刷及雕刻鋼模印刷)組成的組,更佳地選自由絲網印刷、輪轉凹版印刷及柔版印刷組成的組。此等製程係熟習此項技術者所熟知的且例如在Printing Technology, J. M. Adams and P. A. Dolin, Delmar Thomson Learning, 5th Edition中有描述。The coating step b) described herein is preferably performed by a printing process, preferably a combination of freehand screen printing, rotary gravure printing, flexographic printing, and gravure printing (also known in this technique as engraved copperplate printing and engraved stencil printing), more preferably a combination of freehand screen printing, rotary gravure printing, and flexographic printing. These processes are well known to those skilled in the art and are described, for example, in Printing Technology, J. M. Adams and P. A. Dolin, Delmar Thomson Learning, 5th Edition.
此外,在將本文所述的塗層組合物塗覆(步驟b)於本文所述的基板表面上之後、與其部分同時或同時,藉由施加磁場以使片狀磁性或可磁化顏料粒子沿著磁場線對準來定向片狀磁性或可磁化顏料粒子進行定向(步驟c)。在藉由施加磁場來對片狀磁性或可磁化顏料粒子進行定向/對準的步驟(步驟c)之後或與其部分同時,固定或凍結片狀磁性或可磁化顏料粒子的定向,即藉由固化塗層組合物(步驟d)。塗層組合物必須因此值得注意地具有:第一狀態,即液體或糊狀狀態,在第一狀態中塗層組合物足夠濕潤或柔軟,使得分散在塗層組合物中的片狀磁性或可磁化顏料粒子曝露於磁場時可自由移動、旋轉及/或定向;及第二硬化(例如,固體)狀態,在第二狀態中片狀磁性或可磁化顏料粒子被固定或凍結在其相應的位置及定向。Furthermore, after applying the coating composition described herein (step b) to the surface of the substrate described herein, and simultaneously with or concurrently with thereon, the plate-like magnetic or magnetizable pigment particles are oriented by applying a magnetic field to align them along magnetic field lines (step c). Following or simultaneously with step c, which involves orienting/aligning the plate-like magnetic or magnetizable pigment particles by applying a magnetic field, the orientation of the plate-like magnetic or magnetizable pigment particles is fixed or frozen, i.e., by curing the coating composition (step d). The coating composition must therefore noteworthyly possess: a first state, i.e., a liquid or paste state, in which the coating composition is sufficiently wet or soft such that the sheet-like magnetic or magnetizable pigment particles dispersed in the coating composition can move, rotate, and/or orient themselves freely when exposed to a magnetic field; and a second hardened (e.g., solid) state, in which the sheet-like magnetic or magnetizable pigment particles are fixed or frozen in their respective positions and orientations.
此種第一及第二狀態較佳地藉由使用某種類型的塗層組合物來提供。例如,除片狀磁性或可磁化顏料粒子以外的塗層組合物的組分可採取油墨或塗層組合物的形式,諸如在安全應用中使用(例如用於鈔票印刷)的油墨或塗層組合物。上述第一及第二狀態可藉由使用在對刺激(諸如溫度變化或曝露於電磁輻射)的反應中展示出黏度增加的材料來提供。亦即,當流體黏合劑材料硬化或凝固或固化時,該黏合劑材料轉化成第二狀態,即硬化或固化或固體狀態,在第二狀態中片狀磁性或可磁化顏料粒子被固定在其當前的位置及定向且不能不再在黏合劑材料內移動或旋轉。These first and second states are preferably provided by using a certain type of coating composition. For example, the components of the coating composition, other than the lamellar magnetic or magnetizable pigment particles, can be in the form of inks or coating compositions, such as those used in security applications (e.g., for banknote printing). The aforementioned first and second states can be provided by using materials that exhibit an increase in viscosity in response to stimuli (such as temperature changes or exposure to electromagnetic radiation). That is, when the fluid binder material hardens, solidifies, or solidifies, the binder material transforms into the second state, i.e., a hardened, solidified, or solid state, in which the lamellar magnetic or magnetizable pigment particles are fixed in their current position and orientation and can no longer move or rotate within the binder material.
在步驟b)中,特別地在當基板在步驟c)中面向傳送裝置時將會與傳送裝置的磁場產生裝置對準的基板位置處塗覆包括顏料粒子的塗層組合物。在步驟b)中,可印刷塗層組合物以在彼等預定位置處形成花紋圖案。如上所述,傳送裝置包括N個磁性塊,其各自具有M個磁場產生裝置。將塗層組合物塗覆於基板上以針對N個安全特徵中之每一者形成M個獨立的且可選地間隔開(即不接觸)的花紋圖案(對應於總共NxM個花紋圖案)。此等花紋圖案可沿著一條線塗覆。每個所塗覆的塗層組合物花紋圖案可在步驟c)中面向一個磁場產生裝置。因此,每個塊磁場對同一安全特徵的M個所塗覆的花紋圖案的顏料粒子進行定向。安全特徵的所塗覆的M個花紋圖案可具有相同的形狀或不同的形狀。較佳地,N個安全特徵全部相同,這意味著N個安全特徵中之每一者包括相同的M個花紋圖案及相同的磁效應,即N個安全特徵中之每一者包括相同的M個安全元件(在形狀及磁性定向方面)。In step b), a coating composition comprising pigment particles is applied, particularly to the substrate locations where the substrate will align with the magnetic field generating device of the conveying device when it faces the conveying device in step c). In step b), the coating composition can be printed to form patterned designs at those predetermined locations. As described above, the conveying device comprises N magnetic blocks, each having M magnetic field generating devices. The coating composition is applied to the substrate to form M independent and optionally spaced (i.e., non-contacting) patterned designs for each of the N security features (corresponding to a total of N x M patterned designs). These patterned designs may be applied along a line. Each coated pattern can be oriented towards a magnetic field generating device in step c). Therefore, each magnetic field orients the pigment particles of the M coated patterns for the same security feature. The M coated patterns of the security feature can have the same shape or different shapes. Preferably, all N security features are identical, meaning that each of the N security features includes the same M pattern patterns and the same magnetic effect, i.e., each of the N security features includes the same M security elements (in terms of shape and magnetic orientation).
M個獨立的花紋圖案可能彼此接觸(即不間隔開),以增加防偽能力。此處術語「獨立」係指如下事實:M個花紋圖案係不同的花紋圖案及/或施加至其的不同磁效應,以在安全特徵內創建不同的安全元件。獨立的花紋圖案可形成安全特徵的視覺上分開的且可區分的安全元件。M independent patterned designs may be in contact with each other (i.e., not spaced apart) to increase anti-counterfeiting capabilities. The term "independent" here refers to the fact that the M patterned designs are different patterns and/or different magnetic effects applied to them, creating different security elements within the security feature. The independent patterned designs can form visually separate and distinguishable security elements within the security feature.
如本文所定義,一個安全文件(諸如一張鈔票)包括一個安全特徵。一個安全特徵由多個安全元件構成,該等安全元件的特徵在於(i)其形狀(花紋圖案)及(ii)由對應的磁場產生裝置施加至其的磁效應。在非固化狀態下,包括顏料粒子的塗層組合物以花紋圖案的形式塗覆於基板,M個固化的花紋圖案中之每一者(即M個OEL中之每一者)形成安全元件,且M個安全元件(M個OEL)形成N個安全文件中之每一者所帶有的安全特徵。As defined herein, a secure document (such as a banknote) includes a security feature. A security feature consists of multiple security elements characterized by (i) their shape (pattern) and (ii) the magnetic effect applied to them by a corresponding magnetic field generating device. In a non-cured state, a coating composition comprising pigment particles is coated onto a substrate in the form of a pattern. Each of the M cured pattern (i.e., each of the M OELs) forms a security element, and the M security elements (M OELs) form the security feature present in each of the N secure documents.
根據一實施例,第五態樣的方法進一步包含以下步驟:e) 在N個安全特徵之間對基板進行分割以獲得個別的且相同的安全文件。According to one embodiment, the fifth-state method further includes the following steps: e) dividing the substrate among N security features to obtain individual and identical security documents.
作為在N個安全特徵之間進行分割的結果,特別地獲得N個個別的且相同的安全文件。每個安全文件(諸如鈔票)可包括一個安全特徵,其各自特別地包括M個安全元件的多重體。安全特徵可具有細長形狀,且例如沿著安全文件(特別是鈔票)的整個寬度擴展。此項技術中所參考的具有細長形狀的該等安全特徵的典型實例係安全線、安全條帶及安全箔。第五態樣的方法可經擴展以創建NxP個安全文件的陣列,該等安全文件各自包括一個安全特徵。在此情況下,使用具有NxP個磁性塊的傳送裝置在基板上不僅提供一次而是P次對N個安全特徵的對準。因此,可使用一個基板產生大量相同的安全文件。分割可為切割。As a result of segmentation among N security features, N individual and identical security documents are obtained. Each security document (such as a banknote) may include one security feature, each of which specifically includes a multiplicity of M security elements. The security features may have an elongated shape and extend, for example, along the entire width of the security document (especially the banknote). Typical examples of such elongated security features referenced in this technique are security threads, security strips, and security foils. The fifth-state method can be extended to create an array of N x P security documents, each of which includes one security feature. In this case, a transmission device with N x P magnetic blocks provides not just one but P alignments of the N security features on the substrate. Therefore, a large number of identical security documents can be generated using a single substrate. Segmentation can be interpreted as cutting.
根據第五態樣的實施例,N個安全特徵中之每一者包括至少兩個不同的安全元件。According to the fifth-state implementation, each of the N security features includes at least two different security elements.
每個安全特徵包括至少兩個不同的安全元件,這特別地意味著安全元件具有不同的花紋圖案(形狀)及/或與其相關聯的不同的磁效應,其在一個安全文件上至少部分相鄰。Each security feature includes at least two distinct security elements, which in particular means that the security elements have different patterns (shapes) and/or different magnetic effects associated with them, and are at least partially adjacent to each other on a security document.
根據一實施例,第五態樣的方法進一步包括:在步驟b)與步驟c)之間,將片狀磁性或可磁化顏料粒子曝露於時間相關磁場,以對片狀磁性或可磁化顏料粒子進行雙軸預定向。According to one embodiment, the fifth-state method further includes: between step b) and step c), exposing the sheet-like magnetic or magnetizable pigment particles to a time-correlated magnetic field to pre-orient the sheet-like magnetic or magnetizable pigment particles in a biaxial manner.
黏合劑材料中的片狀磁性或可磁化顏料粒子的定向藉由兩個定向步驟來達成,該等步驟藉由以下各項進行:i)根據第一磁場產生裝置的外部時間相關磁場對片狀磁性或可磁化顏料粒子進行雙軸定向(時間相關磁場係靜態或恆定磁場,且藉由在產生靜態或恆定磁場的磁場產生裝置前方移動基板,使該基板經受時間相關磁場);及隨後ii)根據第二磁場產生裝置的靜態外部磁場對片狀磁性或可磁化顏料粒子進行單軸重新定向,第二磁場產生裝置對應於本文所述的傳送裝置。例如,在EP 3079836 A1中描述了顏料粒子的此種兩步定向。The orientation of sheet-like magnetic or magnetizable pigment particles in an adhesive material is achieved through two orientation steps, which are performed by: i) biaxial orientation of the sheet-like magnetic or magnetizable pigment particles according to an external time-correlated magnetic field generated by a first magnetic field generating device (the time-correlated magnetic field is static or constant, and the substrate is subjected to the time-correlated magnetic field by moving the substrate in front of the magnetic field generating device that generates the static or constant magnetic field); and subsequently ii) uniaxial reorientation of the sheet-like magnetic or magnetizable pigment particles according to a static external magnetic field generated by a second magnetic field generating device, which corresponds to the conveying device described herein. For example, such two-step orientation of pigment particles is described in EP 3079836 A1.
進行雙軸定向意味著使片狀磁性或可磁化顏料粒子以其兩個主軸受到限制的方式進行定向。即,可認為每個片狀磁性或可磁化顏料粒子具有在顏料粒子的平面內的長軸及在顏料粒子的平面內的正交的短軸。使片狀磁性或可磁化顏料粒子的長軸及短軸各自根據與時間相關磁場進行定向。實際上,這會導致空間中彼此靠近的相鄰片狀磁性顏料粒子基本上彼此平行。為了執行雙軸定向,必須使片狀磁性顏料粒子經受強時間相關的外部磁場。Biaxial orientation means orienting plate-like magnetic or magnetizable pigment particles in a manner that restricts their two principal axes. That is, each plate-like magnetic or magnetizable pigment particle can be considered to have a major axis in the plane of the pigment particle and an orthogonal minor axis in the plane of the pigment particle. The major and minor axes of the plate-like magnetic or magnetizable pigment particles are each oriented according to a time-dependent magnetic field. In practice, this results in adjacent plate-like magnetic pigment particles that are close to each other in space being substantially parallel to each other. To perform biaxial orientation, the plate-like magnetic pigment particles must be subjected to a strongly time-dependent external magnetic field.
用於雙軸定向顏料粒子的該等第一磁場產生裝置的實例包括但不限於EP 2 157 141 A1、Z.Q. Zhu and D. Howe (Halbach permanent magnet machines and applications: a review, IEE. Proc. Electric Power Appl., 2001, 148, p. 299-308)、US 2007/0172261 A1、CN 102529326 B、WO 2015/082344 A1、WO 2016/026896 A1及WO2018/141547 A1、WO 2021/239607 A1中揭示的裝置。Examples of such first magnetic field generating devices for biaxially oriented pigment particles include, but are not limited to, the devices disclosed in EP 2 157 141 A1, Z.Q. Zhu and D. Howe (Halbach permanent magnet machines and applications: a review, IEE. Proc. Electric Power Appl., 2001, 148, p. 299-308), US 2007/0172261 A1, CN 102529326 B, WO 2015/082344 A1, WO 2016/026896 A1, WO2018/141547 A1, and WO 2021/239607 A1.
或者,可藉由將可固化塗層組合物曝露於上述用於雙軸定向顏料粒子的第一磁場產生裝置與包含一或多個凹陷及/或一或多個空隙及/或一或多個突起的軟磁性板之組合的所得磁場來定向顏料粒子,如WO 2019/14142 A1、WO 2019/141453 A1及WO 2015/086257 A1中描述的。Alternatively, the pigment particles can be oriented by exposing the curable coating composition to the magnetic field resulting from the combination of the first magnetic field generating device for biaxially oriented pigment particles and a soft magnetic plate comprising one or more recesses and/or one or more voids and/or one or more protrusions, as described in WO 2019/14142 A1, WO 2019/141453 A1 and WO 2015/086257 A1.
下文將參考附圖更全面地描述本發明,其中貫穿不同的圖相同的數字表示相同的元件,且其中示出了本發明的顯著態樣及特徵。The invention will be described more fully below with reference to the accompanying figures, in which the same numbers throughout the different figures represent the same elements, and in which the distinctive features and characteristics of the invention are shown.
現在參考圖式及特定實施例更詳細地描述本文所述的磁性總成及方法,其用於在基板上(特別是在聚合物基板上,較佳地在模仿包含失透層的聚合物基板的安全箔的非失透區域上)產生光學效應層(optical effect layer,OEL)作為安全特徵的,特別是安全線、安全條帶或安全箔。The magnetic assemblies and methods described herein are now described in more detail with reference to the accompanying drawings and specific embodiments for generating an optical effect layer (OEL) as a security feature on a substrate (particularly on a polymer substrate, preferably on a non-devitrifying region of a security foil that mimics a devitrifying layer on a polymer substrate). These features include security lines, security strips, or security foils.
第1圖示意性地示出形成基板的紙張S,該紙張用於印刷鈔票1,特別是用於印刷聚合物鈔票1。紙張S包含沿著多個行(在第1圖的實例中為六個行Y1-Y6)及多個列(在第1圖的實例中為八個列R1-R8)邊對邊配置的多張鈔票1。在印刷製程結束時,藉由沿著第1圖中表示的虛擬虛線在列R1-R8之間及在行Y1-Y6之間切割(分割)紙張S獲得了個別鈔票1。例如,第1圖中示出的紙張S將產生48張個別鈔票1。在第1圖中,在聚合物鈔票紙張S的情況下,灰色區域2示意性地表示失透的區域,而白色條帶3示意性地表示模仿安全箔的非失透的透明區域。Figure 1 schematically illustrates a sheet of paper S forming a substrate for printing banknotes 1, particularly polymer banknotes 1. The sheet of paper S comprises multiple banknotes 1 arranged edge-to-edge along multiple rows (six rows Y1-Y6 in the example of Figure 1) and multiple columns (eight columns R1-R8 in the example of Figure 1). At the end of the printing process, individual banknotes 1 are obtained by cutting (dividing) the sheet of paper S along the dotted lines shown in Figure 1 between columns R1-R8 and between rows Y1-Y6. For example, the sheet of paper S shown in Figure 1 will produce 48 individual banknotes 1. In Figure 1, in the case of polymer banknote paper S, the gray area 2 schematically represents the deoptery area, while the white stripe 3 schematically represents the non-deoptery transparent area that mimics the security foil.
如第1圖中示出,紙張S包含沒有鈔票1的前邊緣FE及後邊緣BE,以允許在各種印刷製程期間使用輸送構件(夾持器、滾筒、刷子等)將紙張S輸送通過印刷機。鈔票1中之每一者的非失透的區域3帶有三個安全元件A-C。在替代實例中,安全元件A-C可設置在不透明區域上,諸如鈔票1的不透明區域2上。As shown in Figure 1, the paper S includes the leading edge FE and trailing edge BE of the banknote 1, allowing it to be conveyed through the printing press using conveying components (clamps, rollers, brushes, etc.) during various printing processes. The non-opaque area 3 of each of the banknotes 1 has three security elements A-C. In an alternative embodiment, the security elements A-C may be located on opaque areas, such as opaque area 2 of the banknote 1.
第2a圖至第2b圖示意性地示出第1圖的基板S的鈔票1之實例,該等鈔票包含失透塗層(灰色區域2)及非失透的區域(透明區域3),非失透的區域表示安全箔且帶有呈花紋圖案F1-F3 (例如,在第2a圖中為帆船F1、花朵F2及松樹F3)的形狀的安全元件A-C,該等安全元件A-C包含根據磁效應G1-G3進行定向的磁性或可磁化顏料粒子。不同的磁效應G1-G3提供不同的可見光學效應(由灰線或灰環表示)。第2a圖示出鈔票的實例,其帶有形成安全元件A及B的三個花紋圖案F1、F2及F3以及兩個磁效應G1及G2。第2b圖示出鈔票的實例,其帶有形成安全元件A、B及C的三個花紋圖案F1、F2及F3以及三個磁效應G1、G2及G3。可與第2圖所示的實例不同地設計鈔票1。例如,每張鈔票1可包括一個、兩個或三個以上的圖案F1-F3,圖案可具有根據至少一個、但較佳多個不同的磁效應G1-G3進行定向的顏料粒子。安全元件A-B-A及A-B-C形成細長的安全特徵4。Figures 2a and 2b schematically illustrate examples of banknotes 1 on substrate S of Figure 1. These banknotes include an opaque coating (gray area 2) and a non-opaque area (transparent area 3). The non-opaque area represents a security foil and has security elements A-C in the shape of patterned designs F1-F3 (e.g., sailboat F1, flower F2, and pine tree F3 in Figure 2a). These security elements A-C contain magnetic or magnetizable pigment particles oriented according to magnetic effects G1-G3. Different magnetic effects G1-G3 provide different visible light effects (represented by gray lines or gray rings). Figure 2a shows an example of a banknote with three patterned designs F1, F2, and F3 forming security elements A and B, and two magnetic effects G1 and G2. Figure 2b illustrates an example of a banknote with three patterned designs F1, F2, and F3 forming security elements A, B, and C, and three magnetic effects G1, G2, and G3. The banknote 1 may be designed differently from the example shown in Figure 2. For example, each banknote 1 may include one, two, or more designs F1-F3, which may have pigment particles oriented according to at least one, but preferably multiple, different magnetic effects G1-G3. Security elements A-B-A and A-B-C form elongated security features 4.
第3圖展示用於對基板S上的顏料粒子進行定向以獲得所需效應的傳送裝置100。第3圖表示傳送裝置100的外表面。傳送裝置100在此處係圓柱形傳送裝置100。圓柱形傳送裝置100的形成外表面的側表面在展開時具有矩形形狀,這對應於第3圖的表示。傳送裝置100具有與第1圖的基板S的結構類似的結構,因為傳送裝置100用於在將基板S放置在傳送裝置100前方時對基板S的顏料粒子進行定向。因此,傳送裝置100具有NxP個磁性塊102 (為了方便閱讀,第3圖中僅揭示一些具有參考標誌的磁性塊102),其中N為列數且N=8,而P為行數且P=6。沿著每條對準線103 (與對準線對準且平行)配置N=8個相同的磁性塊102,該對準線在第3圖的表示中延伸穿過一行但是遵循圓柱形傳送裝置100的橫截面的外圓周線。每個磁性塊102具有M=3個磁場產生裝置101,用於根據磁效應G1-G3產生磁場。在第3圖的實例中,最左側三個行具有的磁性塊102各自包括按此順序產生磁效應G1-G2-G1 (即第2a圖的鈔票)的磁場產生裝置101,而最右側三個行具有的磁性塊102各自包括按此順序產生磁效應G1-G2-G3 (即第2b圖的鈔票)的磁場產生裝置101。Figure 3 illustrates a conveying device 100 used to orient pigment particles on a substrate S to obtain a desired effect. Figure 3 shows the outer surface of the conveying device 100. The conveying device 100 here is a cylindrical conveying device 100. The side surfaces forming the outer surface of the cylindrical conveying device 100 have a rectangular shape when unfolded, corresponding to the representation in Figure 3. The conveying device 100 has a structure similar to that of the substrate S in Figure 1, because the conveying device 100 is used to orient the pigment particles on the substrate S when the substrate S is placed in front of the conveying device 100. Therefore, the conveying device 100 has N×P magnetic blocks 102 (for ease of reading, only some magnetic blocks 102 with reference numerals are shown in Figure 3), where N is the number of columns and N=8, and P is the number of rows and P=6. N=8 identical magnetic blocks 102 are arranged along each alignment line 103 (aligned and parallel to the alignment line), which in the representation of Figure 3 extends through a row but follows the outer circumference of the cross section of the cylindrical conveying device 100. Each magnetic block 102 has M=3 magnetic field generating devices 101 for generating magnetic fields according to magnetic effects G1-G3. In the example of Figure 3, the magnetic blocks 102 in the leftmost three rows each include magnetic field generating devices 101 that generate magnetic effects G1-G2-G1 (i.e., the banknotes in Figure 2a) in this order, while the magnetic blocks 102 in the rightmost three rows each include magnetic field generating devices 101 that generate magnetic effects G1-G2-G3 (i.e., the banknotes in Figure 2b) in this order.
如第3圖中可看出,上部及下部磁性塊102 (即與紙張S的後邊緣BE及前邊緣FE相鄰的磁性塊102)形成邊緣磁性塊104,該邊緣磁性塊沿著其對準線103具有僅一個鄰居,而所有其他磁性塊102具有兩個垂直的鄰居。由於沿著對準線103的相鄰磁性塊102會影響彼此的磁場,因此具有一個鄰居的磁性塊102 (即磁性塊104)將顏料粒子曝露於與具有兩個鄰居的磁性塊102不同的磁場。因此,並非所有的鈔票1都曝露於相同的磁場,從而導致在鈔票1上產生的效應之間發生變化。此等變化係不良的,因此傳送裝置100包含用於避免不同的磁性塊102在鈔票1上產生的效應之間發生變化的構件。此等構件可採取下文將描述的不同形式。第一實施例 As can be seen in Figure 3, the upper and lower magnetic blocks 102 (i.e., the magnetic blocks 102 adjacent to the rear edge BE and front edge FE of the paper S) form an edge magnetic block 104. This edge magnetic block has only one neighbor along its alignment line 103, while all other magnetic blocks 102 have two perpendicular neighbors. Since adjacent magnetic blocks 102 along the alignment line 103 affect each other's magnetic fields, a magnetic block 102 with one neighbor (i.e., magnetic block 104) exposes the pigment particles to a different magnetic field than a magnetic block 102 with two neighbors. Therefore, not all banknotes 1 are exposed to the same magnetic field, resulting in variations in the effects produced on the banknotes 1. Such variations are undesirable; therefore, the transmission device 100 includes components to prevent variations in the effects produced by different magnetic blocks 102 on the banknote 1. These components may take different forms as described below. First Embodiment
根據傳送裝置100的第一實施例,藉由沿著對準線103在相鄰磁性塊102之間設置屏蔽元件105來解決上述問題。這展示於第4圖中,第4圖展示第3圖的傳送裝置100的一個行的實例,其中屏蔽元件105沿著對準線103設置在每個相鄰磁性塊102之間。在第4圖的實例中,設置了七個屏蔽元件105。更一般地,為了沿著對準線103對準N個磁性塊102,設置(N-1)個屏蔽元件105。屏蔽元件105由S235鋼製成。屏蔽元件105將每個磁性塊102的磁場與相鄰磁性塊102的磁場隔離。這意味著來自相鄰磁性塊102的磁場不會彼此相互作用。因此,不管磁性塊102沿著對準線103具有單一鄰居(如邊緣磁性塊104的情況)還是具有兩個鄰居,每個磁性塊102提供至基板S上的塊磁場都是相同的。這導致在基板S的所有鈔票1上產生相同的效應。According to a first embodiment of the transmission device 100, the aforementioned problem is solved by providing shielding elements 105 along the alignment line 103 between adjacent magnetic blocks 102. This is shown in Figure 4, which shows an example of a row of the transmission device 100 of Figure 3, wherein shielding elements 105 are provided along the alignment line 103 between each adjacent magnetic block 102. In the example of Figure 4, seven shielding elements 105 are provided. More generally, (N-1) shielding elements 105 are provided to align N magnetic blocks 102 along the alignment line 103. The shielding elements 105 are made of S235 steel. The shielding elements 105 isolate the magnetic field of each magnetic block 102 from the magnetic fields of adjacent magnetic blocks 102. This means that the magnetic fields from adjacent magnetic blocks 102 do not interact with each other. Therefore, whether a magnetic block 102 has a single neighbor along the alignment line 103 (as in the case of the edge magnetic block 104) or two neighbors, the block magnetic field provided by each magnetic block 102 to the substrate S is the same. This results in the same effect on all banknotes 1 on the substrate S.
屏蔽元件105可為容納殼體301的一部分,該等容納殼體各自容納一個磁性塊102。第5圖中示出此種容納殼體301,第5圖展示包含用於容納一個磁性塊102的容納殼體301的磁性定向單元300。此處,屏蔽元件105由容納殼體301的側壁形成。容納殼體301容納形成一個磁性塊102的三個磁場產生裝置101。容納殼體301包含蓋子302。第5a圖示出磁性總成300的橫截面圖,且第5b圖示出磁性組件300的俯視圖(在第5b圖中,為了清楚起見,未表示蓋子302)。第5c圖示意性地示出僅容納殼體301的橫截面圖。第二實施例 The shielding element 105 may be part of a housing 301, each housing a magnetic block 102. This housing 301 is shown in Figure 5, which illustrates a magnetic orientation unit 300 comprising the housing 301 for housing a magnetic block 102. Here, the shielding element 105 is formed from the sidewall of the housing 301. The housing 301 houses three magnetic field generating devices 101 forming a magnetic block 102. The housing 301 includes a cover 302. Figure 5a shows a cross-sectional view of the magnetic assembly 300, and Figure 5b shows a top view of the magnetic assembly 300 (in Figure 5b, the cover 302 is not shown for clarity). Figure 5c schematically shows a cross-sectional view accommodating only the shell 301. Second Embodiment
根據傳送裝置100的第二實施例,藉由給傳送裝置100提供補償磁性塊106及可選的額外補償磁性塊107來解決上述問題,該等磁性塊展示於第6圖中,第6圖展示第3圖的傳送裝置100的一行N=8個磁性塊102,該等磁性塊沿著對準線103對準。與磁性塊102相比,補償磁性塊106及額外補償磁性塊107並不用於在基板S上創建對應的效應,而僅用於針對邊緣磁性塊104模擬額外的相鄰磁性塊102。According to a second embodiment of the transmission device 100, the above-mentioned problem is solved by providing the transmission device 100 with compensating magnetic blocks 106 and optional additional compensating magnetic blocks 107, which are shown in Figure 6. Figure 6 shows a row of N=8 magnetic blocks 102 of the transmission device 100 in Figure 3, which are aligned along the alignment line 103. Compared with the magnetic blocks 102, the compensating magnetic blocks 106 and additional compensating magnetic blocks 107 are not used to create corresponding effects on the substrate S, but are only used to simulate additional adjacent magnetic blocks 102 for the edge magnetic blocks 104.
補償磁性塊106當設置在傳送裝置100上且與對準線103對準時面向紙張S的前邊緣FE。補償磁性塊106包括一個補償磁場產生裝置108,該補償磁場產生裝置係產生磁效應G3的磁場產生裝置101且因此對應於第6圖的對準的每個磁性塊102之第三(第M)個磁場產生裝置101。類似地,額外補償磁性塊107當設置在傳送裝置100上且與對準線103對準時面向紙張S的後邊緣BE。額外補償磁性塊107包括一個額外補償磁場產生裝置109,該額外補償磁場產生裝置係產生磁效應G1的磁場產生裝置101且因此對應於第6圖的對準的每個磁性塊102之第一個磁場產生裝置101。因此,補償磁性塊106及額外補償磁性塊107針對邊緣磁性塊104模擬相鄰磁性塊102的磁場。因此,每個磁性塊102在基板S上產生的磁場係相同的,從而導致每張鈔票1上的安全特徵4相同。The compensating magnetic block 106 faces the leading edge FE of the paper S when it is placed on the conveying device 100 and aligned with the alignment line 103. The compensating magnetic block 106 includes a compensating magnetic field generating device 108, which is the magnetic field generating device 101 that generates the magnetic effect G3 and thus corresponds to the third (Mth) magnetic field generating device 101 of each aligned magnetic block 102 in Figure 6. Similarly, the additional compensating magnetic block 107 faces the trailing edge BE of the paper S when it is placed on the conveying device 100 and aligned with the alignment line 103. The additional compensating magnetic block 107 includes an additional compensating magnetic field generating device 109, which is the magnetic field generating device 101 that generates the magnetic effect G1 and thus corresponds to the first magnetic field generating device 101 of each aligned magnetic block 102 in Figure 6. Therefore, the compensating magnetic block 106 and the additional compensating magnetic block 107 simulate the magnetic field of the adjacent magnetic block 102 for the edge magnetic block 104. Therefore, the magnetic field generated on the substrate S by each magnetic block 102 is the same, resulting in the same security feature 4 on each banknote 1.
補償磁性塊106及/或額外補償磁性塊107可包含多個磁場產生裝置101,而不是僅包括一個補償磁場產生裝置108或109,特別是與其他磁性塊102一樣多,使得補償磁性塊106及/或額外補償磁性塊107可與磁性塊102相同。The compensating magnetic block 106 and/or the additional compensating magnetic block 107 may include multiple magnetic field generating devices 101, rather than just one compensating magnetic field generating device 108 or 109, and in particular, as many as the other magnetic blocks 102, so that the compensating magnetic block 106 and/or the additional compensating magnetic block 107 can be the same as the magnetic block 102.
每個磁性塊102、補償磁性塊106及/或額外補償磁性塊107可由針對第5圖所描述的容納殼體301容納。容納殼體301可包括屏蔽元件105,或可提供成沒有屏蔽元件105。用於產生安全文件的方法 Each magnetic block 102, compensating magnetic block 106, and/or additional compensating magnetic block 107 can be accommodated by a housing 301 as described in Figure 5. The housing 301 may include a shielding element 105, or may be provided without a shielding element 105. Method for generating security documents.
上述第一或第二實施例的傳送裝置100可在產生至少N個安全文件(此處為鈔票1)的製程中使用。第7圖及第8圖中揭示此種製程,以下將詳細說明。The transmission device 100 of the first or second embodiment described above can be used in a process that generates at least N secure documents (here, banknote 1). This process is illustrated in Figures 7 and 8, and will be described in detail below.
在第7圖的步驟a)中,提供紙張狀基板S。在步驟b)中,將包含片狀磁性或可磁化顏料粒子的輻射可固化塗層組合物200塗覆於基板S的表面上。塗層組合物200係在第一狀態下塗覆,在第一狀態下顏料粒子可在基板S的表面上移動。塗層組合物200此處針對N個安全特徵中之每一者以M個獨立的且可選地間隔開的花紋圖案的形式藉由絲網印刷來塗覆。換言之,針對要創建的鈔票1的每個安全元件A-C印刷一個花紋圖案。花紋圖案印刷成採取第2圖所示的花紋圖案F1-F3的形狀。In step a) of Figure 7, a paper-like substrate S is provided. In step b), a radiation-curable coating composition 200 containing sheet-like magnetic or magnetizable pigment particles is applied to the surface of the substrate S. The coating composition 200 is applied in a first state, in which the pigment particles can move on the surface of the substrate S. The coating composition 200 is here applied by screen printing for each of the N security features in the form of M independent and optionally spaced patterns. In other words, one pattern is printed for each security element A-C of the banknote 1 to be created. The patterns are printed in the shapes of patterns F1-F3 shown in Figure 2.
在可選步驟f)中,將顏料粒子曝露於由用於產生時間相關磁場的磁場產生裝置201產生的時間相關磁場,以對顏料粒子進行雙軸預定向。基板S在用於產生時間相關磁場的磁場產生裝置201前方移動,如第7圖的步驟f)中指向右的箭頭所指示。然後將基板S設置在傳送裝置100上。In optional step f), pigment particles are exposed to a time-dependent magnetic field generated by the magnetic field generating device 201 for generating a time-dependent magnetic field, in order to pre-orient the pigment particles in a biaxial manner. The substrate S is moved in front of the magnetic field generating device 201 for generating a time-dependent magnetic field, as indicated by the right-pointing arrow in step f) of Figure 7. The substrate S is then placed on the conveying device 100.
在隨後的步驟c)中,將顏料粒子曝露於由傳送裝置100的磁性塊102產生的塊磁場中。為此,將基板S放置成面向傳送裝置100,使得在製程的步驟b)中塗覆於基板S上的每個花紋圖案F1-F3面向傳送裝置100的磁性塊102的磁場產生裝置101。In subsequent step c), pigment particles are exposed to a block magnetic field generated by the magnetic block 102 of the conveying device 100. For this purpose, the substrate S is positioned facing the conveying device 100, such that each pattern F1-F3 coated on the substrate S in step b) of the process faces the magnetic field generating device 101 of the magnetic block 102 of the conveying device 100.
在第7圖的製程的步驟d)中,將塗層組合物200固化成第二乾燥狀態,在此狀態下顏料粒子被固定。使用紫外線燈202執行固化。結果,在步驟b)中塗覆的每個花紋圖案F1-F3被固化至安全元件A-C中。因此獲得具有至少N個安全特徵4的基板S。藉由在N個安全特徵4之間對基板進行分割,可獲得N張鈔票1。In step d) of the process in Figure 7, the coating composition 200 is cured to a second dry state, in which the pigment particles are fixed. Curing is performed using a UV lamp 202. As a result, each pattern F1-F3 coated in step b) is cured into the security elements A-C. Thus, a substrate S with at least N security features 4 is obtained. By dividing the substrate between the N security features 4, N banknotes 1 can be obtained.
如本文所定義,一個安全文件(鈔票1)包括一個安全特徵4。一個安全特徵4由多個安全元件(多個OEL) A-C構成,該等安全元件的特徵在於(i)其形狀(花紋圖案F1-F3)及(ii)由對應的磁場產生裝置101施加至其的磁效應G1-G3。在非固化狀態下,包括顏料粒子的塗層組合物200以花紋圖案F1-F3的形式塗覆至基板S,每個固化的花紋圖案形成安全元件A-C。安全元件A-C可間隔開或者可至少部分地相鄰(即至少部分地彼此接觸)。As defined herein, a secure document (banknote 1) includes a security feature 4. A security feature 4 comprises multiple security elements (multiple OELs) A-C, characterized by (i) their shape (patterns F1-F3) and (ii) the magnetic effects G1-G3 applied to them by corresponding magnetic field generating devices 101. In a non-cured state, a coating composition 200 comprising pigment particles is coated onto a substrate S in the form of patterns F1-F3, each cured pattern forming a security element A-C. Security elements A-C may be spaced apart or at least partially adjacent (i.e., at least partially in contact with each other).
第8圖示意性地示出執行第7圖的製程以產生至少N個安全文件1的印刷機500之實例。如第8圖中可看出,將紙張S插入並引導通過印刷機500。紙張S具有N個獨立的且(此處)間隔開的所塗覆塗層組合物花紋圖案多重體203(各自包括花紋圖案F1-F3,因此多重體在此處為三重體),該等多重體共同形成塗層組合物200。花紋圖案三重體203係藉由絲網印刷裝置204 (對應於第7圖的步驟b))塗覆的。在第8圖的實例中,印刷機500包括一個磁場產生裝置201,用於產生時間相關磁場以在紙張S到達傳送裝置100之前對顏料粒子進行雙軸定向(第7圖的步驟f))。如第8圖所示,圓柱形傳送裝置100旋轉,從而引導紙張S通過印刷機500。Figure 8 schematically illustrates an example of a printing press 500 performing the process of Figure 7 to produce at least N security documents 1. As can be seen in Figure 8, a sheet of paper S is inserted and guided through the printing press 500. The sheet of paper S has N independent and spaced-apart multi-layers 203 of coated pattern (each including pattern F1-F3, therefore the multi-layer is a triplet here), which together form the coating composition 200. The pattern triplets 203 are coated by a screen printing device 204 (corresponding to step b) of Figure 7. In the example of Figure 8, the printing press 500 includes a magnetic field generating device 201 for generating a time-correlated magnetic field to biaxially orient the pigment particles before the paper S reaches the conveying device 100 (step f in Figure 7). As shown in Figure 8, the cylindrical conveying device 100 rotates, thereby guiding the paper S through the printing press 500.
磁性塊102之間的距離與花紋圖案多重體203之間的距離相同,因此每個磁性塊102對所面對的花紋圖案多重體203的顏料粒子進行定向。紫外線燈202放置成使得固化(第7圖的步驟d))與定向顏料粒子的步驟(第7圖的步驟c))部分同時執行。The distance between the magnetic blocks 102 is the same as the distance between the pattern multiply 203, so each magnetic block 102 orients the pigment particles of the pattern multiply 203 it faces. The ultraviolet lamp 202 is positioned such that curing (step d in Figure 7) and the step of orienting the pigment particles (step c in Figure 7) are performed simultaneously.
第9圖展示第8圖的印刷機500的變型,其中用於產生時間相關磁場以對顏料粒子進行雙軸定向的磁場產生裝置201被設置成面向圓柱形傳送裝置100。Figure 9 shows a variation of the printing press 500 in Figure 8, wherein the magnetic field generating device 201 for generating a time-correlated magnetic field to biaxially orient pigment particles is configured to face the cylindrical conveying device 100.
第10圖展示第8圖及第9圖的印刷機500的另一變型,其包括第8圖及第9圖的用於產生時間相關磁場的兩種磁場產生裝置201,該等磁場產生裝置用於對顏料粒子進行雙軸定向。Figure 10 shows another variation of the printing press 500 of Figures 8 and 9, which includes two magnetic field generating devices 201 of Figures 8 and 9 for generating time-correlated magnetic fields, which are used for biaxial orientation of pigment particles.
上文揭示的標的物應被視為說明性的,而不是限制性的,且用於提供對獨立請求項所定義的本發明之更好的理解。The subject matter disclosed above should be considered illustrative rather than restrictive, and is intended to provide a better understanding of the invention as defined in the independent claim.
1:鈔票2:不透明區域3:透明區域4:安全特徵100:傳送裝置101:磁場產生裝置102:磁性塊103:對準線104:邊緣磁性塊105:屏蔽元件106:補償磁性塊107:額外補償磁性塊108:補償磁場產生裝置109:額外補償磁場產生裝置200:塗層組合物201:產生時間相關磁場的磁場產生裝置202:紫外線燈203:花紋圖案多重體204:絲網印刷裝置300:磁性定向裝置301:容納殼體302:蓋子500:印刷機A-C:安全元件或光學效應層(OEL)BE:後邊緣FE:前邊緣F1-F3:花紋圖案G1-G3:磁效應R1-R8:列S:基板Y1-Y6:行1: Banknote 2: Opaque Area 3: Transparent Area 4: Security Feature 100: Transmission Device 101: Magnetic Field Generating Device 102: Magnetic Block 103: Alignment Line 104: Edge Magnetic Block 105: Shielding Element 106: Compensating Magnetic Block 107: Additional Compensating Magnetic Block 108: Compensating Magnetic Field Generating Device 109: Additional Compensating Magnetic Field Generating Device 200: Coating Composite 201: Time-Related Generation Magnetic field generating device 202: Ultraviolet lamp 203: Pattern multi-body 204: Screen printing device 300: Magnetic orientation device 301: Housing 302: Cover 500: Printing press A-C: Safety element or optical effect layer (OEL) BE: Trailing edge FE: Leading edge F1-F3: Pattern G1-G3: Magnetic effect R1-R8: Column S: Substrate Y1-Y6: Row
第 1 圖展示用於印刷鈔票的基板的實例;第 2a 圖至第 2b 圖展示鈔票的實例;第 3 圖展示傳送裝置;第 4 圖展示根據第一實施例的傳送裝置的截面;第 5a 圖至第 5c 圖展示磁性定向單元;第 6 圖展示根據第二實施例的傳送裝置的截面;第 7 圖展示用於產生安全文件的方法;第 8 圖示意性地展示印刷機的第一實例;第 9 圖示意性地展示印刷機的第二實例;且第 10 圖示意性地展示印刷機的第三實例。 Figure 1 shows an example of a substrate for printing banknotes; Figures 2a and 2b show examples of banknotes; Figure 3 shows a conveying device; Figure 4 shows a cross-section of the conveying device according to the first embodiment; Figures 5a and 5c show magnetic orientation units; Figure 6 shows a cross - section of the conveying device according to the second embodiment; Figure 7 shows a method for generating security documents; Figure 8 schematically shows a first example of a printing press; Figure 9 schematically shows a second example of a printing press; and Figure 10 schematically shows a third example of a printing press.
1:鈔票 1: Banknotes
2:不透明區域 2: Opaque Areas
3:透明區域 3: Transparent Areas
R1-R8:列 R1-R8: Columns
S:基板 S:Substrate
Y1-Y6:行 Y1-Y6: Rows
BE:後邊緣 BE: Back Edge
FE:前邊緣 FE: Leading edge
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