TW210328B - - Google Patents

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TW210328B
TW210328B TW80105212A TW80105212A TW210328B TW 210328 B TW210328 B TW 210328B TW 80105212 A TW80105212 A TW 80105212A TW 80105212 A TW80105212 A TW 80105212A TW 210328 B TW210328 B TW 210328B
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Taiwan
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light
band
wavelength
core
optical
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TW80105212A
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Chinese (zh)
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Sumitomo Electric Industries
Nippon Telegraph & Telephone
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2ΐ〇3λ-Β A 6 Β6 經濟部中央標準局貝工消費合作社印製 五、發明説明(1 ) (産業上之利用範園) 本發明偽有簡於一種可使用在1.3« 箝域之光鑛大的 光功能性玻璃,光鑛,光纖擴大器以及光编雷射。 (習用技術) 為了要鼴用至1.3« b搏域之光通訊範園,因此乃努力 製作使用添加有稀土類元素之玻璃的光繼鑛大器,光鑛 檢澜器,光繼雷射等之光鑛大裝置,例如亦有準備有在 磷酸麵条之多成分玻璃添加有Nd3 +之玻璃,而就由該 玻璃所形成之光鑛之雷射振鹽特性進行評價的報告。( ELECRONICS LETTERS,1 990 V ο 1,26.N〇.2,pp121 - 1 22 ) 〇 在該報告中可知有臞光纖之特性,對於Nd 3 +之螢光尖 峰(peak)波長為 1.32/in,而因 ESA(excited state absorption)所導致之尖峰,其波長為1.31w·,而擴大 光峰波長則為1.36/u ·。 (本發明所要解決之問龎) 但是在上述報告中所示之多成分玻璃.於波長1.3«« 帶域無法得到笛射振鼸增益。而無法得到雷射振衋增益 之原因,邸是在波長1.32«·帶域之Nd3 +之螢光光峰 比較擻弱以及由ESA邏移所導致比較大的吸收尖峰晒好 存在於波長1.31« 之故。 更者如上述之光鑛般,在利用誘導放出激發而進行光 擴大時,不僅在波長1.3«·之螢光尖峰小,又亦存在因 可能之邏移導致螢光尖峰存在的問題,所以在上述光繼 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂. 線. 太燎徜用中阈团甲4扭格(210x297公修) 2103^^ A 6 B6 五、發明説明(2 長 3 波Hd 之輿 + 生 3 産 d few N 嫌 了可 除有 幣他 其 JU 3 之 外長 弱波 較之 比應 峰對 尖移 光* 螢之 之能 域可 供 提 於 061 在 1.長 的 長波 目 波在 要 。礙。主 域防低其 W 帶此降 , 06/UBE1 地此 1 8 ,著於 長0.出顯鑑 波長放率有 ,波導效邸 域該誘其明 帶在於,發 y "而因 B 本3W9I ,亦8U。起放而1.玻又纖更射 I 中 ,0.題係導 長性 光 雷(« 比帶 而 反6« 光.0 發ί 之 域 帶 問光 的發 強之 較域 0 之 光 域 帶 波 在 可2 Ι〇3λ-Β A 6 Β6 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy V. Description of the invention (1) (Industrial use garden) This invention is actually simpler than a light that can be used in 1.3 Mine's optical functional glass, optical mine, fiber amplifier and optical laser. (Conventional technology) In order to use the optical communication field of 1.3 «b-beating domain, we are making great efforts to make optical relays, optical detectors, and lasers that use rare earth added glass For example, there is a report for evaluating the characteristics of the laser vibration salt of the light mine formed by the glass of Nit3 + added to the multi-component glass of phosphoric acid noodles. (ELECRONICS LETTERS, 1 990 V ο 1,26.N〇.2, pp121-1 22) 〇In this report, we can see the characteristics of the fiber, for Nd 3 + fluorescence peak (peak) wavelength is 1.32 / in , And the peak caused by ESA (excited state absorption) has a wavelength of 1.31w ·, and the wavelength of the expanded light peak is 1.36 / u ·. (Problems to be solved by the present invention) However, the multi-component glass shown in the above report cannot obtain the lasing vibration ray gain at the wavelength 1.3 «« band. The reason why the laser vibration gain cannot be obtained is that the fluorescence peak of Nd3 + in the band 1.32 «· band is weak and the large absorption peak caused by the ESA logic shift exists at the wavelength 1.31« Reason. What's more, like the above-mentioned light mine, when the induced emission is used to expand the light, not only is the fluorescent peak at a wavelength 1.3 «· small, but also there is a problem of fluorescent peaks due to possible logic shifts, so in The above Guang Ji (please read the precautions on the back before filling in this page). Binding. Thread. Too much use the middle threshold group armor 4 twisted grid (210x297 public repair) 2103 ^^ A 6 B6 V. Description of invention (2 Long 3 waves of Hd + + 3 produced d few N suspected that in addition to other coins and other JU 3, the long and weak waves can be compared to the peak-to-tip shifting light * The energy range of the firefly is available for 061 at 1. Long long-wave eye waves are important. Obstacle. The main domain is anti-lower and its W-band is lowered, 06 / UBE1 is at this ground 18, and it is at long 0. There is a significant wavelength emission rate, and the waveguide effect domain should induce its bright band. Lies in the fact that it is y " and because of the B 3W9I, it is also 8U. It is released and 1. The glass and the fiber are shot I, 0. The problem is to guide the long light mine («than the belt and the reverse 6« light. 0 hair ί The intensity of the light in the zone is better than that of the zone 0.

帶 W 能 功 光 之 率 效 大 擴 其 高 提 是 或 大 擴 光 行 進 域 供 提。 於件 在元 的徑 目路 之導 明波 發及 本以 又 之 璃 玻 性 能 功 光 述 上 用 使 (請先閱讀背面之注意事項再塡寫本頁) 裝· 供 。 提射 於雷 在件 的元 目徑 之路 明導 發波 本及 者以 mu 0 光 之 纖 光 述 上 用 使 可 訂· 用 作 及 以 段 手 之 賵 問 決 僳可 ,且 I 結璃 之玻 究性 研能 稹功 累光 經之 ,質 M物 問性 述活 上為 決 + 解 3 要Nd 了以 為含 明包 發一 本供 提 進 域 帶 0 U 3 1* 在 功 光 之 明 發 本 。亦0 玻外 之 + 率 3 效Nd 大霣 擴物 其性 高活 提了 是除 或 , 大璃 擴玻 光性 行能 線· 經濟部中央標準局员工消費合作社印製 土 稀 之 外璃 以玻 + 主 3 為 Nd成 之又 幣 。 收劑 吸進 有促 備或 近 _ 附收 吸 JU 1 為 長作 波而 在 , 有子 加離 添類 陣 矩 等, 璃璃 玻玻 鹽条 酸物 磷化 了弗 除用 ,使 璃可 玻亦 分, 成外 多之 之璃 S)玻 as分 gl成 y 多 *1 r 条 rt物 S化 璃氣 玻之 物HC 化藉 磯璃 收 級 可 玻在 性存 齙的如 功 _ 光收 之吸近 明等 發子 本麵 據+ 根 3 r畏 # P » 之波 玻加 S)添 en所之 08及 + 1 以 3 在 4 附 例 太蚯张尺疳诂用中因63¾:捸rn(CNS)甲4規.格(210乂297公:康) 2103^8 A 6 B6 經濟部中央標準局眞工消費合作社印製 五、發明説明(3 ) 波長1.06u·帶域,波長〇.88u·播域)的發光,更者藉 Nd3 +以及所添加之Tb3 +離子等促進«I的存在,可提 高Hd3 +在波長1.3W«帶域的發光櫬率。其结果,可使 Nd3 +在波長1.3«»指域之發光。光擴大成為可能,更 者可如後述般,得到一可增大其效率,增益等之玻璃。 此時,用來吸收波長1.06//·箝域之發光的圾收 除了 Pr3 +以外,亦可使用Yb3 + ,S·3 +等離子。又 用來吸收波長0.88«·帶域之發光的吸收雨,則亦可使 用Ho3 +離子。S —方面用來促進波長1.3«<•箝域之發 光的促進劑,除了 Tb3 +以外,亦可使用Eu3 +等離子 0 又若將Pr3+ ,Yb3+ ,S«+2等之鼸度相對對於Hd3+ »成 重量百分比為50%〜150% ,則更可提高作為吸收劑之 效果。 又本發明之光繼,備有由上述之光功能性玻璃所形成 之核心以及包園該核心而具備較低折射率之教龌。 根據該種光纖,由於在核心玻璃中,除了 Hd3 +以外 ,亦添加有吸收麵及/或促進因此可将在核心玻瑱 中傳送之波長1.31« 帶域之光加以鑛大或是增大其光 擴大增益,又由於藉光繼化,可将光有效率地封閉在核 心以及被封閉之光之損失極低,因此可以低®限值使Hd3 形成反轉分佈。 又本發明之光繼擴大器,乃具備上述之光纖,激起光 (請先閲讀背面之注意事項再塡寫本頁) 裝· 訂_ 線- 五、發明説明(4 ) A 6 B6 經濟部中央標準局员工消費合作社印製 倍學 之之 3 以激内纖構 長3 在 小 之光 内起1.U 源之纖光器 波Nd長可 極 域又 纖檄長 Μ 光域光自振 之之波而 成。 。 箱, 光被波la發帶至來共 内發之, 構射 緯 Η 光 至該之 W 檄U·射将的 纖激内光 可雷 經 3/i起 c入,内而 ,8«入可纖 光被纖射 邸件 之 1.激内導 + u)fc,鑛0.源有光 至該光放 ,元 止 長之纖置3 光 W 光長光成至 入,至生 時徑 為 波域光裝Nd至㈣ 之波發形饑 導+ 入産 纖路 成 送楢至學出入 W 述生激則回 置3 導而 光導 完 傅//射光發導 Η 上産自,光 装Nd被, 述波 至 乃8W入被瀲被fnji備即光中的 學出時導。上及 及 鑛0.源藉而時 H 具源發射近 光發同誘大代以 以 光生光,光同 UC乃光檄笛附 被檄被所鑛取器 理 此産起器起被 Η 大射發将纖其 《而則等光件大 原 在即瀲大激則 U 擴笛激則光或 ,光,光行元擴 之 。源自擴之 ,Μ 光纖此置之域 射發數號進徑件 明 置光光纖域數 Μ 行光在裝明帶 笛激多倍域路元 發 装起起光帶多 Η 進之。學發 U 鑛之大之凿導徑 本 學激激述 u大 Μ 域明置光本3 光域或域 U波路 明 光而将上8«的 Μ 帶發裝而在1.該帶分僭3W以導 W 說 及,則_0.+^//«本學,者長 據"部/iBIl.^波U下 以光置根長3>f3 又光光更波 C根 8 一 3 長又之 Μ 以 源號裝 波Ndwl.及發。之造0.之1.波 型(* ........................^.....^*· · · ά (請先閱讀背面之注意事項再填寫本頁) 太疳ii用Φ因团犮熄rn iCNS)甲4组格m 0 乂 297公分) 2. 24 103^8 A 6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明(5 ) 有藺上述之現象,發明者乃建立2值假設而加以檢討 ,以下依序説明該些假設 (有關第1假設之説明) 被導入至添加有Hd3 +之光功能性玻瑰之0.8« 帶域 之檄發光乃激發作為活性物質的Nd3 +。其結果可對匾 自能量準位4 F 3/2至能量4 I 13/2之遷移而産生1.3 w «帶域的輻射。又其他之輻射,可對應自能量準位4F 3/2至能量準位4 I 11/2或4 I 9/2之遷移,而産生 波長1 . 0 6 « b帶域或0 . 8 8// m帶域的幅射,而將有關N d離 子之上述現象作統合性的考董。在主玻璃中之Hd3 +的 大多數乃被激發,而可産生對應於波長1.3w»帶域之發 光的遷移,又對於不期待發生之與波長〇.88WB帶域, 波長1.06« 帶域之發光對應之遷移亦明可能同時産生 。此時被榭發之上述Nd 3 +的一部分,可《自然放出或 激發放出,而依一定的機率放射波長1.3« b帶域的光。 又被檄發之上述Hd 3 +的一部分,刖藉自然放出或檄發 放出,依一定的機率而不産生1.3«n帶域的光,而是放 射波長0.88«·或1.06«·帶域的光。此時在主玻璃中, 若存在某程度量的吸收劑,亦即是波長0.8 8 w 帶域或 波長1 . 0 6 « *帶域之放射光的吸收體,而不是波長1 . 3 α 帶域之放射光的吸收體,則拜該些吸收劑可將被放射之 0.88«®帶域或1.06«·帶域之光加以吸收。藉該吸收可 抑制因波長0.88« β帶域或1.06w β帶域之放射光所導致 (請先閲讀背面之注意事項再填寫本頁) 裝. 經濟部中央標準局員工消費合作社印製 2103Lb Αβ A ο _ B6_ 五、發明説明(6 ) 之撖發放出現象。例如若考慮使用僅吸收波長1.06/u· 帶域之放射光之吸收劑畤,則該吸收劑至少可抑制Nd 3 ^ 在波長域之發光。更者若考慮使用波長0.88«臟 帶域之光之吸收麵時,則至少可抑制在波長0.88 箝 域之發光,藉此可防止在波長1.3«·错域之檄發放出 效率之降低。有鼸以上之懔設,讁參照第1圆,第2圈 以及第3圈加以具鱺地説明。 第2國你表被添加至磷酸鹽条之玻璃試料之Nd3 +的 能·準位匾。如圏所示之吸,發光邇移波長,俱使用分 光光度計以及光譜分析儀來拥I董由該些玻璃所製作之光 雄而算出。由於說明僳重複,乃就主要之遍移現象加以 説明。藉約0.8w·之激發光,使位在基底準位4 I 9/2 之«子被暫畤激發至準位4 F 5/2,而藉多轚子(phonon )鍰和作用而*移至準位4F 3/2,藉該激發(ρνι·Ρίη8> ,若在準位 4 F 3/2,準位 4 I 9/2, 4 I 11/2, 4 I 13/2以及4 I 15/2之間形成反_分布時,則會以波長 0.88« , 1.06« 波長 1.33« 波長 1.80tf 為光峰(peak )而發光,其中波長0.88«·,波長1.06«麵,及波長1.33 u·之發光的強度比,可自僅將激發光入射至該光纖時 之餐光尖峰之离度比而求得,大約為5:9:1。更者在波 長1.80«·之發光強度,由於比較弱而無法求得。 而針對在波長1.06w 箝域或0.88w β傅域之發光櫬率 極久的事資,第1醒則表示用來滅低因該發光所導致瀲 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂_ 線- 太蚯铬只府这用中团囷宅熄m(CNS)平4痴格m〇x297公修) 經濟部中央標準局員工消費合作社印製 a6 _B6_ 五、發明説明(7 ) 發放出之方法。 在第1鼷(8)中,被激發之第1 Nd3 +離子11,例如 可鞴自然放出而放射波長1.3w·爾域,跨長0.8w»帶域 或波長1.06«·箝域的光。此時由於在波長0.88帶域以 及波長1.06错域之發光機率非常大,因此藉自然放出光 被激發之第2Nd3 +離子12之大多數邸會放出波長0.88 «帶域或是波長1 . 0 6 α 1«帶域的光。另一方面在第1 (b)中,刖與第1匾U)相同,被檄發之第1 Nd3 +離子 11會放射波長1 . 3 « 箝域,波長0.8 8 « 箝域或是波長 1.06箝域的光。例如在此若存在對發光機率高之0.88WB1 帶域或1.06ju 帶域之光可作為吸收繭之吸收黼13時, 則波長0.88« «错域或1.06« 帶域之放射光可被該吸收 黼13所吸收,而對第2 Nd3 +離子不會産生彩鬱。 本發明乃使用波長1.06w 帶域之吸收鼸(或吸收W以 及波長0.8 8 « 帶域之吸收鼸(吸收Μ ,在波長1 . 0 6 «騰 帶域之吸收體時,由於其發光機率比較离,因此可有效 提升在波長1.3«·帶域之激發放出的機率。另一方面 在波長0.88α 帶域之吸收鱺時,雖然無法抑制因波長 1.06«·帶域之放出光所導致之瀲發放出現象,然至少 可抑制因波長0.88« 帶域之放出光所導致之激發放出 現象,因此可提高在波長1.3«·箝域之檄發放出的檐率 〇 作為上述波長1.06iu 域或0.88// 帮域之吸收鱺的 -9 - (請先閲讀背面之注意事項再填寫本頁) 裝. -線·The efficiency of the light with W energy is greatly expanded, and its high speed is improved or provided by the marching light. It is used in the guidance of the path and the path of the element and the glass and glass performance function (please read the precautions on the back before writing this page) for installation and supply. Mentioned by Lei Zai's way of the Yuanmu Path, the guide will send a wave to the light and the light will be mu 0. It can be used as a set and can be used as a question and can be determined by the hand of the hand. The research work of the energy research can lead the light to the light, and the quality of the physical matter is decisive and decisive + the solution 3 is Nd. I think that the Han Ming package sends a copy for the domain to bring 0 U 3 1 * in the power of light Mingfa. It is also 0 outside the glass + rate 3 effect Nd. Dadeng expansion has a high performance. In addition to or, the big glass expands the optical performance line. The Ministry of Economic Affairs Central Standards Bureau staff consumer cooperatives print the rare earth and the glass. Boli + Master 3 is a Nd currency. The suction agent is prepared or close to. _ Attached suction JU 1 is for long working wave, there is a sub-addition moment, etc., the glass is phosphatized and the acid is phosphatized, so that the glass can be Glass is also divided into more glass S) Glass as sub-gl into y more * 1 r rt objects S glass gas glass HC conversion through the glass glass grade can be used as a glass of glass Received the basic data of the near Ming et al. + Root 3 r fear # P »The wave of Bobo S) 08 and +1 of the Tianen Institute 1 to 3 in 4 by-laws.捸 rn (CNS) A 4 rules. Grid (210 to 297 gong: Kang) 2103 ^ 8 A 6 B6 Printed by Suigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy V. Invention description (3) Wavelength 1.06u · band, wavelength 〇.88u · broadcasting area), moreover, Nd3 + and the added Tb3 + ions and the like promote the presence of «I, which can increase the Hd3 + luminescence rate in the 1.3W wavelength band. As a result, Nd3 + can emit light at the wavelength 1.3 «» finger region. It is possible to expand the light. Furthermore, as will be described later, a glass that can increase its efficiency, gain, etc. can be obtained. In this case, in addition to Pr3 +, Yb3 +, S · 3 + plasma can be used to absorb the luminescence with a wavelength of 1.06 // · clamp. Ho3 + ions can also be used for absorbing rain that absorbs light with a wavelength of 0.88 «. S — an accelerator used to promote the luminescence of the wavelength 1.3 «< • clamp domain, in addition to Tb3 +, Eu3 + plasma 0 can also be used. If Pr3 +, Yb3 +, S« +2, etc. are relative to Hd3 + »If the weight percentage is 50% ~ 150%, the effect as an absorbent can be improved. In addition, the optical successor of the present invention includes a core formed of the above-mentioned optical functional glass and a core having a lower refractive index, which surrounds the core. According to this kind of optical fiber, in addition to Hd3 +, the absorption surface and / or promotion are added to the core glass, so that the wavelength 1.31 «band light transmitted in the core glass can be enlarged or increased. The light enlarges the gain, and due to the light relay, the light can be efficiently enclosed in the core and the loss of the enclosed light is extremely low, so the Hd3 can be reversed with a low ® limit. In addition, the optical relay amplifier of the present invention is equipped with the above-mentioned optical fiber to excite the light (please read the precautions on the back before writing this page). Binding · Thread-V. Description of the invention (4) A 6 B6 Ministry of Economic Affairs Printed by the Central Bureau of Standards and Staff's Consumer Cooperatives, No. 3, with the inner fiber structure length 3 in the small light 1. U source fiber optic wave Nd can be long pole and fiber length M light domain self-vibration The wave is made. . The box, the light is brought in by the wave la, and it is sent inwards, and the latitude Η light is sent to the W. The fiber-excited inner light can be lightened by 3 / i from 3 / i. The fiber can be radiated by the fiber. 1. Excite the inner guide + u) fc, mine 0. The source has light to the light, and the long fiber is set to 3 light W. The light grows into the light, to the time of birth The wave-shaped light guide from Nd to (iv) for the wave domain light + the fiber path into the production to send 楢 to learn the entrance and exit W. When the stimulus is set back to 3 guides and the light guide is completed, the light guide is finished. Nd is said, the wave is even 8W into the learned time guide which is fnji prepared by the light.上 和 及 矿 0. The source is used to emit low-beam light from the source, and the light is induced by the light generation, and the light and the UC are the light flute attached to the light, and the light is taken by the mine. Shefa will squeeze it "and wait for the optical piece Ohara to swiftly. When the big excitement is, the U flare excitement is the light or the light, the light element is expanded. From the expansion, the area of the M fiber is set to emit a number of diameter pieces. The number of optical fiber domains is set. The light is installed in the bright band, and the multi-domain field element is installed. Xuefa U Mine's Big Chiseling Guide This study spurs the description of uDa Μ domain Mingzhiguang Ben 3 optical domain or domain U wave path bright light and puts 8 «M belt and installs it in 1. The belt is divided into 3W With the guide W said, then _0. + ^ // «this study, according to the " Ministry / iBIl. ^ Wu U under the light to set the root length 3> f3 and the light is more wave C root 8 a 3 long And M is loaded with Ndwl. The making of 0. of 1. Wave type (* ........................ ^ ..... ^ * · · ά (please first Read the precautions on the back and then fill out this page) Tai Kei ii uses Φ to be replaced by a group rn iCNS) Group 4 cell m 0 297 cm) 2. 24 103 ^ 8 A 6 B6 Ministry of Economic Affairs Central Standards Bureau Beigong Consumer Cooperative Printed 5. Description of the invention (5) The above phenomenon is invented. The inventors established a binary hypothesis and reviewed it. The following explanations of the hypothesis (instructions related to the first hypothesis) are introduced to the light added with Hd3 + The functional glass rose 0.8 «band luminescence stimulates Nd3 + as an active substance. As a result, the plaque can move from the energy level 4 F 3/2 to the energy 4 I 13/2 to produce 1.3 w «band radiation. Still other radiations can correspond to the migration from the energy level 4F 3/2 to the energy level 4 I 11/2 or 4 I 9/2, and produce a wavelength of 1.06 «b band or 0.88 / / m band of radiation, and the above-mentioned phenomenon related to N d ions as a comprehensive test. Most of the Hd3 + in the main glass is excited, and can produce a migration corresponding to the luminescence of the wavelength 1.3w »band, and for the band that is not expected to occur with the wavelength 0.88WB band, the wavelength 1.06« band The corresponding migration of luminescence may also occur at the same time. At this time, a part of the above-mentioned Nd 3 + can be emitted naturally or excitedly, and emit light with a wavelength of 1.3 «b band according to a certain probability. A part of the above Hd 3 + that has been sent out is released or released by nature. According to a certain probability, it does not generate light in the 1.3 «n band, but emits a wavelength of 0.88« or 1.06 «. Light. At this time, in the main glass, if there is a certain amount of absorber, that is, the absorber of the radiated light in the wavelength 0.8 8 w band or the wavelength 1.0 6 «* band, instead of the wavelength 1.3 a band The absorber of the radiated light in the field can absorb the 0.88 «® band or 1.06« · band light radiated by these absorbers. This absorption can suppress the radiation caused by the wavelength of 0.88 «β band or 1.06w β band (please read the precautions on the back and then fill out this page) installed. 2103Lb Αβ printed by Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A ο _ B6_ V. Description of invention (6) The phenomenon of distribution. For example, if it is considered to use an absorber that absorbs only radiation in the wavelength range of 1.06 / u · band, the absorber can at least suppress the emission of Nd 3 ^ in the wavelength range. Furthermore, if the absorption surface of light with a wavelength of 0.88 «in the dirty band is considered, at least the luminescence in the clamped region of 0.88 can be suppressed, thereby preventing the emission efficiency of the wavelength 1.3« in the wrong region from decreasing. If there is a sorrow above the emperor, please refer to circle 1, circle 2 and circle 3 to explain it. In the second country, your watch is added to the Nd3 + energy level plaque of the glass sample of the phosphate bar. As shown in the picture, the absorption and emission shift wavelength, and both spectrophotometers and spectrum analyzers are used to calculate the light intensity produced by these glasses. Due to the repetition of explanations, the main phenomenon of overtravel is explained. With the excitation light of about 0.8w ·, the son at the base level 4 I 9/2 is temporarily excited to the level of 4 F 5/2, and it is moved by the phonon and action To the level 4F 3/2, use this excitation (ρνι · Ρίη8>, if it is at the level 4 F 3/2, the levels 4 I 9/2, 4 I 11/2, 4 I 13/2 and 4 I 15 When an inverse distribution is formed between / 2, it will emit light with a wavelength of 0.88 «, 1.06«, a wavelength of 1.33 «, and a wavelength of 1.80tf, with a wavelength of 0.88«, a wavelength of 1.06 «, and a wavelength of 1.33 u · The luminous intensity ratio can be obtained from the dip ratio of the meal light peak when the excitation light is incident on the fiber, which is about 5: 9: 1. The luminous intensity at wavelength 1.80 It is weak and cannot be obtained. For those with extremely long luminescence rates in the 1.06w clamp domain or 0.88w β-domain, the first wake-up is used to suppress the luminescence caused by the luminescence (please read the back Please pay attention to this page and then fill out this page) Outfit · Order _ Line-Taizhao Chromium Only House This is used by the Central Youth League House (CNS) Ping 4 idiot m〇x297 public repair) Printed by the Employee Consumer Cooperative of the Central Bureau of Standards a6 _B6_ 5. Description of the invention (7) Out of the method. In the first nether (8), the excited first Nd3 + ion 11, for example, can be naturally emitted by the strobosphere and emit light with a wavelength of 1.3 W · Er domain, spanning a length of 0.8 W »band region or a wavelength of 1.06« · Clamp region. At this time, since the luminous probability in the wavelength 0.88 band and the wavelength 1.06 misalignment is very large, most of the 2Nd3 + ions 12 excited by the natural emission light will emit the wavelength 0.88 «band or wavelength 1.06 α 1 «Band of light. On the other hand, in the first (b), the same as the first plaque U), the first Nd3 + ion 11 emitted will emit wavelength 1.3 «clamp domain, wavelength 0.8 8« clamp domain or wavelength 1.06 Clamp the field of light. For example, if there is light in the 0.88WB1 band or 1.06ju band with a high luminous probability that can be used as the absorption cocoon 13 for absorption of cocoons, then the radiated light with a wavelength of 0.88 «wrong domain or 1.06« band can be absorbed by this It is absorbed by 黼 13, and it will not cause color depression to the second Nd3 + ion. The present invention is to use the absorption lam of the wavelength 1.06w band (or absorb W and the wavelength 0.8 8 «absorption band of the band (absorption M, at a wavelength of 1.06« Teng band absorption body, because of its luminous probability comparison It can effectively increase the probability of excitation and emission at the wavelength 1.3 «· band. On the other hand, when the absorption is at the wavelength 0.88α band, although it cannot be suppressed due to the light emitted at the wavelength 1.06« · band Distribute the appearance of the image, but at least it can suppress the excitation of the emission caused by the emitted light of the wavelength 0.88 «band, so the eaves ratio emitted at the wavelength 1.3« · clamp field can be increased. As the wavelength 1.06iu or 0.88 // Help the region absorb the -9-(Please read the precautions on the back before filling this page).

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2103LS A 6 B6 經濟部屮央標準局貝工消費合作社印製 五、發明説明(8 ) 條件,必須要能直接吸收波長約1.06«·或0.88«·之自 然放出光或檄發放出光,且又要不吸收波長約1.3«»之 放出光。若使用作為吸收鼸之活性離子,而將其輿Nd3 + 一起添加至玻璃畤,則不適合使用吸收帶較宽之過渡金 靨離子,而最好使用吸收箝較狹窄之稀土類離子。更者 必須在所需激發對象之能量準位上要存在多數的霣子, 又在所要邇移對象之能量準位的狀態密度要高,而該準 位之佔有率要低。 第3圓像表以該條件所灌擇之稀土類離子。又第3函 所示之稀土類離子之能量準位像位於結晶狀態。 又滿足上述條件之稀土類離子之第1後補者,由於波 長1.06«·之吸收檐率高,且可忽視1.3w·之吸收機率 等理由,可知最好是Pr3 + ,Yb3 +以及S·3 +等離子 。又Pr3 +之3 H4 1 G4之邇移則成為約9700c·—1的 能董,該值則對鼷至波長1.06w ^(9400(^-1)之放射光。 更者Yb3 +之2F 7/2— 2F 5/2邏移輿S·3 +之6H 7/24 6 F 11/2遷移亦分別成為約9600c·—1與約9500c譏1 的能最,而對醮至波長約1.06 «之放射光,此外藉自 然放出程度之吸收效果,並不能在Pr3 +等之稀土類離 子本身形成反轉分布。 以上之假設是否適切並不清楚。但是根據本發明者之 實驗檢討,可在將Hd3 +當作活性物質而添加之玻璃中 若添加Pr3 + ,或是將該Pr3 +相對於Nd3 + ,而添加 -10- (請先閲讀背面之注意事項再塡寫本頁) 裝- 訂_ 線- A 6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(9) 50%至150%之範圃的Pr3 + ,則可藉Pr3 +吸收Hd3 + 之在波長1.06«·帶域之發光,而得到可擴大波長1.3WB 帶域之光強度或是提高其擴大效率的玻璃。又藉在将 Nd3 +當作活性物霣而添加之玻璃中添加S·3 +或是將 S·3 +相對於Nd3 + ,而添加50%至150%之範園的S·3 + ,亦可得到同樣的玻璃,更者藉在將Hd3 +當作活性物 霣而添加之玻璃中添加Yb3 + ,或是將該Yb3 +相對於 Hd3 + ,而添加50%以上的Yb3 + ,而使其在未破壤玻 璃形成能力之範園内進行變化,亦可得到同樣的玻璃。 又《足上述條件之稀土類離子之第2候補者,由於波 長0.88««之吸收機率高,且可忽視波長1.3w·之吸收 機率等理由,最好是Ho3 +。而Ho3 +之5 18分5 15 遷移大約為11000c·-1,而該值對*至波長0.88wb(約 1 1 400c·-1)。 以上之梅設是否適切則不淸楚。但是根據本發明者之 實驗檢討,藉在玻璃中共同添加Nd 3 + , H0 3 + ,可藉 Ho3 +來吸收Nd3 +之在波長0,88«·帶域之發光,而 得到可擴大波長1.3«·箱域之光強度或是提离其擴大率 之玻璃。 (有两第2假設之說明) 被導入至添加有Nd3 +之光功能性玻瓖之0.8« 帶域 的瀲發光則檄發作為活性物霣之Nd3 +。其結果可産生 與4 F 3/2~> 4 I 13/2*移對*之1.3w·帶域之輜射 -11 - (請先閲讀背面之注意事項再填寫本頁) 裝. 訂_ 線- 太蚯?fcK泞iA ffl Φ团H 甲4規格(2〗0父297公;«·)2103LS A 6 B6 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of invention (8) The conditions must be able to directly absorb light with a wavelength of about 1.06 «· or 0.88« · to naturally emit light or emit light, and Otherwise, the emitted light with a wavelength of about 1.3 «» is not absorbed. If you use active ions that absorb mule and add Nd3 + together to the glass, it is not suitable to use transition metal ions with a wide absorption band. Rare earth ions with narrow absorption clamps are best. Furthermore, there must be a large number of enemies on the energy level of the desired excitation object, and the state density of the energy level of the object to be moved must be high, and the occupancy rate of the level should be low. The third round image shows the rare earth ions selected under this condition. Moreover, the energy level image of the rare earth ions shown in the third function is in a crystalline state. The first supplement of rare earth ions that meet the above conditions, because of the high absorption eaves ratio of wavelength 1.06 «·, and the negligible absorption probability of 1.3w ·, it can be known that Pr3 +, Yb3 + and S · 3+ plasma. And the shift of Pr3 +3 H4 1 G4 becomes the energy director of about 9700c · -1, and this value is to the emission light of wavelength 1.06w ^ (9400 (^-1). Furthermore, Yb3 + 2F 7 / 2— 2F 5/2 Logic shifting S · 3 + of 6H 7/24 6 F 11/2 migration also becomes the energy of about 9600c · -1 and about 9500c 讥 1 respectively, and the wavelength is about 1.06 « In addition, due to the absorption effect of the natural emission level, it cannot form a reverse distribution in the rare earth ions such as Pr3 +. Whether the above assumptions are appropriate is not clear. However, according to the experimental review of the inventors, it can be If Pr3 + is added to the glass added as an active substance, or Pr3 + is added to Nd3 +, then add -10- (please read the precautions on the back before writing this page). Line-A 6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention description (9) 50% to 150% of Pr3 + in the nursery, you can borrow Pr3 + to absorb Hd3 + at the wavelength 1.06 Luminescence, and to obtain glass that can expand the light intensity of the 1.3WB band or increase its expansion efficiency. It is also added to the glass that uses Nd3 + as an active substance. S · 3 + or S · 3 + relative to Nd3 +, and adding 50% to 150% of S · 3 + of Fanyuan, you can also get the same glass, and even use Hd3 + as an active substance Add Yb3 + to the added glass, or add more than 50% of Yb3 + to Hd3 +, and change it within the range of unbreakable glass forming ability. The second candidate of rare earth ions that meet the above conditions, because of the high absorption probability of wavelength 0.88 «, and the absorption probability of wavelength 1.3w · can be ignored, it is best to be Ho3 +. Ho3 + No. 5 18 points 5 15 The migration is about 11000c · -1, and this value is * to the wavelength 0.88wb (about 1 1 400c · -1). Whether the above settings are appropriate is not clear. But according to the inventors Experimental review, by adding Nd 3 +, H0 3 + to the glass, Ho3 + can be used to absorb the luminescence of Nd3 + at the wavelength of 0,88 «· band, and the light can be expanded at 1.3« · box. Strength or increase the rate of expansion of the glass. (There are two explanations for the second hypothesis) The light that is introduced into the functional glass bulb with Nd3 + added is 0.8 Nd3 + as an active substance. The result can produce 1.3W with 4 F 3/2 ~> 4 I 13/2 * shift pair *. 辎 射 -11-(Please read the note on the back first Please fill in this page again for items) 装. Order _ line-too earthworm? fcK 泞 iA ffl Φ 团团 A 4 specifications (2〗 0 father 297; «·)

2103-S A 6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(10) 。又其他輻射,則為與自能量準位4 F 3/ 2至能蛋準位 4 I 11/2或4 I 9/2之邏移或對應之波長1.06«·箱域 或波長0.88 w 帶域之輻射。 将有鼷Hd3 +離子之上述現象综合性地加以考盧。在 主玻璃中之Hd3 +多數,你》0.8«·带域之激發光被激 發,而産生可輿波長1.06 «域,波長0.88«·得域以及波長1.3 «帶域之發光相對應之*移狀應,被瀲發之上述Nd3 + 之一部分,像藉自然放出,而依一定的機率放射波長 1.3« 1«帶域的光。又被瀲發之上述Nd 3 +的一部分,則 藉自然放出,以較波長帶域放射光為离的機率放 射波長1.06«»箝域或0.88« b帶域的光,此時用以促進 Nd3 +之在波長1.3««檐域放射光者,即是僅促進放射 波長1.3«·帶域之光之發光促進物,亦即若在主玻璃中 存在某程度量之促進_時,則該些促進》僅能促進Nd 3 + 放出在1.3«b箝域的光,而可提升波長1.06«·薄域之 瀲發放出的效率。更者由於在波長1.06«帶域以及 0.88«·帶域之發光櫬率相對地減少,因此因1.06α·帶 域之光而導出妨礙波長1.3« 帶域光被激發放出之可能 性即可被減少。 以上之假設讅參照第2鼸〜第4 _具钃地加以説明。 如在第2麵所說明般,_波長0.80«·之擻發光之存 在,有可以産生以0.88w·, 1.06«·, 1.33«·為尖峰 (Peak)之發光。該些發光的強度,若没有外因,而僅就 -12- (請先閱讀背面之注意事項再塡寫本頁) 裝· •,τ. 太/ϊίίί 用 Φ 团 Η 宅棵m(CNS)¥4頫格(210x297公帑) 經濟部中央標準局貝工消費合作社印製 103Lb 五、發明説明(u) 自然放出所産生之發光強度來考慮時,分別為5:9:1。 亦即在波長1.3/u 播域之發光機率若與在波長1.06« 帶域以及0.88u 箝域之發光檐率比較乃相當低。 第4 _你表提离在波長1.3«·错域之發光機率的方法 ,而表示有防止因在波長1.06« 帶域以及0.88« 帶域 之發光導致妨礙波長1.3 </薄域光被激發放出,而效率 降低之方法。 藉波長0.8W·帶域光被檄發之Hd3 + ,可例如藉自然放 出,而放射波長0.8«·箝域,波長1.06/i·帮域以及波 長1.3«·帶域的光。在此用以作為儀促進在波長1.3/iB 幣光之適當的促進劑,若是在Nd3 +附近存在具有位在 基底準位(約4000c·—1 )上方之激發準位之活性離子畤, 則可將位在Nd 3 +之能量準位4 I 13/ 2之呈激發狀態 的霣子有效地遷移至基底準位4 I 9/2。亦即藉來自位 在Nd 3 +之能量準位4 I 13/ 2而被瀲發之電子的能* 傳遞,除了可使位在上述活性裡子之基底準位之大多數 電子被瀲發至其檄發準位久,位於Nd3 +之準位4 I 13/2之多數霣子邸會邐移至其基底準位4 I 9/2。換 言之,位於Hd3 +之準位4 I 13/2而被瀲發之«子, 不僅經由輻射遇程,聲子(Phonon)放出遍程而被缓和, 藉其輿附近之活性離子之間的能量傳遞亦可有效地被緩 和。其結果,多數Nd3 + ,在能量準位4F 3/2輿準位 4 I 13/2之間的反轉分佈之程度邸會被提离,而可促 -13- A 6 B6 (請先閱讀背面之注意事項再填寫本頁) 裝· 線· 2103£8 A 6 B6 經濟部屮央標準局Μ工消費合作社印製 五、發明説明(工2) 進放射波長1.3tfB帮域之光。更者明著波長1.3w·帶域 光之放射機率所增大,波長1.06«·帶域光等之放射機 率邸相對地減少。在含有較狀態之Nd 3 +之玻璃中若入 射1.3««箝域之倍號光時,則可滅少因1.06«·帶域以 及0.88w 帶域之發光所導致之在波長13.« «错域之激 發放出被妨璇之可能性,可有效地進行發光。_此則不 管因ESA而導致吸收波長1.3/u 箝域之情況是否存在, 除了可發光及擴大在波長1.3χχ«帶域之光強度外,亦可 增大其光擴大的增益(gain)。 作為上述促進劑之條件,不僅要具備位在基底淮位( 約4000c·-1)上方之能量_位外,亦必須要不吸收波長 約1.3««薄域之放出光以及不吸收激發光。該促進_|, 在将活性離子輿Nd3 + —起添加至主玻瓌時,不適合使 用吸收帶宽的«渡金钃,而#望使用吸收薄窄之稀土類 元素。更者亦期望自該活性醵子之基底準位約4000c·-1 上方之能量_位的狀態密度要高。 如第3鼷所示,《足上述條件之稀土類元素的候補者 最好是Tb3 +或是Eu3 + 。而Tb3 +之7Fe分7F4 遷移以及Eu 3 +之7 F4 7 F 5遷移則分別波數約3200c· 一1 以及3800c·-1。該些值大約輿準位4 I 11/2以及準位 4 I 9/2之能Λ差之波數4000c·-1相對應。 上述之假設是否適切雖不清楚。但是根據本發明人之 實驗檢討,在玻璃中,除了 Nd3 +外,若添加Tb3 +或 -1 4 - (請先閱讀背面之注意事項再填寫本頁) 裝· 訂_ 線· 太饥银尺疳这用申因因宅棵miCNS)甲4規格(210x297公修) 2103L8 A 6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明(^3) Eu3 +或該兩者,藉此可藉Tb3 + 或Eu3 +來促進Nd3 + 在波長1.3//·帶域之發光,而得到可鑛大在波長1.3«· 帶域之光強度或是提高其擴大效率之玻璃。 (光功能性玻璃之應用例) 上述光功能性玻璃偽用以作為光傅送路徑用的材料, 雄然可形成平面波導路徑,然最好是裂作一光纖,其備 有包括:由上述光功能性玻璃所形成之核心以及包園該 核心而具有較該核心為低之折射率之殼黼,藉此可得到 長距離之光傅送路徑。 上述光繼具體地説像如下而製作,首先将添加有Nd3 + 之光功能性玻璃酋作核心之預型儺(prefor·〉藉旋轉管 法而準備。其次將所準備之預型讎設置在第5圓所示之 抽絲裝置而抽成光纖。而如第5圃所示,預型讎21被固 定在輸送裝置22而徐徐地下降。此時預型體21會_加熱 器23被加熱而閬始軟化而抽絲。被抽絲之光纖20則經由 鉸盤(capStan)24被捲取在捲取輪鼓25。第6 _像將由 此獲得之光纖20擴大表示·。光纖20乃具備有:除了 Nd3 + 外,亦添加有 Pr3 + ,Yb3 + ,S鼸3 + ,Tb3 + . Eu 3 + , Ho 3 +等之核心20a以及具有較核心20a相對為 低之折射率,而未添加有Hd 3 +以及Pr 3 +等其他稀土 類離子等之殼讎(cl ad)靥20b。 根據該將上述光功能性玻璃酋作核心之光雄,可應用 至光繼雷射,光纖鑛大器以及光纖檢澜器等,亦邸由於 -15- (請先閲讀背面之注意事項再塡寫本頁) 裝- 訂_ 線- 太蚯银尺/ii«用中困@3«:捃進規格(210乂297公货) 2103L3 A 6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(14) 在核心玻Λ (core glass)中,除了 Nd3 +外,亦添加 Pr3 +等其他之稀土類離子,因此即使是波長1.3WB帶 域,不僅可獲得光擴大增益,亦可減少因波長l.〇6w·帶 域之發光所導致之損失。更者藉光纖化,可將光有效率 地封閉於核心,由於光損失極低,因此可以低》限即可 形成反轉分布,故可應用至高增益之光擴大裝置。 (2)光纖擴大器 像上述光纖2 0之一個應用例,為一可使用在1 . 3 w 帶 域之光鑛擴大器。 如第7_所示,光纖擴大器像具備:添加有稀土類之 光纖30,用於激發之笛射光源32以及光學裝置33,38a, 38b,39a,39b。光纖30乃成為1.3« 帶域之雷射光之光 傳送路徑。又雷射光源32你用以産生波長0.8« b帶域之 激發光,更者光學裝置33,38a,38b,39a,39b,則将檄發 光自雷射光源32人射至光纖30内。因此來自雷射光源32 之檄發光,邸經由光纖39a被導入至光纖縞合器33,而 輿自倍號光源31經由光纖38a被導人至光纖«合器33之 信號光相結合。被結合之佶號光以及瀲發光,即經由光 繼38b被導人至光雄30内。 光纖供合器30可藉將例如2條光繼38,39溶器延伸而形 成。此時自光纖《合器33延伸之1條光纖39b的終端,即 被浸漬在選配油(《etching οί丨)37内。藉此可防止自光 _39b至光繼供合器33之回射光。 (請先閲讀背面之注意事項再填寫本頁) 裝. 訂- 線- -16- A 6 Β6 經濟部中央標準局员工消費合作社印製 五、發明説明(15) 此外在光纖30之输出侧設置光譜分析器35,在兩者之^ 間設置濾光器36。該濾光器36則在自光纖30输出之光中 去除檄發光。其結果使得光譜分析器35僅測定來自光纖 30而输出之倍號光,更者亦可拥(Λ光擴大增益。 根據備有上述光纖,雷射光源以及光學裝置之波長1.3 w·帶域之光纖擴大器,可藉根據光學裝置而被導入至 光繼内之波長〇.8w·之雷射光而瀲發Nd3 + ,該被激發 之Nd3 +之多數,則同時藉被導入至光纖内之波長1.3 帶域之倍號光所檄發而産生放射光,因此可擴大 波長1.3«·糟域之光強度。 (3)光纖雷射 偽上述光《I 2 0之其他的應用例,為一波畏1 . 3 «!«帶域 之光纖雷射。 如第8 _所示,光繼雷射乃具備:添加有稀土類元素 之光纖30,雷射光源32以及光學裝置38。而使用一可産 生波長0.8« β帶域之激發光的雷射二極讎作為雷射光源 32。又光學裝置38則使用可將檄發光自雷射光源32入射 至光编30内之透鏡。又將光纖之輸出端加工成適當的鏡 面,而藉該输出端與雷射二極鱺之端面形成共振器構造 。此時亦可将用以入射檄發光之輸出入端加工成適當的鏡 面,而自該输出入端形成共振器構造。更者共振器構造 亦可為使用介質鏞(dielectric ·ϊ!γγογ·)之通常型式者。 在上述光纖雷射中,來自笛射光源32之波長0.8«Β帶 -17- (請先閲讀背面之注意事項再填寫本頁) 裝·2103-S A 6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (10). For other radiation, it is the logical shift from the energy level 4 F 3/2 to the energy level 4 I 11/2 or 4 I 9/2 or the corresponding wavelength 1.06 «· box domain or wavelength 0.88 w band domain Of radiation. The above phenomenon with the Hd3 + ion is comprehensively taken into consideration. In the Hd3 + majority in the main glass, the excitation light of your "0.8" band is excited, and the corresponding shift of the luminescence of the wavelength 1.06 «domain, wavelength 0.88« and the wavelength 1.3 «band domain is generated. As a result, a part of the above-mentioned Nd3 + that is sent off is like a natural emission, and emits light with a wavelength of 1.3 «1« band according to a certain probability. A part of the above-mentioned Nd 3 + that has been sent out is naturally emitted to emit light with a wavelength of 1.06 «» clamped region or 0.88 «b-band region with the emission light of a wavelength band more distant, which is used to promote Nd3 + The one that emits light at the wavelength 1.3 «« eave area, that is, a luminescence promoter that only promotes the emission of light at the wavelength 1.3 «band, that is, if there is a certain amount of promotion in the main glass, then these "Promotion" can only promote Nd 3 + to emit light in the 1.3 «b clamp domain, and can increase the efficiency of the wavelength 1.06« · thin domain. Furthermore, since the luminous emission rate at the wavelength 1.06 «band and 0.88« · band is relatively reduced, the possibility that the wavelength 1.3 «band light is excited and released due to the light of 1.06α · band can be derived cut back. The above hypothesis is explained with reference to the 2nd to 4th _Yang. As explained on the second surface, the existence of _wavelength 0.80 «· 擞 luminescence, there may be 0.88w ·, 1.06« ·, 1.33 «· as peak (Peak) luminescence. The intensity of these luminescences, if there is no external cause, only -12- (please read the precautions on the back and then write this page) Pretend · •, τ. 太 / ϊίίί Used Φ 团 Η 宅 树 m (CNS) ¥ 4 Folding grid (210x297 public money) 103Lb printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (u) When considering the luminous intensity produced by natural emission, it is 5: 9: 1. That is to say, the probability of luminescence in the 1.3 / u broadcast domain at the wavelength is very low compared to the luminous eaves ratio in the 1.06 «band and 0.88u clamp domain. Section 4 _ You list the method of removing the luminous probability at the wavelength 1.3 «· wrong domain, and indicate that there is a prevention that the wavelength 1.3 < / thin domain light is excited due to the luminescence at the wavelength 1.06« band and 0.88 «band Release, and the method of reducing efficiency. The Hd3 + emitted by the wavelength 0.8W · band light can be emitted by nature, for example, and emits light with a wavelength of 0.8 «· clamping field, a wavelength of 1.06 / i · band and a wavelength of 1.3« · band. It is used here as a suitable accelerator to promote the light at a wavelength of 1.3 / iB. If there is an active ion near the Nd3 + with an excitation level above the base level (about 4000c · -1), then The energetic state of the Nd 3 + energy level 4 I 13/2 in the excited state can be effectively transferred to the base level 4 I 9/2. That is, the energy * of the electrons sent by the energy level 4 I 13/2 at Nd 3 + is transferred, except that most of the electrons at the base level of the above active neutrons can be sent to It has a long-term release level, and most of the encyclopedias at Nd3 + level 4 I 13/2 will move to its base level 4 I 9/2. In other words, the son at the level of 4 I 13/2 at Hd3 +, which is lost, is not only relieved by the radiation, but the phonon (Phonon) is released all the way through the energy, and the energy between the active ions nearby Transmission can also be effectively mitigated. As a result, most Nd3 +, the degree of reverse distribution between the energy level 4F 3/2 and the level 4 I 13/2 will be lifted away, which can promote -13- A 6 B6 (please read first Note on the back and then fill out this page) Installation · Line · 2103 £ 8 A 6 B6 Printed by the Ministry of Economic Affairs, Bureau of Standards, M Industry and Consumer Cooperatives. Fifth, the invention description (Work 2) Enter the light with a wavelength of 1.3tfB. Furthermore, it is apparent that the emission probability of wavelength 1.3w · band light increases, and the emission probability of wavelength 1.06 «· band light etc. decreases relatively. If 1.3 «« clamp zone multiples of light are incident in a glass containing Nd 3 + in a relatively state, it can be eliminated at a wavelength of 13. «« caused by the luminescence of the 1.06 «band and 0.88w band. The excitation of the wrong domain releases the possibility of being disturbed, which can effectively emit light. _This means that regardless of the presence of the absorption band of 1.3 / u in the absorption band due to ESA, in addition to emitting light and expanding the light intensity in the band of 1.3χχ «, it can also increase the gain of its light expansion. As a condition of the above accelerator, not only must it have the energy_position above the base Huai position (about 4000c · -1), but also must not absorb the light emitted at a wavelength of about 1.3 «« thin domain and absorb the excitation light. This promotion _ |, when adding active ions and Nd3 + together to the main glass, is not suitable for the absorption bandwidth of «Wu Jinding, while # hope to use thin absorption rare earth elements. Furthermore, it is also expected that the state density of energy_bits above the base level of the active mound is about 4000c · -1. As shown in Section 3, "The candidates for rare earth elements that satisfy the above conditions are preferably Tb3 + or Eu3 +. The 7F4 migration of Tb3 + 7Fe and the migration of 7 F4 7 F 5 of Eu 3 + are about 3200c · -1 and 3800c · -1 respectively. These values correspond to the wave number 4000c · -1 of the energy difference of level 4 I 11/2 and level 4 I 9/2. Whether the above assumptions are appropriate is unclear. However, according to the inventor's experimental review, in addition to Nd3 +, if Tb3 + or -1 4-are added to the glass (please read the precautions on the back before filling in this page), install, order, thread, too hungry silver ruler This is due to the application of Shine-in MiCNS) A4 specifications (210x297 public repair) 2103L8 A 6 B6 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Invention description (^ 3) Eu3 + or both, by which Tb3 + or Eu3 + can be used to promote the luminescence of Nd3 + in the wavelength 1.3 // · band, and the glass that can be mined in the wavelength 1.3 «· band or to increase its expansion efficiency can be obtained. (Application example of optical functional glass) The optical functional glass described above is used as a material for optical transmission path, which can form a planar waveguide path, but it is best to split it into an optical fiber, which includes: The core formed by the optical functional glass and the shell sheath that surrounds the core and has a lower refractive index than the core can obtain a long-distance optical transmission path. The above-mentioned light is produced specifically as follows. First, the pre-formed Nuo (prefor ·> of light functional glass chief with Nd3 + added as the core is prepared by the rotating tube method. Secondly, the prepared pre-formed clam is set at The drawing device shown in the fifth circle is drawn into an optical fiber. As shown in the fifth garden, the preform 21 is fixed to the conveying device 22 and slowly descends. At this time, the preform 21 will be heated by the heater 23 The fiber starts to soften and is drawn. The drawn fiber 20 is taken up on the take-up drum 25 via a cap 24 (capStan) 24. The sixth image shows the fiber 20 obtained by expanding it. The fiber 20 is equipped with Yes: In addition to Nd3 +, Pr3 +, Yb3 +, Slu 3 +, Tb3 +. Eu 3 +, Ho 3 + and other cores 20a and have a relatively lower refractive index than the core 20a are added. There are other rare earth ions such as Hd 3 + and Pr 3 +, etc. Cl ad Tat 20b. According to this, the above optical functional glass chief is used as the core of the optical hero, which can be applied to optical relays, optical fiber mines As well as fiber optic detectors, etc., also due to -15- (please read the precautions on the back before writing this page) Install-Order _ Line-Taizhao Silver ruler / ii «Used in trouble @ 3«: Driven specifications (210 to 297 public goods) 2103L3 A 6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention description (14) In core glass Λ (core glass ), In addition to Nd3 +, other rare earth ions such as Pr3 + are also added, so even in the 1.3 WB band, not only can the optical gain gain be obtained, but also the luminescence caused by the wavelength 1.06w · band can be reduced. The resulting loss. Furthermore, by fiberization, the light can be efficiently enclosed in the core. Since the light loss is extremely low, the reverse distribution can be formed at a low limit, so it can be applied to high-gain light expansion devices. (2 ) An optical fiber amplifier is an application example of the above-mentioned optical fiber 20, which is a light mine amplifier that can be used in the 1.3W band. As shown in section 7_, the optical fiber amplifier is equipped with: an optical fiber with rare earth added 30. Flute light source 32 for excitation and optical devices 33, 38a, 38b, 39a, 39b. Fiber 30 is a light transmission path of 1.3 «band laser light. Laser light source 32 is used to generate a wavelength of 0.8 «B band excitation light, and optical devices 33, 38a, 38b, 39a, 39b will be sent out The person from the laser light source 32 shoots into the optical fiber 30. Therefore, the light from the laser light source 32 emits light, and is introduced into the optical fiber coupler 33 through the optical fiber 39a, and the multiplier light source 31 is guided into the optical fiber through the optical fiber 38a «The signal light of the combiner 33 is combined. The combined signal light and light emission are led to the light male 30 through the light relay 38b. The optical fiber supply combiner 30 can dissolve, for example, two light relays 38, 39器 Extended to form. At this time, the end of one optical fiber 39b extending from the optical fiber "combiner 33" is immersed in the optional oil 37. This prevents the retro-reflected light from the light_39b to the optical relay 33. (Please read the precautions on the back before filling in this page) Packing. Order-Line--16- A 6 Β6 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (15) Also set on the output side of the optical fiber 30 The spectrum analyzer 35 is provided with a filter 36 between the two. The filter 36 removes the luminescence from the light output from the optical fiber 30. As a result, the spectrum analyzer 35 only measures the doubled light output from the optical fiber 30, and it can also have (Λ light to increase the gain. According to the above-mentioned optical fiber, laser light source and optical device, the wavelength is 1.3 w · band The optical fiber amplifier can transmit Nd3 + by the laser light with a wavelength of 0.8 W · introduced into the optical relay according to the optical device. The majority of the excited Nd3 + is also introduced into the optical fiber at the same time. 1.3 The doubled light in the band produces radiated light, so it can expand the light intensity of the wavelength 1.3 «· bad domain. (3) Other application examples of the optical fiber laser pseudo the above light" I 2 0 are a wave Fear 1. 3 «!« Band optical fiber laser. As shown in section 8_, the optical relay laser is equipped with: an optical fiber 30 added with rare earth elements, a laser light source 32 and an optical device 38. A laser diode that generates excitation light with a wavelength of 0.8 «β band is used as the laser light source 32. The optical device 38 uses a lens that can emit light from the laser light source 32 into the optical fiber 30. The output end is processed into an appropriate mirror surface, and the output end and the end face of the laser diode The resonator structure is formed. At this time, the input and output ends used for incident light emission can be processed into an appropriate mirror surface, and the resonator structure is formed from the input and output ends. Furthermore, the resonator structure can also use a dielectric yin (dielectric · ϊ! γγογ ·) of the usual type. In the above-mentioned fiber laser, the wavelength from the flute light source 32 is 0.8 «B band-17- (please read the precautions on the back before filling this page)

1Λ -1 /f- r n y補充81. 2. M A6 B6 明 (16) 經濟部中央標準局員工消費合作社印製 域的撖起光,傺藉光學裝置38被導入至光纖30内。而光 纖30内之Nd3 +即被激發成一定之狀態,而可發出波長 1.3//»之光線其結果當撖起光之輸出超越所定值時,則 會在波長1.3// 帶域産生雷射振盪。 (4)波導路徑元件擴大器 第9圖傜表應用至波導路徑元件擴大器之例子。在基 板120上乃形成呈雙股狀分技之平面波導路徑130a,130b ,130c。在平面波導路徑130a除了 Hd3 +以外,亦添加 有 Pr3 + ,Yb3 + .Sm3 + ,Tb3 + ,Ειι3 + ,Ηο3 + 等之 活性物質。而在平面波導路徑130a之另一端,則形成有 由光柵(grating)所構成之濾光器136。在平面波導路徑 130b入射有波長1.3«m帶域之倍號光。又在平面波導路 徑130c則入射有波長0.8« m激-發光。此外雷射光源則使 用與第8圖所示相同者。 以下就第9圖之光纖擴大器100之動作簡單地説明。波 長1.3« β帶域之倍號光經由平面波導路徑130b入射至平 面波導路徑130a内。而來自LD等之檄發光源之波長0.8 «β之檄發光,亦經由平面波導路徑130c入射至平面波 導路徑130a内。而被瀲發之Nd 3 +則為倍號光所檄發, 而産生可與4 F 3/24 4 I 13/2遷移成對應之波長1.3 «的放射光:當檄發光超越一定之強度時,則信號光 會被擴大。 (具體的實施例) (請先閱讀背面之注意事項再填寫本頁) 裝· 太疳试用ΨΗΗ«:棵雄(CNS)甲4規格(210x297公:»·) 103^8 A 6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明孕7) 以下本發明者來説明具體的實施例。 (1) 一起添加有Pr3 +之情形。 首先準備《820,六12 03,卩2 05酋作主玻璃材料,則 将其分別之組成如調成15Na2 0-15A12 03 -70PZ 05 (boIJ!)般地加以調合。在此則添加一定量之稀土類元素 Nd之氧化物Nd2 03與Pr2〇3,而使其溶融在白金坩場 (crucible)中,Nd 2 0 3的添加*,乃使其重量濃度相 對於主玻璃成為500ρρ·般地加以調整。又Pr2〇3添加 量,則如使Pr 3 +相對於主玻璃之重量濃度成為0,20 0, 500,700,1000般地加以調整。因此Pr3 +相對於Hd3 + 之濃度則成為0,40,100,140,200%。溶融的材料,則在 完成充分混合之後進行急冷處理使其玻璃化。 為了要評價該玻璃之光擴大特性,乃依下製作光纒。 首先將上述組成之玻璃成形為棒狀,而成為核心用之玻 璁棒。其次則溶融形成組成與該玻璃棒大約相同,而具 有較低折射率之玻璩而作為毅釅管(clad pipe)。該殼 體管之玻璃之組成為2P6 〇-15Na2 0-15Α12 〇3 -68PZ 05 (boIX),而未添加Nd3 +以及Pr2 03。該些心棒與殼 腰管則形成為預型讎,而藉第5圃之装置加以抽絲。其 結果可得到核心直徑8« »,而外徑為125w 之SM光鐵。 該SM光纖為了便於澜董,則切成10·長度的光纖試料。 該光纖試料之特性的評價傜藉第7圓之光繼擴大器而 進行。其結果表示在第10圏。 -19- (請先閲讀背面之注意事項再填寫本頁) 裝. ,tT_ 線· 8 .1 3 ο 1 C ‘1Λ -1 / f- r n y supplement 81. 2. M A6 B6 Ming (16) The light from the printed area of the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is introduced into the optical fiber 30 through the optical device 38. The Nd3 + in the optical fiber 30 is excited to a certain state, and can emit light with a wavelength of 1.3 // ». As a result, when the output of the lifted light exceeds the specified value, a laser will be generated in the wavelength 1.3 // band oscillation. (4) Waveguide path element amplifier Figure 9 shows an example of application of the waveguide path element amplifier. On the substrate 120, planar waveguide paths 130a, 130b, and 130c in the form of double strands are formed. In addition to Hd3 +, active materials such as Pr3 +, Yb3 + .Sm3 +, Tb3 +, Ειι3 +, Hο3 +, etc. are added to the planar waveguide path 130a. At the other end of the planar waveguide path 130a, a filter 136 composed of a grating is formed. In the planar waveguide path 130b, light of a multiple of the wavelength 1.3 m band is incident. In the planar waveguide path 130c, the laser light with a wavelength of 0.8 m is incident. In addition, the same laser light source as shown in Figure 8 is used. The operation of the optical fiber amplifier 100 of FIG. 9 will be briefly described below. The light with a multiple of 1.3 «β band is incident on the planar waveguide path 130a via the planar waveguide path 130b. Also, the luminescence of the wavelength 0.8 «β from the luminescence source of LD and the like also enters the plane waveguide path 130a through the plane waveguide path 130c. The Nd 3 + that has been sent out is emitted by the double-beam light, and generates radiation that can migrate to the corresponding wavelength 1.3 «with 4 F 3/24 4 I 13/2: when the luminescence exceeds a certain intensity , The signal light will be expanded. (Specific example) (Please read the precautions on the back first and then fill out this page) Install · Taiji trial ΨΗΗ «: Kexiong (CNS) A 4 specifications (210x297 g:» ·) 103 ^ 8 A 6 B6 Ministry of Economic Affairs Printed by Beigong Consumer Cooperative of Central Bureau of Standards 5. Description of invention 7) The following inventors will describe specific embodiments. (1) When Pr3 + is added together. First prepare "820, six 12 03, and 2 05 chief as the main glass material, and then adjust their composition as 15Na2 0-15A12 03 -70PZ 05 (boIJ!). Here, a certain amount of rare earth elements Nd oxides Nd203 and Pr203 are added to melt them in a platinum crucible. The addition of Nd203 is the weight concentration relative to the main The glass is adjusted to 500ρρ. The addition amount of Pr203 is adjusted so that the weight concentration of Pr3 + with respect to the main glass becomes 0,200,500,700,1000. Therefore, the concentration of Pr3 + relative to Hd3 + becomes 0,40,100,140,200%. The melted material is quenched and vitrified after it has been thoroughly mixed. In order to evaluate the light-expanding characteristics of the glass, the light source was fabricated as follows. First, the glass with the above composition is formed into a rod shape to become a core glass rod. Secondly, the melt-forming composition is about the same as that of the glass rod, and the glass with a lower refractive index is used as a clad pipe. The glass composition of the shell tube is 2P6 〇-15Na2 0-15A12 〇3 -68PZ 05 (boIX) without adding Nd3 + and Pr203. The mandrels and shell lumbar tube are formed into pre-shaped jaws, and the silk is drawn by means of the fifth garden. As a result, SM iron with a core diameter of 8 «and an outer diameter of 125w can be obtained. In order to facilitate Lan Dong, the SM fiber is cut into 10 · length fiber samples. The evaluation of the characteristics of the optical fiber sample was carried out by using the optical amplifier of the seventh circle. The result is shown on the 10th ring. -19- (Please read the precautions on the back before filling in this page) Pack., TT_ line · 8 .1 3 ο 1 C ‘

66 AB 經濟部中央標準局貝工消t合作社印製 五、發明説明(is) 第1 0 所示之增益葆指在波長1 . 3 1 0 « Β的情形,而雷 射光源32使用Ti -藍II石雷射,激發波長為0.78ju·,檄 發光強度為100·«。輸人倍號之強度為一 30dB·,尖峰波 長為 1.310m η。 如圈所示,一起添加至核心玻璃中之Pr3 +的濃度, 在相對於Nd 3 +為50%〜150%的範園内可得到一定值 以上的增益。而P r 3 +之濃度在5 0 %以下時則增益較小 ,此乃是因為作為活性離子之Pr3 +的濃度低,而在 Hd3 +之附近存在Pr3 +之櫬率變低始然。又可充分吸 收Nd3 +所放射之1.06w·帶域之光的Pr3 +未存在。 此外,P r 3 +濃度在1 5 0 %以上時刖增益較小。此乃是 因為作為活性離子之Pr3 +的濃度太高,而藉Pr3 +在 1.47«»附近之吸收之捸部,可吸收波長1.3«·的倍號 光。 (2>—起添加有S·3 +或Yb3 +之情形 首先準備Na2 0,A12 03以及P2 Op當作主玻璃材料, 則将其分別之組成如調成15Na2 0-15Al 2 03 -70P2 05 (»〇1Χ)般地加以_合。在此則添加一定量之稀土類元素 Nd之氣化物Ndz 03輿Sn2 〇3或Yb3 03而使其溶融在 白金坩場中,Nd203的添加量,乃使其重量濃度相對 於主玻璃成為500ρρ·般地加以譎整。又Sn 2 0 3或Yb203 之添加量,則如使S·3 +或Yb 3 +相對於主玻璃之重量 濃度成為 0,200,300,400,500,600,700,1000般地加以讕 -20- (請先閲讀背面之注意事項再填寫本頁) 裝· 訂- 線- 經濟部中央標準局員工消費合作社印製 α6 _Β_6_五、發明説明(工9) 整。因此Sm3 +或Yb3 +相對於Nd3 +之濃度則成為Ο, 40,60,80,100,120,140,200%。溶融的材料,則在完成 充分混合之後進行急冷處理使其玻璃化。 為了要評儷該玻璃之光擴大特性,乃依下製作光纖。 首先將上述組成之玻璃成形為棒狀,而成為核心用之玻 璃棒。其次則溶融形成组成輿該玻璃棒大約相同,而具 有較低折射率之玻璃而作為殼鱷管(clad pipe)。該殼 «管之玻瑭之組成為 2Pb 0-15Naz 0-15Al 2 03 -68P2 05 (boU),而未添加Nd3 +以及Pr2 03。該些心棒與殼 腰管則形成為預型體,而藉第5圈之裝置加以抽綠。其 結果可得到核心直徑8«b,而外徑為125w·之SM光纖。 該SM光鐵為了便於澜量,則切成10·長度的光纖試料。 該光纖試料之待性的評價偽«第7_之光繼擴大器而 進行。其結果表示在第11_及第12_。 第11圈及第12_所示之增益偽指在波長1.310u I«的情 形,而雷射光源32使用Ti-藍簀石笛射,激發波長為0.78 激發光強度為IOObW。输人倍號之強度為一 30dB», 尖峰波長為1.310« 〇 由上可知笛添加在核心玻璃中之S·3 +濃度相對於Nd 3 +在50%至150%的範麵時則可得到一定值以上的增 益。而S· 3 +濮度在50%以下時則幾乎得不到增益(gain ),而此即是因為作為活性離子之S·3 +的濃度低,而 在Nd 3+附近存在有S·3 +的機率變低使然。又可充分 -21 - (請先閱讀背面之注意事項再填寫本頁) 裝· 訂- 線- 太献银尺疳诎用Ψ团03¾:摞甲4痴格(210x297公修) A 6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明(20) 吸收Nd3 +所放射之1.06W·帮域光之S·3 +亦未存在 。又當Sb3 +之濃度在150%以上時則幾乎得不到增益 ,而此即是因為作為活性離子S·3 +的濃度太高,而藉 Sb3 +在1.3//B附近的微弱趿收,可吸收1.31w·的倍 號光。 另一方面可知與Nd3 + —起添加至核心玻璃之Yb3 + 的濃度,則即使相對於Nd 3 +為50%以上,只要在不損 及玻璃形成能力之程度的範圈内,亦可得到一定值以上 的增益。而在50%以下不能得到增益增益的情形則輿 Sb3 +的情形相同。又由於在Yb3 +時未吸收1.06«· 帶域光,因此即使增加Yb3 +的濃度,增益亦不會減少 〇 (3)—起添加有Ho 3 +的情形。 首先準備Naz 0,A12 03 ,P2 05當作主玻璃材料,貝!1 將其分別之組成如調成15Naz 0-15A1 2 03 -70P2 05 UoU)般地加以讕合。在此則添加一定量之稀土類元素 Nd之氣化物Nd2 03與Ho2 03,而使其溶融在白金坩堝 中,Nd2〇3的添加《,乃使其重量濃度相對於主玻璃 成為IOOOpp·般地加以讕整。又Hoz 03 添加量,則如使 Ho3 +相對於主玻璃之重量濃度成為0,100,200 ,300,400 ,500,600,700,1000般地加以諝整。因此Ho3 +相對於 Nd3 + 之濃度則成為 0,10,20 ,30,40,50,60,70,100%。 溶融的材料,則在完成充分混合之後進行急冷處理使其 (請先閱讀背面之注意事項再填寫本頁) 裝. 訂- 線· 太《.张κ疳诎用ΦΜΚΤί:檍m(CNS)甲4採.格(210乂297公:修) A 6 Β6 經濟部中央標準局貝工消費合作社印製 五、發明説明(21) 玻璃化。 為了要評價該玻璃之光擴大待性,乃依下製作光纖。 首先將上述組成之玻璃成形為棒狀,而成為核心用之玻 璃棒。其次則溶融形成組成與該玻璃棒大約相間,而具 有較低折射率之玻璃而作為殼《管(clad pipe)。該敕 體管之玻璃之組成為 2Pt) 〇_15Na2 0-15Al 2 03 -68f>2 05 (boIX),而未添加Nd3 +以及Pr2 03。該些心棒與殼 體管則形成為預型體,而藉第5圏之裝置加以抽絲。其 結果可得到核心直徑8« «,而外徑為125« «之SM光纖。 該SM光纖為了便於測量,則切成10·長度的光繼試料。 該光纖試料之特性的評價傜藉第7圔之光纖擴大器而 進行。其結果表示在第1 3 。 第12鼷所示之增益僳指在波長1.310«·的情形,而笛 射光源32使用Ti -藍簀石雷射,激發波長為0.78WB,檄 發光強度為l〇〇*W。輸人倍號之強度為一 30dB·,尖峰波 長為 1.310w a。 由上可知,雄著一起添加至核心玻璃中之Ho3 +之濃 度的增加,光纖擴大器之增益會逐漸增大,但是當Ho3 + 對Nd 3 +的濃度超過100%時,則會飽和而其增益幾乎 不增加。 當作當吸收醱之Ho3 +之濃度低時,由於在Nd3 +附 近存在Ho 3 +之機率低,因此增益會變小,又可充分吸 收Nd3 +所放射之0.88«·帶域光之Ho3 +亦不曾存在 (請先閲讀背面之注意事項再填寫本頁) 裝- 訂- 線- 太妖铬兒府诎用中因团宅燸爆(CNS) V4頫格(210x297公婊) 2103^8 A 6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(22) 使然。又當Ho3 +之濃度在100%以上時,由於作為吸 收體之Ho3 +的濃度太高,而可充分地吸收波長〇.88Wb 帶域光,因此即使再添加Ho3 +,其增益亦不會增加。 (4) 一起添加有Tb3 +或Eu3 +的情形。 首先準備除了 Nb3+以外.亦添加有Tb3 +或Eu3 +之»_醒 条玻璃作為光功能性玻璃。此時主玻璃之組成,供如使 其成為15Naz 0-15Al2 〇3 -70P2 05 U〇m般地讕合原 料。又將作為活性物霣之Hd3 +之氣化物,如使Nd3 + 之濃度相對於主玻璃之重》濃度成為100 Oppb地予以添 加。更者將作為發光促進物之Tb 3 +或Eu 3 +的氣化物 ,如使該些1'1>2或£143 +之濃度相對於Nd3 +之重量濃 度成為0,20,30,40,50,60,70, 100%般地予以添加。 為了要評價該玻瓖之光擴大特性,乃依下製作光纖。 首先將上述組成之玻璃成形為棒狀,而成為核心用之玻 璁棒。其次則溶融形成組成與該玻迪棒大約相同,而具 有較低折射率之玻璃而作為殼體管(clad pipe)。該殼 讎管之玻瑰之組成為2Pb 〇_15Na2 0-15A1 2 03 -68P2 05 (moU),而未添加Nd3 +以及Pr2 03。該些心棒與殼 體管則形成為預型讎,而藉第5_之裝置加以抽絲。其 結果可得到核心直徑8w B,而外徑為125« hi之SM光纖。 該SM光纖為了便於測量,則切成1〇Β長度的光纖試料。 該光鑛試料之特性的評價像藉第7圏之光纖擴大器而 進行。 (請先閲讀背面之注意事項再填寫本頁) 裝- 訂_ 線- 經濟部中央標準局員工消費合作社印製 2l^6 A 6 __B6_ 五、發明説明(23) 又撖發光源32使用瀲起波長為0.98« b,檄起输出為 100«w之Ti -藍賨石雷射,而使用半導體雷射作為倍號光 源31。在此由半導讎雷射至光鑛之輪入倍《的強度為 -30dB·,而其尖峰波長為1.310wi〇 上述光功能性玻璃之光纖試料之特性評價的結果則表 示在第14圃,而去白四方形符號者偽表Tb3 +之增益, 而去百圔形符號則表Eii3 +的增益。 由圏中可知,藉共同添加Tb3 +或Eu3 +可增加增益 。因此在以往未一起添加有Tb3 +等活性醵子之習用型 光纖中之增益乃為4dB,然在至少存在20%以上之Tb 3 等活性離子時,可知可得到7 dB以上的增益。更者隨著 Tb 3 +等之活性離子之蠹度的增加,亦可增加光雄擴大 器之增益。而此即是因為皤署Tb 3 +等之濃度的增加, 在Nd3 +附近存在Tb3 +等之活性離子之機率亦變高使 然。藉提高Nd3 +輿Tb3 +等之活性離子之接近機率, 可提高自具有被激發至能量準位4 113/ 2之霣子的Nd3 + 將能量傳遞至Tb 3 +等之活性離子的機率。 (發明之效果) 如上所述,根據本發明之光功能性玻璃,可»激發光 之存在,而使在波長1.3wm帶域之發光以及光擴大成為 可能,或是提高其擴大效率。更者藉將其形成為波導路 徑,光纖等,而可應用至光擴大裝置以及雷射等。特別 是形成為光纖時,可以低S限值得到高增益之光纖擴大 -25- (請先閱讀背面之注意事項再填寫本頁) 裝- 訂_ 線· 太摁進(CNS)甲4鴂格(210x297公嬝) 經濟部中央標準局貝工消費合作社印製 2103^,1 補充 五、發明説明(24) 器。 圖面之簡單説明: 第1画傜表添加至本發明之光功能性玻璃之作為吸收 劑之稀土類元素離子之功能說明薩 第2圖傜表Hd之能量位準画 第3圔係表各種稀土類元素之離子之能量位準圖 第4圖俱表添加至本發明之光功能性玻璃之作為促進 劑之稀土類元素離子之功能説明圖 第5圖俗表使用光功能性玻璃之光纖形成裝置的圖形 第6圖你表由第4圖之裝置所形成之光繼試料的圖形 第7圖係表光纖擴大器之實施例之構成圜 第8圖傺表光纖雷射之實施例之構成圖 第9圖偽波導路徑元件擴大器之實施例 第10圖偽表第7圖之光纖擴大器之在波長1.310am帶 域之增益與Pr3 +之濃度之關偽圖 第11圖傜表第7圖之光纖擴大器之在波長1.310« B帶 域之增益與S»3 +之濃度之關係圖 第12圖傺表第7圏之光鑛擴大器之在波長1 . 310 « b帶 域之增益與Yb 3 +之濃度之鼷稱圖 第13圖係表第7圖之光纖搌大器之在波長1.310// b帶 域之增益與Ho3 +之濃度之關#圖 第14圖偽表第7圖之光纖擴大器之在波長1.310«d!帶 域之增益與Eu3 +或Tb3 +之湊度之關僳圓。 20, 30 ---光纖 32 ---激發光源 33,38,38a,38b,39a.39b---光學裝置66 AB Printed by Beigongxiaot Cooperative, Central Bureau of Standards, Ministry of Economy V. Description of Invention (is) Gain retention shown in Article 10 refers to the case of wavelength 1.3 1 0 «Β, and the laser light source 32 uses Ti- Blue II stone laser with an excitation wavelength of 0.78ju · and a luminous intensity of 100 · «. The strength of the input multiple is -30dB ·, and the peak wave length is 1.310m η. As indicated by the circle, the concentration of Pr3 + added to the core glass together can achieve a gain above a certain value within a range of 50% to 150% relative to Nd 3 +. However, when the concentration of Pr 3 + is less than 50%, the gain is small. This is because the concentration of Pr 3 + as the active ion is low, and the presence of Pr 3 + near Hd 3 + becomes low. In addition, Pr3 + that can fully absorb the 1.06 w · band light emitted by Nd3 + does not exist. In addition, when the Pr 3 + concentration is above 150%, the gain is small. This is because the concentration of Pr3 + as the active ion is too high, and Pr3 + can absorb light at a wavelength of 1.3 «· in the vicinity of the absorption wand near 1.47« ». (2>-From the case where S · 3 + or Yb3 + is added, first prepare Na2 0, A12 03 and P2 Op as the main glass materials, then adjust their respective compositions as 15Na2 0-15Al 2 03 -70P2 05 (»〇1Χ) is added together. Here, a certain amount of the rare earth element Nd vapor Ndz 03 and Sn2 〇3 or Yb3 03 is added to melt it in the platinum crucible field, the amount of Nd203 added is The weight concentration is adjusted to 500 ρ · relative to the main glass. If the amount of Sn 2 0 3 or Yb203 is added, the weight concentration of S · 3 + or Yb 3 + relative to the main glass becomes 0,200,300,400,500,600,700,1000 General -20-20 (Please read the precautions on the back before filling in this page) Binding · Binding-Line-Printed by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperatives α6 _Β_6_ V. Description of Invention (Work 9). So The concentration of Sm3 + or Yb3 + relative to Nd3 + becomes Ο, 40, 60, 80, 100, 120, 140, and 200%. The melted material is quenched after complete mixing to make it vitrified. In order to evaluate the light expansion characteristics of the glass , It is to make optical fiber as follows. First, shape the glass with the above composition Rod-shaped, which becomes a glass rod for the core. Secondly, it is melted to form a glass rod with approximately the same composition, and the glass with a lower refractive index is used as a clad pipe. The shell «管 的 玻璃 瑭 的 组Become 2Pb 0-15Naz 0-15Al 2 03 -68P2 05 (boU), without adding Nd3 + and Pr2 03. The mandrels and shell lumbar tubes are formed into preforms, and the greening of the 5th ring device . As a result, SM fiber with a core diameter of 8 «b and an outer diameter of 125w · can be obtained. The SM iron is cut into a 10 · length optical fiber sample for ease of measurement. The evaluation of the waitability of the optical fiber sample is pseudo« The 7th light is carried out after the amplifier. The results are shown in the 11th and 12th. The gains shown in the 11th circle and the 12th pseudo-refer to the case of the wavelength 1.310u I «, and the laser light source 32 is used Ti-blue grate flute, excitation wavelength is 0.78, excitation light intensity is 100bW. The intensity of the input multiplier is a 30dB », and the peak wavelength is 1.310«. From the above, we can see that the flute is added to the core glass at the S · 3 + concentration Compared with Nd 3 + in the range of 50% to 150%, you can get a gain above a certain value. When S · 3 + Pu degree is below 50% There is almost no gain, and this is because the concentration of S · 3 + as the active ion is low, and the probability of the presence of S · 3 + near Nd 3+ becomes low. It can be fully -21- (Please read the precautions on the back before filling in this page) Packing · Ordering-Thread-Taixian Silver Ruler Use Ψ 团 03¾: Stacked Armor 4 Fool (210x297 public repair) A 6 B6 Bei Gong, Central Standards Bureau, Ministry of Economic Affairs Printed by the consumer cooperative V. Description of the invention (20) The absorption of 1.06W · S · 3 + emitted by Nd3 + · Bangyu Light does not exist. And when the concentration of Sb3 + is above 150%, almost no gain is obtained, and this is because the concentration of S · 3 + as the active ion is too high, and the weak harvest of Sb3 + around 1.3 // B, It can absorb 1.31w · times light. On the other hand, it can be seen that the concentration of Yb3 + added to the core glass together with Nd3 + is at least 50% relative to Nd 3 +, as long as it is within a range that does not impair the glass-forming ability. Gain above the value. The case where the gain cannot be obtained below 50% is the same as the case of Sb3 +. Since Yb3 + does not absorb 1.06 «· band light, the gain will not decrease even if the concentration of Yb3 + is increased. (3) The case where Ho 3 + is added. First prepare Naz 0, A12 03, P2 05 as the main glass material, Pui! 1 their composition is adjusted as 15Naz 0-15A1 2 03 -70P2 05 UoU). Here, a certain amount of Nd2 03 and Ho2 03 vapors of rare earth elements Nd are added to melt them in the platinum crucible. The addition of Nd2〇3 makes its weight concentration relative to the main glass 1000pp Round it up. In addition, the amount of Hoz 03 added, if the weight concentration of Ho3 + relative to the main glass becomes 0,100,200,300,400,500,600,700,1000, it will be rounded up. Therefore, the concentration of Ho3 + relative to Nd3 + becomes 0,10,20, 30,40,50,60,70,100%. The melted material is quenched after it has been fully mixed (please read the precautions on the back before filling in this page) to install. Order-line · too ". Zhang κ 疳 uses ΦΜΚΤί: 檍 m (CNS) A 4 mining. Grid (210 to 297 g: repair) A 6 Β6 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention (21) Vitrification. In order to evaluate the light expansion of the glass, the optical fiber was fabricated as follows. First, the glass having the above composition is formed into a rod shape to become a glass rod for core. Secondly, it melts to form a composition about the same distance as the glass rod, and a glass with a lower refractive index is used as a clad pipe. The composition of the glass of the body tube is 2Pt) _15Na2 0-15Al 2 03 -68f > 2 05 (boIX) without adding Nd3 + and Pr2 03. The mandrels and the shell tube are formed into preforms, and the wire is drawn by means of the fifth ring. As a result, SM fiber with a core diameter of 8 «« and an outer diameter of 125 «« can be obtained. In order to facilitate the measurement, the SM fiber is cut into a 10 · length optical relay sample. The evaluation of the characteristics of the optical fiber sample was conducted with the seventh optical fiber amplifier. The result is shown in No. 1 3. The gain value shown in the 12th element refers to the case where the wavelength is 1.310 mm, and the flue light source 32 uses Ti-blue grit laser, the excitation wavelength is 0.78 WB, and the luminous intensity is 100 * W. The strength of the input multiple is -30dB ·, and the peak wave length is 1.310wa. It can be seen from the above that the concentration of Ho3 + added to the core glass with the masterpiece increases, the gain of the fiber amplifier will gradually increase, but when the concentration of Ho3 + to Nd 3 + exceeds 100%, it will be saturated and its The gain hardly increases. It is considered that when the concentration of the Ho3 + that absorbs the halogen is low, because the probability of Ho 3 + being present near the Nd3 + is low, the gain will be smaller, and the 0.88 emitted by the Nd3 + will be fully absorbed. It has never existed (please read the precautions on the back before filling in this page) Packing-booking-line-Taiyao chrome children's house is used for CNS V4 (210x297 public bitch) 2103 ^ 8 A 6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention Instructions (22) When the concentration of Ho3 + is above 100%, since the concentration of Ho3 + as an absorber is too high, it can fully absorb the light in the wavelength band of 0.88Wb, so even if Ho3 + is added, its gain will not increase. . (4) When Tb3 + or Eu3 + is added together. First of all, besides Nb3 +, Tb3 + or Eu3 + is added as a light functional glass. At this time, the composition of the main glass is such that the raw material can be blended as if it is 15Naz 0-15Al2 〇3 -70P2 05 U〇m. The vaporization of Hd3 + as the active substance was added so that the concentration of Nd3 + relative to the weight of the main glass would be 100 Oppb. Furthermore, the vaporization of Tb 3 + or Eu 3 + as a luminescence promoter, if the concentration of these 1'1> 2 or £ 143 + relative to the weight concentration of Nd3 + becomes 0,20,30,40, Add 50, 60, 70, 100%. In order to evaluate the light expansion characteristics of this glass, the optical fiber was fabricated as follows. First, the glass with the above composition is formed into a rod shape to become a core glass rod. Secondly, the melt-forming composition is about the same as that of the Bodie rod, and the glass with a lower refractive index is used as a clad pipe. The composition of the glass rosette of the shell tube is 2Pb 〇_15Na2 0-15A1 2 03 -68P2 05 (moU) without adding Nd3 + and Pr2 03. The mandrels and the shell tube are formed into pre-shaped jaws, and the wire is drawn by the 5th device. As a result, SM fiber with a core diameter of 8 W B and an outer diameter of 125 mm can be obtained. In order to facilitate the measurement, the SM fiber is cut into 10 OB fiber samples. The characteristics of the light ore sample were evaluated by the seventh fiber optic amplifier. (Please read the precautions on the back before filling in this page) Packing-Order _ Line-Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 2l ^ 6 A 6 __B6_ V. Description of the invention (23) Use the light source 32 again The wavelength is 0.98 «b, and the output is 100« w of Ti-blue laser, and the semiconductor laser is used as the multiple light source 31. Here the intensity of the round-trip laser from the semiconducting laser to the light mine is -30dB ·, and its peak wavelength is 1.310wi. The results of the characteristic evaluation of the optical fiber sample of the above optical functional glass are shown in the 14th garden , And the white square symbol is pseudo-table Tb3 + gain, and the square symbol is Eii3 + gain. It can be seen from the circle that by adding Tb3 + or Eu3 + together, the gain can be increased. Therefore, the gain in conventional optical fibers without the addition of Tb3 + and other active dips in the past is 4 dB. However, when at least 20% of Tb 3 and other active ions are present, it can be seen that a gain of 7 dB or more can be obtained. Moreover, with the increase of the Tb 3 + and other active ions, the gain of the Guangxiong amplifier can also be increased. This is because the concentration of Tb 3 + etc. increases, and the probability of the presence of active ions such as Tb 3 + near Nd3 + also increases. By increasing the proximity probability of Nd3 + Tb3 + and other active ions, it is possible to increase the probability of transferring energy to Nb3 + from Td 3 + and other active ions from Nd3 + with a dazzle excited to energy level 4 113/2. (Effects of the invention) As described above, according to the light functional glass of the present invention, the presence of excitation light can be enabled to enable the emission of light in the 1.3-wavelength band and the expansion of light, or to increase its expansion efficiency. Furthermore, it can be applied to optical amplifying devices, lasers, etc. by forming them into waveguide paths, optical fibers, and the like. Especially when it is formed as an optical fiber, a high gain optical fiber can be expanded with a low S limit -25- (please read the precautions on the back and then fill out this page) Binding-Order _ Line (210x297 gong) Printed 2103 ^, 1 by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Supplement 5. Invention Instructions (24). Brief description of the drawing: The first picture shows the function of rare earth element ions as absorbers added to the light functional glass of the present invention. The energy level drawing of the Hd table in the second picture shows the third picture. The energy level diagram of the ions of rare earth elements. FIG. 4 shows the function description of the rare earth element ions added to the light functional glass of the present invention as an accelerator. FIG. 5 shows the optical fiber formed by using the light functional glass Figure 6 of the device Figure 6 shows the pattern of the light following the sample formed by the device of Figure 4 Figure 7 shows the structure of the embodiment of the fiber amplifier Figure 8 Figure 8 shows the structure of the embodiment of the fiber laser Figure 9 Example of a pseudo-waveguide component amplifier Figure 10 Pseudo table Figure 7 The relationship between the gain of the fiber amplifier in the 1.310am band of the fiber amplifier and the concentration of Pr3 + Figure 11 Figure 7 Wong table Figure 7 The relationship between the gain of the optical fiber amplifier at a wavelength of 1.310 «B-band and the concentration of S» 3+ is shown in Figure 12. Figure 12. The Table 7 of the optical mine amplifier at wavelength 1.310 «b-band. The concentration of Yb 3 + is shown in Figure 13. Figure 13 is the optical fiber amplifier in Figure 7. The relationship between the gain of 1.310 // b band and the concentration of Ho3 + # Figure 14 The pseudo-table of Figure 7 The gain of the fiber amplifier at the wavelength 1.310 «d! Band and Eu3 + or Tb3 + The relationship is round. 20, 30 --- optical fiber 32 --- excitation light source 33, 38, 38a, 38b, 39a. 39b --- optical device

8L ΊΑ Α6 Β6 (請先閲讀背面之注意事項再塡寫本頁) -裝< 線· 太蚯张泞功用Ψ a H 格(210x297公货)8L ΊΑ Α6 Β6 (please read the precautions on the back before writing this page) -install &line; Taizhao Zhangluo function Ψ a H grid (210x297 public goods)

Claims (1)

A7 B7 C7 D7 \ 六、申請專利範圍 第80105212號「光功能性玻璃•光纗,擴大器及雷射 專利案 1. 一種光功能性玻璃,其包含 大A=1.3wm帶域之倍號光 光,其特擻為: 除了上述Hd3 +外,尚添加 收帶之 P r 3 + , Y b 3 + , S m 3 中之至少一種稀土類離子, 之 50% 〜150% ° 2 . —種光纖,具有芯及外殼( 性物質Nd3 +而用於放大λ 振通λ=1.3</π帶域之光, 〜150%之添加添加有在波 (82年6月修正) 活性物質Nd3+ ,用於放 或振通λ =1.3« b帶域之 有在波長1 i附近具有吸 + ,Tb3 + ,Eu3 + 及 Ho3 其添加量為Nd3 +之襄度 (請先閱讀背面之注意事項再填窝本頁) •裝. ,Yb ,S ,Tb 經濟部中央標準局工消費合作社印製 至少一種稀土類離子之光功 包匾著芯且其折射率較該芯 3. —種光纖擴大器,具有可産 光之激發光源(32),産生波 光源(31),分別連接於瀲發 自撖發光源(32)及倍號光源 合之光纖網合器(33),以及 長1.3/ζ Π帶域之倍號光傳輸 包層),該芯 =1 . 3 w m幣域 且以N d3 +之 長1 w η附近具 + ,Eu3 + 及 能性玻璃所形 為低。 生波長0 . 8 « 長1 . 3 w οι帶域 光源及信號光 (31)之檄發光 連接於光纖網 之光纖(30); 像由含有活 之信號光或 濃度之50% 有吸收帶之 Ho3 +中之 成;該外毅 帶域之激發 之倍號光之 源*以將來 及倍號光結 合器以將波 訂 .線. 1 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) A7 B7 C7 D7 六、申請專利範圍 (請先閲讀背面之注意事項再填寫本頁) 該光纖(30)具有芯及外殼,該芯係由含有活性物質 Nd3 +而用於放大λ=1.3«Β帶域之信號光或振强 A=1.3wb帶域之光,且以Nd3 +之濃度之50%~150 %之添加置添加有在波長1« η附近具有吸收帶之Pr3 ,Yb3 + ,Sro3 + ,Tb3 + ,Eu3 + 及 Ho3 + 中之至少一 種稀土類離子之光功能性玻瑰所形成,該外殼包函箸 芯且其折射率較該芯為低。 4. 一種光繼雷射,具有可産生波長0.8W η帶域之撖發光 之激發光源(32),光纖(30),及連接於瀲發光源(32) 與光鐵(30)之間,以將來自激發光源(32)之撖發光入 射於光鐵(30)内之光學裝置(38); 該光繼(30)具有芯及外般,該芯葆由含有活性物質 Nd3 +而用於放大λ =1.3« n箝域之倍號光或振盪 X=1.3/im帶域之光,且以Nd3 +之濃度之50%〜150 炻之添加麗添加有在波長lw m附近具有吸收帶之ΡΓ3 ,Yb3 + ,Sn3 + ,Tb3 + ,Eu3 + 及 Ho3 + 中之至少一 種稀土類離子之光功能性玻璃所形成,該外殼包圃着 芯且其折射率較該芯為低; 經濟部中央標準局R工消费合作社印製 在該光纖(30),平面波導路(130a)之兩端装設在波長 1.3wn帶域具有8 0%以上之反射率之介霣鐃,以構成 共振器構造,俥將來自光纖(30)之波長1.3«·箝域或 其附近之光反饑到該光纖(30)。 5. —種平面波導路(130a),傜由光功能性玻瑱所形成該 -2-本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) 經濟部中央標準局S工消费合作社印製 A7 Q B7 C7 _D7_ 六、申請專利範圍 光功能性玻璃為含有活性物質Nd3 +而用於放大 λ =1.3w η帶域之倍號光或振盪λ =1.3« m帶域之光, 且以Nd3 +之濃度之5 0%〜15 0%之添加量添加有在波 長Ι/iB附近具有吸收帶之Pr3 + ,Yb3 + ,Sni3 + , Tb3 + ,Eu3 +及Ho3 +中之至少一種稀土類離子者。 6. —種波導路元件擴大器,具有由光功能性玻瑰所形成 之平面波導路(130a)而可傳輸波長1.3/i b帶域之倍號 光之導波路元件,産生波長0.8w η帶域之激發光之激 發光源(32),連接於平面波導路(130a)與撖發光源 (32)之間,以將來自激發光源(32)之檄發光入射於該 波導路(130a)之光學裝置(130c); 該光功能性玻璃為含有活性物質Hd3 +而用於放大 λ =1.3w m帶域之倍號光或振盪λ =1.3m m帶域之光, 且以Nd3 +之濃度之50%〜150%之添加量添加有在波 長1/zm附近具有吸收帶之Pr3 + ,Yb3 + ,Sm3 + , Tb3 + ,Eu3 +及Ho3 +中之至少一種稀土類離子者〇 7. —種波導路元件雷射,具有包含由光功能性玻瑰所形 成之平面波導路(130a)之波導路元件,産生波長0.8 wb帶域之激發光之激發光源(32),及連接於波導路 元件(130a)與檄發光源(32)之間,以將來自激發光源 (32)之激發光入射於該波導路元件内之光學裝置 (130c); 該光功能性玻璃為含有活性物質Nd3 +而用於放大 -3- 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) (請先閲讀背面之注意事項再塡寫本頁) 丨裝· 訂 線· 21031,8 A7 B7 C7 D7 六、申請專利範園 λ=1.3«Β帶域之倍號光或振衋λ=1.3/χη帶域之光 ,且以Nd3 +之濃度之50% -150%之添加量添加有在 波長1 w 1»附近具有吸收箝之Pr3 + , Yb3 + , Sid3 + , Tb3 + ,Eu3 +及Ho3 +中之至少一種稀土類離子而 成; 在光繼(30),平面波導路(130a)之兩端設有在波長 1.3/ζι»帶域具有8 0%以上反射率之介質嫌,以構成共 振器構造,俥將來自該波導路元件内之波長1.3/ub帶 域或其附近之光反鋇到該波導路元件(130a)。 (請先閲讀背面之注意事項再填寫本頁) -裝. 訂. 線· 娌滴部中夫螵毕局R工涓费会作社印轚 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐)A7 B7 C7 D7 \ 六 、 Patent application No. 80105212 "Light functional glass, light beam, amplifier and laser patent case 1. A light functional glass, which contains a large number of A = 1.3wm doubled light Light, its special features are: In addition to the above Hd3 +, still at least one kind of rare earth ions of Pr 3 +, Y b 3 +, and S m 3 are added, 50% ~ 150% ° 2. Optical fiber, with a core and a shell (Nd3 +, which is a substance used to amplify the light in the λ vibration pass λ = 1.3 < / π band, ~ 150% of the addition is added to the wave (revised in June 82) Active material Nd3 +, It is used to put or vibrate λ = 1.3 «b band. There are absorption +, Tb3 +, Eu3 + and Ho3 near the wavelength 1 i. The added amount is Nd3 + (Please read the precautions on the back and fill in (This page) • Installed., Yb, S, Tb The Ministry of Economic Affairs, Central Standards Bureau, Industrial and Consumer Cooperative printed at least one rare earth ion optical power package plaque with a core and its refractive index is higher than the core 3.-a fiber amplifier, Excitation light source (32) capable of producing light, generating wave light source (31), respectively connected to the self-luminous light source (32) and the multiple light source Optical fiber network combiner (33), and 1.3 / ζ Π band multiple of the optical transmission cladding), the core = 1.3 wm currency domain and with N d3 + length 1 w η near +, Eu3 + The energy-saving glass is shaped as low. The raw wavelength is 0. 8 «long 1. 3 w οι band light source and the signal light (31) of the light is connected to the optical fiber (30) of the optical fiber network; Or 50% of the concentration of Ho3 + in the absorption band; the source of the multiplied light that is excited by the outer band of the outer Yi * with the future and the multiplier of the optical combiner to bind the wave. 1 This paper size is suitable for China National Standard (CNS) A4 specifications (210 X 297 mm) A7 B7 C7 D7 VI. Scope of patent application (please read the precautions on the back before filling this page) The optical fiber (30) has a core and a shell, the core is It is used to amplify the signal light of λ = 1.3 «B band or the light of A = 1.3wb band containing the active substance Nd3 +, and it is added at 50% ~ 150% of the concentration of Nd3 +. Light functional glass house of at least one rare earth ion of Pr3, Yb3 +, Sro3 +, Tb3 +, Eu3 + and Ho3 + with absorption band near wavelength 1 «η The shell envelops the core and its refractive index is lower than that of the core. 4. A light-following laser with an excitation light source (32) and an optical fiber (30) that can produce luminescence with a wavelength of 0.8 W η band And an optical device (38) connected between the light emitting source (32) and the light iron (30) to incident the light from the excitation light source (32) into the light iron (30); the light continues (30) It has a core and an outer surface. The core is used to amplify light with a multiple of λ = 1.3 «n clamp domain or oscillate X = 1.3 / im band light containing the active substance Nd3 +, and the concentration of Nd3 + is 50 % ~ 150 The addition of stone is formed by adding light functional glass of at least one rare-earth ion among ΡΓ3, Yb3 +, Sn3 +, Tb3 +, Eu3 + and Ho3 + with an absorption band around the wavelength lwm. The shell is covered with a core and its refractive index is lower than that of the core; printed by the R & C Cooperative Society of the Central Bureau of Standards of the Ministry of Economic Affairs on the optical fiber (30), the two ends of the planar waveguide (130a) are installed in the 1.3wn wavelength band With a reflectance of 80% or more, to form a resonator structure, the wavelength from the optical fiber (30) 1.3 Anti-hunger to the optical fiber (30). 5. A kind of planar waveguide (130a), which is formed by optical functional glass. The 2-sheet paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm). A7 Q B7 C7 _D7_ printed by the industrial and consumer cooperatives. 6. Patent application range. The light functional glass contains the active substance Nd3 + and is used to amplify the light of λ = 1.3w η band or oscillate λ = 1.3 «m band. Light, and add Pr3 +, Yb3 +, Sni3 +, Tb3 +, Eu3 + and Ho3 + with the addition amount of 50% ~ 150% of the concentration of Nd3 + in the vicinity of the wavelength Ι / iB At least one rare earth ion. 6. A kind of waveguide component amplifier, which has a planar waveguide (130a) formed by optical functional glass and can transmit a waveguide component with a multiple of wavelength 1.3 / ib band, producing a wavelength of 0.8w η band The excitation light source (32) of the excitation light of the domain is connected between the planar waveguide (130a) and the luminescence source (32), so that the light emitted from the excitation light source (32) is incident on the optics of the waveguide (130a) Device (130c); the light functional glass contains active material Hd3 + and is used to amplify the λ = 1.3wm band multiple light or oscillate λ = 1.3mm band light, and the concentration of Nd3 + 50% ~ 150% of the added amount is added with Pr3 +, Yb3 +, Sm3 +, Tb3 +, Eu3 + and Ho3 + with at least one rare earth ion in the vicinity of the wavelength 1 / zm 〇7.-Type waveguide The element laser has a waveguide element including a planar waveguide (130a) formed by an optical functional glass, an excitation light source (32) that generates excitation light with a wavelength of 0.8 wb, and is connected to the waveguide element (130a) ) And the luminescent source (32), so that the excitation light from the excitation light source (32) is incident on the waveguide The optical device (130c) in the component; the light functional glass contains the active substance Nd3 + and is used for magnification -3- This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) (please first Read the precautions on the back and then write this page) 丨 Installation · Threading · 21031,8 A7 B7 C7 D7 Sixth, apply for a patent fan park λ = 1.3 «multiple number of light in the B band or vibration λ = 1.3 / χη band Light in the field, and add Pr3 +, Yb3 +, Sid3 +, Tb3 +, Eu3 + and Ho3 + with the addition of 50% -150% of the concentration of Nd3 + in the vicinity of the wavelength 1 w 1 » It is made of at least one rare earth ion; at both ends of the optical relay (30), the planar waveguide (130a) is provided with a medium with a reflectivity of more than 80% in the 1.3 / ζι »band of the wavelength to form a resonator In the structure, the light from the wavelength 1.3 / ub band in or near the waveguide element is reflected to the waveguide element (130a). (Please read the precautions on the back before filling out this page)-Packing. Ordering. Thread · Sakububu Nakafuchi Bureau R Gongjuan Feihui Zuoshe Printed Paper This paper applies the Chinese National Standard (CNS) A4 specifications (210 X 297 mm)
TW80105212A 1990-06-20 1991-07-04 TW210328B (en)

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JP16178590 1990-06-20
JP16178690 1990-06-20
JP16740890 1990-06-26
JP22061990 1990-08-22
JP3143552A JP3001672B2 (en) 1990-06-20 1991-06-14 Optical amplifier and laser

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JP3211770B2 (en) 1998-05-11 2001-09-25 日本電気株式会社 Solid-state laser device and solid-state laser amplifier having the same
KR102631645B1 (en) * 2016-10-07 2024-02-01 로렌스 리버모어 내쇼날 시큐리티, 엘엘시 Nd3+ fiber laser and amplifier

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