物425 A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(1 ) 本發明係醑於吸收性物品,詳言之,其係有關於具有 適當吸收體之用完即丟之紙尿褲,生理衛生棉等吸收性 物品者。 紙尿褲,生理用衛生棉,尿失禁者用墊褥等吸收性物 品,主要者係在其中心部配設有可供吸收保持從身體所 排泄之尿液,經血等液體之吸收體,與身體接觸部位配 置有柔軟及液體可滲透性的表層Η材,以及和身體接觸 之反面形成有液體不滲透性的背層Η材者。 吸收體通常係由紙漿纖維及吸水性聚合物所構成。而 吸收性物品,其中經由不織布流入之尿液由紙漿纖維暫 時保持後,再Μ吸水性聚合物保持體液。此時吸水性聚 合物即膨潤並增加吸收體的體積。 通常欲提高吸收體的吸水性而採行增加吸水性聚合物 用量時,相反者減少吸收體中之紙漿含量由於其纏结變 少,而吸水性聚合物膨潤時,常因嬰兒之肢體動作而產 生壓縮或切變應力,致吸收體割裂或壓扁形成阻礙吸收 之原因。 防止此種阻礙吸收之方法,一般係採用將熱熔融纖維 摻混於紙漿纖維中,在同質熱熔融纖維Μ及紙漿纖維和 熱熔融孅維間發生黏著力,藉以提髙保形性之方法。混 合熱熔融纖維改善吸收體之形狀安定性之各案,包括有 特開昭63-92701號公報,特開昭63-318941號公報,特 開昭63-260555號公報及特開平2-74254號公報等。 -3- I . 訂 (請先閲讀背面之注意事項再塡寫本頁) 本紙張Κ度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 82. 5. 20,000 A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(2 ) 然而*維持吸收體的保形性所採用之摻混熱熔融纖維 之方法,雖發現具有可提高吸收體本身之剛性,對於, 界之變形應力產生有較大抵抗力外,由於熱熔融纖維本 身為疏水性,因而有姐礙吸收性之虞。 又*在生產線上需具備有熱熔融糸統,因必須配合熔 融時間,致生產速度受到拘束。更且,由於熱熔融纖維 之混合種類,數量,熔融溫度之差異,使吸收體變成過 於堅硬而易滋生不合適用問題。 是Μ,本發明係在於提供一種勿需加熱處理步驟於吸 收體液時得Μ安定地維持吸收體形狀*不胆礙吸收*而 宜於適用之優異吸收性物品者。 本發明係有關於一種具有液體滲透性的表層片材*液 體不滲透性的背層Η材,以及介於其間之吸收體所組成 ,而該吸收體係Κ紙漿纖維及吸水性聚合物為主體之吸 收性物品,其特徵為,上述吸收體乃係將纖維長度較紙 漿纖維為長之親水性繼維(Μ下稱做為親水性長纖維) 分散於該紙漿纖維内所提供之一種吸收性物品|遽而能 達成上述目的者。 上述吸收體的親水性長纖維,其混合量如Μ紙漿纖維 為計,宜為5〜50重量X,至於上述吸收體之吸水性聚合 物的接混量Μ紙漿纖維為計,最好為1〇〇〜500重量JK , 而上述吸收體的親水性長纖維的纖度宜為0.5〜5d,又 上述親水性長纖維即K含水率在10¾ Μ上的親水性纖維 -4- (請先閲讀背面之注意事項再塡寫本頁) -丨裝. 訂. 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 82. 5· 20,000 S2^425 A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(3 ) 者為佳。 上述吸收性物品的吸收體,於上述親水性長纖維具有 適度之含水率,並且由於纖維較紙漿纖維為長’故在吸 收體液以前可維持其形狀。如上述吸收性物品吸收體液 時,即由吸水性聚合物充分保持體液,即使吸收體中之 紙漿量相對減少時,由於親水性長纖雄與紙漿纖維相互 鏞结,雖因穿甩者之肢體動作而產生有壓縮或切變應力 時,吸收體無有發生割裂虞,亦不會被壓扁。又*親水 性長纖維屬於一種不經熱處理所分散之親水性纖維,蝥 體吸收體維持相當良好之使用狀況,鮮少有發生阻礙吸 收體液之情形。 圖1為鼷於本發明吸收性物品(使用後丟棄之紙尿褲) 的斜視圓。 圖2 (a)及圖"2(b)為圖1吸收性物品吸收體的斷面圖及 部分平面圖。 圖3係有闞於測定本發明吸收性物品之液體吸收性所 用測定裝置之斜視圖。 K下,就本發明有關之吸收性物品,佐Μ附圖詳细說 明之。 參照圖1及圖2所示,有闞於本發明吸收性物品(使 用後即丟之紙尿褲1 ),係由具有液體滲透性的表層片 材2 ,液體不滲透性的背層片材3 ,介於其間之吸收體 4所組成,除該吸收體4 Μ紙漿纗維6及吸水性聚合物 -5- (請先閲讀背面之注意事項再塡寫本頁) 訂, 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 82. 5. 20,000 經濟部中央標準局員工消費合作社印製 A6 __B6__ 五、發明説明U ) 7為主體外,其他即與既有之吸收性物體形成有相同之 構成。 _ 是M,上述吸收體4乃係將纖維長度比紙漿纖維6為 長之親水性長纖維8分散於該紙漿纖維6内所形成。 茲將本發明為再詳加說明之,即使用後即丟棄之紙尿 褲1係由表層片材2 ,背層片材3 ,吸收體4及黏扣片 5a, 5 b所構成,吸收體4即由上面之表層片材2與背層 Η材覆設而成。 表層Η材2只要是具有相當之液體滲透性片材外並無 特別之限制,例如包括有纖布,不镟布,或多孔性片材 等,其材質涵蓋有紙漿,螺繁,聚酯,聚乙烯,聚丙烯 等。圖1之表層片材2係使用由聚酯/聚乙烯所組成之 芯/殻型熱黏合纖維。 背層Η材3除既有吸收性物品所使用之液體不滲透性 片材外並無特別之限制,最好係使用在熱可塑性樹脂添 加以填料經由延伸形故液體不滲透性且能滲透蒸氣之蒸 氣滲透性片材,並具有親虜的感費者為佳,例如可使用 上述薄膜與不織布之複合材料,或為薄膜與嫌布之複合 材料等。 吸收體4係如圖2所示係由紙漿纖維6 ,吸水性聚合 物7 , Μ及纖維長度比紙漿缠維為長之親水性長纖維8 所組成,且因應於吸收性物品的目的形成特定之形狀, . , 例如用完即丟之紙尿褲最好係呈沙漏時鐘之型式.本實 -6- (請先閲讀背面之注意事項再塡寫本頁) 丨裝. 訂. 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 82. 5. 20,000 經濟部中央標準局員工消費合作社印製 五、發明説明(5 ) 施樣態之用完即丟之紙尿褲1係形成縱長件。又,吸收 體4的厚度則視吸收性物品的目的而形成適當之厚度_。 紙漿纖維6 ,除習知吸收體所用者外並無特別之限制 ,紙漿纖維的平均纖維長度,基於粉碎,層積,壓縮處 理等考量,宜介於0.8〜3mm範圍者為佳。 吸水性聚合物7除》7往吸收體所使用者外並無特別限制 ,在本發明中最好係使用高吸水性聚合物,而高吸水性 聚合物之液體吸收率,最好係20w/w Μ上。具體之吸水 性聚合物,適用者為聚丙烯酸納,丙烯酸乙烯醇共聚物 ,聚丙烯酸納交聯體,澱粉一丙烯酸接枝聚合物,異丁 烯一馬來酸酐共聚物或其皂化物,聚丙烯酸鉀,聚丙烯 酸絶等之粉末。吸水性聚合物的混合量Μ紙漿纖維為計 ,係100〜500重量S:,最好為130〜400重量S:,在此範 圍使Μ,吸收體除可充分吸收體液外,兼能充分維持吸 收體的保形性。 上述親水性長纖維8 ,係使用繼維長度比紙漿纖維6 之纖維長度為長而分散於紙漿纖維6者。此種纖維長度 較長者,除可充分總结紙漿纖維及同質之織維外,即使 不混合使用熱熔融纖維亦能充分發揮吸收體4的保形性 。親水性長纖維7之具體纖維長度,如從固定效果的層 面而加Μ考量愈長者愈佳,然如對紙漿之分散性與固定 效果的雙向面加Μ考量,其纖維長度為5 m m〜5 0 β β ,最 好為約7mm〜30mm 0 -7- 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 82. 5. 20,000 (請先閲讀背面之注意事項再塡寫本頁) .裝. ,11. 經濟部中央標準局員工消費合作社印製 A6 B6 五、發明説明(6 ) 上述親水性長纖維8重要者係含水率為103: Μ上的親 水性纖維,如含水率具有10Χ Μ上,而當吸收體4吸敗 體液之當時在纖維內汲取體液之同時藉由維維表面之水 份將纖維黏著,使同質纖維獲致相乘之纏结功效,賦與 吸收體4之保形性。如親水性長纖維8之含水率低於 10%時,則在纖維中頗難以汲取體液,结果降低纖維間 之黏著力,並減少上述之固定效果。 又,上述親水性長繼維8 , Μ吸收體4之固定效果層 面考量則愈细者愈佳,如考慮及於纖維的生產性Κ及紙 漿之分散性,則其纗維直徑宜為0.5〜5d,而Μ0.7〜4d 者為佳。 上逑親水性長缴維8所用之親水性缴維材質,如在纖 維長度,纗維直徑以及含水率所期望之範圍内加K適當 選擇之外,對於材i並無特別之限制,具體上,可單獨 或混合使用螺縈,棉,羊毛,麻等。 上述親水性長纖維8的混合量,Μ紙漿纖維6為計, 係5〜50重量% ,最好為10〜40重量。如混合量未滿 5重量5Κ時,發琨其固定效果不很充分,而超出50重量3! 時吸收體4之厚度加重,不符成本效益。 由Μ上構成所形成之用完即丟之紙尿褲1 ,在穿用時 吸收體4被壓扁,或因嬰兒之肢體動作而產生壓縮或切 變應力時,無有發生割裂之虜,同時亦不發生阻礙吸收 體液之情形。又,上述樣態係將吸收性物品做為用完即 -8 - (請先閲讀背面之注意事項再塡寫本頁) -裝· -^_ 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 82. 5. 20,000425 A6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (1) The present invention is for absorbent articles. In detail, it relates to disposable diapers with appropriate absorbers. Absorbent articles such as sanitary napkins. Absorbent articles such as diapers, sanitary napkins, mattresses for urinary incontinence, etc. The main ones are equipped with absorbers that can absorb and maintain the urine and menstrual fluid discharged from the body at the center of the body. The site is provided with a soft and liquid-permeable surface layer H material, and a liquid-impermeable back layer H material formed on the reverse side of contact with the body. Absorbers are usually composed of pulp fibers and water-absorbing polymers. In absorbent articles, the urine flowing in through the nonwoven fabric is temporarily held by the pulp fibers, and then the water-absorbing polymer is used to hold the body fluid. At this time, the water-absorbing polymer swells and increases the volume of the absorbent body. Generally, when the amount of water-absorbent polymer is increased to increase the water-absorbency of the absorber, on the contrary, the pulp content in the absorber is reduced because its entanglement becomes less, and when the water-absorbent polymer swells, it is often due to the baby's limb movements. Compression or shear stress occurs, causing the absorber to split or squash to form a cause that hinders absorption. The method for preventing such hindering absorption is generally a method of blending hot-melt fibers into pulp fibers to produce adhesion between homogeneous hot-melt fibers M and pulp fibers and hot-melt fibers to improve shape retention. Various cases of blending hot-melt fibers to improve the shape stability of the absorber, including JP-A 63-92701, JP-A 63-318941, JP-A 63-260555, and JP 2-74254 Bulletin etc. -3- I. Order (please read the precautions on the back before writing this page) This paper is suitable for China National Standard (CNS) A 4 specifications (210 X 297 mm) 82. 5. 20,000 A6 B6 Ministry of Economic Affairs Printed by the Central Bureau of Standards' Staff Consumer Cooperative V. Description of the invention (2) However, the method of blending hot-melt fibers used to maintain the shape retention of the absorber has been found to improve the rigidity of the absorber itself. In addition to the greater resistance to deformation stress, the hot-melt fiber itself is hydrophobic, which may hinder absorption. In addition, it is necessary to have a hot-melt system on the production line. The production speed is restricted due to the need to match the melting time. Moreover, due to the difference in the types, quantity, and melting temperature of the hot-melt fibers, the absorber becomes too hard and tends to breed unsuitable problems. It is Μ, and the present invention is to provide an excellent absorbent article suitable for the application that does not require a heat treatment step to maintain the shape of the absorbent body stably when absorbing body fluids * does not hinder absorption *. The invention relates to a liquid-permeable surface layer sheet * liquid-impermeable back layer H material, and an absorber interposed therebetween, and the absorption system is mainly composed of pulp fibers and water-absorbing polymers An absorbent article, characterized in that the above-mentioned absorbent body is an absorbent article provided by dispersing a hydrophilic secondary dimension (hereinafter referred to as a hydrophilic long fiber) whose fiber length is longer than that of pulp fibers in the pulp fibers | Those who can achieve the above goals. For the hydrophilic long fibers of the above absorber, the mixing amount is preferably 5 to 50 weight X based on the M pulp fiber. As for the mixing amount of the water absorbent polymer of the above absorber, the M pulp fiber is preferably 1 〇〇 ~ 500 weight JK, and the fineness of the hydrophilic long fibers of the above absorber is preferably 0.5 ~ 5d, and the above hydrophilic long fibers are hydrophilic fibers with a K moisture content of 10¾ M-4- (please read the back Please pay attention to this page and then write this page)-丨 installed. Ordered. The paper size is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 82. 5 · 20,000 S2 ^ 425 A6 B6 Central Bureau of Standards of the Ministry of Economic Affairs Employee consumer cooperatives print five. Invention description (3) It is better. The absorbent body of the absorbent article has an appropriate water content in the hydrophilic long fibers, and since the fibers are longer than the pulp fibers, the shape can be maintained until the body fluids are absorbed. As the above absorbent article absorbs body fluid, the body fluid is sufficiently retained by the water-absorbing polymer. Even if the amount of pulp in the absorbent body is relatively reduced, the hydrophilic long-fiber males and pulp fibers bind to each other. When there is compression or shear stress during operation, there is no risk of the absorber being cut or squashed. Furthermore, the hydrophilic long fibers belong to a type of hydrophilic fibers that are not dispersed by heat treatment. The candied body absorber maintains a fairly good condition of use, and it rarely happens that hinders absorption of body fluids. Fig. 1 is an oblique view of the absorbent article of the present invention (diaper to be discarded after use). Fig. 2 (a) and Fig. 2 (b) are a cross-sectional view and a partial plan view of the absorbent article absorbent body of Fig. 1. Fig. 3 is a perspective view of a measuring device used for measuring the liquid absorbency of the absorbent article of the present invention. Under K, the absorbent article related to the present invention will be explained in detail with reference to the drawings. 1 and 2, as shown in the absorbent article of the present invention (disposable diapers 1), is composed of a liquid-permeable surface sheet 2, a liquid-impermeable back sheet 3, It is composed of the absorber 4 in between, except for the absorber 4 Μ pulp Puwei 6 and water-absorbing polymer-5- (please read the precautions on the back before writing this page). Standard (CNS) A4 specifications (210 X 297 mm) 82. 5. 20,000 Printed A6 __B6__ by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of invention U) 7 The main body is external, the other is the absorption with the existing Objects have the same composition. _ Is M. The absorber 4 is formed by dispersing hydrophilic long fibers 8 having a fiber length longer than that of the pulp fibers 6 in the pulp fibers 6. The present invention is described in further detail here. The disposable diaper 1 is composed of a surface sheet 2, a back sheet 3, an absorber 4 and adhesive sheets 5a, 5b. The absorber 4 is It is formed by covering the upper surface sheet 2 and the back layer H material. The surface layer H material 2 is not particularly limited as long as it has a relatively liquid-permeable sheet material, including, for example, fiber cloth, non-woven fabric, or porous sheet material. The material covers pulp, snail, polyester, Polyethylene, polypropylene, etc. The surface sheet 2 of Fig. 1 uses a core / shell type thermal bonding fiber composed of polyester / polyethylene. The back layer Η material 3 is not particularly limited except for the liquid-impermeable sheet used in the existing absorbent articles, it is best to use it in the thermoplastic resin added with a filler through extension, so the liquid is impermeable and can permeate vapor The vapour-permeable sheet, and it is better to have a close feeling, for example, the composite material of the film and the non-woven fabric or the composite material of the film and the non-woven fabric can be used. The absorber 4 is composed of pulp fibers 6, water-absorbent polymers 7, M and hydrophilic long fibers 8 whose fiber length is longer than that of the pulp entanglement, as shown in FIG. 2, and is formed according to the purpose of the absorbent article. The shape,.. For example, the disposable diaper should be in the form of an hourglass clock. Honest-6- (Please read the precautions on the back before writing this page) 丨 Installed. Ordered. This paper size is suitable for China National Standard (CNS) A4 specifications (210 X 297 mm) 82. 5. 20,000 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Invention Instructions (5) The disposable diaper 1 series formed after application Long pieces. In addition, the thickness of the absorber 4 is formed to an appropriate thickness depending on the purpose of the absorbent article. Pulp fibers 6 are not particularly limited except for those used in conventional absorbers. The average fiber length of pulp fibers is preferably in the range of 0.8 to 3 mm based on considerations such as crushing, lamination, and compression treatment. The water-absorbing polymer 7 is not particularly limited except for the user of the absorbent body. In the present invention, it is preferable to use a super-absorbent polymer, and the liquid absorption rate of the super-absorbent polymer is preferably 20 w / w Μ 上. Specific water-absorbing polymers are suitable for polyacrylic acid sodium, acrylic acid vinyl alcohol copolymer, polyacrylic acid sodium crosslinked body, starch-acrylic acid graft polymer, isobutylene-maleic anhydride copolymer or its saponification, potassium polyacrylate , Polyacrylic acid absolute powder. The mixed amount of water-absorbent polymer is M pulp fiber, which is 100 ~ 500 weight S :, preferably 130 ~ 400 weight S :, in this range, M, the absorber can fully absorb body fluids, and can be fully maintained. Absorbent shape retention. The above-mentioned hydrophilic long fibers 8 are those in which the following dimension length is longer than that of the pulp fibers 6 and are dispersed in the pulp fibers 6. Such longer fiber lengths can fully summarize the pulp fibers and the homogenous weaving dimensions, and can fully exert the shape-retaining properties of the absorber 4 even if they are not mixed with hot-melt fibers. For the specific fiber length of the hydrophilic long fiber 7, if the M is considered from the aspect of fixing effect, the longer the better, then if the M is considered for the dispersibility of the pulp and the bidirectional surface of the fixing effect, the fiber length is 5 mm ~ 5 0 β β, preferably about 7mm ~ 30mm 0 -7- This paper scale is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) 82. 5. 20,000 (please read the precautions on the back side first Write this page). Installed., 11. A6 B6 printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (6) The above-mentioned hydrophilic long fibers 8 are hydrophilic fibers with an moisture content of 103: M, For example, when the water content is 10 × M, when the absorber 4 absorbs the body fluid, it absorbs the body fluid in the fiber and at the same time, the fiber is adhered by the water on the surface of the dimension, so that the homogenous fiber is multiplied by the entanglement effect. The shape retention of the absorber 4. If the water content of the hydrophilic long fibers 8 is less than 10%, it is quite difficult to absorb body fluids in the fibers, as a result, the adhesion between the fibers is reduced, and the above-mentioned fixing effect is reduced. In addition, the consideration of the fixing effect of the above-mentioned hydrophilic long-dimensional dimension 8 and Μ absorber 4 is the finer the better. If considering the productivity of fiber κ and the dispersion of pulp, the dimension diameter should be 0.5 ~ 5d, and M0.7 ~ 4d is better. There is no special restriction on the material i, except for the appropriate selection of K in the range of fiber length, diameter and water content of the hydrophilic material used in the hydrophilic long-dimensional maintenance 8 of Shangqi. , Can be used alone or mixed with snail, cotton, wool, hemp and so on. The mixing amount of the above-mentioned hydrophilic long fibers 8 is 5 to 50% by weight based on M pulp fibers 6 and preferably 10 to 40% by weight. If the mixing amount is less than 5 weight 5K, the fixing effect of the hair knot is not sufficient, and when the weight exceeds 50 weight 3 !, the thickness of the absorber 4 becomes heavier, which is not cost-effective. When the disposable diaper 1 formed by the M is formed, when the absorbent body 4 is squashed during wearing, or the compression or shear stress is generated due to the movement of the baby's limbs, there are no prisoners who have split, and also There is no situation that hinders the absorption of body fluids. In addition, the above-mentioned aspect is to use absorbent articles as soon as they are used out-8 (please read the precautions on the back before writing this page)-installed ·-^ _ This paper standard is applicable to China National Standard (CNS) A 4 Specifications (210 X 297 mm) 82. 5. 20,000
經濟部中央標準局員工消費合作社印製 五、發明説明( Ί ) 1 I 丟 之 紙 尿 楝 所 做 之 說 明 1·, 如 使 用 做 為 生 理 用 衛 生等 棉 t 1 I 亦 極 為 精 巧 並 不 具 有 穿 著 感 的 問 題 發 生 〇 1 1 是 以 本 發 明 之 吸 收 性 物 品 i 對 於 僅 限 定 於 要求 保 形 1 1 性 的 吸 收 性 物 品 而 梦 乃 為 極 具 適 用 者 〇 請 先 1 1 以 下 係 關 於 本 發 明 之 實 施 例 t 惟 本 發 明 並 不 受以 下 實 閱 1 背 1 施 例 之 限 制 〇 | \ 之 1 實 施 例 注. 意 1 I 在 Η 狀 紙 漿 中 以 紙 漿 為 計 添 加 以 12重量 % 之 螺縈 m 維 事 項 1 1 再 ( 實 施 例 試 樣 1 : 其 含 水 率 為 14 .8% , 大小為0 • 8 d X 18 mm 填 寫 i 實 施 例 試 樣 2 * 其 含 水 率 為 14.1¾. 大小為1 .5 x 3 0 ID ID ) 本 頁 1 做 為 親 水 性 長 纖 維 > 進 行 粉 碎 處 理 9 同 時 以 紙 漿為 計 混 1 I 合 200重量% 之聚丙烯酸鈉作為吸水性聚合物, 施予 層 積 1 1 及 壓 縮 處 理 9 製成基本重量3 9 0g/n 2 t 密 度 0 . 2 g / Π! 3 之 1 1 吸 收 體 ,並測定其纖維含水率, 潤 濕 強 度 及 最 大 吸收 量 〇 訂 又 > 以 紙 漿 為 計 除 添 加 6 重 量 % 及 3 重 量 % 螺縈 做 為 I 親 水 性 長 纖 雒 外 仿 實 施 例 試 樣 2 之 相 同 方 法 t 分別 製 作 1 實 施 例 試 樣 3 及 實 施 例 試 樣 4 » 同 時 測 定 其 潤 濕強 度 及 1 | 最 大 吸 收 量 〇 結 果 如 表 1 所 示 〇 J 如 表 1 所 示 t 所 得 吸 收 體 之 纖 維 含 水 率 均 為 12¾ 〇 I 又 仿 實 施 例 試 樣 1 9 以紙漿為計添加以35重量%螺 1 紫 、 45重量%螺縈 以 及 混 合 以 100重量%、 20 0重量% 1 | 和 350重量%吸水性聚合物, 以分別做成實施例試樣5 1 6 7 % 8 及 9 9 且 測 定 其 潤 濕 強 度 及 最 大 吸 收量 〇 結 1 | 果 如 表 2 所 示 〇 1 比 較 例 1 I 除 不 添 加 螺 紫 m 維 外 仿 實 施 例 (實施例試樣1 )相 同 方 - 1 法 做 成 比 較 例 試 樣 1 〇 同 時 以 添 加 聚 乙 烯 一 聚 丙烯 複 合 1 | 纖 維 (2d > :50m ID)者 代 替 螺 Utik 紫 m 維 所 製 成 之 吸 收 體做 成 比 1 - 9- 1 1 本紙張尺度適用中國國家標準(CNS ) A4规格(210 X 297公釐) 32^425 A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(8 ) 較例試樣2 ,添加聚乙烯對苯二酸酯(2dX50iBB)者代替 螺縈纖維所製成之吸收體做成比較例試樣3 。 ^ 又,添加Μ聚乙烯一聚丙烯複合纖維(2dX5〇Bin)M代 替螺縈纖維,在140 ·〇 下施加Ml秒鐘之壓縮所製成之 吸收體做成比較例試樣4 。測定结果如表1所示。 測定方法 (1 )纖維含水率 準用JIS L 1013之含水率試驗方法测定纖維含水率。 即將試料在60〜70D之溫度下進行1〜2小時預備乾煉。 將此試料放置於溫度20±2*C ,相對濕度65±2!ί標準狀 態的試驗室中直至所吸收之水份到達恒常為止。其次, Κ1小時Κ上之間隔,前後重量測定2次,如前後重量 差形成為後重量差之一定比例Μ内狀態時(纖維素糸纖 維為0.1重量% )則認為其水份平衡己呈一定:而做為 乾燥前的重量。再將此呈一定重量之試料放入於105 土 之乾燥機中,使水份蒸發,測定經乾燥10分鐘前後 之重量差於到達後重量差的一定比例以内(纖維素糸為 0.1重量%)所乾燥試樣之絕對乾燥重量,由下式求出 含水率,反覆進行2次相同操作以其平均值代表缩維含 水率〇 纖維含水率 U)= (W-W’/W’)X100 其中,W:乾燥前之重量(g>, W’=絕對乾燥重量(g> (2)潤濕強度 -10- (請先閲讀背面之注意事項再塡寫本頁) .裝| 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 82. 5. 20,000 A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(9 ) 潤濕強度為,將上述吸收體裁切成70mmX 60mm大小, 加入20cc生理食鹽水,放置5分鐘後,K最大值表示_夾 盤間50mB試樣幅度6〇Bm,拉引速度300mm/min之斷裂強 度。如其最大值在1 2 0 g / 6 0 n m Μ上時,實際上,做為紙 尿褲使用時可資確定吸收體無有破裂。 (3) 最大吸收量 最大吸收量為,將上述吸收體作成200mmX 150mm大小 ,並載置於呈45°傾斜面的傾斜台,將生理食鹽水灌注 於預定之注人點(自端部起140 mmx 75mm位置)。從該注 入點Μ相當於嬰兒每次份之排泄量,每隔5分鐘Μ 5 cc/ 秒速度灌注50cc生理食鹽水。其中,Μ保持於吸收體生 理食鹽水之最大容量做為最大吸收量。紙尿褲被認為所 需求之最大吸收量係相當於4次份尿量(200cc),並Μ 此為目標。 (4) 髙吸水性聚合物之液體吸收率 秤取1.00克經恒溫恒濕(201C, 65¾)過之高吸水性聚 合物。將其浸漬於多餘之生理食鹽水(約150cc)中,直 至聚合物到達平衡潤濕為止放置30分鐘。然後,放入於 預先秤量過之不織布袋體(1 5 X 1 5 c b )內,Μ回轉數1 4 2 0 rpm ,遠心加速度250G進行遠心脫水3分鐘,即席秤量 潤濕聚合物之重量。由此數值扣除聚合物重量(1.00克) 後之餘額做為高吸水性聚合物之液體吸收率(w/w)。 -11- 本紙張尺度適用t國國家標準(CNS)甲4规格(210 X 297公釐) 82. 5. 20,000 (請先閲讀背面之注意事項再塡寫本頁) 丨裝_ *^.Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of Invention (Ί) 1 I Instructions for thrown paper diapers 1. If used as a sanitary cotton t 1 I is also very delicate and does not have to be worn The problem occurs. 〇1 1 is the absorbent article of the present invention. I is only limited to absorbent articles that require shape retention 1 1 and the dream is extremely applicable. Please first 1 1 The following is about the implementation of the present invention Example t However, the present invention is not limited by the following practical examples. 1 Back to 1 Example. Note of 1 Example. Intention 1 I. Add 12% by weight of snail stalk to the pulp in Η-shaped pulp. 1 1 again (Example Sample 1: its moisture content is 14.8%, the size is 0 • 8 d X 18 mm fill in i Example Sample 2 * its moisture content is 14.1¾. The size is 1 .5 x 3 0 ID ID) This page 1 is made into hydrophilic long fiber > It is crushed 9 and mixed with paper pulp 1 I 200% by weight of sodium polyacrylate as water-absorbent polymer, applied to layer 1 1 and compression treatment 9 to make a basic weight of 3 9 0g / n 2 t density of 0.2 g / Π! 3 of 1 1 absorber, and determine the fiber moisture content, wetting strength and maximum absorption amount. Using pulp as the basis except adding 6% and 3% by weight of snails as I. Hydrophilic long-fiber lobes are the same as the example 2 of Example t. 1 Example 3 and Example 4 are made separately Measure its wetting strength and 1 | the maximum absorption. The results are shown in Table 1. 〇J as shown in Table 1. The fiber moisture content of the absorbent body obtained is 12 ¾. Imitate the sample of Example 1 9 based on pulp Add 35% by weight of snail 1 purple, 45% by weight snail, and mix at 100% by weight, 200% by weight 1 | and 350% % Water-absorbent polymer, made into samples 5 1 6 7% 8 and 9 9 of the example, and measured the wetting strength and the maximum absorption. The results are shown in Table 2. 〇1 Comparative Example 1 I The extra-dimensional imitation example (example sample 1) without adding snail purple was prepared in the same way as the sample sample 1 of the comparative method 1 while adding polyethylene-polypropylene composite 1 | fiber (2d >: 50m ID) Instead of the absorber made of snail Utik purple m dimension, the ratio is 1-9- 1 1 The paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 32 ^ 425 A6 B6 Central Standard of Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperative. V. Description of Invention (8) Comparative Sample 2. Samples of Comparative Example 3 were prepared by adding polyethylene terephthalate (2dX50iBB) instead of the absorber made of spiro rayon fiber. ^ Furthermore, an absorber made by adding M polyethylene-polypropylene composite fiber (2dX50 Bin) M instead of snail fiber and applying compression for 140 seconds at 140 seconds was used as Comparative Example Sample 4. The measurement results are shown in Table 1. Measurement method (1) Moisture content of fiber The moisture content test method of JIS L 1013 shall be used to determine the moisture content of fiber. That is, the sample is prepared to be dried at a temperature of 60 to 70D for 1 to 2 hours. Place the sample in a test room at a temperature of 20 ± 2 * C and a relative humidity of 65 ± 2! Standard state until the absorbed water reaches constant. Secondly, the interval between Κ1 hour and Κ, the front and back weight measurement twice, if the front and back weight difference is formed into a certain proportion of the back weight difference Μ within the state (cellulose fiber is 0.1% by weight), it is considered that the water balance has been a certain : And as the weight before drying. Then put this sample with a certain weight in a dryer of 105 soil to evaporate the water, and measure the weight difference after drying for 10 minutes to within a certain percentage of the weight difference after arrival (cellulose 糸 is 0.1% by weight) The absolute dry weight of the dried sample is obtained from the following formula, and the same operation is repeated twice. The average value represents the reduced-dimensional moisture content. The fiber moisture content U) = (W-W '/ W') X100 where , W: weight before drying (g >, W '= absolute dry weight (g > (2) Wetting strength-10- (please read the precautions on the back before writing this page). Loading | This paper size is applicable China National Standard (CNS) Grade A 4 (210 X 297 mm) 82. 5. 20,000 A6 B6 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Invention description (9) Wetting strength is to cut the above-mentioned absorber Into a size of 70mmX 60mm, add 20cc of physiological saline, and leave it for 5 minutes, the maximum value of K means the breaking strength of the 50mB sample width between the chucks is 6Bm, and the drawing speed is 300mm / min. If the maximum value is 1 2 0 g / 6 0 nm Μ, in fact, can be determined when used as a diaper There is no breakage of the absorber. (3) Maximum absorbance The maximum absorbance is the above-mentioned absorber made of 200mmX 150mm size, placed on a tilted table with a 45 ° inclined surface, and the physiological saline is poured into a predetermined injection point (140 mmx 75 mm from the end). From this injection point, M is equivalent to the infant ’s excretion volume, and 50 cc of physiological saline is infused every 5 minutes at a rate of 5 cc / sec. Among them, M is maintained in the absorption body. The maximum capacity of saline is taken as the maximum absorption capacity. The maximum absorption capacity of diapers is considered to be equivalent to 4 servings of urine (200cc), and this is the target. (4) Liquid absorption rate of high water-absorbing polymer Weigh 1.00 g of superabsorbent polymer that has been subjected to constant temperature and humidity (201C, 65¾). Immerse it in excess physiological saline (about 150cc) until the polymer reaches equilibrium wetness and let stand for 30 minutes. Then, Put it in a pre-weighed non-woven bag (1 5 X 1 5 cb), M rotation number 1 4 2 0 rpm, telecentric acceleration 250G for telecentric dehydration for 3 minutes, then weigh the weight of the wet polymer. Deduct polymer weight (1 .00g) The remaining balance is taken as the liquid absorption rate (w / w) of the super absorbent polymer. -11- This paper scale is applicable to the national standard (CNS) A 4 specifications (210 X 297 mm) of 82. 5. 20,000 (please read the precautions on the back before writing this page) 丨 Install _ * ^.
6 B 五、發明説明(10) 經濟部中央標準局員工消費合作社印製 [表1 ] 混合纖維 纖維含 水率 ⑴ 纗維混 合率 ⑴ 潤濕強度 (吸收體斷裂強度) (g/60mm) 最大吸 收量 (CC) 實 施 例 1 螺縈 0,8d^l0mm 12 12 190 200 2 嫘縈 1.5d*30nnn 12 12 180 200 3 螺縈 1.5d^30ffim 12 6 130 200 4 嫘縈 1.5d*30min '12 3 100 200 比 較 例 1 - - 0 80 200 2 PE-PP 2d*5〇Biro 0 12 100 150 3 PE-PET 2d*50aiin 0.3 12 100 150 4 PE-PP 2d:*:50rara 0 12 500 50 -12« 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 82· 5. 20,000 (請先閲讀背面之注意事項再塡寫本頁)6 B 5. Description of the invention (10) Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs [Table 1] Moisture content of mixed fiber fibers ⑴ Mixing ratio of dimensionality ⑴ Wetting strength (breaking strength of absorber) (g / 60mm) Maximum absorption Quantity (CC) Example 1 Spiral ray 0,8d ^ l0mm 12 12 190 200 2 Long ray 1.5d * 30nnn 12 12 180 200 3 Spiral ray 1.5d ^ 30ffim 12 6 130 200 4 Long ray 1.5d * 30min '12 3 100 200 Comparative Example 1--0 80 200 2 PE-PP 2d * 5〇Biro 0 12 100 150 3 PE-PET 2d * 50aiin 0.3 12 100 150 4 PE-PP 2d: *: 50rara 0 12 500 50 -12 « The size of this paper is in accordance with Chinese National Standard (CNS) Grade 4 (210 X 297 mm) 82 · 5. 20,000 (please read the precautions on the back before writing this page)
五、發明説明(β) 經濟部中央標準局員工消費合作社印製 [表 2 ] 潤濕強度 最大吸收量 (吸收體斷裂強度) (g / 6 0 in m ) (c c ) 實 5 190 200 6 190 200 施 7 190 100 例 8 190 300 L-1 9 190 450 (請先閲讀背面之注意事項再填寫本頁) 訂 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 五、發明説明(11) A6 B6 維保的 繼的度 長體程 性收種 水吸某 親 < 有 為度視 4 強可 樣濕雖 試潤 3 例之及。 施度 2 好 實 程樣良 知種試很 可某例不 ,有較性 果具比收 结而,吸 示少於惟 所最至 , 上量。度 Μ 加丨強 由添性濕 的形潤 ---------· ~ ------裝-----f 訂 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社.印製 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 82. 5. 20,000V. Description of the invention (β) Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs [Table 2] Maximum absorption of wetting strength (absorber breaking strength) (g / 6 0 in m) (cc) Actual 5 190 200 6 190 200 Shi 7 190 100 Example 8 190 300 L-1 9 190 450 (Please read the precautions on the back before filling in this page) The size of the revised paper applies to the Chinese National Standard (CNS) A4 specification (210X297mm) V. Description of the invention (11) A6 B6 maintenance of the long-term systemic collection of water absorption of a pro-problem, depending on the strength of the 4 strong and can be sampled wet in 3 cases. Shidu 2 is good, but the sample test is very good, but it is not a case, there is a better result than the result, and the absorption is less than the best, the highest amount. Degree Μ Plus 丨 Strengthen by the addition of wet and moisturizing --------- · ~ ------ Fashion ----- f (please read the precautions on the back before filling this page) Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. The size of the printed paper is in accordance with the Chinese National Standard (CNS) Grade 4 (210 X 297 mm) 82. 5. 20,000