TW433982B

TW433982B - Pesticides

Info

Publication number: TW433982B
Application number: TW85114571A
Authority: TW
Inventors: Saleem Farooq; Stephen Trah; Hugo Ziegler; Rene Zurflueh; Alfons Pascual
Original assignee: Novartis Ag
Priority date: 1995-12-07
Filing date: 1996-11-26
Publication date: 2001-05-16
Also published as: ZA9610282B

Abstract

A compound of the formula, wherein the double bond marked with E has the E-configuration; in which (A) X is N, Y is OR1 or NHR8, R1 is C1-C4 alkyl; R8 is H or C1-C4 alkyl; R9 is methyl; n is 1; G is O; and A is a direct bond; R7 is ethyl; R is an unsubstituted or mono- or polysubstituted C1-C4 alkyl-, C2-C4 alkenyl-, C2-C4 alkynyl-, C3-C6 cycloalkyl-, benzyl- or aryl-group, where the substituents of the groups independently of one another are chosen from the group consisting of halogen, C1-C6 alkyl, halogeno-C1-C6 alkyl, C3-C6 cycloalkyl, halogeno-C3-C6 cycloalkyl, C1-C6 alkoxy, halogeno-C1-C6 alkoxy, C1-C6 alkylthio, halogeno-C1-C6 alkylthio, phenoxy, CN and nitro, or a phenyl radical which is monosubstituted on two adjacent C atoms by an unsubstituted or mono- to tetrasubstituted C1-C4 alkylenedioxy group, where the substituents are selected from the group consisting of C1-C4 alkyl and halogen; or CH2Si(CH3)3; and, where appropriate, in each case in the free form or in salt form. The compounds can be used as agrochemical active compounds and can be prepared in a manner known per se.

Description

433982^ A7 B7 五、發明説明（/ ) 本發明相關於下式化合物 Z ·433982 ^ A7 B7 V. Description of the invention (/) The present invention is related to the compound of the formula Z ·

(請先閱讀背面之注意事項再填寫本頁) ". 其中 (A)或者 X為CH或N * 或 Y為NHRs且 -4 - 本紙張尺度通用中國國家標準（CNS ) A4規格（2! 0 X 297公釐） I11 經濟部中央標隼局員工消費合作社印製經濟部中央標準局員工消費合作社印製 433982^ A7 B7 五、發明説明（>) Z為 0，S或 S ( = 0);(Please read the precautions on the back before filling out this page) ". where (A) or X is CH or N * or Y is NHRs and -4-This paper standard is generally Chinese National Standard (CNS) A4 Specification (2! 0 X 297 mm) I11 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 433982 ^ A7 B7 V. Description of the invention (>) Z is 0, S or S (= 0 );

Ri為Ci — C+院基；為Η，C i 一 C4烷基，鹵素代一C i 一 C+烷基* C3 一“環烷基，Ci —C4烷氧基甲基，Cl —c4烷氧基，鹵素代-Ci — [：4烷氧基，Cl -C4烷基硫*鹵素代一 Ci — C4烷基硫或CN ; R3及IU彼此獨立為Η，C I - C4烷基，C 1 — C4烷氧基，0H*CN，N〇2 * — （Ci - C4 烷基）3 — Si 基團* 其中烷基基團可為相同的或相異的，鹵素，（Cl —C4烷基 )S( = 0) m，（鹵素代一C! — C4 烷基）S( = 0) in，鹵素代一 C i ~ C4烷基或虛素代一 C ^ 一 C4烷氧基；Ri is Ci — C + radical; is Η, Ci — C4 alkyl, halogen — Ci — C + alkyl * C3 — “cycloalkyl, Ci — C4 alkoxymethyl, Cl — c4 alkoxy , Halo-Ci — [: 4 alkoxy, Cl-C4 alkylsulfur * Halo-Ci — C4 alkylsulfur or CN; R3 and IU are independently Η, CI-C4 alkyl, C 1-C4 Alkoxy, 0H * CN, No2 * — (Ci-C4 alkyl) 3 — Si groups * where the alkyl groups can be the same or different, halogen, (Cl —C4 alkyl) S (= 0) m, (halogeno-C! -C4 alkyl) S (= 0) in, halogeno-Ci ~ C4 alkyl or oxo-C ^ -C4 alkoxy;

Rs為Η或C 1 一 C4烷基；為甲基，氟甲基或二氟甲基； is 為 0，1或 2 ; G為0或S ; -5- 本紙張尺度適用中國國家揉準（CNS ) A4規格（210X297公釐} --------,—w—------訂------''级 (請先閱讀背面之注意事項再填寫本頁) 4 3 39 82 ^ A7 B7 五、發明说明（〉）經濟部中央標準局貝工消费合作社印製且A為直鐽’ 一 Ci 〇亞焼基’一 C( = 0) — ’ 一 C ( = S) -或鹵素代一 Cl — Ci 〇亞院基且β7為一自由基β ι ο I 或 A為 Cl — Cl o gg 焼基 * 一 C( = 0) —，一C( = S) —或鹵素代— C! 0亞烷基且卩7為一 CN，ORi ο ，N (l 0 ) 2 ，其中自由基Ri o可為相同的或相異的，或 ~S(=0) pRi 〇 : R為一未經取代的或單——或多重經取代— C4烷基一，C2 ~C<j·铺基一，Cz. — C4 缺基一* C3 — Cs 環焼基一，苄基一，芳基或雜芳基一基圑，其中該類基圑的取代基類彼此獨立選自包拮鹵素，-CS烷基，鹵素代—C i — Cs烷基，C3 — C6環烷基，鹵素代_ C3 — Cs環烷基，Ci —C6垸氧基，鹵素代一Ci — Cs烷氧基，Ci 一％烷基硫，鹵素代_Ci 一 Cs烷基硫，苯氧基，CN及硝基之一群姐，或一苯基自由基，其在兩個鄰近的碳原子上經由一未經取代的或單——至四經取代之_C4亞烷基二氧括包自選偽類基代取；該團中基其的 , 組代群取一 i 之單素行鹵進及團基基烷或Rs is fluorene or C 1 -C4 alkyl; is methyl, fluoromethyl or difluoromethyl; is is 0, 1 or 2; G is 0 or S; -5- This paper size applies to Chinese national standards ( CNS) A4 specification (210X297mm) --------, --w -------- order ------ '' (Please read the precautions on the back before filling this page) 4 3 39 82 ^ A7 B7 V. Description of the invention (〉) Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs and A is a straight line '-Ci 〇Asian'-C (= 0) —' -C (= S)-or halogen-substituted Cl — Ci 〇 subunit and β7 is a radical β ι ο I or A is Cl — Cl o gg 焼 * * C (= 0) —, a C (= S) — Or halo—C! 0 alkylene and 卩 7 is a CN, ORi ο, N (l 0) 2, where the radicals Ri o may be the same or different, or ~ S (= 0) pRi 〇 : R is an unsubstituted or mono- or multi-substituted—C4 alkyl-1, C2 ~ C < j · papyl-1, Cz. — C4 deficient one * C3 — Cs cyclofluorenyl-1, benzyl 1, aryl or heteroaryl-based fluorene, wherein the substituents of this type of fluorene are independently selected from the group consisting of halogen, -CS alkyl, halo -C i- Cs alkyl, C3 — C6 cycloalkyl, halo_ C3 — Cs cycloalkyl, Ci — C6 alkoxy, halo-Ci — Cs alkoxy, Ci 1% alkylsulfur, halo_Ci — Cs alkylsulfur, phenoxy, CN and one of the nitro group, or a phenyl radical, which passes through an unsubstituted or mono- to four-substituted _C4 on two adjacent carbon atoms The alkylene dioxo includes optional pseudo-type radicals; the radicals in the group are replaced by a single element halogen and an alkyl radical or

»1 S 基烷可類團基基烷該中其 (請先閲讀背面之注意事項再填窝本莧) ,¥ -訂·»1 S-based alkane may be similar to alkane-based alkane

i A 本紙張尺度適用中國國家標牟（CNS ) /U说格（210X297公釐）經濟部中央標準局員工消費合作社印製 4 3 39 8 2；i A7 B7 五、發明説明（f ) 為相同的或相異的；i A This paper size applies to China National Standards (CNS) / U Saoge (210X297mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 39 8 2; i A7 B7 5. The invention description (f) is the same Or different

且h為“ —Cs烷基*鹵素代一Ci -Cs烷基，（h —Cs環烷基，鹵素代一Ci — C6環烷基，Ci —Cs烷氧基，鹵素代一 Cl -cs烷氧基，Ci —Cs烷基硫，鹵素代一C 1 一 cs烷基硫，Ci —C6烷基亞磺醯基，鹵素代一 Ci -C s烷基亞磺醢基，Ci —Cs烷基磺醢基*鹵素代—Ci -C 6烷基磺醢基，Ci —Cs烷基磺醯基氧，鹵素代—Ci — C S烷基磺醯基氧，Cl — C6烷氧基一Ci — C6烷基，鹵素代一 Ci — Ce院氧基—Ci — C6,#焼基，Ci — Cs综基硫一C l 一 C6慌基，齒素代一 Ci 一 Cs焼基硫™Ci _Cs院基， Ci — Ce院基亞碌臨基一 Ci — Ce烧基，齒素代—Ci 一 C r s烷基亞磺醢基~Ci — Cs烷基，Ci —Cs烷基磺醯基—C i 一 Cs烷基，鹵素代—Ci —Ce烷基磺醯基一 Ci 一 Cs烷基，Ci — C6烷基羰基，鹵素代—Ci — Ce烷基羰基，Ci —cs烷氧基羰基，鹵素代Ci _CS烷氧基羰基，Ci —c6 烷基胺羰基，Ci —C4烷氣基胺基甲基，二（Ci — c6烷基）胺基羰基，其中該類烷基基圃可為相同的或栢異的；And h is "—Cs alkyl * halo-Ci-Cs alkyl, (h —Cs cycloalkyl, halo-Ci-C6 cycloalkyl, Ci —Cs alkoxy, halo-Cl-cs alkane Oxygen, Ci—Cs alkylsulfur, halo-C 1 -cs alkylsulfur, Ci —C6 alkylsulfinamidinyl, halo-Ci—Cs alkylsulfinamido, Ci —Cs alkyl Sulfonyl * halo—Ci-C 6 alkylsulfonyl, Ci—Cs alkylsulfonyloxy, halogen—Ci—CS alkylsulfonyloxy, Cl—C6 alkoxy—Ci—C6 Alkyl, Halo-Ci—Ce-Ceoxy—Ci—C6, # fluorenyl, Ci—Cs Hexyl-Ci—C6-Ciyl, Dentin-Ci—Cs-Ci-Sulfur ™ Ci—Cs , Ci — Ce, Alkalyl—Ci—Ce, Alkyl, Halo—Ci—Crs alkylsulfinyl — Ci—Cs alkyl, Ci — Cs alkylsulfonyl — C i — Cs alkyl, halogen-Ci-Ce alkylsulfonyl-Ci-Cs alkyl, Ci-C6 alkylcarbonyl, halogen-Ci-Ce alkylcarbonyl, Ci-cs alkoxycarbonyl, halogen Ci _CS alkoxycarbonyl, Ci —c6 alkylaminocarbonyl, Ci —C4 alkylaminoaminomethyl, di (Ci c6 alkyl) aminocarbonyl, wherein such alkyl may be the same or garden Bo-specific;

Ci —Cs烷基胺基硫羰基，二（Ci —c6烷基）胺基硫羰基*其中烷基基團可為相同的或相異的；Ci —Cs alkylaminothiocarbonyl, bis (Ci —c6 alkyl) aminothiocarbonyl * where the alkyl groups may be the same or different;

Ci — Cs烷基胺基，二（Ci — Cs烷基）胺基，其中 -7- 本紙張尺度適用中國國家榇窣（CMS > A4说格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂經濟部中央標李局員工消費合作社印袋 433982^ A7 B7__ 五、發明説明（^) 烷基基團可為相同的或相異的；鹵素，N〇2 ，CN，SF5 ，硫醯胺基，硫氰醯基甲基’ 三甲基矽烷基；一未經取代的或單——至四經取代之Ci — c4亞烷基二氧基團，其中該取代基類係選自包括（^ — C4烷基及鹵素之一群組； \ 芳基一Q—Ci —Ce院基，芳基—Q—Cz — Ce筛基’ 雜環烷基一q-c! —ce烷基，雜環烷基一 Q - c2 _ce烯基*或芳基—Q — Ci —Ce院基，芳基_Q_C2 — Ce稀基，雜環烷基—Q—Ct — Cs烷基或雜環烷基一 Q-C2 —Cs 烯基，其在在芳基或雜環烷基環上為單--至五經取代的，視取代反應的可能性而定*其中該取代基類彼此獨立選自包括齒素，CL 一 Cs院基，齒素代_Ci — Cs燒基，C3 —cs環烷基，鹵素代_c3 一 Cs環烷基，Ci — ce烷氧基 *鹵素代-c6烷氧基，CN，硝基，0C ( = 0) -C、 -cs烷基，0H，NH2及匕—cs烷氧基羰基；其中*若q大於1*自由基Rs可為相同的或相異的q為一直鍵，一CH(OH) -，一 C( = 〇) — 或—S( = 〇) v—; -8 - 本紙張tUi]家標準（CNS ) ( 21Qx297公楚） '' (請先閱讀背面之注意事項再填寫本頁)Ci — Cs alkyl amine, di (Ci — Cs alkyl) amine, of which -7- This paper size applies to the Chinese national standard (CMS > A4 grid (210X297 mm) (Please read the note on the back first) Please fill in this page again) Order the printed bag of the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 433982 ^ A7 B7__ V. Description of the invention (^) The alkyl groups may be the same or different; SF5, Thioamido, Thiocyanomethyl 'trimethylsilyl; one unsubstituted or mono- to four-substituted Ci-c4 alkylene dioxy group, where the substituents are Is selected from the group consisting of one of C ^ alkyl and halogen; \ aryl-Q-Ci-Ce group, aryl-Q-Cz-Ce si group, heterocycloalkyl-qc! -Ce alkane , Heterocycloalkyl-Q-c2_cealkenyl * or aryl-Q-Ci-Ce alkyl, aryl_Q_C2-Ce dialkyl, heterocycloalkyl-Q-Ct-Cs alkyl or heterocyclic Alkyl-Q-C2 —Cs alkenyl, which is mono- to penta-substituted on an aryl or heterocycloalkyl ring, depending on the possibility of a substitution reaction * where the substituents are independently selected from each other package Dentin, CL-Cs compound, Dentin_Ci — Cs alkyl, C3 —cs cycloalkyl, halo_c3 —Cs cycloalkyl, Ci — cealkoxy * halo-c6 alkoxy , CN, nitro, 0C (= 0) -C, -cs alkyl, 0H, NH2, and d-cs alkoxycarbonyl; where * if q is greater than 1 * radical Rs may be the same or different q For a direct bond, one CH (OH)-, one C (= 〇) — or —S (= 〇) v —; -8-tUi] standard (CNS) (21Qx297) for this paper '' (Please first (Read the notes on the back and fill out this page)

V 訂 4 3 39 8 2：^ A7 B7 五、發明説明（& ) v為0，1或2 ;V order 4 3 39 8 2: ^ A7 B7 V. Description of the invention (&) v is 0, 1 or 2;

Ri 〇為 H，“ 一 Cs 烷基，C2 - C8 烯基，C2 -C8 缺基，C3 - Ce環院基；或Ci — Cs焼基，C；2 — Ca蹄基* C2 — C8缺基或C3 - Cs環烷基-，其經由來自包括鹵素之一群組的取代基類進行單--或多重經取代； -Si ( C ! — c4烷基）3 ，其中該類烷基基團可為相同的或相異的；Ri 〇 is H, "mono-Cs alkyl, C2-C8 alkenyl, C2-C8 deficient, C3-Ce ring radical; or Ci-Cs fluorenyl, C; 2-Ca tackyl * C2-C8 deficient Or C3-Cs cycloalkyl-, which are mono- or multiple substituted via substituents from one of the groups including halogens; -Si (C! -C4 alkyl) 3, where such alkyl groups May be the same or different;

Ci —烷氧基羰基，或—芳基或雜環烷基基團*其為未經取代的或經由來自包括鹵素* Ci — c4烷基及鹵素代—c4烷基之一群组的取代基類進行單——或多重經取代，且P為0，1或2 ; 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 且（B)或者（I) η為1或2且q為1，2，3或在η等於1時為4 ; 且 A，C，X，Υ，Ζ，R，R2 * R3 ，IU * Rb ，H7 及 R 9具有上述（Α)中的定義； -9- 本紙張尺度適用t國國家標準（CNS ) A4規格（210 X 297公釐）經濟部中央標隼局員工消費合作社印製 4 3 3 9 8 2」 A7 B7 五、發明説明（/ ) 或（I Π η為0 ; Q為 2，3，4或 5 ; 且 A，X，Y，Z，Rz * R3 * JU ，&s ，&7 及 iig 具有上述（A)中的定義；且自由基R5可為相同的或相異的；其條件為當q為2時，（Rs) 2不為二氯或二甲基，且進一步的條件是當AR7為CH3時，R2不為CH3 ，且（Rs )2為3—氟，5—CF3或，共同為，3，4 —亞甲基二氧且R 3及R 4為Η ; 或（111) n為 0 ; q為 1，A，X * Y，Z * 8之-R3 ，IU ，E7 及 Rg 為具有在上述（A)中的定義；且Rs為第三一丁基，C5 —C6烷基，鹵素代一Ci 一 C S烷基，除了 CF3以外；Ci —alkoxycarbonyl, or —aryl or heterocycloalkyl group * which is unsubstituted or via a substituent from one of the groups including halogen * Ci — c4 alkyl and halo — c4 alkyl Single or multiple replacements, and P is 0, 1, or 2; printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) and (B) or (I) η is 1 or 2 and q is 1, 2, 3 or 4 when η is equal to 1; and A, C, X, Υ, Z, R, R2 * R3, IU * Rb, H7 and R 9 have the above ( Α); -9- This paper size applies to National Standards (CNS) A4 specifications (210 X 297 mm) Printed by the Consumers' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 4 3 3 9 8 2 "A7 B7 5 Explanation of the invention (/) or (I Π η is 0; Q is 2, 3, 4 or 5; and A, X, Y, Z, Rz * R3 * JU, & s, & 7 and iig have the above The definition in (A); and the radicals R5 may be the same or different; the condition is that when q is 2, (Rs) 2 is not dichloro or dimethyl, and the further condition is when AR7 is When CH3, R2 is not CH3, and (Rs) 2 is 3— , 5—CF3 or, together, 3,4-methylenedioxy and R 3 and R 4 are Η; or (111) n is 0; q is 1, A, X * Y, Z * 8 of- R3, IU, E7 and Rg have the definitions in (A) above; and Rs is a third butyl, C5-C6 alkyl, halogen-Ci-CS alkyl, except CF3;

C3 - Cs環烷基，鹵素代一 C3 — Cs環烷基，C5 - C -10- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐> ---------k------、玎------'4 (請先閔讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（f ) 6垸氧基，鹵素代—c3 — cs烷氧基，c2 — cs烷基硫，鹵素代一 Cl 一 Cs烷基硫，Ci -Cs烷基亞磺醯基，鹵素代一Cl —cs烷基亞磺醢基，c2 - cs烷基磺醯基，鹵素代_Ci —Cs烷基磺醢基，Ci _c6烷基磺醯基氧，鹵素代一 Ci — Cs烷基磺醯基氧，Ci — Cs烷氧基一 Ci _Cs 烷基，鹵素代一Ci -Cs烷氧基一Cl — Cs烷基，Ci - c S烷基硫一 Ci 一 Cs烷基，鹵素代—Cl — Cs烷基硫一 Cl _CS烷基* Ci _C6烷基亞磺醯基Ci — cs烷基，鹵素代 —Ct— C6烷基亞磺醯基_Ci —Cs烷基，Ci — Cs烷基磺藤基—Ci _Ce院基，齒素代一 Ci _Ce焼基碌藤基一 Ci —cs烷基，Ci — Cs烷基羰基，鹵素代一 Ci -cs烷基羰基，C2 _Ce烷氧基羰基，鹵素代一 Ci —Ce烷氧基羰基，c2 — Cs烷基胺基羰基，Ci —c4烷氧基亞胺基甲基* 二（c2 _c6烷基）胺基羰基，其中，該類烷基基圃可為相同的或栢異的；C3-Cs cycloalkyl, halogen substituted C3 — Cs cycloalkyl, C5-C -10- This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm > --------- k ------, 玎 ------ '4 (Please read the notes on the back before filling this page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (f) 6 methoxy, halo-c3-cs alkoxy, c2-cs alkylsulfide, halo-Cl-Cs alkylsulfide, Ci -Cs alkylsulfinamido, halo-Cl-cs alkyl Sulfinylene, c2-cs alkylsulfonyl, halo_Ci —Cs alkylsulfonyl, Ci_c6 alkylsulfonyloxy, halo-Ci — Cs alkylsulfonyloxy, Ci — Cs alkoxy-Ci_Cs alkyl, halo-Ci-Cs alkoxy-Cl-Cs alkyl, Ci-c S alkylsulfide-Ci-Cs alkyl, halo-Cl-Cs alkylsulfide- Cl _CS alkyl * Ci _C6 alkylsulfinyl sulfonyl Ci — cs alkyl, halo — Ct — C6 alkyl sulfinyl — Ci — Cs alkyl, Ci — Cs alkylsulfonyl — Ci — Ce Ci-Ce-Ce-Cytyl-Cetyl-Ci-Cs alkyl, Ci-Cs alkylcarbonyl , Halo-Ci-cs alkylcarbonyl, C2-Ce alkoxycarbonyl, halo-Ci-Ce alkoxycarbonyl, c2-Cs alkylaminocarbonyl, Ci-c4 alkoxyiminomethyl * Di (c2_c6 alkyl) aminocarbonyl, wherein the alkyl radicals may be the same or different;

Ci — Cs烷基胺基硫—羰基，二（Ci _Cs烷基）胺基硫羰基，其中該類烷基基團可為相同的或相異的；· c2 烷基胺基，二（c2 — Cs烷基）胺基，其中烷基基團可為相同的或相異的； SFs ，硫氟醯基甲基，三甲基矽烷基，芳基一Q— Ci — -1 1 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐} 、裝訂务 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 4 3 39 8 2、？ A7 B7 五、發明説明（y )Ci — Cs alkylaminothio-carbonyl, di (Ci_Cs alkyl) aminothiocarbonyl, where the alkyl groups may be the same or different; c2 alkylamino, di (c2 — Cs alkyl) amine groups, where the alkyl groups may be the same or different; SFs, thiofluoromethyl, trimethylsilyl, aryl-Q—Ci—-1 1-paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm), binding service (please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 39 8 2,? A7 B7 V. Description of the invention (y)

Cs烷基，芳基一 Q— - C6烯基，雜環烷基— Q-Ci — C s烷基，雜環烷基一 Q — C2 — Ce烯基；或芳基一Q—Ci -（：6烷基，芳碁一 Q— c2 —Cs烯基，雜環烷基一 Q-Ci — Ce烷基或雜環烷基一—cs烯基 *其在芳基或雜環烷基環中進行軍——至五取代，視取代反應的可能性而定，其中該取代基類彼此獨立選自包括鹵素，Ci — Cs烷基，鹵素代一Cl - ce烷基，c3 —c6環烷基，鹵素代—C3 — C6環烷基，Ci —c6烷氧基，鹵素代-Ci —Cs烷氧基，CN，硝基及Ct 烷氧基羰基之一詳組； Q 為直鍵，一 CH(OH) -，-C( = 0) — 或- S( = 〇) v —； V為0，1或2 ; 或（I V) η為1且q為0，· A，X » γ，z，，β3 » R4 ，R7 及 R9 具有在上述（ A)中的定義； G為0 ; -1 2 - 本紙張尺度適用中國國家標车（CNS ) A4規格（210 X 297公釐） 1. 裝訂咏 (請先閱讀背面之注項再填寫本頁) 經濟部中央標準局員工消費合作社印製 433982.j A7 B7 五、發明説明（/^ ) 且R為η —丙基，η — 丁基，第二一丁基，異丁基，C3 一 Cs環院基，C3 — Ce環燒基一Ci _C4综基，鹿素代一 - C6環院基一 Cl 一。4焼基，Ci — C4亞焼基—C3 — cs環烷基，Ci 一[：4亞烷基-鹵素代一C3 —ce環烷基， CH2 SiUi — C4烷基）3 ，其中該類烷基基團可為相同的或相異的；一經取代之芳基或苄基，其中芳基或苄基之取代基類彼此獨立選自包括Ci —C6烷基，鹵素代-Ci — Cs烷基，C 3 — Cs環烷碁，鹵素代_c3 — cs —環烷基，Ci — (^烷氧基，鹵素代一Ci -CS烷氧基，Ci — c6烷基硫，鹵素代-Ci -Ce烷基硫，苯氧基，CN及硝基之一群組；或一苯基自由基，其在兩個鄰近的碳原子上經函一未經取代的或簞——至四經取代之（^ — c4亞烷基二氧基團進行單一取代，其中該類取代基係選自包拮Ci _(U烷基及鹵素之一群組；其條件為，當X為CH* Y為0CH3 ，Z為0，AR7為CH3 ,Cs alkyl, aryl-Q--C6 alkenyl, heterocycloalkyl-Q-Ci-C s alkyl, heterocycloalkyl-Q-C2-Ce alkenyl; or aryl-Q-Ci-( : 6-alkyl, aryl-Q-c2-Cs alkenyl, heterocycloalkyl-Q-Ci-Ce alkyl or heterocycloalkyl-cs alkenyl Carrying out military to five substitutions, depending on the possibility of substitution reaction, wherein the substituents are independently selected from the group consisting of halogen, Ci-Cs alkyl, halogen-Cl-ce alkyl, c3-c6 cycloalkyl , Halo-C3-C6 cycloalkyl, Ci-c6 alkoxy, halo-Ci-Cs alkoxy, CN, nitro and Ct alkoxycarbonyl; Q is a straight bond, one CH (OH)-, -C (= 0) — or-S (= 〇) v —; V is 0, 1 or 2; or (IV) η is 1 and q is 0, · A, X »γ, z , Β3 »R4, R7 and R9 have the definitions in (A) above; G is 0; -1 2-This paper size applies to China National Standard Car (CNS) A4 specification (210 X 297 mm) 1. Binding Yong (please read the note on the back before filling out this page) Preparation 433982.j A7 B7 V. Description of the invention (/ ^) and R is η-propyl, η-butyl, second butyl, isobutyl, C3-Cs ring alkyl group, C3-Ce ring alkyl group A Ci_C4 integrative group, deeroxone-C6 ring courtyard group-Cl one. 4 fluorenyl group, Ci—C4 fluorenyl group—C3—cs cycloalkyl group, Ci — [: 4 alkylene group—halogeno-C3 —Ce cycloalkyl, CH2 SiUi — C4 alkyl) 3, where the alkyl groups may be the same or different; a substituted aryl or benzyl group, in which the aryl or benzyl group is substituted Independently selected from the group consisting of Ci—C6 alkyl, halo-Ci—Cs alkyl, C 3 — Cs cycloalkane, halo — c3 — cs — cycloalkyl, Ci — (^ alkoxy, halo— Ci-CS alkoxy, Ci-c6 alkylsulfide, halo-Ci-Ce alkylsulfide, phenoxy, CN and nitro group; or a phenyl radical in two adjacent A single substitution on the carbon atom is unsubstituted or 箪-to four-substituted (^ — c4 alkylene dioxy groups are single substituted, wherein the substituents are selected from the group consisting of Ci_ (U alkyl And halogen group; when X is C H * Y is 0CH3, Z is 0, AR7 is CH3,

Rz為CH3且R3及IU為Η時，0R不為在4—位置之η—丙基氧或一0CH2 Si ( CH3 ) 3 ; -1 3- 本ϋ尺度適用中國國家標準（CNS ) A4^格（210X297公董) — I I i I — —I I 訂 II 乡 (請先聞讀背面之注意事項再填寫本頁) 4 3 39 8 21 A7 B7____ 明説明（// ) 且進一步的條件是，當OK在P-位置，AK7為CH3 ，R 2為CHs且S3及IU為Η時，R不為在4 一位置經由氟或氛加 Μ取代的苯基，或在4 -位置經由甲基或甲氧基加以取代的或在2—，3_或4—位置經由氟，氛*溴或CF3加以取代的苄基；或者（V) η為1 ; q為β ; A > X > Y > Ζ * R > Rz ，Rs * R4 ，R7 及具有在上述（Λ)中的定義；且G為S ; 其條件為，當R2為甲基時，R不為甲基；或（VI) η為 1 ， q為 0 ; A，G，X，Y，Z，_R2 > R3 ，IU 為 r9 具有在上述（a )中的定義；When Rz is CH3 and R3 and IU are Η, 0R is not η-propyloxy or 4-CH2Si (CH3) 3 at the 4-position; -1 3- This standard applies to China National Standard (CNS) A4 ^ (210X297 public director) — II i I — — II Order II Township (please read the notes on the back before filling out this page) 4 3 39 8 21 A7 B7____ Note (//) and further conditions are, when OK At the P-position, when AK7 is CH3, R 2 is CHs, and S3 and IU are Η, R is not a phenyl group substituted at the 4-position via fluorine or an amine plus M, or a 4-position via methyl or methoxy Benzyl group substituted at the 2-, 3-, or 4-position via fluorine, bromine or bromine or CF3; or (V) η is 1; q is β; A > X > Y > Z * R > Rz, Rs * R4, R7 and have the definitions in the above (Λ); and G is S; provided that when R2 is methyl, R is not methyl; or (VI) η Is 1, q is 0; A, G, X, Y, Z, _R2 > R3, IU is r9 has the definition in (a) above;

A 為直鍵，C7— Clo 亞烷基，一 C( = 〇) -，一 C( = S -14- 本紙張尺度通用宁國國家標準（CNS ) A4規格（210 X 297公釐） I I —i f— . '^i 訂 n I * 線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作社印製經濟部中央標隼局貝工消費合作社印裝 4339821 A7 B7 五、發明説明（f>) )-或鹵素代一Ci -Ci。亞烷基且R7為一自由基Ri 〇 t 或 ASCi - Ci 0 亞烷基，- C( = 0) -，一C( = S) —或鹵素代一 Ci — Ci。亞烷基；且 ίί7 為 CN，0(Ci — C4 烷基）z ，或 NUi - C4 烷基）2 ，，其中該二個烷基自由基可為相同的或相異的* ORi 〇 * tMR! 〇 ) 2 ，其中自由基〇可為相同的或相異的，或一S( = 0p) Ri〇 ; R 1 〇為 Η ; 或Cs — Cs鋪基，C<i· — Cg快基* C3 - Ce環院基；或Cl - c6烷基* c£ - c8烯基，C2 - C8炔基或c3 -Cs環烷基，其經由來自包快鹵素之一群組的取代基類進行單一或多重取代； -Si (Cl 一 C4烷基）3 ，其中該類烷基基團可為相同的或相異的；A is a straight bond, C7—Clo alkylene, one C (= 〇)-, one C (= S -14-, this paper size is generally Ningguo National Standard (CNS) A4 specification (210 X 297 mm) II — if—. '^ i Order n I * line (please read the notes on the back before filling in this page) Printed by the Consumers' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Printed by the Central Bureau of Standards of the Ministry of Economy Printed by the Bayer Consumer Cooperatives 4339821 A7 B7 V. Description of the invention (f >))-or halogen substituted Ci-Ci. Alkylene and R7 is a radical Ri Ot or ASCi-Ci 0 alkylene, -C (= 0)-, a C (= S) —or a halogen substituted Ci—Ci. Alkylene; and ίί7 is CN, 0 (Ci—C4 alkyl) z, or NUi-C4 alkyl) 2, wherein the two alkyl radicals may be the same or different * ORi 〇 * tMR 〇) 2, where the radical 〇 may be the same or different, or a S (= 0p) Ri 〇; R 1 〇 is Η; or Cs — Cs bedding, C < i · — Cg fast radical * C3-Ce cycloalkyl; or Cl-c6 alkyl * c £-c8 alkenyl, C2-C8 alkynyl or c3 -Cs cycloalkyl, which are singulated via substituents from one of the groups containing fast halogens Or multiple substitutions; -Si (Cl-C4 alkyl) 3, where the alkyl groups may be the same or different;

Ci - ce烷氧基羰基，或一芳基或雜環烷基基圑，其 -1 5- 本紙張尺度適用中國國家標準（CNS ) A4说格（210 X 297公釐） n I—. I 里..^衣 ~I n ' ，1TI n (請先閱讀背面之注意事項再填寫本頁) 經濟部中央橾準局貝工消費合作社印策 4 3 3 9 〇 2 - α7 Β7____ 五、發明说明（f〉）為未經取代的或經由來自包括齒素’ Ci _C4院基及齒素代一 Cl 一“垸基進行單一一或多重取代，且R為甲基’乙基，t一丁基，或單--或多重經取代之甲基’乙基或t~ 丁基，其中該類取代基彼此獨立選自包括鹵素，Ci _Cs 烷基，鹵素代一Ci _C6烷基，C3 — Cs環烷基*鹵素代 —c3 — Cs環烷基，Ci —Cs烷氧基*鹵素代一 Ci — Cs 烷氧基，Cl _Ce烷基硫，鹵素代—C1 — “烷基硫，苯氣基，CN及硝基之一群姐，或一苯基自由基’其在兩個鄰近的碳原子上經由—未經取代的或軍—至四經取代之Ci -C4亞烷基二氧基團進行單一取代，其中該類取代基係選自包括（：/一“烷基及鹵素之一群組；或CH2 Si(Ci — C4烷基）3 ，其中烷基基團可為相同的或相異的；或（VI I) π為 1，q為 0 ; A ， G ， X ， Y ， Z ， * R3 1 R4 ， R7 及 Rs 具有在上述（A)中的定義；且R為C2 — C4烯基或C2 — C4炔基，其為經取代的或未經取代的，且其中該類取代基披此獨立選自包括鹵素，C ! — Cs烷基，鹵素代一 Ct 一（：6烷基，C3 — C6環烷基，本紙張尺度適用中國國家標準（CNS ) Α4現格（210X297公;^ ) --------ik------訂------Μ (請先閲讀背面之注意事項再填寫本頁) 433982m 433982m 經濟部中央標準局員工消費合作社印裴 A7 B7 五、發明説明（/f) 鹵素代—c3 — c6環烷基，Ci — Cs烷氧基，鹵素代一Ci —Cs焼氣基，Ci 一 C6院基硫*齒素代一 Ci 燒基硫，苯氧基，CN及硝基之一群組，其條件為，當R2為甲基， h及R4為且G為氧時* AR7不為甲基；且，當合適時，其可能的E/Z異構物頚* E/Z異構物溫合物及/或互麥異構物，在各種情況下Μ游離形式或鹽彤式，這些化合物類* Ε/Ζ異構物類及互變異構物類的製備及使用方法*除害劑類，選自這些化合物，Ε/Ζ異構物類及互變異構物類之活性化合物，及製備及使用這些藥劑類的方法，中間產物類，且，當合適時，其可能的Ε/Ζ異構物類，用於製備這些化合物類之Ε/Ζ異構物混合物類及 /或互變異構物類，其為游離彤式或鹽彤式，當合適時，這些中間產物之互變異構物類，為游離形式或鹽彤式，以及製備及使用這些中間產物類及其互變異構物類的方法。一種偏好之式（I)化合物為，其中或者X為CH或Ν, Υ 為OR，且Ζ為0，或者X為Ν，Υ為NHRs且Ζ為0，S或S ( = 〇) R i為C i 一 C+院基； R2為H，Ci — C4燒基，齒素代一 Ci —C4燒基，C3 -17- 本紙張尺度適用中國國家標準·（ CNS ) A4規格（210X297公ϋ I n I I , I I I H 訂™" n n n —i > 矣 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 43 39 8 2¾¾1 A7 B7 五、發明説明（/jT) 一 c6環烷基，Ci — C4烷氧基甲基，Ci —C4烷氧基，鹵素代一 Ci -c4烷氧基，Ci -C4烷基硫*鹵素代一 Ci — C4烷基硫或CN ; R3及R4彼此獨立為為H，Ci -C4烷基，Ci - C4烷氧基，OH，CN，N〇2 ，一（Ci - C4 烷基）3 - Si 基圑 * 其中該類烷基基團可為相同的或栢異的，鹵素代一（Ci - C 4 烷基）S( = 0) IH，（鹵素代一 Ci — c4 烷基）s( = o) IH，鹵素代一Ci —C4烷基或鹵素代一Cl — C4烷氧碁；Ci-ce alkoxycarbonyl, or an aryl or heterocycloalkyl fluorene, its 1-5-This paper size applies Chinese National Standard (CNS) A4 grid (210 X 297 mm) n I—. I Li .. ^ 衣 ~ I n ', 1TI n (Please read the precautions on the back before filling out this page) Printing Policy of the Central Labor Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives 4 3 3 9 〇2-α7 Β7 ____ 5. Description of the Invention (F>) are unsubstituted or substituted by single or multiple substitutions from the group consisting of dentin 'Ci_C4 and dentinyl-Cl- "fluorene, and R is methyl' ethyl, t-butyl Group, or mono- or multiple substituted methyl'ethyl or t ~ butyl, wherein these substituents are independently selected from each other including halogen, Ci_Cs alkyl, halogen-Ci_C6 alkyl, C3-Cs Cycloalkyl * halo—c3—Cs cycloalkyl, Ci—Cs alkoxy * halo—Ci—Cs alkoxy, Cl_Ce alkylthio, halo—C1— “alkylthio, benzenegasyl , CN and one of the nitro group, or a phenyl radical 'which passes through two unsubstituted or unsubstituted carbon atoms to four substituted Ci-C4 alkylene dioxy groups A single substitution, where the substituents are selected from the group consisting of: (a) alkyl and halogen; or CH2Si (Ci-C4alkyl) 3, where the alkyl groups may be the same or similar Different; or (VI I) π is 1, q is 0; A, G, X, Y, Z, * R3 1 R4, R7 and Rs have the definitions in (A) above; and R is C2-C4 Alkenyl or C2-C4 alkynyl, which are substituted or unsubstituted, and wherein such substituents are independently selected from halogen, C! -Cs alkyl, halo-Ct-(: 6 alkane Base, C3 —C6 cycloalkyl, this paper size is applicable to Chinese National Standard (CNS) Α4 (210X297); ^ -------- ik ------ Order ------ Μ (Please read the notes on the back before filling this page) 433982m 433982m Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, India, Pei A7 B7 V. Description of the invention (/ f) Halogen—c3—c6 cycloalkyl, Ci—Cs alkane Oxygen, halogen-Ci-Cs fluorenyl group, Ci-C6 sulfanyl group * dentin-Ci alkyl group, phenoxy group, CN and nitro group, the conditions are, when R2 is a methyl group H and R4 are and G is oxygen * AR7 is not methyl; and, where appropriate, its possible E / Z isomers * E / Z isomers and / or intermai isomers, in each case M free form or Salty formula, these compounds * E / Z isomers and tautomers are prepared and used * Pesticides, selected from these compounds, E / Z isomers and tautomers Active compounds, and methods for preparing and using these agents, intermediates, and, where appropriate, possible E / Z isomers, for preparing E / Z isomer mixtures of these compounds And / or tautomers, which are free or salty, and where appropriate, the tautomers of these intermediates, free or salty, and the preparation and use of these intermediates and Methods for its tautomeric species. A preferred compound of formula (I) is where either X is CH or N, Υ is OR and Z is 0, or X is N, Υ is NHRs and Z is 0, and S or S (= 〇) R i is C i—C + hospital base; R2 is H, Ci—C4 base, tooth element—Ci—C4 base, C3 -17- This paper size applies to Chinese national standard ((CNS) A4 specification (210X297) I n Order II, IIIH ™ " nnn —i > 矣 (Please read the notes on the back before filling this page) Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 43 39 8 2¾¾1 A7 B7 V. Description of Invention (/ jT) -C6 cycloalkyl, Ci—C4 alkoxymethyl, Ci—C4 alkoxy, halogen—Ci-c4 alkoxy, Ci—C4 alkylthio * halo—Ci—C4 alkylthio or CN R3 and R4 are each independently H, Ci-C4 alkyl, Ci-C4 alkoxy, OH, CN, No2, mono (Ci-C4 alkyl) 3-Si group 圑 * where the alkyl group The groups can be the same or different, halo- (Ci-C 4 alkyl) S (= 0) IH, (halo-Ci — c4 alkyl) s (= o) IH, halo-Ci —C4 alkyl or halogen-substituted Cl—C4 alkoxyphosphonium;

Rs為13或C i - C4烷基； R9為甲基，氟甲基或二氟甲基； m為0，1或2 ; η為0或1 ; q為{]，1，2，3或4或，當η為Q時為5; 或者Α為直鍵，Ci — Ci 〇亞院基，—C ( = 0)—，— C( = s) —或鹵素代一 Ci 一<^ 0亞烷基且R7為一自由基Rs is 13 or Ci-C4 alkyl; R9 is methyl, fluoromethyl or difluoromethyl; m is 0, 1 or 2; η is 0 or 1; q is {], 1, 2, 3 or 4 or, 5 when η is Q; or A is a straight bond, Ci — Ci 〇Yuan Ji, —C (= 0) —, — C (= s) — or halogen—Ci — <^ 0 Alkylene and R7 is a free radical

Rio ； -1 8 - 本紙張尺度適用中國國家標準（CNS ) A4規格（2!0X 297公釐） --------广裝------訂------綵 (請先閲讀背面之注意事項再填寫本頁) A7 433982^ B7 五、發明説明（/6 ) (請先閱讀背面之注意事項再填寫本頁) 或八為“ 一Ci 0 亞烷基，- c( = o) — * — c( = s) —或鹵素代一Cl -C: 0亞垸基且R7為一 CN，OHi ο ，N (iU 〇 ) z ，其中自由基〇可為栢同的或相異的，或 -S ( = Op) R i 〇 ; 偏好為OS! 0 ，JMRi 〇 ) 2 ，其中自由基Ri 0可為相同的或相異的*或一 S( = Op)R10 ; R為一經取代的或未經取代之Ci - C4烷基或芳基基團 *其中該取代基類係選自包括鹵素，Ci _CS烷基，鹵素代_ C i ~ Cs烷基，c3 — cs環烷基，鹵素代~ c3 — cs 環烷基，C! — Cs烷氧基，鹵素代—Ci —Cs烷氧基，CN 及硝基之一群組；.Rio; -1 8-This paper size is applicable to China National Standard (CNS) A4 specification (2! 0X 297 mm) -------- Broadcasting -------- Order ------ Color (Please read the precautions on the back before filling this page) A7 433982 ^ B7 V. Description of the invention (/ 6) (Please read the precautions on the back before filling out this page) Or eight is "-Ci 0 alkylene,- c (= o) — * — c (= s) —or halogen-substituted Cl-C: 0 fluorenyl group and R7 is a CN, OHi ο, N (iU 〇) z, wherein the radical 〇 may be Baitong Or different, or -S (= Op) R i 〇; preference is OS! 0, JMRi 〇) 2, where the radicals Ri 0 can be the same or different * or one S (= Op) R10 R is a substituted or unsubstituted Ci-C4 alkyl or aryl group * wherein the substituent class is selected from the group consisting of halogen, Ci_CS alkyl, halo_Ci ~ Cs alkyl, c3 — cs cycloalkyl, halo ~ c3 — cs cycloalkyl, C! — Cs alkoxy, halo — Ci — Cs alkoxy, CN and nitro group;

Rs為Ci 一 Cs院基，齒素代—Ci — Cs院基，C3 — C s環烷基，鹵素代_C3 — Cs環烷基，Ci —cs垸氧基，經濟部中央標準局員工消費合作社印製鹵素代一 Ci 一（^烷氧基，Ci _C6烷基硫，鹵素代一 Cl —C6烷基硫，Ci — Cs烷基一亞磺醯基，鹵素代—Ci —C S烷基亞磺醢基，Ci _CS烷基磺醢基，鹵素代-Ci — C 6烷基磺豳基，Ci —Cs烷氧基一 Ci —cs烷基，鹵素代 —Ci —Cs烷氧基—Ci _Cs烷基，Ci —Cs烷基硫—Ci —Cs烷基，鹵素代一 Ci -Cs烷基硫一Ci —Cs烷基，c -19- 本紙浪尺度適用中國國家標华（CNS ) A4規格（210 X 297公釐） 433982U a? B7 經濟部中央標隼局員工消費合作社印裝五、發明説明) i —CS烷基亞磺醯基一 Ci _C6烷基，鹵素代一 Ci —c6 烷基亞磺醯基—Ci -Cs烷基，Ci — Cs烷基磺醯基一Ci —Ce焼基*齒素代— C6焼基碼藤基一 Ci — C(3焼基，Ci 一 c6烷基羰基，鹵素代一 Ci —Cs烷基羰基，Ci 一 cs烷氧基羰基，鹵素代—Ci — Cs烷氧基羰基，Ci —cs 烷基胺基羰基* Ci — C4烷氧基亞胺基甲基，二（Ci —c s烷基）胺基羰基，其中烷基基圃可為栢同的或相異的； Ci -Cs烷基胺碁硫羰基，二（Ci - Cs烷基）胺基硫羰基，其中烷基基團可為相同的或相異的，Cl _c6烷基胺基，二（Cl — Cs烷基）胺基，其中烷基基團可為相同的或相異的，鹵素，N〇2 ，CN，SFs *硫醢胺基，硫氟醯基甲基，三甲基矽烷基或一未經取代的或單——至四經取代之Ci - c4亞烷基二氧基團，其中該類取代基選自包括Cl — C4烷基及鹵素之一群组，且其中，若q大於1，自由基Rs可為栢同的或相異的； h 〇為H，Ci — Cs烷基，其為未經取代的或經由來自包括鹵素之一群组的取代基進行單——或多重取代， - C8環烷基，其為未經取代的或經由來自包括鹵累之一群組的取代基進行單--或多重取代，C2 — Cs烯基，其為未經取代的或經由來自包括鹵素之一群組的取代基進行單一—或多重取代，c2 -cs炔基，其為未經取代的或經由 -2 0- (請先閲讀背面之注意事項再填寫本頁) 袭. 訂 .丨年本紙張尺度適用中國國家標準（CNS ) M現格（2ΐ〇χ 297公釐）經濟部中央標準局員工消費合作社印製 4339823 A7 B7 五、發明説\月（/(f) 來自包括鹵素之一群組的取代基進行箪——或多重取代， —SiUi—iU烷基）3 ^其中該類烷基基團可為相同的或相異的，Ci -Cs烷氧基羰基或一芳基或雜環烷基基團，其為未經取代的或經由來自包括鹵素，Ci -C4烷基及鹵素代_Ci — c4烷基之一群組的取代基進行軍——或多重取代；且G為0 ; P為0，1或2 ; 其條件為，當A為亞甲基時，R7不為Η，且進一步的條件是，當Α為直鐽時，R7不是甲基；或A-R7為CH3且或者R5為鹵素，Ci - Cs烷基，齒素代—Ci —C6烷基，C3 — Cs環烷基，鹵素代—C3 — C s環烷基或SiUi -C4烷基）3 ，其中烷基基圑可為相同的或相異的，且其中自由基Rs為相異的； q為 2 * 3，4 或 5 ; 且π為0 ; -2 1 _ 本紙浪尺度適用中國國家標準（CNS > A4規格（210 X 297公釐> ---------\裝------.订------ 線 (請先閲讀背面之注意事項再填寫本頁) A7 4 3 39 8 B7 五'發明説明（q) 或β5為C4 — Cs烷基，c3 — Cs環烷基，鹵素代一 C 3 —Cs環烷基或si(Ci —c4烷基）3 ，其中該類烷基基圑可為相同的或相異的； q為1 ; 且η為0 ; 或R為η—丙基，η—丁基，第二一丁基，異丁基，Ci —C4亞烷基—C3 _CS環烷基，C: —C4亞烷基—鹵素代 -C3 — Cs’環烷基，CH2 Si(Ci — C4烷基）3 ，其中烷基基團可為相同的或相異的*或一經取代之苯基或〒基基團，其中該類取代基偽選自包括鹵素，Ci -c4烷基及鹵素代一 C i 一 C 4烷基之一群組； β £為鹵素； (請先閱讀背面之注意事項再填寫本頁) " 經濟部中央標隼局員工消費合作社印製為或為 η 且式之好偏步進或 Η C 為 X 者或中其物合化本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨0Χ297公釐） 4 3 39 8 2：i A7 B7 五、發明説明^ ) Y為OR，且Z為0 ; 或X為N ; Y為 NHRs 且 Z為 0，S或 S ( = 0); R 1為C 1 一 C4烷基； ϋ2為Η，C ! — C4烷基，鹵素代—C i — C4烷基，C3 —Cs環烷基* Ci 一 C4烷氧基甲基* Ci 一（：4烷氧基，鹵素代一Ci — (U烷氧基，Ci _C+烷基硫，鹵素代-Ci -C4烷基硫或CN ; R3及IU彼此獨立為H，Ci -C4烷基，Ci — C4烷氧基，0H，CN，tJ02 ，一（Ci - C4 烷基）3 — Si 基團，其中烷基基團可為相同的或相異的，鹵素（d —C4烷基）S (=〇) HI * (鹵素代一c i — C4烷基）S ( = 0) !Π，鹵素代一 “ 一04烷基或鹵素代一Ci 一“烷氧基； R8為11或〇1 — C4院基； K3為甲基，氟甲基或二氟甲基； -2 3- 本紙浪尺度適用中國國家標準（€阳）八4规格（210/297公釐） [ ί :: ~]'.、^訂氣 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印装 433982” A7 __B7_ 五、發明説明) in 為 tl，1或 2 ; η為Q或1 ; q為0，1，2，3，4或*當η為0時為5; (3 為 0 ; 且（a) Α為直鍵，Ci — Ci 0亞烷基* - C( = 0) — ，—C( = S) —或鹵素代一 Ci —Ci 0亞烷基且R7為一自由基R i 〇；或（b) A 為 Ci -Ci 〇亞烷基，—C( = 0) -，一 C( ^S)—或齒素代一Ci 一 Ci 〇亞院基且R·?為一 CN，ORi 〇 > N ( R i 〇 ) 2 ，其中自由基Ri 〇可為相同的或相異的 * 或—S( = 0p) R 1 〇 ; 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 且在基團（π及（in中，r為一未經取代的或m — 一或多重經取代之Ci 烷基，c2 — c4烯基，c2 — c 4炔基苄基或芳基基團，其中該取代基類選自包括鹵素，C i — Cs烷基，鹵素代一 Ci _cs烷基，c3 — cs環烷基，鹵素代_C3 —Ce環烷基，（^ —Cs烷氧基，鹵素代—Ci —C6烷氧基，Ci 一 Cs烷基硫，鹵素代一Cl 一％烷基硫 -2 4 - 本紙張尺度適用中國國家標準（CNS ) A4現格（210X 297公釐）經濟部中央標準局員工消費合作社印聚 '433982“ A7 B7 五、發明説明（νΐ ，笨氧基* CN及硝基之一群组，或CHZ Si (Ci —C4烷基 )3 ，其中烷基基團可為相同的或相異的；或一苯基自由基*其在兩個鄰近的碳原子上經由——0 —CH2 _0—基圑進行單一取代；且Rs為Ci — Cs烷基，鹵素代“ 一Cs烷基，C3 - C s環烷基，鹵素代—C3 -Cs環烷基Ci ™CS烷氧基，鹵素代一 Ci — Cs烷氧基，Ci — C6烷基硫，鹵素代一 Ct — Cs烷基硫* Ci — Cs烷基亞磺醯基，鹵素代一Ci -cs烷基亞磺醯基，Ci —C6烷基磺醢基，鹵素代一 Ci —cs烷基磺醯基，Cl 一 Cs烷基磺醢基氧，鹵素代—Ci -cs烷基磺醢基氧，Cl — Cs烷氧基一 Cl - ce烷基*鹵素代_c i - cs烷氧基- Cl -Cs烷基，Ci -C6烷基硫一Cl -C s院基，齒素代一 Ci ~Ce院基硫—Ci — Cs院基，Ci — cs烷基亞磺醯基一Ci 烷基，鹵素代一 Cl —cs烷基亞硬酿基一 Ci — Cs焼基，Ci — Ce燒基購隨基一 Ci —C5 烷基，鹵素代一Ci — 烷基磺醯基一C: — Cs烷基，Cx —Ce烷基羰基，鹵素代一 Ci —Cs烷基羰基，Ci —Cs烷氧基羰基，鹵素代-Ci — Ce烷氧基羰基，Ci —Cs烷基胺基羰基，Ci — C4烷氧基亞胺基甲基，二（Ci —cs烷基）胺基羰基，其中該類烷基基圑可為相同的或栢異的* C i — cs烷基胺基硫羰基，二（Ci — cs烷基）胺基硫羰基 -25- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） I. :"衣 -—I [ "訂 i i (請先鬩讀背面之注意事項再填寫本頁) A7 4 3 3 9 8 2」 B7 _ - - ' ' ' 」.「._「- m 五、發明説明4) ，其中烷基基團可為相同的或相異的，Ci ~Cs烷基胺基 «二（Cl _C6燒基）胺基，其中院基基圑可為相同的或相異的，鹵素，N〇2 · CN · SFs ，硫醯胺基I硫氰醯基甲基，三甲基砂院基，一未經取代的或軍--至四取代之Cl - C4亞烷基二氧基團，其中該取代基類係選自包括Ci — C 4烷基及鹵素之一群組；芳基一 Q—Ci — Cs燒基’芳基一Q—C2 — Cs蹄基* 雜環燒基— Q— Ci —Cs院基’雜環院基一 Q— C2 — Ce烯基，或芳基—Q— Ci 烷基，芳基一Q— C2 — C6烯基 *雜環焼基一 Q - Ci — Ce院基或雜環综基_Q— C2 — Cs 烯基，其在芳基或雜環垸基環中為單——至五經取代的’ 視取代反應的可能性而定，其中該取代基類彼此獨立選自包括齒素’ Ci — Ce焼基’齒素代一 Ci — C6燒基’ C3 — Ce環焼基，齒素代—C3 — Ce _環燒基，Ci — Ce燒氧基，鹵素代一Ci — C6烷氧基，CM*硝基及Ci _C6烷氧基羰基之一群組；且其中，若q大於1，自由基R5可為租同的或相異的； Q 為一直鍵，一 CH(OH) -，一 C( = 0) — 或一S( = 〇 )v -; -2 6- 本紙張尺度適用中國囷家標準（CNS ) A4it格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) :;4Rs is Ci—Cs academy base, dentition—Ci—Cs academy base, C3—Cs cycloalkyl, halo_C3 — Cs cycloalkyl, Ci —cs 垸 oxyl, consumption by employees of the Central Standards Bureau of the Ministry of Economic Affairs Cooperative prints halogen-Ci- (alkoxy, Ci_C6 alkylsulfur, halogen-C1-C6 alkylsulfur, Ci-Cs alkyl-sulfinyl sulfenyl, halogen-Ci-CS alkyl alkylene Sulfonyl, Ci_CS alkylsulfonyl, halo-Ci — C 6 alkylsulfonyl, Ci — Cs alkoxy — Ci — cs alkyl, halo — Ci — Cs alkoxy — Ci — Cs Alkyl, Ci—Cs alkylsulfur—Ci—Cs alkyl, halogen substituted—Ci—Cs alkylsulfur—Ci —Cs alkyl, c -19— The paper scale is applicable to China National Standard (CNS) A4 specifications ( 210 X 297 mm) 433982U a? B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention) i —CS alkylsulfinyl-Ci_C6 alkyl, halogen-Ci—c6 alkylene Sulfonyl-Ci-Cs alkyl, Ci-Cs alkylsulfonyl-Ci-Ce-fluorenyl * dentinyl-C6 fluorenyl-Cetyl-Ci-C (3-fluorenyl, Ci-c6 alkylcarbonyl , Halo-Ci-Cs alkylcarbonyl Ci-cs alkoxycarbonyl, halogenated—Ci—Cs alkoxycarbonyl, Ci—cs alkylaminocarbonyl * Ci—C4 alkoxyiminomethyl, di (Ci—cs alkyl) amino Carbonyl, wherein the alkyl group may be the same or different; Ci -Cs alkylamine thiocarbonyl, di (Ci-Cs alkyl) aminothiocarbonyl, where the alkyl group may be the same or Dissimilar, Cl_c6 alkylamino, bis (Cl-Cs alkyl) amino, in which the alkyl groups can be the same or different, halogen, No2, CN, SFs * thioamino group , Thiofluoromethyl, trimethylsilyl or an unsubstituted or mono- to tetra-substituted Ci-c4 alkylene dioxy group, wherein this type of substituent is selected from Cl-C4 A group of alkyl and halogen, and if q is greater than 1, the radical Rs may be identical or different; h 0 is H, Ci — Cs alkyl, which is unsubstituted or via Mono- or multiple substitution of substituents including one group of halogens,-C8 cycloalkyl, which is unsubstituted or mono- or multiple substitution through substituents including one of halogen groups Generation, C2-Cs alkenyl, which is unsubstituted or single- or multiple-substituted via a substituent from a group including halogen, c2-cs alkynyl, which is unsubstituted or via -2 0 -(Please read the precautions on the reverse side before filling out this page) .. 丨. 丨 This paper size applies to Chinese National Standards (CNS) M Appearance (2ΐ〇χ 297 mm) Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Formula 4339823 A7 B7 V. Invention (/ (f) Substituting a substituent from a group including halogen for 箪 ——or multiple substitutions, —SiUi—iU alkyl) 3 ^ Wherein such alkyl groups may be Are the same or different, Ci -Cs alkoxycarbonyl or an aryl or heterocycloalkyl group, which is unsubstituted or via halogen, Ci -C4 alkyl and halo_Ci — c4 alkyl group of a group of substituents-or multiple substitution; and G is 0; P is 0, 1 or 2; provided that when A is methylene, R7 is not fluorene, and further The condition is that when A is straight, R7 is not methyl; or A-R7 is CH3 and or R5 is halogen, Ci-Cs alkyl, halo-Ci —C6 alkyl, C3 — Cs cycloalkyl, halogenated —C3 — Cs cycloalkyl or SiUi -C4 alkyl) 3, where the alkyl radicals 为 can be the same or different, and where the radical Rs Are different; q is 2 * 3, 4 or 5; and π is 0; -2 1 _ This paper wave scale applies Chinese national standards (CNS > A4 specifications (210 X 297 mm > -----) ---- \ install ------. Order ------ line (please read the notes on the back before filling this page) A7 4 3 39 8 B7 Five 'invention description (q) or β5 is C4 — Cs alkyl, c3 — Cs cycloalkyl, halogenated C 3 —Cs cycloalkyl or si (Ci — c4 alkyl) 3, wherein the alkyl radicals of this type may be the same or different; q is 1; and η is 0; or R is η-propyl, η-butyl, second butyl, isobutyl, Ci —C4 alkylene — C3 —CS cycloalkyl, C: —C4 Alkyl-halo-C3-Cs'cycloalkyl, CH2 Si (Ci-C4 alkyl) 3, where the alkyl group can be the same or different * or a substituted phenyl or fluorenyl group Where the substituents are pseudo-selected from the group consisting of halogen, Ci-c4 alkyl, and halogen-Ci-C4 alkyl; β £ is (Please read the notes on the back before filling out this page) " Printed as or η by the Consumer Cooperatives of the Central Standardization Bureau of the Ministry of Economic Affairs, and the formula is a good step or Η C is X or its combination The size of this paper applies the Chinese National Standard (CNS) A4 specification (2 丨 0 × 297 mm) 4 3 39 8 2: i A7 B7 V. Description of the invention ^) Y is OR, and Z is 0; or X is N; Y Is NHRs and Z is 0, S or S (= 0); R 1 is C 1 -C 4 alkyl; ϋ 2 is Η, C! — C 4 alkyl, halo — C i — C 4 alkyl, C 3 — Cs ring Alkyl * Ci-C4alkoxymethyl * Ci-(: 4alkoxy, halogen-Ci- (Ualkoxy, Ci_C + alkylsulfur, halogen-Ci-C4alkylsulfur or CN; R3 and IU are independently H, Ci-C4 alkyl, Ci-C4 alkoxy, 0H, CN, tJ02, mono (Ci-C4 alkyl) 3-Si group, wherein the alkyl groups can be the same Or different, halogen (d —C4 alkyl) S (= 〇) HI * (halogeno-ci —C4 alkyl) S (= 0)! Π, halogeno — “04 alkyl or halogeno — Ci- "alkoxy; R8 is 11 or 〇1-C4 courtyard; K3 is Base, fluoromethyl or difluoromethyl; -2 3- The paper scale is applicable to the Chinese national standard (€ yang) 8 4 specifications (210/297 mm) [ί :: ~] '., ^ Order gas (please Read the notes on the back before filling in this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 433982 ”A7 __B7_ V. Description of the invention) in is tl, 1 or 2; η is Q or 1; q is 0, 1, 2, 3, 4 or * is 5 when η is 0; (3 is 0; and (a) A is a straight bond, Ci — Ci 0 alkylene *-C (= 0) —, —C (= S ) —Or halogen-substituted Ci—Ci 0 alkylene and R7 is a radical R i 〇; or (b) A is Ci—Ci 0 alkylene, —C (= 0) —, C (^ S ) —Or dentin substitutes Ci—Ci 〇 sub-base and R ·? Is a CN, ORi 〇> N (R i 〇) 2, where the radical Ri 〇 can be the same or different * or— S (= 0p) R 1 〇; printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) and the group (π and (in, r is an unsubstituted Or m-one or more substituted Ci alkyl, c2-c4 alkenyl, c2-c 4 alkynyl benzyl or aryl Group, wherein the substituents are selected from the group consisting of halogen, Ci-Cs alkyl, halogen-Ci_cs alkyl, c3-cs cycloalkyl, halogen_C3-Ce cycloalkyl, (^ -Cs alkyl Oxygen, halogen—Ci —C6 alkoxy, Ci—Cs alkylsulfur, halogen—Cl—% alkylsulfur-2 4-This paper is in accordance with Chinese National Standard (CNS) A4 (210X 297) PCT) Consumers 'Cooperatives Printed Poly' 433982 "A7 B7 of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the Invention (νΐ, one of the groups of benzyloxy * CN and nitro, or CHZ Si (Ci-C4 alkyl) 3, of which The alkyl groups may be the same or different; or a phenyl radical * which is single substituted on two adjacent carbon atoms via a -0-CH2_0-yl group; and Rs is a Ci-Cs alkane Radical, mono-Cs alkyl, C3-Cs cycloalkyl, halogen-C3-Cs cycloalkyl Ci ™ CS alkoxy, halogen-Ci-Cs alkoxy, Ci-C6 alkylsulfide , Halo-Ct — Cs alkylsulfur * Ci — Cs alkylsulfinyl, Halo-Ci-cs alkylsulfinyl, Ci—C6 alkylsulfonyl, Halo-Ci —cs base Fluorenyl, Cl-Cs alkylsulfonyloxy, halo-Ci-cs alkylsulfonyloxy, Cl-Cs alkoxy-Cl-ce alkyl * halo_ci-cs alkoxy-Cl -Cs alkyl, Ci-C6 alkylsulfide-Cl-Cs alkyl, dentino-Ci ~ Ce alkylsulfur-Ci-Cs alkyl, Ci-cs alkylsulfinyl-Ci alkyl, Halo-Ci-Cs alkyl hardened alkyl-Ci-Cs alkyl, Ci-Ce alkyl, Ci-Ci alkyl, Ci-C5 alkyl, halogen-Ci-alkyl sulfo-C:-Cs alkane , Cx —Ce alkylcarbonyl, halo-Ci — Cs alkylcarbonyl, Ci — Cs alkoxycarbonyl, halo —Ci — Ce alkoxycarbonyl, Ci — Cs alkylaminocarbonyl, Ci — C4 Alkoxyiminomethyl, bis (Ci-csalkyl) aminocarbonyl, in which the alkyl group 圑 can be the same or different * Ci-cs alkylaminothiocarbonyl, di ( Ci — cs alkyl) aminothiocarbonyl-25- This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) I.: " 衣 -—I [" Order ii (Please read first Note on the back, please fill out this page) A7 4 3 3 9 8 2 ″ B7 _--' '' ”." ._ "-m 5. Description of the invention 4), where the alkyl groups may be the same or different, Ci ~ Cs alkylamino group« di (Cl_C6 alkyl) amino group, where The radicals can be the same or different, halogen, NO2 · CN · SFs, thiosaminol I, thiocyanomethyl, trimethylsulphonyl, an unsubstituted or military- -To tetra-substituted Cl-C4 alkylene dioxy groups, wherein the substituents are selected from the group consisting of Ci—C 4 alkyl and halogen; aryl—Q—Ci—Cs alkyl; -Q-C2—Cs-Heptyl * Heterocycloalkyl—Q—Ci—Cs—Cycloyl—Heterocyclyl—Q—C2—Celenyl, or aryl—Q—Ci alkyl, aryl—Q — C2 — C6 alkenyl * heterocyclic fluorenyl-Q—Ci—Ce alkenyl or heterocyclic integrator_Q—C2—Cs alkenyl, which is single in the aryl or heterocyclic fluorenyl ring—to the penta-class Substituted according to the possibility of substitution reaction, wherein the substituents are independently selected from the group consisting of dentin 'Ci-Ceenyl' dentin-Ci-C6alkenyl 'C3-Ce cyclofluorenyl, dentin —C3 — Ce _cycloalkyl, Ci — Cealkyl, halogen A group of Ci—C6 alkoxy, CM * nitro, and Ci_C6 alkoxycarbonyl; and if q is greater than 1, the radical R5 may be identical or different; Q is a straight bond, One CH (OH)-, one C (= 0) — or one S (= 〇) v-; -2 6- This paper size is applicable to China National Standard (CNS) A4it grid (210 X 297 mm) (please (Read the precautions on the back before filling out this page):; 4

IT 經濟部中央標準局員工消費合作社印製 4 3 39 8 2.^ A7 __B7_ 五、發明説明（y>) 偏好為直鐽，一CH ( OH) —或-C ( = 0) -，v為Ο，1 或2 ;Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of IT and Economics 4 3 39 8 2. ^ A7 __B7_ V. Description of the Invention (y >) Preference is straight forward, one CH (OH) —or -C (= 0)-, v is 〇, 1 or 2;

Ri 〇為H，h 烷基，其為未經取代的或經由來自包括鹵素之一群組的取代基進行單一-或多重取代，C3 _Ce環烷基，其為未經取代的或經由來自包括鹵素之一群組的取代基進行單——或多重取代，C2 - Cs烯基，其為未經取代的或經由來自包括鹵素之一群組的取代基進行單 —一或多重取代，C2 —（：8玦基*其為未經取代的或經由來自包括鹵素之一群組的取代基進行單——或多重取代， —Si (Ci — C4烷基）3 ，其中該類烷基基團可為相同的或相異的* Ci _CS烷氧基羰基或一芳基或雜環烷基基團，其為未經取代的或經由來自包括鹵素，Ci — C4烷基及鹵素代一 Cl _c4烷基之一群組的取代基進行軍--或多重取代，且P為G，1或2 ; 其條件為A-R7不為CH3 ; 經濟部中央標準局貝工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 或A— E7在下列基團（C)至（10中為CH3且，R* ，R2 .R3 ，R4 ，ΙΪ8 ，Rg及01具有在上述（⑺中的定義，且或者（c) Rs為鹵素，Ci _CS烷基，.函素代 _ Ci _ C 6院基.，C 3 一 Cs環院基’齒素代一 — Ce環烷基或SitCi—C*烷基）3 ，其中烷基基團可為相同的 -2 7 - 本紙張尺度適用中國國家榇準（CNS ) A4規格（210X297公釐）經濟部中央標隼局員工消費合作社印製 4 3 39 82.i A7 B7 五、發明説明或相異的且其中自由基Rs為相異的； q為 2，3，4或 5 ; 且π為0 ; 或（d) Rs為（]4 — C6烷基，C3 — Cs環烷基，鹵素代一 C3 — Cs環垸基或Si ( C i — C4烷基）3 ，其中該類烷基基團可為相同的或相異的； q為1 ; 且π為0 ; 或（e) R為η —丙基，η-丁基•第二—丁基，異丁基，C3 - Cs環焼基，C3 — Cs環烷基-Ci — (U烷基，鹵素代—C3 — Cs環烷基-Ci _C4烷基，Ci — C4亞烷基 -C3 — Cs環烷基，Ci — C4亞烷基一鹵素代-C3 — Cs 環烷基，CH2 Si(Ci - C4烷基）3 *其+垸基基團可為相同的或相異的，或一經取代之苯基或苄基基圑*其中該取代基類係選自包括鹵素，Ci — C4烷基及鹵素代_Ci 一 C 4烷基之一群組； - 2 8 - 本紙張尺度適用中國國家標準（CNS > A4規格（210 X 29?公釐） (請先閱讀背面之注意事項再填寫本頁) 丁 -* 4 3 3 9 8 2 ：iRi 0 is H, h alkyl, which is unsubstituted or single- or multiple substituted via a substituent from one of the groups including halogen, C3-Ce cycloalkyl, which is unsubstituted or via The substituents of one group of halogens are mono- or multiple-substituted, C2-Cs alkenyl, which are unsubstituted or mono-, or multiple-substituted, via substituents from one of the groups including halogen, C2- (: 8 fluorenyl group * which is unsubstituted or mono- or multi-substituted via substituents from one of the groups including halogen, -Si (Ci-C4 alkyl) 3, wherein such alkyl groups May be the same or different * Ci_CS alkoxycarbonyl or an aryl or heterocycloalkyl group, which is unsubstituted or via halogen, Ci—C4 alkyl and halogen-substituted Cl_c4 The substituents of one of the alkyl groups are military or multiple substitutions, and P is G, 1 or 2; the conditions are that A-R7 is not CH3; printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please first Read the notes on the back and fill out this page) or A—E7 in the following groups (C) to (10 is CH3 and R * , R2, R3, R4, IΪ8, Rg and 01 have the definitions in the above (⑺), or (c) Rs is a halogen, Ci_CS alkyl,. _Suo_Ci_C6, C3, C3 One Cs-Cyclo-Cycloyl group-dentinyl-Ce cycloalkyl or SitCi-C * alkyl) 3, in which the alkyl group can be the same -2 7-This paper applies to China National Standards (CNS) A4 Specifications (210X297 mm) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 4 3 39 82.i A7 B7 V. Description of inventions or differences and in which the radical Rs are different; q is 2, 3, 4 Or 5; and π is 0; or (d) Rs is (] 4-C6 alkyl, C3-Cs cycloalkyl, halo-C3-Cs cyclofluorenyl or Si (Ci-C4 alkyl) 3, Wherein such alkyl groups may be the same or different; q is 1; and π is 0; or (e) R is η-propyl, η-butyl • second-butyl, isobutyl , C3-Cs cyclofluorenyl, C3-Cs cycloalkyl-Ci-(U alkyl, halo-C3-Cs cycloalkyl-Ci-C4 alkyl, Ci-C4 alkylene-C3-Cs cycloalkyl , Ci — C4 alkylene-halo-C3 — Cs cycloalkyl, CH2 Si (Ci-C4 alkyl) 3 * Its + fluorenyl group may be the same or different, or a substituted phenyl or benzyl group * where the substituents are selected from the group consisting of halogen, Ci-C4 alkyl and halogeno_Ci One group of one C 4 alkyl group;-2 8-This paper size applies to Chinese national standards (CNS > A4 size (210 X 29? Mm) (Please read the precautions on the back before filling out this page) Ding- * 4 3 3 9 8 2: i

五、發明説明（#)V. Description of the invention (#)

Rs為鹵素’ q為0 ’ 1 ’ 2 ’ 3或4 ; 旦η為1 ; 其條件為*當X為CH，Υ為〇CH3 ’ Ζ為0，R2為CH3 ’ R 3及R4為氫，R9為CH3 ，11為1且q為Q時’ 0R不為在p -位置之m- CF3 —〒基氧；或（f) R為一未經取代的或單--或多重經取代之《^ —C4院基，— C4婦基’C2 _ C4缺基’卞基或芳基基園，其中該取代基類係選自包括鹵素，Ci —cs烷基，鹵素代—Cl — Cs院基’ C3 ·~〔6環院基’齒素代_C3 _C s環烷基，Ci 一 C6烷氧基，鹵素代— Cl 一 Cs烷氧基，C 1 — C6燒基硫，齒素代一Ci — Ce焼基硫’ CN及硝基之一群組；或一 CH2 Site: -C4烷基）3 1其中該類烷基基團經濟部中央標準局員工消費合作社印裝 (請先閱讀背面之注意事項存填寫本頁) 可為相同的或栢異的；或一苯基自由基，其在兩個鄰近的碳原子上經由——0 —C Hz —0-基圃進行單一取代：Rs is halogen; q is 0 '1' 2 '3 or 4; denier η is 1; the conditions are * when X is CH, Υ is 0CH3' Z is 0, R2 is CH3 'R3 and R4 is hydrogen, When R9 is CH3, 11 is 1, and q is Q, '0R is not m-CF3—fluorenyloxy at the p-position; or (f) R is an unsubstituted or mono- or multiple-substituted " ^ —C4 courtyard, — C4 alkyl, 'C2 — C4 deficient' fluorenyl or aryl, wherein the substituents are selected from the group consisting of halogen, Ci — cs alkyl, halogen — Cl — Cs courtyard 'C3 · ~ [6-ring courtyard-based' dentition_C3 _C s cycloalkyl, Ci-C6 alkoxy, halo-Cl-Cs alkoxy, C 1-C6 alkylsulfur, dentin-substituted Ci — Ce 焼 sulfide 'CN and nitro group; or a CH2 Site: -C4 alkyl) 3 1 of which alkyl groups are printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the back first) (Notes on filling out this page) can be the same or different; or a phenyl radical, which is a single substitution on two adjacent carbon atoms via —0 —C Hz —0-base:

Rs為芳基一Q-Ci — Cs烷基*芳基一Q—Cx -C6烯 -29- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）經濟部中央標隼局貝工消費合作社印製 A7 B7 五、發明説明（1) 基，雜環烷基—Q—Ci — 烷基，雜環烷基一 Q - CZ — C 6烯基，或芳基一 Q— h _C6烷基，芳基_C2 — Ce烯基，雜環烷基- Q-Ci —C6烷基或雜環烷基一Q— C2 —（：6 烯基•其在該芳基或雜環烷基環中為軍——至五經取代的，視取代反應的可能性而定*其中該取代基類彼此獨立選自包括鹵素，Ci —Ce烷基，鹵素代一 Ci _ C6烷基，C3 -Cs環烷基，鹵素代一 C3 - Cs環烷基，Ci 一（：6烷氧基鹵素代一h — Cs烷氧基，CN，硝基及Ci -Cs烷氧基羰基之一群组；其中，若q大於1，自由基R5可為相同的或相異的； Q為一直鍵，一CH ( 0H)-; 或-C ( =： 0)-; q為 1，2，3或 4 ; 且η為G或1，其中，當q為2，3或4時，一個或多個自由基Rs亦彼此獨立為Ci -Ce烷基，鹵素代一 Cl -Cs烷基，-Ce環烷基，鹵累代一C3 — C6環烷基，Ci — Cs 院氧基，鹵素代一Ct 一 Cs烷氧基，Ci - c6烷基硫，鹵素代一 Ci 一（：6烷基硫，Ci _C6烧基亞確髓基，鹵素代 -30- 本紙浪尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ----------- {請先閱讀背面之注意事項再填寫本頁) 訂經濟部中央標準局貝工消費合作社印製 4 3 3 9 8 2鐵 μ B7 五、發明説明 -Ci 烷基亞磺醯基，Ci— cs烷基磺醯基，鹵素代 —Ci 一 C6院基碌臨基* Ci — Cs焼氧基—Ci —"Cs踪基，鹵素代一 Ci — Cs烷氧基— Cs烷基，Ci —c6烷基硫—Ci — Cs焼基，齒素代—Ci —C6院基硫_Ci — C s烷基* Ci _CS烷基亞磺醯基一 Ci -Cs烷基，鹵素代 —Ci — C6院基亞礦驢基一 Ci —Cs院基，Ci _Cs焼基磺醯基_Ci —Ce烷基，鹵素代一Ci — cs烷基磺醢基—c 1 — Cs院基，Ci — Cs院基猿基，鹵素代一 Ci _Cs院基顔.基，Ci — Cs烷氧基羰基，鹵素代一 Ci -cs烷氧基羰基I Ci _Cs烷基胺基羰基，Ci — C4烷氧基亞胺基甲基 *二（C! — Cs烷基）胺基羰基，其中烷基基團可為相同的或相異的，Ci — Cs烷基胺基硫羰基，二（Ci —cs烷基）胺基硫羰基，其中該類烷基基團可為相同的或相異的，Cl 一 Cs烷基胺基，二（Cl —cs烷基）胺基，其中該類烷基基團可為相同的或相異的，鹵素，tJ〇2 ，CN，SFs ，硫醯胺基*硫氛醯基甲基，三甲基矽烷基或一 Ci - C4 亞烷基二氣基團；其為未經取代的或單——至四經取代的，其中該類取代基選自包括Ci — c4垸基及鹵素之一群組；或（g) R為C3 — Cs環烷基，鹵素代一 C3 —Cs環烷基或一未經取代的或簞——或多重-經职代之笨基或苄基 -3 1 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂經濟部中央標準局員工消費合作社印製 4 3 39 8 2:^ A7 B7 五、發明説明（>1) 基團，其中該取代基類係選自包括鹵素，Ci — C4烷基及鹵素代—Ci —C4烷基之一群組* Rs為“ —Cs烷基，C i — Cs烷氧基，鹵素代一Ci -Cs烷基或鹵素代—Ci -C 6燒氧基； q為1且η為1，或（h) R為C3 - Cs環烷基一 Ci - C4 烷基或鹵素代一C3 — Cs環烷基一 Ci _C4烷基，R5為C i —Cs烷基，Ci _C6烷氣基，鹵素代一 Ci -Cs烷基或鹵素代一Ci —cs烷氧基； q為1且η為1，或（i) R為甲基*乙基*異丙基或第三一丁基；為（^ —Cs烷基，Ci — Cs烷氧基，鹵素代一C! 一 Cs烷基，鹵素代一 Cl -.Cs烷氧基或鹵素，q為1且η為1 1 或（k) R為η_丙基； β£為Ci —Cs烷基或Ci — 烷氧基； Q為1 ; -32- 本紙ft尺度適用中國國家標準（CNS ) A4規格（210X29?公釐） ---------i本— (請先閲讀背面之注意事項再填寫本頁) 訂 " 經濟部中央標準局員工消費合作社印製 433982璉 A7 B7 五、發明説明（&ϋ) 且η為1 ; 且，當合適時，其可能的Ε/ Ζ異搆物類| Ε/ Ζ異構物混合物類及/或互變異構物類，在各種情況下Κ游離彤式或鹽彤式存在。一些甲氧基丙烯酸衍生物類在文獻中被提出作為除害劑之活性化合物類。然而，這些已知化合物類的生物特性在有害生物控制的領域中並非完全令人滿意的，且為此理由仍有須要提供進一步具有害生物控制特性之化合物類* 特別是針對昆蟲類及蟎目的代表者，且特別是針對植物病原性微生物的控制，此目的可椹據本發明經由提供式（I) 之化合物類而達成0Rs is aryl-Q-Ci — Cs alkyl * aryl-Q-Cx -C6 ene-29- This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) A7 B7 printed by the consumer cooperative V. Explanation of the invention (1) radical, heterocycloalkyl-Q-Ci-alkyl, heterocycloalkyl-Q-CZ-C6 alkenyl, or aryl-Q-h_C6 alkane , Aryl_C2 — Ce alkenyl, heterocycloalkyl- Q-Ci —C6 alkyl or heterocycloalkyl—Q—C2 — (: 6 alkenyl • which is in the aryl or heterocycloalkyl ring Middle-to-five substituted, depending on the possibility of substitution reaction * where the substituents are independently selected from the group consisting of halogen, Ci-Ce alkyl, halogen-Ci_C6 alkyl, C3-Cs ring Alkyl, halo-C3-Cs cycloalkyl, Ci-(: 6alkoxyhalo-h-Csalkoxy, CN, nitro and Ci-Csalkoxycarbonyl group; among them, If q is greater than 1, the radicals R5 may be the same or different; Q is a direct bond, a CH (0H)-; or -C (=: 0)-; q is 1, 2, 3 or 4; and η is G or 1, where one or more are free when q is 2, 3, or 4 Rs is also independently Ci-Ce alkyl, halo-Cl-Cs alkyl, -Ce cycloalkyl, halo-C3-C6 cycloalkyl, Ci-Cs alkyloxy, halo-Ct-Cs alkane Oxygen, Ci-c6 alkylsulfur, halogen-Ci- (6 alkylsulfur, Ci_C6 alkylsulfonyl group, halogen--30 (Mm) ----------- (Please read the notes on the back before filling this page) Order printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 3 9 8 2 Iron μ B7 V. Description of the Invention -Ci alkylsulfinyl, Ci—cs alkylsulfonyl, halogen—Ci—C6—Cycloyl—Ci—Cs alkoxy—Ci— " Cs tracer, halo Ci — Cs alkoxy — Cs alkyl, Ci — c6 alkylsulfide — Ci — Cs fluorenyl, dentino — Ci — C6 alkylsulfur — Ci — C s alkyl * Ci — CS alkylsulfinyl sulfonyl One Ci-Cs alkyl group, halogen-Ci-C6 compound, sulfonyl-Ci-Cs compound, Ci_Cs, sulfosulfanyl group, Ci-Ce alkyl group, halogen-Ci-cs alkylsulfonyl group Base — c 1 — Cs Yuan Ji, Ci — Cs Yuan Ji Yuan, halogen Prime-Ci_Cs-Yan Jiyan.Ci, Ci-Cs alkoxycarbonyl, Halo-Ci-Cs alkoxycarbonyl I Ci_Cs alkylaminocarbonyl, Ci-C4 alkoxyiminomethyl * Di (C! —Cs alkyl) aminocarbonyl, wherein the alkyl groups may be the same or different, Ci—Cs alkylaminothiocarbonyl, bis (Ci—csalkyl) aminothiocarbonyl, Wherein such alkyl groups may be the same or different, Cl-Cs alkylamino, bis (Cl-cs alkyl) amino, where the alkyl groups may be the same or different , Halogen, tJ〇2, CN, SFs, thiocarbamido * thiocarbamylmethyl, trimethylsilyl or a Ci-C4 alkylene digas group; it is unsubstituted or mono- — To four substituted, wherein this type of substituent is selected from the group consisting of Ci—c4fluorenyl and halogen; or (g) R is C3—Cs cycloalkyl, and halogen is a C3—Cs cycloalkyl or An unsubstituted or 箪 ——or multiple-by-generation benzyl or benzyl-3 1-This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back first Refill (This page) Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 4 3 39 8 2: ^ A7 B7 V. Description of the invention (1) Group, where the substituents are selected from the group consisting of halogen, Ci — C4 alkane And halogen-Ci-C4 alkyl group * Rs is "-Cs alkyl, Ci-Cs alkoxy, halogen-Ci-Cs alkyl or halogen-Ci-C 6 alkyl ; Q is 1 and η is 1, or (h) R is C3-Cs cycloalkyl-Ci-C4 alkyl or halogenated-C3-Cs cycloalkyl-Ci_C4 alkyl, R5 is C i -Cs alkyl Group, Ci_C6 alkanoyl group, halo-Ci-Cs alkyl or halo-Ci-cs alkoxy; q is 1 and η is 1, or (i) R is methyl * ethyl * isopropyl Or a third monobutyl group; (^ —Cs alkyl, Ci — Cs alkoxy, halo-C! -Cs alkyl, halo-Cl -.Cs alkoxy or halogen, q is 1 and η Is 1 1 or (k) R is η_propyl; β £ is Ci —Cs alkyl or Ci — alkoxy; Q is 1; -32- The ft dimension of this paper applies the Chinese National Standard (CNS) A4 specification (210X29 ? Mm) --------- i this — (Please read the notes on the back before filling this page) Order " Economy Printed by the Consumer Standards Cooperative of the Central Bureau of Standards 433982 琏 A7 B7 V. Description of the invention (& ϋ) and η is 1; and, when appropriate, its possible E / Z isomers | E / Z isomer mixtures And / or tautomeric species, in each case κ free form or salt form. Some methacrylic acid derivatives have been proposed in the literature as active compounds of pesticides. However, the biological characteristics of these known compounds are not completely satisfactory in the field of pest control, and for this reason there is still a need to provide compounds with further pest control properties * especially for insect and mite Representative, and especially for the control of phytopathogenic microorganisms, this object can be achieved according to the present invention by providing compounds of formula (I).

一些式（I)之化合物類及Μ下定義之式（III)，（ IV)及（VI)化合物含有不對稱碳原子，其意謂該類化合物可Μ光學上活性形式存在。因為C=X及聘亞胺基雙鏈的存在，該類化合物可ME及Z異構物形式存在。該類化合物之 atrop isomer類可進一步發生。式（I) , (III) ，（IV )及（VI)係打算包括所有這些可能的異構性彤式及其混合物類，例如消旋物類或E/Z異構物混合物類，且*當合適時，其鹽類 > 雖然此點並沒有每次特別提到。 -3 3- 本纸張尺度適用中國國家標芈（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂 k 433982¾ A7 B7 五、發明説明p 除非另外有所定義，上文及下文所使用的一般名詞被定義如下。除非另外有所定義，在各種情形下含碳的基團及化合物類含有1M上至8個碳原子*偏好為1K上至6個碳原子，特別是1以上至4個碳原子，尤其是1或2個碳原子。烷基一在本身作為一基圃，或為其他基圃及化合物類，如鹵素代烷基，烷氧基，烷基硫，烷基亞磺醯基，烷基磺醢基，垸基羰基，烷氧基-羰基，烷基胺基，烷氣基亞胺基甲基，烷基胺基羰基及烷基胺基硫羰基之结構元件時，在各種情況下*於相關基團或化合物所含碳原子數目，其隨情況不同而有所不同，之正確考量下：或為直鏈，即甲基*乙基*丙基，丁基，戊基或己基，或為分枝的，例如異丙基，異丁基，第二—丁基，第三一丁基，異戊基，新戊基或異己基。經濟部中央標準局員Η消费合作社印製 (請先閱讀背面之注意事項再填寫本頁) 烯基一在本身作為一基圃，或為其他基團及化合物類，如鹵素代烯基之结構元件時，在各種情況下，於相關基團或化合物所含碳原子數目，其隨情況不同而有所不同，之正確考量下：或為直鏈，例如乙烯基，1一甲基乙烯基，烯丙基’ 1 一丁烯基或2 —己烯基，或為分枝的，例如異丙烯基。 -34- 本紙張尺度適用中國國家標準（CNS ) Α4規格（21 〇 X 297公釐） 4 3 39 823 A7 B7 經濟部中央標準局貝工消費合作杜印製五、發明説明（>公炔基一在本身作為一基圑，或為其他基團及化合物類 ,如鹵素代炔基之结構元件時，在各種清況下’於相關基圃或化合物所含碳原子數目’其随情況不同而有所不同’ 之正確考量下：或為直鋰，例如炔丙基* 2-丁炔基或5 — 己炔基，或為分枝的，例如2 —乙炔基丙基或2 —炔丙基異丙基。 C3 - Cs環烷基為環丙基，環丁基，環戊基或環己基 0 亞烷基-在本身作為一基團，或為其他基團及化合物類，如鹵素代亞烷基之结構元件時，在各種情況下，於相關基團或化合物所含碳原子數目，其隨情況不同而有所不同，之正確考量下：或為直鏈，例如—CH2 CH2 —，一CH 2 CH2 CH2 _ 或— CH2 CHz CH2 CH2 —，或為分枝的，例如一 CH ( CH3 ) - ，一 CH ( C2 Hs ) ， - c ( CH3 ) 2 —， -CH ( CH3 ) CiU —或—CH ( CH3 ) — CH ( CH3 ) ° 芳基為苯基或萘基，特別是笨基。雜環烷基為一具有1至3個雜原子的5-至？一員芳香性或非一芳香性環，雜原子係選自包括》’〇及3之—群組。偏 -3 5 - (請先閱讀背面之注意事項再填寫本頁) i- 訂 •k 本紙張尺度適用中國國家標準（CNS > Α4Ϊ1格（210X297公釐）經濟部中央標準局貝工消費合作社印製 4 3 39 8 2键 A7 B7 五、發明説明（j^) 好為芳香性5—及6—員環，其m括一氮原子作為雜原子且，當合適時，可包含進一步的雜原子，偏好為氮或硫，特別是氮。在自由基8s中偏好的雜芳基自由基為一吡嗪基， _ltl;陡一3' —基，一壯陡一^ —基，一姐陡—4,—基， —唾陡一_基，一喃陡一C —基，—喃陡一基— 暖唑一 2, 一基，—聘唑一 2, —基噻嗯—基，一暖嗯一 3'—基及一暖唯—2’ 一基。鹵素一在本身作為一基圑，或為其他基團及化合物類，如鹵素代院基*鹵素代烯基且鹵素代炔基之結構元件時一為氟，氯，溴或碘，特別是氟，氯或溴，尤其是氟或氮且非常特別為氟。鹵素-經取代之含碳基團及化合物類，如鹵素代烷基，鹵素代烯基或鹵素代炔基，可為部份鹵化的或過鹵化的，且在多重鹵化作用的情形下，鹵素取代基類可為相同的或栢異的。鹵素代烷基的實施例類一在本身作為—基靨’ 或為其他基團及化合物類，如鹵素代烯基之結構元件時— 為甲基，其Κ氟’氯及/或溴進行單--至三取代，如 2或CF3 :乙基，其Μ氣，氯及/或溴進行軍至五取代，如 CH2 CF3 ，CF2 CF3 ，Cl3 ，CFz CHCU ’ 2 CHF2 5 CF2 CFCU ' CFz CHBR2 ' cp2 CHC1F- CF2 CHBrF或CC1FCHC1F;丙基，或異丙棊’其以氣1氯及/或 -36- 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨〇><297公董） (請先聞讀背面之注意事項再填寫本頁) *?τ k_ 4 3 3 9 8 2- a7 B7____ 五、發明説明（多屮溴進行單一-至七取代，如CH2 CHBrCHz Br，CF2 COCf3 ,CH2 CF2 CFs或CH (CF3 ) 2 ;且丁基或其異構物類之一，其以氟，氮及/或溴進行簞一一至九职代，如^ α 3 ) CHFCF3或CH2 ( CFZ ) 2 CF3 。鹵素代烯基為’例如，CH2 CH=CHC1，CHz CH=CCl2 ’ CH2 CF=CF2 或 CH2 CH =CHCH2 Br。鹵素代炔基為，钶如，CHz C三CF , CH2 Ce CCHZ Ci或 CF2 CFz Cs CCBz F °Some of the compounds of formula (I) and compounds of formula (III), (IV) and (VI) as defined below contain asymmetric carbon atoms, which means that such compounds can exist in optically active form. Due to the presence of C = X and imino double chains, these compounds can exist as ME and Z isomers. Atrop isomers of this class of compounds can occur further. Formulas (I), (III), (IV) and (VI) are intended to include all of these possible isomers and mixtures thereof, such as racemates or E / Z isomer mixtures, and * When appropriate, its salts > Although not specifically mentioned at this point. -3 3- This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling out this page) Order k 433982¾ A7 B7 V. Description of invention p Unless otherwise specified Definitions. The general terms used above and below are defined as follows. Unless otherwise defined, carbon-containing groups and compounds contain from 1M to 8 carbon atoms in each case * Preference is from 1K to 6 carbon atoms, especially from 1 to 4 carbon atoms, especially from 1 Or 2 carbon atoms. Alkyl is used as a base in itself, or other bases and compounds, such as haloalkyl, alkoxy, alkylsulfide, alkylsulfinyl, alkylsulfonyl, fluorenylcarbonyl, In the case of structural elements of alkoxy-carbonyl, alkylamino, alkaminoiminomethyl, alkylaminocarbonyl and alkylaminothiocarbonyl groups, in all cases * is included in the relevant group or compound The number of carbon atoms, which varies depending on the situation, under the correct consideration: either straight chain, that is methyl * ethyl * propyl, butyl, pentyl or hexyl, or branched, such as isopropyl Group, isobutyl, second-butyl, third-butyl, isopentyl, neopentyl or isohexyl. Printed by a member of the Central Standards Bureau of the Ministry of Economic Affairs and a Consumer Cooperative (please read the notes on the back before filling out this page). Alkenyl is used as a base in itself, or for other groups and compounds, such as halogenated alkenyl structural elements. In each case, the number of carbon atoms contained in the relevant group or compound will vary from case to case, under the correct consideration: or a straight chain, such as vinyl, 1-methylvinyl, ene Propyl '1-butenyl or 2-hexenyl, or branched, such as isopropenyl. -34- This paper size applies to Chinese National Standard (CNS) A4 specification (21 OX 297 mm) 4 3 39 823 A7 B7 Printed by the Bayer Consumer Cooperation Department of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (> In the case where the radical one itself is a radical, or is a structural element of other groups and compounds, such as a halogenoalkynyl group, under various circumstances, 'the number of carbon atoms contained in the relevant base or compound' is different according to circumstances. But it ’s different. Under the correct consideration: either straight lithium, such as propargyl * 2-butynyl or 5-hexynyl, or branched, such as 2-ethynylpropyl or 2-propargyl Isopropyl. C3-Cs cycloalkyl is cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl 0 alkylene-as a group in itself, or other groups and compounds such as halogenated In the case of alkylene structural elements, the number of carbon atoms contained in the relevant group or compound varies in different cases under different circumstances. The correct consideration is: or a straight chain, such as —CH2 CH2 —, One CH 2 CH2 CH2 _ or — CH2 CHz CH2 CH2 — or branched, such as one CH (CH 3)-, -CH (C2 Hs),-c (CH3) 2 —, -CH (CH3) CiU —or —CH (CH3) — CH (CH3) ° aryl is phenyl or naphthyl, especially benzyl Heterocycloalkyl is a 5- to 6-membered aromatic or non-aromatic ring with 1 to 3 heteroatoms, and the heteroatoms are selected from the group consisting of "0 and 3". Partial -3 5 -(Please read the precautions on the back before filling in this page) i- order • k This paper size applies to Chinese National Standards (CNS > A4Ϊ1 (210X297 mm)) Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 39 8 2 bond A7 B7 V. Description of the invention (j ^) It is preferably aromatic 5- and 6-membered rings, where m includes a nitrogen atom as a hetero atom and, when appropriate, may include further hetero atoms. The preference is Nitrogen or sulfur, especially nitrogen. The preferred heteroaryl radical in radical 8s is a pyrazinyl group, _ltl; a steep 3'- group, a strong and steep ^ group, and a sister steep -4,- Radical, sialo-C, radical, C-base, num-acid, base-Nunazole-2, 1-base, -an-oxazole-2, --- thienium-base, 1-null-3 ' —Base and One Nuanwei—2 Halo—as a radical in itself, or other groups and compounds, such as halogenated alkyl * haloalkenyl and halogenated alkynyl structural elements—fluorine, chlorine, bromine or iodine, Especially fluorine, chlorine or bromine, especially fluorine or nitrogen and very particularly fluorine. Halogen-substituted carbon-containing groups and compounds, such as haloalkyl, haloalkenyl or haloalkynyl, may be Partially halogenated or perhalogenated, and in the case of multiple halogenation, the halogen substituents may be the same or cyano. The example of the halogenated alkyl group is a methyl group when it is used as a radical or other group and compound, such as a structural element of a halogenated alkenyl group, and its fluoro group is chlorine and / or bromine. -To three substitutions, such as 2 or CF3: ethyl, its M gas, chlorine and / or bromine to five substitutions, such as CH2 CF3, CF2 CF3, Cl3, CFz CHCU '2 CHF2 5 CF2 CFCU' CFz CHBR2 ' cp2 CHC1F- CF2 CHBrF or CC1FCHC1F; propyl, or isopropylamidine 'its gas 1 chlorine and / or -36- This paper size applies Chinese National Standard (CNS) A4 specifications (2 丨〇 > < 297 public director ) (Please read the notes on the back before filling in this page) *? Τ k_ 4 3 3 9 8 2- a7 B7____ 5. Description of the invention (Single-to-seven substitution of polyfluorene bromide, such as CH2 CHBrCHz Br, CF2 COCf3 , CH2 CF2 CFs or CH (CF3) 2; and butyl or one of its isomers, which is carried out with fluorine, nitrogen and / or bromine, one to nineteenth generation, such as ^ α3) CHFCF3 or CH2 ( CFZ) 2 CF3. The haloalkenyl group is, for example, CH2 CH = CHC1, CHz CH = CCl2, CH2 CF = CF2, or CH2 CH = CHCH2 Br. Haloalkynyl is, for example, CHz C tri CF, CH2 Ce CCHZ Ci or CF2 CFz Cs CCBz F °

—些式（I)及M下定義之式（贝1) ，（IV)及（VI )化合物類對專家來說為熟習的’其以互麥異構物存在’ 特別是當R7為Η時。上文及下文中式（Π * (III) ’ （ IV)及（VI)化合物因此應被瞭解包括相關之互變異溝物類，雖然後者並沒有在每種情況下均特別提到。經濟部中央標準局負工消費合作社印製 (請先聞讀背面之注意事項再填寫本頁) 至少具有一個鹼性中心的式（I)及Μ下定義之式（ III) ，（IV)及（VI)化合物類可以形成，例如，酸加& 鹽類。酸加成鹽類可與例如*無機性酸類形成，如礦物酸類，例如過氮酸，硫酸，亞硝酸*硝酸*磷酸或一氫鹵酸，或與強烈有機性羧酸類彤成•如Ci —c4烷基羧酸類，其為未經取代的或經由*例如鹵素，加Μ取代，例如乙酸 *如飽和的或不飽和的二羧酸類，例如乙二酸，丙二酸，丁二酸，順丁烯二酸，反丁烯二酸或鈦酸，如羥基羧酸類，例如抗壞血酸，乳酸，malic，酒石酸或樟樣酸，或如苯 -3 7 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 433982缳 B7 _ ，-· ~ …」n —- ' "' — 五、發明説明（歹0 {請先閱讀背面之注意事項再填寫本頁) 甲酸*或與有機性磺酸類形成，如Cl _c4烷一或芳基磺酸類，其為未經取代的或經由*例如鹵素，加Μ取代，例如甲烷—或Ρ—甲苯磺酸。具有至少一個酸性基團之式（I )之化合物類可進而與鹼形成鹽類。與鹼類所形成合適的鹽類為，例如，金屬鹽類，如鹼金属或鹼土金屬鹽類，洌如納，鉀或鎂鹽頚，或與氨或有機性胺彤成的鹽類，如嗎啉基，哌啶，吡咯啶，一種單——，二一或三-低階烷基胺，例如乙基一 *二乙基一，三乙基一或二甲基丙基胺，或一種單——，二—或三羥基一低階烷基胺，例如單-- 經濟部中央標準局員工消費合作社印裝，_二-或三乙醇胺。當合適時，相關的内鹽類可進一步形成，在本發明内容中偏好農化上有利的盥類；然而，本發明亦相關於在農化用途上不利之鹽類，例如對蜜蜂或魚具有毒性的鹽類，其被用於，例如，箪離或純化式（I)之游離化合物類其農化上可使用的鹽類。由於游離形式之式（I )化合物類及其鹽類形式之間的密切關係，上文或下文中式（I)之游離化合物類或其鹽類因此且合適地被理解意諝相關的鹽類或當合適時，分別意諝相關的盥類及式（I)之游離化合物類。同樣的情形亦適用於式（I) ，（II1) ’ (IV)及（VI)之互變異構物類及其鹽類。通常，在所有情況下，偏好游離形式者。在本發明中偏好的具體事實-在各種情形下均考慮上述的條件一為： ~ 3 8 本紙張尺度適用中國國家標準（CNS ) Α4規格（2ίΟΧ 297公釐）經濟部中夬標準局員工消費合作社印製 4339 82 = A7 B7 五、發明説明（)厶） (1) 一種式（I)化合物，其中X為CH ; (2) —種式（I)化合物，其中Y為ORi ，偏好為“ —C2烷氧基*特別是甲氧基； (3) —種式（I)化合物，其中Z為0 ; (4) 一種式（I)化合物•其中Ει為“ _C2烷基； (5) —種式（I)化合物，其中R2為H，Ci -C4烷基，鹵素代一Ci —C4烷基或C3 — Cs環烷基 > 偏好為Ci —C4烷基或齒素代一（W -C4烷基，特別是Ci -C2烷基，尤其是甲基； (6) —種式（I)化合物*其中R3為H，Ci _C4烷基* Ci -C4烷氧基，OH，CN，NOz ，鹵素，鹵素代一 Cl -C4烷基或鹵素代—h — C4烷氧基，偏好為H，Ci —C 4垸基，h — C4烷氧基或鹵素，特別是Η，甲基，甲氧基，氯或氟，尤其是Η ; (Ή 一種式（I)化合物，其中R+為Η，C i — C4烷基，Ci — C4烷氧基，OH，CN，N〇2 *鹵素，鹵素代一 Ci -39- 本紙張尺度適用中國國家標隼（CNS ) A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) :% 4 3 3 9 8 2 A7 B7 五、發明説明一（U烷基或鹵素代—Ci _C4烷氧基，偏好為H，Cl — C 4烷基，Ci _C4垸氧基或鹵素*特別是Η，甲基，甲氧基 •氯或氟，尤其是U ; (8) —種式（I)化合物*其中R8為Η或Ci —C2烷基，偏好為（^ _C2烷基且特別是甲基； (9) 一種式（I)化合物，其中R3為甲基或氟甲基，偏好為甲基； (10) —種式（I)化合物，其中10為0或2*偏好為2; (11) 一種式（I)化合物，其中η為1或2，偏好為1; (12) —種式（I)化合物，其中η為1且q為0 r (13) —種式（I)化合物，其中AR7為乙基，η為1且經濟部中央標準局員工消費合作社印製 ---------裝-- (請先閲讀背面之注意事項再填寫本頁) Q為0 ; (14) 一種式（I)化合物，其中AR 7為甲基，η為0且 q為2 ; (15) —種式（I)化合物，其中G為氧； -4 0 ~ 本紙乐尺度適用中國國家標準（CNS ) Μ規格（210X29?公釐）經濟部中央樣準局負工消費合作.杜印製 4 3 3982^ A7 B7 五、發明説明（>&) (16) —種式（I)化合物’其中η為1且q為1或2;偏好ϋ為1旦q為1 ; (17) —種式（I)化合物*其中A為直鍵’Ci -Ci 〇亞烷基，或鹵素代一 Cl — Cl 0亞烷基*偏好為一直鐽或匕—C4亞烷基，特別是一直鍵或亞甲基*且h為一自由基Εί 1 〇 ; (18) —種式（I)化合物’其中AR7為C! - C4焼基，C3烯基，其選擇性經由Μ加以取代；或“烯基；偏好為甲基或乙基；特別是乙基；特別是甲基*· (19) η為1* q為0，且R為一經取代之芳基—或苄基一基圃，其中該取代基類係選自包括鹵素，“ 一C4烷基，齒素代一 Ci — C4院基，C3 _Ce環综基及虛素代_C3 —— Some of the compounds defined by formulae (I) and M (bei 1), (IV) and (VI) are familiar to the expert as 'there is the presence of the isomers', especially when R7 is Η . The compounds of formulae (Π * (III) '(IV) and (VI) above and below should therefore be understood to include related intervariant species, although the latter is not specifically mentioned in each case. Central Ministry of Economic Affairs Printed by the Standards Bureau Consumer Cooperative (please read the notes on the back before filling out this page) Formulas (I) and (III), (IV), and (VI) with at least one basic center Compounds can be formed, for example, acid addition & salts. Acid addition salts can be formed with, for example, inorganic minerals, such as mineral acids, such as nitrous acid, sulfuric acid, nitrous acid * nitric acid * phosphoric acid, or monohydrohalic acid Or with strong organic carboxylic acids such as Ci-c4 alkyl carboxylic acids, which are unsubstituted or substituted via * such as halogen, plus M, such as acetic acid * such as saturated or unsaturated dicarboxylic acids, For example oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid or titanic acid, such as hydroxycarboxylic acids, such as ascorbic acid, lactic acid, malic, tartaric acid or cinnamolic acid, or such as benzene- 3 7-This paper size applies to China National Standard (CNS) A4 (2 10X297 mm) A7 433982 缳 B7 _,-· ~… "n —- '"' — V. Description of the invention (歹 0 {Please read the notes on the back before filling this page) Formic acid * or organic sulfur Acids are formed, such as Cl_c4 alkanes or arylsulfonic acids, which are unsubstituted or substituted via * such as halogen, plus M, such as methane- or p-toluenesulfonic acid. Formulas having at least one acidic group (I ) Compounds can further form salts with bases. Suitable salts with bases are, for example, metal salts such as alkali metal or alkaline earth metal salts, such as sodium, potassium or magnesium salts, or with Salts formed by ammonia or organic amines, such as morpholinyl, piperidine, pyrrolidine, a mono-, di-, or tri-lower alkylamine, such as ethyl- * diethyl-, triethyl Mono- or dimethylpropylamine, or a mono-, di- or trihydroxy-lower alkylamine, such as mono-, tri- or triethanolamine, printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. When appropriate, related internal salts may be further formed, and in the context of the present invention preference is given to agrochemically advantageous toilets; Furthermore, the present invention is also related to salts which are disadvantageous in agrochemical use, such as salts which are toxic to bees or fish, which are used, for example, to isolate or purify the free compounds of formula (I) and their agrochemicals. The salts which can be used above. Due to the close relationship between the compounds of formula (I) in their free form and their salt forms, the above-mentioned or below-mentioned free compounds of formula (I) or their salts are therefore appropriately understood Meaning related salts or, where appropriate, related toilets and free compounds of formula (I), respectively. The same applies to formulas (I), (II1) '(IV) and (VI) Tautomers and their salts. Usually, in all cases, the free form is preferred. Specific facts preferred in the present invention-the above conditions are taken into account in various situations. One is: ~ 3 8 This paper size applies to China National Standard (CNS) Α4 size (2ί〇 × 297 mm) Employees of the China Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative 4339 82 = A7 B7 V. Description of the invention () 厶) (1) A compound of formula (I), where X is CH; (2) — A compound of formula (I), where Y is ORi, and the preference is " —C2 alkoxy * especially methoxy; (3) —a compound of formula (I) in which Z is 0; (4) a compound of formula (I) • where Em is “—C2 alkyl”; (5) — A compound of formula (I), wherein R2 is H, Ci-C4 alkyl, halogen-Ci-C4 alkyl or C3-Cs cycloalkyl > preference is Ci-C4 alkyl or halo-(- C4 alkyl, especially Ci-C2 alkyl, especially methyl; (6) — compounds of formula (I) * where R3 is H, Ci_C4 alkyl * Ci-C4 alkoxy, OH, CN, NOz , Halogen, halogen-Cl-C4 alkyl or halogen-h-C4 alkoxy, preference is H, Ci-C 4 fluorenyl, h-C4 alkoxy or halogen, especially fluorene, methyl, methyl Oxygen, chlorine or fluorine , Especially Η; (Ή) a compound of formula (I), wherein R + is Η, Ci-C4 alkyl, Ci-C4 alkoxy, OH, CN, No2 * halogen, halogen-Ci-39- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page):% 4 3 3 9 8 2 A7 B7 V. Description of Invention 1 (U Alkyl or halo-Ci_C4 alkoxy, preference is H, Cl-C4 alkyl, Ci_C4 alkoxy or halogen * especially fluorene, methyl, methoxy • chlorine or fluorine, especially U; (8) a compound of formula (I) * wherein R8 is fluorene or Ci-C2 alkyl, preferably (^ _C2 alkyl and especially methyl); (9) a compound of formula (I), wherein R3 is methyl Or fluoromethyl, preference is methyl; (10) — a compound of formula (I), where 10 is 0 or 2 * preference is 2; (11) a compound of formula (I), where η is 1 or 2, preference Is 1; (12) — a compound of formula (I), where η is 1 and q is 0 r (13) — a compound of formula (I), where AR7 is ethyl, η is 1, and employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by Consumer Cooperatives ------------- Please read the Note: Please fill in this page again.) Q is 0; (14) a compound of formula (I), where AR 7 is methyl, η is 0 and q is 2; (15) — a compound of formula (I), where G is Oxygen; -4 0 ~ This paper scale is applicable to the Chinese National Standard (CNS) M specification (210X29? Mm). The work of the Central Sample Bureau of the Ministry of Economic Affairs is responsible for consumer cooperation. Du Yin 4 3 3982 ^ A7 B7 V. Description of the invention (> &) (16)-a compound of formula (I) where η is 1 and q is 1 or 2; preference ϋ is 1 denier and q is 1; (17)-a compound of formula (I) * where A is straight Bond 'Ci-Ci 0 alkylene, or halogenated Cl-Cl 0 alkylene * is preferred to be straight fluorene or d-C4 alkylene, especially straight bond or methylene * and h is a radical Εί 1 〇; (18)-a compound of formula (I) 'where AR7 is C!-C4 fluorenyl, C3 alkenyl, which is optionally substituted through M; or "alkenyl; preference is methyl or ethyl; particularly Is an ethyl group; in particular, methyl * · (19) η is 1 * q is 0, and R is a substituted aryl—or benzyl-based group, wherein the substituent group is selected from the group consisting of halogens, “— C4 alkyl, halogenated Ci—C4 courtyard, C3_Ce ring synthesis Base and virtual prime _C3 —

Cs環烷基之一詳組，或CH2 Si(CH3 ) 3 ，偏好為一經取代的苯基或苄基基團，其中該取代基類係選自包括鹵素，C 1 — C4烷基及鹵素代一h _C4烷氧基之一群組，特別是鹵素甲基及鹵素代甲基，尤其是氛及三氟甲基； (2 0) —種式（I)化合物，其中η為1，g為0且OR在對 -4 1- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X：297公釐） ----------..裝— (請先閱讀背面之注意事項再填寫本頁) 訂丨紙經濟部中央標準局貝工消費合作社印製 4 3 39 8 2讜 A7 B7 五、發明説明G4/) 一位置； (21) —種式（Π化合物，其中A為直鍵’Ci-Ci 〇亞烷基，或鹵素代一 “ 一Ci 〇亞烷基，偏好為直鍵或C i—CU亞烷基，特別是一直鍵或亞甲基；且R7為Ci _C4烷基，其為未經取代的或經由來自包括鹵素之一群組的取代基進行單一一至三取代’ C3 — Cs 環烷基，其為未經取代的或經由來自包括鹵素之一群組的取代基進行單--或二取代，C2 _C4烯基，其為未經取代的或經由來自包括鹵素之一群姐的取代基進行單--或三取代，c2 — c4炔基，其為未經取代的或經由來自包括鹵素之一群组的取代基進行軍--或二取代，—Si (CH3 )3 ，Ci_C4烷氧基羰基，或一芳基基團其為未經取代的或經由來自包括鹵素，Ci — C4烷基及鹵素代—Ci -C 4烷基，偏好為未經取代之Ci 一（：4烷基之一群組的取代基進行單——或二取代，環丙基，其經由來自包括鹵素之一群組的取代基進行二取代，c2 — c3晞基，其其經由來自包括鹵素之一群組的取代基進行二取代，未經取代之C2 — C3缺基’ — Si (CH3 ) 3 ，Ci — C4·燒氧基額基’或~本基基團，其經由來自包括鹵素，Cl -C2烷基及鹵素代-C 1 - c4烷基之一群組之取代基進行二取代，特别是未經取代之Ci _C3烷基，環丙基，其經由氛進行二取代，乙烯基 -42- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） n i n n n 1 n l·. .^r I i— I ϋ T I fi n I] ifr- -5 务 (請先閱讀背面之注意事項再填寫本頁) 經濟部中夬標隼局員工消費合作社印製 43 39 8 A7 B7 五、發明説明（斗D) ，其經由氯進行二取代，雙亞乙基（acetyl enyl)，一 Si ( CB3 ) 3 ，乙氧基羰基或三氟—苯基； (22) —種式（I)化合物，其中A— R7為CH3 ，Rs 為鹵素，Ci _C4烷基，Ci 一（：4烷氧基，鹵素代一Ci — C4院基* C3 — c6環院基或Si (CH3 ) 3 ，偏好為鹵素，One detailed group of Cs cycloalkyl, or CH2 Si (CH3) 3, is preferably a substituted phenyl or benzyl group, wherein the substituents are selected from the group consisting of halogen, C 1 -C4 alkyl and halogenated A group of h _C4 alkoxy groups, especially halogen methyl and halomethyl, especially trifluoro and trifluoromethyl; (2 0)-a compound of formula (I), wherein η is 1, and g is 0 and OR on -4 1- This paper size applies the Chinese National Standard (CNS) A4 specification (210X: 297 mm) ---------- .. installed— (Please read the precautions on the back first (Fill in this page again) Order 丨 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Paper Economy 4 3 39 8 2 谠 A7 B7 V. Description of the invention G4 /) One position; (21) —Specification (II compound, where A A straight bond 'Ci-Ci 0 alkylene, or a halogenated mono- "Ci 0 alkylene, prefers a straight bond or Ci-CU alkylene, especially a straight bond or methylene; and R7 is Ci_C4 Alkyl, which is unsubstituted or single- to tri-substituted through a substituent from one of the groups including halogen, 'C3-Cs cycloalkyl, which is unsubstituted or via one The substituents of the group are mono- or di-substituted, C2-C4 alkenyl, which are unsubstituted or mono- or tri-substituted via a substituent from one of the group including halogen, c2-c4 alkynyl, which Is unsubstituted or is substituted via a substituent from one of the groups including halogens-or disubstituted,-Si (CH3) 3, Ci_C4 alkoxycarbonyl, or an aryl group which is unsubstituted Or mono- or di-substituted via substituents including halogen, Ci-C4 alkyl and halogen-Ci-C4 alkyl, preferably unsubstituted Ci-(: 4 alkyl group), Cyclopropyl, which is disubstituted via a substituent from a group including halogen, c2-c3 fluorenyl, which is disubstituted via a substituent from a group including halogen, unsubstituted C2-C3 A radical '—Si (CH3) 3, Ci — C4 · alkoxy radical' or ~ this radical, which is derived from one of halogen, Cl-C2 alkyl and halogen -C 1-c4 alkyl The substituents of the group are disubstituted, especially the unsubstituted Ci_C3 alkyl group, cyclopropyl group, which is disubstituted via cyano, Alkenyl-42- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) ninnn 1 nl ·.. ^ R I i— I ϋ TI fi n I] ifr- -5 (Please read the back first Please pay attention to this page, please fill in this page) Printed by the Consumers' Cooperatives of the Ministry of Economic Affairs, the Ministry of Economic Affairs 43 39 8 A7 B7 V. Description of the Invention (Dou D), which is disubstituted by chlorine, acetyl enyl, -Si (CB3) 3, ethoxycarbonyl or trifluoro-phenyl; (22)-a compound of formula (I), wherein A-R7 is CH3, Rs is halogen, Ci_C4 alkyl, Ci a (: 4 Alkoxy, halogen substituted Ci—C4 courtyard * C3—c6 ring courtyard or Si (CH3) 3, preference is halogen,

Ci — C2烷基或Ci 一(]4烷氧基，特別是氯，氟*甲基或 Ci -c3烷氧基；尤其是氟，甲基或Ci -c2烷氧基，且其中自由基R5在各種情形下相同的或相異的*特別是相異的 ;且q為2或3，偏好為2;且η為0; (23) —種式（I)化合物，其中A— h為CH3 ，Rs 為C3 — Cs環烷基，鹵素代一C3 - Cs環烷基或Si(CH3 )3 *偏好為C3 — Cs環烷基或Si ( CH3 ) 3 *特別是環丙基或Si ( CH3 ) 3 ，且q為1 ;且η為0 ; (24) —種式（I)化合物，其中A- Η7為CH3 ; β為η 一丙基，η—丁基，第二一丁基，異丁基，C3 - Cs環院基，C，一 C2亞烷基一鹵素代一 C3 - C6環烷基或Si (CK 3)3 ，偏好為η— 丁基，第二一丁基，異丁碁或環戊基；且η為1旦q為0 ; (2 5)—種式（I)化合物，其中X為CH ; Y為C i -43- 本紙張尺度適用中國國家標準^阳丨众私·^。…/]?^^^) I n η ί d n I - n n n li I n n n I (請先閱讀背面之注意事項再填窝本頁) A7 433982巧 B7 五、發明説明（么/) 烷氧基；Z為〇; A為一直键或亞甲基；R2及R9為甲基；R 3及1U為Η ; η為1 ; q為1或2 ; R7為一自由基R丄0 ;兄為一經取代之芳基基團’其中該取代基類像選自包括鹵素，. 甲基且鹵素代甲基之一群组；且βι 〇為Η，未經取代之Ci - C4烷基，環丙基’其經由來自包括鹵素之一群組的取代基進行二取代，C2 — C3烯基，其經由來自包括鹵素之一群組的取代基進行二取代，未經取代之C2 — C3炔基’一 Si ( ch3)3 ，Ci — C4烷氧基羰基，或一苯基基團，其經由來自包括鹵素，Ci —C2烷基及鹵素代一Ci — c4烷基之一群組之驭代基進行單一取代； (2 6) —種式（I)化合物，其中X為CH ; Y為c i 一 C2 烷氧基；Z為0 ; Rz及β9為甲基；Rs及iU為Η ; η為0 ; q 為2; A-R7為CH3 ;且反5為氯，氟，甲基，鹵素代甲基或Ci 一 C4烷氧基；尤其是其中自由基Rs為相異的； (2 7)—種式（I)化合物，其中X為CH ; 丫為C t — C2 烷氧基；Z為0; R2及R9為甲基；R3及1U為Η; π為1; q 為1或2; R為一經取代之苯基或苄基基團，其中該取代基類選自包括氟，氯，溴*甲基及鹵素代甲基之一群組，且Rs 為氣或氯ί (28) —種式（I)化合物*其中η為0，q為1，Q為一 -44- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） .·-^衣訂 ^ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製經濟部中央標隼局員工消費合作社印製 4 3 39 8 2^1 A7 B7 五、發明説明直鍵且ϋ5為苯基一乙基，苯基一乙烯基I雜芳基一乙基或雜芳基一乙烯基，或苯基-乙基•苯基-乙烯基，雜芳基一乙基或雜芳基-乙烯基，其在苯基或雜芳基環中為單一 _至三經取代的，其視取代反應的可能性而定，其中該類取代基彼此獨立選自包括氟，氯，溴，c i 一 c2烷基，鹵素代甲基*甲氧基，鹵素代甲氧基及Ci — C2烷氧基羰基之一群組； (29) —種式（I)化合物，其中A— R7為申基或乙基，11為（：3 — Cs環烷基一CH2 —或鹵素代一 C3 — C3環垸基 —ch2 -，R5為Ci -C2烷基，Ci -c2烷氧基或鹵素且 Q為1且π為1， (30) —種式（U化合物，其中A— R7為CH3 ，R為甲基，乙基，異丙基或第三一丁基；IU為“ —C4烷基， Cl — C4燒氧基，氟或氯；q為1;且11為1; (31) —種式（I)化合物，其中A—R7為CH3 ，R為η —丙基；Rs為Ci 一（：4烷基或Ci 一（：4烷氧基；q為1;且 π為1 ; (3 2) X為 CH ; 丫為 C i 烷氧基；Z為 0 ; Rz 及 R3 為甲基；R3及IU為Κ; η為1; q為1或2; β為亞甲基二氛環 -4 5- 本纸張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） . 裝灯" (請先閲讀背面之注意事項再填寫本頁) A7 433982^ B7 五、發明説明丙基或一經取代之苯基或苄基基團，其中，該取代基類選自包括氟，氯，溴，甲基及鹵素代甲基之一群組；且Rs為氟或氯； (3 3) AR7為甲基或乙基，η為1 ，q為Q，且R為CH2 Si (CH3 ) 3或一經取代之芳基或苄基基團，其中該取代基類係選自包括鹵素，Ci - C4烷基，鹵素代-Ci — C4烷基，C3 — Cs環烷基及鹵素代一 C3 - Cs環烷基之一群組 t (3 6)下式之化合物（la)，其中Ci — C2 alkyl or Ci mono (] 4 alkoxy, especially chlorine, fluoro * methyl or Ci -c3 alkoxy; especially fluorine, methyl or Ci -c2 alkoxy, and wherein the radical R5 In all cases the same or different * especially different; and q is 2 or 3, preference is 2; and η is 0; (23)-a compound of formula (I), wherein A-h is CH3 , Rs is C3-Cs cycloalkyl, halogen substituted C3-Cs cycloalkyl or Si (CH3) 3 * C3-Cs cycloalkyl or Si (CH3) 3 is preferred * especially cyclopropyl or Si (CH3 ) 3, and q is 1; and η is 0; (24)-a compound of formula (I), wherein A- Η7 is CH3; β is η-propyl, η-butyl, second butyl, iso Butyl, C3-Cs cycloalkyl, C, -C2 alkylene-halo-C3-C6 cycloalkyl or Si (CK 3) 3, preference is η-butyl, second butyl, isobutyl碁 or cyclopentyl; and η is 1 denier and q is 0; (2 5) —A compound of formula (I), where X is CH; Y is C i -43- This paper is in accordance with the Chinese national standard ^ 阳丨众Private · ^ .... /]? ^^^) I n η ί dn I-nnn li I nnn I (Please read the notes on the back before filling in this page) A7 433982qiao B7 5 Description of the invention (?) Alkoxy; Z is 0; A is a straight bond or methylene; R2 and R9 are methyl; R 3 and 1U are Η; η is 1; q is 1 or 2; R7 is one Radical R 丄 0; Br is a substituted aryl group, wherein the substituents are selected from the group consisting of halogen, methyl and halomethyl; and βι〇 is Η, unsubstituted Ci-C4 alkyl, cyclopropyl 'which is disubstituted via a substituent from a group including halogen, C2-C3 alkenyl which is disubstituted via a substituent from a group including halogen, without Substituted C2-C3 alkynyl'-Si (ch3) 3, Ci-C4 alkoxycarbonyl, or a phenyl group via a halogen-containing, Ci-C2 alkyl and halogen-Ci-c4 alkyl (2 6) —A compound of formula (I), where X is CH; Y is ci-C2 alkoxy; Z is 0; Rz and β9 are methyl; Rs And iU is Η; η is 0; q is 2; A-R7 is CH3; and trans 5 is chlorine, fluorine, methyl, halomethyl or Ci-C4 alkoxy; especially where the radical Rs is phase Different; (2 7) —formula (I) combination Where X is CH; y is Ct-C2 alkoxy; Z is 0; R2 and R9 are methyl; R3 and 1U are Η; π is 1; q is 1 or 2; R is a substituted phenyl Or benzyl group, wherein the substituents are selected from the group consisting of fluorine, chlorine, bromine * methyl and halomethyl, and Rs is chloro or chloro. (28)-a compound of formula (I) * Η is 0, q is 1, Q is -44- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). ·-^ Ordering (please read the precautions on the back first) (Fill in this page) Printed by the Employees 'Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Monovinyl I heteroaryl monoethyl or heteroaryl monovinyl, or phenyl-ethyl • phenyl-vinyl, heteroaryl monoethyl or heteroaryl-vinyl, which is in phenyl Or heteroaryl ring is single-to-three substituted, depending on the possibility of substitution reaction, wherein these types of substituents are independently selected from each other including fluorine, chlorine, bromine, ci-c2 alkyl, haloformyl Base * methoxy Group, a group of halogenomethoxy and Ci—C2 alkoxycarbonyl; (29) —A compound of formula (I), in which A—R7 is Shen or ethyl, and 11 is (: 3—Cs ring Alkyl-CH2—or halogen-substituted C3—C3 cyclofluorenyl—ch2—, R5 is Ci—C2 alkyl, Ci—c2 alkoxy or halogen and Q is 1 and π is 1, (30) — (U compound, where A-R7 is CH3, R is methyl, ethyl, isopropyl or tertiary butyl; IU is "-C4 alkyl, Cl-C4 alkyloxy, fluorine or chlorine; q is 1; and 11 is 1; (31) —A compound of formula (I), wherein A—R7 is CH3 and R is η—propyl; Rs is Ci— (4 alkyl or Ci— (4 alkoxy) Q is 1; and π is 1; (3 2) X is CH; y is Ci alkoxy; Z is 0; Rz and R3 are methyl; R3 and IU are KK; η is 1; q is 1 Or 2; β is methylene diatom ring-4 5- This paper size is applicable to China National Standard (CNS) A4 size (210 X 297 mm). Install the lamp " (Please read the precautions on the back before filling (This page) A7 433982 ^ B7 V. Description of the invention Propyl or substituted phenyl or benzyl groups, where the substituents are selected from Including fluorine, chlorine, bromine, methyl, and halomethyl; and Rs is fluorine or chlorine; (3 3) AR7 is methyl or ethyl, η is 1, q is Q, and R is CH2 Si (CH3) 3 or a substituted aryl or benzyl group, wherein the substituents are selected from the group consisting of halogen, Ci-C4 alkyl, halo-Ci-C4 alkyl, C3-Cs cycloalkyl and A compound (la) of the formula t (3 6), which is one of the halogenated C3-Cs cycloalkyl groups, wherein

ME標示的C=N雙鐽具有E構形； (37) ( 2- { 2— 〔 4- ( 2，2—二氯一環丙基甲氧基 )—3—氟一苯基]一 2 —甲氧基亞胺基一1 一甲基一亞乙基胺基氧甲基}—苯基）—3 —甲氧基一丙烯酸甲基醋（化合物 1 . 3); -46- 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） /、裝訂级 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作社印裝經濟部中夬標準局員工消費合作社印製 43 39822 at __；_B7_ 五、發明説明（++) (38) 甲氧基亞胺基-(2—【2—甲氧基亞胺基一1 — 甲基一 2— ( 4- ( 3—三氟甲基一苯氧基）一苯基]—亞乙基胺基氧甲基）一苯基）一乙酸甲基酯（化合物2.31); (39) ( 2 - { 2- 〔3，5_ 二氟一4— (3-三氟甲基 -苄基氧）一苯基]—2—甲氧基亞胺基一 1_甲基一亞乙基胺基氧甲基} 一苯基）—3—甲氧基一丙烯酸甲基酯（化合物 1.11); ' (40) 2 —甲氧基亞胺基一2— (2— (2—甲氧基亞胺基一 1—甲基一2— 〔4一（3—三氟甲基一笼氧基）一苯基〕-亞乙基胺基氧甲基）一苯基）-N—甲基一乙醯胺（化合物3 . 31); (4 1) 〔2— （2— { 4- 〔2— (3，5 —雙一三氟甲基 -苯基）一乙基〕—苯基）-2-甲氧基亞胺基一1-甲基一亞乙基胺基氧甲基）一苯基〕一 3_甲氧基一丙烯酸甲基酯（化合物1 5 5 · 6 ); (42) 3 -甲氧基一2— 〔2— (2—甲氧基亞胺基一 1 一甲基一2— (4 — 〔2— (3 —三氟甲基一苯基）一乙基〕一笨基}_亞乙基胺基氧甲基）一苯基〕一丙烯酸甲基酯 (化合物1 5 5 . 7 ); -47- 本紙張尺度適用中國國家標準（CNS ) A4規格（2 10 X 297公釐} H , . . * 訂 H^ (請先閱讀背面之注意事項再填寫本頁} ^33982^ Μ Β7 五、發明説明（<Γ) (43) ( 2— （ 2— 〔 4_ ( 2，2—二氮一環丙基甲氧基 (請先閲讀背面之注意事項再填寫本頁) )—2，5—二氟一苯基]一 2—甲氧基亞胺基一 1 一甲基一亞乙基胺基氧甲基}'—苯基）一 3-甲氧基一丙烯酸甲基酯 (化合物1 . 1 3 ); (44) { 2- { 2- 〔2，5— 二氟一4— (3 -三氟甲基 —苄基氧）~苯基]_2—甲氧基亞胺基一 1 一甲基—亞乙基胺基氧甲基）一苯基）一 3 —甲氧基一丙烯酸甲基酯（化合物1 . 14)； (45) 3 —甲氧基一2- 〔2— （1一 {甲氧基亞胺基一〔4— (3_三氟甲基一苄基氧）_苯基]一甲基）亞丙基胺基氧甲基）-苯基]_丙烯酸甲基酯（化合物1.25); (46) 〔 2— ( 1 - { [4- (4 一氟一苄基氧）一苯基經濟部中央標準局員工消費合作社印製〕—甲氧基亞胺基—甲基} 一亞丙基一胺基氧甲基）-苯基〕—3 -甲氧基一丙烯酸甲基酯（化合物1.66)； (47) 〔 2(2— { 4- 〔2— （2*4—二氯苯基）一乙基]—苯基）_2—甲氧基亞胺基一 1—甲基一亞乙基—胺基氧甲基）—苯基〕-3—甲氧基一丙烯酸甲基酯（化合物 155.3); _ 4 8 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 △33982缝 B7 五、發明説明（你） (48) (2— {2— [4— (4 —溴一苯氧基）_ 苯基〕 —2_甲氧基亞胺基一1—甲基一亞乙基一胺基氧甲基} 一苯基）一3 —甲氧基一丙烯酸甲基酯（化合物1.41) ; (49) { 2- { 2 - 〔2—氟一 4— (3—三氟甲基一苄基氧）一苯基]一 2—甲氧基亞胺基一 1 一甲基一亞乙基胺基氧甲基} 一苯基）—3 -甲氧基一丙烯酸甲基酯（化合物 1.7)； (50) ( 2— （ 2—烯丙基氧亞胺基一 1一甲基-2— 〔 4 一（3—三氟甲基一苄基氧）一苯基〕一亞乙基一胺基氣甲基}—苯基）一 3 —甲氧基—丙烯酸甲基酯（化合物4.4) (5 1) ( 2- ( 2-乙氧基亞胺基—1一甲基一 2— [ 4 — (3—三氟甲基一苄基氧）一苯基]一亞乙基一胺基氧甲基 }-笨基）一3 -甲氧基一丙烯酸甲基酯（化合物4.5); (52) 3 一甲氧基一2— (2— {1—甲基一 2 —丙一2- 炔基氧亞胺基—2— 〔4一（3-三氟甲基一苄基氧）一苯基〕_亞乙基胺基氧甲基}_苯基）一丙烯酸甲基酯（化合物 4.6)； -49- 本紙張尺度適用中國國家標孪（CNS ) Α4规格（210X297公釐） -裝 it 訂 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製經濟部中央標準局員工消費合作社印装 433982 璉 a? B7 五、發明説明（少7) (53) ( 2— { 2- 〔 4— ( 2，2—二 Μ —環丙基甲氧基 )—2—氟一笨基〕一2—甲氧基匪胺基—1一甲基一亞乙基胺基氧甲基} 一苯基）—3 —甲氧基一丙烯酸甲基酯（化合物 1 . 9); (54) {2- 〔4一（4 —溴一苯氧基）一苯基]—2- 甲氧基亞胺基一1一甲基一亞乙基一胺基氧甲基} 一苯基）一甲氧基亞胺基—乙酸甲基酯（化合物2.28)； (55) ( 2- [ 2_ 〔 4— ( 3—氯一苯氧基）_ 笨基〕 —2 —甲氧基亞胺基—1 一甲基一亞乙基—胺基氧甲基）一笨基）—3 —甲氧基一丙烯酸甲基酯（化合物1.36); (56) ( 2- （ 2— 〔 4— ( 4—第三一丁基一苄基氧） -苯基〕一2-甲氧基亞胺基一 1—甲基一亞乙基—胺基氧甲基}_苯基）一 3 —甲氧基—丙烯酸甲基酯（化合物1.28 )； (57) ( 2— { 2— 〔 4一（ 4一氟一苄基氧）一苯基〕一 1—甲基一 2—丙一 2_炔基氧亞胺基一亞乙基一胺基氧甲基茏基）—3 -甲氧基一丙烯酸甲基酯（化合物4.21) 本紙張尺度適用中國國家標準{ CNS ) Α4規格（210Χ297公釐） (請先閱讀背面之注意事項再填寫本頁) 、-° '線 43398212 A 7 B7 五、發明説明（¢/) (58) ( Z— { 2-乙氧基亞胺基—2— 〔 4— ( 4—氟一苄基氧）一苯基]—1一甲基一亞乙基一胺基氧甲基）一苯基）一3—甲氧基一丙烯酸甲基酿（化合物4.24)； (59) 甲氧基亞胺基一(2— （1-甲基-2—丙一 2 — 炔基氧亞胺基一2— 〔4_ (3 —三氟甲基一苄基氧）一苯基〕一亞乙基胺基氧甲基）一苯基）一乙酸甲基酯（化合物 4.18)； (60) ( 2 — ( 2— 丁氧基亞胺基—1 —甲基—2 - 〔 4- (3—三氟甲基—苄基氧）_苯基]一亞乙基一胺基氧甲基 }—苯基）—3-甲氧基一丙烯酸甲基酷（化合物4.15); (61) ( 2- { 2— 〔 4— 〔 4一氯一苯氧基）一苯基] —2 —乙氧基亞胺基一1_甲基一亞乙基一胺基氧甲基} 一苯基）一3—甲氧基一丙烯酸甲基酯（化合物4.20); (62) (2— 〔2- (4—異丁氧基一苯基）一 2 -甲氧基胺基一1一甲基一亞乙基胺基氧甲基〕一苯基）一3 —甲氧基一丙烯酸甲基酯（化合物1.31); (63) { 2 — 〔2- （2— 氣一4 一丙氧基—策基）一2- -51- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） - n^i K i ί ί I - > i^n^i 1r ^^^1 ^^^1 il-i ^ J. i l_ i·— 1 *i^n ^ US-5务 {請先閱讀背面之注意事項再填寫本頁) 經濟部中央標华局員工消費合作社印製經濟部中央標準局員工消費合作社印製 4 3 3 9 8 2 a7 B7 五 '發明説明（kp 甲氧基亞胺基_1_甲基一亞乙基—胺基氧甲基〕—苯基） —3 -甲氧基一丙烯酸甲基酯（化合物1·63); (64) (2— { 2-乙氧基亞胺基一 1 一甲基一2— 〔4- (4—三氟甲基一苄基氧）_苯基〕一亞乙基一胺基氧甲基 )—苯基）—3—甲氧基—丙烯酸甲基酯（化合物4.25); (65) ( 2—乙氧基亞胺基一1—甲基一 2— [ 4— （ 4一三氟甲基一苄氧基）一苯基〕-亞乙基一胺基氧甲基）一苯基）一甲氧基亞胺基一乙酸甲基酯（化合物4.2 6); (66) (2— { 2—乙氧基亞胺基一 1 一甲基一2 — 〔4 — (4 —三氟甲基一予基氧）一苯基〕一亞乙基一胺基氧甲基 } _苯基）一2 —甲氧基亞胺基_Ν_甲基一乙醯胺（化合物 4 _ 27) _ ; (67) ( 2—乙氧基亞胺基一 1一甲基一 2— 〔 4一（ 2 — 三氟甲基一苄基氧）—苯基]一亞乙基一胺基氧甲基} 一苯基）一甲氧基亞胺基-乙酸甲基酯（化合物4.28); (68) ( 2— { 2—乙氧基亞胺基一1—甲基一 2— 〔 4一 (2—三氟甲基一苄基氧）一苯基]一亞乙基一胺基氧甲基 } 一苯基）_2—甲氧基亞胺基一Ν —甲基一乙醢胺（化合 -5 2- 本紙承尺度適用中國國家榡準（CNS ) Α4規格（210X 297公釐） n I— n fi IK It .^1 i I n t _ _I T ---- - —1 i,r (請先閱讀背面之注意事項再填寫本頁) A7 433982」 B7 五、發明説明（上〇) 物 4.2 9); (69) ( 2— （ 2—乙氧基亞胺基一1 —甲基—2— 〔 4一 (3 —三氟甲基—苯氧基）一苯基]—亞乙基一胺基氧甲基 } 一苯基）一3—甲氧基一丙烯酸甲基酯（化合物4.32); (70) { 2— 〔 4- ( 4—氛一苯氧基）一苯基]一 2 — 乙氣基亞胺基一1 一甲基一亞乙基一胺基氧甲基}—苯基） -甲氧基亞胺基一乙酸甲基酯（化合物4.68); (71) ( 2 - （ 2- 〔 4_ ( 4一氯一苯氧基）_ 苯基] —2 —乙氧基亞胺基—1 一甲基_亞乙基一胺基氧甲基} 一苯基）一 2—甲氧基亞胺基一 N—甲基一乙醯胺（化合物 4.70); (72) {2— 〔4一（3，4一二氯 ~~ 苯氧基）一苯基〕 —2—乙氧基亞胺基一 1 一甲基—亞乙基—胺基氧甲基}苯基）-甲氧基亞胺基一乙酸甲基酯（化合物4.71); (73) (2- (2- 〔4一（3，4 —二氯一苯氧基）一苯基]—2—乙氧基胺基一 1 一甲基一亞乙基一胺基氧甲基） -苯基）-3—甲氧基一丙烯酸甲基酯（化合物4.72); -5 3- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (I - - ! fi - 1, 、士氏--I In - 1^1 T n _ _ _ ft » (請先閱讀背面之注意事項再填窝本頁) 經濟部中央標準局員工消費合作社印製 433982^ A7 B7 五、發明説明㊉丨） (74) ( 2 — { 2— [ 4— ( 3，4—二氮一苯氧基）—苯基〕一 2—乙氧基亞胺基一 1—甲基一亞乙基一胺基氧甲基 }—苯基）一 2 —甲氧基亞胺基一N —甲基一'乙醯胺（化合物 4 . 73); (75) ( 2— （ 2—乙氧基亞胺基—1 —甲基一2— 〔 4一 (4 一三氟甲基一苯氧基）一笨基〕一亞乙基一胺基氧甲基 )一笨基）一 2-甲氧基亞胺基—N —甲基-乙醯胺（化合物 4 . 146); (76) ( 2— { 2-乙氧基亞胺基一1 -甲基一 2— [ 4 — (4~三氟甲基一苯氧基）一苯基]一亞乙基一胺基氧甲基 )一苯基）一 2 —甲氧基亞胺基一 ίί -甲基—乙醯胺（化合物 4 ‘ 1 4 4 ); (77) ( 2 —乙氧基亞胺基一1 —甲基一2- 〔4- (4 — 三氟甲基一笨氧基）—苯基〕一亞乙基一肢基氧甲基）一苯基）一甲氧基亞胺基—乙酸甲基酯（化合物4.141); (78) (2— (2 — 〔4— (4 一氣—τ 基氧）一苯基] —2-乙氧基亞胺基一 1一甲基一亞乙基一胺基氧甲基]— 苯基）—3—甲氧基一丙烯酸甲基酯（化合物4.SS); -54- 本紙浪尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) '11 L·^ 經濟部t央標率局員工消費合作社印製經濟部中央標隼扃員工消費合作杜印装ME = C = N bisfluorene has E configuration; (37) (2- {2— [4- (2, 2-dichloro-cyclopropylmethoxy) — 3-fluoro-phenyl] — 2 — Methoxyimino- 1-methyl-ethylideneaminooxymethyl} -phenyl) -3 -methoxy-methacrylic acid methyl vinegar (compound 1.3); -46- applicable to this paper size China National Standard (CNS) A4 specification (210X297 mm) /, binding grade (please read the precautions on the back before filling this page) Printed by the Ministry of Economic Affairs, the Central Consumers ’Cooperatives Consumer Cooperatives Printed by the Ministry of Economics, the China Standards Bureau ’s Consumer Cooperatives Printed 43 39822 at __; _B7_ V. Description of the invention (++) (38) Methoxyimino- (2— [2-methoxyimino-1—methyl—2— (4- ( 3-trifluoromethyl monophenoxy) monophenyl] -ethyleneaminooxymethyl) monophenyl) monoacetic acid methyl ester (compound 2.31); (39) (2-{2- [3 , 5_difluoro-4- (3-trifluoromethyl-benzyloxy) -phenyl] -2-methoxyimino- 1-methyl-ethyleneaminooxymethyl} monophenyl ) —3-Methoxy Monoacrylate (Compound 1.11); '(40) 2 —Formyl Imino-2- (2 -— (2-methoxyimino-1-methyl-2— [4-((3-trifluoromethyl-cageoxy) -phenyl]]-ethylene Aminooxymethyl) monophenyl) -N-methylmonoethylammonium (Compound 3. 31); (4 1) [2— (2— {4- [2— (3, 5 —bis one three Fluoromethyl-phenyl) monoethyl] -phenyl) -2-methoxyimino-1-methylmonoethyleneaminooxymethyl) -phenyl] -3-methoxy-1 Methyl acrylate (compound 1 5 5 · 6); (42) 3 -methoxy- 2— [2— (2-methoxyimino- 1 —methyl — 2 — (4 — [2— (3-trifluoromethyl monophenyl) monoethyl] monobenzyl} _ethyleneaminooxymethyl) monophenyl] monoacrylate (compound 15.5. 7); -47- This paper size applies to Chinese National Standard (CNS) A4 specifications (2 10 X 297 mm) H,.. * Order H ^ (Please read the precautions on the back before filling this page} ^ 33982 ^ Μ Β7 V. Description of the invention (&Lt; Γ) (43) (2— (2— [4_ (2,2-diaza-cyclopropylmethoxy) (Please read the precautions on the back before filling this page)) —2, 5-difluoromonophenyl] -2-methoxyimino- 1-methyl-ethyleneiminooxymethyl} '-phenyl)-3-methoxy monomethyl acrylate (compound 1. 1. 3); (44) {2- {2- [2,5-difluoro-1 4- (3-trifluoromethyl-benzyloxy) ~ phenyl] _2-methoxyimino-1 1 monomethyl-ethyleneaminooxymethyl) monophenyl)-3-methoxy monomethyl acrylate (compound 1. 14); (45) 3- methoxy mono 2- [2- (1- (methoxymethoxyimino- [4- (3-trifluoromethyl-benzyloxy) _phenyl] monomethyl) propyleneaminooxymethyl) -phenyl] -methacrylic acid Ester (compound 1.25); (46) [2— (1-{[4- (4 monofluoro-benzyloxy) -phenyl printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs]-methoxyimino —Methyl} monopropylene monoaminooxymethyl) -phenyl] -3-methoxymethyl acrylate (compound 1.66); (47) [2 (2— {4- [2— ( 2 * 4-dichlorophenyl) monoethyl] -phenyl) -2-methoxyimino-1-methylmonoethylene-aminooxymethyl) -phenyl] -3-methoxy Methyl monoacrylate (compound 155.3); _ 4 8-This paper size applies to the Chinese National Standard (CNS) A4 (210X297 mm) A7 △ 33982 seam B7 V. Description of the invention (you) (48) (2— {2- [4- (4-bromomonophenoxy) _phenyl] 2-2-methoxyimino-1-methyl-ethylene-amino-oxymethyl} monophenyl) -3 —Methoxy monoacrylate (Compound 1.41); (49) {2- {2-[2-Fluoro-4— (3-trifluoromethyl-benzyloxy) -phenyl] —2-methyl Oxyimino- 1-methyl-ethylene-aminoamine oxymethyl} monophenyl) -3 -methoxy-monomethyl acrylate (compound 1.7); (50) (2— (2-ene Propyloxyimino- 1-methyl-2— [4-((3-trifluoromethyl-benzyloxy) -phenyl] -ethylene-amino-aminomethyl} -phenyl) -3 —Methoxy-Methyl Acrylate (Compound 4.4) (5 1) (2- (2-ethoxyimino-1—methyl—2— [4 — (3-trifluoromethyl-benzyl) Oxygen) monophenyl] monoethylene monoamino oxymethyl} -benzyl) 3 3-methoxy monomethyl acrylate (combination物 4.5); (52) 3 monomethoxy-2- (2- (1-methyl-1 2-propan-2-ynyloxyimino-2— [4-tri (3-trifluoromethyl-1 Benzyloxy) monophenyl] _ethyleneaminooxymethyl} _phenyl) monoacrylate (compound 4.6); -49- This paper size applies to China National Standard (CNS) A4 specification (210X297 (Mm)-Binding (please read the notes on the back before filling out this page) Printed by the Central Consumers' Cooperative of the Ministry of Economic Affairs, printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economics, printed by 433982 琏 a? B7 V. Description of the invention ( Less 7) (53) (2— {2- 〔4— (2,2-Di M —cyclopropylmethoxy) 2 —fluoro-benzyl] 2 —methoxymethoxyamine — 1 — Methyl-ethylideneaminooxymethyl} monophenyl) -3 -methoxy monomethyl acrylate (compound 1.9); (54) {2- [4-a (4-bromo-phenoxy) Group) monophenyl] -2-methoxyimino- 1-methyl-ethylene-amino-oxymethyl} monophenyl) monomethoxyimino-methyl acetate (compound 2.28 ); (55) (2- [2_ 〔4— (3-chloro-phenoxy) _ stupid ] —2 —methoxyimino-1 monomethylmonoethylene-aminooxymethyl) 1-benzyl) —3-methoxymonomethyl acrylate (compound 1.36); (56) ( 2- (2- [4- (4-Third-butyl-benzyloxy) -phenyl] -2-methoxyimino-1-methyl-ethylene-aminooxymethyl} _Phenyl) 3-methoxy-methyl acrylate (compound 1.28); (57) (2- {2-— [4-((4-fluoro-benzyloxy) -phenyl]-1-methyl One 2-propane-2_alkynyloxyimino-ethylene-amino-oxymethylfluorenyl group) 3 -methoxy-methyl methacrylate (compound 4.21) This paper size applies to Chinese National Standards {CNS ) Α4 specification (210 × 297 mm) (Please read the precautions on the back before filling out this page),-° 'Line 43398212 A 7 B7 V. Description of the invention (¢ /) (58) (Z— {2-ethoxy Imino-2— [4- (4-fluoro-benzyloxy) -phenyl] -1-methyl-ethylene-amino-oxymethyl) -phenyl) -3-methoxy-acrylic acid Methyl alcohol (compound 4.24); (59) methoxyimino- (2- (1-methyl -2-propane 2-alkynyloxyimino group 2-[4- (3-trifluoromethyl-benzyloxy) -phenyl] -ethyleneaminooxymethyl) -phenyl)- Methyl acetate (compound 4.18); (60) (2 — (2-butoxyimino-1-methyl-2-[4- (3-trifluoromethyl-benzyloxy) _phenyl ] -Ethylene-monoaminooxymethyl} -phenyl) -3-methoxy-monomethyl methacrylate (compound 4.15); (61) (2- {2— [4— [4 -chloro-benzene (Oxy) monophenyl] -2 -ethoxyimino- 1-methyl-ethylene-amino-oxymethyl} mono-phenyl)-3-methoxy-methyl acrylate (compound 4.20 ); (62) (2- [2- (4-isobutoxy-phenyl) -2-methoxyamino- 1-methyl-ethyleneaminooxymethyl] -phenyl)- 3-Methoxy-monomethyl acrylate (compound 1.31); (63) {2 — [2- (2-—Gas 4—Propoxy—Ceryl) — 2—51- This paper size applies to China Standard (CNS) A4 Specification (210X297 mm)-n ^ i K i ί I-> i ^ n ^ i 1r ^^^ 1 ^^^ 1 il-i ^ J. i l_ i · — 1 * i ^ n ^ US-5 business {Please read the notes on the back before filling this page) Printed by the Central Consumers 'Cooperative of the Ministry of Economic Affairs and printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economics and printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 3 9 8 2 a7 B7 Imino_1_methylmonoethylidene-aminooxymethyl] -phenyl) —3-methoxy monomethyl acrylate (compound 1.63); (64) (2— {2 -Ethoxyimino- 1-methyl- 2— [4- (4-trifluoromethyl-benzyloxy) _phenyl] -ethylene-aminoiminooxymethyl) —phenyl) — 3-methoxy-methyl acrylate (compound 4.25); (65) (2-ethoxyimino- 1-methyl- 2— [4— (4-trifluoromethyl-benzyloxy) (Monophenyl) -ethylidene monoaminooxymethyl) monophenyl) monomethoxyimino monoacetic acid methyl ester (compound 4.2 6); (66) (2- {2-ethoxy Amino- 1-methyl- 2-[4- (4-trifluoromethyl-l-oxyl) -phenyl] -ethylene-amino-aminomethyl} -phenyl) -2 -methoxy Imino_N_methylmonoacetamide (compound 4-27); (67) (2-ethoxyimino 1-methyl-1 2- [4-((2-trifluoromethyl-benzyloxy) -phenyl] -ethylene-aminoaminomethyl} monophenyl) -methoxyimino-acetic acid Methyl ester (compound 4.28); (68) (2- {2-ethoxyimino-1-methyl- 2-— [4-((2-trifluoromethyl-benzyloxy) -phenyl] Monoethylene monoaminooxymethyl} monophenyl) _2-methoxyimino-N-methyl monoethylamine (Chemical-5 2- This paper bears the standard applicable to China National Standards (CNS) Α4 Specifications (210X 297mm) n I— n fi IK It. ^ 1 i I nt _ _I T -----—1 i, r (Please read the notes on the back before filling this page) A7 433982 ”B7 V. Description of the invention (above) Product 4.2 9); (69) (2— (2-ethoxyimino-1—methyl-2— [4— (3-trifluoromethyl—phenoxy) ) -Phenyl] -Ethylene-Aminooxymethyl} -Phenyl) -3-Methoxy Monoacrylate (Compound 4.32); (70) {2— [4- (4-— (Phenoxy) monophenyl]-2-ethylamino imino-1-methyl monoethylidene monoamino oxymethyl}-phenyl)-methoxy Aminomonoacetic acid methyl ester (compound 4.68); (71) (2-(2- [4_ (4 -chloro-phenoxy) _phenyl]-2 -ethoxyimino-1 monomethyl _Ethylene monoaminooxymethyl} monophenyl) a 2-methoxyimino mono N-methyl monoethylamine (compound 4.70); (72) {2— [4 一 (3, 4-dichloro ~~ phenoxy) monophenyl] 2-ethoxyimino-1 monomethyl-ethylene-aminooxymethyl} phenyl) -methoxyimino Methyl acetate (compound 4.71); (73) (2- (2- [4-((3,4-dichloro-phenoxy) -phenyl]]-2-ethoxyamino- 1-methyl Monoethylene monoaminooxymethyl) -phenyl) 3-methoxy monomethyl acrylate (compound 4.72); -5 3- This paper size applies to Chinese National Standard (CNS) A4 (210X297) (%) (I--! Fi-1,, Shishi --I In-1 ^ 1 T n _ _ _ ft »(Please read the precautions on the back before filling in this page) Employees of the Central Bureau of Standards, Ministry of Economic Affairs Printed by the cooperative 433982 ^ A7 B7 V. Description of the invention ㊉丨) (74) (2 — {2— [4— (3,4—diaza-phenoxy) —Phenyl] —2-ethoxyimino-1-methyl-ethylene-amino-oxymethyl} —phenyl) -2-methoxyimino—N—methyl-'ethyl Sulfonamide (compound 4. 73); (75) (2- (2-ethoxyimino-1-methyl-1 2- [4-tri (4-trifluoromethyl-phenoxy) -benzyl ] Ethylene-amino-aminomethyl) -benzyl) -2-methoxyimino-N-methyl-acetamidine (compound 4.146); (76) (2— {2- Ethoxyimino- 1-methyl- 2— [4 — (4-trifluoromethyl-phenoxy) -phenyl] -ethylene-aminoiminooxymethyl) -phenyl) -2 —Methoxyimino—L-methyl—acetamidine (Compound 4 ′ 1 4 4); (77) (2 —Ethoxyimino—1-methyl—2- [4- (4 — Trifluoromethyl-monobenzyloxy) -phenyl] -ethylidene-methyloxymethyl) -phenyl) -methoxyimino-methyl acetate (compound 4.141); (78) ( 2— (2 — [4 -— (4-Gas—τoxy) -phenyl]] —2-ethoxyimino—1-methyl-ethylene-aminooxymethyl] —phenyl) — 3-methoxy Methyl Acrylate (Compound 4.SS); -54- This paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) '11 L · ^ Printed by the Ministry of Economic Affairs and the Central Bureau of Staff Consumer Cooperatives. Printed by the Ministry of Economic Affairs.

4 3 3 9 8 2」 AV B7 五、發明説明 (79) (2~ [2 — 〔4— (4 一溴一苯氧基）一苯基] 一 2—乙氧基亞胺基一 1 一甲基一亞乙基—胺基氧甲基）一苯基）-3-甲氧基一丙烯酸甲基酯（化合物4.33); (8〇) ( 2— { 2— 〔 4— ( 4一第三一丁基—笨氧基）一苯基1— 2 —乙氧基亞胺基~1 一甲基一亞乙基—胺基氧甲基} 一苯基）一 3 —甲氧基-丙烯酸甲基酯（化合物4.55) > (81) [ 4—異丁氧基一苯基]—2—甲氧基亞胺基一 1 一甲基一亞乙基胺基氧甲基）一苯基）一3—甲氣基一丙烯酸甲基酷（化合物1.31); (82) 〔 4~氟一 2—甲基一苯基〕_ 2-甲氧基亞胺基 —1—甲基一亞乙基胺基氧甲基} 一苯基）一 3 —甲氧基— 丙嫌酸甲基酷（化合物1.51)； (83) 〔 2 -氟一 4 一甲基一苯基]一 2 —甲氧基亞胺基 —1—甲基一亞乙基胺基氧甲基} 一苯基）一 3~甲氧基一丙烯酸甲基酯（化合物1.57); (84) 〔 4—環戊基氧—苯基]一 2 -甲氧基亞胺基一1 —甲基一亞乙基胺基氧甲基} 一苯基）一3—甲氧基一丙烯 -55- 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） ---------;裝------1T------4 (請先聞讀背面之注意事項再填寫本頁) A7 4 3 3982^ _B7 五、發明説明（rj) 酸甲基酯（化合物1 . 6 2 ); (85) 〔 2—氟—4— η-丙基氧—苯基]一 2—甲氧基亞胺基—1 一甲基一亞乙基一胺基氧甲基} 一苯基）—3 — 甲氧基-丙烯酸甲基酯（化合物1,63); (86) [ 2—甲基一4一 η—丙氧基一苯基]_ 2—甲氧基亞胺基一 1一甲基一亞乙基—胺基氧甲基）一苯基）一3 -甲氧基一丙烯酸甲基酯（化合物1.64); (87) 〔2—氟—4一乙氧基一笨基]一2_甲氧基亞胺基一 1—甲基一亞乙基胺基氧甲基}—苯基）一3—甲氧基一丙烯酸甲基酯（化合物1.70); (88) 〔 2—氟一4 _甲氧基一苯基]一 2—甲氧基亞胺基—1_甲基一亞乙基胺基氧甲基）一苯基）一3 —甲氧基 —丙烯酸甲基酷（化合物1.72); (89) 〔 4一乙氣基一 2—甲基—苯基]一 2-甲氧基亞胺基一 1一甲基一亞乙基胺基氧甲基）一苯基）一 3—甲氧基一丙烯酸甲基酯（化合物1.79)； (90) 2—甲氧基亞胺基_ (2— {2—甲氧基亞胺基一 -56- 本紙張尺度適用中國國家標牟（CNS ) A4規格（210 X 297公釐） --------裝------ix------ .飨 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印製經濟部中央標隼局員工消費合作社印製 433982」 A7 B7 五 '發明説明（0) 1—甲基一 2 — 〔4—異丁氧基）一苯基]一亞乙基一胺基氧甲基} 一苯基）一乙酸甲基酯（化合物2.22); (91) 2 —甲氧基亞胺基—（2 — （2—甲氧基亞胺基一 1—甲基—2— 〔4_n—丙氧基一苯基〕一亞乙基胺基氧甲基}—苯基）一乙酸甲基酯（化合物2·23); (92) 2 —甲氧基亞胺基一（2— {2 —甲氧基亞胺基— 1 一甲基一 2— 〔4 一氟_2—甲基—苯基} 一亞乙基胺基氧甲基）—苯基）—乙酸甲基酯（化合物2.35); (93) 2—甲氧基亞胺基一（2- {2—甲氧基亞胺基一 1 一甲基~2— 〔2—氟-4 一甲基一苯基]-亞乙基胺基氧甲基）一苯基）一乙酸甲基酯（化合物2.39); (94) 2—甲氧基亞胺基一（2— (2-甲氧基亞胺基一 1一甲基—2— 〔4 一環戊基氧一苯基〕—亞乙基胺基氧甲基 }-苯基）一乙酸甲基酯（化合物2·44); (35) 2—甲氧基亞胺基一（2— ί2—甲氧基亞胺基一丨―甲基一 2一〔 2—氟一4_ η—丙氧基~苯基]一亞乙基胺基氧甲基）一苯基）一乙酸甲基酯（化合物2·45)；本紙張尺度適用中國國家標辛（CNS ) Α4規格（2! Ο X 297公釐） / 扣衣訂 .. 叙 (請先聞讀背面之注意事項再填寫本頁) 4 3 39 8 A7 B7 五、發明説明（θ) (36) 2-甲氧基亞胺基一（2— ί2—甲氧基亞胺基一 1-甲基—2— [2—甲基一 4— η—丙氧基一笨基]—亞乙基胺基氧甲基}—苯基）_乙酸甲基酯（化合物2.46); (9 7) 2 —甲氧基亞胺基一（2 - ( 2 _甲氧基亞胺基— 1—甲基—2— 〔2—氟一 4 一乙氧基一苯基]—亞乙基胺基氧甲基）-苯基）—乙酸甲基酯（化合物2.4 9)， (98) 2—甲氧基亞胺基一（2— {2—甲氧基亞胺基— 1—甲基一 2— 〔2—氟一 4 一甲氧基一苯基}· 一亞乙基鞍基氧甲基}—笨基）一乙酸甲基酯（化合物2.52); (99) 2-甲氧基亞肢基一（2- {2—甲氧基亞胺基一 1—甲基一2 — 〔4— H —乙氧基一 2 —甲基一苯基]—亞乙基胺基氧甲基} 一苯基）一乙酸甲基酯（化合物2.59); (100) 2—甲氧基亞胺基一 2— (2— {2—甲氧基亞胺基一 1一甲基一 2— 〔4—異丁氧基一苯基]一亞乙基胺基氧甲基）一苯基）—Ν —甲基一乙醯胺（化合物3·22); (1 Q 1) 2 —甲氧基亞胺基一 2 — （ 2 — [ 2 —甲氧基亞胺基一1-甲基一2- 〔4- η-.两氧基一苯基]-亞乙基胺基氣甲基）一苯基）一Ν—甲基一乙醢胺（化合物3.23); -5 8 - 本紙張尺度逍用中國國家標準（CNS ) Α4規格（210X 297公釐） ^本訂矣 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 4 3 39 8 2 i A7 B7 經濟部中央標準局肩工消費合作社印製五、發明説明CKfo (1 Ο 2 ) 2 —甲氧基亞胺基一2 — ( 2 — ( 2—甲氧基亞胺基—1一甲基—2_ 〔4_n—丁氧基一苯基]-亞乙基胺基氧甲基）一苯基）-N—甲基_乙醯胺（化合物3.24); (103) 2—甲氧基亞胺基一 2— （2- (2—甲氧基亞胺基一 1一甲基一2— 〔4一氟一 2—甲基一苯基〕-亞乙基胺基氧甲基} 一苯基）一 H —甲基一乙醯胺（化合物3.35); (1D4) 2-甲氧基胺基一 2— （2 - {2 —甲氧基亞胺基 —1—甲基一2— 〔2—氟一 4 一甲基一苯基〕一亞乙基胺基氧甲基} 一苯基）一N—甲基一乙醯胺（化合物3.39)； (105) 2—甲氧基亞胺基一 2 — （2— ί2—甲氧基亞胺基—1—甲基—2— 〔4_環戊基氧—苯基〕-亞乙基胺基氧甲基} 一苯基）-Ν—甲基一乙醯胺（化合物3.45); (106) 2-甲氧基亞胺基一 2— （2— （2—甲氧基亞胺基一 1—甲基一 2— 〔2-氟一4— η—丙氧基一苯基]—亞乙基胺基氧甲基）一笨基）-Ν—甲基一.乙醯胺（化合物3_46 )； (107) 2 —甲氧基亞胺基一2— (2 — {2 -甲氧基亞胺 -59- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐} I _ .~~. 訂务 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 ^339 82，j a7 B7 五、發明説明基一 1一甲基一 2 — 〔 2 —甲基一 4— π—丙氧基一苯基]一亞乙基胺基氣甲基} 一苯基）一N —甲基一乙醢胺（化合物 3.47)； (108) 2 —甲氧基亞胺基一2— (2- (2—甲氧基亞胺基一1—甲基一2— 〔2 —氟一4 —乙氧基_苯基〕一亞乙基胺基氧甲基} 一苯基）—N —甲基一乙醯胺（化合物3·50) t (109) 2 —甲氧基亞胺基—2- (2- {2 —甲氧基亞胺基一1—甲基一 2— 〔2—氟一4_甲氧基一苯基〕一亞乙基胺基氧甲基}—苯基）一 N —甲基—乙醯胺（化合物3.53) t 及（110) 2—甲氧基亞胺基一2— （ 2— ( 2-甲氧基亞胺基一1 -甲基一2 — 〔 4一乙氧基—2 —甲基一苯基〕—亞乙基胺基氧甲基）一苯基）一 Ν —甲基—乙醯胺（化合物 3.60) 〇在本發明之内容中*示於表1至158之式（I)化合物類及，當合適時，其Ε/ Ζ異構物類及Ε/ Ζ異構物混合物類為特別偏好的。 -60- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ---------.裝-- {請先閱讀背面之注意事項再填寫本頁) '1Τ4 3 3 9 8 2 "AV B7 V. Description of the invention (79) (2 ~ [2 — [4 -— (4-bromo-phenoxy) -phenyl]] 2-ethoxyimino-1 1- Methyl-ethylene-amino-oxymethyl) monophenyl) -3-methoxy monoacrylate (compound 4.33); (80) (2— {2— 〔4— (4— 第Tri-butyl-benzyloxy) monophenyl1-2-ethoxyimino ~ 1 monomethylmonoethylene-aminooxymethyl} monophenyl) -3-methoxy-acrylic acid Methyl Ester (Compound 4.55) > (81) [4-Isobutoxy-phenyl] -2-methoxyimino- 1-methyl-ethylene-ethyleneaminooxymethyl) -phenyl ) A 3-methylamino-acrylic acid methyl compound (compound 1.31); (82) [4-fluoro-2-methyl-phenyl] 2-methoxyimino-1-methyl-ethylene Aminoaminooxymethyl} monophenyl) a 3-methoxy-propanoic acid methyl compound (compound 1.51); (83) [2-fluoro-4 methylmethylphenyl] a 2-methoxy Imino-1-methyl monoethyleniminooxymethyl} monophenyl) 3 ~ methoxy monomethyl acrylate (compound 1.57); (84) [4— Cyclopentyloxy-phenyl]-2 -methoxyimino-1 -methyl-ethylideneaminooxymethyl} -phenyl) -3 -methoxy-propylene -55- paper size Applicable to China National Standard (CNS) A4 specification (210X297mm) ---------; installation ------ 1T ------ 4 (Please read the precautions on the back before filling (This page) A7 4 3 3982 ^ _B7 V. Description of the invention (rj) Acid methyl ester (Compound 1. 6 2); (85) [2-fluoro-4 — η-propyloxy —phenyl] — 2 — Methoxyimino-1 monomethyl monoethylene monoamino oxymethyl} monophenyl) -3 methoxy-methyl acrylate (compound 1, 63); (86) [2— Methyl- 4 -η-propoxy-phenyl]-2-methoxyimino- 1 -methyl-ethylene-amino-oxymethyl) -phenyl) -3 -methoxy- Methyl acrylate (compound 1.64); (87) [2-fluoro-4-ethoxy-benzyl] -2-methoxyimino-1-methyl-ethyleneaminooxymethyl} —Phenyl) —3-Methoxymonoacrylate (Compound 1.70); (88) [2-fluoro-4_methoxymethoxyphenyl] —2-methoxyimino-1-methyl Keiichi Ethylaminooxymethyl) -phenyl) -3-methoxy-acrylic acid methyl compound (compound 1.72); (89) [4-ethylamino-2-methyl-phenyl] 2-methyl Oxyimino- 1-methyl-ethyleneamino oxymethyl) -phenyl)-3-methoxy-methyl acrylate (compound 1.79); (90) 2-methoxyimine (2— {2-methoxymethoxyimino-56-) This paper size applies to China National Standards (CNS) A4 specifications (210 X 297 mm) -------- install --- --- ix ------. 飨 (Please read the notes on the back before filling out this page) Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives printed 433982 "A7 B7 Five 'Description of the Invention (0) 1-methyl-1 2- [4-isobutoxy) -phenyl] -ethylene-aminoaminomethyl} -phenyl) monoacetate (compound 2.22 ); (91) 2-methoxyimino— (2 -— (2-methoxyimino-1-methyl-2— [4-n-propoxymonophenyl] -ethyleneamine Oxymethyl} -phenyl) monoacetic acid methyl ester (compound 2.23); (92) 2-methoxy Imino- (2- {2-methoxyimino- 1-methyl-2— [4-monofluoro_2-methyl-phenyl} -monoethylaminooxymethyl) -phenyl ) —Methyl acetate (compound 2.35); (93) 2-methoxyimino- (2- {2-methoxyimino- 1-methyl ~ 2— [2-fluoro-4 a Methyl monophenyl] -ethyleneaminooxymethyl) monophenyl) monoacetic acid methyl ester (compound 2.39); (94) 2-methoxyimino- (2- (2-methoxy) Imino- 1 -methyl-2-[4 -cyclopentyloxy-phenyl] -ethyleneaminooxymethyl} -phenyl) monoacetic acid methyl ester (compound 2.44); (35 ) 2-methoxyimino group (2- methoxy 2-imino group-丨-methyl-2-[2-fluoro-4-η-propoxy ~ phenyl]-ethyleneamine Oxymethyl) monophenyl) monoacetic acid methyl ester (compound 2.45); This paper size applies to Chinese National Standard Xin (CNS) A4 specification (2! 〇 X 297 mm) Please read the notes on the back before filling out this page) 4 3 39 8 A7 B7 V. Description of the invention (θ) (36) 2-methoxyimino- (2 ί 2-methoxyimino-1-methyl-2— [2-methyl-4— η-propoxy-benzyl] —ethyleneaminooxymethyl} -phenyl) _methyl acetate Ester (compound 2.46); (9 7) 2-methoxyimino- (2--2-methoxyimino- 1-methyl-2-[2-fluoro-4 4-ethoxy Monophenyl] -ethyleneaminooxymethyl) -phenyl) -acetic acid methyl ester (compound 2.4 9), (98) 2-methoxyimino- (2- {2-methoxy Imino — 1-methyl — 2 — [2-fluoro-4 4-methoxy-phenyl} · 1 ethylene anthryloxymethyl} -benzyl) monoacetate (compound 2.52); (99) 2-methoxyliminyl- (2- {2-methoxyimino-1-methyl-1 2- [4-H-ethoxy-1 2-methyl-phenyl]- Ethyleneaminooxymethyl} monophenyl) monoacetic acid methyl ester (compound 2.59); (100) 2-methoxyimino-1- (2- {2-methoxyimino-1 1-methyl-2- [4-isobutoxy-phenyl] -ethyleneaminooxymethyl) -phenyl) -N-methyl-ethylacetamide (compound 3.22); (1 Q 1) 2 —Methoxyimino- 2 — (2 — [2-methoxyimino- 1-methyl- 2- [4- η-.dioxymonophenyl] -ethyleneamine Methyl) monophenyl) -N-methylmonoacetamide (compound 3.23); -5 8-This paper uses Chinese National Standards (CNS) A4 specifications (210X 297 mm) ^ This order (please (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 39 8 2 i A7 B7 2 —methoxyimino- 2 — (2 — (2-methoxyimino-1—methyl-2 — [4_n-butoxymonophenyl] -ethyleneaminooxymethyl) (Monophenyl) -N-methyl-acetamidine (compound 3.24); (103) 2-methoxyimino- 2- (2- (2-methoxyimino- 1-methyl- 2— [4-fluoro-2-methyl-phenyl] -ethyleneaminooxymethyl} monophenyl) -H-methylmonoethylamine (compound 3.35); (1D4) 2-methoxy -Amino- 2-(2-{2-methoxyimino- 1 -methyl-2-[2- Fluoro-4 monomethylmonophenyl] monoethyleneaminooxymethyl} monophenyl) N-methylmonoethylamine (compound 3.39); (105) 2-methoxyimino 2— (2—ί2-methoxyimino-1-methyl-2— [4-cyclopentyloxy-phenyl] -ethyleneaminooxymethyl} monophenyl) -N-methyl Acetylamidine (compound 3.45); (106) 2-methoxyimino- 2— (2- (2-methoxyimino- 1-methyl-2— [2-fluoro-4 — Η-propoxymonophenyl] -ethyleneaminooxymethyl) -benzyl) -N-methylmonomethylamine (Compound 3_46); (107) 2 -methoxyimino 1 2 — (2 — {2 -Methoxyimine-59- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) I _. ~~. Ordering (please read the first Please fill in this page again for attention) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ^ 339 82, j a7 B7 V. Explanation of the invention 1-methyl-1 2-[2 -methyl-4-π-propoxy Monophenyl] monoethyleneaminomethyl} monophenyl) -N-methylmonoethylamine (combined 3.47); (108) 2-methoxyimino-2- (2- (2-methoxyimino-1-methyl-2) [2-fluoro-4-ethoxy-phenyl ] Monoethyleneaminooxymethyl} monophenyl) —N —methylmonoethylamine (compound 3.50) t (109) 2 —methoxyimino—2- (2- {2 —Methoxyimino-1—methyl—2— [2-fluoro—4-methoxymonophenyl] —ethyleneaminooxymethyl} —phenyl) —N—methyl—ethyl Amine (compound 3.53) t and (110) 2-methoxyimino- 2— (2-— 2-methoxyimino- 1-methyl-2 — [4-ethoxy-2 —Methylmonophenyl] —Ethyleneaminooxymethyl) —Phenyl) —N—Methyl-Ethylamine (Compound 3.60) 〇 In the context of the present invention *, the formulas shown in Tables 1 to 158 are shown. (I) Compounds and, where appropriate, E / Z isomers and E / Z isomer mixtures are particularly preferred. -60- This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) ---------. Loading-{Please read the precautions on the back before filling this page) '1Τ

A 4 3 3 9 8 2 A7 B7 五 '發明説明（t(h 本發明進而相關於一種製備式（I)化合物或，當合適時，其E/Z異構物類或互變異構物類之一，在各種情形下為游離形式或鹽彤式，的方法，其包括，例如， al)或者將下式之化合物 (請先閱讀背面之注意事項再填寫本頁) k-A 4 3 3 9 8 2 A7 B7 Five (5) invention description (t (h the present invention is further related to the preparation of a compound of formula (I) or, when appropriate, its First, the method in each case is free form or salt form, which includes, for example, al) or a compound of the following formula (please read the precautions on the back before filling this page)

ZZ

X, 00. 訂經濟部中央標準局負工消費合作社印聚，其中X’ Y，Z，R3 ，R4及R9具有如在式（I)中的定義，且Xi為一離去性基團，且，其中針對式（I)化合物所提到的條件亦適用，偏好為在一鹼的存在下，與下式化合物進行反應 (vT〇、a-R7X, 00. Ordered by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives, where X 'Y, Z, R3, R4 and R9 have the definitions as in formula (I) and Xi is a leaving group Moreover, the conditions mentioned for the compound of formula (I) are also applicable, and preference is to react with the compound of the formula (vT0, a-R7 in the presence of a base)

-61' (Ml). 本紙張尺度適用中國國家標芈（CNS ) A4規格（210X297公釐） 433982^ A7 B7 五、發明説明，其中η，<1，A* G，R，尺2 ，Rs及玟7具有如在式（I )中的定義*且，其中針對式（I)化合物所提到的條件亦適用，或a2)將下式之化合物 >0、〆^-61 '(Ml). This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 433982 ^ A7 B7 V. Description of invention, where η, < 1, A * G, R, ruler 2, Rs and 玟 7 have the same definitions as in formula (I) *, and the conditions mentioned for the compound of formula (I) also apply, or a2) the compound of formula > 0, 〆 ^

(IV) ，其中n*q，E，A，G，R2 ，Rs及具有如在式（I )中的定義，且，其中針對式（I)化合物所提到的條件亦適用•當合適時在一鹼的存在下，與下式化合物進行反應 {請先閱讀背面之注意事項再填寫本頁) /10-- 訂經濟部中央標準局貝工消費合作社印製(IV), where n * q, E, A, G, R2, Rs and have the definitions as in formula (I), and where the conditions mentioned for the compound of formula (I) also apply • when appropriate In the presence of a base, react with a compound of the formula {Please read the notes on the back before filling this page) / 10-- Order printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

ZZ

onh3ci (V) 62- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）經濟部中央標準局員工消費合作杜印製 4 3 39 82^ at B7 五、發明説明（p) 其為已知的或可K本身為已知的方法加以製備，且，其中X，Y，，iu及具有如在式（I)中的定義，或 b) 為了製備其中Υ為NHRs且Ζ為0之式（I)化合物，將式U)之化合物，其中Y為ORi ，與式Rs NH2之化合物進行反應，其為已知的或可以本身為已知的方法加以製備且*其中Rs具有如在式（I)中的定義，或 c) 為了製備其中Y為NHRs且Z為S之式（I)化合物，將式（I)之化合物，其中Y為R8 NHz且Z為0，與P4 S ! 〇或Lawesson' s反應劑進行反應，或者 d) 為了製備其中Y為NHR8且Z為SO之式（I)化合物，將式（I)之化合物，其中Z為S*與一氧化劑進行皮應，或onh3ci (V) 62- This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperative Department of the Central Bureau of Standards of the Ministry of Economic Affairs 4 3 39 82 ^ at B7 V. Description of Invention (p) It is Known or can be prepared by a method known per se, and wherein X, Y ,, iu and have the definition as in formula (I), or b) for the preparation where Υ is NHRs and Z is 0 A compound of formula (I), wherein a compound of formula U), in which Y is ORi, is reacted with a compound of formula Rs NH2, which is known or can be prepared by a method known per se and * where Rs has the formula (I), or c) In order to prepare a compound of formula (I) in which Y is NHRs and Z is S, a compound of formula (I) in which Y is R8 NHz and Z is 0, and P4 S! 〇 Or Lawesson's reagent, or d) in order to prepare a compound of formula (I) in which Y is NHR8 and Z is SO, a compound of formula (I) in which Z is S * is reacted with an oxidant, or

e) 為了製備式（〗）化合物，其中rs為芳基一Q — c2 一％烷基，芳基—q—(；2 — Cs烯基，雜環烷基一Q_C2 —C6烷基，雜環烷基—Q— c2 _c6烯基，或芳基一 Q— C 1 — Ce焼基或芳基一 q— — Cs稀基，雜環焼基—Q—c 2 - cs烷基或雜環烷基一 q_c2 — cs烯基，其在荠基或雜環院基環上為單一至五經取代的，其視取代反應的可能 -63- 本紙乐尺度適用中國囤家標準（CNS > ( 2[〇X297公釐） (請先閱讀背面之注意事項再填寫本頁) ,ya 4 3 3 9 8 2 :j μ B7 五、發明説明（‘/) 性而定，且其中該取代基類彼此獨立選自包括鹵素* Ci -Cs烷基，鹵素代—Ci 一 Ce烷基，C3 — Cs環烷基，鹵素代一 C3 — Ce —環焼基，Ci — Cs院氧基，鹵素代一 Ci -C6 —烷氧基，CN·硝基及Ci - Cs烷氧基羰基之一群組，且 Q為直鐽，一CH(OH) —，一 C( = 0) - or-S( = 0) v 且將下式化合物 ----------- (請先閲讀背面之注意事項再填寫本頁)e) In order to prepare compounds of formula (), where rs is aryl-Q-c2-% alkyl, aryl-q- (; 2-Cs alkenyl, heterocycloalkyl-Q_C2-C6 alkyl, heterocyclic Alkyl—Q—c2 —c6 alkenyl, or aryl—Q—C 1 —Ce fluorenyl or aryl—q——Cs dilute, heterocyclic fluorenyl—Q—c 2-cs alkyl or heterocycloalkane Radical q_c2 — cs alkenyl, which is single to pentamer substituted on the fluorenyl or heterocyclic ring, depending on the possibility of substitution reaction 〇X297mm) (Please read the notes on the back before filling in this page), ya 4 3 3 9 8 2: j μ B7 5. The description of the invention ('/) depends on the nature, and the substituents are independent of each other Selected from the group consisting of halogen * Ci-Cs alkyl, halogen-Ci-Ce alkyl, C3-Cs cycloalkyl, halogen-C3-Ce-cyclofluorenyl, Ci-Cs alkyloxy, halogen-Ci- C6 —alkoxy, a group of CN · nitro and Ci-Cs alkoxycarbonyl, and Q is straight, one CH (OH) —, one C (= 0)-or-S (= 0) v And the compound of the following formula ----------- (Please read the note on the back first (Fill in this page again)

ZZ

Nrf〇、A為 ΟNrf〇, A is 〇

、-& 經濟部中央標準局員工消費合作杜印製 lb),-&Amp; Consumption Co-operation by Employees of the Central Bureau of Standards, Ministry of Economic Affairs, printed lb)

，其中 Χ，Υ，Ζ，ΙΪ3 ，R4 * 89 ，n，q，R，A，G，R2&R 7具有如在式（I)中的定義*Rs a為芳基一 Q-C2 — Ce 炔基或雜環烷基一q_c2 — Cs炔基，或芳基一 Q—C2 —c s炔基或雜環烷基—Q- C2 —Cs玦基，其在芳基或雜環烷基環上為單一至五經取代的，其視取代反應的可能性而定，且其中該取代基類彼此獨立地選自選自包括鹵素，Ci — -64- 本紙張尺度適用中國國家標隼（CNS ) A4規格（210X297公釐）經濟部中央標準局員工消費合作社印製五、發明説明, Where X, Y, Z, Ι3, R4 * 89, n, q, R, A, G, R2 & R7 have the definition as in formula (I) * Rs a is aryl-Q-C2-Ce Alkynyl or heterocycloalkyl-q_c2 —Cs alkynyl, or aryl—Q—C2 —cs alkynyl or heterocycloalkyl—Q—C2 —Csfluorenyl, which is on the aryl or heterocycloalkyl ring It is single to penta substituted, depending on the possibility of substitution reaction, and the substituents are independently selected from the group consisting of halogen, Ci — -64- This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

Ce院基’ _素代一 Cl — Cs —烷基，c3 —ce環烷基，鹵素代一 C3 ~ce —環烷基，Ci _Cs烷氧基，鹵素代一 Ci —cs _院氧基，CN，硝基及Cl — c6烷氧基羰碁之一群組 t Q 為直键，一CH(OH) —，一 C( = 0) —〆一S( = 〇) v — ; 且v為Q，1或2 ; '其中針對式（I)化合物所提到的條件亦適用；且其為已知的或可Μ本身為已知的方法加K製備，與氫在氫化作用觸媒的存在下進行反懕，且在各種情況下，可依喜好，將根據本方法或另一種方式可得到的式（I)化合物或其一種Ε/Ζ異構物或互變異構物，在各種情況下為游離彤式或鹽彤式者，轉變成另一種式（I)化合物或其一種Ε/Ζ異構物或互變異構物，在各種情況下為游離形式或鹽形式者，將根據本方法可得到的Ε/Ζ異構物類的混合物分離或單離喜好的異構物，及/或將根據本方法或另一種方式可得到的游離式（I)化合物或其一種Ε/Ζ異溝物或互變異構物轉變成為一種鹽或將根據本方法或S 一種方式可得到的式（I)化合物或其一種Ε/Ζ異構物或互變異構物的 -6 5 - 本紙張尺度適用中國國家標準{ CNS ) Α4規格（210X297公釐) {請先閱讀背面之注意事項再填寫本頁) •τCe-Cycyl '_ prime-Cl — Cs —alkyl, c3 —cecycloalkyl, halogen-C3 ~ ce-cycloalkyl, Ci_Cs alkoxy, halogen-Ci —cs —codoxy, CN, nitro and one of the groups of Cl — c6 alkoxycarbonyl hydrazone t Q are straight bonds, one CH (OH) —, one C (= 0) — 〆 S (= 〇) v —; and v is Q, 1 or 2; 'The conditions mentioned for the compound of formula (I) also apply; and it is known or can be prepared by a known method plus K, and the presence of hydrogen in the presence of a hydrogenation catalyst The reaction is carried out under various conditions, and in each case, the compound of formula (I) or one of its E / Z isomers or tautomers, which can be obtained according to this method or another way, can be obtained according to preference, Those in free form or salt form, converted to another compound of formula (I) or one of its E / Z isomers or tautomers, in each case free form or salt form, will be in accordance with this method A mixture of available E / Z isomers is isolated or isolated from the preferred isomer, and / or the free compound of formula (I) or one of E / Z isomers or tautomers are converted into a salt or a compound of formula (I) or one of its E / Z isomers or tautomers will be obtained according to this method or S in a manner. -This paper size applies the Chinese National Standard {CNS) Α4 size (210X297mm) {Please read the precautions on the back before filling this page) • τ

433982 A7 B7 五、發明説明鹽轉變成為游離式（I)化合物或其一種E/Z異構物或互變異構物或轉變成為另一種鹽。本發明進而相關於一種製備式（III)化合物，在各種情形下為游離胗式或鹽形式者，的方法，其包拮，例如， f) 將式（IV)化合物，其中n，q，A* G，β* Rz * R s及R7具有式（I)中的定義，且，其中針對式（I)化合物所提到的條件亦適用，當合適時在鹼的存在下，與INOH 或其一種鹽進行反應*或者 g) 將下式化合物 ---------^..^-- (請先閲讀背面之注意事項再填寫本頁) 訂433982 A7 B7 V. Description of the invention The salt is transformed into a free compound of formula (I) or one of its E / Z isomers or tautomers or into another salt. The present invention further relates to a method for preparing a compound of formula (III), in each case free hydrazone or salt form, which includes, for example, f) a compound of formula (IV), wherein n, q, A * G, β * Rz * R s and R7 have the definitions in formula (I), and the conditions mentioned for compounds of formula (I) also apply, when appropriate, in the presence of a base, with INOH or its A salt is used for the reaction * or g) The compound of the formula --------- ^ .. ^-(Please read the precautions on the back before filling this page) Order

經濟部中央標準局負工消費合作社印聚 (VI). ’其中n，G* R，R2及RS具有在式（I)中的定義 S *其中針對式（D化合物所提到的條件亦適甩，當合 -6 8 - 本紙張尺度適用t國國家榡準（CNS )八4祕（21〇χ297公瘦）經濟部中央標準局員工消費合作社印製 4 3 39 8 2s3 a7 B7 五、發明説明適時在鹼的存在下’與下式化合物進行反應 R7 Αί1Η2 ( VII)，其為已知的或可Μ本身為已知的方法加Μ製備且，其中Α及R7具有式（I)中的定義，且在各種情況下，可依喜好，將根據本方法或另一種方式可得到的式（III)化合物或其一種E/Z異構物或互變異搆物，在各種情況下為游離形式或鹽形式者，轉變成另一種式（III)化合物或其一種 E/Z異構物或互變異構物，在各種情況下為游離胗式或鹽胗式者，將根據本方法可得到的E/ Z異構物類的混合物分離或單離喜好的異構物，及/或將根據本方法或另一種方式可得到的游雛式（III)化合物或其一種E/Z異構物或互變異構物轉變成為一種鹽或將根據本方法或另一種方式可得到的式（III)化合物或其一種E/Z異構物或互變異構皦的鹽轉變成為游離式（III)化合物或其一種E/Z異構物或互變異構物或轉變成為另一種鹽。由於结構，式（III) ，（ IV)及（VI)之化合物特別適合製備新穎之式（I)之活性終產物或其他具有此部份结構之活性物質，本發明相關於這些新穎化合物或物質。上述針對式（I)及（III)之化合物類之E/Z異構物 -67- 本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨0X29*7公釐） (請先閱讀背面之注意事項再填寫本頁)Yin Ju (VI) of the Consumers 'Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs.' Where n, G * R, R 2 and RS have the definitions in formula (I) S * where the conditions mentioned for compounds of formula (D are also applicable) Duo, Danghe-6 8-This paper size is applicable to the National Standards of the People's Republic of China (CNS) Eighty-fourth Secret (21〇χ297 thin) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 39 8 2s3 a7 B7 V. Invention It is shown that the reaction with a compound of the formula R7 Αί1Η2 (VII) is known in the presence of a base in a timely manner, which is known or can be prepared by a known method plus M and wherein A and R7 have the formula (I) Definition, and in each case, according to preference, the compound of formula (III) or one of its E / Z isomers or tautomers, which can be obtained according to this method or another way, is in free form in each case Or salt form, converted into another compound of formula (III) or one of its E / Z isomers or tautomers, in each case free hydrazone or salt hydrazone, will be obtained according to this method The mixture of E / Z isomers is separated or isolated from the preferred isomer, and / or Or a compound of formula (III) obtainable from another method or an E / Z isomer or tautomer thereof is converted into a salt or a compound of formula (III) obtainable according to the method or another method or One of its E / Z isomers or tautomers is converted to a free compound of formula (III) or one of its E / Z isomers or tautomers is converted to another salt. Due to the structure, formula (III ), (IV) and (VI) compounds are particularly suitable for the preparation of novel active end products of formula (I) or other active substances having this partial structure, and the present invention relates to these novel compounds or substances. ) And (III) E / Z isomers of compounds-67- This paper size applies Chinese National Standard (CNS) A4 specification (2 丨 0X29 * 7 mm) (Please read the precautions on the back before filling in this page)

、1T 經濟部中央標準局員工消費合作社印製 433982搜五、發明説明類及互變異構物類的敍述从相似的方式適用於上文及下文所定義之起始物質及其S/Z異構物類互變異構物類。上文及下文所述之反應Μ本身已知的方式進行’例如在缺少或通常存在一合適的溶劑或稀釋劑或其温合物時進行反應*該反應可依需要，在室溫下進行冷卻或加熱’例如，在自約Ot：至反應基質之沸點的溫度*偏好自約2()t至約+ 120Ό，特別是6〇υ至80¾，且，若有需要，在—封閉的容器中'，於壓力下，在一惰性氣體中及/或在無水條件下進行。特別有利的反應條件可在實施例中看到° 上文或下文所定義之用於製備式（I)之化合物I類’且，當合適時，其Ε/Ζ異構物類及互變異構物類之起始跡質為已知的或可Μ本身為習知的方法加Κ製備’例如根據下列指示。變異方式al/ a2): 在式（π)之化合物類中的合適離去性基團χ為’例如 *羥基，Ci - Cs烷氧基，鹵素代一 Cl — Ca _烷氧基’ c i — Cs烷豳基氧，硫氫基，Ci _C8烷基硫，鹵素代—c i ~Cs -烷基硫，Ci — Cs烷磺醯基氧，鹵素代—C1 — c 8 —烷磺醸基氧，苯磺醯基氧，甲苯磺醢基氧及鹵素，偏 -68- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閏讀背面之注意事項再填寫本頁) 訂經濟部中失標準局負工消賢合作杜印製 433982® a? _ _B7____ 五、發明説明（έθ 好為甲苯磺醯基*三氟甲烷磺臨基氧及鹵素*特別是鹵素〇協助該反應的合適鹼類為，例如，鹼金屬或鹼土金靥氫氧化物類，氫化物類，醯胺類，烷醇酸物類，乙酸物類 •碳酸物類，二烷基醯胺類或烷基砂烷基-醢胺類，烷基胺類，亞烷基二胺類，非一烷基化的或Ν-烷基化的，飽和的或不飽和的環烷基胺類，鹼性雜環性化合物類*氫氧化胺類及羧酸物類。實施例類為氫氧化納，氫化納，醢胺納 *甲醇酸納，乙酸鈉*及碳酸納，第三-丁酸鉀，氫氧化鉀，碳酸鉀及氫化鉀 > 二異丙基醯胺鋰，雙（三甲基矽烷基）-醯胺鉀，氫化鈣·三乙基胺二異丙基乙基-胺*三伸乙基二胺，環己基胺，Ν —環己基-Ν，ί! 一二甲基胺，Ν ，Ν—二乙基笨胺，吡啶* 4— (Ν，Ν —二甲基胺基）毗啶，奎寧環（quinuclidine)，N -甲基嗎啉基，苄基三甲基氫氧化銨及 1，5 -二氮雜環〔5.4_(]〕Η---5 -烯（DBU) 0 反應靱可彼此反應|即不須加入一溶劑或稀釋劑，例如在熔融狀態。通常，然而，加入一情性溶劑或稀釋劑或或其混合物為有利的。此類溶劑或稀釋劑的實施例為：芳香性•脂肪性及脂環性氫碳化物類及經鹵化之氫碳化物類，如苯，甲苯，二甲苯，3，5 -三甲基苯（mesitylene) -69- 本紙張尺度適用中國國家榡準（CNS ) A4規格（210X297公釐） (請先聞讀背面之注意事項再填寫本頁) 訂 A7 43 39 82^1 B7 五、發明説明，1* 2* 3，4 -四氫蔡（tetralin)，氯苯，二氯苯，溴-苯，石油醚，己烷，環己烷，亞甲基氯•氯仿，四氯化碳， (請先閱讀背面之注意事項再填寫本頁) 二氮乙烷，三氯乙烯或四氯乙烯；酯類，如乙酸乙酯，醚類，如二乙基醚，二丙基醚，二異丙基醚，二丁基醚，第三一丁基甲基醚，伸乙基乙二醇單甲基醚，伸乙基乙二醇單乙基醚*伸乙基乙二醇二甲基醚，二甲氧基二乙基醚，四氫呋哺或二氧陸環；_類，如丙酮，甲基乙基_或甲基異丁基醇類，如甲醇*乙醇'丙醇，異丙醇，丁酵，伸乙基乙二醇或甘油；醯胺類，如N* Μ-二甲基甲醯胺，N ，ϋ -二乙基甲醯胺，fj，Ν —二甲基乙醯胺* Ν—甲基一吡咯嗣或六甲基磷酸三醯胺；腈類，如乙腈或丙及亞® 類，如二甲基亞楓。若反應在一鹼的存在下進行，使用過量的鹼，如三乙基胺，毗啶，N—甲基嗎啉基或N，N—二乙基苯胺，亦可作為溶劑或稀釋劑。 Λ 經濟部中央標隼局員工消費合作杜印製該反應有利地在約0亡至約1 8 Q t的溫度，偏好自約1 0 υ至約8 0 的溫度*在許多情況下在介於室溫及該反應混合物之迴流溫度之間的溫度進行。該反應偏好在正常壓力下進行。該反應可在沒有一惰性氣體環境下進行；然而，偏好在一憤性氣體環境下，例如氮或氩，特別是氮，進行。 -70- 本紙張尺度適用中國國家標準i CNS ) AA規格（2ίΟΧ 297公釐） A7 43 39 82 B7 五、發明説明（IP) (請先閲讀背面之注意事項再填寫本頁) 反應時間並非重要的；偏好的反應時間為約Q . 1至約2 4 小時，特別是約0 . 5至約2小時。產物經由慣用的方法加以翬離，例如經由過溏，结晶，蒸餾或色層分析或任何這些過程的合適姐合。在變異方法al/ a2)之偏好的具體事實中，化合物（ II)與化合物（III)在0口至8Gt?，偏好IOC至SOC，於一惰性溶劑中，偏好為一醢胺，特別是N* N—二甲基甲醯胺，在金屬氫化物，偏好為氫化納，的存在下進行反應。反應之特別偏好的條件見逑於實施例Hid)及Hie)。式（11)之化合物類為已知的或可以類似於已知化合物類的方式加以製備。經濟部中央樣準局員工消費合作社印製變異方法b) 反應物可彼此反應，即不須加入一溶劑或稀釋劑，例如在熔融狀態。通常，然而，加入一惰性溶劑或稀釋劑或或其混合物為有利的。此類溶劑或稀釋劑的實施例為見述於變異方法al/a2)中者。本紙張又度適用中國國家標準（CNS ) A4见格（210X297公釐） 433982」 A7 B7 五發明説明（ 10温約應自反好該偏及，溫度室溫於的介 P 在 . L80下。行 I況行進情進下多度力許溫壓約在.的常在-間正地度之在利溫度好有的溫偏應 P 流應反80迴反該約之該至物 V 合1.1T printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy Tautomeric species. The reactions described above and below are carried out in a manner known per se 'for example in the absence or usual presence of a suitable solvent or diluent or a warm compound thereof. Or heating ', for example, at a temperature from about Ot: to the boiling point of the reaction substrate *, preferably from about 2 () t to about + 120Ό, especially from 60 to 80¾, and, if necessary, in a closed container ', Under pressure, in an inert gas and / or under anhydrous conditions. Particularly advantageous reaction conditions can be seen in the examples ° Class I 'for the preparation of compounds of formula (I) as defined above or below, and, where appropriate, their E / Z isomers and tautomers The starting traces of the species are known or can be prepared by adding K in itself by conventional methods, for example according to the following instructions. Variation al / a2): A suitable leaving group χ in the compounds of the formula (π) is 'for example * hydroxyl, Ci-Cs alkoxy, halo-Cl-Ca _alkoxy' ci- Cs alkylsulfanyloxy, sulfhydryl, Ci_C8 alkylsulfur, halo-ci ~ Cs-alkylsulfur, Ci — Cs alkylsulfonyloxy, halo—C1 — c 8 —alkylsulfonyloxy, Benzenesulfonyloxy, tosylsulfonyloxy and halogen, partial -68- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) Order The Ministry of Economic Affairs, Bureau of Standards and Loss of Labor, Co-operation, Du Yinxian 433982® a? _ _B7____ V. Description of the invention (έθ is preferably tosylsulfonyl * trifluoromethanesulfonyloxy and halogen *, especially halogen. 0 to assist the reaction Suitable bases are, for example, alkali metal or alkaline earth metal hydrazone hydroxides, hydrides, amidines, alkanoates, acetates, carbonates, dialkylamidoamines, or alkyl Saralkyl-amidoamines, alkylamines, alkylene diamines, non-alkylated or N-alkylated, saturated or unsaturated naphthenes Amines, basic heterocyclic compounds * amine hydroxides and carboxylic acids. Examples are sodium hydroxide, sodium hydride, sodium amine * sodium methoxide, sodium acetate * and sodium carbonate, third- Potassium butyrate, potassium hydroxide, potassium carbonate and potassium hydride > lithium diisopropylamidamine, potassium bis (trimethylsilyl) -amidamine, calcium hydride · triethylamine diisopropylethyl- Amine * Triethylenediamine, cyclohexylamine, N-cyclohexyl-N, ί! Dimethylamine, N, N-diethylbenzylamine, pyridine * 4- (N, N-dimethyl Amine) pyrimidine, quinuclidine, N-methylmorpholinyl, benzyltrimethylammonium hydroxide and 1,5-diazepine heterocyclic ring [5.4 _ (]] Η --- 5- Olefin (DBU) 0 reaction 靱 can react with each other | that is, without the need to add a solvent or diluent, such as in the molten state. Usually, however, it is advantageous to add a solvent or diluent or a mixture thereof. Such solvents or Examples of diluents are: aromatic, fatty and alicyclic hydrocarbides and halogenated hydrocarbides, such as benzene, toluene, xylene, 3,5-trimethylbenzene (mesitylene) -69 -This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Please read the notes on the back before filling in this page) Order A7 43 39 82 ^ 1 B7 V. Description of the invention, 1 * 2 * 3,4-tetrahydro, tetrachloro, chlorobenzene, dichlorobenzene, bromo-benzene, petroleum ether, hexane, cyclohexane, methylene chloride • chloroform, carbon tetrachloride, (Please read the Note: Please fill in this page again) Diazaethane, trichloroethylene or tetrachloroethylene; esters, such as ethyl acetate, ethers, such as diethyl ether, dipropyl ether, diisopropyl ether, dibutyl Ether, tertiary butyl methyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether * ethylene glycol dimethyl ether, dimethoxydiethyl Ethers, tetrahydrofuran or dioxolan; classes, such as acetone, methyl ethyl, or methyl isobutyl alcohols, such as methanol * ethanol'propanol, isopropanol, butyrate, ethyl ether Ethylene glycol or glycerol; amines, such as N * M-dimethylformamide, N, fluorene-diethylformamide, fj, N-dimethylacetamide * Ν-methyl-pyrrole Samarium or trimethylamine hexamethyl phosphate; nitriles Such as acetonitrile or propionitrile and sub ® such as dimethyl sulfoxide. If the reaction is carried out in the presence of a base, an excess of a base such as triethylamine, pyridine, N-methylmorpholinyl or N, N-diethylaniline can also be used as a solvent or diluent. Λ The consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs has printed the response. The reaction is favorably at a temperature of about 0 to about 18 Qt, and a temperature of about 10 to about 8 * is preferred in many cases. The temperature is between room temperature and the reflux temperature of the reaction mixture. This reaction is preferred to be performed under normal pressure. The reaction can be carried out without an inert gas environment; however, it is preferred to carry out under an inert gas environment, such as nitrogen or argon, especially nitrogen. -70- This paper size applies to the Chinese National Standard i CNS) AA specification (2ίΟΧ 297 mm) A7 43 39 82 B7 V. Description of the invention (IP) (Please read the notes on the back before filling this page) Response time is not important The preferred reaction time is from about Q.1 to about 24 hours, especially from about 0.5 to about 2 hours. The product is deionized by conventional methods, such as by dehydration, crystallization, distillation or chromatography, or a suitable combination of any of these processes. In the specific facts of the preference of the variation method al / a2), compound (II) and compound (III) are in the range of 0 to 8 Gt ?, IOC to SOC, and in an inert solvent, preference is given to monoamine, especially N * N-dimethylformamide is reacted in the presence of a metal hydride, preferably sodium hydride. The particular preferred conditions of the reaction are described in Examples Hid) and Hie). Compounds of formula (11) are known or can be prepared in a manner similar to known compounds. Printed by the Consumer Cooperative of the Central Bureau of Procurement of the Ministry of Economic Affairs Variation method b) The reactants can react with each other, that is, without adding a solvent or diluent, for example, in a molten state. Usually, however, it is advantageous to add an inert solvent or diluent or a mixture thereof. Examples of such solvents or diluents are those described in the variant method al / a2). This paper is again applicable to the Chinese National Standard (CNS) A4, see the standard (210X297 mm) 433982 "A7 B7 Five invention instructions (10 temperature should be reflexive, the partial temperature, room temperature at room temperature P is below L80. I will continue to make progress with more efforts to allow the temperature and pressure to be around. Often-between positive and negative degrees, the temperature is good, and some temperature deviations P flow should be reversed 80 times.

約至 V 好偏。 , 行而進然，氮行是進別下特境’ 環氬體或氣氮性如憤例 I - 有下沒境在環可體應氣反性該惰 1 在 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標苹局員工消費合作社印製反應時間並非重要的；偏好的反應時間為的〇 . i至約24 小時》特別是約Q · 5至約2小時。產物經由慣用的方法加以單離，例如經由過液，结晶，蒸餾或色層分析或任何這些過程的合適組合。變異方法C ) 反應物可彼此反應，即不須加入一溶劑或稀釋劑，例如在熔融狀態。通常，然而，加入一惰性溶劑或稀釋劑或或其混合物為有利的。此類溶劑或稀釋劑的寅施例為：芳香性，脂肪性及脂環性氫碳化物類及經鹵化之氫碳化物類，如苯，甲苯，二甲苯，1，3，5 -三甲基苯（mesitylene) -72- 本紙乐尺度適用中國國家標準（CNS ) A4規格（210X297公釐）經濟部中央標隼局員工消費合作社印裝 4 3 39 8 2)5 A7 _B7____ 五、發明説明（^) 1 5 2，3，4 -四氬萘（tetralin)，氯笼 > 二氣笨，溴一苯·石油醚，己烷，環己烷，亞甲基氯，氯仿，四氯化碳 *二氮乙烷*三氮乙烯或四氯乙烯；酯類’如乙酸乙酯’ 醚類，如二乙基醚，二丙基醚，二異丙基醚，二丁基醚’ 第三一丁基甲基醚，伸乙基乙二醇單甲塞醚，伸乙基乙二酵單乙基醚，伸乙基乙二醇二甲基醚，二甲氧基二乙基醚，四氫呋哺或二氧陸環；及亞通類，如二甲基亞碾。該反應有利地在約G °C至約+ 1 2 Q υ的溫度，偏好自約 SOO至約+ I2G1C的溫度下進行。該反應偏好在正常壓力下進行。該反應可在沒有一惰性氣體環境下進行；然而，偏好在一惰性氣體環境下，例如氮或氩，特別是氮，進行。反應時間並非重要的；偏好的反應時間為約G . 1至約2 4 小時•特別是約0 . 5至约2小時。產物經由慣用的方法加Μ單離，例如經由過濾，结晶，蒸豳或色層分析或任何這些過程的合適姐合。變異方法d) -73- 本紙張尺度適用中國國家標準（CNS ) A4規格（2! Ο X 297公釐） 1,-衣 I ! : H 訂 n ' (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 4 3 39 82-^ at Β7 五、發明説明（"7/) 合適的氧化劑為，例如，無機性過氧化物類，如過硼酸鈉，或過氧化氫’或有機性過酸類*如過苯甲酸或過乙酸，或有機酸類及過氧化氮的温合物類’例1如乙酸氧化氫。反應物可彼此反應，即不須加入一溶劑或稀釋劑，例如在熔融狀態。通常’然而’加入—惰性溶劑或稀釋劑或或其混合物為有利的。此類溶劑或稀釋劑的實施例為：芳香性，脂肪性及脂環性氫碳化物類及經鹵化之氫碳化物類，如苯，甲苯，二甲苯，1，3，5-三甲碁苯（mesitylene) ，1，2，3* 4 -四氫蔡（tetralin)，氯苯，二氯苯，溴一苯，石油醚，己烷，環己烷，亞甲基Μ *氯仿*四氯化碳* 二氯乙烷，三氯乙烯或四氯乙烯；酯類，如乙酸乙酯，醚類，如二乙基醚*二丙基醚，二異丙基醚，二丁基醚，第三一丁基甲基醚，伸乙基乙二醇單甲基醚，伸乙基乙二醇單乙基醚，伸乙基乙二酵二甲基醚，二甲氧基二乙基醚，四氫呋喃或二氧陸環；嗣類，如丙嗣，甲基乙基嗣或甲基異丁基酮；醇類，如甲醇，乙醇，丙醇，異丙醇，丁醇，伸乙基乙二酵或甘油；醢胺類，如Ν，Ν—二甲基甲醯胺，Ν ，Ν—二乙基甲醢胺，ν，Ν -二甲基乙醢胺，Ν—甲基一吡塔嗣或六甲基磷酸三醯胺；腈類，如乙腈或丙腈；及亞楓類’如二甲基亞碾。若反應在一有機酸或過酸的存在下進 -74- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 訂 4 經濟部中央標隼局負工消費合作社印製 4 3 3982α Α7 Β7 五、發明説明（j>) 行，使用過量的酸，例如強烈有機羧酸類，如C 1 — C4烷 -羧酸類，其為未經取代的或經由f例如鹵素，加以取代，例如甲酸，乙酸或丙酸，亦可作為溶劑或稀釋劑。該反應有利地在約0 口至約+ 1 2 0 t的溫度，偏好自約0 C至約+40TC的溫度下進行。該反應偏好在正常壓力下進行。該反應可在沒有一憤性氣體環境下進行；然而，偏好在一惰性氣體環境下，例如氮或氯，特別是氮·進行。反應時間並非重要的；偏好的反應時間為約0 . 1至約2 4 小時*特別是約0 . 5至约2小時。產物經由慣用的方法加K單離，例如經由過濾，結晶，蒸餾或色層分析或任何這呰過程的合適姐合。差異方法e) 合適的氮化作用觸媒類為，特別是，過渡金屬觸媒類，特別是鈀*釕，铑，鎳，鋅或鉑觸媒，Raney鎳，活性碳上鈀及Lindlar觸媒（Pd-CaC〇3 _PbO)為特別合適的。 -75- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） ---------^:東------訂------ (請先閲讀背面之注意事項再填寫本頁) 433982^ at B7 五、發明説明（Pj) 然而，氫化作用可於一均質溶液中進行，例如在Rhci ( Ph 3 ) 3 (Wilkinson' s觸媒）的存在下。反應物可彼此反應，即不須加入一溶劑或稀釋劑，：例如在熔融狀態。通常，然而*加入一情性溶劑或稀釋劑或或其混合物為有利的。此類溶劑或稀釋劑的實施例為見述於變異方法al/a2)中者。醚類，如四氫呋喃或二氧陸環 *及酯類*如乙酸乙醒，為特別合適的。該反應有利地在約至約80¾的溫度，偏好自約10P 至約5ϋυ的溫度，在許多情況下在室溫下進行。該反應偏好在正常壓力或稍徽増壓下進行，偏好在正常壓力下進行。反應時間並非重要的；偏好的反應時間為約〇 . 1至約2 4 小時，特別是約0 . 5至約2小時。經濟部令央標準局員工消費合作社印製 (請先聞讀背面之注意事項再填寫本頁) 產物經由慣用的方法加以單離，例如經由過濾*结晶，蒸餾或色曆分析或任何這些過程的合適組合。反應之特別偏好的條件見述於實施例H3a)至c)。 -76- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) 433982^ A7 B7 五、發明説明變異方法f) (請先閱讀背面之注意事項再填寫本頁) 協助反應的合適鹼類，例如，為見述於變異方法al/ a 2)中者。反應物可彼此反應’即不須加入一溶劑或稀釋劑，例如在熔融狀態。通常’然而，加入一愦性溶劑或稀釋劑或或其混合物為有利的。此頚溶劑或稀釋劑的實施例為見述於變異方法al/ a2)中者。該反應有利地在約Ot；至約I80t：的溫度，偏好自約lfl 至約8Q°C的溫度，在許多情況下在介於室溫及該反應溫合物之迴流溫度之間的溫度進行。該反應偏好在正常壓力下進行。經濟部中央標隼局員工消費合作社印製該反應可在沒有一惰性氣體環境下進行；然而’偏好在一惰性氣體環境下，例如氮或氬，特別是氮，進行。反應時間並非重要的；偏好的反應時間為約〇 * 1至約2 4 小時，特別是約0 . 5至約2小時。產物經由慣用的方法加以軍離，例如經由過濾，结晶 -77- 本紙張尺度適用中國國家標準{ CNS ) A4規格{ 210X 297公釐） 4 3 39 8 2绕 Α7 Β7 經濟部中央標準局負工消費合作社印裝五、發明説明（yp ，蒸餾或色層分析或任何這呰過程的合適組合。變異方法g) 協肋反應的合適鹼類’例如，為見述於變異方法al〆 a2)中者。反懕物可彼此反應 > 即不須加入一溶劑或稀釋劑，例如在熔融狀態。通常，然而，加入一憤性溶劑或稀釋劑或或其溫合物為有利的。此類溶劑或稀釋劑的實施例為見述於變異方法a 1 / a 2)中者。該反應有利地在約0 至約1 8 0 的溫度，偏好自約1 0 t；至約δ (TC的溫度’在許多情況下在介於室溫及該反應混合物之迴流溫度之間的溫度進行。該反應偏好在正常壓力下進行。該反躍可在沒有一惰性氣體環境下進行；然而，偏好在一惰性氣體環境下，例如氮或氬，特別是氮*進行。反應時間並非重要的；偏好的反應時間為約0 · 1至約2 4 小時，特別是約〇 . 5至約2小時。 * -78- (請先閱讀背面之注意事項再填寫本頁) .4衣' ,ιτ ,4, 本紙張尺度適用中國國家標準（CNS ) Μ規格（210X297公釐）經濟部中央標準局貝工消費合作社印製 43 39 8 a7 B7 五、發明説明) 產物經由慣用的方法加K單離*例如經由過逋*结晶，蒸餾或色層分析或任何這些過程的合適組合。在愛異方法η之偏好的具題事貿中•化合物（vi)與化合物（VII)在0 =至ίζοπ，偏好6Q1C至120t：，於一惰性溶劑中*偏好為一胺，特別是吡啶，進行反應。式（I) | ( II) * ( III) ，（ IV) ，（ V)及（VI) 之化合物類可K一種可能異構物類或以其混合物的方式存在，例如依不對稱碳原子的數目Μ及絕對及相對的構形，可為純化的異構物類 > 如對映體類及/或立體異構物類* 或為異構物溫合物類|如對映異構物溫合物，例如消旋物類，立體異構物混合物類或消旋混合物類；本發明栢闞於純化的異構物類及所有可能的異構物混合物類且在每種情形下在上文及下文中均被理解為如此，雖然立體化學的细節並沒有每次都特別指出。About V is biased. Going forward, Nitrogen is going to go to the next special state 'ring argon or gas nitrogen as in Example I-there is no real world in the ring can respond to gas inertia the inertia 1 (Please read the note on the back first Please fill in this page for further information.) The response time printed by the Ministry of Economic Affairs Central Standard Bureau Bureau Consumer Cooperative is not important; the preferred response time is from 0.1 to about 24 hours, especially about Q · 5 to about 2 hours. The product is isolated by customary methods, such as by liquid, crystallization, distillation or chromatography, or any suitable combination of these processes. Variation C) The reactants can react with each other, i.e. without adding a solvent or diluent, e.g. in a molten state. Usually, however, it is advantageous to add an inert solvent or diluent or a mixture thereof. Examples of such solvents or diluents are: aromatic, fatty and alicyclic hydrocarbides and halogenated hydrocarbides, such as benzene, toluene, xylene, 1, 3, 5 -trimethyl Mesitylene -72- The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) Printed by the Consumer Cooperatives of the Central Standardization Bureau of the Ministry of Economic Affairs 4 3 39 8 2) 5 A7 _B7____ V. Description of the invention ( ^) 1 5 2,3,4-tetralin, chlorine cage > Digas, bromo-benzene · petroleum ether, hexane, cyclohexane, methylene chloride, chloroform, carbon tetrachloride * Diazaethane * Triazethylene or tetrachloroethylene; esters' such as ethyl acetate 'ethers, such as diethyl ether, dipropyl ether, diisopropyl ether, dibutyl ether' Butyl methyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol dimethyl ether, dimethoxydiethyl ether, tetrahydrofuran Or dioxocyclic ring; and suballoys, such as dimethylimine. The reaction is advantageously carried out at a temperature of about G ° C to about + 12Q, preferably at a temperature from about SOO to about + 12G1C. This reaction is preferred to be performed under normal pressure. The reaction can be carried out without an inert gas environment; however, it is preferred to carry out under an inert gas environment, such as nitrogen or argon, especially nitrogen. The reaction time is not important; the preferred reaction time is from about G.1 to about 24 hours. Especially about 0.5 to about 2 hours. The product is isolated by conventional methods plus M isolation, such as by filtration, crystallization, distillation or chromatography, or a suitable combination of any of these processes. Variation method d) -73- This paper size is applicable to Chinese National Standard (CNS) A4 specification (2! 〇 X 297 mm) 1, -I!: H Order n '(Please read the precautions on the back before filling in this Page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 39 82- ^ at Β7 V. Description of the invention (" 7 /) Suitable oxidants are, for example, inorganic peroxides, such as sodium perborate, or Hydrogen peroxide 'or organic peracids * such as perbenzoic acid or peracetic acid, or warm compounds of organic acids and nitrogen peroxide' Example 1 such as hydrogen acetate. The reactants can react with each other, i.e. without adding a solvent or diluent, e.g. in a molten state. Usually, however, it is advantageous to add-an inert solvent or diluent or a mixture thereof. Examples of such solvents or diluents are: aromatic, fatty and alicyclic hydrocarbides and halogenated hydrocarbides such as benzene, toluene, xylene, 1,3,5-trimethylbenzene (Mesitylene), 1,2,3 * 4-tetrahydrotetralin, chlorobenzene, dichlorobenzene, bromomonobenzene, petroleum ether, hexane, cyclohexane, methylene M * chloroform * tetrachloride Carbon * dichloroethane, trichloroethylene or tetrachloroethylene; esters such as ethyl acetate, ethers such as diethyl ether * dipropyl ether, diisopropyl ether, dibutyl ether, tertiary Monobutyl methyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol dimethyl ether, dimethoxydiethyl ether, tetrahydrofuran or diethyl ether Oxytetracycline; amidines, such as propane, methylethylamidine or methyl isobutyl ketone; alcohols, such as methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol or glycerol; Amines, such as N, N-dimethylformamide, N, N-diethylformamide, ν, N-dimethylacetamide, N-methyl-pyridine or hexamethyl Triamidine phosphate; nitriles, such as acetonitrile Propionitrile; and sub-classes Maple 'dimethylethylene as grinding. If the reaction progresses in the presence of an organic acid or peracid -74- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) Order 4 Printed by the Central Bureau of Standards, Ministry of Economic Affairs and Consumer Cooperatives 4 3 3982α Α7 Β7 V. Description of the invention (j >) OK, using excess acid, such as strong organic carboxylic acids, such as C 1-C4 alkane-carboxylic acids, which are Unsubstituted or substituted via f such as halogen, such as formic acid, acetic acid or propionic acid, may also serve as a solvent or diluent. The reaction is advantageously carried out at a temperature of about 0 to about + 120 °, preferably at a temperature of about 0 C to about +40 TC. This reaction is preferred to be performed under normal pressure. The reaction can be carried out without an inert gas atmosphere; however, it is preferred to carry out under an inert gas environment such as nitrogen or chlorine, especially nitrogen. The reaction time is not important; the preferred reaction time is from about 0.1 to about 24 hours *, especially from about 0.5 to about 2 hours. The product is isolated by conventional methods plus K isolation, such as by filtration, crystallization, distillation or chromatography, or any suitable combination of this process. Different methods e) Suitable nitriding catalysts are, in particular, transition metal catalysts, especially palladium * ruthenium, rhodium, nickel, zinc or platinum catalysts, Raney nickel, palladium on activated carbon and Lindlar catalysts (Pd-CaC03_PbO) is particularly suitable. -75- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) --------- ^: East ------ Order ------ (please first Read the notes on the back and fill in this page) 433982 ^ at B7 V. Description of Invention (Pj) However, hydrogenation can be performed in a homogeneous solution, such as the presence of Rhci (Ph 3) 3 (Wilkinson's catalyst) under. The reactants can react with each other, i.e. without adding a solvent or diluent: for example in the molten state. In general, however * it is advantageous to add an intimate solvent or diluent or a mixture thereof. Examples of such solvents or diluents are those described in the variant method al / a2). Ethers such as tetrahydrofuran or dioxolan * and esters * such as ethyl acetate are particularly suitable. The reaction is advantageously carried out at a temperature of from about to about 80 °, preferably from about 10P to about 5 °, and in many cases at room temperature. The reaction is preferred to be performed under normal pressure or a little pressure, and it is preferred to be performed under normal pressure. The reaction time is not important; the preferred reaction time is from about 0.1 to about 24 hours, especially from about 0.5 to about 2 hours. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). The right combination. Particularly preferred conditions for the reaction are described in Examples H3a) to c). -76- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297mm) 433982 ^ A7 B7 V. Invention description Variation method f) (Please read the notes on the back before filling this page) Suitable base to assist the reaction Classes, for example, are those described in the mutation method al / a 2). The reactants can react with each other ', i.e. without adding a solvent or diluent, e.g. in a molten state. Generally, however, it is advantageous to add an alkaline solvent or diluent or a mixture thereof. Examples of this rhenium solvent or diluent are those described in the variant method al / a2). The reaction is advantageously carried out at a temperature of about Ot; to about 80 t :, preferably a temperature of from about lfl to about 8Q ° C, and in many cases at a temperature between room temperature and the reflux temperature of the reaction temperature compound . This reaction is preferred to be performed under normal pressure. Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs. The reaction can be performed without an inert gas environment; however, it is preferred to perform it under an inert gas environment, such as nitrogen or argon, especially nitrogen. The reaction time is not important; the preferred reaction time is from about 0 * 1 to about 24 hours, especially from about 0.5 to about 2 hours. The product is separated by customary methods, such as filtering and crystallizing. -77- This paper size applies Chinese national standard {CNS) A4 specification {210X 297 mm) 4 3 39 8 2 Around A7 Β7 Ministry of Economy Central Standards Bureau Consumer cooperatives 'printing V. Description of the invention (yp, distillation or chromatographic analysis or any suitable combination of this process. Variation method g) Suitable bases for co-ribbon reactions' For example, see in Variation method al〆a2) By. The reactants can react with each other > That is, there is no need to add a solvent or diluent, for example, in a molten state. Generally, however, it is advantageous to add an annoying solvent or diluent or its warm compound. Examples of such solvents or diluents are those described in variant methods a 1 / a 2). The reaction is advantageously at a temperature of about 0 to about 180, preferably from about 10 t; to a temperature of about δ (TC 'in many cases between a room temperature and the reflux temperature of the reaction mixture The reaction is preferably carried out under normal pressure. The inversion can be carried out without an inert gas environment; however, it is preferred to carry out under an inert gas environment, such as nitrogen or argon, especially nitrogen *. The reaction time is not important ; The preferred response time is about 0.1 to about 24 hours, especially about 0.5 to about 2 hours. * -78- (Please read the precautions on the back before filling out this page) .4 衣 ', ιτ 4,4 This paper size applies the Chinese National Standard (CNS) M specifications (210X297 mm) Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 43 39 8 a7 B7 V. Description of the invention * E.g. Via perylene * crystallization, distillation or chromatography, or any suitable combination of these processes. In the subject matter of the preference method of love method η • Compound (vi) and compound (VII) at 0 = to ίζοπ, preference 6Q1C to 120t: in an inert solvent * preference to monoamines, especially pyridine, Perform the reaction. Compounds of formula (I) | (II) * (III), (IV), (V) and (VI) may exist as a possible isomer or as a mixture thereof, for example, by an asymmetric carbon atom. The number M and the absolute and relative configuration may be purified isomers > such as enantiomers and / or stereoisomers * or isomer isomers | such as enantiomers Warm compounds, such as racemates, stereoisomer mixtures or racemic mixtures; the present invention is based on purified isomers and all possible isomer mixtures and in each case above This and the following are to be understood as such, although the details of stereochemistry are not specifically pointed out each time.

由於成份的物理一化學差異性，可根據本方法一依照起始物質及步驟的選擇一或其他方式得到的式（I) ，（II )，（III) ，（IV) ，（V)及（VI)化合物類之立體異構物混合物類及消旋物混合物類可Κ習知的方法分雛成為纯化的立體異構物或消旋物，例如經由部份结晶法*蒸餾 -79- 本紙張尺度適用中固國家標準（CNS ) Α4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 丄衣訂經濟部中央標率局員工消費合作社印製 4 3 3 9 8 2-- a? Β7 五、發明説明及/或色層分析。相關可得到的對映異構物混合物類1如消旋物類’可用已知方法分離成為光學性對映體類，例如經由自—光學活性溶劑中進行再結晶，經由在掌對稱性吸附劑上進行色層分析，例如在乙醯基纖維素上進行高壓疲體色層分析（ Η P L C )，藉助於合適的微生物，經由K特異性，固著性酵素加Μ切割，或經由内含化合物類的形成’例如使用掌對稱性冠狀_類…僅有_ 一種對映異構物被複合。如同經由相關異構物混合物類的分雛，純化的立體異構物類或對映異構物類亦可根據本發明經由立體異構選擇性或對映異構選擇性合成的一般習知的方法，例如經由Κ 具有相關合適的立體化學的反應物進行本發明的方法。在每種情況下，當個別的成份具有相異的生物活性時 *較具生物活性的異構物，例如對映異構物，或異構物混合物，例如對映異構物混合物，係有利地被_離或合成。式（Π ，（ II) ，（ III). ，（ IV) ，（ V)及（VI) 的化合物類亦可Μ其水合物及/或包括其他溶劑的形式得到，例如可被用於使固體形式化合物類结晶的溶劑。 -80- 本紙乐尺度適用中國國家標準（CNS ) A4規格（2 i Ο X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂 ^ A7 43 3982^ _B7_ _ 五、發明説明（分） {請先閲讀背面之注意事項再填寫本頁) 本發明相關於本方法所有的具體事實，其中在該方法任一步驟可得到的化合物被用於作為起始物質或中間產物且進行全部或一些不足的步驟，或一起始物質K一衍生物或鹽及/或其消旋物或對映體類或，特別是，於本反應條件下所形成者的形式被使用。在本發明的方法中，得到上述定義之式（I)化合物之起始物質及中間產物為特別有價值的且偏好加K使用。本發明特別相關於見述於實施例Hla)至e)的方法。本發明同漾地栢關於本發明用於製備式（I)化合物之起始物質及中間產物類且相關於其用途及其製備方法*特別是新穎之式（III) ，（ IV)及（VI)化合物。特別是，式（III)及（VI)化合物類可分別κ類Μ於實施例Hlc) 及Hlb)的方式加以製備。經濟部中央標準局員工消費合作社印製依據本發明之式（I)化合物，即使在害蟲領域中所諝低比率之施用時，成為預防性及/或治癒性之具有一非常有利除害範圍之有價值化合物*且同時顯示可以被溫血動物類，魚類或植物所容忍的有利特性。依據本發明的活性化合物以有效地對抗全部或個別發育時期之正常感受性K 及抗藥性動物害蟲，如昆蟲及蟎目之代表者，K及植物病 -8 1 - 本紙乐尺度適用中國國家標準（CNS ) A4C格（2IOX297公釐）經濟部中央標準局貝工消費合作.杜印製 1 433982 j a? B7 一· Λ - — π-π——.......... — 五、發明説明Op 原性真菌。侬據本發明化合物類的殺昆蟲性，殺卵性及/ 或殺熵性作用可K直接地彰顯於有害生物的致死率方面，其立即地或僅經過一些時間後發生•例如在孵化時，或在蛋的致死率方面，或者間接地彰顯於降低的產卵率及/或孵化率方面*良好的活性相當於至少5 0至60%致死率。 Μ上提及的動物害蟲包括，例如：來自鱗翅目（Lepidoptera)的昆蟲，例如捲葉蛾屬（ Acleris spp.)，小捲棻蛾屬（Due to the physical-chemical differences of the components, formulas (I), (II), (III), (IV), (V) and ( VI) Stereoisomer mixtures and racemate mixtures of compounds can be separated into purified stereoisomers or racemates by conventional methods, for example, by partial crystallization * distillation-79- Standards are applicable to China Solid State Standards (CNS) A4 specifications (210X 297 mm) (Please read the notes on the back before filling this page) -a? Β7 5. Description of the invention and / or color analysis. Relevant available enantiomeric mixtures 1 such as the racemates can be separated into optical enantiomers by known methods, for example, by recrystallization from an auto-optically active solvent, via a palm-symmetric adsorbent Chromatographic analysis, such as high pressure fatigue chromatographic analysis (（PLC) on ethyl cellulose, with the help of suitable microorganisms, through K-specific, fixative enzymes plus cleavage, or via contained compounds The formation of the class' for example using palm symmetry corona_class ... only_ one enantiomer is compounded. As with the incubation of related isomer mixtures, purified stereoisomers or enantiomers may also be synthesized according to the present invention via stereoselective or enantioselective general synthesis The method, for example, is carried out via a K reactant having a relevant suitable stereochemistry. In each case, when the individual ingredients have different biological activities, it is advantageous to have more biologically active isomers, such as enantiomers, or isomer mixtures, such as enantiomeric mixtures. Ground cover_off or composite. Compounds of formula (Π, (II), (III)., (IV), (V) and (VI) can also be obtained in the form of hydrates and / or other solvents, for example, can be used to make solid Solvents for the crystallization of form compounds. -80- The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2 i 0 X 297 mm) (Please read the precautions on the back before filling this page) Order ^ A7 43 3982 ^ _B7_ _ V. Description of the invention (minutes) {Please read the notes on the back before filling out this page) The present invention is related to all the specific facts of the method, in which the compounds available at any step of the method are used as a starting point Substance or intermediate and all or a few inadequate steps, or a starting material K, a derivative or salt and / or its racemate or enantiomer or, in particular, the form of the one formed under the conditions of this reaction used. In the method of the present invention, the starting materials and intermediates to obtain the compound of formula (I) as defined above are particularly valuable and are preferred to use K. The invention is particularly relevant to the methods described in Examples Hla) to e). The present invention is related to Yangdibai related to the starting materials and intermediates of the present invention for the preparation of compounds of formula (I) and is related to its use and its preparation method * especially the novel formulas (III), (IV) and (VI) ) Compounds. In particular, the compounds of the formulae (III) and (VI) can be prepared in the manner of the kappa class M in Examples Hlc) and Hlb), respectively. The Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs has printed the compound of formula (I) according to the present invention, and even when applied at a low rate in the field of pests, it has a very beneficial range of prevention and / or cure. Valuable compounds * and at the same time show advantageous properties that can be tolerated by warm-blooded animals, fish or plants. The active compounds according to the present invention are effective against normal or allergic K and drug-resistant animal pests at all or individual developmental stages, such as representatives of insects and acarina, K and plant diseases-8 1-This paper scale applies Chinese national standards ( CNS) A4C (2IOX297 mm) Shellfish consumer cooperation with the Central Standards Bureau of the Ministry of Economic Affairs. Du Yin 1 433982 ja? B7 I · Λ-— π-π ——............ Description of the invention Opogenic fungi. According to the insecticidal, ovicidal and / or entropic properties of the compounds of the present invention, they can be directly displayed in terms of the lethality of pests, which occur immediately or only after some time. For example, when hatching, Either in terms of egg mortality, or indirectly, in terms of reduced spawning and / or hatching rates, * good activity is equivalent to at least 50 to 60% mortality. Animal pests mentioned on M include, for example: insects from the order Lepidoptera, such as Acleris spp.

Ado xophy e s spp _)，透翅蛾屬（Aegeria spp.)，地老虎屬(A g r o t i s spp.) ， Alabama argillaceae » Am y 1 o i s s pp ·，黎豆夜娥（Ant i c a r s i a έβ m m at a 1 i s) ，捲葉蛾屬（ Archips spp.)，捲葉蛾屬（Ado xophy es spp _), Aegeria spp., A grotis spp., Alabama argillaceae »Am y 1 oiss pp ·, Ant icarsia β β mm at a 1 is ), Archips spp.

Argyrotaenia spp.)，夜蛾屬（Autographa spp.) * .Busseola fusca，粉斑螟（Cadra cautella)，桃小食心蟲（ Carposina nipponensis )，稻摸屬（Chilo spp.)，捲葉蛾靥（Ciioristoneura spp .) ·葡萄果截蛾 (Clysia aaik i gu e 11 a)，縱捲螟臑（C naph a 1 o c r o c i s spp.)，捲葉蛾屬（Cnephasia spp.)， Cochylis spp·，鞘蛾屬（.Coleophora spp.) Crocidoloraia b i η o t a 1 i s， C r y p t ο p h 1 e b i a 1 e u c o t r e t a，II 蛾屬（C y d i a -82- 本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨ΟΧ297公釐） (請先閱讀背面之注意事項再填寫本I) .44- ,ιτ 經濟部中央標準扃員工消费合作社印裝 4 3 3 9 8 2 A7 B7 五、發明説明（洲） spp ·)，螺屬（D iatraea spp.) * Diparopsis castanea，金鋼鑽屬（Earias spp·)，粉慎屬（Argyrotaenia spp.), Autographa spp. *. Busseola fusca, Cadra cautella, Carposina nipponensis, Chilo spp., Ciioristoneura spp. · Clysia aaik i gu e 11 a, C naph a 1 ocrocis spp., Cnephasia spp., Cochylis spp., Coleophora spp. Crocidoloraia bi η ota 1 is, C rypt ο ph 1 ebia 1 eucotreta, II genus (C ydia -82- This paper size applies to China National Standard (CNS) Α4 size (2 丨〇 × 297 mm) (Please read the back Please fill in this note I). 44-, ιτ Central Standard of the Ministry of Economics, printed by employee consumer cooperatives 4 3 3 9 8 2 A7 B7 V. Description of Invention (Continent) spp ·), Diatraea spp.) * Diparopsis castanea, Earias spp ·, Pink Shen (

Ephe st i a spp ·)，蜞屬（Euc o sma spp .) *Ephe st i a spp ·), Euc o sma spp.) *

Eupoecilia ambiguella，毒蛾臑（Euproctis spp.) 1 根蟲靥（Suxoa spp.) * Grapholitaspp,，綠小捲葉蛾（Hedya nuti i f er ana)，棉龄蟲屬（He 1 i o t h i s spp·) »菜螟屬（Hellula spp·) »美國白蛾（Eupoecilia ambiguella, Euproctis spp. 1 Suxoa spp. * Grapholitaspp ,, Hedya nuti if er ana, He 1 iothis spp · »Hellula spp ·) »American White Moth (

Hyphantria cunea)，番茄蠹蛾（ Keiferia 1 y c 〇 p e r s i c e 11 a)，旋紋潛葉蛾（L e u c o p t e I· a s c i t e 11 a) ，细紋廛（Lithocoilethis spp,) Lobesia botrana ，毒娥屬（Lymantria spp .) * 潛葉蛾屬（L y ◦ π e t i a spp .) *幕毛蟲靥（Malacosoma spp.)，甘藍夜蛾（Hyphantria cunea), tomato moth (Keiferia 1 yc 〇persice 11 a), spine leaf moth (L eucopte I · ascite 11 a), fine-lined pupa (Lithocoilethis spp,) Lobesia botrana, Lymantria spp. ) * Leaf miner (L y ◦ etia spp.) * Malacosoma spp.

Mamestra brassicae) » 煙草天蛾（Manduca sexta)，尺蠖屬（Operophtera spp.)，歐洲玉求螺（Ostrinia nubilalis) » P am m e 11 e s p p .，捲葉餓屬（P a n d e m i s spp.) - Panolis flararaea，紅铃蟲（Pectinophora gossypiella) » Phthor imaea o pe r e u i e 11 a，桑粉媒（ Pieris rapae)，粉蝶藤（Pieris spp.)，小葉娥（ P 1 u t e 11 a xy 1 o s t e 1 I a) * 巢蛾題（p r ay s spp.)，白螟靥（Sc irpophaga spp.)，夜蛾屬（Sesamia spp . )^ 捲葉蛾屬（Sparganotiiis spp.)，夜蛾靥（ Spodoptera spp .)，透翅蛾屬（Synanthedon spp.) » Thaumetopoea s p p ‘，捲葉蛾屬（τ 〇 r t r i x s pp .)， -83- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） I i I I I -- I I — ' 裝 I I I I I 訂 I i 1 J 0 {請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 4339823 g 五、發明説明（<Γ I) 粉紋夜蛾（Trichoplusia ni)及巢蛾屬（Yponomeuta spp ); 來自鞘翅目（Coleoptera)的昆蟲，例如 0卩甲屬( Agriotes spp .) > Anthonomus spp.，Mamestra brassicae) »Manduca sexta, Operophtera spp., Ostrinia nubilalis» P am me 11 espp., P andemis spp.-Panolis flararaea, Red bollworm (Pectinophora gossypiella) »Phthor imaea o pe reuie 11 a, Pieris rapae, Pieris spp., P 1 ute 11 a xy 1 oste 1 I a) * Nest moth Question (pr ay s spp.), White pheasant (Sc irpophaga spp.), Spodoptera (Sesamia spp.) ^ Sparganotiiis spp., Spodoptera spp., Spodoptera spp. Synanthedon spp.) »Thaumetopoea spp ', τ 〇rtrixs pp., -83- This paper size applies to China National Standard (CNS) A4 (210X297 mm) I i III-II —' Order IIIII I i 1 J 0 (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4339823 g 5. Description of the invention (< Γ I) Trichoplusia ni and nest Moth (Yponomeuta spp); Insects from Coleoptera, such as Agriotes spp. &Gt; Anthonomus spp.,

Atomaria linearis* 甜菜脛跳甲（Chaetocnema tibialis )，象甲靥(Cosmopolites spp.) ， Curculio spp .) ，蠹屬（Dernestes spp·) * 葉甲屬（Diabrotica spp ,)，瓢蟲靥（Epi lachna spp .) * Eremnus spp . ，馬玲薯甲蟲（Leptinotarsa d e c e m 1 i n e a t a) >Atomaria linearis * Chaetocnema tibialis, Cosmopolites spp., Curculio spp., Dernestes spp. * Diabrotica spp, Ladybug pupa, Epi lachna spp .) * Eremnus spp., Leptinotarsa decem 1 ineata >

Lissorhoptrus spp.，蹈角金龜廛（Melolontha spp .) * Orycaephilus spp . * Ot iorhynchus spp .- > Phlyctinus spp .，麗金 © 屬（P〇Pi 11 ia spp.) 跳甲靥（Psylliodes spp.) » Rhizopertha spp.，金龜科（S c a r ab e i da e)，米象屬（S i t oph i 1 us spp.)，蛾屬（Sitotroga spp .)，擬步甲屬（T en e b r i o spp . )，粉甲屬.（T r i b o 1 i um s pp .)及皮蠢屬（T r o g 〇 d e r m a spp .); 來自直翅目（Orthoptera)的昆蟲，例如蜚蠊屬（Blatta spp.) *德國小蠊屬（Blattella -8 4 _ 本紙乐尺度適用中國國家標準（CNS ) A4規格（210X 297公釐} . .... r I 厂— 訂 . '~'" (請先閱讀背面之注意事項再填寫本頁) 433982^ A7 B7 經濟部中央標準局員工消費合作社印製五、發明説明（(J^) SPP·)，螻蛄屬（Gryllotalpa SPP ·)，馬得拉蜚蠊屬 (Leucophaea maderae)，飛蜂屬（Locusta spp.)，大蠊.鏖（Periplaneta spp.)及蚱猛屬（Schistocerca spp.)；來自等翅目（Isoptera)的昆蟲，例如，白蟻屬（ Reticulitermes spp.); 來自嚙蟲目（Psocoptera)的昆蟲，例如，書虱靥（ Liposcelis spp.); 來自蝨目（Anoplura)的昆蟲*例如*盲蝨屬（ Haematopinus spp，） * 長額蟲靥（Linognathus spp. )，蝨屬（Pediculus spp ·)，瘿棉蚜屬（Pemphigus spp .)及根瘤蚜屬（Phylloxera spp.); 來自食毛目（Mallophaga)的昆蟲，例如，Lissorhoptrus spp., Melolontha spp. * Orycaephilus spp. * Ot iorhynchus spp.- > Phlyctinus spp., Psylliodes spp. »Rhizopertha spp., S car ab ei da e, S it oph i 1 us spp., Sitotroga spp., T en ebrio spp., T ribo 1 i um s pp. And T rog Oderma spp.; Insects from Orthoptera, such as Blatta spp. * German cockroach (Blattella -8 4 _ This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm)... R Factory — Order. '~' &Quot; (Please read the precautions on the back before (Fill in this page) 433982 ^ A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy Locusta spp., Periplaneta spp. And Schistocerca spp .; from Isopt era) insects, eg, Reticulitermes spp .; insects from the order Psocoptera, eg, Liposcelis spp .; insects from the order Anoplura * eg * (Haematopinus spp,) * Linognathus spp., Pediculus spp., Pemphigus spp., And Phylloxera spp .; from the order of Mallophaga Insects, for example,

Daialinea spp.及羽益屬（Trichodectes spp.); 來自理翅目（Thysanoptera)的昆蟲•例如*蘇馬屬 ( Frankliniella spp.) 馬屬（Hercinothrips spp ·)，薊馬屬（Taeniothrips spp.) > T h r i p s Palffli ，棉M 馬（Thrips tabaci)及黃薊馬（ -85- 本紙張尺度適用中國國家標车（CNS ) A4規格（2I0X297公釐） ^ ..裝訂泳 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作杜印製 Λ 3 39 8 a? Β7 五、發明説明（Pj )Daialinea spp. And Trichodectes spp .; Insects from Thysanoptera • For example * Frankliniella spp. Hercinothrips spp · Taeniothrips spp. &Gt; T hrips Palffli, cotton M horse (Thrips tabaci) and yellow thrips (-85- This paper size applies to China National Standard Car (CNS) A4 size (2I0X297 mm) ^ .. binding swimming (please read the note on the back first) Please fill in this page for further information) Consumption Cooperation by Employees of the Central Bureau of Standards, Ministry of Economic Affairs, Λ 3 39 8 a? Β7 V. Description of Invention (Pj)

Scirtothrips auranti i)；來自異翅目（Heteroptera)的昆蟲'例如，臭蟲屬（ Cisiex spp.) ， Distantiella theobroma，紅捲象靥（ Dysder cus spp. ) » Euchistus spp.，椿象屬（Scirtothrips auranti i); Insects from Heteroptera 'for example, Cisiex spp., Distantiella theobroma, Dysder cus spp. »Euchistus spp.

Eurygaster spp ,)，緣樁象屬（Leptocor isa spp .) ，綠樁屬（Nezara spp·)，擬網樁象靥（Piesma spp .) ， Rhodnius spp.，Sahlbergella singularis » 黑樁象靥（Scotinophara spp_)及獵樁象靥（Triatoraa spp .)；來自同翅目（Homoptera)的昆蟲，例如，綿粉風（ A1 eurothrixus floccosus)，粉显（A 1 eyrodes b i? a s s i c a e)，圓阶屬（Ao n i d i e 11 a spp.)，扮科（Eurygaster spp,), Leptocor isa spp., Nezara spp., Piema spp., Rhodnius spp., Sahlbergella singularis »Scotinophara spp_ ) And Triatoraa spp .; insects from Homoptera, such as A1 eurothrixus floccosus, A 1 eyrodes bi? Assicae, Ao nidie 11 a spp.)

Ap h i d i d a e )，晚屬（A p h i s spp·)，圓阶屬（Ap h i d i d a e), late genus (A p h i s spp ·), round order genus (

Aspidiotus spp·)，烟粉虱（Bemisia tabaci)，繼阶屬（C e r〇p 1 as t e! spp .)，.茶褐圓阶（Chrysomphalus ao n i d i unt)，蓄薇輪紛（C h r y s o mp 11 a 1 u s dictyosperrni )，芒果福軟盼（C o c c u s . h e s p e r i d u m) *微葉禪屬（Aspidiotus spp.), Bemisia tabaci, Ceropp 1 as te! Spp., Chrysomphalus ao nidi unt, C hryso mp 11 a 1 us dictyosperrni), C occus. hesperidum) * 微叶禅属（

Einpoasca s p p . ) * 蘋果綿扮（E r i o s o m a 1 a r i g e r u ra)，斑葉螺屬（Erythroneura spp.) > Gascardia spp. * 飛凰屬（Laodelphax spp.)，李蠟阶（Lecanium corni )，规蚧屬（Lepidosaphes spp·)，長管蚜屬 -8 6 _ 本紙張尺度逋用中國國家標準（CNS } A4規格（210X297公釐） ^ 私衣 I !訂—! I 級 {讀先閱讀背面之注意事項再填寫本頁) 經濟部中央樣準局貝μ消費合作社印製 4 3 39 8 2迖 at B7 五、發明説明（#) (Macrosiphm spp ·)，瘤額蚜屬（Myzus spp.), Nephotettix spp .，稻显屬（Ni1aparvata spp.)，Einpoasca spp.) * Eriosoma 1 arigeru ra, Erythroneura spp. &Gt; Gascardia spp. * Laodelphax spp., Lecanium corni, regulations Genus (Lepidosaphes spp ·), Long aphid genus-8 6 _ This paper uses the Chinese National Standard (CNS) A4 size (210X297 mm) ^ 衣衣 I! 订 —! Class I {Read the note on the back first Please fill in this page again.) Printed by the Central Samples Bureau of the Ministry of Economic Affairs, Bei μ Consumer Cooperative, 4 3 39 8 2 迖 at B7 V. Description of Invention (#) (Macrosiphm spp ·), Myzus spp., Nephotettix spp., Ni1aparvata spp.,

Paratona spp.，癖棉姐屬（Pemphigus spp.)，粉阶屬（P 1 anoco c cus spp .)，白紛靥（pseudaulacasp is spp .)，粉紛屬（ Pseudococcus spp.)，木蝨屬（ Psy 11 a spp .) > Pu 1 v inar i a aet liiοpica，圓蚧属（Paratona spp., Pemphigus spp., P 1 anoco c cus spp., Pseudaulacasp is spp., Pseudococcus spp. Psy 11 a spp.) &Gt; Pu 1 v inar ia aet liiοpica,

Quadraspidiotus spp .) ， Rhopalosiphura spp.* 葱紛屬（Saissetia s pp .) * 葉掘靥（S c apho i d e u s spp . )，二叉蚜靥（Schizaphis spp.)，溢管蚜靥（Quadraspidiotus spp.), Rhopalosiphura spp. * Saisia spp. * Sac apho i d e u s spp., Schizaphis spp.

Sitobion spp.)，溫室白粉蟲（Trialeurodes vaporar iorum) ， Trioza erytreae 及橘盾松(Unaspi s c i t r i); 來自膜翅目（Hymenoptera)的昆蟲*例如， Acromyrmex ，切葉 _ 屬（Atta spp.)，麥莖蜂屬（ Cephus spp ‘），鋸角葉蜂屬（D ipr ion spp.)，鋸角葉蜂科（D i p r i ο n i d a e) ， G i 1 p i n i a p o 1 y t o id a > 葉蜂屬（Sitobion spp.), Trialeurodes vaporar iorum, Trioza erytreae and Unaspi scitri; insects from Hymenoptera * For example, Acromyrmex, Atta spp., Wheat Cephus spp ', Dirpion spp., Diprinidae, G i 1 piniapo 1 yto id a >

Hoplocampa s pp )，摄屬（L as i u s spp.)，厨懷.（ Monofflorium pharaonis)，葉條屬（Neodiprion spp.) 1 火蟠屬（Solenopsis spp·)及黃蜂屬（Vespa SPP _ )；來自雙翅目（Diptera)的昆蟲，例如，伊蚊屬（ -87- 本紙張尺度適用中國國家標準{ CNS ) A4規格（210X297公漤) (請先閲讀背面之注意事項再填寫本頁) 訂經濟部中央標準局買工消費合作社印策 4 3 39 8 2 ：^ A7 B7 五、發明説明（(Pf)Hoplocampa s pp), Las ius spp., Monofflorium pharaonis, Neodiprion spp. 1 Solenopsis spp. And Vespa SPP _); from Insects of Diptera, for example, Aedes (-87-) This paper size applies Chinese National Standard {CNS) A4 (210X297 cm) (Please read the precautions on the back before filling this page) Printed by the Central Standards Bureau of the Ministry of Purchase and Consumer Cooperatives 4 3 39 8 2: ^ A7 B7 V. Description of Invention ((Pf)

Aedes s pp -) * Anther igona soccata·毛蚊(Bibio hortulanus) * 紅頭麗蠅（Calliphora erythrocephala) > € ϋ M (Ceriititis spp.) ， Chrysoiyiai spp·’ 痘抆屬（Culex spp.)‘，疽蠅屬（Cuterebra spp·) ，實蠅屬（Dacus spp.)，黃猩猩果挪（Drosophila m e 1 an o g a s t e r)，廢繩屬（F1 a π n i a spp·) ’Aedes s pp-) * Anther igona soccata · Bimos hortulanus * Calliphora erythrocephala > € ϋ M (Ceriititis spp.), Chrysoiyiai spp · 'Culex spp.', Gangrene (Cuterebra spp ·), Dacus spp., Drosophila me 1 an ogaster, F1 a π nia spp · '

Gastrophilus spp ·，舌蠅靥（G1 ossina spp ‘），皮蠅靥（Hypoderma spp.) ， Hyppobosca spp.，潛繩屬（Liriontyza s p p )，綠蠅靥（L u c i i i a spp.) »Gastrophilus spp · G1 ossina spp ‘, Hypoderma spp., Hyppobosca spp., Liriontyza s p p, Green fly magpie (L u c i i i a spp.)»

Melanagroniyza spp.，象蠅屬（Musca spp.)，狂蠅屬（Oestrus spp.) * Orseolia spp·，瑞典麥稈蠅（ Oscinel la frit)，甜菜潛葉花挪（Pegomyia hyoscyami )， Phor bi a spp.，蘋果實蠅（ Rhagoletis poaion e 11 a )，尖眼茸蚊靥（S c i a r a spp.)，蝥繩屬 { S t omoxos spp.)，牛蛇屬（T ab anus spp .) Tanni a spp ·及大蚊屬（T ipul a _ spp ); 來自蚤目（Siphonaptera)的昆蟲，.例如，蚤屬（ Ceratophyllus spp·)及東方鼠蚤（Xenopsylla c h e o p i s ) ; 來自雙尾目（Thysanura)的昆蟲，例如》西洋衣魚（ Lepisna sacchar ina);及 —8 8 - 本紙張尺度適用中國國家標準{ CNS ) A4規格（210X297公釐） n I :、訂......; — Λ_^. (請先閲讀背面之注意事項再填寫本頁) 433982α A 7 Β7 五、發明説明（找）來自摘目（Acarina)的毘蟲，例如，粗腳粉觸（Melanagroniyza spp., Musca spp., Oestrus spp. * Orseolia spp., Oscinel la frit, Pegomyia hyoscyami, Phor bi a spp ., Apple fruit fly (Rhagoletis poaion e 11 a), Sciara spp., T omoxos spp., T ab anus spp. Tanni a spp · Tipul a s spp; insects from the order Siphonaptera, for example, Ceratophyllus spp. And Xenopsylla cheopis; insects from the order Thysanura, for example 》 Lepisna sacchar ina; and — 8 8-This paper size applies the Chinese National Standard {CNS) A4 specification (210X297 mm) n I:, order ...; — Λ_ ^. (Please (Read the precautions on the back before filling this page) 433982α A 7 Β7 V. Description of the invention (find) The worms from Acarina, for example, thick-footed powder touch (

Ac ar us siro)，枯芽瘦蟎（Aceria sheldoni)，娘剌瘿擬（Aculus schlechtendali)，花練屬（Amblyomaia spp .)，隱曝蛛屬（Ar gas spp ·)，蜂屬（Boophi 1 us spp )，短鬚蟎（ Brevipalpus spp.)，苜蓿苔蟎（Ac ar us siro), Aceria sheldoni, Aculus schlechtendali, Amblyomaia spp., Ar gas spp., Boophi 1 us spp), Brevipalpus spp.

Bi'yobia praetiosa)，上三節溺熵屬（Calipitrimerus spp.)，癢蟎屬（Chorioptes spp.)，雞剌皮蟎（ Dermanyssus gallinae )，鶴耳櫪始葉摘（Bi'yobia praetiosa), Calipitrimerus spp., Chorioptes spp., Dermanyssus gallinae, Pickle leaf

Eotetranychus c ar p i n i)，瘦描屬（E r i o pby e s spp. )，Hyal omma spp.，硬碑屬（Ixodes spp.)，草地小爪蟎（ Olygonychus pratensis )，鈍嗲螝屬（ Ornithodoros spp_) * 全爪摘屬（ Panonychus spp. )j Phyl locoptruta o 1 e i vor a * Polyphagotarsonemus latus ，痛摘屬（P s o r o p t e s s pp .) * Rhipicephalus spp.，根摘屬（ Rhizoglyphus spp.)，疥摘屬（ Sarcoptes spp.)，線插屬（Tarsonemus spp.)及紅葉暢屬（T e t r a n y c h ii s s p p .)。被提到的植物致病性真菌包括，例如：來自不完全真菌翻（Fungi imperfecti)，例如 -89- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂經濟部中央標準局負工消費合作社印製 4 3 3982」 A7 B7 經濟部t央標隼局員工消費合作社印製五、發明説明（/p 葡萄孢菌靥（ Botrytis spp.) ’微火菌屬（ Pyricularia spp .)，長孀孢菌靥（Helminthospor ium spp )，鐮刀菌屬（Fusar ium spp .) ’殼針抱菌’屬（ Septoria spp ·) ’ 尾孢菌屬（Cercospora spp·)， Altemaria spp·；擔子菌網（Basidiomycetes) ’例如絲核菌屬（Rhizoctonia spp.) »咖啡駝孢菌屬（ Hentileia spp )及柄銹菌屬（P uc c i n i a spp .); 來自子囊菌綱（Ascomycetes) ’例如黒星菌屬（Venturia spp_)，紅管菌屬（Erysiphe spp.)，叉綠軍囊骰屬（Podosphaera spp.)，叢梗孢菌屬（Monilinia spp .)，及釣絲殻靥（Unc inul a spp .); 卵孢菌網（Oomycetes)，例如：疫徽屬（Phytophthora spp .)，腐徽屬（pythium s pp .)及單軸徽屬（P 1 a s mo pa r a spp.)。 -90- (請先閱請背面之注意事項再填寫本頁) 1'- 訂 /A. 本紙法尺度適用中國國家標準（CNS ) A4規格（210X297公釐} 經濟部中央標準局員工消費合作杜印製 43 39 82^ at B7 五、發明説明（cT(f) 使用本發明之活性化合物類可用以控制，即抑制或破壞上述特別發生在植物之害蟲種類，更特別的是在農業上，圜藝學上及森林學上的農作物及景觀植物，或這些植物的一部份，如果實，花*葉，莖*塊莖或根，甚而這些植物稍後時期成長的一些部份亦額外受到保護而免於這些害蟲的侵害。目標作物為，特別是》穀物類*如小麥，大麥，裸麥，燕麥，稻米，玉米或高梁；甜菜，如糖甜菜及飼料（ f 〇 d d e r)甜菜；果實類，例如梨果類，堅果及軟果，如蘋果類，梨頚，桃類，水蜜桃類*杏仁類，櫻桃類或莓類，例如草莓類，覆盆子類（raspberry)及藍莓類；亘科植物類*如豌豆，金麥豌（lentil)，青豆或黃豆；油脂作物類|如油菜，芥菜，罌粟，橄欖，向日葵，椰子，蓖麻油植物，可可亞或花生；黃瓜植物類，如南瓜類，黃瓜類或甜瓜類；纖維性植物，如棉花，亞麻，廠或黃麻；柑桔屬 (citrus)水果，如橘類，檸樣類•葡萄柚或酸橙類；蔬菜類，如菠菜*萵苣*蘆筍類，包心菜類•胡蘿蔔類，洋蔥類，番茄類，馬鈐薯類或甜椒類；月桂科（lauraceae) ，如酪梨類（avocado) *桂皮或樟腦；K及煙草，胡桃，咖啡•茄科植物（aubergines) *甘蔗，茶樹，藤類，蛇麻類（hops)，芭蕉科植物，天然橡膠植物類以及觀寊用 -9 1- 本紙張尺度適用中國國家標準（CMS ) A4規格（210 X 297公釐） *^-- (請先聞讀背面之注意事項再填寫本頁) 訂 433982」經濟部中央標率局員工消費合泎社印說 A7 B7 五、發明説明（<^) 植物類。根據本發明之活性化合物類特別合適控制毘蟲及蟎目的代表*特別是在棉花，果實，玉米，黃豆，藤及蔬菜農作物上的植物病原性喷食害蟲*如 Anthonomus grandis ，葉甲屬昆蟲（Diabrotica b a It e a t a)，棉蛉蟲屬毘蟲 (Heliothis virescens)幼蟲，小葉蛾（Piutella x y 1 o s t e 11 a)及夜蛾屬昆蟲（S p o d o p t e r a 1 i 11 o r a 1 i s)幼蟲，及挪姝摘類，如紅葉摘.屬（Tetranychus spp.) 〇依據本發明之活性成份之混合物的其它方面應用在於保護貯存的貨物，貯備物及物質，及衛生範圍，特別是保護飼養動物及生產性家畜以對抗前述種類的害蟲。本發明因此亦相關於除害劑類，依據想要的目的及蟲害盛行的環境*如可乳化的濃縮物類，懸浮性濃縮物類* 直接可噴灑性或直接可稀釋性溶疲類*可分佈之糊狀物類 *可稀釋性乳化劑類，可溶解的粉末類，可分散性粉末類，可溼濁性粉末類，粉塵類，賴粒類或在聚合性材料中的囊化物類，其包含至少一種依據本發明之活性化合物類。在這些組成物中，活性成份以純化的型式被施用：例如 > 固體活性成份以特定顆粒大小施用，或偏好地與至少 -92- 本紙乐尺度通用中國國家標準（CNS ) Α4規格（210 X 297公釐） - -—^1 _ I - 1 - I I-- k. - H (請先閲讀背面之注意事項再填寫本頁) -,?τ 線經濟部中央標準局員工消費合阼'?±.中笑 433982^ A7 B7 五、發明説明（t27) 一種在調劑技術領域中習慣使用的佐劑一起施用’佐劑可為擴散劑類’例如溶劑類或固體®劑類f或界面’活性化合物類（界面活性劑類）°本發明組成物類亦可包含ϋν—安定劑類，如苯並三唑’二苯嗣’草酸醯苯胺’肉桂酸或8一三嗪一衍生物。溶劑類之實例為：未氣化或部份.氫化之芳香性羥類，偏好為Cs到Ci 2的烷基苯類部份’例如二甲苯混合物’ 烷基化萘類或四氫萘，脂肪性或環脂肪性羥類’例如石臘類或環己烷，醇類，如乙醇’丙酵或丁酵，乙二醇類及其醚類及酯類，如丙二醇’二伸丙基乙二醇醚’乙二醇，乙二醇單甲基醚或乙二醇單乙基醚，釅類，如環己嗣，異佛 _或二丙嗣酵*強烈極性溶劑類，如N —甲基吡咯烷- 2 _ 酮，二甲基亞厢或ίΐ，N —二甲基甲醯胺，水，未環氧化或環氣化之植物油類，如未環氣化或環氧化之菜油，蓖麻油，椰子油或黃豆油，Μ及矽酮油類。所使用的固體載劑類，洌如針對粉塵類或可散佈之粉末類，通常為地面天然碾物類，如方解石（caicite)，滑石，高嶺土（ k a ο 1 i η)，蒙脫土（ m ο n t m 〇 r i 11 〇 n i t e)或美國活性白土（attapulgUe)。為了改菩其物理捋性，亦有可能使用高度敗佈之矽化合物或高度散佈之吸收性聚合物。針對顆粒製劑之合適粒狀吸收性載體類為多孔性型態， _ 9 3 — 本紙張尺度適用中國國家標準（CNS > A4規格（210X297公釐} -----Γ ----?^衣-- (請先閱讀背面之注意事項再填寫本頁) 訂 A7Eotetranychus c ar pini), Erio pby es spp., Hyal omma spp., Ixodes spp., Olygonychus pratensis, Ornithodoros spp_) * Panonychus spp. J Phyl locoptruta o 1 ei vor a * Polyphagotarsonemus latus, P soroptess pp. * Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp. .), Tarsonemus spp. And Tetranych ii sspp. The mentioned phytopathogenic fungi include, for example: Fungi imperfecti, such as -89- This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Please read the back Note: Please fill in this page again.) Order printed by the Central Standards Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives. 4 3 3982 "A7 B7 Printed by the Consumers Cooperative of the Central Bureau of Standards and Labor of the Ministry of Economic Affairs. 5. Description of the invention (/ p Botrytis (Botrytis spp.) 'Pyricularia spp.', Helminthospor ium spp., Fusar ium spp. 'Septoria spp.' 'Cercospora Cercospora spp ·, Altemaria spp ·; Basidiomycetes' for example Rhizoctonia spp. »Hentileia spp and P uc cinia spp. From Ascomycetes' For example Venturia spp_, Erysiphe spp., Podosphaera spp., Monilinia spp. , And fishing line shell inul a spp.); Oomycetes, for example: Phytophthora spp., Pythium s pp. and P 1 as mo pa ra spp. -90- (Please read the notes on the back before filling in this page) 1'-Order / A. The size of this paper method is applicable to Chinese National Standard (CNS) A4 (210X297 mm) Printed 43 39 82 ^ at B7 V. Description of the invention (cT (f) The use of the active compounds of the present invention can be used to control, that is, to inhibit or destroy the above pest species that occur particularly in plants, more particularly in agriculture, 圜Artistic and forestry crops and landscape plants, or parts of these plants, if real, flowers * leaves, stems * tubers or roots, and even some parts of these plants that grow in later periods are additionally protected and Protected against these pests. Target crops are, in particular, cereals * such as wheat, barley, rye, oats, rice, corn or sorghum; sugar beets, such as sugar beets and fodder beets; fruits, Such as pears, nuts and soft fruits, such as apples Fruits, pears, peaches, peaches * almonds, cherries or raspberries, such as strawberries, raspberry and blueberries; Polygonaceae * such as peas, lentil , Green beans or soybeans; oil crops | such as canola, mustard, poppy, olive, sunflower, coconut, castor oil plants, cocoa or peanuts; cucumber plants, such as pumpkins, cucumbers or melon; fibrous plants, such as Cotton, flax, plant or jute; citrus fruits, such as tangerines, lemons • grapefruit or limes; vegetables, such as spinach * lettuce * asparagus, cabbages, carrots, onions Types, tomatoes, yam or sweet peppers; lauraceae, such as avocado * cinnamon or camphor; K and tobacco, walnuts, coffee • aubergines * sugar cane, tea trees , Rattans, hops, Musa plants, natural rubber plants, and ornamental -9-1- This paper size applies to the Chinese National Standard (CMS) A4 specification (210 X 297 mm) * ^- (Please read the notes on the back before filling in this page ) Order 433982 "A7 B7 printed by the Consumer Consumption Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of Invention (&) Plants. The active compounds according to the present invention are particularly suitable for controlling parasites and mites. * Especially phytopathogenic spraying pests on cotton, fruits, corn, soybeans, vines and vegetable crops * such as Anthonomus grandis, leaf insects ( Diabrotica ba It eata), larvae of Heliothis virescens, small leaf moths (Piutella xy 1 oste 11 a) and larvae of S podoptera 1 i 11 ora 1 is , Such as red leaf pick. Genus (Tetranychus spp.) 〇 Other aspects of the active ingredient mixture according to the present invention are used to protect stored goods, stocks and substances, and sanitary scope, especially to protect domestic animals and productive livestock against Pests of the aforementioned kind. The present invention is therefore also related to pesticides, depending on the desired purpose and the environment in which pests prevail * such as emulsifiable concentrates, suspension concentrates * direct sprayable or directly dilutable lysotropic * Distribution pastes * dilutable emulsifiers, soluble powders, dispersible powders, wettable powders, dusts, granules or encapsulations in polymerizable materials, It contains at least one active compound according to the invention. In these compositions, the active ingredient is applied in a purified form: for example,> solid active ingredient is applied at a specific particle size, or it is preferred to be at least -92- Chinese paper standard (CNS) A4 specification (210 X 297 mm)--— ^ 1 _ I-1-I I-- k.-H (Please read the precautions on the back before filling out this page)-,? τ Consumer spending for the Central Standards Bureau of the Ministry of Economic Affairs' ±. Zhongxiao 433982 ^ A7 B7 V. Description of the Invention (t27) An adjuvant customarily used in the field of dispensing technology is administered together with 'adjuvants can be diffusing agents' such as solvents or solids ® agents or interfaces' Active compounds (surfactants) ° The compositions of the present invention may also include ϋν- stabilizers, such as benzotriazole 'diphenylhydrazone' oxalate aniline 'cinnamic acid or 8-triazine-derivatives. Examples of solvents are: non-gasified or partially hydrogenated aromatic hydroxys, alkylbenzenes that prefer Cs to Ci 2 'e.g. xylene mixtures' alkylated naphthalenes or tetrahydronaphthalenes, fats Sexual or cycloaliphatic hydroxyls' such as paraffin or cyclohexane, alcohols such as ethanol 'propionate or butyrate, glycols and their ethers and esters, such as propylene glycol' dipropylene glycol Alcohol ether 'ethylene glycol, ethylene glycol monomethyl ether or ethylene glycol monoethyl ether, amidines, such as cyclohexane, isophorol or dipropionase * Strongly polar solvents, such as N-methyl Pyrrolidine-2 _ ketone, dimethyl subbox or 或, N-dimethylformamide, water, unepoxidized or epoxidized vegetable oils, such as unepoxidized or epoxidized vegetable oil, castor oil , Coconut oil or soybean oil, M and silicone oils. The solid carriers used, such as for dusts or dispersible powders, are usually ground natural grounds, such as calcite, talc, kaolin (ka ο 1 i η), montmorillonite (m ο ntm 〇ri 11 〇nite) or American activated clay (attapulgUe). In order to change its physical properties, it is also possible to use highly tarnished silicon compounds or highly dispersed absorbent polymers. The suitable granular absorbent carrier for granular preparations is porous. _ 9 3 — This paper size applies to Chinese national standards (CNS > A4 specifications (210X297 mm) ----- Γ ----? ^ Clothing-(Please read the precautions on the back before filling this page) Order A7

4339824J B7 五、發明説明（f|l ) 例如浮石（pumice)，磚砂（brick grit)，海泡石（ sepiolite)或澎潤土（bentonite)，且合適的非圾收性載體材料為方解石或砂。進而，可使用具無機或有機特性之大量顆粒狀材料*特別是白雲石（dolomite)或粉碎之植物殘留物類。合適之界面活性化合物類為，依據欲調配之化合物的天然特性，非離子性，陽離子性及/或陰離子性界面活性劑類或具有良好之乳化，散佈及濕潤特性之界面活性劑温合物。下列的界面活性劑僅打算視為實例*在調劑技術領域所習慣使用及適於本發明用途之更多的其它界面活性劑見述於相翮的文獻資料中。合適之非離子性界面活性劑主要為脂肪性或環脂肪性醇頚之聚乙二醇醚類衍生物類，鉋和或未飽和之脂肪酸類及烷基酚類，其具有3到3 G個乙二醇醚基團，且在（脂肪性 )羥自由基上具有8到2 0個碳原子且在烷基酚類的烷基自由基上具有6到18個碳原子。合適的尚有添加聚伸丙基乙二酵，伸乙基二胺基聚伸丙基乙二醇及烷基聚伸丙基乙二醇之水溶性聚環氧乙烯加成物*其在烷基鐽上具有1到1Q個碳原子且包括20到2 5 0個伸乙基乙二醇醚基團及10到1〇〇個伸丙基乙二醇醚基圑。上述之化合物通常每一個伸丙基乙二醇單元具有1至5個伸乙基乙二醇單元。常被提到之實例為壬 ~ 9 4 一本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） I I. II I I —典衣訂u I ^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央樣準局員工消費合作社印製 433982禳 A7 B7 經濟部中夬標準局員工消費合作枉印裝五、發明説明（基酚聚乙氧基乙醇類，蓖麻油聚乙二醇醚，環氧丙烯/環氧乙烯加成物類，三丁基苯氧基聚乙氧基乙醇*聚伸乙基乙二醇及辛基酚聚乙氧基乙醇。其他合適的為脂肪酸酯類或聚氧乙烯山梨糖，如三油酸聚氧乙烯山梨糖酯。陽雜子性界面活性劑主要為四级銨鹽類，其具有至少一種具有8到2 2個碳原子的烷基團作為取代基類且，具有較低级，鹵化或未鹵化之烷基，苄基或較低級之羥基烷基團作為進一步之取代基類。此鹽類偏好為鹵化物類，甲基硫酸鹽類或乙基硫酸鹽類之形式。實施例為硬脂酿基一三甲基一氯化鞍及苄醯基一二一（2 —氯乙基）乙基溴化銨。合適之陰離子性界面活性劑可為水溶性皂類Μ及水溶性人工合成界面活性化合物類。合適的皂類為鹼金屬鹽類，鹼土金屬鹽類或經取代的或未經取代的較高趿脂肪酸（C ^ 〇 — C 2 2 )之銨鹽類*例如油酸或硬脂酸之鈉鹽類或鉀鹽類*或為天然脂肪酸温合物之鈉鹽或鉀鹽類，其可得自椰子神或松漿油；進而必須提及的是脂肪酸甲基胺基乙磺酸鹽類。然而，所請人工合成式界面活性劑則'比較常用，特別是脂肪性磺酸鹽頚，脂肪性硫酸鹽類，磺酸化苄咪唑衍生物類或烷基月桂醢磺酸鹽類。該脂肪性磺酸鹽類及脂肪性硫酸鹽類通常為齙金屬鹽類*鹼土金屬盥類或經取代的或未經取代之銨鹽類的型式，且通常具有8到2 2個碳原子 -95- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） n —ί n in I n V' n n n II 1^1 T n I n I n 0¾ τα 势 <請先閱讀背面之注意事項再填寫本頁) 經濟部中央標率局貝工消費合作社印？4 433982^ A7 B7 五、發明説明的烷基自由基，烷基亦包括醯基之烷基團’例如木質素磺酸鹽，十二烷基硫酸酯或從天然性脂肪酸加以製備的脂肪醇硫酸鹽混合物之納鹽或鈣鹽。此群亦包括脂肪醇之硫酸醇類及磺酸類/環氧乙烷加成物之鹽類。磺酸化的苄咪唑衍生物類偏好包括2個磺醯基團及一個大約具有8到2 2個碳原子的腊肪酸自由基。烷基月桂醢磺酸鹽頚為*例如1十二烷基苯磺酸或萘磺酸/甲醛濃縮產物之鈉盥類，鈣鹽類或三乙醇铵鹽類。合適的磷酸鹽類*例如對_壬基酚-（4 - 14) 一環氧乙烷加成物之磷酸酯鹽類，或者磷脂類亦為適合的。通常，該組成物類包含〇 . 1 %到3 3 % *特別是Q . 1 %到 35%之活性化合物，以及1%到99 . 9%，特別是5%到39 . 9 %之至少一種固體或液體佐劑，可能地*通常組成物之〇% 到2 5%，特別是0 . 1 %到2 0%，為界面活性劑類（％茌每種情形下表示重量百分比）。然而濃縮的組成物則比較偏好作為商業上可購得之貨品，通常最後消費者使用稀釋過的組成物類•其具有相當低濃度之活性物質。偏好之組成物特別是由以下所組成（％ =重量百分宰）：可乳化的濃縮物類：活性成份之混合物：1%到9096，偏好為5%到20% -96- 本紙張尺度適用中國國家標羋（CNS〉A4規格U10X297公釐） (請先閱讀背面之注意事項再填寫本頁) 装- 訂經濟部中央標準局員工消費合作社印製 4339 82^ A7 B7 五、發明説明（今w 界面活性劑： 1%到30%，偏好為到20% 溶劑： 5%到98%，偏好為70%到85% 粉塵類：活性成份之混合物：〇 · 到1 ，偏好為〇 · 1%到1% 固體載劑： 99.9%到90%，偏好為89.9%到99% 懸浮性濃縮物類：活性成份之混合物：5%到75%，偏好為10%到50% 水： 94%到24%，偏好為88%到30% 界面活性劑： 1 %到4 Q %，偏好為2 %到3 0 % 可濕潤之粉末類：活性成份之溫合物：0 . 5%到9 Q%，偏好為1%到80% 界面活性劑： 0 . 5 %到2卩％，偏好為1%到1 5 % 固體載劑： 5%到39%，偏好為15%到38% 顆粒類：活性成份之混合物：0 . 5%到3 0%，偏好為3%到 -97- 本紙悵尺度適用中國國家標準（CNS〉A4規格（2丨0X29*7公釐) (請先閲讀背面之注意事項再填寫本頁) 、\Ηβ4339824J B7 5. Description of the invention (f | l) For example pumice, brick grit, sepiolite or bentonite, and suitable non-garbage carrier materials are calcite or sand. Furthermore, it is possible to use a large amount of granular materials *, especially dolomite or pulverized plant residues, which have inorganic or organic characteristics. Suitable surfactants are surfactants based on the natural characteristics, non-ionic, cationic and / or anionic surfactants of the compound to be formulated or surfactants with good emulsifying, dispersing and wetting properties. The following surfactants are intended to be examples only. * Other surfactants customarily used in the field of dispensing technology and suitable for the purposes of the present invention are described in the relevant literature. Suitable non-ionic surfactants are mainly polyethylene glycol ether derivatives of fatty or cycloaliphatic alcohols, planed and / or unsaturated fatty acids and alkyl phenols, which have 3 to 3 G Glycol ether group, and has 8 to 20 carbon atoms on the (fatty) hydroxyl radical and 6 to 18 carbon atoms on the alkyl phenolic alkyl radical. Suitable water-soluble poly (ethylene oxide) adducts of added poly (ethylene propylene glycol), poly (ethylene diamine) poly (ethylene glycol) and alkyl poly (ethylene glycol) * The hydrazone has 1 to 1Q carbon atoms and includes 20 to 250 ethylene glycol ether groups and 10 to 100 propylene glycol ether ethers. The above compounds usually have 1 to 5 ethylene glycol units per ethylene glycol unit. Examples often mentioned are Ren ~ 9 4 A paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) I I. II II—Ding Yiu u I ^ (Please read the precautions on the back before (Fill in this page) Printed by the Consumer Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs 433982 禳 A7 B7 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 枉 Printing 5. Description of Invention Alcohol ethers, propylene oxide / ethylene oxide adducts, tributylphenoxy polyethoxyethanol * polyethylene glycol and octylphenol polyethoxyethanol. Other suitable are fatty acid esters Or polyoxyethylene sorbose, such as polyoxyethylene sorbitan trioleate. The cationic surfactants are mainly quaternary ammonium salts, which have at least one alkyl group having 8 to 22 carbon atoms. As a substituent, and has a lower, halogenated or unhalogenated alkyl group, benzyl or a lower hydroxyalkyl group as a further substituent. This salt is preferably a halide, a methyl sulfate Or ethyl sulfates. Examples are stearin Methyl saddle chloride and benzamidine 1,2 (2-chloroethyl) ethylammonium bromide. Suitable anionic surfactants can be water-soluble soaps M and water-soluble synthetic surface-active compounds. Suitable soaps are alkali metal salts, alkaline earth metal salts or ammonium salts of substituted or unsubstituted higher ammonium fatty acids (C ^ 〇-C 2 2) * such as sodium oleic acid or sodium stearate Salts or potassium salts * or sodium or potassium salts of natural fatty acid warm compounds, which can be obtained from coconut god or pine oil; furthermore, fatty acid methylaminoethane sulfonate must be mentioned. However, the artificial surfactants are more commonly used, especially fatty sulfonates, fatty sulfates, sulfonated benzimidazole derivatives or alkyl lauryl sulfonates. The fatty properties Sulfonates and fatty sulphates are usually 龅 metal salts * alkaline earth metal toilets or substituted or unsubstituted ammonium salts, and usually have 8 to 2 2 carbon atoms Paper size applies to China National Standard (CNS) Α4 specification (210 × 297 mm) n —ί n in I n V 'n n n II 1 ^ 1 T n I n I n 0¾ τα Potential < Please read the notes on the back before filling out this page) Printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs? 4 433982 ^ A7 B7 5. Alkyl radicals as described in the invention. Alkyl also includes alkyl groups of fluorenyl groups such as lignin sulfonate, dodecyl sulfate or fatty alcohol sulfuric acid prepared from natural fatty acids. Sodium or calcium salts of salt mixtures. This group also includes sulfate alcohols of fatty alcohols and salts of sulfonic acid / ethylene oxide adducts. The preference for sulfonated benzimidazole derivatives includes 2 sulfofluorenyl groups and a fatty acid radical with approximately 8 to 22 carbon atoms. Alkyl lauryl sulfonates are, for example, sodium dodecylbenzenesulfonic acid or naphthalenesulfonic acid / formaldehyde concentrated products, sodium salts, calcium salts or triethanolammonium salts. Suitable phosphates * such as phosphate salts of p-nonylphenol- (4-14) -ethylene oxide adducts, or phospholipids are also suitable. Usually, the composition contains 0.1% to 33% * especially Q. 1% to 35% of active compound, and 1% to 99.9%, especially at least 5% to 39.9%. Solid or liquid adjuvants, possibly * usually from 0% to 25% of the composition, in particular from 0.1% to 20%, are surfactants (% 表示 weight percentage in each case). Concentrated compositions, however, are more preferred. As commercially available products, the final consumer usually uses diluted compositions that have a relatively low concentration of active substance. The preferred composition is especially composed of the following (% = weight percent slaughter): Emulsifiable concentrates: Mixture of active ingredients: 1% to 9096, preference is 5% to 20% -96- This paper size applies China National Standards (CNS> A4 specification U10X297 mm) (Please read the precautions on the back before filling this page) Packing-Order printed by the Central Consumers Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 4339 82 ^ A7 B7 w Surfactant: 1% to 30%, preference to 20% Solvent: 5% to 98%, preference to 70% to 85% Dust: Mixture of active ingredients: 0 to 1 and preference to 0.1% To 1% solid carrier: 99.9% to 90%, preference is 89.9% to 99% Suspended concentrates: Active ingredient mixture: 5% to 75%, preference is 10% to 50% Water: 94% to 24 %, Preference is 88% to 30%. Surfactant: 1% to 4 Q%, preference is 2% to 30%. Wettable powders: warm compound of active ingredient: 0.5% to 9 Q%, Preference is 1% to 80%. Surfactant: 0.5% to 2%, preference is 1% to 15%. Solid carrier: 5% to 39%, preference is 15% to 38%. Granules: Active ingredient Mixture: 0.5% to 30%, preference is 3% to -97- The standard of this paper is Chinese national standard (CNS> A4 specification (2 丨 0X29 * 7mm)) (Please read the notes on the back before filling (This page), \ Ηβ

經濟部中央標準局員工消費合作社印裝 433982」 A7 B7 五、發明説明（yp 圃體載劑： 99 . 5%到7G%，偏好為97%到85¾ 藉由加入其他殺昆蟲性或殺蟎性活性成份*本發明組成物之作用範圍可Μ作實質上地擴展，並適合盛行的環境。在本發明中可以加入的殺昆蟲性或殺蟎性活性組成物類包括，例如*下列活性成份種類的代表：有機磷化合物類 *硝基酚類及其衍生物，甲醯基脒類，醯基尿素類，胺基甲酸酯類|擬除蟲菊酯類，硝基胺類及其衍生物類*吡咯類，硫脲類及其衍生物類，氯化氫碳化物類及蘇力桿菌（ Bacillus thuringiensis)的製葡物。這些本發明的組成物亦可包含其他固體或液體輔劑，如安定劑類，例如未經修飾的或環氧化的植物油類（例如環氧化椰子油*菜仔油或黃豆油），抗泡涞劑類，例如矽化物油類，防腐劑類，黏度調節劑類，结合劑類及/或膠黏劑類，及肥料類或其他可K達到特異性效果的活性成份，例如殺细菌劑類，殺線蟲劑類，殺蝸牛劑類或選擇性除草劑類。Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 433982 ”A7 B7 V. Description of the Invention (yp nursery vehicle: 99.5% to 7G%, preference is 97% to 85¾ by adding other insecticidal or acaricidal properties Active ingredients * The range of action of the composition of the present invention can be substantially expanded and suitable for prevailing environments. Insecticide or acaricidal active compositions that can be added in the present invention include, for example, the following types of active ingredients Representatives: organophosphorus compounds * nitrophenols and their derivatives, formamidines, amidoureas, carbamates | pyrethroids, nitroamines and their derivatives * Pyrrole, thiourea and its derivatives, hydrochloride and Bacillus thuringiensis. These compositions of the present invention may also contain other solid or liquid adjuvants, such as stabilizers , Such as unmodified or epoxidized vegetable oils (such as epoxidized coconut oil * rapeseed oil or soybean oil), antifoam tinctures such as silicide oils, preservatives, viscosity modifiers, binding agents And / or adhesives , And fertilizers or other active ingredients that can achieve specific effects, such as bactericides, nematicides, snails or selective herbicides.

本發明之組成物類K習知的方式加Μ製備*例如*在輔劑不存在的情形下，Κ研磨，篩選及/或一固體活性成份或活性成份混合物之壓製，例如可得到一被定義之顆粒大小，且當至少一種輔劑存在於之下，例如將活性物質及活性物質混合物與輔劑或輔劑温合物經過密切的溫合或/ 及研磨。本發明之目的亦為製備本發明组成物的方法及式I -98- 本纸張尺度適用中國國家榇準（CNS ) A4规格（2Ι0Χ2ί>7公釐） I n n n n I I J:訂·I I 备， (請先閱讀背面之注意事項再填寫本頁) A7 4 3 3 9 8 2:』 B7_ 五、發明説明行么〉化合物作為製備這空姐成物的用途。本發明亦相關於應用這些組成物的方法’也就是說防制上逑種類昆蟲的方法，例如噴灑’菘化’煙塵’塗抹，包覆，散佈或傾倒’其選擇則視打算之目的及流行的環境而定，並相關於用於防制上述種類昆蟲的組成物類。典型濃度的比例為介於0 · 1到10 0Q p p ®之間’偏好介於0.1到 5 0 0 ppm之間的活性成份。每公頃應用的比例通常為每公頃1 到2G00公克活性成份，特別是10到公克/公頃，偏好為2 0到6 D D公克/公頃。在農作物保護的領域中一種偏好的應甩方法為施用到植物的葉片上（葉片應用）*其施用的頻率及比率可K視個別害蟲大量感染的程度而定。然而，該活性成份可藉由 Μ—液體組成物灌溉植物生長區域或將固體型式之活性成份嵌入植物生長區域，例如嵌入土壤，例如Μ顆粒的型式 (土壤應用）而經由根系（系統性應用）到達植物。在水稻作物中，此種顆粒可Μ經計算的份量施用至水稻田中。本發明之組成物類亦合適來保護植物繁殖物質，例'如種子，如果實，塊莖或穀粒類*或植物幼苗*免於動物害蟲的危害。繁殖物質可Κ於種植前用該配方加Κ處理：例如，種子在下種前進行包覆。本發明之化合物類亦可被施 -99- 本紙張尺度適用t國國家標準（CNS ) A4規格（210X297公釐） ---------/.^-- (請先閲讀背面之注意事項再填寫本頁) ，tr 經濟部中央標準局貞工消費合作社印^ 433982^ A7 B7 五、發明説明（77) 用於穀粒（包覆作用）’其由以一種疲體配方浸覆毅物或以一種画體配方去包覆穀物。當種植繁殖物質時，該配方亦可被施用於植人位置’例如在下種時施用於田畦之上。本發明進一步之目的在於處理植物繁殖物質的方法及因而相關於被處理的植物繁殖物質。下列實施例偽意欲示範說明本發明。他們並不限制本發明。溫度覃位為攝氏。製備簧施例實施例 111: 2— 〔〔〔（1—甲基一2— (4— （3 —三氟甲基苯基甲氧基）—苯基）—2— E—〔乙氧基亞胺基〕亞乙基）胺基〕氧]甲基]—cc -(甲氧基亞甲基）一苯基乙酸甲詣及2— 〔 [ 〔（1 一甲基一2_ (4 — （3 —三氟甲經濟部中央標準局員工消費合作杜印製 (請先閣讀背面之注意事項再填寫本頁) 基苯基甲氧基）一苯基）—2_Z—〔乙氧基亞胺基〕亞乙基）胺基〕氧〕甲基]一 α —(甲氧基亞甲基）一苯基乙酸甲酯（表7中的化合物類Α.1) a) 1— 〔4一（3 —三氟甲基苯基甲氧基）一苯基]一 1 -丙_ 17 2公克之1一（氮甲基）一3—（三氟甲基）一苯被鍰 -10 0' 本紙張尺度適用中國國家榇準（CNS ) A4規格（210X297公釐）經濟部中央標準局員工消費合作社印製 4:3 39 8 2驪The composition K of the present invention is prepared by adding M in a conventional manner. For example, in the absence of an adjuvant, K grinding, screening and / or pressing of a solid active ingredient or active ingredient mixture, for example, a defined Particle size, and when at least one adjuvant is present, such as subjecting the active substance and active substance mixture to the adjuvant or adjuvant warm compound to intimate warming or / and grinding. The purpose of the present invention is also the method and formula I-98 for preparing the composition of the present invention. The paper size is applicable to China National Standard (CNS) A4 specification (2Ι0 × 2ί > 7 mm). I nnnn IIJ: Order · II. (Please read the notes on the back before filling out this page) A7 4 3 3 9 8 2: 『B7_ 5. What is the description of the invention> The use of the compound as a preparation for this stewardess. The present invention also relates to a method of applying these compositions, that is, a method of controlling insects of the upper slug type, such as spraying, 'smearing,' smoke, dust, smearing, coating, spreading, or pouring. ' Depending on the environment, and related to the composition used to control the above-mentioned insects. Typical concentration ratios are between 0 · 1 to 10 0Q p p ® ′ preference for active ingredients between 0.1 and 500 ppm. The application rate per hectare is usually 1 to 2 G00 g of active ingredient per hectare, especially 10 to g / ha, with a preference of 20 to 6 D D g / ha. A preferred method of application in the field of crop protection is to apply to the leaves of plants (leaf application) * the frequency and rate of application can depend on the degree of individual infection by a large number of insects. However, the active ingredient can be irrigated by the M-liquid composition in the plant growth area or embedded in the solid growth type of the active ingredient, such as in the soil, such as the type of M particles (soil application) through the root system (systemic application) Reach the plant. In rice crops, such particles can be applied to rice fields in calculated portions. The composition of the present invention is also suitable for protecting plant propagation material, such as' seeds, if applicable, tubers or grains * or plant seedlings * from animal pests. Propagating material can be treated with this formula plus K before planting: for example, seeds are coated before planting. The compounds of the present invention can also be applied -99- This paper size is applicable to the national standard (CNS) A4 specification (210X297 mm) --------- /. ^-(Please read the back Note for refilling this page), tr Printed by Zhengong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs ^ 433982 ^ A7 B7 V. Description of the invention (77) For grains (coating effect) 'It is covered with a fatigue formula Yiwu may use a paint formula to coat the grain. This formulation can also be applied to the planting site when planting the propagation material, for example, on a field barn at the time of seeding. A further object of the present invention is a method for treating plant propagation material and, therefore, related to the plant propagation material being treated. The following examples are intended to illustrate the invention. They do not limit the invention. Temperature Qin is Celsius. Preparation Example 111: 2— [[[(1-methyl-1 2- (4- (3-trifluoromethylphenylmethoxy) -phenyl) -2—E— [ethoxy Imino] ethylene) amino] oxy] methyl] —cc- (methoxymethylene) monophenylacetamidine and 2- [[[((1 monomethyl-2_ (4 — ( 3 —Printed by Du Fu staff of the Central Bureau of Standards, Ministry of Economic Affairs (please read the precautions on the back before filling out this page) Phenylmethoxy) Monophenyl) — 2_Z — [ethoxyimine Group] ethylene) amino] oxy] methyl] -α — (methoxymethylene) monophenylacetic acid methyl ester (compounds A.1 in Table 7) a) 1— [4 一 ( 3-trifluoromethylphenylmethoxy) -phenyl]-1-propane- 17 2 g of 1- (nitromethyl) -3- (trifluoromethyl) -benzene is fluorene-10 0 'present Paper size applies to China National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4: 3 39 8 2 骊

五、發明説明（pH 慢地加入12E)公克之1- (4_理基笼基）-1—丙酮1 2‘21 公克之碳酸鉀及500毫升之N，N —二甲基甲醯胺於室溫下形成的混合物内。之後，該反應混合物於6Q°進行搜拌1小時且隨後進行冷卻及進行過漶，並將逋液於真空狀態下進行揮發。殘餘物被溶解於乙酸乙酯中並將有機相以水清洗兩次並以飽和的氯化鈉溶疲清洗一次1以硫酸鈉進行乾燥並進行揮發，粗製產物與50 0毫升之己烷進行搅拌並進行冷卻，進行過濾並於真空狀態下進行乾燥。得到熔點63 — 4°之純化的1_ 〔4一（3—三氟甲基苯基甲氧基）-苯基〕一1 一丙嗣。 b) 1— 〔4一（3—三氟甲棊笨基甲氧基）一苯基〕_1 ，》2—丙烷二酮2 —肟 ‘ (請先閱讀背面之注意事項再填寫本頁) 訂 Μ 1 0 7公克之亞硝酸異戊基酯被媛慢地逐滴加入2 3 4 . 3公克之1- 〔4一（3—三氟甲基苯基甲氣基）一笨基]一 1一丙嗣於1500毫升之1，4 -二氧陸環之溶疲内，其以氫氮酸氣體加以酸化。該反應混合物隨後於室溫進行攪拌1 . 5小時，隨後以三乙基胺調成鹼性並於真空狀態下進行揮發。殘餘物被溶解於乙酸乙酯中且有機相Μ水進行清洗兩次並K 飽和的氯化鈉溶液清洗一次，Μ硫酸鈉進行乾燥並進行揮發粗製產物被懸浮於己烷中|進行濾除並於真空狀態下進行揮發。 -10 1- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐）經濟部中央標準局員工消費合作社印製 433982^ A7 B7 五、發明説明（户7) 得到熔點137— 8°之1— 〔4一（3—三氟甲基苯基甲氧基）一苯基〕一1*2 —丙烷二酮2 —肟。 c) 1_ [4— (3—三氟甲基苯基甲氧基）一苯基〕_1 ,2 —丙烷二酮1— E-[乙基肟〕一 2—肟及1_ 〔4一（3 — 三氟甲基苯基甲氧基）一苯基〕1，2—丙烷二嗣 1 一 Z — 〔乙基肟]一 2 —肟 67.4公克之1一〔4— (3 —三氟甲基苯基甲氧基）一苯基]—1，2-丙烷二酮2-肟及19· 5公克之〇—乙基羥基胺氫氯化物於300毫升之吡啶中形成的混合物加熱迴流1.5小時。冷卻之後，1〇〇〇毫升之甲苯被加入該反應混合物中且該混合物於冥空狀態下進行揮發。殘餘物被溶解於乙酸乙酯中且有機相K水進行清洗兩次並以飽和的氯化鈉溶液'清洗一次，Μ硫酸鈉進行乾燥並進行揮發。粗製產物經由快速色層分析法於矽膠（乙酸乙酯/己烷1: 3)上加以纯化，得到兩個異構性化合物熔點125 — 7。之1一〔4— (3-三氟甲基苯基甲氧基）一苯基〕一1*2—丙烷二酮1一 Ε— 〔乙基肟]一 2 —肟及樹脂彤式之1一〔4一（3—三氟甲基苯基甲氧基苯基〕—1，2 -丙烷二酮1一 Ζ — 〔乙基肟〕 —2 —蔣0 -102- 本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨ΟΧ297公釐） (請先閲讀背面之注意事項再填寫本頁) 訂 A7 B7 433982^ 五、發明説明（/阳） d) 2一 [ 〔〔（1一甲基一 2~· (4— （3—三氟甲基苯基甲氧基）一苯基）—2—E_ 〔乙氣棊亞胺基〕亞乙基） =ιΐ^Ί ί田窗甚亞甲基）一聚基乙酸甲胺基〕氧〕甲基〕一 α 一（中現巷HS甲^ ^ 醋 4.5公克之1-〔4—(3—三氟甲基笼基甲氧基）—苯基〕一1，2 —丙烷二圃1_Ε—〔乙基肟〕—肟，被溶解於15毫升之Ν，Ν —二甲基申醯胺，被逐滴加入公克之氫化納於25毫升之Ν，N—二甲基甲藤胺中所行成的懸浮液内，且該反應混合物隨後在室溫下進行搜伴10分鐘。之後，於15毫升之H，N —二甲基中的3.7公克之2— （溴甲基） - ct_ (甲氧基亞甲基）一苯基乙酸甲酿被逐滴加人且言亥反應混合物進而於室溫下進行攪拌1小時。之後，該混合物 Μ乙酸進行酸化並於真空狀態下進行揮發。將殘餘物溶解於乙酸乙酷中且該溶疲Κ水進行清洗三次並以飽和的氯化納溶液清洗一次，Μ硫酸納進行乾燥且於真空狀態下進行揮發。經由快速色層分析法（矽膠，乙酸乙酯/己烷1: 3 )後，得到熔點81— 83°之標題化合物之Ε異構物。 e) 2— 〔〔〔（1—甲基一2— (4 — （3—三氟甲基苯基甲氧基）一苯基）一2-Z—〔乙氧基亞胺基]亞乙基）一胺基〕氧]甲基〕一 c(一（甲氧基亞甲基）一苯基乙酸 -1 03- 本紙珉尺度適用中國國家橾準（CNS ) Α4規格（2!ΟΧ297公釐） I II--- - - - I (請先閱讀背面之注意事項再填寫本頁)V. Description of the invention (12E slowly added with 12E) grams of 1- (4-Ricyl cage) -1-acetone 1 2'21 grams of potassium carbonate and 500 ml of N, N-dimethylformamide in Inside the mixture formed at room temperature. Then, the reaction mixture was searched and stirred at 6Q ° for 1 hour, and then cooled and subjected to decantation, and the decanter was evaporated under vacuum. The residue was dissolved in ethyl acetate and the organic phase was washed twice with water and once with saturated sodium chloride. 1 It was dried over sodium sulfate and evaporated. The crude product was stirred with 500 ml of hexane. It was cooled, filtered, and dried under vacuum. Purified 1- [4-((3-trifluoromethylphenylmethoxy) -phenyl]-1-propylamidine) having a melting point of 63-4 ° was obtained. b) 1— [4- (3-trifluoromethanebenzylmethoxy) -phenyl] _1, "2-propanedione 2-oxime '(Please read the precautions on the back before filling this page) Order Μ 1 7 7 g of isoamyl nitrite was slowly added dropwise by 2 3 4. 3 g of 1-[4-((3-trifluoromethylphenylmethylamino) -benzyl]-1 Isopropylammonium is dissolved in 1500 ml of 1,4-dioxolane, which is acidified with nitric acid gas. The reaction mixture was then stirred at room temperature for 1.5 hours, then made basic with triethylamine and volatilized under vacuum. The residue was dissolved in ethyl acetate and the organic phase was washed twice with M water and once with K saturated sodium chloride solution. The sodium sulfate was dried and volatile. The crude product was suspended in hexanes | filtered off and Volatilize under vacuum. -10 1- The size of this paper applies to Chinese National Standard (CNS) A4 (210X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 433982 ^ A7 B7 V. Description of the invention (house 7) Melting point 137-8 1— [4-((3-trifluoromethylphenylmethoxy) -phenyl]] 1 * 2-propanedione 2-oxime. c) 1_ [4- (3-trifluoromethylphenylmethoxy) -phenyl] _1, 2-propanedione 1- E- [ethyloxime]-2-oxime and 1_ [4 一 (3 — Trifluoromethylphenylmethoxy) monophenyl] 1,2-propanedifluorene1—Z— [ethyloxime] —2—oxime 67.4 g of 1— [4— (3-trifluoromethyl A mixture of phenylmethoxy) monophenyl] -1,2-propanedione 2-oxime and 19.5 g of 0-ethylhydroxylamine hydrochloride in 300 ml of pyridine was heated under reflux for 1.5 hours. After cooling, 1,000 ml of toluene was added to the reaction mixture, and the mixture was volatilized in a hollow state. The residue was dissolved in ethyl acetate and the organic phase was washed twice with K water and once with a saturated sodium chloride solution, dried over sodium sulfate and evaporated. The crude product was purified by rapid chromatography on silica gel (ethyl acetate / hexane 1: 3) to obtain two isomeric compounds with melting points 125-7. 1- [4- (3-trifluoromethylphenylmethoxy) -phenyl]-1 * 2-propanedione 1-E— [ethyloxime] 2- 2-oxime and resin formula 1 [[4-((3-trifluoromethylphenylmethoxyphenyl)] 1,2-propanedione 1-Z — [ethyloxime] —2 —Jiang 0 -102- This paper is applicable to China Standard (CNS) Α4 specification (2 丨〇 × 297 mm) (Please read the precautions on the back before filling out this page) Order A7 B7 433982 ^ V. Description of the invention (/ yang) d) 2 1 [[[((1 一甲-2 ~ · (4- (3-trifluoromethylphenylmethoxy) -phenyl) —2-E_ 〔ethane 棊 imino〕 ethylene group) = ιΐ ^ Ί ί 田窗甚亚Methyl) monomethylacetaminoacetate] oxy] methyl] -α- (Medium HS methyl ^ vinegar 4.5 g of 1- [4- (3-trifluoromethyl cageylmethoxy) — Phenyl] -1,2-propanedihydro 1-Ε- [ethyloxime] -oxime was dissolved in 15 ml of N, N-dimethylshenamine, and was added dropwise to 25 ml of sodium hydride. In the suspension formed in Ν, N-dimethylmetamine, and the reaction was mixed The product was then searched at room temperature for 10 minutes. After that, 3.7 g of 2- (bromomethyl) -ct_ (methoxymethylene) -phenyl in 3.7 g of H, N-dimethyl in 15 ml was added. The ethyl acetate was added dropwise and the reaction mixture was further stirred at room temperature for 1 hour. After that, the mixture was acidified with acetic acid and volatilized under vacuum. The residue was dissolved in ethyl acetate and the The K was washed three times with water and once with a saturated sodium chloride solution, and the sodium sulfate was dried and evaporated under vacuum. By rapid chromatography (silica gel, ethyl acetate / hexane 1: 3) After that, the E isomer of the title compound having a melting point of 81-83 ° was obtained. E) 2- [ Group) -2-Z— [ethoxyimino] ethylene) monoamino] oxy] methyl] -c (mono (methoxymethylene) -phenylacetic acid-1 03- paper Standards apply to China National Standards (CNS) Α4 specifications (2! 〇 × 297 mm) I II ------I (Please read the notes on the back before filling This page)

，1T 經濟部中央標隼局員工消費合作钍印裝經濟部中央標準局員工消費合作社印製 433982^ A7 B7 五、發明説明（/ί?/ ) 甲酯黏稠油狀物彩式之標題化合物之Z異構物Μ類似見述於實施洌Hid)的方式自起始物1一〔4— (3 -三氟甲基苯基甲氧基）一苯基]一1，2—丙烷二_1—Z-〔乙基肟〕一 2 一肟得到。 f) 2— 〔〔〔 U—甲基一 2— (4— （3 —三氟甲基苯基甲氧基）一苯基）一 2— E—〔乙氧基亞胺基]亞乙基）胺基〕氧〕甲基]—ct —(甲氧基亞胺基）一苯基乙酸甲酷熔點68- 7D°之標題化合物Μ類似見述於實施例Hid) 的方式自1- 〔4— (3 —三氟甲基苯基甲氧基）一苯基〕一 1，2 —两焼二酮1—E— 〔乙基蔣} — 2—0弓及2—(漠申基 )~ α -(甲氧基亞胺基）一笨基乙酸甲酯。 g) 2— 〔 [ 〔（1—甲基一2— (4— （3—三氟甲基苯基甲氧基）一苯基）-2— E—〔乙氧基亞胺基〕亞乙基）胺基〕氧〕甲基〕一 C(—(甲氧基亞胺基）一笨基乙酸甲基醯胺 6.8公克之2- 〔〔〔（1—甲基一2- (4— (3 —三氟 -1 04 - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） r 訂 .^ϊ Μ (請先閱讀背面之注意事項再填寫本頁) 4339823 A 7 B7 五、發明説明甲基苯基甲氣基）一苯基）一2— E— C乙氧基亞胺基]亞乙基）胺基]氧〕甲基〕一(甲氧基亞胺基）一苯基乙酸甲酯及4..3毫升之甲基胺於乙酵中所彤成的S莫耳溶液的溫合物靜置於室溫4天。將混合物於真空狀態下進行揮發。殘餘物被納入乙酸甲酯中且該溶菝Μ水及飽和的氛化鈉溶液清洗，於硫酸鈉上進行乾燥並於真空狀態下進行揮發。殘餘物自乙酸甲酯/己烷】：1中進行再结晶。得到熔點 130 — 132°之標題化合物。實施例Η2:其他示於表1至154之化合物類亦可Κ類似見述於實施例Η1的方式加Μ製備。在表1至4之〃物理數據 #檷中，在各種情況下溫度係指化合物熔點。C · ΡΓ〇py 1為環丙基。表1 :下列通式之化合物類 (請先閏讀背面之注意事項再填寫本頁) 订經濟部中央標隼局負工消費合作社印製， 1T Consumption cooperation with employees of the Central Bureau of Standards of the Ministry of Economic Affairs 钍 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 433982 ^ A7 B7 V. Description of the invention (/ ί? /) Z isomer M is similar to that described in the implementation of 洌 Hid) from the starting material 1- [4- (3-trifluoromethylphenylmethoxy) -phenyl] -1,2-propanedi_1 —Z- [ethyloxime] -2 2-oxime. f) 2 — [[[U—methyl—2— (4 -— (3-trifluoromethylphenylmethoxy) —phenyl] —2—E— [ethoxyimino] ethylene ) Amine] oxy] methyl] -ct — (methoxyimino) -phenylacetic acid methyl ester Melting point 68-7 D ° The title compound M is similar to that described in Example Hid) from 1 to [4 — (3-trifluoromethylphenylmethoxy) -phenyl] —1,2—dioxanedione 1—E— [ethyl chloride] — 2-0 and 2— (mothenyl) ~ α- (methoxyimino) -benzyl methyl acetate. g) 2— [[((1-methyl-1, 2- (4- (3-trifluoromethylphenylmethoxy) -phenyl) -2—E— [ethoxyimino] ethylene Group) Amine] oxy] methyl] -C (— (methoxyimino) -benzylmethylacetamide 6.8 g of 2- [[[((1-methyl-1 2- (4— ( 3 —Trifluoro-1 04-This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) r order. ^ Ϊ Μ (Please read the notes on the back before filling this page) 4339823 A 7 B7 V. DESCRIPTION OF THE INVENTION Methylphenylmethylamino) monophenyl)-2-E-Cethoxyimino] ethylene) amino] oxy] methyl]-(methoxyimino) monobenzene The warm compound of methyl molybdate and 4..3 ml of methylamine in acetic acid was left at room temperature for 4 days. The mixture was evaporated under vacuum. The residue was evaporated. It was taken into methyl acetate and washed with DM water and saturated sodium hydroxide solution, dried over sodium sulfate and evaporated under vacuum. The residue was recrystallized from methyl acetate / hexane]: 1 . Get a melting point of 130 — The title compound at 132 °. Example Η2: Other compounds shown in Tables 1 to 154 can also be prepared in a manner similar to that described in Example Η1 plus M. In 〃Physical Data # 檷 in Tables 1 to 4, in In all cases, the temperature refers to the melting point of the compound. C · ΡΓ〇py 1 is cyclopropyl. Table 1: Compounds of the following general formula (please read the precautions on the back before filling this page) Order the Central Bureau of Standards of the Ministry of Economic Affairs Printed by Offload Consumer Cooperatives

-105- 本紙张尺度適用中國國家標準（CNS ) A4規格（21〇’乂297公嫠） 433982^ B7 經濟部中央標準局員工消費合作社印製五、發明説明q〇>) Γ 1 1 •fb^s η ㈣η (Rs }q mm tlil* J ! 1 1 讀先閱 1 1 1 1.1 1 4-OCfe C6 -3-CF3 0¾ 3-F A 112-4° 讀背 1 τέ 之注意事 1 1 1 η (0R)n Rz (Rs )q mm mmm 再填寫本頁 1 ) 1 I 1.2 1 4-OCIfe Ce lit -3-CF3 Cfe 3-F B 讕旨 1 1 1.3 1 4-OCHz -c-C3 H3 -2,2-Clz (¾ 3-F A 翻旨 1 1 1.4 1 4-0CH2 -c-C3 & -2.2-C12 (¾ 3-F B 樹脂 1 訂 1.5 1 4-OCHz C6 ^ -4-F Cife 3-F A 88-90。 i 1 1.6 1 4-00¾ C6 Et -2-F Cfl3 3-F A 103-105° 1 1 1.7 1 4-OC82 C6 Ik -3-CFs C03 2-F A 100-103° 1 1 1.8 1 4-OCHz C6 1¼ -4-F CHs 2-F A 89-95° 1 汰 1.9 1 4-OCIfe -c-C3 ife -2,2-Clz Cfe 2-F A 73-74。 [ | 1.10 1 4-OCH2 -C-C3 Hs -2,2-Clz Cife 2-F B 蒯旨 1 1 U1 1 4-OCHz Ce -3-CF3 Cfe 3,5-¾ A 114-116 1 1 1.12 1 4-OCHz -C-C3 Ha -2,2-CIe 0Ϊ3 3,5-F2 A 79-81。 1 I 1.13 1 4-OCHz -C-C3 tfe -2,2-Clz c& 2,5-Fz A 綳旨 ί I 1.14 1 4-OCHz C6 ^ -3-CF3 Cife 2,5-Fz A 纖 1 ! 1 15 1 4-OCHz (¾ ik -4-F Cife 2,5-¾ A 102-105° 1 1 1.16 1 4_0Cife Ce tk KF3 Cfe 3-C1 k 134-135° 1 1 -106- i 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） A7 經濟部中央標準局員工消費合作社印製 433982^ B7 五、發明説明（/十） 1.17 1 4-OCIfe Cs Ηφ -3-CF3 Clfe 3-C1 B 梛& 1.18 1 4-OCH2 C6 ^ -4-F Cfe 3-C1 A 103-105* 1.19 1 4-OCHz -c-C3 H3 -2,2-Cl2 Clfe 3-C1 A 樹脂 1.20 1 4-OCHz -c-〇3 fe -2,2~Cl2 Cfe 3-C1 B 備 1.21 1 4-OCHz C6 Et -3-CF3 Cife 3,5-012 A 99-100。 1.22 1 4-OCfe C6 H4 -3-CF3 (¾ 3,5'CIz B 樹脂 1.23 1 4_OCH2 Ce H4. -4~F CHs 3,5-Clz A 112-114° 1.24 1 4-0(¾ Ce H4 -4-F Clfe 3,5-Cl2 B 臟 1.25 1 4-0¾ C6 fk -3-CF3 c2 h5 - A 樹脂 1.26 1 4-0¾ Ce Et -3-CF3 Cz Hs - B 樹脂 1.27 1 4-OCHe Cs H4 -3-CF3 CM - A/B 翻旨 1.28 1 4-〇cii2 c6 \u -i-t-rm Clfe - A 53-55。 1.29 1 4-0CH(Cffe Kz Hs Ofe - A 1.30 1 4-0CH(Cife )C2 Hs CHs - B 藏物 1.31 1 4-OCHs CH(CIfe )2 CH3 - A 灘物 1.32 1 4-OCH2 CH(Cife )z Clfe - R mm 1.33 1 4-0((¾ )3 CH3 Clfe - A/B wmi η (OR) η (¾ )q異構物 mmm 1.34 1 4-OCe Sk -3-Br Cfe - A 129-13Γ 1.35 1 4-0C6 -3-Br CH3 - B iMf -107- (請先閲讀背面之注意事項再填寫本頁)-105- This paper size applies Chinese National Standard (CNS) A4 specification (21〇'297297 乂) 433982 ^ B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention q〇 >) Γ 1 1 fb ^ s η ㈣η (Rs) q mm tlil * J! 1 1 Read first read 1 1 1 1.1 1 4-OCfe C6 -3-CF3 0¾ 3-FA 112-4 ° Read back 1 τέ Note 1 1 1 η (0R) n Rz (Rs) q mm mmm Please fill in this page 1) 1 I 1.2 1 4-OCIfe Ce lit -3-CF3 Cfe 3-FB Mission 1 1 1.3 1 4-OCHz -c-C3 H3- 2,2-Clz (¾ 3-FA Reverse 1 1 1.4 1 4-0CH2 -c-C3 & -2.2-C12 (¾ 3-FB resin 1 order 1.5 1 4-OCHz C6 ^ -4-F Cife 3 -FA 88-90. I 1 1.6 1 4-00¾ C6 Et -2-F Cfl3 3-FA 103-105 ° 1 1 1.7 1 4-OC82 C6 Ik -3-CFs C03 2-FA 100-103 ° 1 1 1.8 1 4-OCHz C6 1¼ -4-F CHs 2-FA 89-95 ° 1 1.9 1 4-OCIfe -c-C3 ife -2,2-Clz Cfe 2-FA 73-74. [| 1.10 1 4 -OCH2 -C-C3 Hs -2,2-Clz Cife 2-FB Purpose 1 1 U1 1 4-OCHz Ce -3-CF3 Cfe 3,5-¾ A 114-116 1 1 1.12 1 4-OCHz -C -C3 Ha -2,2-CIe 0Ϊ3 3,5-F2 A 79-81. 1 I 1.13 1 4-OCHz -C-C3 tfe -2,2-Clz c & 2,5-Fz A Purpose I 1.14 1 4-OCHz C6 ^ -3-CF3 Cife 2,5-Fz A fiber 1 ! 1 15 1 4-OCHz (¾ ik -4-F Cife 2,5-¾ A 102-105 ° 1 1 1.16 1 4_0Cife Ce tk KF3 Cfe 3-C1 k 134-135 ° 1 1 -106- i 1 copies Paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) A7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 433982 ^ B7 V. Description of invention (/ ten) 1.17 1 4-OCIfe Cs Ηφ -3-CF3 Clfe 3-C1 B 梛 & 1.18 1 4-OCH2 C6 ^ -4-F Cfe 3-C1 A 103-105 * 1.19 1 4-OCHz -c-C3 H3 -2,2-Cl2 Clfe 3-C1 A resin 1.20 1 4-OCHz -c-〇3 fe -2,2 ~ Cl2 Cfe 3-C1 B Preparation 1.21 1 4-OCHz C6 Et -3-CF3 Cife 3,5-012 A 99-100. 1.22 1 4-OCfe C6 H4 -3-CF3 (¾ 3,5'CIz B resin 1.23 1 4_OCH2 Ce H4. -4 ~ F CHs 3,5-Clz A 112-114 ° 1.24 1 4-0 (¾ Ce H4 -4-F Clfe 3,5-Cl2 B dirty 1.25 1 4-0¾ C6 fk -3-CF3 c2 h5-A resin 1.26 1 4-0¾ Ce Et -3-CF3 Cz Hs-B resin 1.27 1 4-OCHe Cs H4 -3-CF3 CM-A / B Reverse 1.28 1 4-〇cii2 c6 \ u -it-rm Clfe-A 53-55. 1.29 1 4-0CH (Cffe Kz Hs Ofe-A 1.30 1 4-0CH ( Cife) C2 Hs CHs-B Collection 1.31 1 4-OCHs CH (CIfe) 2 CH3-A Beach 1.32 1 4-OCH2 CH (Cife) z Clfe-R mm 1.33 1 4-0 ((¾) 3 CH3 Clfe -A / B wmi η (OR) η (¾) q isomer mmm 1.34 1 4-OCe Sk -3-Br Cfe-A 129-13Γ 1.35 1 4-0C6 -3-Br CH3-B iMf -107- (Please read the notes on the back before filling this page)

'tT Μ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐）經濟部中央標準局員工消費合作社印製 433982。 Α7 _Β7 五、發明説明（/°Γ) 1.36 1 4-OC6 )h -3-C1 Clfe - A 106-108^ 1.37 1 4-0¾ fk -3-C1 Clfe - B mm 1.38 1 4-0C6 H4 -4-CIfe CH3 A 135-137。 1.39 1 4-OCe Et -4-Cfe 0¾ - B 灘物 1.40 1 4-OCe fti -4-Br Clfe - A 124-126。 1.41 1 4-OC0 fU -4-Br (¾ - B 瞒 1.42 1 4-OCe H4 -2-F Clfe - A 122-124° 1.43 1 4-0C6 Et -2-F (¾ B 翻旨 1.44 1 4_0Ce H4 _3-iF Cife - A 129-13Γ 1.45 1 4-0C6 flv -3-F Clfe - B 油獅 1.46 1 3-OCe Ik -3-CF3 Clfe - A mm 1 47 1 3-OCs Ik -3-CF3 Clfe - B :mm 1.48 1 4-0¾ Si(CH3 h CH3 - 1.49 0 Cffe 4-Si (Clfe h A 1.50 0 Cfe 4-Si(CHs )3 B 1.51 0 Clfe 2-CH3 ,4-F A Wii 1.52 0 Cffe 2-CHs ,5-F A 130-132。 1.53 0 CHs 3-CFs ,4-Cl A 140-142。 1.54 0 Clfe 3-CFs ,4-Cl B mm 1.55 0 Cife 5-(¾ ,2-F A 165-167 1.56 0 Clfe 5-(¾ ,2-F B 樹脂 1.57 0 Clfe 4-C& ,2-F A ni-iir B 80-82。 i·— ^^^^1 i^n ί - -1 ljm. -〆 i— I :1 «n nil Jm lCTJf—^— s ^^^^1 [^1^1 ^^^^1 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家梯準（CNS ) A4規格（2〖OX：297公釐）經濟部中央標準局員工消費合作社印製 433982_ A7 B7 五、發明説明（/4) 1.58 0 Cife 4-0-¾ H$ A 油漏 1.59 0 Cife 4-C-C3 H5 B mm 1.60 1 4-OCe ^ -4-1-7¾ Cife - A mm 1.61 1 4-0¾¾ -4-t-j 基 Cife - B 樹脂 1.62 1 4-0-¾^ Cife - A B 1.63 1 4-0(¾ )z Clfe Cffe 2-F A mm B 樹脂 1.64 1 4-0 (CHz )z Cife Cife 2-Cib A mm n (0R)n fe CRs )q mssm 1.65 〇 CH3 2,4-Fz A 121-123。 1.66 1 4-OCH2 c6 Kl· "4-F C2 h5 ~~ A 105-107 1.67 1 4-OCH2 C6 Ife -2,4-CIe Cife - A 154-156 1.68 1 4-OCe H3 -2,4-Clz Cife — A 113-11 5° 1.69 1 2-0CIfe Cife 4-0-C& A/B mm 1.70 1 4-0Cz H5 Cife 2-F A mm 1.71 1 4-0-((¾ )3 Cife CH3 2-F A mm 1.72 1 4-OCIfe Cife 2-F A iSM B 臟 1.73 1 4-0CH(CIfe )z Cfe 2-F A m -109- (請先閱讀背面之注意事項再填寫本頁)'tT Μ This paper size applies to Chinese National Standard (CNS) A4 (210 × 297 mm) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 433982. Α7 _Β7 V. Description of the invention (/ ° Γ) 1.36 1 4-OC6) h -3-C1 Clfe-A 106-108 ^ 1.37 1 4-0¾ fk -3-C1 Clfe-B mm 1.38 1 4-0C6 H4- 4-CIfe CH3 A 135-137. 1.39 1 4-OCe Et -4-Cfe 0¾-B Beach 1.40 1 4-OCe fti -4-Br Clfe-A 124-126. 1.41 1 4-OC0 fU -4-Br (¾-B Concealed 1.42 1 4-OCe H4 -2-F Clfe-A 122-124 ° 1.43 1 4-0C6 Et -2-F (¾ B Reverse 1.44 1 4_0Ce H4 _3-iF Cife-A 129-13Γ 1.45 1 4-0C6 flv -3-F Clfe-B Youshi 1.46 1 3-OCe Ik -3-CF3 Clfe-A mm 1 47 1 3-OCs Ik -3-CF3 Clfe-B: mm 1.48 1 4-0¾ Si (CH3 h CH3-1.49 0 Cffe 4-Si (Clfe h A 1.50 0 Cfe 4-Si (CHs) 3 B 1.51 0 Clfe 2-CH3, 4-FA Wii 1.52 0 Cffe 2-CHs, 5-FA 130-132. 1.53 0 CHs 3-CFs, 4-Cl A 140-142. 1.54 0 Clfe 3-CFs, 4-Cl B mm 1.55 0 Cife 5- (¾, 2-FA 165-167 1.56 0 Clfe 5- (¾, 2-FB resin 1.57 0 Clfe 4-C &, 2-FA ni-iir B 80-82. I · — ^^^^ 1 i ^ n ί--1 ljm . -〆i— I: 1 «n nil Jm lCTJf — ^ — s ^^^^ 1 [^ 1 ^ 1 ^^^^ 1 (Please read the precautions on the back before filling this page) This paper size is applicable to China National Ladder Standard (CNS) A4 specification (2 〖OX: 297 mm） Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 433982_ A7 B7 V. Description of the invention (/ 4) 1.58 0 Cife 4-0-¾ H $ A Oil Leak 1.59 0 Cife 4-C-C3 H5 B mm 1.60 1 4-OCe ^ -4-1-7¾ Cife-A mm 1.61 1 4-0¾¾ -4-tj Cife-B resin 1.62 1 4-0-¾ ^ Cife-AB 1.63 1 4-0 (¾) z Clfe Cffe 2-FA mm B resin 1.64 1 4-0 (CHz) z Cife Cife 2-Cib A mm n (0R) n fe CRs) q mssm 1.65 〇CH3 2,4-Fz A 121-123. 1.66 1 4-OCH2 c6 Kl " 4-F C2 h5 ~~ A 105-107 1.67 1 4-OCH2 C6 Ife -2,4-CIe Cife-A 154-156 1.68 1 4-OCe H3 -2,4 -Clz Cife — A 113-11 5 ° 1.69 1 2-0CIfe Cife 4-0-C & A / B mm 1.70 1 4-0Cz H5 Cife 2-FA mm 1.71 1 4-0-((¾) 3 Cife CH3 2-FA mm 1.72 1 4-OCIfe Cife 2-FA iSM B Dirty 1.73 1 4-0CH (CIfe) z Cfe 2-FA m -109- (Please read the precautions on the back before filling this page)

，1T Μ 本纸張尺度適用中國國家標车（CNS ) A4規格（2IOX297公釐）經濟部中央標隼局貝工消費合作社印製 43 39 82^ A7 B7 五、發明説明C/〇> B 翻旨 1.74 1 2-0(¾ CIb 4-F A 臟物 B 樹脂 1.75 1 4-0CH(Cife )C2 Hs CH3 2-F A B 灘物 1.76 1 2-OCIfe CIb 4-CIfe A/B 麵 1.77 1 4-O-c纖 Cfe 2-F A 職 B 樹脂 1.78 1 4-OCife Clfe 2-CIfe A mm 1.79 1 4-OCz H5 (¾ 2-Cife A mm 1.80 1 4-0CH(CIfe )z CH3 2-CH3 A 臟 1.81 1 4-O-c.ra CH3 2-CIfe A 麵 1.82 1 4-0-¾ -c-C3 E3 -2,2-Ch CH3 2-Cfe A 樹脂 1.83 1 4-OCH2 Ce Ik -3-CF3 Clfe 2-(¾ 1.84 1 4-OCg Ηφ -4-C1 CH3 2-(¾ 1.85 1 4-0Ce ftt -3-CF3 CHs 2-CIfe 1.86 1 2-0(¾ )z Cffe Clfe A mm 1.87 1 3-OCIfe Clfe 4-OCIfe A/B 臟 1.88 1 4-OCIfe C6 IU -4-C1 (¾ — A 113-115 1.89 1 4-OCe Hs -3,4~Cl2 Clfe — A 130-132 1.90 1 4-OCHz Ce fia -3,4-Clz Clfe - A 93-96 1.91 1 4-OCH2 C6 fe -3-CU-Bi* CH3 - A 109-111 1.92 1 4_0Ce H4 -2_C1 Cffe - A 128-130 -110- (請先閱讀背面之注意事項再填寫本頁) 訂 Λ, 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）經濟部中央標準扃員工消費合作社印 433982缝 A7 _B7 五、發明説明（"(Π 1.93 1 4-0Ce ^ -4-SCH3 Clfe A 109-m η ㈣η . S2 (¾ )q 異觏 ai mimm 1.94 1 4OCe HU ~ZA~?z CH3 - A 110-112 1.35 1 4-0¾ -4-OCF3 Cfe A 108-110 1.96 1 4 OC6 H4 -4-0C6H5 CH3 - A 108-110 1.97 1 4***0Ce ~4~0Cfe Clfe - A 122-125 LS8 1 4-0Ce IU -4~F c2 Hs - A 105-107 1.99 1 4-OCH2 Cs H4 -4-CF3 Cfe 2-C2 Hs A 臟 1.100 1 4~OCe H4 -4"CF3 CH3 - A 114-116 1.101 1 4-0-(2-難） CH3 - A 114-117 1.102 1 4-0Ce Ht -4-CN Clfe - A 142-144 1.103 0 Cfe 2-C1.4-F 1.104 0 Clfe 2-F.4-C1 1.105 0 Clfe 2-M-CF3 1.106 0 Cffe 2,5-F2 158-160 1.107 1 4-0(¾ C6 H+ ~4~CF3 Clfe 2-CIfe 在”物理數據”襴，上表及下表中的數值在每種情肜下表示化合物的熔點υ。 -1 1 1 _ (請先閲讀背面之注意事項再填寫本页) '1Τ 本紙張尺度適用中國國家標準（CNS ) Μ規格（210Χ297公釐） 4 3 3982¾ A7 B7 五、發明説明（/々）表2:下列通式之化合物類， 1T Μ This paper size is applicable to China National Standard Vehicle (CNS) A4 specification (2IOX297mm) Printed by the Shell Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 43 39 82 ^ A7 B7 V. Description of the invention C / 〇 > B Reverse 1.74 1 2-0 (¾ CIb 4-FA Dirt B resin 1.75 1 4-0CH (Cife) C2 Hs CH3 2-FAB Beach 1.76 1 2-OCIfe CIb 4-CIfe A / B surface 1.77 1 4- Oc fiber Cfe 2-FA Job B resin 1.78 1 4-OCife Clfe 2-CIfe A mm 1.79 1 4-OCz H5 (¾ 2-Cife A mm 1.80 1 4-0CH (CIfe) z CH3 2-CH3 A dirty 1.81 1 4-Oc.ra CH3 2-CIfe A surface 1.82 1 4-0-¾ -c-C3 E3 -2,2-Ch CH3 2-Cfe A resin 1.83 1 4-OCH2 Ce Ik -3-CF3 Clfe 2- ( ¾ 1.84 1 4-OCg Ηφ -4-C1 CH3 2- (¾ 1.85 1 4-0Ce ftt -3-CF3 CHs 2-CIfe 1.86 1 2-0 (¾) z Cffe Clfe A mm 1.87 1 3-OCIfe Clfe 4 -OCIfe A / B dirty 1.88 1 4-OCIfe C6 IU -4-C1 (¾ — A 113-115 1.89 1 4-OCe Hs -3,4 ~ Cl2 Clfe — A 130-132 1.90 1 4-OCHz Ce fia- 3,4-Clz Clfe-A 93-96 1.91 1 4-OCH2 C6 fe -3-CU-Bi * CH3-A 109-111 1.92 1 4_0Ce H4 -2_C1 Cffe-A 128-130 -110- (Please read first Back of Please fill in this page if you want to pay attention to the matter) Order Λ, this paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) Central Standard of the Ministry of Economic Affairs 扃 Employee Consumer Cooperatives printed 433982 seam A7 _B7 V. Description of the invention (" (Π 1.93 1 4-0Ce ^ -4-SCH3 Clfe A 109-m η ㈣η. S2 (¾) q iso 觏 ai mimm 1.94 1 4OCe HU ~ ZA ~? Z CH3-A 110-112 1.35 1 4-0¾ -4-OCF3 Cfe A 108-110 1.96 1 4 OC6 H4 -4-0C6H5 CH3-A 108-110 1.97 1 4 *** 0Ce ~ 4 ~ 0Cfe Clfe-A 122-125 LS8 1 4-0Ce IU -4 ~ F c2 Hs- A 105-107 1.99 1 4-OCH2 Cs H4 -4-CF3 Cfe 2-C2 Hs A Dirty 1.100 1 4 ~ OCe H4 -4 " CF3 CH3-A 114-116 1.101 1 4-0- (2-difficult) CH3 -A 114-117 1.102 1 4-0Ce Ht -4-CN Clfe-A 142-144 1.103 0 Cfe 2-C1.4-F 1.104 0 Clfe 2-F.4-C1 1.105 0 Clfe 2-M-CF3 1.106 0 Cffe 2,5-F2 158-160 1.107 1 4-0 (¾ C6 H + ~ 4 ~ CF3 Clfe 2-CIfe In the "physical data" 襕, the values in the table and table below represent compounds in each case Melting point υ. -1 1 1 _ (Please read the notes on the back before filling out this page) '1T This paper size is applicable to Chinese National Standard (CNS) M specifications (210 × 297 mm) 4 3 3982¾ A7 B7 V. Description of the invention (/ 々) Table 2: Compounds of the following formula

(請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印製(Please read the notes on the back before filling out this page)

ih^S η (OR) η (Rs )q 跡MM 2.1 1 4~0CH2 〇6 Ε^γ _3~CF3 Ofe 3-F 2.2 1 4-OCHz -c-C3 ife -2,2-Clz Clfe 3-F 2.3 1 4-OCHz C6 H+ -4-F (¾ 3-F 2.4 1 4-OHHz C6 \k -2-F Cfe 3-F 2.5 1 4-OCSz Ce 1¼ -3-CF3 Clfe 2-F n C〇R)n fe (R5 )q 挪 1W 2.6 1 4-OCHz Ce Et -4-F Cfe 2-F 2.7 1 4-OCHz -c-C3 ffe -2,2-Clz Cfe 2-F -112-ih ^ S η (OR) η (Rs) q Trace MM 2.1 1 4 ~ 0CH2 〇6 Ε ^ γ _3 ~ CF3 Ofe 3-F 2.2 1 4-OCHz -c-C3 ife -2,2-Clz Clfe 3- F 2.3 1 4-OCHz C6 H + -4-F (¾ 3-F 2.4 1 4-OHHz C6 \ k -2-F Cfe 3-F 2.5 1 4-OCSz Ce 1¼ -3-CF3 Clfe 2-F n C 〇R) n fe (R5) q 1W 2.6 1 4-OCHz Ce Et -4-F Cfe 2-F 2.7 1 4-OCHz -c-C3 ffe -2,2-Clz Cfe 2-F -112-

，1T 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐）經濟部中央標準局員工消費合作社印製 M3398 2 ^ 47 A7 B7， 1T This paper size applies Chinese National Standard (CNS) Α4 specification (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy M3398 2 ^ 47 A7 B7

五、發明説明（//W 2.8 1 4-OCHz C6 Hv 3 CF3 (¾ 3,5-Fz 2.9 1 4-OCHz -C-C3 Ife -2.2-C12 Clfe 3,5-Fz 2.10 1 4-OCHz -c-C3 h -2,2-Clz Clfe 2,5-F2 2.11 1 4-0¾ Ce -3-CFa CH3 2,5七 2.12 1 4-OCHz C6 Et -4-F Cfe 2,5-F2 2.13 1 4-OClfe Ce H4 -3-CF3 Clfe 3-C1 2.14 1 4-OCH2 Ce H4 -4_F Clfe 3-C1 2.15 1 4-OCH2 -c-Ca ffe -2,2-01^ Clfe 3-C1 2.16 1 4-OCB2 Cs H4--3-CF3 Cfe 3,5-Clz 2.17 1 4-OCfe Ce -4-F CH3 3,5-Clz 2.18 1 4-0CB2 Ce Ik -3-CF3 C2 Hs ™ 2.19 1 4-OCfe C6 H* -3-CF3 CS - 2.20 1 4-OCfe C6 Ik -4-t-TS Cffe ~ 2.21 1 4-0Cfl(Cife )C2 Hs CH3 - 84-86。 2.22 1 4-OCHz CH(C% )z Cfe - mm 2.23 1 4-0(CH2)z CIb CH3 - ίι» 2.24 1 4-0 (CHz h Clfe (¾ - mm 2.25 1 4-0Cs H4 -3-Br Clfe - 127-129° 2.26 1 4-OCs H4 -3_C1 CH3 - 118-120° 2.27 1 4-OCs ^ -4-(¾ Clfe - 107-109° 2.28 1 4-〇Ce H4 -4_Br Cife - 109-11Γ 2.29 1 4-OC6 ik -2-F CH3 - 2.30 1 4-0C6 H4 -3-F CH3 - -113- (請先閲讀背面之注意事項再填寫本頁) 訂 d, 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐> 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（///) 2.31 1 4-OCe H4 _3_CF3 CH3 106-108° 2.32 1 3-OCs IU -3-F Clfe - 2.33 1 4-OCHz Si(CIfe )3 0¾ 油狀物 2.34 0 Clfe 4-Si((¾ )3 mm 2.35 0 CH3 2-CH3 ，4-F 116-119。 2.36 0 CH3 2-C& ,5-F 112-114。 2.37 0 Clfe 3-CF3 ,4-Cl 97-39。 fba® n (0R)n (¾ )q mmm 2.38 〇 Cfe 5-CH3 , 2-F 158-160° 2.39 0 Clfe 4-Cife , 2-F 116-118。 2.40 0 CHs 4-t-丁基 120-122° 2.41 0 Clfe 4-c-〇3 Hs 2.42 1 4-OCIfe CF3 Clfe - 101-103° 2.43 1 4-0Ce Ei -4-t-TS Clfe - 129-13Γ 2.44 1 4-0-^¾ (¾ - «S 2.45 1 4-0 (Cfc )2 Clfe (¾ 2-F mm 2.48 1 4-0(CHz )2 CB3 Clfe 2-CIfe 2.47 1 4-0Cife Ce Ife -2,4~Cl2 Clfe - 149-15Γ 2.48 1 4-0Ce fe -2,4-Clz CH3 - 112-114。 2.49 1 4-0C2 Hb CH3 2-F 104-106° -114- (請先閱讀背面之注意事項再填寫本頁) l·% -5 'Μ. 本紙張尺度適用中國國家標隼（CNS ) A4規格（210X297公釐）經濟部中央標準局員工消費合作社印裝 "4 3 3 9 8 2 ί Α7 Β7 五、發明説明（//Μ 2.50 1 2-OCIfe CHs 4-OCffe 灘物 2.51 1 4-0-(CH2 )3 CH3 Clfe 2-F mm 2.52 1 4-OHCb Cfe 2-F 99-101。 2.53 1 4-OCH(Cife )z Cife 2-F mm 2.54 1 2-0CIfe c& 4-F 翻旨 2.55 1 4-OCHCCJfe )C2 Hs CH3 2-F mm 2.56 1 2-OCffe CH3 4-CH3 纖 2.57 1 4-0-c·趨 CH3 2-F mm 2.58 1 4-OCHs Cife 2-Clfe 127-130° 2.59 1 4-0¾ Hs Cfe 2-0¾ 101-103 2.60 1 4-0CH(CIfe )2 Cife 2-Cfe 樹脂 2.61 1 4-0-c.· CH3 2-(¾ mm 2.62 1 4-0-(¾，c~*C3 ife -2,2-CI2 cife 2-C& 臟 2.63 1 4-OCHz C6 H4 -3-CF3 CHs 2-(¾ 2.64 1 4-OCe ^ -4-C1 Cffe 2-CIfe 2.65 1 4-0Cs ik -3-CF3 C& 2-CH3 2.66 1 2-0(CHz )2 Cife Cife - mm 2.67 1 3-OCH3 c& 4-OCH3 樹脂 2.68 1 4-0¾ C6 ^ -4-C1 cife - 108-109 2.69 1 4-OCe Ife -3.4-C12 (¾ 104-106 η (0R)n Rz (Rs )q mmm -115- (請先閱讀背面之注意事項再填寫本胃) 訂 d. 本紙浪尺度適用中國國家標準（CNS ) A4規格（210 X 297公嫠} 經濟部中央標隼局員工消費合作社印製 ^3 39 8 2-^ at B7 五、發明説明（/^) 2.70 1 4-0CHe Cs Ife -3,4-Cl2 Clfe - 104-106 2.71 1 4-OCHz Cs -3-CU-Br (¾ - 114-116 2.72 1 4-OCe Et -2-C1 (¾ - 112-114 2.73 1 4-OCs H4 -4-SCH3 Clfe - 114-116 2.74 1 4-〇Ce E4 -2,4-F2 Clfe - 114-116 2.75 1 4-0C6 1¼ -4-OCF3 CH3 - 139-141 2.76 1 4-OCs 1¾ -4-0C6 H5 Clfe - 128-180 2.77 1 4-OCe H4 -4-0CH3 Cfe - 97-100 2.78 1 4-0(¾ C6 H4 -4-CF3 0¾ 2~Cz H5 101-107 2.79 1 4-C6 Et -4-Cf3 Cfe - 143-145 2.80 1 4-0-(2-¾¾) Cfe 103-106 2.81 1 4-Ce H4 -4-CN CHs - 158-160 2.82 0 (¾ 2,4-¾ 110-111 2.83 0 CHs 2-Cl,4-F 2.84 0 Clfe 2-M-C1 2.85 0 Clfe 2-F.4-CF3 2.36 0 CH3 2,5-F2 139-142 2.87 1 4-OCHe Ce ik -4-CF3 Clfe 2-Cffe 表3 :下列通式之化合物類 -116- —»^^1 Εκ . ... I Hi (請先閱讀背面之注意事項再填寫本頁) -a 線本紙浪尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） A7 ^3 39 8 2d B7 五、發明説明（// Y)V. Description of the invention (// W 2.8 1 4-OCHz C6 Hv 3 CF3 (¾ 3,5-Fz 2.9 1 4-OCHz -C-C3 Ife -2.2-C12 Clfe 3,5-Fz 2.10 1 4-OCHz- c-C3 h -2,2-Clz Clfe 2,5-F2 2.11 1 4-0¾ Ce -3-CFa CH3 2,5 seven 2.12 1 4-OCHz C6 Et -4-F Cfe 2,5-F2 2.13 1 4-OClfe Ce H4 -3-CF3 Clfe 3-C1 2.14 1 4-OCH2 Ce H4 -4_F Clfe 3-C1 2.15 1 4-OCH2 -c-Ca ffe -2,2-01 ^ Clfe 3-C1 2.16 1 4 -OCB2 Cs H4--3-CF3 Cfe 3,5-Clz 2.17 1 4-OCfe Ce -4-F CH3 3,5-Clz 2.18 1 4-0CB2 Ce Ik -3-CF3 C2 Hs ™ 2.19 1 4-OCfe C6 H * -3-CF3 CS-2.20 1 4-OCfe C6 Ik -4-t-TS Cffe ~ 2.21 1 4-0Cfl (Cife) C2 Hs CH3-84-86. 2.22 1 4-OCHz CH (C%) z Cfe-mm 2.23 1 4-0 (CH2) z CIb CH3-ί »2.24 1 4-0 (CHz h Clfe (¾-mm 2.25 1 4-0Cs H4 -3-Br Clfe-127-129 ° 2.26 1 4 -OCs H4 -3_C1 CH3-118-120 ° 2.27 1 4-OCs ^ -4- (¾ Clfe-107-109 ° 2.28 1 4-〇Ce H4 -4_Br Cife-109-11Γ 2.29 1 4-OC6 ik -2 -F CH3-2.30 1 4-0C6 H4 -3-F CH3--113- (Please read the precautions on the back before filling this page) Order d, this paper size applies to Chinese national standards (CNS) A4 specification (210X297 mm)> Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (///) 2.31 1 4-OCe H4 _3_CF3 CH3 106-108 ° 2.32 1 3-OCs IU -3-F Clfe-2.33 1 4-OCHz Si (CIfe) 3 0¾ Oil 2.34 0 Clfe 4-Si ((¾) 3 mm 2.35 0 CH3 2-CH3, 4-F 116-119. 2.36 0 CH3 2-C &, 5-F 112-114. 2.37 0 Clfe 3-CF3, 4-Cl 97-39. fba® n (0R) n (¾) q mmm 2.38 〇 Cfe 5-CH3, 2-F 158-160 ° 2.39 0 Clfe 4-Cife, 2-F 116-118. 2.40 0 CHs 4-t-butyl 120-122 ° 2.41 0 Clfe 4-c-〇3 Hs 2.42 1 4-OCIfe CF3 Clfe-101-103 ° 2.43 1 4-0Ce Ei -4-t-TS Clfe-129 -13Γ 2.44 1 4-0- ^ ¾ (¾-«S 2.45 1 4-0 (Cfc) 2 Clfe (¾ 2-F mm 2.48 1 4-0 (CHz) 2 CB3 Clfe 2-CIfe 2.47 1 4-0Cife Ce Ife -2,4 ~ Cl2 Clfe-149-15Γ 2.48 1 4-0Ce fe -2,4-Clz CH3-112-114. 2.49 1 4-0C2 Hb CH3 2-F 104-106 ° -114- (Please Read the notes on the back before filling this page) l ·% -5 'M. This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs " 4 3 3 9 8 2 ί Α7 Β7 V. Description of the invention (// M 2.50 1 2-OCIfe CHs 4-OCffe Beach 2.51 1 4-0- (CH2) 3 CH3 Clfe 2-F mm 2.52 1 4-OHCb Cfe 2 -F 99-101. 2.53 1 4-OCH (Cife) z Cife 2-F mm 2.54 1 2-0CIfe c & 4-F Reverse 2.55 1 4-OCHCCJfe) C2 Hs CH3 2-F mm 2.56 1 2-OCffe CH3 4-CH3 fiber 2.57 1 4-0-c · CH3 2-F mm 2.58 1 4-OCHs Cife 2-Clfe 127-130 ° 2.59 1 4-0¾ Hs Cfe 2-0¾ 101-103 2.60 1 4-0CH (CIfe) 2 Cife 2-Cfe resin 2.6 1 1 4-0-c. · CH3 2- (¾ mm 2.62 1 4-0- (¾, c ~ * C3 ife -2,2-CI2 cife 2-C & dirty 2.63 1 4-OCHz C6 H4 -3 -CF3 CHs 2- (¾ 2.64 1 4-OCe ^ -4-C1 Cffe 2-CIfe 2.65 1 4-0Cs ik -3-CF3 C & 2-CH3 2.66 1 2-0 (CHz) 2 Cife Cife-mm 2.67 1 3-OCH3 c & 4-OCH3 resin 2.68 1 4-0¾ C6 ^ -4-C1 cife-108-109 2.69 1 4-OCe Ife -3.4-C12 (¾ 104-106 η (0R) n Rz (Rs) q mmm -115- (Please read the precautions on the back before filling in the stomach) Order d. The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 gong) printed by the Staff Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs ^ 3 39 8 2- ^ at B7 V. Description of the invention (/ ^) 2.70 1 4-0CHe Cs Ife -3,4-Cl2 Clfe-104-106 2.71 1 4-OCHz Cs -3-CU-Br (¾ -114-116 2.72 1 4-OCe Et -2-C1 (¾-112-114 2.73 1 4-OCs H4 -4-SCH3 Clfe-114-116 2.74 1 4-〇Ce E4 -2,4-F2 Clfe- 114-116 2.75 1 4-0C6 1¼ -4-OCF3 CH3-139-141 2.76 1 4-OCs 1¾ -4-0C6 H5 Clfe-128-180 2.77 1 4-OCe H4 -4-0CH3 Cfe-97-100 2.78 1 4-0 (¾ C6 H4 -4-CF3 0¾ 2 ~ Cz H5 101-107 2.79 1 4-C6 Et -4-Cf3 Cfe-143-145 2.80 1 4-0- (2-¾¾) Cfe 103-106 2.81 1 4-Ce H4 -4-CN CHs-158-160 2.82 0 (¾ 2,4-¾ 110-111 2.83 0 CHs 2-Cl, 4-F 2.84 0 Clfe 2-M-C1 2.85 0 Clfe 2-F.4-CF3 2.36 0 CH3 2,5-F2 139-142 2.87 1 4-OCHe Ce ik -4-CF3 Clfe 2- Cffe Table 3: Compounds of the following general formula -116- — »^^ 1 Εκ. ... I Hi (Please read the notes on the back before filling out this page) -a The scale of the paper is applicable to Chinese national standards (CNS ) A4 specification (210 X 297 mm) A7 ^ 3 39 8 2d B7 V. Description of the invention (// Y)

η (0R}n R2 (Rb )q mmm 3.1 1 4-OCH2 C6 -3-CF3 CH3 3-F 3.2 1 4-OCH2 -C-C3 Ife -2,2-Clz CH3 3-F 3.3 1 4-OCHz Ce H4 -4-F Clfe 3-F 3.4 1 4-OCH2 Ce K+ -2-F Clfe 3-F (請先閱讀背面之注意事項再填寫本頁) 訂經濟部中央標準局員工消費合作社印裝化細 n (0R)n (β5 )q ^ 3.5 1 4-0CH2 C6 H4 -3-CF3 Clfe 2-F 3.6 1 4-OCHz C6 ik -4-F Cfe 2-F 3.7 1 4-OCHz -C-C3 tfe -2,2-Cl 2 CHS 2^F 3.3 1 4-OCH2 Cs Et -3-CF3 Cife 3,5~F2 3.9 1 4-OCHz -c-C3 fe -2,2-Cl2 CH3 3,5-F2 3.10 1 4-OCHz -C-C3 «3 -2,2-Clz CH3 2,5-Fz -117- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） 433982^ A7 B7 經濟部中央標準局員工消費合作社印製五、發明説明（/丨ο 3.11 1 4-OCHz C6 Ki -3-CF3 Clfe 2>F2 3.12 1 4-OClfe Ce IU -4-F Cfe 2,5-¾ 3.13 1 4-OCH2 C6 Ik -3-CF3 CH3 3-Cl 3.14 1 4-0(]¾ Ce -4- F CH3 3-C1 3.15 1 4-OCIfe； ~c~C3 fe -2,2-01^ CH3 3-C1 3.16 1 4-OCS2 Ce ^ -3-CF3 Clfe 3,5-Cl2 3.17 1 4-0CH2 Ce H4 -4-F Clfe 3,5-Clz 3.18 1 4-OCHz C6 fl4 -3-CF3 c2 h5 3.19 1 4-OCHz C6 fk -3-CF3 CN - 3.20 1 4~0CHz Cg H4 -4-t^J ^ Clfe - 3.21 1 4-0CH{Clfe )C2 H5 Clfe - 100-1023 3.22 1 4-OCfe CH(CIfe )z CHs - 124-106V 3.23 1 4-0(CHz )2 CH3 Clfe - mm 3.24 1 4-0 (Clfe )3 Clfe Clfe - mm 3.25 1 4-OCs Ik -3-Br Cife - 119-122° 3.26 1 4~0Ce H4· ~3~C1 Cfe - 3.27 1 4-0Ce lit -4-C& CH3 - 119-121° 3.28 1 4-OCe iU ^4Έγ Cffe - 138-140° 3.29 1 4OCe H4 ^-2-F Clfe - 3.30 1 4-0C6 ^ ~3-F Clfe - 3.31 1 4-OCe fk -3-CF3 CH3 - 89-31。 3.32 1 3™0Ce E4. ~3'F Clfe 一 3.33 I 4-OCHz SKCH3 )3 Cfe -118- (請先閱讀背面之注意事項再填寫本頁) 訂本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 4 3 39 8 2 j A7 B7 經濟部中央標隼局員工消費合作社印製五、發明説明（//t) 1 1 1 3.34 0 CH3 4-si(c& )3 mm 1 1 1 3.35 0 Cife 2-CHs , 4-F油狀物 1 請先鬩讀 1 I 1 1 背 1 1 n (OR)η R2 (Rs )q tSMS 之注意事項再填寫本頁 s_y 1 i i 3.36 3.37 0 0 Cife CH3 2- CH3 ,5-F 139-140° 3- CFs ,4-Cl 泡沫物 1 1 ] 3.38 0 Cife 5-CIfe , 2-F 125-128" I 1 3.39 Q CH3 4-Cffe , 2-F 130-134。 1 1 3.40 0 Cife 4-t-丁基泡流物 i 訂 3.41 0 Cife 4-c-Ce H5 1 J 3.42 1 4-0Ce El· -4-F CHs - mms 1 1 3.43 1 4-0CH2 cf3 Cife - 159-16Γ 1 1 3.44 1 4-〇c6 ik -A-t-rm Cife ™ 挪旨 1 级 i 1 3.45 1 (¾ - 133-135。 3.46 1 4-0(CH2 )2 Cfe Cife 2-F 油狀物 1 1 3.47 1 4-0(CH2 )z (¾ Cife 2-0¾ 99-101。 i 1 3.48 1 4-OCH2 Ce Ife -2,4-Clz CH3 - 87-88° i 1 3.49 1 4-OCe Hs -2,4-Clz CHs - 118-120° 1 1 3.50 1 4-OC2 H5 Cife 2-F 97-99° I 1 1 3.51 1 2-0Cffe Cife 4-OCfe 樹脂 1 1 3.52 1 4-0-{CHz )3 Cife Cfe 2-F 樹脂 1 1 -119- i 1 本紙張尺度適用中國國家標準{ CNS ) A4規格（210Χ297公釐） 433982 A7 B7 五、發明説明經濟部中央標隼局員工消費合作社印製 3.53 1 4-OCIfe Cife 2-F 132-134° 3.54 1 4-0CH(Clfe )2 Clfe 2-F mm 3.55 1 2-OCH3 Clfe 4-F 186-189。 3.56 1 4-0CH(CIfe )C2 Hs CH3 2-F 翻旨 3.57 1 2-0CIfe Clfe 4-CH3 臟 3.58 1 4-0-c·· Cife 2-F 131-133° 3.59 1 4-OCHs Clfe 2-(¾ W^3 3.60 1 4-OCz Hs Clfe 2-CH3 mm 3.61 1 4-0CH(CH3 )2 Clfe 2 - Cfe mms 3.62 1 4-0-c.應 Cfe 2-CH3 112-113。 3.63 1 4-0CH2 -c-C3 H3 -2.2-C12 Clfe 2-CH3 mm 3.64 1 4-OCH2 Ce Ik -3-CFs CH3 2-Cffe 3.65 1 4-OCe -4-C1 Clfe 2-CB3 3.66 1 4-0C6 H4 -3-CF3 Cife 2-CIb ib^tJ η (0R)n Rz (Rs )q mmm 3.67 1 2-CKCH2 )2 Cfe Clfe - 3.68 1 3-OCH3 Cife 4-OCH3 樹脂 3.69 1 4-OCHz Cs H4 -4-C1 C83 - 121-124。 3.70 1 4-OCe Ife -3,4-Clz Cffe - 135-137。 3.71 1 4-OCH2 C6 Ife -3,4-Clz (¾ - 146-148° -1Z0- —. i ' . .~I ^"衣 _. r —. 訂 .! 紙 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標羋（CNS >戍4说格（2110X297公釐）經濟部中央標準局員工消費合作社印製 4 3 39 8 2-j A7 __B7 五、發明説明（丨必 3.72 1 4-OCHe C6 1¾ -2-Cl,4-Br Clfe 128-130° 3.73 1 4-0Cs Et -2-C1 Cffe - 160-162。 3.74 1 4-OCe -4-SCife Cife - 117-119。 3.75 1 4-OCe Η* -2-OCF3 Clfe - 129-13Γ 3.76 1 4-OCs -4-OCs Hs Cfe — 94-96° 3.77 1 4_0Ce H4 "2,4-Fz Cfe - 112-114° 3.78 1 4-OCs Et -4-0Cife (¾ — 106-109° 3.79 1 4-OCHz Cs H4 -4-CF3 Cih 2-C2 Hs 119-122。 3.80 1 4-0Cs H4 -4-CF3 CH3 - 128-131° 3.81 1 4-0-(2-萘基） C& - 155-157° 3.82 1 4-0Ce H4 -4-CN Clfe - 126-128。 3.83 0 Clfe 2,4-¾ 145° 3.84 0 Cffe 2-C1.4-F 3.85 0 Cffe 2-F.4-C1 3.86 0 Clfe 2-F,4-CF3 3.87 0 Cfe 2,5-Fz 154-1563 3.88 1 4-OCHz C6 H4 -4-CF3 0¾ 2-Cife 表4 :下列通式之化合物類 -12 1- (請先閱讀背面之注意事項再填寫本頁)η (0R) n R2 (Rb) q mmm 3.1 1 4-OCH2 C6 -3-CF3 CH3 3-F 3.2 1 4-OCH2 -C-C3 Ife -2,2-Clz CH3 3-F 3.3 1 4-OCHz Ce H4 -4-F Clfe 3-F 3.4 1 4-OCH2 Ce K + -2-F Clfe 3-F (Please read the precautions on the back before filling out this page) Order the printout of the staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Fine n (0R) n (β5) q ^ 3.5 1 4-0CH2 C6 H4 -3-CF3 Clfe 2-F 3.6 1 4-OCHz C6 ik -4-F Cfe 2-F 3.7 1 4-OCHz -C-C3 tfe -2,2-Cl 2 CHS 2 ^ F 3.3 1 4-OCH2 Cs Et -3-CF3 Cife 3,5 ~ F2 3.9 1 4-OCHz -c-C3 fe -2,2-Cl2 CH3 3,5- F2 3.10 1 4-OCHz -C-C3 «3 -2,2-Clz CH3 2,5-Fz -117- This paper size applies to China National Standard (CNS) Α4 size (210X297 mm) 433982 ^ A7 B7 Ministry of Economy Printed by the Consumer Standards Cooperative of the Central Bureau of Standards 5. Description of Invention (/ 丨 ο 3.11 1 4-OCHz C6 Ki -3-CF3 Clfe 2 > F2 3.12 1 4-OClfe Ce IU -4-F Cfe 2,5-¾ 3.13 1 4-OCH2 C6 Ik -3-CF3 CH3 3-Cl 3.14 1 4-0 (] ¾ Ce -4- F CH3 3-C1 3.15 1 4-OCIfe; ~ c ~ C3 fe -2,2-01 ^ CH3 3 -C1 3.16 1 4-OCS2 Ce ^ -3-CF3 Clfe 3,5-Cl2 3.17 1 4-0CH2 Ce H4 -4-F Clfe 3,5 -Clz 3.18 1 4-OCHz C6 fl4 -3-CF3 c2 h5 3.19 1 4-OCHz C6 fk -3-CF3 CN-3.20 1 4 ~ 0CHz Cg H4 -4-t ^ J ^ Clfe-3.21 1 4-0CH { Clfe) C2 H5 Clfe-100-1023 3.22 1 4-OCfe CH (CIfe) z CHs-124-106V 3.23 1 4-0 (CHz) 2 CH3 Clfe-mm 3.24 1 4-0 (Clfe) 3 Clfe Clfe-mm 3.25 1 4-OCs Ik -3-Br Cife-119-122 ° 3.26 1 4 ~ 0Ce H4 · ~ 3 ~ C1 Cfe-3.27 1 4-0Ce lit -4-C & CH3-119-121 ° 3.28 1 4- OCe iU ^ 4Έγ Cffe-138-140 ° 3.29 1 4OCe H4 ^ -2-F Clfe-3.30 1 4-0C6 ^ ~ 3-F Clfe-3.31 1 4-OCe fk -3-CF3 CH3-89-31. 3.32 1 3 ™ 0Ce E4. ~ 3'F Clfe One 3.33 I 4-OCHz SKCH3) 3 Cfe -118- (Please read the precautions on the back before filling this page) The paper size of the book is applicable to the Chinese National Standard (CNS) Α4 Specifications (210 × 297 mm) 4 3 39 8 2 j A7 B7 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (// t) 1 1 1 3.34 0 CH3 4-si (c &) 3 mm 1 1 1 3.35 0 Cife 2-CHs, 4-F Oily 1 Please read 1 I 1 1 Back 1 1 n (OR) η R2 (Rs) q Note for tSMS before filling out this page s_y 1 ii 3.36 3.37 0 0 Cife CH3 2- CH3, 5-F 139-140 ° 3- CFs, 4-Cl foam 1 1] 3.38 0 Cife 5-CIfe, 2-F 125-128 " I 1 3.39 Q CH3 4-Cffe, 2-F 130-134. 1 1 3.40 0 Cife 4-t-butyl foam fluid Order 3.41 0 Cife 4-c-Ce H5 1 J 3.42 1 4-0Ce El · -4-F CHs-mms 1 1 3.43 1 4-0CH2 cf3 Cife -159-16Γ 1 1 3.44 1 4-〇c6 ik -At-rm Cife ™ No. 1 level i 1 3.45 1 (¾-133-135. 3.46 1 4-0 (CH2) 2 Cfe Cife 2-F Oily 1 1 3.47 1 4-0 (CH2) z (¾ Cife 2-0¾ 99-101. I 1 3.48 1 4-OCH2 Ce Ife -2,4-Clz CH3-87-88 ° i 1 3.49 1 4-OCe Hs -2,4-Clz CHs-118-120 ° 1 1 3.50 1 4-OC2 H5 Cife 2-F 97-99 ° I 1 1 3.51 1 2-0 Cffe Cife 4-OCfe resin 1 1 3.52 1 4-0- {CHz) 3 Cife Cfe 2-F Resin 1 1 -119- i 1 This paper size applies to Chinese national standard {CNS) A4 specification (210 × 297 mm) 433982 A7 B7 V. Description of invention Employees ’Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs Printed 3.53 1 4-OCIfe Cife 2-F 132-134 ° 3.54 1 4-0CH (Clfe) 2 Clfe 2-F mm 3.55 1 2-OCH3 Clfe 4-F 186-189. 3.56 1 4-0CH (CIfe) C2 Hs CH3 2-F Reverse 3.57 1 2-0CIfe Clfe 4-CH3 Dirty 3.58 1 4-0-c · Cife 2-F 131-133 ° 3.59 1 4-OCHs Clfe 2 -(¾ W ^ 3 3.60 1 4-OCz Hs Clfe 2-CH3 mm 3.61 1 4-0CH (CH3) 2 Clfe 2-Cfe mms 3.62 1 4-0-c. Should be Cfe 2-CH3 112-113. 3.63 1 4-0CH2 -c-C3 H3 -2.2-C12 Clfe 2-CH3 mm 3.64 1 4-OCH2 Ce Ik -3-CFs CH3 2-Cffe 3.65 1 4-OCe -4-C1 Clfe 2-CB3 3.66 1 4-0C6 H4 -3-CF3 Cife 2-CIb ib ^ tJ η (0R) n Rz (Rs) q mmm 3.67 1 2-CKCH2) 2 Cfe Clfe-3.68 1 3-OCH3 Cife 4-OCH3 resin 3.69 1 4-OCHz Cs H4 -4-C1 C83-121-124. 3.70 1 4-OCe Ife -3,4-Clz Cffe-135-137. 3.71 1 4-OCH2 C6 Ife -3,4-Clz (¾-146-148 ° -1Z0- —. I '.. ~ I ^ " 衣 _. R —. Order.! Paper (Please read the first Note: Please fill in this page again.) This paper size applies to Chinese national standard (CNS > 说 4 grid (2110X297 mm). Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 4 3 39 8 2-j A7 __B7 V. Invention Explanation (丨 must be 3.72 1 4-OCHe C6 1¾ -2-Cl, 4-Br Clfe 128-130 ° 3.73 1 4-0Cs Et -2-C1 Cffe-160-162. 3.74 1 4-OCe -4-SCife Cife -117-119. 3.75 1 4-OCe Η * -2-OCF3 Clfe-129-13Γ 3.76 1 4-OCs -4-OCs Hs Cfe — 94-96 ° 3.77 1 4_0Ce H4 " 2,4-Fz Cfe- 112-114 ° 3.78 1 4-OCs Et -4-0Cife (¾ — 106-109 ° 3.79 1 4-OCHz Cs H4 -4-CF3 Cih 2-C2 Hs 119-122. 3.80 1 4-0Cs H4 -4- CF3 CH3-128-131 ° 3.81 1 4-0- (2-naphthyl) C &-155-157 ° 3.82 1 4-0Ce H4 -4-CN Clfe-126-128. 3.83 0 Clfe 2,4-¾ 145 ° 3.84 0 Cffe 2-C1.4-F 3.85 0 Cffe 2-F.4-C1 3.86 0 Clfe 2-F, 4-CF3 3.87 0 Cfe 2,5-Fz 154-1563 3.88 1 4-OCHz C6 H4 -4-CF3 0¾ 2-Cife Table 4: Compounds of the formula -12 1- (Please read the precautions on the back before filling this page)

'IT 本紙張尺度適用中國國家標準（CMS ) A4規格（210X 297公釐） 4339 82 ^ A7 _ B7 五、發明説明（〖θ ) 0'IT This paper size applies the Chinese National Standard (CMS) A4 specification (210X 297 mm) 4339 82 ^ A7 _ B7 V. Description of the invention (〖θ) 0

經濟部中央標隼局員工.消費合作社印製化娜 X Υ R AR7 ί mmm 4.1 CH OCHs c& CHz Ce H4 -3-CFs 樹脂 4.2 CH OCIfe Cife CHz C^CH 臟 4.3 CH OOfe CHs CHz CH=CC12 樹脂 4.4 CR 0CH3 CHz Ce ^ -3-CF3 CHa CH:CHz 73-75。 4.5 CH OCffe Cflz C6 h -3-CF3 Cz Hb 81-83° 4.6 CH OCfe CHz C6 心-3-CF3 (¾ c_ 翻旨 4.7 CH OClfe CHz Ce Et -3-CF3 CHz CH=CC12 樹脂 4 8 CH 0C& CHe C6 ^ -3-CF3 CHe Si(Cfe h 樹脂 4,9 CH OCfe CHz Cs H4 -3-CFs CH2 -0-¾ 1¾ -2,2-Clz 樹脂 4.10 CH OCffe ΖΈζ Cs ik -3-CF3 CHz COOCz Hg 樹9旨 4.11 CH 0CH3 (¾ Cs H4 -3-CFa CH(CIfe )C00C2 Hs 樹脂 4.12 CH OCIfe CHz C6 Ε» -3-CF3 CHz CFs 賺 4.13 CH OCIfe CHz Ce H4 -3-CF3 n-C3 H7 翻旨 4.14 CH 0CH3 CHz C6 H4 -3-CF3 i-C3 H7 樹脂 4.15 CH OCIfe CHz C6 iU -3-CF3 n-C4 H9 樹脂 -122- (請先閣讀背面之注意事項再填寫本頁) - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐）Employees of the Central Bureau of Standards, Ministry of Economic Affairs. Printed by the consumer cooperative X X R AR7 ί mmm 4.1 CH OCHs c & CHz Ce H4 -3-CFs resin 4.2 CH OCIfe Cife CHz C ^ CH dirty 4.3 CH OOfe CHs CHz CH = CC12 Resin 4.4 CR 0CH3 CHz Ce ^ -3-CF3 CHa CH: CHz 73-75. 4.5 CH OCffe Cflz C6 h -3-CF3 Cz Hb 81-83 ° 4.6 CH OCfe CHz C6 Heart-3-CF3 (¾ c_ Reverse 4.7 CH OClfe CHz Ce Et -3-CF3 CHz CH = CC12 resin 4 8 CH 0C & CHe C6 ^ -3-CF3 CHe Si (Cfe h resin 4,9 CH OCfe CHz Cs H4 -3-CFs CH2 -0-¾ 1¾ -2,2-Clz resin 4.10 CH OCffe ZnΈζ Cs ik -3-CF3 CHz COOCz Hg tree 9 purpose 4.11 CH 0CH3 (¾ Cs H4 -3-CFa CH (CIfe) C00C2 Hs resin 4.12 CH OCIfe CHz C6 Ε »-3-CF3 CHz CFs earn 4.13 CH OCIfe CHz Ce H4 -3-CF3 n-C3 H7 Reverse 4.14 CH 0CH3 CHz C6 H4 -3-CF3 i-C3 H7 resin 4.15 CH OCIfe CHz C6 iU -3-CF3 n-C4 H9 resin -122- (Please read the precautions on the back before filling this page) -This paper size applies to China National Standard (CNS) Α4 specification (210X297 mm)

4 339 82 J A7 B7 五、發明説明 4.16 Ν OCHs CHe (¾ IU -3-CF3 fe Hs 68-70° 4.17 Ν NHCIfe CSz C6 Et -3-CF3 c2 h5 130-132° 4.18 Ν OCfe CB2 Ce H4 -3-CF3 CHz C=CH 樹脂 4.19 Ν NHCIfe CHe Ce H4 -3-CF3 Cliz C-CH 89-91 4.20 CH OCIfe Cs H4 +C1 C2 H5 87-89° 4.21 CH OCIfe CHe C6 B4 -4-F CH2 C=CH 112-114 4.22 CH OCIfe CH2 Ce -4-F CHz CH=CClz 樹脂 4.23 CH OCHa Cfiz Cs H4 -4-F CH2 Cs H4 ~3-CF3 樹脂 4.24 CH OCife CHz C6 H4 -4-F C2 HS 綳旨 4.25 CH 0(¾ (¾ C6 Ik -4-CFs Cz fl5 樹脂 4.26 Ν 0C& CHz C6 ^ -4-CF3 C2 Hs 75-77。 4.27 Ν NHCife Cfe (¾ ftt -4-CF3 C2 Hs 131-133° 4.28 η OCH3 CHz C6 H4 -2-CF3 Cz H5 80-82° 4.29 Ν NHCIfe Clfe C6 Ik -2-CF3 Cz Hs 112-114。 — - -¾^訂 Μ (請先閱讀背面之注意事項再填寫本頁) 經濟部中夬標隼局員工消費合作社印聚 X Y R AR7 mmm 4.30 Ν 0C& -Ce Ik -3 CF3 C2 Hs 102-104° 4.31 Ν NHOb -C6 IU -3-CF3 C2 Hs 88-90° 4.32 CH OOfe -Ce fk -3-CF3 C2 Hs 72-74° 4.33 CH OCHa C}fe C6 H4 -2-CF3 Cz Hs 93-95° 4.34 CH OCIfe CHzCe \k -2-F C2 h5 90-92。 -123- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 29?公釐） 433982j A7 B7 五、發明説明（丨y ) 經濟部中央標準局員工消費合作杜印製 4.35 CH OCIfe C82 Ce Ik -3-0¾ CH2 -CN ms 4.36 ϋ OCIfe CHz C6 -2-F C2 Hs 翻旨 4.37 CH 0CH3 CHz Ce H4 -3-CF3 t~C4 Hg 89-31。 4.38 Ν NHCffe Cife C6 H4 -2-F C2 H5 135-137° 4.39 CH OCIfe -Ce Sk ~4_Br C2 HS 93-95° 4.40 N OCife ^Ce El· ^4"Br Cz H5 94-97° 4.41 N NHCH3 -Ce H4 ^4_Br C2 H5 137-133。 4.42 CH 0(¾ Cifc Cs H4 "4-t-But Cz Hs 樹脂 4.43 N OCH3 Clfe Cs H4 ~4_t-But Cz Hs 101-103° 4.44 N NHCfe CHz C6 % -4-t-But C2 Hs 133-135° 4.45 CH 0C& CHz C6 -2,4-Cle Cz Hs 107-109° 4.46 N OCife CHz Cs Ife -2,4-Clz Cz H5 103-105° 4.47 S NHCife CHz C6 Ife -Z.4-C12 Cz H5 98-100° 4.48 N OCfe H3 ~2,4"Cl2 c2 h5 141-143° 4.49 N OCife Ce H4 _4_t_But C2 Hs 92-94° 4.50 N OCHe iu -3-C1 C2 H5 93-955 4.51 CH OCife Ce fe -2,4-Clz Cz Hs 116-118° 4.52 N NHCife Ce H3 _2,4_Clz C2 H5 147-148° 4.53 N NHCife Ce ik -4-t-But Cz Hs 68-69° 4.54 N NHCffe Ce H4 *3"C1 Ce H5 90-92* 4.55 CH OCife C6 fU -4-t-But C2 Hs 106-107° 4.56 CH OCife C6 H4 -3-C1 C2 Hs 85-87° 4.57 CH 0C& 11-C3 H? Cz H5 ίώ» -124- (請先閲讀背面之注意事項再填寫本頁) '東' 訂 }A. 本紙蒗尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 43 39 82 .j A7 B7 經濟部中央標準局員工消費合作社印製五、發明説明（fM 1 1 I 4.58 OCfe n-C3 H7 C2 Hs 86-89· 1 1 1 4.59 il NHCife n_Cs H7 Cz H5 139-141° 1 I 4.60 CH OCfe 11-C3 H7 n-C3 H7 mm 請閲 ί | 4.61 Ν OCH3 n_Cs H7 n-Cs B7 mm 讀背 ιέ 之注意章 1 1 1 1 化娜 X Y R ar7 mimm 項再填寫本頁 1 V 裝 | 1 | 4.62 Ν NHCH3 n-C3 H7 n-C3 S7 128-131° 1 1 4.63 CH OCfe 11-C3 Hv CHz C=CH 臟 1 I 4.64 Ν OCfe n-C3 H7 CH2 C=CH 86-89ΰ 1 訂 4.65 NHCH3 n-C3 H7 CBz C=CH 樹脂 1 I 4.66 CH 0CH3 CH2 C6 H4 -4-C1 C2 Hs 77-79 1 1 4.67 s 0(¾ GHz C6 Ik -4-C1 fe Hs Π1-112 ! I 4.68 N 0(¾ Ce H4 -4-C1 Cz H5 90-93 線 ! j 4.69 s NHCIfe CH2 C6 % -4-C1 Cz Hs 142-145 4.70 N NHCH3 C6 El· -4-C1 c2 h5 126-129 1 1 4.71 N OCH3 Ce H3 -3,4-Clz Cz H5 102-103 1 [ 4.72 CH OCIfe Ce Ife -3,4-Cl2 C2 Hs 85-87 1 I 4.73 N NHCIfe Ce Ife -3,4-01^ Cz Hs 118-120 1 I 4.74 N 0(¾ C6 ffe -2-Cl,4-Br C2 Ηξ 127-129 1 1 4.75 CH 0(¾ C6 H3 -2-CU-Br Cz Hs 104-10 1 1 4.76 CH OCIfe C82 Ce ffe ^3,4-Clz C2 Hs 94-96 1 1 -125- 1 1 本紙張尺度適用中國國家標準（CNS ) A4現格（210X 297公釐） 433982 A7 B7 五、發明説明（f^) 4.77 4.78 OCffe CH2 Ce ife -3,4-Cl2 C2 Hb NHCHs Clfe C6 H3 -3.4-C12 C2 Hs4 339 82 J A7 B7 V. Description of the invention 4.16 Ν OCHs CHe (¾ IU -3-CF3 fe Hs 68-70 ° 4.17 Ν NHCIfe CSz C6 Et -3-CF3 c2 h5 130-132 ° 4.18 Ν OCfe CB2 Ce H4- 3-CF3 CHz C = CH resin 4.19 Ν NHCIfe CHe Ce H4 -3-CF3 Cliz C-CH 89-91 4.20 CH OCIfe Cs H4 + C1 C2 H5 87-89 ° 4.21 CH OCIfe CHe C6 B4 -4-F CH2 C = CH 112-114 4.22 CH OCIfe CH2 Ce -4-F CHz CH = CClz resin 4.23 CH OCHa Cfiz Cs H4 -4-F CH2 Cs H4 ~ 3-CF3 resin 4.24 CH OCife CHz C6 H4 -4-F C2 HS 綳Purpose 4.25 CH 0 (¾ (¾ C6 Ik -4-CFs Cz fl5 resin 4.26 Ν 0C & CHz C6 ^ -4-CF3 C2 Hs 75-77. 4.27 Ν NHCife Cfe (¾ ftt -4-CF3 C2 Hs 131-133 ° 4.28 η OCH3 CHz C6 H4 -2-CF3 Cz H5 80-82 ° 4.29 Ν NHCIfe Clfe C6 Ik -2-CF3 Cz Hs 112-114. —--¾ ^ Order (please read the notes on the back before filling (This page) Employees' Cooperatives of the Ministry of Economic Affairs of the Ministry of Economic Affairs of the People's Republic of China XYR AR7 mmm 4.30 Ν 0C & -Ce Ik -3 CF3 C2 Hs 102-104 ° 4.31 Ν NHOb -C6 IU -3-CF3 C2 Hs 88-90 ° 4.32 CH OOfe -Ce fk -3-CF3 C2 Hs 72-74 ° 4.33 CH OCHa C} fe C6 H4 -2-CF3 Cz Hs 93 -95 ° 4.34 CH OCIfe CHzCe \ k -2-F C2 h5 90-92. -123- This paper size applies to China National Standard (CNS) A4 specification (210 X 29? Mm) 433982j A7 B7 V. Description of the invention (丨 y) Consumption cooperation by employees of the Central Bureau of Standards, Ministry of Economic Affairs, Du printed 4.35 CH OCIfe C82 Ce Ik -3-0¾ CH2 -CN ms 4.36 ϋ OCIfe CHz C6 -2-F C2 Hs Reverse 4.37 CH 0CH3 CHz Ce H4 -3- CF3 t ~ C4 Hg 89-31. 4.38 Ν NHCffe Cife C6 H4 -2-F C2 H5 135-137 ° 4.39 CH OCIfe -Ce Sk ~ 4_Br C2 HS 93-95 ° 4.40 N OCife ^ Ce El · ^ 4 " Br Cz H5 94-97 ° 4.41 N NHCH3 -Ce H4 ^ 4_Br C2 H5 137-133. 4.42 CH 0 (¾ Cifc Cs H4 " 4-t-But Cz Hs resin 4.43 N OCH3 Clfe Cs H4 ~ 4_t-But Cz Hs 101-103 ° 4.44 N NHCfe CHz C6% -4-t-But C2 Hs 133- 135 ° 4.45 CH 0C & CHz C6 -2,4-Cle Cz Hs 107-109 ° 4.46 N OCife CHz Cs Ife -2,4-Clz Cz H5 103-105 ° 4.47 S NHCife CHz C6 Ife -Z.4-C12 Cz H5 98-100 ° 4.48 N OCfe H3 ~ 2,4 " Cl2 c2 h5 141-143 ° 4.49 N OCife Ce H4 _4_t_But C2 Hs 92-94 ° 4.50 N OCHe iu -3-C1 C2 H5 93-955 4.51 CH OCife Ce fe -2,4-Clz Cz Hs 116-118 ° 4.52 N NHCife Ce H3 _2,4_Clz C2 H5 147-148 ° 4.53 N NHCife Ce ik -4-t-But Cz Hs 68-69 ° 4.54 N NHCffe Ce H4 * 3 " C1 Ce H5 90-92 * 4.55 CH OCife C6 fU -4-t-But C2 Hs 106-107 ° 4.56 CH OCife C6 H4 -3-C1 C2 Hs 85-87 ° 4.57 CH 0C & 11-C3 H ? Cz H5 ίώ »-124- (Please read the notes on the back before filling in this page) 'East' Order} A. The size of this paper applies the Chinese National Standard (CNS) A4 (210X297 mm) 43 39 82 .j A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Description C2 Hs 86-89 · 1 1 1 4.59 il NHCife n_Cs H7 Cz H5 139-141 ° 1 I 4.60 CH OCfe 11-C3 H7 n-C3 H7 mm Please read | 4.61 Ν OCH3 n_Cs H7 n-Cs B7 mm read back Please note the chapter 1 1 1 1 Hanna XYR ar7 mimm and fill in this page again 1 V set | 1 | 4.62 Ν NHCH3 n-C3 H7 n-C3 S7 128-131 ° 1 1 4.63 CH OCfe 11-C3 Hv CHz C = CH dirty 1 I 4.64 Ν OCfe n-C3 H7 CH2 C = CH 86-89ΰ 1 order 4.65 NHCH3 n-C3 H7 CBz C = CH resin 1 I 4.66 CH 0CH3 CH2 C6 H4 -4-C1 C2 Hs 77-79 1 1 4.67 s 0 (¾ GHz C6 Ik -4-C1 fe Hs Π1-112! I 4.68 N 0 (¾ Ce H4 -4-C1 Cz H5 90-93 line! J 4.69 s NHCIfe CH2 C6% -4-C1 Cz Hs 142-145 4.70 N NHCH3 C6 El · -4-C1 c2 h5 126-129 1 1 4.71 N OCH3 Ce H3 -3,4-Clz Cz H5 102-103 1 [4.72 CH OCIfe Ce Ife -3,4-Cl2 C2 Hs 85-87 1 I 4.73 N NHCIfe Ce Ife -3,4-01 ^ Cz Hs 118-120 1 I 4.74 N 0 (¾ C6 ffe -2-Cl, 4-Br C2 Ηξ 127-129 1 1 4.75 CH 0 (¾ C6 H3 -2-CU-Br Cz Hs 104-10 1 1 4.76 CH OCIfe C82 Ce ffe ^ 3,4-Clz C2 Hs 94-96 1 1 -125- 1 1 This paper size applies to China Of Standards (CNS) A4 is now grid (210X 297 mm) 433982 A7 B7 V. invention is described in (f ^) 4.77 4.78 OCffe CH2 Ce ife -3,4-Cl2 C2 Hb NHCHs Clfe C6 H3 -3.4-C12 C2 Hs

4.79 N OCIfe 4.80 OCffe4.79 N OCIfe 4.80 OCffe

4-cP4-cP

Cz Hs C2 H5 84-86 142-145 84-86 綳旨經濟部中夬標隼局員工消f合作社印製 4.81 N OCH3 Ce H4 -4-CI CHz C=CH 93-95 4.82 N OCfe Ce Et -4-C1 (〇Ηε )z CH3 95-96 4.83 N OCIfe Cs -2-Cl c2 h5 107-109 4.84 CH OCHs Zq H4 -2-C1 Cz Hs 119-121 4.85 NHCIfe Ce tfe -2-CL4*-Br Cz fl5 138-140 〇\ 4.86 Ν NHCfe C2 h5 142-144 X Y R ar7 1 跡I* 4.87 CK OCIfe C6 -4-C1 CHz C=CH 103-105 4.88 CH OCffe Cs Et -4-C1 (CHz )2 CH3 90-92 4.89 N NHCHs (¾ -4-C1 CHz C三CH 130-132 4.90 N NHCfe Ce H4 -4-Cl (CHz )z CHs S6-98 4.31 N 隨Cfe Ce H4 -2-C1 C2 h5 128-130 -126- \kf.r 丨 ^裝訂藏 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） A7 經濟部中央標準局員工消費合作社印製 433982^ B7 五、發明説明（f4) 4.92 Ν OCIfe Ce Hs -4-SCH3 Cz Hs 纖 4.93 CH OCIfe Ce H5 -4-SClfe Cz Hs 97-99 4.94 Ν NHCH3 C6 Hs -4-SCIfe Cz Hs 118-120 4.95 S OCHa Ce -4-C1 CHz CH=CIfe 74-76 4.96 S OCIfe H4 ~4_C1 1-C3 H7 75-77 4.97 CH OC03 C6 fk -4-C1 CH2 CH=CH2 73-75 4.98 CH OCIfe C6 H4 -4-C1 1-C3 H7 樹脂 4.99 Ν NHCIfe ^ fU -4-C1 (¾ CH^CH2 101-103 4.100 Ν NHCH3 Cs fU -4-C1 1-C3 H7 104-105 4.101 CH OCIfe Ce % -3-CF3 CHz (^CH 樹脂 4.102 Ν OCfe Clfe Ce fk -4-CFs CHz C=CH 104-106 4.103 Ν OCIfe CHz C6 H4 -4-CF3 CH2 CH=CIi2 93-95 4.104 Ν OCIfe CSz C6 H4 -4-CF3 n-C3 H7 87-88 4.105 CH OCH3 CBz C6 Et -4-CF3 11-C3 H7 88-89 4.106 Ν NHCIfe CHz C6 Et -4-CF3 Cffe C-CH 114-116 4 107 Ν 嶋 CHz Ce H4 -4-CF3 CH2 CH=CH2 115-117 4.108 Η OCIfe CHz Ce ik -4-CFs CHz C=CH 121-123 4.109 CH OCIfe CHz C6 H4 -4-CF3 CH2 CH=CH2 82-84 4.110 Ν NHCIfe CHz C6 Ή4 -4-CF3 11-C3 H? 132-134 4.111 Ν OCfe Cs Ife -2,4-¾ CZ Hs 90-92 4.112 CH OCIfe Ce -2,4-Fz C2 Hb 90-92 4.113 CH OCfe C6 IU -4-OCF3 Cz Hs 102-104 4.114 Ν OCIfe C6 )k -4-OCFs C2 H5 70-7Z -127- (請先閱讀背面之注意事項再填寫本頁)Cz Hs C2 H5 84-86 142-145 84-86 Designated by the Ministry of Economic Affairs, China Bureau of Standards and Technology Bureau, Consumer Cooperative, printed 4.81 N OCH3 Ce H4 -4-CI CHz C = CH 93-95 4.82 N OCfe Ce Et- 4-C1 (〇Ηε) z CH3 95-96 4.83 N OCIfe Cs -2-Cl c2 h5 107-109 4.84 CH OCHs Zq H4 -2-C1 Cz Hs 119-121 4.85 NHCIfe Ce tfe -2-CL4 * -Br Cz fl5 138-140 〇 \ 4.86 Ν NHCfe C2 h5 142-144 XYR ar7 1 trace I * 4.87 CK OCIfe C6 -4-C1 CHz C = CH 103-105 4.88 CH OCffe Cs Et -4-C1 (CHz) 2 CH3 90-92 4.89 N NHCHs (¾ -4-C1 CHz C three CH 130-132 4.90 N NHCfe Ce H4 -4-Cl (CHz) z CHs S6-98 4.31 N with Cfe Ce H4 -2-C1 C2 h5 128- 130 -126- \ kf.r 丨 ^ Bookbinding (please read the notes on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) A7 Central Bureau of Standards, Ministry of Economic Affairs Printed by employee consumer cooperative 433982 ^ B7 V. Description of invention (f4) 4.92 Ν OCIfe Ce Hs -4-SCH3 Cz Hs Fiber 4.93 CH OCIfe Ce H5 -4-SClfe Cz Hs 97-99 4.94 Ν NHCH3 C6 Hs -4-SCIfe Cz Hs 118-120 4.95 S OCHa Ce -4-C1 CHz CH = CIfe 74-76 4.96 S OCIf e H4 ~ 4_C1 1-C3 H7 75-77 4.97 CH OC03 C6 fk -4-C1 CH2 CH = CH2 73-75 4.98 CH OCIfe C6 H4 -4-C1 1-C3 H7 resin 4.99 NHCIfe ^ fU -4-C1 (¾ CH ^ CH2 101-103 4.100 Ν NHCH3 Cs fU -4-C1 1-C3 H7 104-105 4.101 CH OCIfe Ce% -3-CF3 CHz (^ CH resin 4.102 Ν OCfe Clfe Ce fk -4-CFs CHz C = CH 104-106 4.103 Ν OCIfe CHz C6 H4 -4-CF3 CH2 CH = CIi2 93-95 4.104 Ν OCIfe CSz C6 H4 -4-CF3 n-C3 H7 87-88 4.105 CH OCH3 CBz C6 Et -4-CF3 11 -C3 H7 88-89 4.106 Ν NHCIfe CHz C6 Et -4-CF3 Cffe C-CH 114-116 4 107 Ν 嶋 CHz Ce H4 -4-CF3 CH2 CH = CH2 115-117 4.108 Η OCIfe CHz Ce ik -4- CFs CHz C = CH 121-123 4.109 CH OCIfe CHz C6 H4 -4-CF3 CH2 CH = CH2 82-84 4.110 Ν NHCIfe CHz C6 Ή4 -4-CF3 11-C3 H? 132-134 4.111 OCfe Cs Ife -2 , 4-¾ CZ Hs 90-92 4.112 CH OCIfe Ce -2,4-Fz C2 Hb 90-92 4.113 CH OCfe C6 IU -4-OCF3 Cz Hs 102-104 4.114 Ν OCIfe C6) k -4-OCFs C2 H5 70-7Z -127- (Please read the precautions on the back before filling this page)

、1T 線本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 433982^ A7 B7 經濟部中夬標準局員工消費合作社印製五、發明説明 1 i 1 4.115 NHCIfe Ce Ife -Zyi-ΐζ c2 h5 125-127 1 1 1 4.116 N OCfe Cg H4 ™4~F c2 Hs 91-93 請先閲讀 1 1 1 ! 化細 X Y R AR7 mmm 背之注意事項再填寫本 I i 1 1 j 4.117 4.118 N CH 職 OCife C6 H4 -4-OCF3 Ce H+ -4-F Ce Hs Cz H5 119-121 88-90 ί 4.119 N 0CH3 Cs 1¾ -4-CH3 Cz H5 75-77 1 I 4.120 NHCIfe Ce Ik -4-F CZ Hs 118-120 1 1 4.121 lN OCife Cg H4 '4~Cl n-C4 Ha 102-104 1 訂 4.122 N 0(¾ Ce H4. -4-〇Ce Hs Cz Hs 95-97 1 1 4.123 CH 0(¾ Ce -4-C1 CHz 0C2 Hs 樹脂 1 i 4.124 N NBCH3 Ce H4 _4_C1 n~*C4 Hg 翻旨 ί f 4.125 CH OCHs Cs H4 -4-0C6 H5 Cz H5 101-103 1 级 4.128 N SHCH3 Cs H4 _4~0Ce H5 Cz Hs 82-84 1 4.127 N OCHs Ce ~4™Cl CHz 〇C2 H5 104-106 1 i 4.128 CH OCHs Ce S4 _4_C1 B-C4 Hg 旨 ί 1 4.129 N SHCH3 C6 U4 -4-C1 Clfe 0C2 H5 描脂 1 1 4.130 CH OCH3 C6 H4 -4-CIfe Cz Hs 102-104 1 I 4.131 N NHCIfe C6 H4 -4-Cffe Cz Hs 116-118 1 i 4 132 N OCH3 C6 H4 -4-OClfe C2 Hs 76-79 i 1 4 133 CH OCRs C6 -4-0CH3 C2 H5 98-100 1 1 -128 - i 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐}1. The paper size of the 1T line is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 433982 ^ A7 B7 Printed by the Consumers' Cooperative of the Zhongli Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention 1 i 1 4.115 NHCIfe Ce Ife -Zyi -ΐζ c2 h5 125-127 1 1 1 4.116 N OCfe Cg H4 ™ 4 ~ F c2 Hs 91-93 Please read 1 1 1! Refine the precautions for XYR AR7 mmm before filling in this I i 1 1 j 4.117 4.118 N CH OCife C6 H4 -4-OCF3 Ce H + -4-F Ce Hs Cz H5 119-121 88-90 ί 4.119 N 0CH3 Cs 1¾ -4-CH3 Cz H5 75-77 1 I 4.120 NHCIfe Ce Ik -4- F CZ Hs 118-120 1 1 4.121 lN OCife Cg H4 '4 ~ Cl n-C4 Ha 102-104 1 Order 4.122 N 0 (¾ Ce H4. -4-〇Ce Hs Cz Hs 95-97 1 1 4.123 CH 0 (¾ Ce -4-C1 CHz 0C2 Hs resin 1 i 4.124 N NBCH3 Ce H4 _4_C1 n ~ * C4 Hg 旨 f 4.125 CH OCHs Cs H4 -4-0C6 H5 Cz H5 101-103 Class 1 4.128 N SHCH3 Cs H4 _4 ~ 0Ce H5 Cz Hs 82-84 1 4.127 N OCHs Ce ~ 4 ™ Cl CHz 〇C2 H5 104-106 1 i 4.128 CH OCHs Ce S4 _4_C1 B-C4 Hg Purpose 1 4.129 N SHCH3 C6 U4 -4-C1 Clfe 0C2 H5 Grease 1 1 4.130 CH OCH3 C6 H4 -4-CIfe Cz Hs 102-104 1 I 4.131 N NHCIfe C6 H4 -4-Cffe Cz Hs 116-118 1 i 4 132 N OCH3 C6 H4 -4-OClfe C2 Hs 76-79 i 1 4 133 CH OCRs C6 -4-0CH3 C2 H5 98-100 1 1 -128-i 1 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

4 3 39 8 2 .J A7 B7 五、發明説明（ 4.134 N NHC& Ce Ht -4-OCJfe Cz H5 125-127 4.135 N OCffe 2-難 C2 H5 103-106 4.136 CH 0CH3 2· C2 Hs 93-96 4.137 f! OC03 Ce fk -4-CM Cz Hs 113-116 4.138 CH 0CH3 Ce H4 ~4_CN C2 H5 105-107 4.139 S NHCH3 2-雜 Cz Hs 148-150 4.140 N NHCH3 C6 ru -4-CN c2 h5 146-148 4.141 N 0(¾ C6 H4 -4-CF3 C2 Hs 111-113 4.142 N 0C& C6 H4 -4-CF3 CHz C=CH 98-100 4.143 N NHCIfe Ce H4 -4-CF3 (¾ C=CH 117-118 4.144 CH OCH3 C6 H4 -4-CF3 Cz H5 109 111 4.145 CH OCH3 C6 H4 -4-CF3 Ofe C^CH 102-104 4.146 N NHCH3 C6 Ei -4-CF3 Cz H5 143-145 4.147 CH 0CH3 CH2 -2-m c2 h5 107-109 ----------裝------1r------.線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 X Y R AR7 mmm 4.148 N OCfe CHz -2-蔡基 Cz Hs 86-89 4.149 if NHCH3 CHz -2-縫 C2 Hs 148-150 4.150 CH 0C& Clfe Cs H4 -4-CN Cz Hs 80-84 4.151 N OCfe Cfe C6 H4 -4-CN Cz Hs 113-116 4.152 N NHCIfe Cfe C6 iU -4-CfJ Cz Hs 126-129 -129- 本紙乐尺度適用中國國家標準（CNS ) A4現格（210X297公釐）經濟部中央標準局員工消費合作社印裝 4 3 39 8 2'^ A7 B7 五、發明説明（丨>"]) 表5: 下列通式之化合物類4 3 39 8 2 .J A7 B7 V. Description of the invention (4.134 N NHC & Ce Ht -4-OCJfe Cz H5 125-127 4.135 N OCffe 2- Difficult C2 H5 103-106 4.136 CH 0CH3 2 · C2 Hs 93-96 4.137 f! OC03 Ce fk -4-CM Cz Hs 113-116 4.138 CH 0CH3 Ce H4 ~ 4_CN C2 H5 105-107 4.139 S NHCH3 2-Miscellaneous Cz Hs 148-150 4.140 N NHCH3 C6 ru -4-CN c2 h5 146 -148 4.141 N 0 (¾ C6 H4 -4-CF3 C2 Hs 111-113 4.142 N 0C & C6 H4 -4-CF3 CHz C = CH 98-100 4.143 N NHCIfe Ce H4 -4-CF3 (¾ C = CH 117 -118 4.144 CH OCH3 C6 H4 -4-CF3 Cz H5 109 111 4.145 CH OCH3 C6 H4 -4-CF3 Ofe C ^ CH 102-104 4.146 N NHCH3 C6 Ei -4-CF3 Cz H5 143-145 4.147 CH 0CH3 CH2- 2-m c2 h5 107-109 ---------- install ------ 1r ------. Line (please read the precautions on the back before filling this page) Printed by the Consumer Bureau of Standards Bureau XYR AR7 mmm 4.148 N OCfe CHz -2-Caiji Cz Hs 86-89 4.149 if NHCH3 CHz -2-Slit C2 Hs 148-150 4.150 CH 0C & Clfe Cs H4 -4-CN Cz Hs 80-84 4.151 N OCfe Cfe C6 H4 -4-CN Cz Hs 113-116 4.152 N NHCIfe Cfe C6 iU -4-CfJ Cz Hs 126-129 -129- paper ruler Applicable to Chinese National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 39 8 2 '^ A7 B7 V. Description of Invention (丨 > "]) Table 5: The following Compounds of general formula

，其中R為CH2 Si ( Cfi3 ) 3且化合物之取代基A - δ7 在各種情況下相關於表Α中的一行。表6:通式ί.1之化合物類，其中R為CH2 Cs H4 — CF3且化合物之取代基A_K7在各種情況下相醞於表A中的一行0 表7:通式1.1之化合物類，其中R為CH2 C6 H4 — 3 — CFs且化合物之取代基A - R7在各種情況下相關於表A中的一行0 表8:通式1.1之化合物類，其中R為CH2 “ H4 — 4 — -130- 本紙張尺度適用中國國家標芈（CNS ) A4規格（210X297公釐） n —I— H. . . .~1 1 .....[..... !訂 . i— —i-^ (請先閲讀背面之注意事項再填寫本頁) A7 B7 4 3 398 五、發明説明（/d) CF3且化合物之取代基A— R7在各種情況下相關於表A中的一行。Where R is CH2Si (Cfi3) 3 and the substituents A-δ7 of the compound are in each case related to a row in Table A. Table 6: Compounds of general formula Γ.1, in which R is CH2 Cs H4-CF3 and the substituent A_K7 of the compound is in each case in a row 0 of Table A. Table 7: Compounds of general formula 1.1, where R is CH2 C6 H4 — 3 — CFs and the substituents A-R7 of the compound are in each case related to a row in Table A 0 Table 8: Compounds of the general formula 1.1 where R is CH2 “H4 — 4 — -130 -This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) n —I— H.... ~ 1 1 ..... [.....! Order. I— —i- ^ (Please read the notes on the back before filling this page) A7 B7 4 3 398 V. Description of the invention (/ d) CF3 and the substituent A-R7 of the compound are related to a row in Table A in each case.

表9;通式1.1之化合物類，其中R為C82 _2— F 且化合物之取代基A— R7在各種情況下相醖於表4中的一行 0 表通式1.1之化合物類，其中R為CH2 cs 1U — 3-F且化合物之取代基A — R7在各種情況下相關於表A中的一行0 表11:通式1.1之化合物類，其中R為CH2 cs H4 — 4 — F且化合物之取代基Α— β7在各種情況下相顒於表A中的一行。表12:通式1.1之化合物類，其中R為CHz Ce H4 ~2~ Cl且化合物之取代基a- R7在各種情況下相闞於表A中的一行0 表13:通式1.1之化合物類，其中R為CHz Cs H4 —3 — Cl且化合物之取代基a - R7在各種情況下相關於表A中的一行0 -131- 本紙張尺度適用中國國家榡準（CNS ) A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂 Μ 經濟部中央榡隼扃員工消費合作社印製 433982鱷 A7 B7 五、發明説明（/7j) 表14:通式I.1之化合物類，其中^為1^2 Ce 04 — C1且化合物之取代基A_ R7在各種情況下相13於表Αφ 8勺一行。表15:通式I.1之化合物類*其中RSCH2 Cs 114 _2一 Br且化合物之取代基A— R7在各種情況下相關於表儿中的一行。表16 :通式I . 1之化合物類，其中R為GHz c6 H4 — 3_ Br且化合物之取代基A— R7在各種情況下相關於表A中的一行。表17:通式1.1之化合物類，其中R為CH2 C6 1U _4~ Br且化合物之取代基A— R7在各種情況下相關於表A中的一行0 表18:通式1.1之化合物類，其中R為Ce B4 - 2— F且化合物之取代基A—R·/在各種情況下相關於表A中的一行。表19:通式1.1之化合物類，其中R為Cs H4 - 3— F且化合物之取代基A— R7在各種情況下相關於表&中的一行。表20:通式1.1之化合物類，其中R為Cs iU - 4-F且 -132- 本紙張尺度適用中國國家標準（CNS ) A4规格（210X 297公釐） I ...... 訂 I1H1 ~~. .~"" (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印^ 經濟部中央標準局負工消費合作杜印製 3 3 9 8 2 A7 B7 五、發明説明（化合物之取代基A-R7在各種情況下相關於表Α中的一行。表21:通式1.1之化合物類，其中R為Cs H4 — 2-C1且化合物之取代基A—R·?在各種情況下相關於表A中的一行。表22:通式1.1之化合物類，其中R為Cs H4 — 3— C1且化合物之取代基Α_ β7在各種情況下相關於表A中的一行。表23:通式1.1之化合物類，其中R為Cs H4 —4一 C1且化合物之取代基A_R7在各種情況下相關於表A中的一行。表24:通式1.1之化合物類，其中R為Cs H4 - 2- CF3 且化合物之取代基A- R7在各種情況下相關於表A中的一行 0 表25 :通式I . 1之化合物類，其中R為Cs H4 — 3 — CF3 且化合物之取代基A— ϋ7在各種情況下相關於表A中的一行 0 ' 表26:通式1.1之化合物類，其中R為Cs IU - 4-CF3 且化合物之取代基A_R7在各種情況下相關於表A中的一行 0 -1 3 3- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) -β 絲經濟部中央標隼局員工消費合作社印製 433982^ A7 B7 五、發明説明（hi) 表27:通式1.1之化合物類，其中η為一CH2 — 2’ 2 — 二氯- 1_環丙基且化合物之取代基Α- Κ7在各種情況下相關於表A中的一行。表28:通式1.1之化合物類，其中R為一 CH2 — 2 — 二溴一 1一環丙基且化合物之取代基A— R7在各種情況下相關於表A中的一行。表29 :通式I . 1之化合物類，其中R為一CH2 - 2 ’ 2-二氟-1-環丙基且化合物之取代基Α-1Ϊ7在各種情況下相關於表A中的一行。表30:通式1.1之化合物類，其中R為一 GHz C=CH且化合物之取代基A— R7在各種情況下相關於表A中的一行。表31:通式1.1之化合物類，其中R為一CH2 且化合物之取代基A— R7在各種情況下相關於表4中的一行表32:通式1.1之化合物類，其中R為一Ciu 3且化合物之取代基A— R7在各種情況下相關於表4中的一行。 -134- 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨OX 297公釐) (請先閱讀背面之注意事項再填寫本頁) 象· 訂 4 3 39 8 2a 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（0·^) 表33:通式1,1之化合物類*其中R為一 CH2 CH=C (CE 3 ) z且化合物之取代基A_R7在各種情況下相關於表A中的一行。表34:通式1.1之化合物類，其中ϊί為一CH2 CH=CC12 且化合物之取代基A — R7在各種情況下相關於表A中的一行 0 表35 :通式I . 1之化合物類，其中ϋ為一 CH ( CH3 ) CH = CH2且化合物之取代基A- R7在各種情況下柜關於表A中的一行。表36:通式1.1之化合物類，其中R為一 Cs H4 — 2— Br 且化合物之取代基A- R7在各種情況下相關於表A中的一行 0 表37通式1.1之化合物類，，其中R為一 Cs Η4 - 3- ΒΓ 且化合物之取代基A - R7在各種情況下相關於表A中的一行 0 表38:通式1*1之化合物類，其中1U — 4— Br 且化合物之取代基A— R7在各種情況下相關於表A中的一行 0 -1 3 5 - 本紙張尺度適用中國國家榡準（CNS > A4規格（210 X 297公釐）裝訂,—τ ίΜ· (請先閱讀背面之注意事項再填寫本頁)Table 9; Compounds of general formula 1.1, where R is C82_2_F and the substituents A-R7 of the compound are in each case in a row 0 in Table 4 Table of compounds of general formula 1.1, where R is CH2 cs 1U — 3-F and the substituents A — R7 of the compound are related in each case to a row in Table A 0 Table 11: Compounds of the general formula 1.1, where R is CH2 cs H4 — 4 — F and the substitution of the compound The radicals A-β7 correspond in each case to a row in Table A. Table 12: Compounds of the general formula 1.1, where R is CHz Ce H4 ~ 2 ~ Cl and the substituents a-R7 of the compound are in each case a row 0 in Table A. Table 13: Compounds of the general formula 1.1 , Where R is CHz Cs H4 —3 — Cl and the substituent a-R7 of the compound is related to a row in Table A in all cases 0 -131- This paper size applies to China National Standards (CNS) A4 specifications (210 X 297 mm) (Please read the notes on the back before filling out this page) Order M Printed by the Central Government of the Ministry of Economics and Staff Consumer Cooperative 433982 Crocodile A7 B7 V. Description of the Invention (/ 7j) Compounds of which ^ is 1 ^ 2 Ce 04-C1 and the substituent A_R7 of the compound is in each case 13 in Table Aφ 8 rows. Table 15: Compounds of the general formula I.1 * in which RSCH2 Cs 114 _2-Br and the substituents A-R7 of the compound are in each case related to a row in Table 1. Table 16: Compounds of the general formula I.1, where R is GHz c6 H4- 3_Br and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 17: Compounds of the general formula 1.1, where R is CH2 C6 1U _4 ~ Br and the substituents A- R7 of the compound are related in each case to a row 0 in Table A. Table 18: Compounds of the general formula 1.1, where R is Ce B4-2-F and the substituents A-R · / of the compound are in each case related to a row in Table A. Table 19: Compounds of the general formula 1.1 in which R is Cs H4-3-F and the substituents A-R7 of the compound are in each case related to a row in the table & Table 20: Compounds of general formula 1.1, where R is Cs iU-4-F and -132- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) I ...... Order I1H1 ~~ ... B7 V. Description of the invention (The substituents A-R7 of the compound are related to a row in Table A in various cases. Table 21: Compounds of general formula 1.1, where R is Cs H4- 2-C1 and the substituent A of the compound —R ·? In each case is related to a row in Table A. Table 22: Compounds of general formula 1.1, where R is Cs H4- 3-C1 and the substituent A_ β7 of the compound is in each case related to Table A Table 23: Compounds of general formula 1.1, where R is Cs H4- 4 -C1 and the substituents A_R7 of the compound are in each case related to one row of table A. Table 24: Compounds of general formula 1.1 , Where R is Cs H4-2- CF3 and the substituents A- R7 of the compound are in each case related to a row in Table A 0 Table 25: Formula I Compounds of 1 in which R is Cs H4—3—CF3 and the substituent A—ϋ7 of the compound is in each case related to a row in Table A 0 ′ Table 26: Compounds of Formula 1.1, where R is Cs IU-4-CF3 and the substituent A_R7 of the compound are related in each case to a row in Table A. 0 -1 3 3- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please first Read the notes on the back and fill in this page)-β Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs 433982 ^ A7 B7 V. Description of the invention (hi) Table 27: Compounds of general formula 1.1, where η is a CH2 — 2 ′ 2 —dichloro-1 —cyclopropyl and the substituents A-K7 of the compound are in each case related to one row in Table A. Table 28: Compounds of the general formula 1.1, where R is a CH 2 — 2 — Dibromo-1 cyclopropyl and the substituents A—R7 of the compound are in each case related to one row in Table A. Table 29: Compounds of the general formula I.1, where R is a CH 2-2 '2- Difluoro-1-cyclopropyl and the substituent A-1Ϊ7 of the compound are in each case related to one row in Table A. Table 30: Formula 1 .1 compounds, where R is a GHz C = CH and the substituent A-R7 of the compound is in each case related to a row in Table A. Table 31: Compounds of general formula 1.1, where R is a CH2 and The substituents A-R7 of the compound are related in each case to a row in Table 4. Table 32: Compounds of the general formula 1.1 in which R is a Ciu 3 and the substituents A-R7 of the compound are related to Table 4 in each case. In a row. -134- This paper size applies to Chinese National Standard (CNS) A4 specification (2 丨 OX 297 mm) (Please read the precautions on the back before filling this page) Image · Order 4 3 39 8 2a Staff of Central Bureau of Standards, Ministry of Economic Affairs Printed by Consumer Cooperatives A7 B7 V. Description of the invention (0 · ^) Table 33: Compounds of the general formula 1,1 * where R is a CH2 CH = C (CE 3) z and the substituent A_R7 of the compound under various circumstances Related to a row in Table A. Table 34: Compounds of the general formula 1.1, wherein ϊ is a CH2 CH = CC12 and the substituents A — R7 of the compound are related in each case to a row in Table A 0 Where ϋ is a CH (CH3) CH = CH2 and the substituents A-R7 of the compound are in each case a row in Table A. Table 36: Compounds of the general formula 1.1, where R is a Cs H4- 2-Br and the substituents A- R7 of the compound are in each case related to a row 0 in Table A Where R is a Cs Η 4-3- ΒΓ and the substituents A-R7 of the compound are in each case related to a row in Table A 0 Table 38: Compounds of the general formula 1 * 1, of which 1U — 4 — Br The substituent A—R7 in each case is related to a row in Table A. 0 -1 3 5-This paper size applies to the Chinese national standard (CNS > A4 size (210 X 297 mm) binding, —τ ίΜ · (Please read the notes on the back before filling this page)

經濟部中央標準局員工消費合作社印$L 43 39 8 2^ Α7 Β7 五、發明説明（fD) 表39:通式Ι·1之化合物類，其中^為_{^ (CH3 ) C2 Hs且化合物之取代基A_R7在各種情況下相關於表纟中的 —〇表40··通式1.1之化合物頚，其中ϋ為一CH2 CH (CH3 )2且化合物之取代基A— β·7在各種情況下相關於表A中的一行0 表41.1:通式1.1之化合物類，其中K為η — C4 H9且化合物之取代基A-R7在各種情況下相關於表A中的一行。表41.2:通式1_1之化合物類，其中1^為一〇}12—(^[1 4 — 4一 t一丁基且化合物之取代基A—R7在各種情況下相關於表A中的一行。表41.3:通式1.1之化合物類，其中R為一CH2 — Cs Η 3 — 3，4— Cl2且化合物之取代基Α — R7在各種情況下相關於表A中的一行。表41.4:通式1.1之化合物類，其中R為一 CHz — C6 Η 3 — 2，4— Cl2且化合物之取代基A— R7在各種情況下相關於表A中的一行。 -136- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 2ί»7公釐） (請先閲讀背面之注意事項再填窝本買) r泰‘ 、·*>*-Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs $ L 43 39 8 2 ^ Α7 Β7 V. Description of Invention (fD) Table 39: Compounds of the general formula 1.1, where ^ is _ {^ (CH3) C2 Hs and the compound The substituent A_R7 is related in various cases to Table 纟 —Table 40 ·· Compounds of Formula 1.1, where ϋ is a CH2 CH (CH3) 2 and the substituent A-β · 7 of the compound is in various cases The following is related to a row 0 in Table A. Table 41.1: Compounds of the general formula 1.1 where K is η-C4 H9 and the substituents A-R7 of the compound are related to a row in Table A in each case. Table 41.2: Compounds of the general formula 1_1, where 1 ^ is 〇} 12 — (^ [1 4—4-t-butyl and the substituents A-R7 of the compound are related to a row in Table A in each case Table 41.3: Compounds of general formula 1.1, in which R is a CH2 — Cs Η 3, 3 — 4-Cl2 and the substituents A — R7 of the compound are in each case related to a row in Table A. Table 41.4: General Compounds of formula 1.1, in which R is a CHz — C6 Η 3, 2, 4-Cl2 and the substituents A — R7 of the compound are related to a row in Table A in each case. -136- This paper scale applies to China Standard (CNS) A4 size (210 X 2ί »7mm) (Please read the precautions on the back before filling in the book) r Thai '、 · * > *-

43 3982^ A7 B7 經濟部中央搮準局貝工消費合作社印製五、發明説明A 表41.5:通式I.1之化合物類，其中R為一 Cs H3 — 2» 4 — Clz且化合物之取代基A— R7在各種情況下相關於表A 中的一行。表4 1 . 6 :通式I . 1之化合物類，其中R為_ Ce H3 — 3， 4— Clz且化合物之取代基A— R7在各種情況下相關於表A 中的一行。表41.7:通式ί·1之化合物類，其中R為一Cs H3 — 2 — Cl» 4 — ΒΓ且化合物之取代基Α- Ιί7在各種情況下相關於表 A中的一行。表41.8:通式1.1之化合物類*其中R為一Cs H3 — 3, 4一（一 O—CHz — 〇—)且化合物之取代基A— R7在各種情況下相關於表A中的一行。表41.9:通式1.1之化合物類，其中11為一（^{{4—4一 SCH3且化合物之取代基A-R7在各種情況下相關於表A中的一行。表41.10:通式1.1之化合物類，其中R為一C3 H4 — 4 -OCF3且化合物之取代基A— R7在各種情況下相關於表A -137- (請先閱讀背面之注意事項再填寫本頁) l·裝. 訂43 3982 ^ A7 B7 Printed by Shellfish Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs 5. Description of Invention A Table 41.5: Compounds of general formula I.1, where R is a Cs H3 — 2 »4 — Clz and the substitution of the compound The base A-R7 is in each case related to a row in Table A. Table 4 1.6: Compounds of the general formula I.1, where R is -CeH3- 3, 4-Clz and the substituents A- R7 of the compound are in each case related to a row in Table A. Table 41.7: Compounds of the general formula Γ · 1, in which R is a Cs H3- 2-Cl »4-ΒΓ and the substituent A-Ιί7 of the compound is in each case related to a row in Table A. Table 41.8: Compounds of Formula 1.1 * where R is -Cs H3-3, 4-(-O-CHz-0-) and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 41.9: Compounds of general formula 1.1, in which 11 is a (^ {{4--4-SCH3 and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 41.10: General formula 1.1 Compounds, in which R is a C3 H4- 4 -OCF3 and the substituent A- R7 of the compound is related to Table A -137- in each case (please read the precautions on the back before filling out this page)

M 本紙張尺度適用中國國家標孪（CNS > A4規《格（210X 297公釐） 4339821 經濟部中央標率局負工消費合作社印裝 A7 B7 五、發明説明（f'f) 中的一行。表41.11:通式1.1之化合物類，其中！^為一％1^—4 一 t — 丁基且化合物之取代基A— R·?在各種情況下相關於表 A中的一行。表41.12:通式1.1之化合物類，其中R為一 C6 1U — 4 -0CH3且化合物之取代基A— R7在各種情況下相關於表A 中的一行。表41.13:通式1.1之化合物類，其中11為一〇6114—4 —CH3且化合物之取代基A— R7在各種情況下相關於表A中的一行s 表41.14:通式1.1之化合物類，其中R為2_蔡基且化合物之取代基A_R7在各種情況下相關於表A中的一行。表41.15:通式1.1之化合物類，其中R為一 CH2 — 2-萘基且化合物之取代基A- R7在各種情況下相關於表A中的一行。表U . 1S :通式I . 1之化合物類，其中ϋ為一Ce — 4 —〇—（：6 Hs且化合物之取代基A— R7在各種情況下相關於 -1 3 8 ~ 本紙張尺度適用中國國家標率（CNS ) A4規格（210X297公釐） (請先聞讀背面之注意事項再填寫本頁) f% 訂 ^33982^ 經濟部中央標準局員工消費合作社印製M This paper size applies to the Chinese national standard (CNS > A4 rule, "(210X 297mm) 4339821 Central Government Standards Bureau of the Ministry of Economic Affairs, Consumer Work Cooperative, printed A7 B7 V. One line in the description of the invention (f'f) Table 41.11: Compounds of the general formula 1.1, where! ^ Is a% 1 ^ -4 to t-butyl and the substituent A-R ·? Of the compound is in each case related to a row in Table A. Table 41.12 : Compounds of general formula 1.1, where R is a C6 1U — 4 -0CH3 and the substituents A- R7 of the compound are in each case related to one row in Table A. Table 41.13: Compounds of general formula 1.1, of which 11 Is 0101114-CH3 and the substituent A-R7 of the compound is in each case related to a row in Table A. Table 41.14: Compounds of the general formula 1.1, where R is 2-Ceichyl and the substituent of the compound A_R7 is related to a row in Table A in various cases. Table 41.15: Compounds of general formula 1.1, where R is a CH2-2-naphthyl group and the substituent A-R7 of the compound is related to Table A in various cases. Table U. 1S: Compounds of the general formula I. 1, where ϋ is a Ce — 4 —〇— (: 6 Hs The substituent A—R7 of the compound is related to -1 3 8 ~ in various cases. This paper size is applicable to China National Standards (CNS) A4 specifications (210X297 mm) (Please read the precautions on the back before filling this page) f% Order ^ 33982 ^ Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

A7 B7五、發明説明表A中的一行。表4 1 . 1 7 :通式I . 1之化合物類，其中R為—C s H4 — 4 - CN且化合物之取代基A— H7在各種情況下相關於表A中的 —'行0 表U . 18 :通式I . 1之化合物類，其中S為一CH2 Cs H4 —4 - CN且化合物之取代基A - R7在各種情況下相關於表A 中的一行。表41 . 19 :通式I . 1之化合物類，其中E為一 C6 H3 — 3 —Cl— 4_CF3且化合物之取代基A— R7在各種情況下相關於表A中的一行。表4 1 , 2 0 :通式I . 1之化合物類，其中R為一 C έ H3 — 2 一 Cl— 4— CF3且化合物之取代基A— fi7在各種情況下相關於表Α中的一行。表A (請先閲讀背面之注意事項再填寫本頁) 訂 .線化合物 No. A-R7 -1 3 9- 本紙張尺度適用中國國家標準（CNS )六4说格U【〇X297公釐）經濟部中央標準局員工消費合作社印製 4 3 39 8 2 .j a7 B7 五、發明説明q W) A . 1 C 2 H 5 A . 2 n- C3 Hv A . 3 1-C3 b7 A . 4 n ~ C 4 Hg A . 5 n - C e Hi 3 A . 6 CHz F A . 7 chf2 A . 8 CHz C f3 A . 9 CHz ch=ch2 A . 10 ch2 ch=chch3 A . 1 1 CHe CH=C(CH3 )2 A . 12 ch2 CH = CHC 1 A . 13 CHz CH= C C 12 A . 1 4 ch2 C(CH3 )=ch2 A . 1 S CHz C= CH A . 1 6 CHz Si(CH3 )3 A . 17 CH2 _ c .丙基-2，2 A . 1 8 CHz -c .丙基 A . 1 9 ch2 CN A. 20 ch2 COOCH3 A . 2 L ch2 COOCz h5 -140- (請先閱讀背面之注意事項再填寫本頁)A7 B7 V. Description of the invention A row in Table A. Table 4 1. 17: Compounds of the general formula I.1, where R is -C s H4-4 -CN and the substituents A-H7 of the compound are in each case related to the-'line 0 table in Table A U. 18: Compounds of the general formula I. 1, where S is a CH2 Cs H4- 4 -CN and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 41.19: Compounds of the general formula I.1, in which E is a C6H3-3-Cl-4_CF3 and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 4 1, 2 0: Compounds of the general formula I. 1 in which R is a C 3 H 2 2-Cl 4 4-CF 3 and the substituent A- fi 7 of the compound is in each case related to a row in Table A . Form A (Please read the precautions on the back before filling this page) Order. Wire Compound No. A-R7 -1 3 9- This paper size applies to the Chinese National Standard (CNS) Sixty-fourth U [〇X297mm] Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 39 8 2 .j a7 B7 V. Description of the invention q W) A. 1 C 2 H 5 A. 2 n- C3 Hv A. 3 1-C3 b7 A. 4 n ~ C 4 Hg A. 5 n-C e Hi 3 A. 6 CHz FA. 7 chf2 A. 8 CHz C f3 A. 9 CHz ch = ch2 A. 10 ch2 ch = chch3 A. 1 1 CHe CH = C (CH3) 2 A. 12 ch2 CH = CHC 1 A. 13 CHz CH = CC 12 A. 1 4 ch2 C (CH3) = ch2 A. 1 S CHz C = CH A. 1 6 CHz Si (CH3) 3 A 17 CH2 _ c. Propyl-2, 2 A. 1 8 CHz -c. Propyl A. 1 9 ch2 CN A. 20 ch2 COOCH3 A. 2 L ch2 COOCz h5 -140- (Please read the note on the back first (Fill in this page again)

、1T ,—给本紙浪尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐）經濟部中夬標準局員工消費合作社印製 433982」 A7 B7 五、發明説明 A . 22 ch2 COO -i ~ C3 h7 A 23 ch ( ch3 )c〇〇c2 Hs A · 24 C(=0)oc z Hs A . 25 C(=0)nhch3 A . 26 C( = 0)C ( = 0) oc2 Hs A . 2 7 ch2 c6 HS A · 28 ch2 c6 h4 -2 - F k· 29 CH2 C6 H4 -3- F A . 30 CHz C6 h4 -4- F A . 3 1 CH2 c6 h4 -2- Cl A . 32 ch2 C 6 h4 -3- Cl A . 33 CHe C6 h4 -4- Cl A . 34 CHz c6 h4 -2- Br A . 35 CH2 Ce h4 -3- Br A · 36 CHz C6 R4 -4- B r A . 37 ch2 c6 H4 -2- C f3 A · 38 ch2 Ce h4 -3- cf3 A . 3 9 ch2 Ce H4 -4- c f3 表 42 : 下列通式之化合物類 -141- ---------~ -裝-- (請先聞讀背面之注意事項再填寫本買) -5 d 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 433^s2.^ αί __B7， 1T, —Apply the Chinese National Standard (CNS) A4 specification (210 × 297 mm) to the paper scale. Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs 433982 ”A7 B7 V. Description of the invention A. 22 ch2 COO -i ~ C3 h7 A 23 ch (ch3) c〇〇c2 Hs A · 24 C (= 0) oc z Hs A. 25 C (= 0) nhch3 A. 26 C (= 0) C (= 0) oc2 Hs A. 2 7 ch2 c6 HS A · 28 ch2 c6 h4 -2-F k · 29 CH2 C6 H4 -3- FA. 30 CHz C6 h4 -4- FA. 3 1 CH2 c6 h4 -2- Cl A. 32 ch2 C 6 h4 -3- Cl A. 33 CHe C6 h4 -4- Cl A. 34 CHz c6 h4 -2- Br A. 35 CH2 Ce h4 -3- Br A · 36 CHz C6 R4 -4- B r A. 37 ch2 c6 H4 -2- C f3 A · 38 ch2 Ce h4 -3- cf3 A. 3 9 ch2 Ce H4 -4- c f3 Table 42: Compounds of the following formula -141- --------- ~ -Pack-(Please read the precautions on the back before filling in this purchase) -5 d The paper size is applicable to China National Standard (CNS) A4 size (210X297 mm) 433 ^ s2. ^ Αί __B7

五、發明説明（I5. Description of the invention

，其中化合物之取代基類（Rs ) η，（ OR) q及A— R7 組合在各種情況下相關於表B中的一行。。他們的物理數據示於下表中。化合物編號栢關於表B。 (請先閱讀背面之注意事項再填寫本頁) 化合物編號物理數據化合物編號物理數據 4 2.3 樹脂 42.79 樹脂 42.12 樹脂 42.80 油狀物 4 2.14 樹脂 4 2.81 樹脂 42.20 樹脂 42.82 樹脂 42.21 樹脂、1Τ 經濟部中央標準局員工消費合作社印製The combination of the substituents (Rs) η, (OR) q and A-R7 of the compound is related to a row in Table B in each case. . Their physical data are shown in the table below. Compound No. Cypress on Table B. (Please read the precautions on the back before filling this page) Compound No. Physical Data Compound No. Physical Data 4 2.3 Resin 42.79 Resin 42.12 Resin 42.80 Oil 4 2.14 Resin 4 2.81 Resin 42.20 Resin 42.82 Resin 42.21 Resin, 1T Central Standards of the Ministry of Economy Printed by Bureau Consumers Cooperative

表B 化合物 No. (R 5 )q (〇 R)n A-R 7 -142- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）經濟部中央標準局員工消費合作社印製 4 3 3 9 8 2」 A7 _B7 五、發明説明（/P) Β . 1 - 2-0CH3 CHz C f3 Β . 2 - 3-0CH3 CEz cf3 Β . 3 - 4-0Cfi3 CHz CF3 Β . 4 - 2-OCz h5 ch2 CFs Β . 5 - 3-OCz H5 CHz C f3 Β . 6 4 * 0 C 2 H 5 CH2 CFs Β . 7 4-〇-η^〇3 H 7 CH2 C f3 Β . 8 - 4-0-i-C3 H 7 ch2 CF3 Β . 9 - 4~0^π~〇5 Η i 1 CHz C f3 Β . 1 0 4-0-Ce Hi 3 CH2 cf3 Β . 1 1 4-0-t-丁基 CHz cf3 Β . 12 2-CH3 - CH2 c f3 Β . 1 3 3-CH3 - CHz c f3 Β . 1 4 4-CH3 - CH2 CF3 Β . 15 2-Cz Hb - ch2 cf3 Β . 18 3 - C 2 Η 5 - ch2 CFs Β . 17 4 ^ C z H 5 - CHz CF3 Β . 18 2-CF3 - ch2 CF3 Β . 19 3 - c R3 - CHz cf3 Β . 20 4-CF3 - CHz c f3 Β . 2 1 4-SCH3 - CHz cf3 Β . 2 2 2-C1 - CHz CFs -143- (請先聞讀背面之注意事項再填寫本頁)Table B Compound No. (R 5) q (〇R) n AR 7 -142- This paper size applies to China National Standard (CNS) A4 (210X 297 mm) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 3 9 8 2 ″ A7 _B7 V. Description of the invention (/ P) Β. 1-2-0CH3 CHz C f3 Β. 2-3-0CH3 CEz cf3 Β. 3-4-0 Cfi3 CHz CF3 Β. 4-2-OCz h5 ch2 CFs Β. 5-3-OCz H5 CHz C f3 Β. 6 4 * 0 C 2 H 5 CH2 CFs Β. 7 4-〇-η ^ 〇3 H 7 CH2 C f3 Β. 8-4-0- i-C3 H 7 ch2 CF3 Β. 9-4 ~ 0 ^ π ~ 〇5 Η i 1 CHz C f3 Β. 1 0 4-0-Ce Hi 3 CH2 cf3 Β. 1 1 4-0-t-butyl CHz cf3 Β. 12 2-CH3-CH2 c f3 Β. 1 3 3-CH3-CHz c f3 Β. 1 4 4-CH3-CH2 CF3 Β. 15 2-Cz Hb-ch2 cf3 Β. 18 3-C 2 Η 5-ch2 CFs Β. 17 4 ^ C z H 5-CHz CF3 Β. 18 2-CF3-ch2 CF3 Β. 19 3-c R3-CHz cf3 Β. 20 4-CF3-CHz c f3 Β. 2 1 4-SCH3-CHz cf3 Β. 2 2 2-C1-CHz CFs -143- (Please read the precautions on the back before filling this page)

，1T '络本紙張尺度適用中國國家標準（CNS) Α4規格（210Χ297公釐）， 1T 'Network This paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm)

4 3 39 8 2-J A7 B7 五、發明説明w，) 經濟部中央標準局負工消費合作社印製 Β . 2 3 3-C 1 - CHz cf3 Β . 24 4-C1 - CH2 cf3 Β . 2 5 2-Br - CH2 C Fs Β . 26 4 - Β r - CHz CFs Β . 2 7 — 2-OCH3 CH2 F Β . 28 - 3-OCH3 CHz F Β . 29 - 4-OCH3 CHz F Β . 30 - 2-OCz Hs ch2 F Β . 3 1 - 3-OCz Hs CHz F Β . 3 2 - 4-OCz h5 ch2 F Β . 33 - 4-〇-il-C3 H? ch2 F Β . 34 - 4-0-1-C3 H7 ch2 F Β . 35 4-Q-II-C5 Hg CHz F Β . 36 - 4-〇-〇6 Hi 3 CHz F Β . 37 - 4-〇-t -丁基 CHz F Β . 38 2-CH3 - CUz F Β . 39 3-CH3 - CBz F Β . 40 4-CH3 - CHz F Β . 4 1 2-C2 H5 - CH2 F Β . 42 3 - C 2 Η 5 - CHz F Β. 43 4-C2 Hs - CHz F Β . 44 2-CFa - CUz F Β . 45 3-CF3 - CHz F -1 44- 11 H1 ~ , I II : 訂 Ϊ) . I 叙 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家榇準（CNS ) A4規格（210X297公釐）經濟部中央標準局員工消費合作社印製 433982·^ A7 B7 五、發明説明（/if4 B . 46 4-CF3 - ch2 B . 47 4'SCH3 - cr2 B . 48 2-C1 - cuz B . 49 3-C1 - CHe 8.50 4-C1 - CHz B . 5 1 2- Br - CHz B . 52 4 - B r — CHz B . 53 - 2-OCH3 chf2 B . 54 - 3-OCH3 CHF2 δ . 55 - 4-0CH3 CHFe Β . 56 - 2-OCz Hs CHFz Β . 57 - 3-OCz Hb chf2 Β . 58 - 4 - 0 C z H 5 CHFz Β . 59 - 4-0-11-C3 H 7 CHFz Β . 6 0 - 4-O-1-C3 H7 chf2 Β . 6 1 - 4-0-Π-C5 Hi 1 CHF2 Β . 62 - 4-0-Cs Hi i CHFz Β . 63 - 4-0-t-丁基 chf2 Β . 64 2-CHs - CHF2 Β . 6 5 3-CH3 - CHFz Β . 66 4-CH3 — chf2 Β . 67 2 ™ C 2 H 5 - CHFz Β . 68 3 - C 2 H s 一 CHFz —1 4 5- -. I It il ~1. * ~.......~1 I n ^ Γί I Ϊ 1 M 1 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 433982-. A7 B7 五、發明説明（/0¾ B . 6 9 B . 70 B . 7 1 B . 7 2 B . 7 3 B. 74 B . 7 5 B . 76 B . 77 B . 78 B . 79 B . 80 B . 8 1 B . 82 4-Cz Hs 2- CF3 3- CF3 4 - CF3 4- SCH3 2- Cl 3- C1 4- Cl 2-Br 4 - Br 2.4- F2 2.4- Fz 2,4 -F2 2 , 4-Fz4 3 39 8 2-J A7 B7 V. Description of the invention w,) Printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Β. 2 3 3-C 1-CHz cf3 Β. 24 4-C1-CH2 cf3 Β. 2 5 2-Br-CH2 C Fs Β. 26 4-Β r-CHz CFs Β. 2 7 — 2-OCH3 CH2 F Β. 28-3-OCH3 CHz F Β. 29-4-OCH3 CHz F Β. 30- 2-OCz Hs ch2 F Β. 3 1-3-OCz Hs CHz F Β. 3 2-4-OCz h5 ch2 F Β. 33-4-〇-il-C3 H? Ch2 F Β. 34-4-0 -1-C3 H7 ch2 F Β. 35 4-Q-II-C5 Hg CHz F Β. 36-4-〇-〇6 Hi 3 CHz F Β. 37-4-〇-t-butyl CHz F Β. 38 2-CH3-CUz F Β. 39 3-CH3-CBz F Β. 40 4-CH3-CHz F Β. 4 1 2-C2 H5-CH2 F Β. 42 3-C 2 Η 5-CHz F Β. 43 4-C2 Hs-CHz F Β. 44 2-CFa-CUz F Β. 45 3-CF3-CHz F -1 44- 11 H1 ~, I II: Order). I (Please read the note on the back first Please fill in this page again for this matter) This paper size is applicable to China National Standards (CNS) A4 specification (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 433982 · ^ A7 B7 V. Description of the invention (/ if4 B. 46 4 -CF3-ch2 B. 47 4'SCH3 -cr2 B. 48 2-C1-cuz B. 49 3-C1-CHe 8.50 4-C1-CHz B. 5 1 2- Br-CHz B. 52 4-B r — CHz B. 53-2-OCH3 chf2 B. 54-3-OCH3 CHF2 δ. 55-4-0CH3 CHFe Β. 56-2-OCz Hs CHFz Β. 57-3-OCz Hb chf2 Β. 58-4-0 C z H 5 CHFz Β. 59- 4-0-11-C3 H 7 CHFz Β. 6 0-4-O-1-C3 H7 chf2 Β. 6 1-4-0-Π-C5 Hi 1 CHF2 Β. 62-4-0-Cs Hi i CHFz Β. 63-4-0-t-butyl chf2 Β. 64 2-CHs-CHF2 Β. 6 5 3-CH3-CHFz Β. 66 4-CH3 — chf2 Β. 67 2 ™ C 2 H 5-CHFz Β. 68 3-C 2 H s -CHFz —1 4 5--. I It il ~ 1. * ~ ....... ~ 1 I n ^ Γί I Ϊ 1 M 1 (Please read the Please fill in this page for the matters needing attention) This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 433982-. A7 B7 V. Description of invention (/ 0¾ B. 6 9 B. 70 B. 7 1 B. 7 2 B. 7 3 B. 74 B. 7 5 B. 76 B. 77 B. 78 B. 79 B. 80 B. 8 1 B. 82 4-Cz Hs 2- CF3 3- CF3 4-CF3 4- SCH3 2- Cl 3- C1 4- Cl 2-Br 4-Br 2.4- F2 2.4- Fz 2,4 -F2 2, 4-Fz

CHF2 CHFz CHFz CHFz CHF2 CHFz chf2 CR?z CHF2 chf2 Cz Hs CHz -CH=CHZ CH2 C= CH H (請先閱讀背面之注意事項再填寫本頁) 訂 d 表43:下列通式之化合物類經濟部中央標隼局員工消費合作社印製CHF2 CHFz CHFz CHFz CHF2 CHFz chf2 CR? Z CHF2 chf2 Cz Hs CHz -CH = CHZ CH2 C = CH H (Please read the precautions on the back before filling out this page) Order d Table 43: Compounds of the following general formula Printed by the Central Bureau of Standards Staff Consumer Cooperatives

CH -14 6- 本紙張尺度適用中国國家標準（CNS ) A4現格（210X 297公釐）經濟部中央標準局員工消費合作社印製 433982 迖 A7 B7 五、發明説明（/抑），其中R為CH2 Si ( CH3 ) 3且化合物之取代基A— R7 在各種情況下相翮於表A中的一行。表44;通式1.2之化合物頚，其中R為CHz Cs H4 - 2 — CF3且化合物之取代基A- R7在各種情況下相關於表A中的一行0 表45:通式1.2之化合物類，其中R為CH2 Ce IU — 3-CF3且化合物之取代基A— R7在各種情況下相關於表A中的一行。表46:通式1.2之化合物類，其中R為CH2 Cs IU — 4 — CF3且化合物之取代基A— R7在各種情況下相關於表A中的一行。表4 7 :通式I . 2之化合物類，其中R為CH2 Cs 1U - 2- P 且化合物之取代基A- R7在各種情況下栢關於表A中的一行 0 表48 :通式I . 2之化合物類，其中R為GH2 Cs H4 ~ F且化合物之取代基A— R7在各種情況下相關於表A中的一行。 -147- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐} (請先閲請背面之注意事項再填寫本頁)CH -14 6- This paper size is applicable to Chinese National Standard (CNS) A4 (210X 297 mm). Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. CH2 Si (CH3) 3 and the substituents A to R7 of the compound in each case stand in a row in Table A. Table 44; Compound 頚 of the general formula 1.2, wherein R is CHz Cs H4-2-CF3 and the substituents A- R7 of the compound are in each case related to a row 0 in Table A Where R is CH2 Ce IU — 3-CF3 and the substituents A — R7 of the compound are in each case related to a row in Table A. Table 46: Compounds of general formula 1.2, where R is CH2 Cs IU — 4 — CF3 and the substituents A — R7 of the compound are in each case related to a row in Table A. Table 4 7: Compounds of the general formula I.2, where R is CH2Cs 1U-2-P and the substituents A-R7 of the compound are in each case a row 0 in Table A. Table 48: General formula I. Compounds of 2 in which R is GH2 Cs H4 ~ F and the substituents A to R7 of the compound are related to a row in Table A in each case. -147- This paper size applies to Chinese National Standard (CNS) Α4 specification (210X297 mm) (Please read the notes on the back before filling this page)

、1T 絲經濟部中央樣隼局員工消費合作社印衆 433982^ Λ7 B7 五、發明説明表49:通式1.2之化合物類，其中R為C2 Cs H4 - 4 — F 且化合物之取代基Α- ϋ7在各種情況下相關於表A中的一行 0 表5iJ :通式I . 2之化合物類，其中R為CH2 C6 H4 - 2 — Cl且化合物之取代基A_R7在各種情況下相關於表A中的一行0 表51:通式1,2之化合物類，其中R為CH2 Cs ίϊ4 -3-, C 1且化合物之取代基A— R7在各種情況下相關於表A中的一行。表52:通式1.2之化合物類，其中R為CH2 Cs 1U — 4 — Cl且化合物之取代基A- R7在各種情況下相關於表A中的一行。表53:通式1.2之化合物類，其中R為CH2 C6 IU — 2 — Br且化合物之取代基A - R7在各種情況下相關於表A中的一行。表54 :通式I . 2之化合物類，其中R為CH2 Cs H4 — 3-Br且化合物之取代基Α_ Εϊ7在各種情況下相關於表A中的一 -1 4 8 - 本紙張尺度適用中國國家標华（CNS ) A4規格（210X 297公釐} ---------------ΪΤ------絲 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 433982^ A7 B7 五、發明説明（/%) 行。表55:通式1.2之化合物類，其中R為CH2 Ce SU -4-Br且化合物之取代基A — R7在各種情況下相關於表A中的一行0 表56:通式1.2之化合物類，其中RgCs tU — 2 — F且化合物之取代基A_R7在各種情況下相關於表A中的一行。表57:通式1.2之化合物類，其中β為Cs H4 —3— F且化合物之取代基A- R7在各種情況下相關於表A中的一行。表58:通式1.2之化合物類，其中R為Cs H4 — 4一 F且化合物之取代基A_R7在各種情況下相關於表A中的一行。表53:通式1.2之化合物類，其中R為Cs H4 - 2-C1且化合物之取代基A— R7在各種情況下相關於表A中的一行。表60 :通式I . 2之化合物類，其中R為Cs H4 - 3 — C1且化合物之取代基A— R7在各種情況下相關於表A中的一行.。表61:通式1.2之化合物類，其中R為Q H4 — 4-C1且化合物之取代基A— R7在各種情況下相關於表A中的一行。 -1 4 9- 本紙張尺度適用中國國家標孪{ CNS ) A4規格（210X297公釐）批衣 Ί .13] 1 J媒 (請先聞讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作社印製 ν433982」 Α7 _Β7______ 五、發明説明（(的）表62:通式1.2之化合物類，其中R為Cs Η4 — 2-CF3 且化合物之取代基A- R·;在各種情況下相關於表&中的一行 0 表63 :通式I . 2之化合物類’其中R為Cs H4 — 3一 CF3 且化合物之取代基A- R·?在各種情況下相關於表的一行 0 表通式1.2之化合物類，其中R為Ce H4 _4_CF3 且化合物之取代基A- R7在各種情況下相關於表.Αφ的一行 0 表65:通式1.2之化合物類，其中位為“2 ―2’ 2_二氯—1-環丙基且化合物之取代基Α— R7在各種情況下相關於表A中的一行。表66:通式1.2之化合物類，其中— 2’ 2_ 一溴-1—環丙基且化合物之取代基A - R"?在各種情況下相關於表A中的一行。表67 :通式I . 2之化合物類，其中尺為CHz 一 2 ’ 2_二氟一 1 一環丙基且化合物之取代基A- K7在各種情況下相關 -1 5 0- 本紙張尺度適用中國國家標準（CNS ) A4規格（2[0Χ 297公釐） I I (1 _ [ 1. ~~n ~111 ~~, 訂 I , . 妹 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央橾孪局員工消費合作社印製 4339 82 , A7 B7 五、發明説明（/Iff) 於表A中的一行。 _ 表68 :通式I . 2之化合物類，其中R為CHz Ce CH且化合物之取代基A_R7在各種情況下枏關於表A中的一行。表69:通式1.2之化合物類，其中ϋ為CH2 CH=CH2且化合物之取代基A— R7在各種情況下相關於表A中的一行。表70:通式1.2之化合物類，其中R為Cii2 CH=CHCH3 且化合物之取代基A - R7在各種情況下相關於表A中的一行 0 表71 :通式I . 2之化合物類，其中R為CH2 CH = C ( CHs )2且化合物之取代基A— R7在各種情況下相關於表A中的一行。表72:通式1.2之化合物類*其中R為CH2 CH=CC12 & 化合物之取代基A~R7在各種情況下相關於表A中的一行。表73 :通式I . 2之化合物類，其中R為CH ( CHs ) CH = CH2且化合物之取代基A— R7在各種情況下相關於表A中的一行0 -15 1- 本紙張尺度適用中國國家#準（CNS ) A4規格（210X 297公釐） ^衣訂" (請先閱讀背面之注意事項再填寫本頁) ^ 3 39 q 2 .1 A7 B7 經濟部中央標隼局貝工消費合作社印製五、發明説明表74:通式1.2之化合物類，其中R為IU _2-Br且化合物之取代基A - R7在各種情況下相關於表A中的一行。表75:通式1.2之化合物類，其中11為（：6 IU — 3 — Br且化合物之取代基A—R7在各種情況下相關於表A中的一行。表76:通式1.2之化合物類 > 其中R為H4 - 4— Br且化合物之取代基A— R·?在各種情況下相關於表A中的一行。表77:通式1.2之化合物類，其中R為CH (CH3 ) C2 Η s且化合物之取代基A — R7在各種情況下相腿於表Α中的一行。表78 ;通式I . 2之化合物類，其中R為CH2 CH ( CH3 ) 2且化合物之取代基A— R7在各種情況下相關於表A中的一行0 表79.1:通式ί.2之化合物類，，其中S為n-C4 H3且化合物之取代基A_R7在各種情況下相關於表A中的一行。表79 . 2 :通式I . 2之化合物類，其中β為CH2 — Cs B4 —4_t- 丁基且化合物之取代基A— R7在各種情況下相關於表A中的一行。 -152- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本買) 訂經濟部中央標準局貝工消費合作社印製 4339 8 2,j A7 B7 五、發明説明（ίθ) 表79.3:通式1.2之化合物類，其中&為[：112-(^113 一 3，4— Clz且化合物之取代基A— R7在各種情況下相關於表A中的一行。表79 . 4 :通式I . 2之化合物類，其中R為CH2 — Cs H3 —Z，4一 Cl2且化合物之取代基A— 在各種情況下相關於表A中的一行。表73 . 5 :通式Ϊ . 2之化合物類，其中R為Cs fi4 — 2，4 一 Cl2且化合物之取代基A- R7在各種情況下栢關於表A中的一行。表79.6:通式1.2之化合物類，其中R為Ce H3 — 3，4 ~ Cl2且化合物之取代基A- R7在各種情況下相關於表A中的一行。表7g.7:通式I.2之化合物類，其中R為CsH3—2—Cl * 4—Br旦化合物之取代基A— R7在各種情況下相關於表A 中的一行。表7S . 8 :通式I . 2之化合物類，其中R為Cs Ih — 3，4 一（―0— CH2 — 〇—）且化合物之取代基Α-ϋ7在各種情 -1 53- 本紙乐尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) ，1Τ 經濟部中央橾準局負工消资合作社印製 4 3 3982^ at B7 五、發明説明#1) 況下相關於表A中的一行。表79.9:通式1.2之化合物類，其中R為Cs H4 — 4 — SCHs且化合物之取代基A_R7在各種情況下相關於表九中的一行。表79.10:通式1.2之化合物類，其中R為C 6 H4 - 4 _ 0CF3且化合物之取代基A_R7在各種情況下相關於表4中的一行。表79.11:通式1.2之化合物類，其中兄為（^114一4-七 -丁基且化合物之取代基A-R7在各種情況下相關於表A中的一行。表79·12:通式1.2之化合物類，其中R為Cs IU — 4 — OCH3且化合物之取代基A - R7在各種情況下相關於表A中的一行。表79 . 13 :通式I . 2之化合物類，其中R為Cs H4 - 4 — CH3且化合物之取代基A-R7在各種情況下相關於表A中的 ^r-r, 订 0 表79.14:通式1.1之化合物頸，其中R為2 —萘基且化 -1 5 4 - 本紙張尺度適用中國國家標準（CNS ) A4現格（2丨0X297公釐） (請先閲讀背面之注意事項再填寫本頁) 訂 433982 經濟部中央標準局員工消费合作社印製 A7 B7 五、發明説明（[ΓΗ 合物之取代基A— R7在各種情況下相關於表Α中的一行。表73·15:通式1.1之化合物類，，其中R為一 CH2— 2 —萘基且化合物之取代基A— R7在各種情況下相關於表A中的一行。表79.16:通式1.1之化合物類，其中R為一 Cs H4 - 4 一 0— Ce H5且化合物之取代基A~R7在各種情況下相關於表A中的一行。表79 . 1 7 :通式I . 1之化合物類，其中R為一 Cs H4 ~ 4 _ CIJ且化合物之取代基A— R7在各種情況下相關於表A中的 —行。表79.18;通式1.1之化合物類，其中&為_{^2(^114 一 4一 CN且化合物之取代基A- 在各種情況下相關於表A 中的一行。表7 3. 19 :通式I . 2之化合物類，其中R為一 C6 H3 — 3 —Cl 一 4 — CF3且化合物之取代基Α— β·?在各種情況下相關於表Α中的一行。表73.20:通式1.2之化合物類’其中R為一 Cs _2 -155- 本紙浪尺度適用中國國家標隼（CNS ) Α4規格（210Χ297公釐} (請先閱讀背面之注意事項再填寫本頁) 訂 Μ 433982 A7 B7 五、發明説明（/0) -Cl - 4- CFs且化合物之取代基A— β7在各種情況下相關於表Α中的一行。表80:下列通式之化合物類1.1T Consumer Cooperatives of Central Sample Industry Bureau, Ministry of Economic Affairs, Yinzhong 433982 ^ Λ7 B7 V. Description of the invention Table 49: Compounds of general formula 1.2, where R is C2 Cs H4-4-F and the substituent A- ϋ7 of the compound In each case it is related to a row 0 in Table A. Table 5iJ: Compounds of the general formula I. 2 in which R is CH2 C6 H4-2 —Cl and the substituent A_R7 of the compound is in each case related to Table A. Row 0 Table 51: Compounds of the general formula 1,2, where R is CH2 Cs ϊ4-3-, C 1 and the substituents A-R7 of the compound are related to a row in Table A in each case. Table 52: Compounds of the general formula 1.2 where R is CH2Cs1U-4-Cl and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 53: Compounds of general formula 1.2 in which R is CH2 C6 IU — 2 — Br and the substituents A-R7 of the compound are in each case related to one row in Table A. Table 54: Compounds of the general formula I. 2 in which R is CH2 Cs H4- 3-Br and the substituent A_Eϊ7 of the compound is in all cases related to -1 in Table A-1 8-This paper is for China National Standard Chinese (CNS) A4 specification (210X 297mm) --------------- ΪΤ ------ Silk (Please read the precautions on the back before filling this page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 433982 ^ A7 B7 V. Description of the invention (/%) Table 55: Compounds of general formula 1.2, where R is CH2 Ce SU -4-Br and the substituent A of the compound — R7 in each case is related to a row in Table A 0 Table 56: Compounds of the general formula 1.2 in which RgCs tU — 2 — F and the substituent A_R7 of the compound are in each case related to a row in Table A. Table 57: Compounds of general formula 1.2, where β is Cs H4-3-F and the substituents A-R7 of the compound are in each case related to one row in Table A. Table 58: Compounds of general formula 1.2, where R Is Cs H4- 4 -F and the substituent A_R7 of the compound is in each case related to a row in Table A. Table 53: Compounds of general formula 1.2, where R is Cs H4-2-C1 and The substituents A-R7 of the compound are in each case related to a row in Table A. Table 60: Compounds of the general formula 1.2, where R is Cs H4-3-C1 and the substituents A-R7 of the compound are in various In this case, it is related to one row in Table A. Table 61: Compounds of general formula 1.2, where R is Q H4-4-C1 and the substituents A-R7 of the compound are related to one row in Table A in each case. -1 4 9- The size of this paper applies to the Chinese National Standard {CNS) A4 size (210X297 mm) Approved clothing .13] 1 J media (please read the precautions on the back before filling this page) Ministry of Economy Central Standard Printed by the Bureau ’s Consumer Cooperatives ν433982 ”Α7 _Β7 ______ 5. Description of the invention (() Table 62: Compounds of general formula 1.2, where R is Cs Η 4 — 2-CF3 and the substituents of the compounds A-R ·; in various Corresponding to a row 0 in the table & Table 63: Compounds of the general formula I. 2 'where R is Cs H4- 3-CF3 and the substituents A-R ·? Of the compound are related to the table in various cases One row of 0 represents a compound of general formula 1.2, where R is Ce H4_4_CF3 and the substituents A-R7 of the compound are in each case Table 0. Aφ 0 of the table. Table 65: Compounds of the general formula 1.2 in which the position is "2-2 '2-dichloro-1-cyclopropyl and the substituents A-R7 of the compound are related to the table in various cases. A line in A. Table 66: Compounds of the general formula 1.2, in which-2 '2 -bromo-1 -cyclopropyl and the substituent A-R " of the compound are in each case related to a row in Table A. Table 67: Compounds of the general formula I.2, where the ruler is CHz-2 '2 -difluoro-1 -cyclopropyl and the substituent A-K7 of the compound is relevant in various cases-1 5 0-This paper size applies China National Standard (CNS) A4 Specification (2 [0 × 297 mm) II (1 _ [1. ~~ n ~ 111 ~~, Order I,. Sister (Please read the precautions on the back before filling this page) Economy Printed by the Consumer Cooperatives of the Ministry of Health and Labor of the People's Republic of China 4339 82, A7 B7 5. The description of the invention (/ Iff) is in a row in Table A. _ Table 68: Compounds of general formula 1.2, where R is CHz Ce CH and The substituent A_R7 of the compound is in each case 枏 about a row in Table A. Table 69: Compounds of the general formula 1.2, in which ϋ is CH2 CH = CH2 and the substituent A_R7 of the compound is related to Table A in each case Table 70: Compounds of general formula 1.2, where R is Cii2 CH = CHCH3 and the substituents A-R7 of the compound are in each case related to a row 0 in Table A. Table 71: General formula I. 2 Compounds where R is CH2 CH = C (CHs) 2 and the substituents A-R7 of the compound are in each case related to one row in Table A. Table 72: Formula 1.2 Compounds * where R is CH2 CH = CC12 & The substituents A ~ R7 of the compound are in each case related to one row in Table A. Table 73: Compounds of general formula 1.2 where R is CH (CHs) CH = CH2 and the substituent A—R7 of the compound are related to a row in Table A in each case. 0 -15 1- This paper size applies to China National Standard #CNS (CNS) A4 (210X 297 mm) ^ Clothing " (Please read the notes on the back before filling out this page) ^ 3 39 q 2 .1 A7 B7 Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of Invention Table 74: Compounds of Formula 1.2, of which R is IU _2-Br and the substituents A-R7 of the compound are in each case related to one row in Table A. Table 75: Compounds of general formula 1.2, where 11 is (: 6 IU — 3 — Br and The substituents A-R7 are in each case related to a row in Table A. Table 76: Compounds of Formula 1.2 > where R is H4-4-Br and the substituent A-R · of the compound in each case Related to one row in Table A. Table 77: Compounds of Formula 1.2, where R is CH (CH3) C2 3 s and the substituent A — R7 In each case, the row is in a row in Table A. Table 78; Compounds of the general formula 1.2, where R is CH2 CH (CH3) 2 and the substituents A-R7 of the compound are related to Table A in each case One row 0 in Table 79.1: Compounds of general formula Γ.2, where S is n-C4 H3 and the substituent A_R7 of the compound is related to a row in Table A in each case. Table 79.2: Compounds of general formula I.2. Where β is CH2-CsB4-4-t-butyl and the substituents A-R7 of the compound are in each case related to a row in Table A. -152- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297mm) (Please read the notes on the back before filling in this purchase) Order printed by the Central Standards Bureau of the Ministry of Economic Affairs and printed by Cooper Cooperative 4339 8 2, j A7 B7 V. Description of the invention (ίθ) Table 79.3: Compounds of general formula 1.2, where & is [: 112-(^ 113-3,4-Clz and the substituent A-R7 of the compound is related in various cases. One row in Table A. Table 79.4: Compounds of the general formula I.2. Where R is CH2-CsH3-Z, 4-Cl2 and the substituent A of the compound is related in each case to Table A. One row. Table 73.5: Compounds of the general formula Ϊ. 2, where R is Cs fi4--2,4-Cl2 and the substituents A-R7 of the compound are in each case a row in Table A. Table 79.6: Compounds of general formula 1.2, in which R is Ce H3-3-4, Cl2 and the substituents A-R7 of the compound are in each case related to one row in Table A. Table 7g.7: Compounds of general formula I.2. Class, in which R is the substituent A-R7 of the CsH3--2-Cl * 4-Br denier compound in each case is related to a row in Table A. Table 7S. 8: Compounds of the formula I.2, where R is Cs Ih — 3,4 — (“0 — CH2 — 0 —) and the substituents A-ϋ7 of the compound are in various situations -1 53- This paper music standard applies Chinese national standards ( CNS) Α4 specification (210X297 mm) (please read the precautions on the back before filling this page), printed by 1T Central Government Standards Bureau, Ministry of Economic Affairs, Consumers and Consumers Cooperatives 4 3 3982 ^ at B7 V. Invention Description # 1) In this case, it is related to a row in Table A. Table 79.9: Compounds of general formula 1.2, where R is Cs H4- 4-SCHs and the substituent A_R7 of the compound is in each case related to a row in Table IX. Table 79.10: Compounds of general formula 1.2 where R is C 6 H4-4 _0CF3 and the substituent A_R7 of the compound is in each case related to a row in Table 4. Table 79.11: Compounds of the general formula 1.2, in which the brother is (^ 114-4-hepta-butyl and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 79 · 12: General formula Compounds of 1.2, where R is Cs IU — 4 — OCH3 and the substituents A-R7 of the compound are in each case related to one row in Table A. Table 79. 13: Compounds of general formula 1.2, where R Is Cs H4-4-CH3 and the substituents A-R7 of the compound are related to ^ rr in Table A in each case, Table 0. Table 79.14: Compound neck of formula 1.1, where R is 2 -naphthyl and- 1 5 4-This paper size applies to Chinese National Standard (CNS) A4 (2 丨 0X297 mm) (Please read the precautions on the back before filling out this page) Order 433982 Printed by A7, Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs B7 V. Description of the invention ([Substituents A-R7 of the ΓΗ compound are related to a row in Table A in various cases. Table 73 · 15: Compounds of the general formula 1.1, where R is a CH2-2-naphthalene The substituents A to R7 of the compound are in each case related to one row in Table A. Table 79.16: Compounds of the general formula 1.1, which R is a Cs H4-4-0-Ce H5 and the substituents A to R7 of the compound are in each case related to a row in Table A. Table 79. 17: Compounds of the general formula I. 1, where R is A Cs H4 ~ 4_CIJ and the substituents A-R7 of the compound are in various cases related to the-line in Table A. Table 79.18; Compounds of general formula 1.1, where & is _ {^ 2 (^ 114 a 4-CN and the substituent A- of the compound are in each case related to one row in Table A. Table 7 3. 19: Compounds of the general formula I. 2 where R is -C6 H3-3 -Cl-4- CF3 and the substituent A—β ·? Of the compound are in each case related to a row in Table A. Table 73.20: Compounds of general formula 1.2 'where R is a Cs _2 -155- (CNS) A4 specification (210 × 297 mm) (Please read the notes on the back before filling this page) Order M 433982 A7 B7 V. Description of the invention (/ 0) -Cl-4- CFs and the substituent A- β7 of the compound In each case it is related to a row in Table A. Table 80: Compounds of the following formulae

(〇F〇n ，其中化合物之取代基類Hs ，OR及A — ΙΪ7的組合在各種情況下相關於表8中的一行。化合物 H 〇物理數據装 i i ^ I-^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印製 80.79 80.80 80.81 熔點 8 4 - 8 5 °C 油狀物樹脂^ 表8 1 :下列通式之化合物類 -156- 本纸張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） 43 39 ^2^ A7 _________B7 I、發明説明（奶）(Fon), where the combination of the substituents Hs of the compound, OR, and A — Ι7 is related in each case to a row in Table 8. Compound H 〇 Physical data package ii ^ I- ^ (Please read the back Note: Please fill in this page again.) Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shelley Consumer Cooperatives. 80.79 80.80 80.81 Melting point 8 4-8 5 ° C Oily resin ^ Table 8 1: Compounds of the following general formula -156- This paper Standards are applicable to China National Standard (CNS) A4 specifications (210X297 mm) 43 39 ^ 2 ^ A7 _________B7 I. Description of invention (milk)

，其中R為CHz Si (CH3 ) 3且化合物之収代基A—R"? 在各種情況下栢關於表A中的一行。表82:通式1.3之化合物類，其中R為CH2 H4 — 2 — CF3且化合物之取代基A— R7在各種情況下相關於表A中的一行0 表83 :通式I . 3之化合物類，其中U為CH2 C6 Η4 — 3-CF3且化合物之取代基Α— ίί7在各種情況下相關於表九中的一行。 ---------i------訂-------.if (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消费合作社印製行類物R7 合一 b A 彳基之 35代 I.取式之通物 : 合 84化表且的中 A 表於 cegi 目 2 耗 CE下成況 ί情 I 種各在之 3 I 式通 * * 5 8 表, Where R is CHz Si (CH3) 3 and the compound's substituent group A—R "? In each case, Bo is about a row in Table A. Table 82: Compounds of the general formula 1.3, where R is CH2 H4-2-CF3 and the substituents A-R7 of the compound are in each case related to a row in Table A 0 , Where U is CH2 C6 Η4 — 3-CF3 and the substituent A— ί7 of the compound is in each case related to a row in Table 9. --------- i ------ Order -------. if (Please read the notes on the back before filling out this page) Printed by the Consumer Consumption Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Class R7 Consolidation b A 35th generation of A base I. General formula: Combined 84 chemical tables and middle A tables in cegi Heading 2 Condition under CE consumption Situation I Each type of 3 I type communication * * 5 8 tables

基代职之物合化且 F 中其 4 Η 為表於關相下中況其情，'a 類各物在合 7The basic agent's things are combined, and 4 of them in F is the same as the situation under the relevant phase.

4 Η 6 C 的中本紙張尺度適用中國园家裙準（CNS )从规格（21QX297公瘦） 4 3 39 8 2^ A7 B7 經濟部中央標準局貞工消费合作社印製五、發明説明（"ί) 行。表85:通式1,3之化合物類，其中I^CH2 % ίϊ4 — 3 — F且化合物之取代基Α_β·?在各種情況下栢關於表4中的一行。表87:通式Ι·3之化合物、類’其中Η4 -4-F且化合物之取代基A - 8·?在各種情況下栢關於表&中的一行。表8δ:通式1.3之化合物類*其中Κ為CH2 Cs Η4 —2-C1且化合物之取代基A_R·?在各種情況下相關於表^申的一行。 . 表89 :通式1.3之化合物類，其中R為CH2 Cs U4 — 3_ Cl且化合物之取代基A_R7在各種情況下相關於表A中的一行。表90:通式1.3之化合物類’其中R為CH2 % !14 ~4~ C1且化合物之取代基A-R·?.在各種情況下相關於表Α中的一行0 表91:通式Ι·3之化合物類’其中1^CH2 Cs Η4 — 2~ -158- 本紙張尺度適用中國國家標準（CNS ) Α4规格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 裝. 、-ιτ 線經濟部中央標隼局員工消費合作社印製 433982-^ A7 A7 ___B7_ 五、發明説明（0?)4 Η 6 C Chinese paper standard is applicable to Chinese gardener skirt standard (CNS) from specifications (21QX297 male thin) 4 3 39 8 2 ^ A7 B7 Printed by Zhengong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs ; ί) OK. Table 85: Compounds of the general formulae 1, 3, in which I ^ CH2% ϊ — 4- 3-F and the substituent A_β ·? Of the compound are in each case a row in Table 4. Table 87: Compounds of the general formula I · 3, in which Η4-4-F and the substituent A-8 of the compound are in each case a row on the table & Table 8δ: Compounds of the general formula 1.3 * where K is CH2 Cs Η4-2-C1 and the substituent A_R ·? Of the compound is related to the row of Table ^ in each case. Table 89: Compounds of general formula 1.3, where R is CH2 Cs U4- 3 -Cl and the substituent A_R7 of the compound is in each case related to a row in Table A. Table 90: Compounds of the general formula 1.3 where R is CH2%! 14 ~ 4 ~ C1 and the substituents AR ·? Of the compound are related in each case to a row 0 in Table A. Table 91: General formula 1-3 Compounds of which '1 ^ CH2 Cs Η4 — 2 ~ -158- This paper size applies to China National Standard (CNS) A4 specifications (210X 297 mm) (Please read the precautions on the back before filling this page). -ιτ Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs 433982- ^ A7 A7 ___B7_ V. Description of the Invention (0?)

Br且化合物之取代基Α— β7在各種情況下相關於表A中的一行0 表32 :通式I . 3之化合物類，其中R為CH2 Cs H4 — 3-ΒΓ且化合物之取代基A— R7在各種情況下相關於表A中的一行。表33:通式1.3之化合物類，其中R為CH2 Cs fU — 4 — Br且化合物之取代基A - R7在各種情況下相關於表A中的一行。表94:通式1.3之化合物類，其中R為C6 H4 — 2—F且化合物之取代基A- R7在各種情況下相關於表A中的一行。表95:通式1.3之化合物類，其中R為Ce IU — 3— F且化合物之取代基A— R7在各種情況下相關於表A中的—行。表96:通式1.3之化合物類*其中R為C6 H4 — 4一卩且化合物之取代基A— R·?在各種情況下栢關於表A中的一表37:通式1.3之化合物類，其中R為Ce IU — 2— CIS 化合物之取代基A- R7在各種情況下相關於表A中的一行β -1 5 9- 本紙乐尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁)Br and the substituents A-β7 of the compound are in each case related to a row 0 in Table A. Table 32: Compounds of the general formula 1.3, where R is CH2 Cs H4- 3-BΓ and the substituent A- R7 is in each case related to a row in Table A. Table 33: Compounds of general formula 1.3 in which R is CH2Cs fU-4-Br and the substituents A-R7 of the compound are in each case related to one row in Table A. Table 94: Compounds of the general formula 1.3 in which R is C6 H4- 2 -F and the substituents A to R7 of the compound are in each case related to a row in Table A. Table 95: Compounds of general formula 1.3 in which R is Ce IU — 3 — F and the substituents A — R 7 of the compound are in each case related to the line in Table A. Table 96: Compounds of general formula 1.3 *, where R is C6 H4--4, and the substituents A-R ·? Of the compound, in each case, about Table A in Table A: Table 37: Compounds of general formula 1.3, Wherein R is Ce IU — 2— CIS compound substituent A- R7 is related to a row in Table A β -1 5 9- The paper scale is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) ) (Please read the notes on the back before filling this page)

,1T 433982·.^ A7 B7 五、發明説明（ί<Ί) 表98:通式1.3之化合物類，其中R為Cs IU — 3-C1且化合物之取代基A— R7在各種情況下相關於表A中的一行。表93:通式1,3之化合物類，其中R為Ce β4 — 4— C1且化合物之取代基A-R7在各種情況下相瞄於表Α中的一行。表100:通式1.3之化合物類，其中R為Cs H4 —2— CF 3且化合物之取代基Α— β7在各種情況下相關於表A中的一行。表10 1:通式1.3之化合物類，其中R為C6 fU —3— CF 3且化合物之取代基A - R7在各種情況下相關於表A中的一行。表102:通式1.3之化合物類，其中R為Cs H4 -3且化合物之取代基A— R7在各種情況下相關於行。訂 I IM (請先閱請背面之注意事項再填寫本頁) 經济部中夬標隼局員工消費合作社印製表類物合化之二氛中 A 表於表基代取之物合 I.化式且。通基行 : 丙一 03環的 1^5 -柑 "下 Ζ*況一情 2 種 CH各為在 R 中R7 其 ~ 式通為 R 中其類物合化之二本紙張尺度通用中國國家標準（CNS ) A4規格（210x297公釐）1T 433982 ·. ^ A7 B7 V. Description of the invention (ί < Ί) Table 98: Compounds of the general formula 1.3, in which R is Cs IU — 3-C1 and the substituents A- R7 of the compound are related in various cases One row in Table A. Table 93: Compounds of general formulas 1, 3, where R is Ce β 4-4-C 1 and the substituents A-R 7 of the compound are in each case aligned in a row in Table A. Table 100: Compounds of the general formula 1.3 in which R is Cs H4- 2-CF 3 and the substituents A-β7 of the compound are in each case related to one row in Table A. Table 10 1: Compounds of general formula 1.3, where R is C6 fU —3 — CF 3 and the substituents A-R7 of the compound are in each case related to one row in Table A. Table 102: Compounds of the general formula 1.3 in which R is Cs H4 -3 and the substituents A to R7 of the compound are relevant in each case. Order I IM (please read the precautions on the back before filling this page) The Ministry of Economic Affairs, the Bureau of Standards, the Bureau of Employees, Consumer Cooperatives, printed the two kinds of composites of watch-type materials, and the A-table on the table base substitutes the material I. Formula and. Tongji Line: 1 ^ 5-Cinnamon 03 Ring #quotes in the lower part of the quot; the next two kinds of CH are R7 in R, which is ~ the formula is the combination of the two kinds of paper in R, the standard paper China National Standard (CNS) A4 specification (210x297 mm)

A7 B7 五、發明説明溴一1 一環丙基且化合物之取代基A- R7在各種情況下栢關於表A中的一行。表105:通式1.3之化合物類，其中R為CH2 — 2，2 —二氟一 1 一環丙基且化合物之取代基a—r7在各種情況下相關於表A中的一行。表106 :通式I . 3之化合物類，其中R為CH2 CH且化合物之取代基A— R7在各種情況下相關於表A中的一行。表107:通式1.3之化合物類，其中K為CH2 CH=CH2且化合物之取代基A— R7在各種情況下相關於表A中的一行。表108 :通式I . 3之化合物類，其中R為CH2 CH= CHCH3 且化合物之取代基A- R7在各種情況下相關於表A中的一行 Ο 表10 9 :通式I . 3之化合物類，其中R為CH2 CH= C ( CH 3 ) 2且化合物之取代基A- R7在各種情況下相關於表A中的一行。表110 :通式I . 3之化合物類，其中R為CHz CH= CC 12 且化合物之取代基A- R7在各種情況下相關於表A中的一行 -1 6 1 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） ---------ί------IT------Μ (請先聞讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製經濟部中央標隼局貝工消費合作社印製 4339823 Λ7 Α7 B7 五、發明説明（tf]) 〇表111:通式1.3之化合物類，其中R為CH(CH3 ) CH = CH2且化合物之取代基A- R7在各種情況下相關於表A中的一行0 表112:通式1.3之化合物類，其中ϋ為Cs IU — 2-ΒΓ 且化合物之取代基A— R7在各種情況下相關於表A中的一行 0 表113:通式1.3之化合物類，其中R為“ H4 -3—Br 且化合物之取代基A— R7在各種情況下相關於表A中的一行 Ο 表114 :通式I . 3之化合物類，其中R為Ce H4 — 4 - Br 且化合物之取代基A— R7在各種情況下相關於表A中的一行 Ο 表115:通式1.3之化合物類，其中R為CH(CH3 ) C2 Η 5且化合物之取代基A- R7在各種情況下相關於表Α中的一行。表116 :通式I . 3之化合物類，其中R為CH2 CH ( CH3 ) -1 6 2 - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） i 媒 (請先Μ讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印製 4 3 39 8 2、， A7 B7 五、發明説明%θ 2且化合物之取代基A— R7在各種情況下相關於表Α中的一行。表U7.1:通式1.3之化合物類*其中R為η - C4 H3且化合物之取代基A- R7在各種情況下相關於表A中的一行。表117.2:通式1.3之化合物類1其中R為一 CHz —Ce Η 4 _4_t — 丁基且化合物之取代基A_R7在各種情況下相關於表A中的一行。表117.3:通式1.3之化合物類，其中R為一CH2 — Cs Η 3 4— Cl2且化合物之取代基A-R7在各種情況下相關於表A中的一行。表117.4:通式1.3之化合物類，其中1?為一（：112.-(^!1 3 - 2 , 4 - C12且化合物之取代基A- R7在各種情況下相關於表A中的一行。表11 7 5 :通式I · 3之化合物類，其中R為一 Cs fh — 2 '4 — C 1 2且化合樹之取代基A — R7在各種情況下相關於表 A中的一行。表117 . 6 :通式I _ 3之化合物類，其中R為一Cs H3 — 3 -1 6 3 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ---------d------.玎------d. (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 ^33982^ A7 __B7_ 五、發明説明（/〇) ，4一 C 12且化合物之取代基Α — R 7在各種情況下相關於表 A中的一行。表117 · 7 :通式I . 3之化合物類*其中R為一Cs H3 — 2 —Cl，4— Br且化合物之取代基A-R7在各種情況下相關於表A中的一行。表117 . 8 :通式I . 3之化合物類，其中R為—Cs H3 — 3 ，4— (― 0—CH2 — 〇-）且化合物之取代基A— R7在各種情況下相關於表Α中的一行。表1 1 7 . 3 :通式I . 3之化合物類*其中R為一Cs H4 — 4 —S C Hs且化合物之取代基A _ R 7在各種情況下栢關於表A 中的一行。表1 17 . 10 :通式I . 3之化合物類，其中R為一 C6 H4 - 4 —〇CF3且化合物之取代基A - R7在各種情況下相關於表A 中的一行。表117.11:通式1.3之化合物類，其中R為一Cs IU — 4 _t 一丁基且化合物之取代基A— R7在各種情況下相關於表 A中的一行。 -164- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） "5^ 訂線 (請先閱讀背面之注意事項再填窝本頁) 43 39 8 2·^ A 7 B7 五、發明説明（/(β 表117.12:通式I.3之化合物類，其中R為一C6 Η4 - 4 — 0CH3且化合物之取代基A - R7在各種情況下相關於表Α中的一行。表117.13:通式1.3之化合物類，其中R為_Ce JU — 4 -CH3且化合物之取代基A-R7在各種情況下相鼸於表A中的一行。表117.14:通式1.3之化合物類*其中R為2_萘基且化合物之取代基A—R7在各種情況下相關於表A中的一行。表117.15:通式1.3之化合物類，其中R為一— 2 — 萘基且化合物之取代基A—R7在各種情況下相醞於表A中的一行。表1 17 . 16 :通式I · 3之化合物頚*其中R為—— 4 一 0_C6 Hs且化合物之取代基A— R7在各種情況下相關於表A中的一行。表1 1? . 17 :通式I . 3之化合物類，其中β為一 “ ~ 4 -CN且化合物之取代基Α — ϋ7在各種情況下相鼷於表八中的 —行0 -1 6 5- 本紙張尺度適用中國國家標準（CNS ) A4it格（210X297公釐）紫訂線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 4 3 3982」 at _B7_._ 五、發明说明表117.18:通式1.3之化合物類’其中^為_{^2〇611 4 一 4 - CN且化合物之取代基Α— β7在各種情況下相關於表 Α中的一行◊ 表117.19:通式1.3之化合物類*其中R為一 Ce H3 _3 一 4一 CF3且化合物之取代基A-R·?在各種情況下相關於表A中的一行。表117.20:通式I_3之化合物類，其中R為一CsH3-2 _C1 一 4_CF3且化合物之取代基A - R7在各種情況下相醞於表A中的一行。表1 1 8 :下列通式之化合物類 (請先閱讀背面之注意事項再填寫本頁) ch3oA7 B7 V. Description of the invention Bromine-1 cyclopropyl and the substituents A-R7 of the compound are in one row in Table A in each case. Table 105: Compounds of the general formula 1.3 in which R is CH2-2,2-difluoro-1cyclocyclo and the substituents a-r7 of the compound are in each case related to a row in Table A. Table 106: Compounds of general formula 1.3 where R is CH2CH and the substituents A to R7 of the compound are in each case related to a row in Table A. Table 107: Compounds of general formula 1.3 where K is CH2 CH = CH2 and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 108: Compounds of the general formula 1.3 where R is CH2 CH = CHCH3 and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 10 9: Compounds of general formula 1.3 Class, where R is CH2 CH = C (CH3) 2 and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 110: Compounds of general formula 1.3, where R is CHz CH = CC 12 and the substituents A-R7 of the compound are in each case related to a row in Table A -1 6 1-This paper size applies to China Standard (CNS) A4 specification (210 X 297 mm) --------- ί ------ IT ------ Μ (Please read the notes on the back before filling in this page ) Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs and printed by the Central Standards Bureau of the Ministry of Economic Affairs and printed by the Shellfish Consumer Cooperatives of the Ministry of Economic Affairs. (CH3) CH = CH2 and the substituents A- R7 of the compound are related in each case to a row 0 in Table A. Table 112: Compounds of general formula 1.3, where ϋ is Cs IU — 2-ΒΓ and the substituent of the compound A—R7 is related to a row 0 in Table A in each case. Table 113: Compounds of the general formula 1.3, where R is “H4-3—Br and the substituent A—R7 of the compound is related to Table A in each case. One row in Table TABLE 114: Compounds of general formula 1.3, where R is Ce H4- 4-Br and the substituents A- R7 of the compound are in each case related to one of Table A Row 115 Table 115: Compounds of general formula 1.3 where R is CH (CH3) C2 Η 5 and the substituents A-R7 of the compound are in each case related to one row in table A. Table 116: general formula 1.3 Compounds, where R is CH2 CH (CH3) -1 6 2-This paper size applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm) i Medium (please read the precautions on the back before filling this page) Printed by the Central Laboratories of the Ministry of Economic Affairs, Consumer Cooperatives 4 3 39 8 2, A7 B7 V. Description of the invention% θ 2 and the substituents A-R7 of the compound are related to a row in Table A in various cases. Table U7. 1: Compounds of general formula 1.3 * where R is η-C4 H3 and the substituents A- R7 of the compound are in each case related to one row in Table A. Table 117.2: Compounds of general formula 1.3 where R is one CHz —Ce Η 4 — 4 — t — butyl and the substituent A_R7 of the compound is in each case related to one row in Table A. Table 117.3: Compounds of general formula 1.3, where R is a CH 2 — Cs Η 3 4 — Cl2 and The substituents A-R7 of the compound are in each case related to one row in Table A. Table 117.4: Compounds of general formula 1.3, which Zhong 1? Is one (: 112 .- (^! 1 3-2, 4-C12) and the substituents A- R7 of the compound are in each case related to a row in Table A. Table 11 7 5: Compounds of the general formula I · 3, where R is a Cs fh — 2 '4 — C 1 2 and the substituent A — R7 of the compound tree is in each case related to a row in Table A. Table 117.6: Compounds of the general formula I_3, where R is a Cs H3 — 3 -1 6 3-This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) ------ --- d ------. 玎 ------ d. (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ^ 33982 ^ A7 __B7_ V. Description of the invention (/ 〇), 4-C 12 and the substituents A-R 7 of the compound are in each case related to a row in Table A. Table 117 · 7: Compounds of the general formula 1.3. Where R is a Cs H3-2-Cl, 4-Br and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 117.8: Compounds of general formula 1.3, where R is -Cs H3-3, 4-(-0-CH2-0-) and the substituents A-R7 of the compound are in each case related to Table A In a row. Table 11.7: Compounds of the general formula 1.3. Where R is a Cs H4- 4 -S C Hs and the substituent A_R 7 of the compound is in each case a row on Table A. Table 11.7.10: Compounds of the general formula 1.3, where R is a C6H4-4-OCF3 and the substituents A-R7 of the compound are in each case related to a row in Table A. Table 117.11: Compounds of the general formula 1.3, where R is a Cs IU-4_t-butyl and the substituents A-R7 of the compound are in each case related to a row in Table A. -164- This paper size applies to Chinese National Standard (CNS) A4 (210X297mm) " 5 ^ Thread (please read the precautions on the back before filling in this page) 43 39 8 2 · ^ A 7 B7 5 Description of the invention (/ (β Table 117.12: Compounds of the general formula I.3, where R is a C6 Η 4-4-0CH3 and the substituents A-R7 of the compound are related to a row in Table A in each case. Table 117.13: Compounds of general formula 1.3, in which R is _Ce JU — 4 -CH3 and the substituents A-R7 of the compound are in each case in a row in Table A. Table 117.14: Compounds of general formula 1.3 * Wherein R is 2-naphthyl and the substituents A-R7 of the compound are in each case related to one row in Table A. Table 117.15: Compounds of the general formula 1.3, where R is mono-2-naphthyl and the substitution of the compound The groups A-R7 are in each case considered in a row in Table A. Table 1 17.16: Compounds of the general formula I · 3 頚 * where R is-4-0_C6 Hs and the substituents A- R7 of the compound are in Each case is related to a row in Table A. Table 1 1.. 17: Compounds of general formula I. 3, where β is a "~ 4-CN and the substitution of the compound Base A — ϋ7 in each case is comparable to that in Table 8. —Line 0 -1 6 5- This paper size applies to China National Standard (CNS) A4it grid (210X297 mm) Purple Thread (please read the note on the back first) Please fill in this page again) Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 3982 "at _B7 _._ V. Description of the invention Table 117.18: Compounds of the general formula 1.3 'where ^ is _ {^ 2〇611 4-4 -CN and the compound's substituent A-β7 in each case is related to a row in Table A. Table 117.19: Compounds of the general formula 1.3 * where R is a Ce H3 _3-4-CF3 and the substituent AR of the compound. In each case, it is related to a row in Table A. Table 117.20: Compounds of the general formula I_3, where R is a CsH3-2 _C1-4_CF3 and the substituents A-R7 of the compound are in Table A in each case One row in the table. Table 1 1 8: Compounds of the following general formula (please read the precautions on the back before filling this page) ch3o

(〇R)n 經濟部t央標準局負工消費合作社印製，其中化合物之取代基類.R 5 ，OR及A_R7的組合在各種情況下相關於表B中的一行。他們的物理數據示於下表中。化合物編號栢關於表B。 '16 6- 本紙張尺度適用中國國家標羋（CNS ) A4规格（210X 297公釐） 433982」五、發明説明（丨叫) A7 B7 化合物 N 〇 . 熔點 118.79 ί18.80 118.81(〇R) n Printed by the Central Bureau of Standards, Ministry of Economic Affairs and Consumer Cooperatives, in which the substituent class of the compound. The combination of R 5, OR, and A_R 7 is related to a row in Table B in each case. Their physical data are shown in the table below. Compound No. Cypress on Table B. '16 6- The size of this paper is applicable to China National Standard (CNS) A4 (210X 297 mm) 433982 "5. Description of the invention (丨) A7 B7 Compound N 〇 Melting point 118.79 ί18.80 118.81

12 1 9 5 - 9 6 t： 106 °C 表119:下列通式之化合物類 (請先閲讀背面之注意事項再填寫本頁) 012 1 9 5-9 6 t: 106 ° C Table 119: Compounds of the following formula (Please read the precautions on the back before filling this page) 0

R 12 經濟部中央標準局員工消費合作社印製 1.4 ，其中E為一 C H2 —且取代基R ί 2在各種情況下相關於表C中的一行。化合物異構物熔點 119.2-1 A 119.2-2 B -167- 1 2 2 - 1 2 4 ¾ 9 9 - 1 0 2 t：本紙張尺度逋用中國國家標準（CNS > A4規格（210X 297公釐） 433982」 A7 __B7 五、發明説明（iif)R 12 is printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 1.4, where E is a C H2-and the substituent R 2 is in each case related to a row in Table C. Compound isomer melting point 119.2-1 A 119.2-2 B -167- 1 2 2-1 2 4 ¾ 9 9-1 0 2 t: This paper adopts Chinese national standard (CNS > A4 size (210X 297) (Centi) 433982 "A7 __B7 V. Description of the invention (iif)

119.3 A 101-103^ 119.4 A 98-101 1C 119.5 A 1 4 9 - 1 5 1 cC 表120:下列通式之化合物類 Ο119.3 A 101-103 ^ 119.4 A 98-101 1C 119.5 A 1 4 9-1 5 1 cC Table 120: Compounds of the following formula 〇

{請先閲讀背面之注意事項再填寫本頁) ，其中E為一CH2 -且Ri 2在各種情況下相關於表C中的一行。他們的物理數據示於下表中。化合物編號相關於表C。經濟部中央標準局員工消費合作社印製化合物異構物熔點 120.2 A 1 2 5 - 1 2 6 Ό 12 0.3 A 9 0 - 9 2 〇C 12 0.4 A 100 - 10 1¾ 120.5 A 1 1 0 - 112¾ -168- 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 433982 Α7 Β7 五、發明説明（/Μ) 120 .{Please read the notes on the back before filling this page), where E is a CH2-and Ri 2 is related to a row in Table C in each case. Their physical data are shown in the table below. Compound numbers are related to Table C. Melting point of compound isomers printed by employees' cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 120.2 A 1 2 5-1 2 6 Ό 12 0.3 A 9 0-9 2 〇C 12 0.4 A 100-10 1¾ 120.5 A 1 1 0-112¾- 168- The size of this paper is applicable to Chinese National Standard (CNS) A4 (210X297 mm) 433982 Α7 Β7 V. Description of invention (/ Μ) 120.

Harz 表1 2 1 : 下列通式之化合物類 ch3oHarz Table 1 2 1: Compounds of the formula ch3o

R, E： •其中E為—CH2 —且Rt 2在各種情況下相關於表C中的一行。他們的物理數據示於下表中。化合物編號相關於表〇化合物異構物熔點 ---------裝------ΪΤ------f (請先閣讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製R, E: • where E is —CH2 — and Rt 2 is in each case related to a row in Table C. Their physical data are shown in the table below. The compound number is related to the melting point of the compound isomers in Table 0 .-------------------- Τ ------ f (please read the precautions on the back before filling this page) Economy Printed by the Consumer Standards Cooperative of the Ministry of Standards

12 1 .2—1 A 103- 10 4。。 12 1, • 2 - 2 B 111- 11 3 12 1, ,3 A 104- 106Ό 12 1. _ 4 A 91- -92C 12 1. .5 A 98 — 100°C -16 9 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 29?公釐） ^33982^ A7 ^_B7五、發明説明（fq) 表1 2 2 :下列通式之化合物類 012 1 .2—1 A 103- 10 4. . 12 1, • 2-2 B 111- 11 3 12 1,, 3 A 104- 106Ό 12 1. _ 4 A 91- -92C 12 1. .5 A 98 — 100 ° C -16 9 This paper is for China National Standard (CNS) A4 specification (210 X 29? Mm) ^ 33982 ^ A7 ^ _B7 V. Description of the invention (fq) Table 1 2 2: Compounds of the following general formula 0

，其中S為一 CH2 —且Si 2在各種情況下相關於表C中的一行。他們的物理數據示於下表中。化合物編號相關於表C。化合物異構物熔點經濟部中央標举局員工消費合作社印裂 122.2 A 86 — 88¾ 122.3 A 80 - 8 31； 12 2.4 A 86 - 88¾ 122.5 A Harz 122.6 A Harz 表 1 2 3 : 下列通式之化合物類 -170- (請先閲讀背面之注意事項再填寫本頁)Where S is a CH2—and Si2 is in each case related to a row in Table C. Their physical data are shown in the table below. Compound numbers are related to Table C. Melting point of compound isomers The Central Coordinating Bureau of the Ministry of Economic Affairs of the People's Republic of China printed 122.2 A 86 — 88¾ 122.3 A 80-8 31; 12 2.4 A 86-88¾ 122.5 A Harz 122.6 A Harz Table 1 2 3: Compounds of the following general formula Class-170- (Please read the notes on the back before filling this page)

本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）經濟部中央標準局員Η消費合作社印策 ^33982^ at -___B7 五、發明説明（/Lp 〇This paper size applies to China National Standard (CNS) A4 (210X297 mm) Member of the Central Standards Bureau of the Ministry of Economic Affairs Η33982 ^ at -___ B7 V. Description of the invention (/ Lp 〇

1.8 ，其中E為一 C Hz —且I 2在各種情況下相關於表C中的一行。化合物異構物熔點 123.2-1 A 1 6 3 - 1 6 5 °C 123.2-2 B 9 8 - 1 0 2 T： 123.3 A 159-161Ό 12 3.4 A 1 4 6 - 1 4 8 °C 12 3.5 A 172-173¾ 表12 4: 下列通式之化合物類 -17 1- 本紙張尺度適用中國國家標準（CNS〉Α4規格（210 X 297公釐）银訂铸 {請先閲讀背面之注意事項再填寫本頁) 433982^ 五、發明説明 Α7 Β71.8 where E is a C Hz — and I 2 is in each case related to a row in Table C. Compound isomer melting point 123.2-1 A 1 6 3-1 6 5 ° C 123.2-2 B 9 8-1 0 2 T: 123.3 A 159-161Ό 12 3.4 A 1 4 6-1 4 8 ° C 12 3.5 A 172-173¾ Table 12 4: Compounds of the following general formula-17 1- This paper size applies to Chinese National Standards (CNS> Α4 size (210 X 297 mm) silver custom casting {Please read the precautions on the back before filling in this Page) 433982 ^ V. Description of the invention Α7 Β7

1.9 Ε 其中Ε為一 CH2 —且Rt 2在各種情況下相關於表C中的一行表1 2 5 :下列通式之化合物類1.9 Ε where E is a CH2—and Rt 2 is in each case related to a row in Table C Table 1 2 5: Compounds of the following general formula

1.10 12 1 — J.^衣 li 訂綿 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製其中E為一 CH2 —且！Ϊ1 2在各種情況下相關於表C中的一行化合物異構物熔點 12 5. A 1 5 6 - 1 5 8 Ό 17 2- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） A7 B7 五、發明説明 125.3 A 132 - 134¾ 12 5.4 A 14 6 — 147t； 12 5.5 A 142 - 14 3〇C 125.6 A 131- 132¾ 表126:下列通式之化合物類 ch3o1.10 12 1 — J. ^ clothing order (please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economics where E is a CH2 —and! Ϊ1 2 In each case it is related to the melting point of a row of compound isomers in Table C. 12 5. A 1 5 6-1 5 8 Ό 17 2- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297) A7 B7 V. Description of the invention 125.3 A 132-134¾ 12 5.4 A 14 6 — 147t; 12 5.5 A 142-14 3〇C 125.6 A 131- 132¾ Table 126: Compounds of the following general formula ch3o

1.11 (請先閲讀背面之注意事項再填窝本頁) R,1.11 (Please read the notes on the back before filling in this page) R,

'1T *其中E為—CHz —且Ri 2.在各種情況下相關於表C中的一行。表1 2 7 :下列通式之化合物類絲經濟部中央標準局員工消费合作杜印製'1T * where E is —CHz — and Ri 2. In each case it is related to a row in Table C. Table 1 2 7: Compounds of the following general formula Silk

1.12 -17 3- 本纸張尺度適用中國®家標準（CNS ) A4規格（2i〇X297公釐） 433982U Λ7 __ _B7 五、發明説明（!1丨) ，其中E為一CH2 -且取代基Ar在各種情況下相關於表 D中的一行。表1 2 8 :下列通式之化合物類 (請先閱讀背面之注意事項再填寫本頁) 装-1.12 -17 3- This paper size is applicable to China® Standard (CNS) A4 (2i × 297mm) 433982U Λ7 __ _B7 V. Description of the invention (! 1 丨), where E is a CH2-and the substituent Ar Corresponding to a row in Table D in each case. Table 1 2 8: Compounds of the following formula (please read the precautions on the back before filling this page)

、1T 0, 1T 0

，其中E為一CHZ —且取代基Ar在各種情況下相關於表 D中的一行。表1 2 3 :下列通式之化合物類绦經濟部中央標準局負工消費合作社印製 0Where E is a CHZ — and the substituent Ar is related to a row in Table D in each case. Table 1 2 3: Compounds of the following general formula 印 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 0

本紙張尺度適用中國國家標準（CNS )八4規>洛（210Χ297公釐） 4 3 3 9 8 2 A7 B7 ch3oThis paper size applies to China National Standard (CNS) Rule 8 > Luo (210 × 297 mm) 4 3 3 9 8 2 A7 B7 ch3o

五、發明説明（^巧，其中E為一 CH2 —且取代基Ar在各種情況下相關於表 D中的一行。 Φ 表1 3 (3 :下列通式之化合物類 1.15 ，其中E為一CH2 —且取代基Ar在各種情況下相關於表 D中的一行。實賍例 H3:a) 2— 〔〔〔（1-甲基一2— （4 一（2 — [2，4 一二氯苯基）乙基）一苯基）一2-E—〔甲氧基亞胺基]亞乙基）胺基〕氧]甲基]一 c(一（甲氧基亞甲基 )—苯基乙酸甲酯 CH,0'V. Description of the Invention (wherein E is a CH2 — and the substituent Ar is related to a row in Table D in various cases. Φ Table 1 3 (3: Compounds of the following general formula 1.15, where E is a CH2 —And the substituent Ar is related in each case to a row in Table D. Example H3: a) 2— [[[(1-methyl-1 2— (4 1 (2 — [2, 4 dichloro) Phenyl) ethyl) monophenyl) 2-E- [methoxyimino] ethylene) amino] oxy] methyl] -c (mono (methoxymethylene) -phenyl Methyl acetate CH, 0 '

Cl 175- 本紙乐尺度適用中國國家標準（CNS ) A4规格（210X297公釐）装 i 嫁 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印製Cl 175- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm). I (Please read the precautions on the back before filling out this page) Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives

433982 A7 B7 五、發明説明（ί^) 4公克之Pd( 10%在活性碳上）被加人4公克之2—〔〔〔（1一甲基一2—(4—（2_{2，4一二氮苯基}乙炔基 )一苯基）_2— E — 〔甲氧基亞胺基〕亞乙基）胺基]氧〕甲基]一 ct _ (甲氧基亞甲基）一苯基乙酸甲酯於8 (1毫升之四氫呋喃中所胺成的溶菠内，且在正常壓力下2〇·〇通入3 2 5 . 17毫升之氫。混合物於Si02 ( Cel it e)上進行過濾並將濾疲為進行揮發。殘餘物於二異丙基醚/石油醚1: 2 中進行攪拌並將得到的固體進行過濾。得到得到熔點11 2 — 11 4 °C之標題化合物。 b) 2_ 〔〔〔（1_ 甲基一2_ (4~ {2—毗嗪基}乙烯棊）_苯基）一 2— E - 〔甲氧基亞胺基]亞乙基）胺基〕氧]甲基〕一《 — （甲氧基亞甲基）一苯棊乙酸甲酯 (請先閲讀背面之注意事項再填寫本頁) ,-b -¾. 經濟部中央標準扃員工消費合作社印製433982 A7 B7 V. Description of the Invention (ί ^) 4 grams of Pd (10% on activated carbon) was added to 4 grams of 2-[[[(1-methyl- 2— (4— (2_ {2, 4-diazophenyl} ethynyl) monophenyl) _2—E — [methoxyimino] ethylene) amino] oxy] methyl] -ct _ (methoxymethylene)- Phenylacetate was dissolved in 8 (1 ml of tetrahydrofuran amine dissolved in the solution, and 20.5.17 ml of hydrogen was passed through at 20.0 under normal pressure. The mixture was on SiO 2 (Cel it e) Filtration was performed and the filtration was performed as volatilization. The residue was stirred in diisopropyl ether / petroleum ether 1: 2 and the resulting solid was filtered. The title compound having a melting point of 11 2-11 4 ° C was obtained. B ) 2_ [[((1-methyl-2- (4 ~ {2-pyrazinyl) vinylhydrazone) _phenyl) -2-E-[methoxyimino] ethylene) amino] oxy] Methyl]-"-(methoxymethylene) monophenylacetic acid methyl acetate (please read the precautions on the back before filling this page), -b -¾. Printed by the Central Standard of the Ministry of Economy 扃 Employee Consumer Cooperative

660毫克之Lindlar觸媒被加入2‘2公克之2- 〔〔〔（1 -176- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）經濟部中央標準局負工消費合作社印黎 4339B2ti A7 B7 五、發明说明ί1ψ) 一甲基一 2 — （4— (2— [ft嗪基}乙炔基）一苯基）一 2— Ε —〔甲氧基亞胺基〕亞乙基）胺基]氧]甲基〕—《 — ( 甲氧基亞甲基）一苯基乙酸甲酯於80毫升之四氫呋喃中所形成的溶疲中，且在正常壓力下20Ό通入98.6毫升之氫。將標題混合物於Si02進行過濾並將溏液進行揮發。殘餘物於矽膠（洗提劑乙酸乙酯/己烷1: 1)上進行色層分析。得到無色樹脂形式之標題化合物。 c) 2 - 〔〔〔（ 1 -甲基一2 — ( 4 — ( 2 - ( 3 -氯苄醢基}乙基）—苯基）一 2-E — 〔甲氧基亞胺基]-亞乙基 )胺基〕氧]甲基〕—α — （甲氧基亞胺基）一苯基乙酸甲酯660 milligrams of Lindlar catalyst was added to 2'2 grams of 2- [[[(1 -176- This paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 mm). Li 4339B2ti A7 B7 V. Description of the invention ί 1ψ) monomethyl 2 — (4- (2 — [ftazinyl} ethynyl) monophenyl) — 2 — E — [methoxyimino] ethylene ) Amine] oxy] methyl] — "— (methoxymethylene) monophenylacetate in 80 ml of tetrahydrofuran formed in the solvent, and under normal pressure 20 压力 into 98.6 ml of hydrogen. The title mixture was filtered over SiO 2 and the mash was evaporated. The residue was subjected to chromatography on silica gel (eluent: ethyl acetate / hexane 1: 1). The title compound was obtained as a colorless resin. c) 2-[[[(1 -methyl-1 2 — (4 — (2-(3 -chlorobenzylidene} ethyl) -phenyl) -phenyl) -2-methoxyimino]- Ethylene) amino] oxy] methyl] —α — (methoxyimino) monophenylmethyl acetate

880毫克之Raney鎳被加入2.8公克之2— 〔〔〔（1-甲880 mg of Raney nickel was added to 2.8 grams of 2— [[[(1-A

基一 2- (4— (2— (3 -氛〒醯基}乙炔基）一苯基）一 Z -E-〔甲氧基亞胺基]亞乙基）胺基〕氧]—甲基]一（ α -(甲氧基亞胺基）-苯基乙酸甲酯於80毫升之四氫呋喃及120毫升之乙酸乙酯中所形成的溶疲內。在正常壓力下 -177- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ2ί>7公釐）装訂線 (請先閲讀背面之注意事項再填寫本頁) 4339 82㈡ A7 B7 五、發明説明（〖/-0 20C通入219.37毫升之氫。將温合物於Si02上進行過濾並將濾液進行揮發。殘餘物於矽膠（洗提劑二異丙基醚/乙醚1: 1)上進行色曆分析。得到熔點128 — 131TC之標題化合物。實施例H4:其他示於表131- 154之化合物類Μ類似見述於實施例Η3 a)至c)的方式加Κ製備。表131:通式1.4之化合物類，其中E為一CHz — CH2 — 且取代基Ri 2在各種情況下相關於表C中的一行° 表132:通式1.5之化合物類，其中E為一 CH2 — Cil2 — 且取代基2在各種情況下相關於表C中的一行° 表133 :通式I · 6之化合物類* ，其中E為一 CH2 — CH2 一且取代基Ri 2在各種情況下栢關於表C中的一行° 表134 ·‘通式I . 7之化合物類，，其中E為一 CH2 — CHz —且取代基1^ 2在各種情況下相關於表C中的一"行° 表135 :通式I .8之化合物類，其中E為一 — 且取代基Ri 2在各種情況下相關於表C中的一行° -1 78- 本紙張尺度適用中國國家標準（CNS ) M規格（21〇><29·7公釐） ----------d------ΪΤ------Μ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局男工消費合作社印裝 A72- (4- (2- (3-amino)} ethynyl) -phenyl) -Z-E- [methoxyimino] ethylene) amino] oxy] -methyl ] (Α- (methoxyimino) -phenylacetic acid methyl ester in 80 ml of tetrahydrofuran and 120 ml of ethyl acetate. Under normal pressure -177- This paper size applies China National Standard (CNS) Α4 Specification (210 × 2ί > 7 mm) Binding Line (Please read the precautions on the back before filling out this page) 4339 82㈡ A7 B7 V. Description of the invention (〖/ -0 20C access 219.37 ml of Hydrogen. The warm compound was filtered on SiO2 and the filtrate was evaporated. The residue was subjected to color history analysis on silica gel (eluent diisopropyl ether / ether 1: 1). The title compound having a melting point of 128-131TC was obtained. Example H4: Other Compounds M shown in Tables 131-154 are prepared in a manner similar to that described in Example VII 3 a) to c) plus K. Table 131: Compounds of general formula 1.4, where E is a CHz — CH2 — and the substituent Ri 2 is in each case related to a row in Table C. Table 132: Compounds of general formula 1.5, where E is a CH2 — Cil2 — and the substituent 2 is related to a row in Table C in various cases. Table 133: Compounds of the general formula I · 6 *, where E is a CH 2 — CH 2 and the substituent Ri 2 in each case Regarding one row in Table C. Table 134. 'Compounds of the general formula I. 7 in which E is a CH 2 —CHz — and the substituent 1 ^ 2 is in each case related to a “quote” in Table C. Table 135: Compounds of the general formula I.8, where E is one—and the substituent Ri 2 is related to a row in Table C in all cases ° -1 78- This paper size applies the Chinese National Standard (CNS) M specification (21〇 > < 29 · 7mm) ---------- d ------ ΪΤ ------ Μ (Please read the notes on the back before filling in this page ) Male Worker Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs, printed A7

3982.J __'_._B7_ 五、發明説明（/外）表136:通式1.9之化合物類，其中E為一 CH2 - CH2 — 且取代基111 2在各種情況下相關於表C中的一行。表137:通式I.1Q之化合物類，其中E為一CH2 -Cfi2 一且取代基Ri 2在各種情況下相關於表C中的一·行。表138:通式1.11之化合物類，其中E為一 CH2 — CH2 一且取代基Ri 2在各種情況下相關於表C中的一行。表139;通式1.4之化合物類，其中E為一CH=CH-且取代基2在各種情況下相關於表C中的一行。表140:通式1.5之化合物類，其中E為一 CH=CH —且取代基Ri 2在各種情況下相關於表C中的一行。表1U;通式1.6之化合物類τ ，其中E為一 CH=CH—且取代基R: 2在各種情況下租關於表C中的一行。表142:通式1.7之化合物類，其中E為CH=CH —且取代基Ri 2在各種情況下相關於表C中的一行。表143:通式1.8之化合物類，其中E為-CH=CH -且取代基2在各種情況下相關於表C中的一行。 -179- 本紙乐尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂線經濟部中央標準局員工消費合作社印製經濟部中央標隼局員工消費合作社印製 433982」 A7 _B7 五、發明説明（（Μ) 表144:通式1.9之化合物類，其中Ε為一CH=CH-且取代基2在各種情況下相關於表C中的一行。表145:通式1.10之化合物類*其中E為一CH=CH —且取代基Ei 2在各種情況下相關於表C中的一行。表146:通式1.11之化合物類，其中E為一CH=CH -且取代基Ri 2在各種情況下相關於表C中的一行。表C 化合物 R 1 2 C . 1 Η C . 2 4- Cl C . 3 3- Cl C · 4 3 > 4- Cl23982.J __'_._ B7_ V. Description of the invention (/ outside) Table 136: Compounds of the general formula 1.9, where E is a CH2-CH2 — and the substituent 111 2 is related to a row in Table C in each case . Table 137: Compounds of the general formula I.1Q, where E is -CH2-Cfi2 and the substituent Ri 2 is in each case related to one row in Table C. Table 138: Compounds of the general formula 1.11, where E is a CH2-CH2 and the substituent Ri2 is in each case related to a row in Table C. Table 139; Compounds of the general formula 1.4, wherein E is -CH = CH- and the substituent group 2 is in each case related to a row in Table C. Table 140: Compounds of the general formula 1.5 in which E is a CH = CH—and the substituent Ri 2 is in each case related to a row in Table C. Table 1U; compound class τ of general formula 1.6, where E is a CH = CH— and the substituent R: 2 is in each case assigned to a row in Table C. Table 142: Compounds of the general formula 1.7 in which E is CH = CH — and the substituent Ri 2 is in each case related to a row in Table C. Table 143: Compounds of the general formula 1.8 where E is -CH = CH- and the substituent 2 is in each case related to a row in Table C. -179- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the notes on the back before filling this page) Threading Central Standard Bureau of the Ministry of Economy Staff Consumer Cooperatives Printing the Central Standard of the Ministry of Economics Printed by the Consumer Affairs Cooperative of the Municipal Bureau 433982 "A7 _B7 V. Description of the invention ((M) Table 144: Compounds of general formula 1.9, where E is a CH = CH- and the substituent 2 is related to Table C in various cases Table 145: Compounds of general formula 1.10 * where E is a CH = CH — and the substituent Ei 2 is in each case related to a row of Table C. Table 146: Compounds of general formula 1.11, where E Is a CH = CH- and the substituent Ri 2 is in each case related to a row in Table C. Table C Compound R 1 2 C. 1 Η C. 2 4- Cl C. 3 3- Cl C · 4 3 > 4- Cl2

C · 5 4- FC · 5 4- F

C . 6 3 - F -180 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） ----------.d------ir------# (請先閱讀背面之注意事項再填寫本頁) 4 3 398 A7 B7 五、發明説明（ί冰 f5 化合物煸號經濟部中夬標準局員工消費合作社印製 C . 1 0 C . 11 C . 1 2 C . 1 3 C . 1 4 C . 15 C . 1 6 C . 17 C . 18 C . 1 9 C . 20 C . 2 1 C . 22 C . 2 3 C . 24 3，4 — F 2 4 ~ 0 — C F 2 3 — 0 - C F 3 4- CF3 3 — C F 3 3 * 5 — F 2 3，4 > 5— F3 3，4- CH= CR- CH= CH 2，4 — C 1 2 4 - 0CH3 3，5 — CF3 3，4 — C 12 2，4，6 — C 1 3 4 - B r 3，4，5 — 0 C H 3 3，5- ( CH3 ) 2 4 — C 12 -181- 本紙張尺度適用令國國家標準（CNS ) A4規格（210X297公釐） i !—. I Ϊ [ , 1 訂 I 1 ^ (請先閱讀背面之注意事項再填寫本頁) 433982 A7 _B7_ 五、發明説明（丨竹） C. 2 5 4 - OCH3 C . 2 6 4 - CF3 C . 2 7 4 — ΒΓ C. 2 8 3 * 4 * 5 - ( OCH3 ) 3 C . 2 9 3， 5- ( CH3 ) 2 C . 3 0 2 - C 1 C . 3 1 2 - 4- F2C. 6 3-F -180-This paper size applies to China National Standard (CNS) A4 (210X 297 mm) ----------. D ------ ir ---- -# (Please read the notes on the back before filling out this page) 4 3 398 A7 B7 V. Description of the invention (ίbing f5 compound # No. Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs C. 1 0 C. 11 C. 1 2 C. 1 3 C. 1 4 C. 15 C. 16 C. 17 C. 18 C. 1 9 C. 20 C. 2 1 C. 22 C. 2 3 C. 24 3, 4 — F 2 4 ~ 0 — CF 2 3 — 0-CF 3 4-CF3 3 — CF 3 3 * 5 — F 2 3, 4 > 5 — F3 3, 4- CH = CR- CH = CH 2, 4 — C 1 2 4-0CH3 3,5 — CF3 3,4 — C 12 2,4,6 — C 1 3 4-B r 3,4,5 — 0 CH 3 3,5- (CH3) 2 4 — C 12 -181- The paper size is applicable to the national standard (CNS) A4 specification (210X297 mm) i! —. I Ϊ [, 1 order I 1 ^ (Please read the precautions on the back before filling this page) 433982 A7 _B7_ V. Description of the invention (Bamboo) C. 2 5 4-OCH3 C. 2 6 4-CF3 C. 2 7 4 — ΒΓ C. 2 8 3 * 4 * 5-(OCH3) 3 C. 2 9 3, 5- (CH3) 2 C. 3 0 2-C 1 C. 3 1 2-4- F2

C . 3 2 2 - F 表147:通式1.12之化合物類，其中E為—C Hz -CH2 一且取代基Ar在各種情況下相關於表D中的一行。表148:通式1.12之化合物類，其中E為一 CH=CH -且取代基Ar在各種情況下相關於表D中的一行。表143 :通式I . 13之化合物類，其中E為一CH2 — CH2 -且取代基Ar在各種情況下相關於表D中的一行。表150:通式1.13之化合物類，其中E為一CH=CH -且取代基Ar在各種情況下相關於表D中的一行。表151:通式1.14之化合物類，其中E為一 CH2 -CH2 -且取代基Ar在各種情況下相關於表D中的一行。 -182- 本紙張尺度適用中國國家標準（CNS ) A4規格{ 210X 297公釐） 1 抑本訂線 {請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 433982」 A7 _B7五、發明説明表152:通式I.U之化合物類*其中E為—CH=CH—且取代基Ar在各種情況下相關於表D中的一行。表153:通式1.15之化合物類，其中E為-CH2 — CH2 -且取代基Ar在各種情況下相關於表D中的一行。表154:通式1.15之化合物類，其中E為一CH=Cfl_且取代基Ar在各種情況下相關於表D中的一行。表D : 化合物編號 Ar I----------裝------1T------M· (請先閱讀背面之注意事項再填寫本頁) 經濟部令夬標準局员工消費合作社印裝 .1 -吡嗪基 .2 -吡啶-3 ’ —基 .3 -姐陡-2 ’一基 • 4 -吡啶_4 ’ 一基 .S -嘧啶-2 ’ —基 • 6 -嘧啶-4 ’ —基 .7 -嘧啶-5 ’ —基 -183- 本紙張尺度逋用中國國家標準（CNS ) A4規格（2ίΟΧ297公釐）經濟部中夬標準局員工消費合作社印製 43398匕 A7 B7 五、發明説明（必） D . 8 -噻唑-2 ， -基 D . 9 -聘唑- 2，一基 D . 10 -噻嗯_ 2 ’ — 基 D . 11 -噻嗯- 3，— 基 D · 12 -噻唑_ 2，一基 D . 13 -C0 ~ C β h4 -3 - cf3 D · 14 -C0 _ C δ h4 -4 - F D ‘ 15 -C0 _ C 6 .h5 化合物編號 A r D , 16 一 CO— Ce H4 - 3- Cl D.17 — CO— Cs H* — 2— CF3 D，18 - CO— fflt 陡一 3' - 基 D , 19 一 CO— Cs H4 - 4- Cl D . 2 0 — CO—Cs H4 —4— CH3 D * 2 1 — C0_Ce H4 — 4— CF3 D . 2 2 — CO— Cg H4 - 3— OCF3 D . 23 - CO- Ce H4 - 3- OCH3 D . 24 - CH ( OH) - Ce H4 - 3 - CFs —1 8 4 - 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨0 X 29?公釐） ----------裝------訂------Μ (請先聞讀背面之注意事項再填寫本頁) 4 3 39 8 2缝 4 3 ϋ' 0 2 A7 B7 五、發明説明（丨&：>) E . 25 —CH ( 0H) —C 6 Η 5 D . 2 6 -CH ( 0H) ~ C 6 Η 4 表 155 : 下列通式之化合物類 0C. 3 2 2-F Table 147: Compounds of the general formula 1.12 where E is -C Hz -CH2 and the substituent Ar is related in each case to a row in Table D. Table 148: Compounds of the general formula 1.12 where E is a CH = CH- and the substituent Ar is in each case related to a row in Table D. Table 143: Compounds of the general formula I. 13 where E is a CH2-CH2- and the substituent Ar is related in each case to a row in Table D. Table 150: Compounds of the general formula 1.13 in which E is a CH = CH- and the substituent Ar is in each case related to a row in Table D. Table 151: Compounds of the general formula 1.14 in which E is a CH2-CH2- and the substituent Ar is related in each case to a row in Table D. -182- This paper size applies Chinese National Standard (CNS) A4 specifications {210X 297 mm) 1 This line is fixed {Please read the precautions on the back before filling this page) Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 433982 A7_B7 V. Description of the invention Table 152: Compounds of the general formula IU * where E is -CH = CH- and the substituent Ar is related to a row in Table D in various cases. Table 153: Compounds of the general formula 1.15 in which E is -CH2-CH2- and the substituent Ar is in each case related to a row in Table D. Table 154: Compounds of the general formula 1.15, where E is a CH = Cfl_ and the substituent Ar is in each case related to a row in Table D. Table D: Compound No. Ar I ---------- Package ------ 1T ------ M · (Please read the precautions on the back before filling this page) Order of the Ministry of Economic Affairs 夬Standard Bureau employee consumer cooperative printing. 1 -pyrazinyl. 2 -pyridine-3'-based. 3 -Jiasu-2'-based • 4 -pyridine_4'-based.S -pyrimidin-2'-based • 6-Pyrimidine-4'-base. 7-Pyrimidine-5'-base-183- This paper size is printed using the Chinese National Standard (CNS) A4 specification (2ί〇 × 297 mm) Printed by the Employees' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs 43398 D7 A7 B7 V. Description of the invention (required) D. 8-thiazole-2,-radical D. 9-thiazole-2, one radical D. 10-thien_ 2 '— radical D. 11-thien- 3, — group D · 12 -thiazole_ 2, one group D. 13 -C0 ~ C β h4 -3-cf3 D · 14 -C0 _ C δ h4 -4-FD '15 -C0 _ C 6 .h5 compound Number A r D, 16-CO— Ce H4-3- Cl D. 17 — CO— Cs H * — 2— CF3 D, 18-CO— fflt steep 3 '-radical D, 19 — CO— Cs H4- 4- Cl D. 2 0 — CO—Cs H4 —4— CH3 D * 2 1 — C0_Ce H4 — 4— CF3 D. 2 2 — CO— Cg H4-3— OCF3 D. 23-CO- Ce H4-3- OCH3 D. 24-CH (OH)-Ce H4-3-CFs —1 8 4-This paper size applies Chinese National Standard (CNS) A4 specification (2 丨 0 X 29 ? Mm) ---------- install ------ order ------ Μ (please read the precautions on the back before filling this page) 4 3 39 8 2 sewing 4 3 ϋ '0 2 A7 B7 V. Description of the invention (丨 &: >) E. 25 —CH (0H) —C 6 Η 5 D. 2 6 -CH (0H) ~ C 6 Η 4 Table 155: The following Compounds of general formula 0

(請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局負工消費合作社印製 ih^} 1 Y E-Ar mmm 155.1 CH OCIfe -CM-®» 164-166 155,2 CH OCHb -CM-瓏挪$-3-* 臟 155.3 CH OCIfe -((¾ )2 -¾ fe -2,4-Cl2 m-114 155.4 CH 0C& -(C& )z ~Ce Hs 樹I旨 155.5 CH OCfe -(CHz )z -C6 Et -4-0(¾ 84-8*7 Ιΰΰ.6 CH OCfe "(Cife )2 ^Cq -3,5_CF3 99-101 155.7 CH 0(¾ -CHz -CHz -Ce ^ -3-CF3 174-177 -185- 本紙張尺度適用中國國家標準（CNS ) A4規格（2:0X297公釐） 433982^ A7 B7 五、發明説明經濟部t央標隼局員工消費合作社印製 155.8 CH OCJfe -(CH2 )z -ttM 87-89 155.9 CH OCfe -(CHz )2 -i®&3邊 88-90 155.10 CH 0(¾ -(CHz )2 CH(0H)Ce Ife -3-C1 樹脂 155.11 S 0C& -{Cife )2 ™Ce H4 -3-CF3 99-101 ihcM X Y E-Ar mimm 155.12 N OCIfe -(Cfe )z -C0C6 Bs -3-CF3 143-145 155.13 N OCfe _(CHz )2 -COCe H3 **3-Cl 128-130 155.14 N OClfe -(Cfe )z -«a 101-103 155.15 ' N OCIfe -(CHz )z -_-3雀 98-100 155.16 CH OOfe -(CHz )2 CH(〇H)Ce Ife -3-CFs 樹0旨 155.17 CH 0CH3 -CK=CH-C0Ce ^ -3-C1 155.18 CH OCfe -(CHe )2 U -3-C1 翻旨 155.19 CH 0(¾ -(Cife )2 暇~2雀 94-97 155.20 CH OCfe -(Cfe )z 删-3雀 155.21 CH OCfe -(CHz )z -Ce fU -3-Cife 103-104 155.22 CH OCfe _(CHz )2 _Cs B4 -4-0¾ 77-80 155.23 CH 0(¾ -(Cffe h -酿箱 98-103 155.24 CH 0CH3 -(Cfe )z -C6 iu -4-OCOCH3 112-114 155.25 CH 0CH3 -(GHz )z -Ce lit -2-(¾ 86-88 -186- (請先閱讀背面之注意事項再填寫本頁) ..裝- 、-口絲本紙張尺度適用中國國家標準（CNS } A4規格（210X 297公釐） ^ S 39 Q 2,j A7 __B7 五、發明説明（丨作） 155.26 CH 0CH3 -(Ok )ζ -«-5^ -(ch2)2^s、n 155.27 CH 0CH3 Μ CN Cl 155.28 -(CHz )z -Ce ^ -4-COOCIfe 107-120 155.29 -(Clfe )2ik -4-COOC2 Ss 155.30 -{CBz )2 -C6 fe -2.5-C& )z 155.31 _(Qfe )z m -4-8H2 155.32 "(CHz )z "Ce H4 "3_NHz 155.33 -(CHz )z -Ce Η» -3-Cl-4-0C0Cfe 155.34 -(¾ )z -萘基(1) 155.35 -(CHz )z -Ce H4 -4-0H 155.36 -(CHz )2 -萘基⑵ 155.37 -(Cife )2 售睡(chinolinyl)(3) 155.38 -(CHz )z -t©^S(5) 120-123 {請先閱讀背面之注意事項再填寫本頁) 訂 Μ 經濟部中央標準局員工消費合作社印製表1 5 6 :下列通式之化合物類〇(Please read the precautions on the back before filling out this page) Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Ih ^} 1 Y E-Ar mmm 155.1 CH OCIfe -CM-® »164-166 155, 2 CH OCHb -CM- 龙诺 $ -3- * Dirty 155.3 CH OCIfe-((¾) 2 -¾ fe -2,4-Cl2 m-114 155.4 CH 0C &-(C &) z ~ Ce Hs tree I purpose 155.5 CH OCfe-(CHz) z -C6 Et -4-0 (¾ 84-8 * 7 Ιΰΰ.6 CH OCfe " (Cife) 2 ^ Cq -3,5_CF3 99-101 155.7 CH 0 (¾ -CHz -CHz- Ce ^ -3-CF3 174-177 -185- This paper size applies to Chinese National Standard (CNS) A4 (2: 0X297 mm) 433982 ^ A7 B7 V. Description of the invention Printed by the Ministry of Economic Affairs t Central Standards Bureau Employee Consumption Cooperative 155.8 CH OCJfe-(CH2) z -ttM 87-89 155.9 CH OCfe-(CHz) 2 -i® & 3 side 88-90 155.10 CH 0 (¾-(CHz) 2 CH (0H) Ce Ife -3 -C1 resin 155.11 S 0C &-(Cife) 2 ™ Ce H4 -3-CF3 99-101 ihcM XY E-Ar mimm 155.12 N OCIfe-(Cfe) z -C0C6 Bs -3-CF3 143-145 155.13 N OCfe _ (CHz) 2 -COCe H3 ** 3-Cl 128-130 155.14 N OClfe-(Cfe) z-«a 101-103 155.15 'N OCIfe-(CHz) z -_- 3 bird 98-100 155.16 CH OOfe- (CHz) 2 CH ( 〇H) Ce Ife -3-CFs tree 0155.17 CH 0CH3 -CK = CH-C0Ce ^ -3-C1 155.18 CH OCfe-(CHe) 2 U -3-C1 155.19 CH 0 (¾-(Cife) 2 leisure ~ 2 birds 94-97 155.20 CH OCfe-(Cfe) z delete-3 birds 155.21 CH OCfe-(CHz) z -Ce fU -3-Cife 103-104 155.22 CH OCfe _ (CHz) 2 _Cs B4 -4 -0¾ 77-80 155.23 CH 0 (¾-(Cffe h -making box 98-103 155.24 CH 0CH3-(Cfe) z -C6 iu -4-OCOCH3 112-114 155.25 CH 0CH3-(GHz) z -Ce lit- 2- (¾ 86-88 -186- (Please read the precautions on the back before filling out this page) .. Loading-,-Mouth silk This paper size is applicable to the Chinese national standard (CNS) A4 size (210X 297 mm) ^ S 39 Q 2, j A7 __B7 V. Description of the invention (work) 155.26 CH 0CH3-(Ok) ζ-«-5 ^-(ch2) 2 ^ s, n 155.27 CH 0CH3 Μ CN Cl 155.28-(CHz) z -Ce ^ -4-COOCIfe 107-120 155.29-(Clfe) 2ik -4-COOC2 Ss 155.30-(CBz) 2 -C6 fe -2.5-C &) z 155.31 _ (Qfe) zm -4-8H2 155.32 " (CHz) z " Ce H4 " 3_NHz 155.33-(CHz) z -Ce Η »-3-Cl-4-0C0Cfe 155.34-(¾) z -naphthyl (1) 155.35-(CHz) z -Ce H4 -4-0H 155.36 -(CHz) 2 -Naphthylfluorene 155.37-(Cife) 2 Sales (chinolinyl) (3) 155.38-(CHz) z -t © ^ S (5) 120-123 {Please read the precautions on the back before filling (This page) Ordered by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs to print a table 156: Compounds of the following general formula:

-187- 本紙浪尺度適用中國國家標準（CNS ) A4規格（2I0X 297公釐）經濟部中央標準局員工消费合作杜印製 A7 B7 五、發明説明"幻 ih^m X Y At r5 mmm 156.1 CH OCfe ~Ce H4. -4-C1 3-F 88-90 156.2 N OCH3 -¾ ftt _4~Cl 3-F 91-93 156.3 N SHCIfe -C6 H4 -4-C1 3-F 110-112 156.4 CH OCfe -CH^ -Cq fU. ^4~CF3 2-F 109-111 156.5 N 0CH3 -GHz -C6 \k -4-CF3 2-F 108-109 156.6 N NHC& -CHa -Ce -4-CF3 2-F 149-151 156.7 CH 0(¾ -(¾ -¾ Ht ~4_F 2-F 94-96 156.8 N OCfe -Cfe -Ce fU -4-F 2-F 105-107 156.9 N SHCH3 -Cfl2 ~Ce H4 ~4^F 2-F 143-145 156.10 N OCfe -Ce H4 -4-C1 2-OClfe 89-91 156.11 CH 0C& -Ce -4-C1 2-OCH3 100-102 156.12 N NHCH3 H4 _4~Cl 2-OCfe 表1 5 7 :下列通式之化合物類 Ο-187- The scale of this paper applies the Chinese National Standard (CNS) A4 specification (2I0X 297 mm). The consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs has printed A7 B7. 5. Description of the invention " OCfe ~ Ce H4. -4-C1 3-F 88-90 156.2 N OCH3 -¾ ftt _4 ~ Cl 3-F 91-93 156.3 N SHCIfe -C6 H4 -4-C1 3-F 110-112 156.4 CH OCfe- CH ^ -Cq fU. ^ 4 ~ CF3 2-F 109-111 156.5 N 0CH3 -GHz -C6 \ k -4-CF3 2-F 108-109 156.6 N NHC & -CHa -Ce -4-CF3 2-F 149-151 156.7 CH 0 (¾-(¾ -¾ Ht ~ 4_F 2-F 94-96 156.8 N OCfe -Cfe -Ce fU -4-F 2-F 105-107 156.9 N SHCH3 -Cfl2 ~ Ce H4 ~ 4 ^ F 2-F 143-145 156.10 N OCfe -Ce H4 -4-C1 2-OClfe 89-91 156.11 CH 0C & -Ce -4-C1 2-OCH3 100-102 156.12 N NHCH3 H4 _4 ~ Cl 2-OCfe Table 1 5 7: Compounds of the following formula

-188- (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 4 3 398 2^2 A7 B7 五、發明説明（//¾ 化合物 X Y Hal AR7 物理數據 157.1 CH 0CH3 F CHs 112-114 157.2 Ν OCH3 F CHs 67-69 157.3 Ν NHCH3 F CH3 151-153 {請先閱讀背面之注意事項再填寫本頁) V裝. 經濟部中央標隼局員工消費合作社印製化合物 X Y Hal AR7 物理數據 157.4 CH 0CH3 Cl CH3 111-114 157.5 N 0CH3 Cl ch3 101-104 157.6 N NHCH3 Cl ch3 149-151 157.7 CH OCHs Br ch3 120-122 157.8 N OCH3 Br ch3 106-108 157.9 N NHCHs Br ch3 135-137 157.1Q CH OCH3 F C2 Hs 87-91 157.11 N OCH3 F C2 H5 99-102 157.12 N NHCH3 F c2 h5 137-140 157.13 CH OCH3 Cl C2 Hs 95-97 157.14 N OCH3 Cl C2 Hs 112-114 -189--188- (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 4 3 398 2 ^ 2 A7 B7 V. Description of the invention (// ¾ compound XY Hal AR7 Physical data 157.1 CH 0CH3 F CHs 112-114 157.2 Ν OCH3 F CHs 67-69 157.3 Ν NHCH3 F CH3 151-153 (Please read the precautions on the back before filling this page) Bureaux Consumer Cooperatives printed compounds XY Hal AR7 Physical data 157.4 CH 0CH3 Cl CH3 111-114 157.5 N 0CH3 Cl ch3 101-104 157.6 N NHCH3 Cl ch3 149-151 157.7 CH OCHs Br ch3 120-122 157.8 N OCH3 Br ch3 106 -108 157.9 N NHCHs Br ch3 135-137 157.1Q CH OCH3 F C2 Hs 87-91 157.11 N OCH3 F C2 H5 99-102 157.12 N NHCH3 F c2 h5 137-140 157.13 CH OCH3 Cl C2 Hs 95-97 157.14 N OCH3 Cl C2 Hs 112-114 -189-

,1T 本紙乐尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） 433982^ A7 ___B7 五、發明説明（（θ) 157.15 N NHCH3 Cl C2 h5 153-155 157.16 CH OCH3 Br Cz Hs 96-99 157.17 N och3 Br 〇2 h5 107-110 157.18 N NHCH3 Br 〇2 Hs 147-150 表1 5 8 :下列通式之化合物類 0, 1T This paper scale is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 433982 ^ A7 ___B7 V. Description of the invention ((θ) 157.15 N NHCH3 Cl C2 h5 153-155 157.16 CH OCH3 Br Cz Hs 96-99 157.17 No och3 Br 〇2 h5 107-110 157.18 N NHCH3 Br 〇2 Hs 147-150 Table 1 5 8: Compounds of the following general formula 0

經濟部中央標隼局員工消費合作社印製化合物 X Y T AR7 物理數據 158.1 CH och3 4-Br C2 Hs nD2 2 : 158.2 N OCH3 4-Br c2 h5 樹脂 158.3 N SHCH3 4-Br Ce Hs 樹脂 158.4 CH OCH3 4-Br CHs 樹脂 158.5 s OCH3 4-Br CH3 樹脂 158.6 N MHCH3 4-Br CHa 樹脂 -130- ^ 訂絲 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS )八4規格（210X297公釐） 433982α Α7 Β7五、發明説明（/0) 化合物 X Y T as7 物理數據 158.7 CH OCHe 4-0-CH3 C2 h5 158.8 N OCH3 4-0-CH3 C2 樹脂 158.9 N MCH3 4-0-CH3 Hs 158.10 CH OCH3 4-t-丁基 C2 Hs 158.11 N OCH3 4-t-丁基 Hs 158.12 S NHCH3 4-t-丁基 C2 Hs 158.13 CH OCH3 4-CF3 C2 h5 158.14 S OCH3 4-CFs C2 Hs 158.15 N KHCH3 4-CF3 C2 h5 配方竄施例（％ = :重量百分比） (請先閱讀背面之注意事項再填寫本頁) .裝- 訂經濟部中央標準局員工消費合作社印製實施例 F 1 :乳化劑濃縮物類 a) 活性物質 25 X 磺酸十二烷基苯酯鈣 5.¾ 蓖廂油聚乙二醇醚 (36莫耳之 E0) 5 % 三丁基酚聚乙二醇醚 -19 1- b % % 8 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）經濟部中央標準局員工消費合作社印製 4 3 39 8 2:^ at B7 - 五、發明説明（丨0) (30冥耳之E0) - 12 % 4 η 環己酮 - 15 % 20 V f〇二甲苯混合物 65 % 25 % 20 % 將微细磨碎之活性物質與添加物溫合得到乳化劑濃縮物類*任何希望的轧化劑濃度均可藉由κ水稀釋此濃度而得到。Printed Compound XYT AR7 by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Physical Data 158.1 CH och3 4-Br C2 Hs nD2 2: 158.2 N OCH3 4-Br c2 h5 Resin 158.3 N SHCH3 4-Br Ce Hs Resin 158.4 CH OCH3 4- Br CHs Resin 158.5 s OCH3 4-Br CH3 Resin 158.6 N MHCH3 4-Br CHa Resin-130- ^ Staple (please read the precautions on the back before filling out this page) This paper size applies to Chinese National Standard (CNS) 8-4 Specification (210X297 mm) 433982α Α7 B7 V. Description of the invention (/ 0) Compound XYT as7 Physical data 158.7 CH OCHe 4-0-CH3 C2 h5 158.8 N OCH3 4-0-CH3 C2 resin 158.9 N MCH3 4-0-CH3 Hs 158.10 CH OCH3 4-t-butyl C2 Hs 158.11 N OCH3 4-t-butyl Hs 158.12 S NHCH3 4-t-butyl C2 Hs 158.13 CH OCH3 4-CF3 C2 h5 158.14 S OCH3 4-CFs C2 Hs 158.15 N KHCH3 4-CF3 C2 h5 Formulation Example (% =: Weight percentage) (Please read the precautions on the back before filling out this page). Binding-Order Printed Example F 1 by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs: Emulsifier concentrates a) Active substance 25 X sulfonic acid Dialkyl phenyl ester calcium 5.¾ Castor oil polyethylene glycol ether (E0 of 36 moles) 5% Tributylphenol polyethylene glycol ether-19 1- b%% 8 This paper size applies to Chinese national standards (CNS) A4 size (210X297 mm) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 39 8 2: ^ at B7-V. Description of the invention (丨 0) (30 E0)-12% 4 η Cyclohexanone-15% 20 V f〇xylene mixture 65% 25% 20% The finely ground active substance is warmed with the additives to obtain emulsifier concentrates. * Any desired rolling agent concentration can be determined by κ It is obtained by diluting this concentration with water.

莨施例F2:溶液類 a) b) c) d) 活性物質 80 % 10 % 5 % 95 % 乙二醇單甲基醚 20 3； - - - 聚乙二醇MW 40Q - 70 % - - N-甲基-2-毗咯烷酮 - 20 % - - 環氧化椰子油 — - 1 % 5 X 石油精（沸點範圍16Q-190°C ) - - 94 % - 將微细磨碎之活性物質與添加物混合得到溶疲濃縮物類，該溶疲合適K微滴的型式施用。實施例F3 :顆粒 a) b) c) d) -192- 本紙張尺度適用中國國家標芈（CNS ) A4規格（210X 297公釐） I n n 裝-—i [ 11 訂-^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中夬樣準局員工消f合作社印製 4 3 3 9 8 2^ A7 _ B7 五、發明説明（丨莨 Example F2: solution a) b) c) d) active substance 80% 10% 5% 95% ethylene glycol monomethyl ether 20 3;---polyethylene glycol MW 40Q-70%--N -Methyl-2-pyrrolidone-20%--Epoxidized coconut oil--1% 5 X petroleum spirit (boiling point range 16Q-190 ° C)--94%-Finely ground active material and added The mixture is mixed to give a lysate concentrate which is suitable for application in the form of K droplets. Example F3: Granules a) b) c) d) -192- This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) I nn Pack--i [11 Order-^ (Please read first Note on the back, please fill out this page again) Printed by the staff of the Prospective Bureau in the Ministry of Economic Affairs, printed by the cooperative 4 3 3 9 8 2 ^ A7 _ B7 V. Description of the invention (丨

L 活性物質 5 % 10 % 8 % 21 % 高嶺土 . 94 % 7 9 % 54 % - - 高度分散性矽化物 1 % - 13 % 7 % 美國活性白土 - 90 % - 18 % 該活性成分被溶於二氯甲烷，該溶液被唄灑到載劑上，且該溶劑隨後於真空狀態下進行揮發。實施例F4 :粉塵 a) b 活性物質 2 % δ 高度分散性矽化物 1 % 5 滑石 97¾ - 高嶺土 - 90% 藉由混合活性物質與載劑得到準備好可以使用的粉塵類。實施例F5:可濕潤之粉末類 a) b) c ) 活性物質 25 % 50 % 75 % -19 3- 本紙張尺度適用中國國家標隼（CNS ) 規格（210X 297公釐} ^参訂 '^ (請先閱讀背面之注意事項再填寫本頁) 4 3 39 8 2鰱經濟部中央標準局員工消費合作杜印裝 A7 B7 五、發明説明（沒I) 木質素磺酸鈉 5 5i 5 1 - 硫酸月桂醯酿鈉 3 % - 5 % 二異丁基萘磺酸納 - 6 % 10 X 辛基酚聚伸乙基乙二醇醚 (7-8莫耳之環氧乙烷） - I % - 高度散佈性之矽化物 5 % 10 % 10¾ 高嶺土 62% 27% - 將這些活性成分類與這些添加物類混合，且這些混合物在適當的磨碎機中完全加K磨碎。此得到可濕潤之粉末類，其可Μ用水加以稀釋而得到任何希望濃度之懸浮液。實施例 F 6 : 乳化劑濃縮物活性物質辛基酚聚乙二醇醚 (4-5莫耳之 Ε0 ) 十二烷基苯磺酸鈣蓖麻油聚乙二醇醚 (36莫耳之 ΕΟ) 環己酮二甲苯溫合物 -1 94- 10 % 3 % 30 % '50 % 本紙張尺度適用尹國國家標準（CNS ) Α4規格（210Χ297公釐） ---------.裝---：---1Τ------Μ (請先閲讀背面之注意事項再填寫本頁) 4 3 39 8 2驩 Α7 Β7 五 '發明説明任何希望滬度的乳化劑均可藉由以水稀釋此濃度而得到。實施例F7 : 粉塵 a) b) 活性物質 5 % δ % 滑石粉 95 % — 高嶺土 92 9 將活性成分類與載劑類混合，且溫合物在適當的磨碎機中加以磨碎而得到隨時可用的粉塵。實施例F 8 : 擠出性顆粒類 (請先聞讀背面之注意事項再填寫本頁) 裝- -ls 經濟部中夬標準局員工消費合作杜印製活性物質 H) % 木質素磺酸鈉 2 % 羧基甲基鎇維素 1% 高嶺土 8 7 96 該活性成分與添加物類温合*且該混合物被加Μ研磨並Μ水濕潤。該混合物被擠出並接著在一空氣流中進行乾燥。 -195- 本紙張尺度適用中國國家榡準（CNS ) A4规格（210X297公釐）線經濟部中央標準局員工消費合作社印^. 433982^ Λ7 Α7 __ Β7 五、發明説明（f^) 莨施例F9:包覆性顆粒類活性物質 3 3ί 聚乙二醇（MW 200) 3 % 高嶺土 94 % 在一混合器之中，精细研磨之活性成分均勻施用於高嶺土，該高嶺土成分已使用伸乙基乙二酵加Μ濕潤，可得到無塵之包覆之顆粒。貿施例F1D :懸浮液湄縮物活性物質 40 % 伸乙基乙二酵 10 % 士基酚聚伸乙基乙二醇醚 (15萁耳之環氧乙烷） 6 % 木質素磺酸納 10 % 羧基甲基纖維素 1 % 3 7%之甲醛水溶疲 0.2 % 7 5 %乳化劑型式之矽油 0 . 8 % 水 32 % 將精细研磨的活性成分與添加物類混合。此得到一懸 -196- 本紙張尺度適用中國國家標隼（CNS ) Α4規格（210乂297公釐） ---------裝------1Τ------^ (請先閔讀背面之注意事項再填寫本頁) 433982 键 Α7 Β7 經濟部中央標準局員工消費合作社印裝五、發明説明（(外} 浮疲濃縮物，由該懸浮液可藉由Μ水稀釋製備任何希望濃度之懸浮液類。生物性實施例 Α)殺微生物性作用實例Β— 1:在蕃茄植物體對抗破壞植物菌屬真菌（ P h y t ο p h t h 〇 r a i π f e s t a n s)的作用 a) 治療作用經過3個星期種植期，蕃茄之變種〃紅精怪（R〇 t e r Gnoaie) Λ被以真菌的游動孢子（zoospore)懸浮液噴灑後，在18至20 t：及飽和濕度下於潮濕箱内培養。24個小時之後中斷溼潤。當植物體乾後，它們被自被調劑成可濕潤粉末之活性物質所製備之濃度2G0ppin的混合物噴灑。當噴灑上的覆蓋物乾後，此植物體再度被置於潮濕箱内四天。此時間後出現之典型的葉片斑點之數量和大小被當作評估此試驗物質效果的標準。 b) 預防性一糸統作Μ -197- (請先閱讀背面之注意事項再填寫本頁) .裝. 訂锑本紙張尺度適用中國國家標芈（CNS ) Α4規格（21 Ox：297公釐）經濟部中央標準局員工消費合作社印裂 433982^ A7 B7 五、發明説明被調劑成可濕潤粉末之活性成分在濃度6E)P Pm (根據土壤的體積）被倒入栽種三週大蕃茄要種〃紅精怪（er Gnome)"之土壤的表面°經過三天等待.此植物體葉片内側被K真菌的游動孢子懸浮疲噴灑°之後此試驗的植物體被放置在18至20 °C及飽和濕度的噴灑小屋五天經過此時期後 > 典型的葉片斑點之數量和大小被當作評估此試驗物質效果的標準。在未處理且被感染的對照組植物體100%發病，而Μ表 1至Π 8其中之一的活性化合物使得大童感染的情形在兩種試驗中都減少至2 0%或更低。特別是，大量感染的情形Μ 2 0 ρρ m漶度之下列化合物處理受到完全地抑制：1 . 3，1. 4 * 1.13， 1_19， 1.20， 1.30， 1,31* 1.33* 1_43至 1.57， 1.62至 1.72，1.75A，1.78至 1.80，2.21 至 2.25，2.27， 2.32，2,35至 2.52，2.5 5 * 2 . 5 8，2.59至 3.26，3.33至 3.39，3.43至 3.54，3.56，3.60，4.3，4.57及 4.6G〇黃例B-2:在藤Μ植物上對抗鄰孢菌屬真菌（ Plasmopara viticola) ( Bert. e t Curt.) (Berl. e t DeToni)的作用 a)殘餘-預防性作用 -198- 本紙張尺度適用中國國家標準（CNS ) A4规格（2IOX297公釐} (锖先閲讀背面之注意事項再填寫本頁) I.裝. 、-ir 經濟部中央標準局貝Μ消費合作社印製 A7 __B7_ 五、發明説明（( 轉蘧植物插枝變種"Chasselas"種植於溫室内。於十葉階段，三棵植物體被噴上疲體（活性化合物2 0 0 ppm)。當噴灑之覆蓋物乾後，植物體一致在葉片内側感染真菌的孢子懸浮疲。之後此植物體被置於潮濕箱内八天。經過這段時間，獨特的病激會在對照組植物體上出現。在處理過的植物體上感染部位的數量和大小被當作評估此試驗化合物效果的標準。 b)治療作用藤蓃植物插枝箸種〃 Chasselas〃種植於溫室內並於十葉階段在葉子内側以鄰孢菌屬真菌（Piasmopara viticola )之孢子懸浮液感染。被置於潮濕箱内24小時後，此植物體被噴上液體（活性化合物2QQ ppm，60ppm及20ρρια)。此植物體隨後再被置於潮濕箱内t天。經過這段時間，獨特的病激會在對照組植物體上出現。在處理過的植物體上感染部位的數最和大小被當作評估此試驗物質效果的標準。L Active substance 5% 10% 8% 21% Kaolin. 94% 7 9% 54%--Highly dispersible silicide 1%-13% 7% American active clay-90%-18% This active ingredient is dissolved in two Methyl chloride, the solution was sprayed onto the vehicle, and the solvent was subsequently evaporated under vacuum. Example F4: Dust a) b Active material 2% δ Highly dispersible silicide 1% 5 Talc 97¾-Kaolin-90% A mixture of active materials and a carrier is used to obtain ready-to-use dust. Example F5: Wettable powders a) b) c) Active material 25% 50% 75% -19 3- This paper size is applicable to China National Standard (CNS) specifications (210X 297 mm) ^ references' ^ (Please read the notes on the back before filling out this page) 4 3 39 8 2 消费 Consumer cooperation with employees of the Central Bureau of Standards of the Ministry of Economic Affairs Du printed A7 B7 V. Description of the invention (not I) Sodium lignosulfonate 5 5i 5 1- Lauryl Sulfate Sulfate 3%-5% Sodium Diisobutylnaphthalene Sulfonate-6% 10 X Octylphenol Polyethylene Ethylene Glycol Ether (7-8 Mol ethylene oxide)-I%- Highly disperse silicide 5% 10% 10¾ Kaolin 62% 27%-Mix these active ingredients with these additives, and these mixtures are completely crushed with K in a suitable mill. This gives a wettable Powders, which can be diluted with water to obtain suspensions of any desired concentration. Example F 6: Emulsifier concentrate active substance octylphenol polyethylene glycol ether (4-5 moles of E0) dodecyl Calcium Besylate Castor Oil Polyethylene Glycol Ether (36 mol of EO) Cyclohexanone xylene temperature compound-1 94-10% 3% 30% '50% Paper size Use Yin National Standard (CNS) Α4 specification (210 × 297 mm) ---------. Installation ---: --- 1T --- M (Please read the precautions on the back before (Fill in this page) 4 3 39 8 2 Huan A7 B7 5 'Invention Description Any emulsifier that you want can be obtained by diluting this concentration with water. Example F7: Dust a) b) Active substance 5% δ% Talc powder 95%-Kaolin 92 9 The active ingredients are mixed with the carriers, and the warm compound is ground in a suitable mill to obtain ready-to-use dust. Example F 8: Extruded granules (please read the precautions on the back before filling out this page) Pack--ls Consumers' cooperation with the China Standards Bureau of the Ministry of Economic Affairs Du printed active substances H)% Sodium lignosulfonate 2% Carboxymethyl savirin 1% Kaolin 8 7 96 The active ingredient is warmly combined with the additives * and the mixture is ground with M and moistened with M water. The mixture was extruded and then dried in an air stream. -195- This paper size is applicable to China National Standard for Standards (CNS) A4 (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ^. 433982 ^ Λ7 Α7 __ Β7 V. Description of the Invention (f ^) F9: coated granular active substance 3 3 polyethylene glycol (MW 200) 3% kaolin 94% In a mixer, the finely-ground active ingredients are evenly applied to kaolin, which has been used as the kaolin ingredient. The two yeasts are moisturized to obtain dust-free coated particles. Trade Example F1D: Suspension Mae Shrink Active Substance 40% Ethylene Glycol Enzyme 10% Silylphenol Polyethylene Glycol Ether (15 oz. Of ethylene oxide) 6% Sodium Lignosulfonate 10% carboxymethyl cellulose 1% 3 7% formaldehyde water-soluble 0.2% 75% emulsifier type silicone oil 0.8% water 32% Mix the finely ground active ingredients with additives. This results in a suspension -196- This paper size applies to China National Standard (CNS) Α4 specifications (210 乂 297 mm) --------- installation ----- 1T ------ ^ (Please read the notes on the reverse side before filling out this page) 433982 key A7 Β7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention ((outside) floating fatigue concentrate, the suspension can be used by Μ Suspensions of any desired concentration are prepared by dilution with water. Biological Example A) Example of microbicidal action B-1: Effect on Phytomyces fungi (P hyt ο rai π festans) in tomato plants a) After three weeks of planting, the tomato variety Roter Gnoaie Λ was sprayed with a zoospore suspension of the fungus, and then in a humid box at 18 to 20 t: and saturated humidity Within culture. Wet was discontinued after 24 hours. When the plants are dry, they are sprayed with a mixture of 2 Gppin prepared from the active substance adjusted to a wettable powder. When the sprayed covering was dry, the plant was placed in a humid box for another four days. The number and size of typical leaf spots that appear after this time are used as criteria for evaluating the effectiveness of this test substance. b) Preventive integrated work M-197- (Please read the precautions on the back before filling out this page). Packing. Order antimony This paper size is applicable to China National Standard (CNS) A4 specification (21 Ox: 297 mm) Employees' cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China printed 433982 ^ A7 B7 V. Description of the invention The active ingredient adjusted to a wettable powder at a concentration of 6E) P Pm (according to the volume of the soil) was poured into three weeks of growing tomatoes. The surface of the soil of "er Gnome" ° After three days of waiting, the leaves of this plant body were sprayed with K fungal zoospores and suspended and sprayed ° After this test, the plant body was placed at 18 to 20 ° C and saturated After five days of spraying the cabin with humidity, the number and size of typical leaf spots were used as a criterion for evaluating the effect of the test substance. 100% of the disease occurred in the untreated and infected control plants, while the active compound of one of Tables 1 to 8 reduced the incidence of infection in older children to 20% or less in both tests. In particular, in the case of a large number of infections, the treatment of the following compounds with a degree of M 2 0 ρρ m is completely inhibited: 1.3, 1.4 * 1.13, 1_19, 1.20, 1.30, 1,31 * 1.33 * 1_43 to 1.57, 1.62 To 1.72, 1.75A, 1.78 to 1.80, 2.21 to 2.25, 2.27, 2.32, 2,35 to 2.52, 2.5 5 * 2. .5 8, 2.59 to 3.26, 3.33 to 3.39, 3.43 to 3.54, 3.56, 3.60, 4.3, 4.57 and 4.6G. Case B-2: Effect on vine plants against Plasmopara viticola (Bert. Et Curt.) (Berl. Et DeToni) a) Residual-preventive effect-198 -This paper size is in accordance with Chinese National Standard (CNS) A4 (2IOX297mm) (锖 Please read the notes on the back before filling in this page) I. Packing, -ir Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and printed by A7 __B7_ 5. Description of the invention ((Transgenic plant cuttings " Chasselas " are planted in a greenhouse. At the ten-leaf stage, three plant bodies are sprayed with fatigue (active compound 200 ppm). When sprayed cover After drying, the plant body was consistently tired of spores infected with the fungus on the inside of the leaf. The plant body was then placed Eight days in a humid chamber. After this time, unique irritation will appear on the plants of the control group. The number and size of infected sites on the treated plants will be used as a criterion for evaluating the effect of this test compound. B) Therapeutic effect: Chasselas, a vine plant cutting plant, is planted in a greenhouse and infected with spore suspensions of the genus Piasmopara viticola on the inside of the leaves at the ten-leaf stage. After being placed in a humid chamber for 24 hours, The plant body was sprayed with liquid (active compounds 2QQ ppm, 60ppm and 20ρρα). The plant body was then placed in a humid box for t days. After this period of time, a unique disease would appear on the control plant body. The number and size of infected sites on the treated plants were used as the criteria for evaluating the effect of the test substance.

與對Μ組植物體作比較，Μ表1至11 8其中之一的活性化合物使得大童感染的情形在兩種試驗中都減少至或更低。特別是*大量感染的情形Κ 2 [) ppm濃度之下列化合物處理仍達到完全地抑制：丨.3，1 . 4，1 . 1 3，1. 2 9，1 . 3 0， 1.31· 1.33* 1.52> 1.63B· 1.71A- 1.710' 1.73A- 1.73B -1 99- 本紙張又度適·用中國國家標芈（CNS ) Α4規格（2【0 X 297公釐） ! . ^裝 III ^5^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作社印製 4 3 39 8 2鏞 at B7 五、發明説明，1.73，2.21，.2,22，2.25，2.27，2.33，2.45，2.49， 2.55> 2,58， 3.21， 3.43* 3.43， 3.46， 3.56， 4.3， 4.57 ，4.58，4 · 60及 4 . 65。實例B— 3:在甜菜（Beta vulgaris)對抗腐敗菌靥真菌（Pythiuin debaryanuti )的作用 a) 土壤施用後的作用真菌被培植於無菌的燕麥毅粒内並加至土壤一沙子混合物内。感染的土壤被置於花盆内並灑上甜菜種子。灑上種子之後，被調製成可濕濶粉末之活性成分K水溶液懸浮疲的彤式被倒於土壤之上（根據土壌體積為20ppra活性組成份。此盆被置於溫室2Q至24=0達2至3個星期，此土壤Μ水輕微噴灑來維持溼潤。為了評估此試驗，決定甜菜的萌芽情形及健康和生病之植物體的比例。 b) 以被覆愿用後的作用真菌被培植於無菌的燕麥穀粒内並加至土壊/沙子混合物内。感染的土壤被置於花盆丙並灑上經受試製備物，其被調製成被覆粉末（根據種子重量為10OOPΡΐα)，被覆過的甜菜種子。此盆被置於溫室内20至24 υ 2至3個星期，此 -2 0 0 - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐）裝訂錄 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明土壊以水輕微噴灑來維持溼潤。為了評估此試驗，甜菜的葫芽及健康和生病之植物體的比例會被決定。 K表1至118之活性化合物進行處理之後，超過80%的植物體長出且有健康的外表。在對照組盆内，只觀察到有少數的植物體，可見到有病容。實例B — 4:在花生植物體對抗尾形孢子菌屬真菌（ Cercospora araehidicola)的殘餘保護作用 10至15公分高的花生k水性噴灑混合物（0.Q 2%活性組成份）被噴灑，並於48小時後感染此真菌之分生孢子懸浮疲。感染的植物體在21·Ό及高濕度下培養72小時，之後被放置於溫室内直到典型的葉片斑點出_現。此活性組成份的評估是在感染12天之後做的，並且是根據葉片斑點的數量和大小。表1至11 8之活性化合物使葉片斑點的減少至少於葉片表面區域的1Q%。特別是，此病經由使用下列化合物完全被抑制（0至5%的大量感染的情形）：化合物1.49至1.72 ,1.79，2.20至 2.24，2.35至 2.39，2.44至 2.52，2·59， -20 1- 本紙張尺度適用中國國家標隼（CNS ) Α4現格（210X29?公ϋ ---------裝------、訂------·# (請先閱讀背面之注意事項再填寫本頁) 4339 82^ A7 B7__ 五、發明説明 3.22至 3.24* 3.34至 3_39，3.45至 3.60及 3. 62。實例B-5:在小麥對抗赤澀菌屬真菌（Puccinia graminis)的作用 4 a) 殘餘保護作用撤下種子6天後·小麥以水性噴灑液體（O.Q 2%活性物質）被噴灑至滴落程度，並於24小時後感染此冥菌之夏孢子懸浮疲。4M、時培養期後（條件：相對濕度35至100 % ,20 V )，此植物體被置於22 °C溫室內。感染12天後評估斑疣的生成。 b) 系統性作用 .- 撒種5天之後，小麥植物體以水性噴灑液體（（3 . 〇 Q S % 活性组成份，根據土壤的重量）澆灌。小心照顧勿使噴灑混合勿接觸到植物體高出土壤的部份。經過處理的植物體4 8小時後以真菌夏孢子懸浮疲感染。48小時培養期後（條件 :相對濕度95至100 % , 20 t：)，此植物體被置於22 C溫室内。感染12天後評估斑疣的生成。表1至U8之活性化合物使真菌大量感染的情形顯著減 - 2 0 2 - 本紙張尺度適用中國國家標準（CNS > Α4規格（210X 297公釐） ί . I 扣本 I —1 I 訂·~ ~~^ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印製經濟部中央標準局貝工消費合作社印裳 4 3 3 9 8 2 ίΐ； α7 _____Β7 _ 五、發明説明（㈣）少*有時降到1 0 - 0 %。特別是，此病經由使用下列化合物完全被抑制（0至5%的大量感染的情形）：化合物1.51， 1.57， 1.62至 1.64, 1.79， 2,222.23， 2.35， 2.39， 2.44 ，2,45- 2.49· 2.52- 2.59，3,22至 3.24，3.35，3.39， 3.45至 3.47， 3.50， 3.53，及 3.60。實例Β — 6 :在稻米對抗微火菌屬真菌（Pyr icular i a oryzae)的作用 a) 殘餘保護作用經過2個星期的培養後，稻米K水性噴灑液體（G. 02 %活性物質）被噴灑，並於48小時後感染此真菌之分生孢子懸浮Μ。感染5天後評估真菌的大量感樂程度，在期間維持相對濕度9 5至1 0 0 %和溫度2 0亡。 b) 系铳作用 2個星期大的稻米Μ水性噴灑疲體（H.Q06%活性組成份，根摞土壤的重量）灌溉。小心照顧勿使噴灑温合勿接觸到植物體高出土壤的部份。之後盆内装滿水使使稻米的莖最低的部位能站在水中。96小時後，此植物體Κ真菌分生孢子懸浮液感染之並在相對濕度95至100%溫度24¾下維 - 2 0 3 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐} I I I I 1 I I I i 訂— 線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央樣隼局員工消費合作社印製 433982 - A7 _ _B7 _ 五、發明説明Mp 捋5天。表1至118之活性化合物在受感染植物之大部份防止疾病的發作。特別是，此病經由使用下列化合物完全被抑制 (0至5%的大童感染的情形）：化合物1 . 51，1 .57 | 1 ·62 至 1,64， 1.?9， 2.222.23， 2.35， 2.39* 2.44， 2.45’ 2.49， 2.52， 2,59， 3.22至 3.24， 3.35， 3.39* 3·45至 3.47，3,50，3.53，及 3.60。實例Β— 7:在蘋果對抗彎脈菌屬真菌（Venturia iaaequal )的作用有1 0至2 0公分長之新鮮的蘋果插枝噴灑上噴灑温合物 (0 . 0 2 %活性組成份），並於2 4小時後感染此真菌的分生孢子懸浮疲。之後此植物體在相對濕度3 0至10 0%下培養5 天，並放入溫室内於20至24 °C下再10天。感染15天之後評估斑點侵擾程度。表1至118的化合物類中主要對抗斑點病有長效的作用。實例B-8:在大麥對抗紅管菌屬真菌（Erysiphe graminis 的作用 - 2 0 4- 本紙張尺度適用中國國家標芈（CNS ) A4規格（210X297公釐）Compared with the plants of group M, the active compound of one of M Tables 1 to 118 reduced the incidence of infection in older children to or less in both tests. In particular, in the case of a large number of infections, the following compounds at κ 2 [) ppm concentrations were still completely inhibited by treatment: 丨. 3, 1.4, 1. 1.3, 1. 2 9., 1.3, 1.31 · 1.33 * 1.52 &1.6; 1.63B · 1.71A- 1.710 '1.73A- 1.73B -1 99- This paper is suitable again · Use China National Standard (CNS) Α4 size (2 [0 X 297 mm)!. ^ Pack III ^ 5 ^ (Please read the notes on the back before filling this page) Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs 4 3 39 8 2 镛 at B7 V. Description of the invention, 1.73, 2.21, .2, 22, 2.25 , 2.27, 2.33, 2.45, 2.49, 2.55 > 2,58, 3.21, 3.43 * 3.43, 3.46, 3.56, 4.3, 4.57, 4.58, 4.60 and 4.65. Example B-3: Effect of beet (Beta vulgaris) against spoilage fungus Pythiuin debaryanuti a) Effect after soil application Fungus was cultivated in sterile oat granules and added to soil-sand mixture. The infected soil was placed in pots and sprinkled with beet seeds. After spraying the seeds, the active ingredient K aqueous solution, which is prepared as a wettable powder, was poured onto the soil (based on the volume of the soil moth, 20 ppra active ingredient. This pot was placed in a greenhouse 2Q to 24 = 0. For 2 to 3 weeks, the soil was sprayed with water to maintain moistness. In order to evaluate this test, the germination of sugar beets and the proportion of healthy and diseased plants were determined. B) The fungi after being covered with the desired fungus were cultured in sterile Oat grains and add to soil / sand mixture. The infected soil was placed in a flowerpot C and sprinkled with a test preparation, which was prepared as a coating powder (10 OOPPΐα according to the seed weight), and coated beet seeds. This pot is placed in a greenhouse for 20 to 24 υ 2 to 3 weeks, this-2 0 0-This paper size applies to China National Standard (CNS) Α4 size (210 × 297 mm) binding (please read the precautions on the back first) (Fill in this page again.) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Α7 Β7 V. Description of the invention The soil is sprayed with water to keep it moist. To evaluate this test, the percentage of beet gourds and healthy and diseased plants will be determined. After treatment of the active compounds in Tables 1 to 118, more than 80% of the plants grow and have a healthy appearance. In the control pot, only a few plants were observed, and a sick appearance was seen. Example B-4: Residual protection against Cercospora araehidicola in peanut plants 10 to 15 cm high peanut k aqueous spray mixture (0.Q 2% active ingredient) was sprayed at 48 Conidia contaminated with this fungus were suspended after an hour. The infected plant body was cultured at 21 · Ό and high humidity for 72 hours, and then placed in a greenhouse until typical leaf spots appeared. The evaluation of this active ingredient was done 12 days after infection and was based on the number and size of leaf spots. The active compounds of Tables 1 to 118 reduced leaf spots by at least 1Q% of the leaf surface area. In particular, the disease is completely suppressed by using the following compounds (in the case of a large number of infections from 0 to 5%): compounds 1.49 to 1.72, 1.79, 2.20 to 2.24, 2.35 to 2.39, 2.44 to 2.52, 2.59, -20 1 -This paper size is applicable to China National Standards (CNS) Α4 now (210X29? Public address --------- install --------, order -------- · # (Please read first Note on the back, please fill out this page again) 4339 82 ^ A7 B7__ V. Description of the invention 3.22 to 3.24 * 3.34 to 3_39, 3.45 to 3.60 and 3. 62. Example B-5: Puccinia graminis against wheat in the wheat (Puccinia graminis) Effect of a) 4 a) Residual protective effect 6 days after the seeds are removed · Wheat is sprayed to the extent of dripping with an aqueous spray liquid (OQ 2% active substance), and the summer spores infected with this fungus are tired after 24 hours. After 4M incubation period (conditions: 35 to 100% relative humidity, 20 V), the plant was placed in a 22 ° C greenhouse. Evaluation of the development of spot warts 12 days after infection. b) Systemic effects.- After 5 days of sowing, wheat plants are watered with an aqueous spray liquid ((3.0QS% active ingredient, based on the weight of the soil). Care should be taken not to mix the spray and to avoid contact with the plant height The soil was removed. The treated plant was infected with fungal summer spore suspension after 48 hours. After 48 hours of cultivation (conditions: relative humidity 95 to 100%, 20 t :), the plant was placed at 22 In greenhouse C. Evaluation of the development of spot warts 12 days after infection. The active compounds of Tables 1 to U8 significantly reduce the number of fungal infections-2 0 2-This paper is in accordance with Chinese national standards (CNS > A4 size (210X 297) (Mm) ί. I deduction I — 1 I order · ~~~ ^ (Please read the notes on the back before filling out this page) Printed by the Central Standards Bureau of the Ministry of Economy Cooperatives Yin Chang 4 3 3 9 8 2 ίΐ; α7 _____ Β7 _ V. Description of the invention (㈣) Less * sometimes reduced to 10-0%. In particular, the disease is completely inhibited by using the following compounds (0 to 5% Of severe infections): Compounds 1.51, 1.5 7, 1.62 to 1.64, 1.79, 2,222.23, 2.35, 2.39, 2.44, 2,45- 2.49 · 2.52- 2.59, 3, 22 to 3.24, 3.35, 3.39, 3.45 to 3.47, 3.50, 3.53, and 3.60. Example B — 6: The action of rice against Pyr icular ia oryzae a) Residual protective effect After 2 weeks of cultivation, rice K aqueous spraying liquid (G. 02% active substance) was sprayed, and at 48 The conidia suspension of the fungus was infected after 1 hour. After 5 days of infection, the degree of fungi of the fungus was assessed, and the relative humidity was maintained at 95 to 100% and the temperature was reduced to 20. b) Systemic action for 2 weeks A large amount of rice M was sprayed with water (H.Q06% active ingredient, root weight of soil) for irrigation. Take care not to make the spray warm and do not touch the part of the plant above the soil. The pot is then filled with water so that the lowest part of the rice stalk can stand in the water. After 96 hours, this plant ’s K fungal conidial suspension was infected and maintained at a relative humidity of 95 to 100% at a temperature of 24¾-2 0 3-This paper size applies to the Chinese National Standard (CNS) A4 (210X 297 mm) } IIII 1 III i order (please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Samples Bureau of the Ministry of Economic Affairs 433982-A7 _ _B7 _ V. Description of the invention Mp 捋 5 days. Table 1 to The active compound of 118 prevents the onset of disease in most of the infected plants. In particular, the disease is completely suppressed by the use of the following compounds (in the case of 0 to 5% older child infections): Compounds 1. 51, 1. 57 | 1 · 62 to 1,64, 1.?9, 2.222.23, 2.35, 2.39 * 2.44, 2.45 '2.49, 2.52, 2,59, 3.22 to 3.24, 3.35, 3.39 * 3.45 to 3.47, 3, 50, 3.53, and 3.60. Example B-7: The effect of apples against Venturia iaaequal on fresh apple cuttings with a length of 10 to 20 cm was sprayed with warm compound (0.0 2% active ingredient), and conidia infected with the fungus were suspended after 24 hours. Plants were cultured at a relative humidity of 30 to 100% for 5 days and placed in a greenhouse at 20 to 24 ° C for another 10 days. The degree of spot infestation was evaluated after 15 days of infection. The main compounds in Tables 1 to 118 It has a long-lasting effect against blight. Example B-8: The effect against Erysiphe graminis in barley-2 0 4-This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm)

It n^. I I —訂I — 線 (請先閲讀背面之注意事項再填寫本頁)is 4 3 39 8 2:^ A7 B7 五、發明説明（>〇1) a) 殘餘保護作用系勺8公分高的大麥以水性噴灑混合物（0.02%活性物質）噴灑並於3至4小時後撤下此真菌的分生抱子。感染的植物體被放置於22t：的溫室内。感染10天之後評估此真菌的大量感染程度。 b) 系統作用 8公分高的大麥K水性嗔灑液體（0.002%活性組成份，根據土壤的體漬）灌溉鄰近區。小心照顧勿使噴灑温合接觸到植物體高出土壊的部份。處理過的植物體4S小時後撒下此真菌的分生孢子。受感染的植物體被放置在22Ό 的溫室内。感染1Q天後評估此真菌的大量感染程度。表1至表Π8之化合物通常能夠降低疾病水平至2D90M 下，在有竖情況下甚至完全地抑制。經濟部中央樣隼局員工消费合阼社印裝 (請先閱讀背面之注意事項再填寫本頁) 簧例B—3:在蘋果芽對抗爵球足菌屬真菌（Podosphaera ieucotricha)的作用殘餘保護作用 - 2 0 5 - 本紙張尺度適用中國國家標牟（CNS )_ A4规格（210X25»7公釐〉經濟部中央標準局貝工消費合作社印製 433982U A7 B7 五、發明説明有約1 5公分長新鮮嫩芽的蘋果插枝以水性噴灌液體 (0 · 06%活性物質）噴灑。此處理過的椬物體24小時後感染此真菌的分生孢子並被放置於相對濕度70%和2〇υ的溫室内。感染12天之後評估此真菌的大量感染程度。表1至表Ιΐδ之活性化合物將此疾病降低至20%以下。在對照組植物體的發病率是100%。實例B— 1D:在蘋果果簧對抗葡萄菌屬真菌（Botrytis ci 的作用殘餘保護作用人為破壞的蘋果處理幾滴噴灑液體（0.0 2%活性物質 )至受破壊的位置。處理過的果實隨後接種此冥菌的孢子懸浮疲並在高濕度和大約2QTC下培養一個星期。受試物質之殺真菌的作用可由破壞區菱腐熥的數目看出。表1至118的活性化合物能夠避免腐熥的蔓延，在有些情況下可完全抑制3 實例B_H:在小麥對抗蟲形菌靨真菌（ H e i in i n t h 〇 s ρ 〇 r i u m g r a m i n e u m)的作用 - 2 0 6 - 本紙浪尺度適用中國國家標準（CNS ) 格（2〖OX 297公嫠) ---------^裝--^----訂------Μ 6 (請先閱讀背面之注意事項再填寫本頁)eL, A7 4 3 3982::』 B7 五、發明説明（>£?的將小麥穀粒攙雜此真菌的孢子懸浮疲並使之乾燥。受污染的穀粒覆蓋試驗物質（根據種子重量為60Qppm的活性組成份）的懸浮液。兩天之後，此穀粒排列在適當的凝膠培養皿上，四天後評估穀粒四周長出的真菌菌落。真菌菌落的數量和大小被用來評估此試驗化合物。 .表1至11 8之化合物有些情況下展現很好的作用，即完全抑制真菌菌落。特別是，此病經由使用下列化合物完全被抑制（0至5%的大量感染的情脬）：化合物1 · 5 1，1 , 6 2 至 1.64, 2.22， 2.23， 2·33* 2.44， 2.49， 2.52， 3.22至 3·24 ， 3.35 ， 3.45至 3.47 ， 3.53 ，及 3. 60〇實例Β — 12:在黃瓜對抗黏毛菌匾真菌（ Co+lletotrichum iagenariuai)的作用經過2個星期的培養後，黃瓜以噴灑疲體（濃度〇〇2 %)被噴灑。兩天後，此植物體Μ真菌之孢子懸浮疲（ l,5xlQs孢子/毫升）並在23亡和高濕度下培養36小時。繼潢在正常大氣濕度及約2 2 _ 2 3 培養。感染8天後評估真菌的大量感染程度。在未經處理並受感染的對照組植物體其真菌的侵擾為。 - 2 0 7 - 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) —裝' ,-t 經濟部中央標隼局員工消費合作社印製 433982^ 經濟部中央標準局員工消費合作社印裝 A7 B7五、發明説明（yjf) 在一些情況，表1至118之化合物幾乎完全抑制疾病。實例B — 13:在燕麥對抗纺缍形孢子菌屬真菌（ F u s a r i u m n i v a 1 e)的作用自然感染纺綞形孢子菌屬真菌（Fusarium nivale)的燕麥變種 tetrahell被耰蓋上欲試驗的殺真菌劑，並使用 K下的濃度：20或6ppm (根據種子的重量）。受感染並處理過的燕麥在十月初撒種，用撒種機撤下三公尺長的六排種子。每一種濃度均做三重複。此試験的作物一直培養在正常的田野條件下直到評估其大量感染程度（最好在冬季月份期間沒有雪覆蓋的區域 )° 為了測定植物毒性，種子的萌發在秋季評估並且每單位區域此植物體的密度/數量在春季評估。為了決定化合物的活性，在春天，在雪剛剛溶化之後，便計算受纺缍形孢子菌屬（Fusariuin)大量感染的植物百分比比例。在此情形下，病株植物的百分比少於5%。而萌發的植物體外表是健康的。特別是，此病經由使用下列 -208 - (請先閲讀背面之注意事項再填寫本頁) .裝-It n ^. II —Order I — Line (please read the notes on the back before filling this page) is 4 3 39 8 2: ^ A7 B7 V. Description of the invention (> 〇1) a) Residual protection function 8 cm tall barley is sprayed with an aqueous spray mixture (0.02% active substance) and the fungal conidia are removed after 3 to 4 hours. The infected plants were placed in a 22 t: greenhouse. Ten days after the infection, the degree of massive infection of the fungus was evaluated. b) Systemic action 8-meter-high barley K water-based sprinkler liquid (0.002% active ingredient, based on soil stains) irrigates adjacent areas. Take care not to expose the spray to warm parts of the plant that are above the soil. After 4S hours of the treated plant body, conidia of this fungus were sprinkled. The infected plants were placed in a 22Ό greenhouse. The extent of this fungal infection was assessed 1Q days after infection. The compounds of Tables 1 to 8 are generally capable of reducing disease levels to 2D90M and even completely inhibiting them in the presence of uprights. Printed by the Consumer Affairs Agency of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) Spring case B-3: Residual protection against the action of apple buds against Podosphaera ieucotricha Function-2 0 5-This paper size is applicable to China National Standards (CNS) _ A4 size (210X25 »7mm) Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, 433982U A7 B7 5. The description of the invention is about 15 cm Apple shoots with fresh shoots were sprayed with an aqueous spray liquid (0. 06% active substance). The treated pupae were infected with conidia of the fungus 24 hours later and placed at a relative humidity of 70% and 20% In the greenhouse. The infection degree of this fungus was evaluated 12 days after the infection. The active compounds of Table 1 to Table Iΐδ reduced this disease to less than 20%. The incidence of plants in the control group was 100%. Example B-1D: The apple fruit spring against Botrytis ci fungi (Botrytis ci) Residual protective effect Artificially damaged apples are treated with a few drops of spraying liquid (0.0 2% active substance) to the location of the pupae. The treated fruits are then inoculated with this The spores were suspended and cultured for one week at high humidity and about 2QTC. The fungicidal effect of the test substance can be seen from the number of maggots in the destruction zone. The active compounds of Tables 1 to 118 can prevent the spread of rot. In some cases, it can be completely inhibited. 3 Example B_H: Effect of wheat against infestation of fungi (H ei in in 〇s ρ 〇 riumgramineum)-2 0 6-This paper applies the Chinese National Standard (CNS) standard (2 〖 OX 297) 嫠 --------- ^ 装-^ ---- Order ------ M 6 (Please read the notes on the back before filling this page) eL, A7 4 3 3982 :: "B7 V. Description of the invention (> The wheat spores are doped with spores of this fungus and suspended and dried. The contaminated grains cover the test substance (based on the active ingredient of 60 Qppm) After two days, the grains were arranged on an appropriate gel culture dish, and four days later, the fungal colonies growing around the grains were evaluated. The number and size of the fungal colonies were used to evaluate the test compound. Table The compounds of 1 to 11 8 show good effects in some cases, ie Fully inhibits fungal colonies. In particular, the disease is completely inhibited by using the following compounds (from 0 to 5% of large infections): Compounds 1 · 5 1, 1, 6 2 to 1.64, 2.22, 2.23, 2.33 * 2.44, 2.49, 2.52, 3.22 to 3.24, 3.35, 3.45 to 3.47, 3.53, and 3.60. Example B-12: The role of cucumber against Co + lletotrichum iagenariuai in cucumber After one week of cultivation, cucumbers were sprayed with spray fatigue (concentration 0.02%). Two days later, the spores of this plant's M fungus were suspended (1.5xlQs spores / ml) and cultured at 23 h and 36 h for 36 hours. Following the cultivation in normal atmospheric humidity and about 2 2 _ 2 3. Eight days after the infection, the degree of substantial infection of the fungus was evaluated. The fungal infestation was found in untreated and infected control plants. -2 0 7-This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling out this page) —packing ',-tEmployees ’consumption by the Central Bureau of Standards, Ministry of Economic Affairs Printed by a cooperative 433982 ^ A7 B7 printed by a cooperative of employees of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (yjf) In some cases, the compounds of Tables 1 to 118 almost completely inhibit disease. Examples B-13: Effect of Oat against Fusariumniva 1 e. Oat variant tetrahell, which naturally infects Fusarium nivale, is covered with the fungicide to be tested. And use the concentration under K: 20 or 6ppm (depending on the weight of the seed). The infected and treated oats were sown in early October, and the seeder was used to remove six rows of three meters long seeds. Each concentration was done in triplicate. The test crop was cultivated under normal field conditions until the extent of infection was assessed (preferably in areas not covered by snow during the winter months) ° To determine phytotoxicity, the germination of seeds was evaluated in autumn and this plant body per unit area The density / quantity is evaluated in the spring. In order to determine the activity of the compound, in the spring, immediately after the snow had melted, the percentage of plants heavily infected by Fusariuin was calculated. In this case, the percentage of diseased plants is less than 5%. The germinated plant is healthy on the outside. In particular, this disease is achieved by using the following -208-(Please read the precautions on the back before filling this page).

、1T 'Μ 本纸張尺度適用令國國家標準（CNS } A4規格（210X297公釐} 4 3 398 2^i A7 ___B7 _ 五、發明説明（>^6) 化合物完全被抑制（Q至5%的大量感染的情形）：化合物 1.57， 1.62至 1·64, 1.79， 2.23^2.35， 2.39， 2.44， 2.49，2.52，2.59，3.22至 3.24，3.39，3.45至 3.47， 3.53，及 3 · 60 ° 實洌14:在小麥上對抗腐爝菌靨真菌（Sept oria no do run)作用在三葉期的小麥M自活性物質之可溼潤粉末調製（2.3 :1)之噴灑疲體（60ρρπ活性物質）進行噴灑。 24小時後，此處理過的植物體感染此真菌的分生®子懸浮疲。隨後此植物體在相對濕度9 0至10 0%培養兩天並被置於2 ΰ至2 4 D的溫室内在培養1 G天。感染1 3天之後評估此真菌的大量感染程度。少於1%的小麥植物體顯示出大量感染的情彤。貿例Β - 15:在稻米上對抗假根菌靥真菌（ ϋ h i 2 〇 c 1; ο π i a s ο 1 a n i )的作用保護性局部土壊應用十天大的稻株鄰近K自被調製之受試物，質所製顏的-懸 - 2 0 9 - 本紙張尺度適用中國國家標準（CNS ) A4規格（2[0X297公釐） ---------.裝------ir------Μ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印裳、 1T 'Μ This paper size applies the national standard of the country (CNS) A4 specification (210X297 mm) 4 3 398 2 ^ i A7 ___B7 _ 5. Description of the invention (> ^ 6) Compounds are completely inhibited (Q to 5 % Of cases with large infections): Compounds 1.57, 1.62 to 1.64, 1.79, 2.23 ^ 2.35, 2.39, 2.44, 2.49, 2.52, 2.59, 3.22 to 3.24, 3.39, 3.45 to 3.47, 3.53, and 3.60 ° Practice 洌 14: Anti-rot fungus fungus (Sept oria no do run) on wheat Trifoliate stage Wet powder preparation (2.3: 1) of wheat M self-active substance spray spray (60ρρπ active substance) Spraying was performed. After 24 hours, the treated plants became infected with the conidia of the fungus. The plants were then cultured at a relative humidity of 90 to 100% for two days and placed at 2 to 2 4 D. The culture was carried out in a greenhouse for 1 G days. The extent of this fungal infection was evaluated after 1 to 3 days of infection. Less than 1% of wheat plants showed a large number of infections. Trade Example B-15: Resistance to pseudorhizobia on rice The role of tadpole fungi (ϋ hi 2 〇c 1; ο π ias ο 1 ani). Tianda's rice plant is adjacent to the K-modulated test substance, which is made by the quality-hanging-2 0 9-This paper size applies the Chinese National Standard (CNS) A4 specification (2 [0X297 mm) ---- -----.Equipment ------ ir ------ Μ (Please read the notes on the back before filling this page) Yin Chang

4 3 39 8 2.J A7 _B7 _ 五、發明説明浮液（噴灑液體）灌溉，並且不污染到植物體高出土壤的部份。三天後在每一盆稻米間放置一片受假根菌屬真菌（ Rhizoctonia solani)感染的大麥桿來進行感染。真菌大量感染的評估是在白天溫度29¾晩上溫度2STC相對濕度95 %的環境控制箱子内培養六天後進行。少於5%的稻米植物體顯示大量感染的情形。植物體有健康的外表。保護性局部葉片應用十二天大的稻米Μ被調製之受試驗物質的懸浮液噴灑。一天後在每一盆稻米間放置一片受假根菌靥真菌（ Rhizoctonia solani)感染的大麥桿來進行感染。評估是 _在白天溫度291晚上溫度26¾相對濕度9 5%的環境控制箱子内培養六天後進行。在未經處理且受感染的對照組植物體受冥菌大量感染是1Q0%。在一些情況下，表1至118之化合物幾乎完全抑制疾病。經濟部中央標隼局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) β .殺昆蟲性作用實施例 Β - 16:對抗班屬昆蟲（Aphis craccivora) 的作用銳豆幼苗以晚靥昆蟲（Aphis craccivora)進行感染 -210- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐} 經濟部中央標準局員工消費合作社印製4 3 39 8 2.J A7 _B7 _ V. Description of the invention Floating liquid (spraying liquid) is irrigated and does not pollute the part of the plant that is higher than the soil. Three days later, a piece of barley straw infected with Rhizoctonia solani was placed between each pot of rice for infection. The evaluation of a large number of fungal infections was performed after six days of incubation in an environmental control box at a temperature of 29¾ 晩 and a temperature of 2STC and a relative humidity of 95%. Less than 5% of the rice plant body showed a large number of infections. Plants have a healthy appearance. Protective local leaf application Twelve-day-old rice M was sprayed with a suspension of the test substance prepared. One day later, a piece of barley straw infected with Rhizoctonia solani was placed between each pot of rice for infection. The evaluation was performed _ in an environmentally controlled box at day temperature 291 night temperature 26¾ relative humidity 9 5% after six days of incubation. In the untreated and infected control plants, the number of bacterial infections was 1Q0%. In some cases, the compounds of Tables 1 to 118 inhibit disease almost completely. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) β. Insecticide effect example B-16: The effect against Aphis craccivora Late Insect Insect (Aphis craccivora) infection -210- This paper size applies to China National Standard (CNS) A4 (210X297 mm) printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

^3398 2U 〜 A7 ____ B7 五、發明説明（>f ’接者以一包含1QQ ppm之活性化合物的噴灑液體進行噴灑，且隨後在20¾進行培養。經由在經處理的及未經處理的植物上比較死亡蚜蟲的數目，於3及6天後決定族群降低百分率（％作用）。茌此試驗中，表1至Π8之化合物類大部份顯示良好的作用。實施例B — 17:對抗葉甲屬昆蟲（Diabrotica balteata)之活性在玉蜀黍幼苗上噴灑包含4 0 0 ppm受試化合物之乳化水溶疲。當噴灑的包覆層乾燥之後，將10隻第2階段的葉甲鼷昆蟲（Diabrotica balteata)幼蟲散佈至玉蜀黍幼苗上並置於塑膠容器中。6 天後進行評估。族群降低的比例（％作用）經由比較在經處理植物上及未經處理植物上的幼蟲死亡數目加以決定。 .在此試驗中，表1到表11S的化合物表現良好的活性。特別是，下列化合物在此試驗中顯示超過80%之作用：化合物 1.9， 2.31， 4.4， 4.5， 4.6， 4‘16， 4.17， 4.20， 4.2 5- 4.3 4，4.3 9 * 4 . 40至 4.47* 4.141，4.144及 4.146° -2 11- 本紙張尺度適用中國國家標车（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) I.裝· 訂 A7 B7 433982^ 五、發明説明) 實施例B-13:對抗棉蛉蟲靥昆蟲（Heliothis virescens)的作用在黃豆幼苗上噴’灑包含1WPP®受試化合物之乳化水溶液。當噴灑的包覆層乾燥之後’將10隻第1階段的棉岭蟲屬昆蟲（H e 1 i 〇 t h i s v i r e s c e n s)毛蟲散佈至每株黃豆幼苗上並置於塑膠容器中。6天後進行評估。族群降低比例的百分例及飼養損害的降低百分率（％作用）經由比較在經處理植物上及未經處理植物上的毛蟲死亡數目及受試植物的薛I 養損害程度來決定。在此試驗中，表1到表Π 8的化合物大部份表現良好的活性。特別是，下列化合物在此試驗中顯示超過8β%之作用：化合物 1.9， 2.31’ 4.5’ 4.20， 4.29， 4.33， 4.39， 4 . 4 0 至 4 . 4 7，4 . 14 1，4 . 1 4 4 及 4 . I 4 6。實施例Β— 19:對抗夜蛾屬昆蟲（Spodoptera litloralis)的作用在黃豆幼苗上噴灑包含lOQppm活性化合物之乳化水性疲體，當噴灑的包覆層乾燥之後，將10隻第3階段的夜蛾屬昆蟲（Spodoptera litloralis)毛蟲散佈至每株黃豆幼苗上並置於塑膠容器中。6天後進行評估。族群降低比例的百 -2 12- 本紙浪尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）裝 ..—I 訂線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作杜印裝經濟部中央標準局員工消費合作社印裝 A7 B7 五、發明説明分例及阙養損害的降低百分率（％作用）經由比較在經處理植物上及未經處理植物上的毛蟲死亡數目及受試植物的飼養損害程度來決定。在此試驗中，表1到表Η&的化合物表現良好的活性。特別是，下列化合物在此試驗中顯示超過8Q%之作用：化合物 1.9， 4 5，4 . 1 6，4 . 1 7，4 . 2 0，4 2 5至 4 . 3 2 * 4 , 4 7 及 4.141 至 4.146。 C .殺蟎性作用實施例 B-2Q:對抗紅葉蟎靥昆蟲（Tetranychus urticae)的作用豆幼苗Μ紅葉蟎龎（ Tetranychus urticae)的混合族群加以散佈且 1天後K含有100 PP®受試化合物之乳化水性菠體進行噴灑。該植物陲後於 25Ό培育6天且隨即進行評估。族群降低比例的百分率（％作用）經由比較在經處理植物上及未經處理楦物上的死卵*幼蟲及成蟲數目加以洪定。在此試驗中，表1到表118的化合物大部份表現良好的活性。特別是，下列化合物在此試驗中顯示超過80%之作 -213- 本纸浪尺度適用中國國家標準（CNS ) A4規格（2! Ο X 297公釐）裝 I ^ I ^ {請先閲讀背面之注意事項再填莴本頁) 433982m A7 B7 五、發明説明（>Π) 1·及 Ϊ 6 物 4 合 4化至 ο : 4 用 4 至 (請先閱讀背面之注意事項再填寫本頁) I裝· 、1Τ Μ: 經濟部中央標準局員工消費合作杜印製本紙浪尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐）^ 3398 2U ~ A7 ____ B7 V. Description of the invention (&f; These are sprayed with a spray liquid containing 1QQ ppm of active compound, and then cultivated at 20¾. By using in treated and untreated plants The number of dead aphids was compared in the above, and the percentage reduction (% effect) of the population was determined after 3 and 6 days. 茌 In this test, most of the compounds of Tables 1 to Π8 showed good effects. Example B-17: Anti-leaf Diabrotica balteata activity Sprayed on maize seedlings with emulsified water containing 400 ppm of the test compound. When the spray coating was dried, 10 second-stage leaf beetle insects (Diabrotica balteata) ) The larvae were scattered on maize seedlings and placed in plastic containers. Evaluation was performed after 6 days. The proportion of population reduction (% effect) was determined by comparing the number of larval deaths on treated and untreated plants. Here In the tests, the compounds of Tables 1 to 11S showed good activity. In particular, the following compounds showed more than 80% effect in this test: Compounds 1.9, 2.31 , 4.4, 4.5, 4.6, 4'16, 4.17, 4.20, 4.2 5-4.3 4, 4.3 9 * 4.40 to 4.47 * 4.141, 4.144, and 4.146 ° -2 11- This paper size applies to Chinese national standard vehicles (CNS ) A4 size (210X297 mm) (Please read the precautions on the back before filling out this page) I. Packing and ordering A7 B7 433982 ^ V. Description of the invention Example B-13: Resistance to cotton borer insects (Heliothis virescens ) Spray soybean seedlings with an emulsified aqueous solution containing 1WPP® test compound. When the sprayed coating is dried, 10 caterpillars of the first stage of the cotton worm (H e 1 i 0 t h i s v i r s c en s) were spread on each soybean seedling and placed in a plastic container. Evaluation was performed after 6 days. The percentage reduction of the population and the percentage reduction of feeding damage (% effect) were determined by comparing the number of caterpillar deaths on treated and untreated plants with the extent of Xue I nutritional damage in the test plants. In this test, most of the compounds of Tables 1 to 8 showed good activity. In particular, the following compounds showed an effect of more than 8β% in this test: Compounds 1.9, 2.31 '4.5' 4.20, 4.29, 4.33, 4.39, 4.40 to 4.4 7,4.14 1,4.1 4 4 and 4. I 4 6. Example B-19: Action against Spodoptera litloralis. Soybean seedlings were sprayed with an emulsified aqueous fatigue body containing 10Qppm active compound. After the spray coating was dried, 10 third-stage Spodoptera litura were sprayed. Caterpillars of the genus Spodoptera litloralis were spread on each soybean seedling and placed in plastic containers. Evaluation was performed after 6 days. The percentage of the ethnic group is reduced by a hundred-2 12- The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) Packing .. —I Thread (please read the precautions on the back before filling this page) Central Ministry of Economic Affairs Standards Bureau employee consumption cooperation Du printed equipment Central Ministry of Economic Affairs Central Standards Bureau employee consumption cooperative printed A7 B7 V. Description of invention and percentage reduction of maintenance damage (% effect) Through comparison on treated plants and untreated plants The number of caterpillar deaths and the degree of rearing damage of the test plants are determined. In this test, the compounds of Tables 1 to VII & showed good activity. In particular, the following compounds showed an effect of more than 8Q% in this test: Compounds 1.9, 4 5, 4. 16, 4. 1 7, 4. 2 0, 4 2 5 to 4. 3 2 * 4, 4 7 And 4.141 to 4.146. C. Acaricidal effect Example B-2Q: Effect against Tetranychus urticae against a red spider mite A mixed population of bean seedlings M Tetranychus urticae is spread and after 1 day K contains 100 PP® test compound Spray the emulsified aqueous spinach. The plant was subsequently bred for 6 days at 25 ° C and evaluated immediately. The percentage of population reduction (% effect) was determined by comparing the number of dead eggs * larvae and adults on treated plants and untreated pupae. In this test, most of the compounds of Tables 1 to 118 showed good activity. In particular, the following compounds show more than 80% of the work in this test -213- The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2! 〇 X 297 mm) Packing I ^ I ^ {Please read the back first Note for refilling the lettuce page) 433982m A7 B7 V. Description of the invention (> Π) 1 · and Ϊ 6 objects 4 in 4 to ο: 4 to 4 (Please read the precautions on the back before filling in this page ) I, 1T Μ: Consumption cooperation between employees of the Central Bureau of Standards of the Ministry of Economic Affairs, printed paper and paper scales applicable to Chinese National Standard (CNS) Α4 specifications (210 X 297 mm)

Claims

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

(η, where μ ε-labeled difluorene has E-configuration; where U) X is S * Υ is 0 R 1 or NHR e Si is Ci—C4 compound; yttrium 8 is erbium or C i — C4 fluorenyl group Rs is methyl El Elί G is 0; Density A is a direct bond; R7 is ethyl; R is an uncertified or single or multiple substituted C i -C4 integrative one, C2- C4 pavement one, C2 —iU iron group ~, C3 — Cs-cycloalkyl group ~, benzyl one or aryl one group * Among which the substituents of these groups 1-This paper standard is applicable to Chinese National Standard (CNS ) A4 size (210 X 297 mm) 谞谞 Please read the precautions on the back before filling this page) 4 3 3982α §8 CS D8 c. Scope of patent application (please read the precautions on the back before filling out this page > category Independently selected from halogen, Ci-Cs alkyl, halogen-Ci ~ Cs alkyl * c3 _ "cyclofluorenyl * halo-c3-cs cycloalkyl Ci-cs alkoxy, halogen-Ci -Ce alkoxy, Ci—CS alkylthio, halo_Ci_Cs alkylthio, phenoxy, c ί and nitro, or a phenyl radical, which Two neighbors The carbon atom 'is substituted by s-unsubstituted or mono- to tetra-substituted Ci-c4 alkylenedioxy fluorene with a single substitution I wherein the substituent class is selected from the group consisting of Ci_C4 alkyl and halogen ^ ChT2 Si (CHs) 3; each, when appropriate, is in free or salt form in each case. 2. If the compound of formula (I) is claimed in item 1 of the patent scope, Where Y is 0 pt i ο 3 * If the compound of formula (ί) in item 1 or 2 of the patent scope is requested, it is C! — X2 Comprehensive base 0 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 4. The formula (I) of the first scope of the patent is a chemical compound, where RS is a or c!-C 2 alkyl. 5. If the compound of the formula (I) of the first scope of the patent is claimed, wherein AR 7 is ethyl, η is 1 and IΪ is a substituted phenyl or benzyl group, wherein the substituents are selected from the group consisting of halogen, Ci ~ C4 alkyl or halogenated—Ci — (U This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 4 3 398 A8 B8 C8 D8 VI. One of the groups in the scope of patent applications. Wherein the formula (I) is chemically tough, wherein Y is a Ct-C2 alkoxy group; Rg is a methyl group; and R is a substituted phenyl or benzyl group, wherein the substituent is selected from the group consisting of fluorine, One of the groups of chlorine, bromine, methyl and halomethyl. 7. For example, the formula of item 丨 of the patent application (II) is used (where the compound is {2-ethoxypanamino-1-methyl ~ 2- [4- (4-trifluoromethyl- Phenoxy) -phenyl] -ethyleneaminooxymethylphenylphenyl) ~ methoxyimino-methyl acetate. S.—A method for preparing a compound of formula (I), such as the patented item No. 1, which is in a free form or a salt form under various circumstances, and includes a compound of the following formula: r9o ^ x ^^ y

This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) --------- I --- I I ---- I order --------- line (Please read the precautions on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, 9 82 Domain AS B8 C8 D8 Patent Application Scope (II) where X-· Y and R g are as in formula (I) And X i is chloro, prefer to react with a compound of the formula HO in the presence of a base HO

(GR) n (III where n, A, G, R and β7 have the definitions as in formula (I) (please read the precautions on the back before filling this page) or a2) the wisdom of the Ministry of Economics of the compound of the following formula Printed by the Property Agency Staff Consumer Cooperative

(GR) n IV) where η, R, G, A, and R 7 have the definitions as in formula U) —4 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) u289 33 4 cqoooo 梠 ABCD patent application scope if appropriate * In the presence of a base, react with the following formula 〇I ″ R90, y, Y 〇〇NH, CI Η. (V) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Make it Zheng Zheng or Ke Jing as a known method plus 加, and wherein X, Υ and S s have the definition as in formula (I), or b) for the preparation where Y is SSR8 And Z is a compound of formula (I) of G, and a compound of formula (I): wherein Y is OR! Is reacted with a compound of formula R8 SK2, which is Bru or K itself may be a known method. K is prepared, where k has the definition as in formula (I), is known to each other or may be prepared by a known method plus K, and reacts with hydrogen in the presence of a heavy catalyst. 3. — A compound of the type 〇, β, HO

-δ This paper size is applicable to the national standard (CNS) A4 specification (210 X 297 mm) --- I ------- 11 -------- Order ------- --- line— r (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 43 39 8 2 ^ A8 B8 C8 D8 VI. Patent Application Range (111) Of which n, A , G, E7 have the definitions in formula (I) in item 1 of the scope of the application, and are in free form or salt form. 1 0. — A method for preparing a compound by enforcing formula (111) of item S of the patent scope, which compound is in free form or salt form in various cases, which includes, f) formula (IV) Compounds in which n, A, R and R7 have the definitions in formula (I) in item 1 of the scope of the patent application, if appropriate, in the presence of a base> reacting with ^ Νβϋ or a salt thereof, or g ) Add the compound of the formula OH.

Among them, η, G and R have the definitions as in the formula U) in the first item of the patent application range, and if appropriate, react with the following formula in the presence of a base -6 ~ This paper applies to China National Standard (CNS) A4 Specification (210 X 297 mm) ----- I ------- Crack -------Order --- J I ---- line (please first Read the notes on the back and fill in this page> Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, 433,982 stitches D8 VI. Patent application scope R7 ANKz (VII)-where A and R7 have Definitions in formula (I). 1 1.-A pesticide that includes at least one effective concentration. For example, the compound of formula (I) in the scope of the patent application, the formula (I), is in free form or agricultural chemistry. A salt form used as a living compound and at least one adjuvant. 0 12. A method for controlling pests, which comprises incorporating a compound of formula (I) as described in item 1 of the patent application or patent application The composition of the scope mii is applied to the pest or its environment. I 3. If the method of the scope 12 of the patent application is applied, it is used for protection. Plant propagation material, which includes the location to handle the propagation toughness or the location where the propagation material is frightened. I 4. A compound of the following formula-7- This paper size applies to the National Standard (CNS) A4 (210 X 297 mm) --I ---------- install !! Order --I ---! · Line (please read the precautions on the back before filling this page) 433982 A8 B8 C8 D8 Patent Application Scope

Zhong Li Fan Li, whose style is defined in. Special type Please shape the string of salt in or like the shape and shape with 7 swims R Γ ί and i_, A and other items of the compound formula below

(Please read the notes on the back before filling out this page) Printed item r —- * of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, please refer to πϋ $ 有有 Rri 离和游 G 为 ”Among them Defined 0 or 8 of the paper form are in accordance with Chinese National Standard (CNS) A4 specification (210 X 297 mm) Announcement 1 Application date is redundant, / ^ -1 Case No. St // ^ 7 / Category A〇, υ > 7 (. ^ / π > (the above columns are filled in by the Bureau) 86. Year El Elly modified!! A4 C4 433982 II Patent Specification Chinese Invention New Name Pod Name Nationality Pesticide Pesticidfifi (1 Factory Sand Lin Faluo, Shi Fang, Terra, creator and residence, Hu Guo, ⑷ René, ⑸ Yafeng, ⑹ Henry, ⑺ Loger, ⑴Switzerland ⑸Switzerland ⑸Spain ⑺United Kingdom Q) Switzerland 4422 Yasdorf .27 Church Street 731Germany 73111 Guanleburg, Andrea, 15 卩 3 Hoover Street ⑶Switzerland 41Q8 Wittsweier-Boyak 15 ⑷Switzerland 4Q52 Bassel 180 Road ⑸ Switzerland 40 53 Basel, County Detinger 43 No. 3⑹Switzerland 4323 Wachbach, Borden-g). Switzerland 4 U 71 Xu Xu title No. 5 __—— Cigler. Early rich green Pascust Strandski Grahan Howard Germany 莆 ⑵Switzerland⑹Switzerland Binding name (name) Zahua Company Line M Central Ministry of Economy and Social Affairs, Central Bureau of Quasi-Employees, Consumers' Cooperatives, Printed Country, Switzerland 3. Applicant's Residence (Office) Representative Name, Switzerland 4058 Basel City, 215 Black Forest Avenue 1. Werner * Wadek 2. Watlow Fogle This paper size is applicable to the national standard (CNS) M standard of the country (210X297 public celebration) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

(η, where μ ε-labeled difluorene has E-configuration; where U) X is S * Υ is 0 R 1 or NHR e Si is Ci—C4 compound; yttrium 8 is erbium or C i — C4 fluorenyl group Rs is methyl El Elί G is 0; Density A is a direct bond; R7 is ethyl; R is an uncertified or single or multiple substituted C i -C4 integrative one, C2- C4 pavement one, C2 —iU iron group ~, C3 — Cs-cycloalkyl group ~, benzyl one or aryl one group * Among which the substituents of these groups 1-This paper standard is applicable to Chinese National Standard (CNS ) A4 size (210 X 297 mm) (谞 Please read the precautions on the back before filling in this page)