TW457324B - Manufacture method of an environmental floor tile - Google Patents

Abstract

This invention provides a manufacture method of an environmental floor tile. Materials included are garbage, magnesia, blend agent, hydration modifier, and organic hydrolysis lessening agent. Percentage of weight accordingly: garbage 60-80%, magnesia 19-25%, blend agent 11.7-13%, hydration modifier 1.04-1.06%, and organic hydrolysis lessening agent 0.26-0.40%. Garbage mentioned is ordinary garbage and kitchen waste treated by sieving. The adding of proper amount of modifier will ensure floor tile containing undesired magnesium to solve damp, cracking, and strength lessening problem of conventional floor tiles. The adding of organic hydrolysis lessening agent will help solve conventional floor tile problems of toxic emitting, ozone, and environmental pollution.

Description

457324 A7 B7 V. Description of the invention (1) The present invention relates to a method for preparing environmentally friendly floor tiles, in particular to a method that can completely solve the problems of moisture absorption and cracking and reduced strength of existing floor tiles, and can solve the existing floor tiles. The use of toxic and odorous gases will pollute the environment. According to the current use of garbage made of concrete (environmental floor tiles for paving) is composed of garbage and composite materials, the composite material is composed of magnesium oxide, south piece and modifiers. The modifiers include ferrous sulfate, copper sulfate, Magnesium sulfate, potassium ferrate, urea-formaldehyde resin, and gasified ammonia; the manufacturing steps are as follows: dissolve the toothed pieces with water, then add the adjusting agent, and then add magnesium oxide, stir evenly to make a binder, and finally add the binder to the treatment In the subsequent garbage, they are mixed and stirred to make garbage floor tiles. However, although the above-mentioned method can be used to produce garbage monuments for the purpose of recycling waste, this environmentally-friendly monument made of garbage has the following disadvantages. : 1. Because too few modifiers are added, the problems of moisture absorption and moisture return caused by excessive magnesium ions in environmental stele due to various reasons cannot be properly solved, and the environmental strength of the environmental stele will reduce the strength and crack easily. problem. 2. Because the added modifier does not contain the components that can degrade the organic matter in the garbage, the organic matter in the environmentally friendly floor tiles will deteriorate and emit odorous gas during use, causing environmental pollution. It is true that the above-mentioned conventional waste manufacturing engineering has the following disadvantages: because the tooth solution, water, modifier and magnesium oxide are used to make the binder solution, and then the binder solution is added to the treated garbage, mixed and stirred to make Environmentally friendly floor tiles, so 'before the binder solution is added, part of the halogen flakes made by the binder solution' are difficult to deal with the waste after disposal: affairs' ;: This paper size is applicable to China Standard rate (CNS) A4 specification (210X297 mm) Page 3 I. Luxury on this page / •: Z. From left to right; must not be clear.: 5. Use _ k to reveal the .t 着.-I shows the invention Printed by Shellfish Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs

j 457324 A7 ------------ Γ57 V. Description of the invention (2) Mixing 'causes a direct impact on the combination with garbage and greatly reduces the intensity of the stele. In view of this, the creators of this case, after careful consideration and constant observation, research, and repeated trials, finally came out of the invention. That is, the main object of the present invention is to provide a method for preparing an environmentally friendly floor tile which does not absorb moisture, has high strength, and has no responsibilities or harm to the environment. The secondary object of the present invention is to provide an environmentally friendly land that can completely solve the problems of moisture absorption and cracked and reduced strength of existing environmentally friendly floor tiles, and can solve the problems of the existing environmentally friendly floor tiles that emit toxic and odorous gases and pollute the environment. Stele preparation method. The reason is that a method for preparing an environmentally friendly floor tile according to the present invention includes garbage, magnesium oxide, a blending agent, water and a modifier, and includes an organic matter degrading agent. The garbage is general garbage and kitchen waste. Treated and salty, the weight percentage of each component is: garbage: 60 ~ 80%, oxidation town: 19 ~ 25% 'blending agent: 11.7 ~ 13%, modifier: 1.04 ~ 1.60%, and organic matter degradation Agent: 〇. 26 ~ 0. 40%, by adding an appropriate amount of modifier, the stele does not contain excess magnesium ions, in order to completely solve the problem of moisture absorption and cracked, reduced strength of existing floor tiles, and borrow By adding the organic substance degrading agent, the floor tiles do not contain undegraded organic matter, so as to completely solve the problems of the existing floor tiles emitting poisonous and odorous gases and polluting the environment. In order to make the purpose, features, and effects of the present invention further understood, a preferred embodiment is described below with reference to the drawings: Brief description of the drawings: The first drawing is a preferred embodiment of the present invention Manufacturing flow chart. The paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297 mm page 4)

^ 73 2 4 Α7 Β7 Printed by Zhengong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (3) A "preparation method of environmentally friendly floor tiles" according to a preferred embodiment of the present invention, mainly including garbage, magnesium oxide, blending Agent, water and chemical agents, as well as organic degradants, the garbage is the general garbage, kitchen waste, and the total weight of each component is: garbage: 60 ~ 80%; magnesium oxide: 1 9 ~ 25%; Blending agent: 11.7 ~ 13%; Modifier: 1.04 ~ 1. 60%; Organic matter degrading agent: 0.26 ~ 0.40% »The blending agent can be halogen tablets, magnesium sulfate, ferrous sulfate Mixture with halogen tablets. The modifier may be a water reducing agent, such as a naphthalene sulfonate; it may be a water resistance agent, such as: an inorganic iron salt, vaporized iron and ferrous sulfate, an inorganic aluminum salt; and a water blocking enhancer, such as water-soluble or water Milky polymer, such as styrene_methyl acrylate copolymer emulsion, polymethyl methacrylate emulsion, polyvinylidene chloride emulsion, ethyl silicate, styrene-butadiene emulsion; can be produced with excess side tablets Excess magnesium ions form active substances such as pumice, tuff, phosphate, copper sulfate, and hydrochloric acid. The organic substance degrading agent may be vitamin 'such as Bi2, vc, may be tetraazafolate' or a metal chelating agent 'such as ethylenediaminetetraacetic acid. As shown in the first circle, as for a preferred embodiment of the present invention, the method for manufacturing an environmental stele by using garbage further includes the following steps: Step 1: Use a pulverizer to pulverize the garbage from which the larger metal pieces have been removed. Fineness. The standard of this paper is applicable to the National Standard (CNS) A4 specification (2 〇297297). Page 5 ill shows that you can pull it according to: 1) invention of the back; phantom_ 明明 _β) invention: ## To understand this clearly, the scholar should read the 陂 mark, so as to be correct. _ Item, or · 丨 language should [of the translation _f left to right 4 i must not be 4 4 Explanation /!

A7 B7 4 57 3 2 4 V. Description of the invention (4) Steps · 1 ’Use a magnetic separator to lower and lower the ferrous metal in the crushed garbage. Step 3: Use a vibrating screen to sieve 潠 ψ ^ ^ to free the crushed garbage that meets the fineness requirements. Step 4: Add a certain amount of halogen powder, Shi 1 Λ θ Youyue powder to a fixed amount of water to make a quantitative magnesium gas solution. Step 5: Add equal amounts of modifier powder and a fixed amount of organic degradation agent powder. Add a certain amount of gasification ballast solution to stir to make a quantitative mixed solution. Step 6: Add a fixed amount of magnesium oxide powder and a fixed amount of mixed solution to obtain a certain amount of garbage. Into concrete (environmental floor tiles) bulk material '俾 is used for paving the roadbed. In fact, after step 3: using a magnetic separator to remove the iron metal that crushes the garbage, you can use the crusher to crush the garbage again, and in step 26: after adding a certain amount of magnesium oxide powder and a certain amount of mixed solution, you can The concrete is injected into the mold, and it is made into concrete (environmental floor tiles) with or without pressure. The "method of preparing environmentally-friendly floor tiles" according to the present invention are summarized as follows: 1. The concrete (environment-friendly floor tiles) does not contain excess magnesium ions because the present invention is added with an appropriate amount of modifiers. It can effectively solve the problem that the garbage concrete (environmental-friendly floor tiles) used for the purpose is easy to absorb moisture and return to moisture, which makes the strength of the environmental-friendly floor tiles increase and it is not easy to crack. 2. As the organic substance degrading agent is added in the present invention, the concrete (environmental protection monument) does not contain undegraded organic matter. In this way, the currently used concrete (environmental protection tile) can be used to release poison due to deterioration in use. , Odorous gas, causing environmental pollution problems, so the environmentally friendly place of the present invention > 4 is non-toxic: ξ should be clear that there are reeds according to W ⑴ 硌 Ming Lao.觥 Looking for the name of the iti_item > _ is not allowed. It is stated that the Ministry of Economic Affairs has won the bid rate A. The employee consumer cooperative prints this paper. ) Page 6

57324 A7 B7 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the Invention (5) It also has the advantages of environmental protection. In addition, in the method for manufacturing environmentally friendly floor tiles according to the present invention, the mixed solution composed of the magnesium oxide powder and the vaporized magnesium solution added with the modifier powder and the organic substance degrading agent powder is simultaneously added to garbage with a certain fineness, so there is no existence There are gasification locks, oxidation ballasts, modifiers, and organic matter degradation agents that cause curing problems before they are added. They can be fully mixed with garbage with a certain degree of fineness to make the strength of garbage concrete (environmental floor tiles) higher. The method for preparing the raw materials for the actual test of the present invention is described as follows: [Application Example 1] 1. The raw material formula used to make concrete (environmental-friendly floor tiles) from domestic waste is as follows: Domestic waste: 680Kg magnesium oxide: 190Kg halogen flakes: lI7Kg Cai Que Acid salt, ferrous sulfate 'polymethyl acrylate emulsion and phosphoric acid: 10.4Kg of vitamin B12: 2. 6Kg 2' The method for manufacturing concrete (environmental floor tiles) from the above raw materials is as follows: Step 1: Remove larger metal parts Domestic garbage (mainly kitchen waste, fruit, paper, plastic, crushed wood, earth, fiber, glass, metal, etc.) is crushed by a shredder. Step 2: Use a magnetic separator to remove the ferrous metal from the crushed garbage. Step 3: Use a vibrating screen to screen out garbage with a fineness of 10-3nim and take it; Step 4: Add halogen tablet powder 1 i 7Kg to i 3〇Kg of water, -1-1 ·, 踉 明明明. According to: 1) invention ⑵ invention j3) invention 符 胡 k 明 # ^ 士 间 k Mark Pzhenu sj no; left to 2 must not be right. ¥ This paper rule μ uses Ning Guanjia standard (CNS> A4 is now marked as 297)

457324 Printed by K-Standard Bureau of Consumer Electronics Co., Ltd. Use a magnetic separator to remove ferrous metals from the crushed garbage. Use a crusher to crush the garbage obtained from step 2. Use a vibrating screen to screen out garbage with a fineness of 10-20 mm. The paper size is suitable for Chinese National Su 7 ^ 7 ^: Ding 2 丨 0 > < 2971 ^ > Page 8 A7 B7 V. Description of the invention (6 ) Magnesium chloride solution》 Step five: Add naphthalene sulfonate 'ferrous sulfate, polymethyl acrylate emulsion and phosphoric acid 10.4Kg and vitamin B12-2.6Kg to the magnesium oxide solution obtained from the step to prepare a mixed solution. Step 6: Add 190Kg of oxidized powder and the mixed solution obtained in Step 5 to the garbage obtained in Step 3 and stir well to make concrete (environmental protection monument) bulk material for paving the roadbed. [Application example two] 1. The raw material formula used for making concrete from domestic waste is as follows: Domestic waste: 600Kg magnesium oxide: 250Kg halogen flakes: 130Kg gasified iron and ferrous sulfate, styrene-methyl acrylate copolymer emulsion and copper sulfate: 16Kg Tetrahydrofolate 'Vc and ethylenediaminetetraacetic acid: 4Kg 2. The method for manufacturing concrete (environmental floor tiles) from the above raw materials is as follows: Step 1: Domestic waste (mainly Weiyu, fruit) from which large metal parts have been removed , Paper, plastic, crushed wood, earth and stone, fiber, glass, metal, etc.) pulverized by the crusher β Step 2 Step 3 Step 4 600Kg standby Step 5 'Add ferrous sulfate and halogen tablet powder 130 Kg,' 1: : 矣. .....—— _ _ _ · 457324

A7 B7 V. Explanation of the invention (7) 'Making ferrous sulfate and magnesium vaporized solution in water' Step 6: Put gasified iron and ferrous sulfate, styrene-methyl acrylate copolymer emulsion and copper sulfate 16Kg and tetrahydrofolate, Vc and 4Kg of ethylenediaminetetraacetic acid and the gasified magnesium solution obtained in step 5 were used to prepare a mixed solution. Step 7: Add 250 Kg of magnesium oxide powder and the mixed solution obtained in Step 6 to the garbage obtained in Step 4 and stir well to make a concrete bulk material. Step 8: From the concrete bulk obtained in Step 7, pressurized or non-pressurized concrete (environmental floor tiles) materials, such as: walkway monuments (such as the accompanying one, two, i), road stones or wave blocks ... and many more. [Application example three] 1. The raw material formula used to make concrete from industrial waste is as follows: Household waste: 640Kg magnesium oxide · 220Kg 'halogen tablets: 125Kg. Modifier gasification Ming' polyvinylidene chloride milk and phosphate: 12Kg vitamins B12 'Vc and ethylenediaminetetraacetic acid: 3Kg 2 _ ^ The method of manufacturing concrete (environmental floor tiles) with the above raw materials is as follows: Step one: The industrial waste (mainly slag, fly ash) will be removed from large metal parts. .. etc.) Crush with a shredder. Step 2: Use a magnetic separator to remove iron birds that have been crushed. Step 2. Use a vibrating screen to screen out waste with a fineness of 40-120mm. Take out 640Kg for future use. Step 4: Add 125Kg of tooth powder to 129Kg of water _. _ _. T 槔 Zhangming is relevant; Laco is based on reality; ί · I) Final Ming > Jing • I k) Summary of invention The meaning of ^ is exhausted. It is clear that f is written in '^' after reading, so that it can be compared with the f item, or the translation name of the order should be J], 71 y left to right: ΐ 不 模 H ίExplanation应 j by ▲ Printed by the Consumers' Cooperatives

Dimensions of this paper are suitable _ page 9 45 ^ 324 Printed by Shellfish Consumer Cooperative of Central Sample Rate Bureau of the Ministry of Lijing A7 B7 V. Description of invention (none) Gasification solution. Step 5: Add 12 Kg of sodium chloride, polyvinylidene chloride milk and tank salt, vitamin B12 'Vc, and 3 Kg of ethylenediamine tetraacetic acid to the magnesium oxide solution obtained in step 4 to prepare a mixed solution. Step 6: Add 220 Kg of magnesium oxide powder and the mixed solution obtained in Step 5 to the garbage obtained in Step 3, stir and make a concrete bulk evenly for paving the roadbed or pavement. [Application Example 4] 1. The raw material formula used to make concrete from construction waste is as follows: Construction waste: 635Kg magnesium oxide: 225Kg magnesium sulfate: 125Kg naphthalene sulfonate 'iron oxide' ethyl silicate, styrene-butadiene emulsion and hydrochloric acid: 13Kg Tetrahydrofolate and ethylenediaminetetraacetic acid: 2Kg 2. The method for manufacturing concrete (environmental stele) from the above raw materials is as follows: Step 1: Remove construction waste (mainly broken stele, stone crushed concrete, Waste soil, waste sand, etc.) are pulverized with a pulverizer. Step 2: Use a magnetic separator to remove the ferrous metal from the crushed garbage. Step 2: Use a vibrating screen to screen out garbage with a fineness of 40-120mm. Take out 635Kg for future use. Step 4: Add 125Kg of magnesium sulfate powder to 129Kg of water to make a sulfuric acid solution. Step 5: Add 13Kg of naphthalenesulfonate, gasified iron, ethyl silicate, butyl and hydrochloric acid and 2Kg of tetrahydrofolate and ethylenediaminetetraacetic acid from Γ " Table paper size applies Chinese National Standard (CNS) A4 specifications (2i0x297 Gongchu) '| cutting food can be based on reality. 1) invention' Background-Magic invention outline il ;: b details of the invention =; iik meaning reading and reading J ，, both (as opposed to Bu Zhen, or & Ying Ming i's name; ί film left to right i [Must not be vaguely explained 4

_ ί | 7324 A7 B7 V. Description of invention (9) The mixed solution was prepared from the solution of Lujun Town obtained. Step 6: Add 225Kg of magnesium oxide powder and the mixed solution obtained in Step 5 to the garbage obtained in Step 3 and stir to make a concrete bulk material for paving the roadbed or pavement β Step 7. The concrete obtained from Step 6 Manufacture of concrete (environmental floor tiles) materials in bulk, with or without pressure, for example: trails (such as Annex I, U) 'roadstone, wave block ... To sum up, the "preparation method for environmentally friendly floor tiles" of the present invention does provide many innovative structures and progressive effects. In addition, before the application, the same articles were not found in publications or publicly used. The same patent is approved first, and the patent requirements that meet the novelty are a creation that conforms to the protection granted to the patent right. However, the structural description and drawings disclosed above are only a preferred embodiment of the present invention. Those skilled in the art who are familiar with the present invention may do so based on the structural features or technical ideas of the scope of the present invention. Equivalent design should be included in the scope of patent application of the present invention.

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

This ... Zhang scales Shicaiguan family materials (⑽) A4 specifications (read) (page 11) Vf-> 1 v ϋτ:

Claims (1)

5 4 2 3 ABCD VI. Application scope of patents' 1 ·-A method of making environmentally friendly floor tiles, including garbage, oxidized town, blending agents, water and modifiers, and including organic matter degradation agents, weight percentage of each component For: Garbage: 60 ~ 80%; Magnesium oxide: 19 ~ 25%; Blending agent · '11. 7 ~ 13%; Modifier: 1. 04 ~ 1. 60%; Organic matter degradation agent: 0.26 ~ 0.40%. 2. The method for preparing environmentally friendly floor tiles according to Item 丨 of the patent application park, where the blending agent may be a mixture of toothed tablets, magnesium sulfate, ferrous sulfate and toothed tablets. 3. According to the method for preparing environmentally friendly floor tiles according to item 1 of the scope of the patent application, wherein the modifier may be a water reducing agent, such as a naphthalenesulfonate. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4. According to the method for preparing the environmental stele described in item 1 of the scope of the patent application, where the modifier can be a water-resistant agent, such as inorganic iron salt gasified iron and Ferrous sulfate, inorganic aluminum salt. 5. The method for preparing an environmental stele according to the item [# 1] of the patent application park, wherein the modifier may be a water blocking enhancer, such as a water-soluble or water-emulsion polymer such as styrene- Copolymer emulsion of methyl acrylate, methyl acrylate emulsion, polyvinylidene chloride emulsion, ethyl silicate, styrene-butadiene emulsion # 6. According to the environmental protection floor tile manufacturing method described in the first patent application park, +., Run, method, wherein the modifier can form a non-rollable W 锃 pupil 锃 active substance j ?. pumice stone with the excess _ body produced by the excess halogen tablets, This paper size applies to Chinese National Standard (CNS) A4 specification (2 丨 OX297) 第 12 Yu 457324 A8 B8 C8 D8 Intellectual Property Cooperative of Employees ’Cooperatives of Intellectual Property Bureau of Ministry of Economic Affairs, patent scope of canal acid salt, sulfuric acid steel, hydrochloric acid 7. According to the method for preparing environmental stele described in item 丨 of the scope of the patent application, wherein the organic degradation agent may be a vitamin, for example, b12, Vc, tetrahydrofolate, or a metal chelator, such as ethyl Diamine tetraacetic acid. 8. According to the method for preparing the environmentally friendly floor tile described in the item [Scope of the patent application], the manufacturing steps are as follows: Step 1. Use a pulverizer to pulverize the garbage from which the larger metal parts have been removed to a certain fineness; Step 2 1. Use a magnetic separator to remove the ferrous metal from the crushed garbage. Step 3. Screen the crushed garbage that meets the fineness requirements with a vibrating screen. Step 4. Add a certain amount of halogen flake powder to a certain amount of water to make a certain amount of gasification. Magnesium solution; 'Step 5. Add quantitative modifier powder and quantitative organic degradation agent powder to the added amount of magnesium chloride solution and stir uniformly to make a quantitative mixture. Solution; step six, add a certain amount of magnesium oxide powder and a certain amount of mixed solution to 'to obtain a certain amount of garbage, after mixing evenly, make a concrete bulk material, 俾 for paving the roadbed "9. According to the scope of patent application No. 1 The method and method of environmentally friendly land described in Item 1, in which a magnetic separator is used to remove and pulverize the ferrous metal in the waste | The waste is pulverized again with a pulverizer. 4 According to the environmental protection described in Item 1 of the patent application park, The method of the tombstone (j method, where a certain amount of magnesium oxide powder and a certain amount of mixed solution are melted _ and then injected into the mold with concrete, pressurized or not pressurized. Item 1 belongs to: two items should be settled ^ & items include; L ^ can be used in two items; the item narrator is L item or affiliated; ) A4 Specifications (210X297 Male #) Page 13