TW486427B - Oxygen scavenging compositions with low migration - Google Patents

Oxygen scavenging compositions with low migration Download PDF

Info

Publication number: TW486427B
Authority: TW; Taiwan
Prior art keywords: transition metal; patent application; oxygen; soil; copper
Prior art date: 1995-12-15

Application number

TW85115533A

Other languages

English (en)

Chinese (zh)

Inventor

Cynthia Louise Ebner

Thomas Andrew Blinka

Original Assignee

W R Grace & Amp Co Conn

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-12-15

Filing date

1996-12-16

Publication date

2002-05-11

1996-12-16 Application filed by W R Grace & Amp Co Conn filed Critical W R Grace & Amp Co Conn

2002-05-11 Application granted granted Critical

2002-05-11 Publication of TW486427B publication Critical patent/TW486427B/zh

Links

239000000203 mixture Substances 0.000 title claims abstract description 195
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 97
239000001301 oxygen Substances 0.000 title claims abstract description 97
229910052760 oxygen Inorganic materials 0.000 title claims abstract description 97
230000002000 scavenging effect Effects 0.000 title claims abstract description 18
230000005012 migration Effects 0.000 title description 10
238000013508 migration Methods 0.000 title description 10
239000011159 matrix material Substances 0.000 claims abstract description 54
229940123973 Oxygen scavenger Drugs 0.000 claims abstract description 50
229910052723 transition metal Inorganic materials 0.000 claims abstract description 36
150000003624 transition metals Chemical class 0.000 claims abstract description 30
150000001875 compounds Chemical class 0.000 claims abstract description 23
239000010949 copper Substances 0.000 claims description 136
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 125
239000011668 ascorbic acid Substances 0.000 claims description 65
229910052802 copper Inorganic materials 0.000 claims description 64
235000010323 ascorbic acid Nutrition 0.000 claims description 63
229920000642 polymer Polymers 0.000 claims description 61
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 55
229940072107 ascorbate Drugs 0.000 claims description 50
-1 ascorbate compound Chemical class 0.000 claims description 49
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 49
229910052751 metal Inorganic materials 0.000 claims description 47
239000002184 metal Substances 0.000 claims description 47
239000000126 substance Substances 0.000 claims description 43
150000003623 transition metal compounds Chemical class 0.000 claims description 33
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 26
229920001577 copolymer Polymers 0.000 claims description 20
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Natural products CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
239000003795 chemical substances by application Substances 0.000 claims description 15
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 14
239000005977 Ethylene Substances 0.000 claims description 13
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238000000034 method Methods 0.000 claims description 12
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239000004698 Polyethylene Substances 0.000 claims description 10
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 9
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125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 claims description 6
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MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 4
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239000001648 tannin Substances 0.000 claims description 4
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WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 3
229910052719 titanium Inorganic materials 0.000 claims description 3
239000010936 titanium Substances 0.000 claims description 3
229910052720 vanadium Inorganic materials 0.000 claims description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 2
NJAHGEUFOYIGKR-UHFFFAOYSA-N 2-chloroethanimidamide Chemical compound NC(=N)CCl NJAHGEUFOYIGKR-UHFFFAOYSA-N 0.000 claims description 2
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239000010941 cobalt Substances 0.000 claims 4
229910017052 cobalt Inorganic materials 0.000 claims 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 4
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 4
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KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
239000004215 Carbon black (E152) Substances 0.000 claims 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
239000011651 chromium Substances 0.000 claims 2
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GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 2
PIMKIZUVIMAVSF-UHFFFAOYSA-N 1-(2-phenylethyl)-9h-fluorene Chemical compound C=1C=CC=2C3=CC=CC=C3CC=2C=1CCC1=CC=CC=C1 PIMKIZUVIMAVSF-UHFFFAOYSA-N 0.000 claims 1
YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 claims 1
LNUFLCYMSVYYNW-ZPJMAFJPSA-N [(2r,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6r)-6-[(2r,3r,4s,5r,6r)-6-[(2r,3r,4s,5r,6r)-6-[[(3s,5s,8r,9s,10s,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1h-cyclopenta[a]phenanthren-3-yl]oxy]-4,5-disulfo Chemical compound O([C@@H]1[C@@H](COS(O)(=O)=O)O[C@@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1[C@@H](COS(O)(=O)=O)O[C@@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1[C@@H](COS(O)(=O)=O)O[C@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1C[C@@H]2CC[C@H]3[C@@H]4CC[C@@H]([C@]4(CC[C@@H]3[C@@]2(C)CC1)C)[C@H](C)CCCC(C)C)[C@H]1O[C@H](COS(O)(=O)=O)[C@@H](OS(O)(=O)=O)[C@H](OS(O)(=O)=O)[C@H]1OS(O)(=O)=O LNUFLCYMSVYYNW-ZPJMAFJPSA-N 0.000 claims 1
IPBVNPXQWQGGJP-UHFFFAOYSA-N acetic acid phenyl ester Natural products CC(=O)OC1=CC=CC=C1 IPBVNPXQWQGGJP-UHFFFAOYSA-N 0.000 claims 1
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125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims 1
125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 claims 1
229920003244 diene elastomer Polymers 0.000 claims 1
229960003750 ethyl chloride Drugs 0.000 claims 1
GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 claims 1
150000002736 metal compounds Chemical class 0.000 claims 1
150000002978 peroxides Chemical class 0.000 claims 1
229940049953 phenylacetate Drugs 0.000 claims 1
WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 claims 1
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims 1
229920000098 polyolefin Polymers 0.000 claims 1
238000004806 packaging method and process Methods 0.000 abstract description 20
238000003860 storage Methods 0.000 abstract description 10
239000000463 material Substances 0.000 abstract description 8
239000002689 soil Substances 0.000 description 173
239000003054 catalyst Substances 0.000 description 137
PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 68
235000010378 sodium ascorbate Nutrition 0.000 description 67
PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 67
229960005055 sodium ascorbate Drugs 0.000 description 67
229920001944 Plastisol Polymers 0.000 description 60
239000004999 plastisol Substances 0.000 description 60
229910000366 copper(II) sulfate Inorganic materials 0.000 description 44
SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 33
238000009928 pasteurization Methods 0.000 description 28
150000003839 salts Chemical class 0.000 description 25
OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 21
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FWBOFUGDKHMVPI-UHFFFAOYSA-K dicopper;2-oxidopropane-1,2,3-tricarboxylate Chemical compound [Cu+2].[Cu+2].[O-]C(=O)CC([O-])(C([O-])=O)CC([O-])=O FWBOFUGDKHMVPI-UHFFFAOYSA-K 0.000 description 10
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239000011248 coating agent Substances 0.000 description 9
238000006392 deoxygenation reaction Methods 0.000 description 9
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
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235000010376 calcium ascorbate Nutrition 0.000 description 8
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229940026239 isoascorbic acid Drugs 0.000 description 8
150000000994 L-ascorbates Chemical class 0.000 description 7
229910052782 aluminium Inorganic materials 0.000 description 7
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BLORRZQTHNGFTI-ZZMNMWMASA-L calcium-L-ascorbate Chemical compound [Ca+2].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] BLORRZQTHNGFTI-ZZMNMWMASA-L 0.000 description 7
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150000001879 copper Chemical class 0.000 description 4
CXGHLNDIGXESIH-GRVYQHKQSA-L copper;(9z,12z)-octadeca-9,12-dienoate Chemical compound [Cu+2].CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O.CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O CXGHLNDIGXESIH-GRVYQHKQSA-L 0.000 description 4
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GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
JSPBAVGTJNAVBJ-UHFFFAOYSA-N ethyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCC)OC1=CC=CC=C1 JSPBAVGTJNAVBJ-UHFFFAOYSA-N 0.000 description 1
TWVQGYRLVKAYFL-UHFFFAOYSA-K europium(3+);octadecanoate Chemical compound [Eu+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O TWVQGYRLVKAYFL-UHFFFAOYSA-K 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
VEPSWGHMGZQCIN-UHFFFAOYSA-H ferric oxalate Chemical compound [Fe+3].[Fe+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O VEPSWGHMGZQCIN-UHFFFAOYSA-H 0.000 description 1
KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
239000002657 fibrous material Substances 0.000 description 1
238000009459 flexible packaging Methods 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
235000012041 food component Nutrition 0.000 description 1
239000005417 food ingredient Substances 0.000 description 1
SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
235000011389 fruit/vegetable juice Nutrition 0.000 description 1
LRBQNJMCXXYXIU-QWKBTXIPSA-N gallotannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@H]2[C@@H]([C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-QWKBTXIPSA-N 0.000 description 1
239000003292 glue Substances 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
238000013007 heat curing Methods 0.000 description 1
238000009998 heat setting Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
229910052900 illite Inorganic materials 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
229920000831 ionic polymer Polymers 0.000 description 1
YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
BUJJNPWRTNNUCG-UHFFFAOYSA-L iron(2+);dibenzoate Chemical compound [Fe+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 BUJJNPWRTNNUCG-UHFFFAOYSA-L 0.000 description 1
229910000399 iron(III) phosphate Inorganic materials 0.000 description 1
238000002955 isolation Methods 0.000 description 1
238000002386 leaching Methods 0.000 description 1
230000007774 longterm Effects 0.000 description 1
239000002075 main ingredient Substances 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000012528 membrane Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
239000004570 mortar (masonry) Substances 0.000 description 1
150000002782 muconic acid derivatives Chemical class 0.000 description 1
229940105132 myristate Drugs 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
239000002929 natural lacquer Substances 0.000 description 1
229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
229920001220 nitrocellulos Polymers 0.000 description 1
VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
239000004745 nonwoven fabric Substances 0.000 description 1
BNTPVRGYUHJFHN-UHFFFAOYSA-N oct-2-enedioic acid Chemical compound OC(=O)CCCCC=CC(O)=O BNTPVRGYUHJFHN-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000005416 organic matter Substances 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
238000010525 oxidative degradation reaction Methods 0.000 description 1
229920006280 packaging film Polymers 0.000 description 1
239000012785 packaging film Substances 0.000 description 1
238000012536 packaging technology Methods 0.000 description 1
238000005192 partition Methods 0.000 description 1
230000035515 penetration Effects 0.000 description 1
SCRKTTJILRGIEY-UHFFFAOYSA-N pentanedioic acid;zinc Chemical compound [Zn].OC(=O)CCCC(O)=O SCRKTTJILRGIEY-UHFFFAOYSA-N 0.000 description 1
239000002304 perfume Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
230000035699 permeability Effects 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
229920006254 polymer film Polymers 0.000 description 1
229920005606 polypropylene copolymer Polymers 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000004321 preservation Methods 0.000 description 1
230000008569 process Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
239000010453 quartz Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
229910052706 scandium Inorganic materials 0.000 description 1
235000015170 shellfish Nutrition 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
230000035943 smell Effects 0.000 description 1
NZRSEGYTVSNMCK-UHFFFAOYSA-N sodium;undecyl benzenesulfonate Chemical compound [Na].CCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 NZRSEGYTVSNMCK-UHFFFAOYSA-N 0.000 description 1
235000010199 sorbic acid Nutrition 0.000 description 1
239000004334 sorbic acid Substances 0.000 description 1
229940075582 sorbic acid Drugs 0.000 description 1
WSWCOQWTEOXDQX-MQQKCMAXSA-N sorbic acid group Chemical class C(\C=C\C=C\C)(=O)O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
241000894007 species Species 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
239000000758 substrate Substances 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000013589 supplement Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
235000015523 tannic acid Nutrition 0.000 description 1
229920002258 tannic acid Polymers 0.000 description 1
229940033123 tannic acid Drugs 0.000 description 1
TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
229920001187 thermosetting polymer Polymers 0.000 description 1
229940098465 tincture Drugs 0.000 description 1
229910001428 transition metal ion Inorganic materials 0.000 description 1
YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
230000001960 triggered effect Effects 0.000 description 1
JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
229940005605 valeric acid Drugs 0.000 description 1
229920001866 very low density polyethylene Polymers 0.000 description 1
239000002759 woven fabric Substances 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
229910000859 α-Fe Inorganic materials 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/704—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
- A23B2/708—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
- A23B2/712—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
- A23B2/717—Oxygen absorbent
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1355—Elemental metal containing [e.g., substrate, foil, film, coating, etc.]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Life Sciences & Earth Sciences (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Food Science & Technology (AREA)
Chemical Kinetics & Catalysis (AREA)
Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Packages (AREA)
Compositions Of Macromolecular Compounds (AREA)
Anti-Oxidant Or Stabilizer Compositions (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Gas Separation By Absorption (AREA)
Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Medicinal Preparation (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

TW85115533A 1995-12-15 1996-12-16 Oxygen scavenging compositions with low migration TW486427B (en)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US57333895A	1995-12-15	1995-12-15
US57333595A	1995-12-15	1995-12-15
US57308695A	1995-12-15	1995-12-15
US08/753,990 US6274210B1 (en)	1995-12-15	1996-12-03	Oxygen scavenging compositions with low migration

Publications (1)

Publication Number	Publication Date
TW486427B true TW486427B (en)	2002-05-11

Family

ID=27504901

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW85115533A TW486427B (en)	1995-12-15	1996-12-16	Oxygen scavenging compositions with low migration

Country Status (17)

Country	Link
US (2)	US6274210B1 (de)
EP (1)	EP0898508B1 (de)
JP (1)	JP2002515822A (de)
CN (1)	CN1090223C (de)
AR (1)	AR004385A1 (de)
AT (1)	ATE319768T1 (de)
AU (1)	AU709799B2 (de)
CA (1)	CA2240113C (de)
DE (1)	DE69635904T2 (de)
DK (1)	DK0898508T3 (de)
ES (1)	ES2259183T3 (de)
ID (1)	ID18224A (de)
MX (1)	MX9804077A (de)
MY (1)	MY118034A (de)
NZ (1)	NZ324599A (de)
TW (1)	TW486427B (de)
WO (1)	WO1997022469A1 (de)

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US5977212A (en) *	1997-11-21	1999-11-02	W. R. Grace & Co.-Conn.	Oxygen scavenging compositions

1996
- 1996-12-03 US US08/753,990 patent/US6274210B1/en not_active Expired - Fee Related
- 1996-12-10 DK DK96942911T patent/DK0898508T3/da active
- 1996-12-10 CA CA 2240113 patent/CA2240113C/en not_active Expired - Fee Related
- 1996-12-10 JP JP52285397A patent/JP2002515822A/ja active Pending
- 1996-12-10 AU AU11481/97A patent/AU709799B2/en not_active Ceased
- 1996-12-10 ES ES96942911T patent/ES2259183T3/es not_active Expired - Lifetime
- 1996-12-10 WO PCT/US1996/019430 patent/WO1997022469A1/en not_active Ceased
- 1996-12-10 AT AT96942911T patent/ATE319768T1/de not_active IP Right Cessation
- 1996-12-10 NZ NZ32459996A patent/NZ324599A/xx not_active IP Right Cessation
- 1996-12-10 DE DE1996635904 patent/DE69635904T2/de not_active Expired - Lifetime
- 1996-12-10 EP EP96942911A patent/EP0898508B1/de not_active Expired - Lifetime
- 1996-12-10 CN CN96199056A patent/CN1090223C/zh not_active Expired - Fee Related
- 1996-12-13 AR ARP960105682 patent/AR004385A1/es unknown
- 1996-12-13 MY MYPI96005257A patent/MY118034A/en unknown
- 1996-12-16 TW TW85115533A patent/TW486427B/zh active
- 1996-12-16 ID ID963738A patent/ID18224A/id unknown
1998
- 1998-05-22 MX MX9804077A patent/MX9804077A/es not_active IP Right Cessation
- 1998-10-30 US US09/183,239 patent/US6228284B1/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
US6274210B1 (en)	2001-08-14
NZ324599A (en)	1999-11-29
EP0898508B1 (de)	2006-03-08
ES2259183T3 (es)	2006-09-16
EP0898508A4 (de)	2000-02-23
MX9804077A (es)	1998-09-30
CA2240113A1 (en)	1997-06-26
EP0898508A1 (de)	1999-03-03
HK1017638A1 (en)	1999-11-26
DK0898508T3 (da)	2006-07-10
CN1204279A (zh)	1999-01-06
CA2240113C (en)	2005-06-14
DE69635904T2 (de)	2006-10-19
AU709799B2 (en)	1999-09-09
AU1148197A (en)	1997-07-14
ATE319768T1 (de)	2006-03-15
DE69635904D1 (de)	2006-05-04
JP2002515822A (ja)	2002-05-28
ID18224A (id)	1998-03-19
WO1997022469A1 (en)	1997-06-26
US6228284B1 (en)	2001-05-08
MY118034A (en)	2004-08-30
AR004385A1 (es)	1998-11-04
CN1090223C (zh)	2002-09-04

Legal Events

Date	Code	Title	Description
2002-08-26	GD4A	Issue of patent certificate for granted invention patent

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