TW486501B - Propylenic composition, preparation thereof, polypropylenic composition and molded article - Google Patents

Propylenic composition, preparation thereof, polypropylenic composition and molded article Download PDF

Info

Publication number
TW486501B
TW486501B TW85114348A TW85114348A TW486501B TW 486501 B TW486501 B TW 486501B TW 85114348 A TW85114348 A TW 85114348A TW 85114348 A TW85114348 A TW 85114348A TW 486501 B TW486501 B TW 486501B
Authority
TW
Taiwan
Prior art keywords
propylene
based composition
scope
polypropylene
weight
Prior art date
Application number
TW85114348A
Other languages
Chinese (zh)
Inventor
Chikashi Okayama
Takanori Nakashima
Masami Kimura
Mayumi Wakata
Kazuhiro Kimura
Original Assignee
Chisso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chisso Corp filed Critical Chisso Corp
Application granted granted Critical
Publication of TW486501B publication Critical patent/TW486501B/en

Links

Landscapes

  • Compositions Of Macromolecular Compounds (AREA)

Abstract

This invention provides a polypropylenic composition for obtaining various molded articles having an excellent molding property, molding shrinkage, rigidity, softness, impact resistance, particularly impact resistance in low temperature, transparency, lustre, anti-whitening, and balance of these properties; and various molded article having these properties; a useful propylenic composition as a base resin of said polypropylenic composition and preparation thereof. Propylenic composition characterized by comprising propylene homopolymer and propylene-ethylene copolymer, the intrinsic viscosity of copolymer ([η]RC) is 1.7-2.8 dl/g; the intrinsic viscosity ratio of homopolymer to copolymer ([η]RC/[η]PP) is 0.7-1.2; and the product of the weight ratio of homopolymer to copolymer (WPP/WRC) by the intrinsic viscosity ratio thereof (WPP/WRC) x ([η]RC/[η]pp) is 1.0-3.0.

Description

486501 A7 ____B7_ 五、發明説明（1 ) 链明夕抟銜節蟪 本發明係鼷於丙烯系組成物，尤指丙烯均聚物和丙烯 -乙烯共聚物構成之組成物，·及其製法，堪有Μ此姐成 物為主成份之聚丙烯系組成物，及此等組成物製成之成 型品、尤指射出成型品、壓出片材、膜、和中空成型品。 技術背.景__ 聚丙烯樹脂較廉價，具有優秀的諸項特性，故今天使 用於各種成型品，例如片狀、容器、栓等，Μ及具有鉸 件構造的射出成型品、膜材、風管等中空成型品多種範 疇。膜材以其機槭性、光學性、熱性、而廣用做食品、 纖維製品等包裝材料。 而分別因應成型用途所需特性，使用丙烯均聚物，、丙 烯和α-烯烴，尤其是和乙烯的共聚物，Μ及丙烯均聚 物和丙烯-cT-烯烴的共聚物的組成物為主成份之聚丙烯 系組成物。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 一般丙烯均聚物具有高度剛性、耐熱性優良、柔軟性 不足、附衝擊性，尤其是低溫耐衝擊性，Μ及薄膜時的 撕裂強度劣。丙烯- ot-烯烴共聚物的透明性、柔軟性優 良，但耐熱性、低溫附衝擊性劣。又因已知組成物的酎 熱性和低溫耐衝擊性優良，開始廣用於汽車、家電範噶 的各種產業，惟透明性、光澤較均聚物劣、成型收縮率 與均聚物同樣大。另方面，撕裂強度和柔軟性較共聚物 劣。就衝擊或折曲引起的白化現象加Κ觀察，抗白化性 均不足。 一3 - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 486501 A7 B7 五、發明説明（2 ) 為改善此等不充分的諸特性，有聚合物、共聚物或姐 成物諸特性改變方法，Μ及利用添加劑之方法。 例如一般方法，是採用充填滑粉等無機物Μ改善姐成 物的成型收縮率，惟為了提高成型收縮率，必須添加大 量的滑粉等無機物，而大為增加成型品之重量，並使外 親顯著惡化。另方面，可採取降低組成物中的共聚物內 之乙烯含量，Μ提高透明性或光澤，可是一般期望降低 共聚物中的乙烯含量Μ提高光澤，會降低低溫耐衝擊性 和剛性。 特開昭60-28411號公報揭示高剛性乙烯-丙烯共聚物 ，即丙烯系姐成物之製法，係將乙烯_丙烯共聚物分成 三階段，分別改變乙烯含量而逐次共聚合。此方法所得 姐成物，不但具有高剛性，尚具有優良的耐白化性、耐 衝擊性、耐熱性等，惟成型品之透明性、光澤、外観、 成型時的成型收縮率等，仍有待改善。 特公平7-30 1 45號公報揭示一種丙烯嵌段共聚物，即 丙烯条組成物，係用結晶性聚丙烯部和乙烯-丙烯無規 共聚合嵌段而得，结晶性聚丙烯成份含量55〜95重量％ 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) ,兩成份的極限黏度比（[π ]Ep / U ]ρρ )為〇 . 5〜2 · 0 , 且乙烯-丙烯無規共聚物嵌段的玻璃化溫度在-30它Μ 下。此姐成物與乙烯-丙烯共聚物成份含量，以及與丙 烯均聚物的共聚合成份之極限黏度比，在大約同樣範圍 ，而具有優良的耐衝擊性、剛性等機械特性，惟成型品 的透明性、光澤、外觀等，尤其是成型品的抗白化性， 一 4- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（5 ) K及成型時的成型收縮率，仍有待改善。 特開平6-9306 1號公報倡議一種聚丙烯嵌段共聚物， 係將丙烯為主的聚合物按全聚合量的60〜80重量X聚合 ,再將乙烯含量20〜50重量：《的乙烯-丙烯共聚合部加 W聚合所得嵌段共聚物，將乙烯-丙烯共聚合部的極限 黏度（U]b)在2.0dl/gK上，而兩成份的極限黏度比 ([n]B/U]A)在1·8 Μ下的嵌段共聚物融混而成。 此組成物的乙烯-丙烯共聚合成份含量Μ及與丙烯均聚 物的共聚合成份之極限黏度比，亦在大約同樣範圍，雖 具有優良的低溫附衝擊性、耐封閉性、外觀等，惟剛性 等機槭特性、或成型時的成型收縮率方面均有待改善。 特開平6-328640號公報倡議一種多曆膜，在直鐽狀低 密度聚乙烯層的兩面積層Κ聚丙烯系樹脂，大幅改善撕 裂強度。在此多層膜中，積層的低密度聚乙烯與聚丙烯 系樹脂之相容性不太好，要用融再製膜時，容易發生魚 眼。 特開昭52- 1 26450號公報揭示三成份混合物，包括乙 烯-α-烯烴共聚物橡膠、聚丙烯或高密度聚乙烯，Κ及 鐽烷烴油或環烷油。此混合物的柔軟性優良，惟耐熱性 則降低〇 特開平4-282232號公報擬議一種樹脂性管狀體，係將 硬質聚烯烴糸樹脂所形成剛性部，與熱塑性彈料所形成 撓性部加Μ連接。此管狀體的剛性部與撓性部黏接強度 不足。 -5 一 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） 486501 A7 B7 五、發明説明（4 搿琨夕目的 本發明之目的，在於提供一種丙烯糸組成物及其製法 ，適用做聚丙烯系組成物之基質樹脂，各種成型品的附 衝擊性，尤其是低溫耐衝擊性、剛性、折裂強度、耐熱 性、透明性、光澤、抗白化性等諸特性，及其成型時的 成型收縮率均優，且其間之平衡性亦優。 本發明另一目的，在於提供一種聚丙烯組成物，以 上述丙烯系組成物為基質樹脂。 本發明又一目的，在於提供使用上述聚丙烯系組成物 之各種成型品及其製法。 發明之細；要 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 本發明人等為達成上述目的，進行潛心研究結果.，發 琨在使用大粒徑含鈦固體觸媒成份的立體規則性觸媒存 在下，將丙烯單獨，再將丙烯和乙烯混合物連縝性氣相 聚合，所得丙烯均聚物和丙烯-乙烯共聚物構成之丙烯 系組成物，其丙烯-乙烯共聚物的極限黏度，兩成份的 極限黏度比，Μ及此極限黏度比與兩成份重量比之乘積 ,在一定範圍時，耐衝擊性，尤指低溫耐衝擊性、剛性 、透明性、光澤、抗白化性、成型時的成型收縮率等， 及其間的平衡性均優，而完成本發明。 本發明丙烯系組成物U),係由聚丙烯（ΡΡ)和丙烯-乙烯共聚物（RC)構成，其特徵為，丙烯-乙烯共聚物（RC) 的極限黏度（[n]RG)為1.7〜2.8dl/g;丙烯-乙烯共聚 物（RC)與丙烯均聚物（PP)之極限黏度比（[η ]Re / [ η ]pp -6 一 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 __^_B7_^_五、發明説明（5 ) 為0, 7〜1.2;且丙烯均聚物（PP)與丙烯-乙烯共聚物（RC) 之重量比（Wpp/ &gt;與其極限黏度比（[r? ]^ / [ r?]) Π KC RC pp 之乘積（[r? ]RC / U ]pp ) x (·νρρ / WRC)在 1 · 0〜3 · 0範圍 者。 另一發明為前述丙烯系組成物（A)之製法，其特徵為 ，包括第一聚合步驟，即在平均粒徑為25〜300以a的含 钛固體觸媒成份（a),通式A1R 1 (式中R1為 瓜 5-m C 1 - 2〇烴基，Χ為鹵素原子，ia為3^n&gt;1.5之正數） 所示有機鋁化合物（b);和通式R2xR3YSi(0R4)z (式中R2和R4為烴基，R3為烴基或含雜原子之烴基， X , Y , Z 為 0SXS2, 1SYS3, IS ZS 3,且 X + Y + Z = 4) 所示有機矽化合物U);所組成立體規則性觸媒存在下 ，於氣相中將丙烯單獨聚合，Κ生成全重量的78-60重 量》!之丙烯均聚量（PP);接著第二聚合步驟，將乙烯和 丙烯共聚合，聚合物中乙烯單元含量為25〜55重量S；的 丙烯-乙烯共聚物（RC),生成全重量的22〜40重量S!者。 又一發明為聚丙烯糸組成物（C) , Κ前述丙烯系組成 物（Α)為主成份，含有視需要添加之添加劑。 再一發明為使用此聚丙烯系組成物之成型品（D),尤 指射出成型品、片材、膜材，及中空成型品。 搿明夕管觖形鮪 在本發明丙烯系組成物（Α)中，丙烯均聚物（ΡΡ)係等 規五價物分率（Ρ) 0.95Μ上，而以0.955以上為佳之高 结晶性，即具有立體規則性的聚丙烯，丙烯均聚物（ΡΡ) -7- (請先閲讀背面之注意事項再填寫本頁) 本纸張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（6 ) 的等規五價物分率（P),影響成型品（D)的剛性、附熱 性等機槭特性，其值愈大，剛性和耐熱性愈大。 另方面，丙烯-乙烯共聚物·（!?(：）係K丙烯-乙烯共聚物 (RC)簠量為基準，含25〜55重量χ ,最好30〜55重量ίϋ 乙烯聚合單元之乙烯-丙烯無規共聚物。丙烯-乙烯共聚 物（RC)中的乙烯聚合單元影響成型品（D)的剛性、柔軟 性、耐衝擊性，尤指低溫酎衝擊性，和抗白化性，大到 可提高柔軟性和酎衝擊性，惟太大時，會影響丙烯-乙 烯共聚物（RC)於丙烯均聚物（ΡΡ)之分散性，使成型品 (D)的透明性、光澤、抗白化性等降低。 再者，丙烯-乙烯共聚物（RC)在135υ#滿中測得極限 黏度（[T7]R(3)在1.7〜2.8dl/g範圍，且與丙烯均聚物 (PP)在同一條件測得極限黏度（[π ]%)間之極限黏度比 ([π ]只υ / [ π ]pp )為 〇·7 〜1·2, K0.8 〜1.2 範圍為佳。 由於丙烯-乙烯共聚物（RC)的極限黏度（[π ]RCJ )無法 直接測定，係由可直接測定的丙烯均聚物（PP)的極限黏 度（[η ]pp ),和丙烯备組成物（A)全體的極限黏度 ([nlwHOM；),以及丙烯-乙烯共聚物（RC)的重量χ (ΐισ ) ，按下式求得： [77 ] RC = ( [ n ] WHOLE -（卜％。/100^77 ]ΡΡ ) / ( tfRC / 1 0 0 ) 丙烯-乙烯共聚物（RC)的極限黏度（[77]RC!),影響聚 丙烯糸組成物（C)的成型循環性，製造膜材時的製膜性 ，和成型品（D)之剛性、附熱性等機械特性，丙烯-乙 烯共聚物（RC)和丙烯均聚物（PP)的極限黏度比（U ]aQ -8- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 486501 A7 B7 五、發明説明（7 ) /[r?]pp),影響丙烯-乙烯共聚物（RC)於丙烯均聚物 (PP)的分散性。丙烯-乙烯共聚物（RC)的極限黏度 ([n ]Ra)愈大，愈能改善成型品（D)的機械特性，但聚 丙烯系組成物（C)的成型循環性降低，即使與丙烯均聚 物（PP)的極限黏度比（[n ]Re / [ 77 ]pi&gt; )太大或太小，成 型品（D)在低溫的耐衝擊性和抗白化性仍不足。且太小 時，成型品（D)的柔軟性不足，太大時，聚丙烯条組成 物（C)的成型收縮率和成型品（D)的透明性改善效果降 低，未能達成目的特性。 丙烯-乙烯共聚物（RC)M丙烯-乙烯共聚物（RC)重量為 基準，含80重量》： Μ上，M85重量為佳之201C二甲苯可 溶物。丙烯-乙烯共聚物（RC)的20Ό二甲苯可溶物重量S； (cxsRa)並非直接測定，而是由丙烯均聚物（ΡΡ)的2〇υ 二甲苯可溶物重量％ (CXSpp),和組成物（Α&gt;全體的20¾ 二甲苯可溶物重量3： (CXS^mjj), K及丙烯-乙烯共聚 物（RC)之重量％ (WRe),按下式求出： CXSRC = {CXSra〇LE-(l-WRC/ 100)CXSpp}/ (WRC/ 100) 經濟部中央標準局貝工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 在本發明丙烯系組成物（A)中，丙烯均聚物（PP)對丙 烯-乙烯共聚物（RC)之重量比（Wpp / ,與前逑二成 份極限黏度比（[π ]βσ / [ 77 )之乘積，（[n ]RC / [r? ]pp ) x (Wp;p / W RC),在 1 · 0 x 3 · 0範圍。 二成份重量比與極限黏度比之乘積，係表示聚丙烯系 組成物（C)成型收縮率之指標。其值小者，成型收縮率 Μ及成型品（D)抗拉強度和熔接強度有所改善，但成型 -9- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 __B7_五、發明説明（8 ) 品（D)的耐熱性或剛性降低會加大，另方面，其值大者 ,抗白化性降低，其標的成型收縮率和抗拉強度及熔接 強度，難求改善。 _ 丙烯系組成物（A)的具體組成，Μ組成物（A)的重量 基準，丙烯-乙烯共聚物（RC)為22〜40重量, Κ25〜 40重量X為佳。 又，丙烯条姐成物（Α)具有Q值（Mw/Mn )在5 Μ下 ，最好4.5 Κ下的狹小分散性分子量分佈。分子量分佈 幅度大者，成型品（D)的光澤和熔接強度會降低。 本發明丙烯系組成物（Α)由於可滿足上述諸項特性， 適用做聚丙烯系組成物（C)的基質樹脂，所製成的成型 品，成型時的成型收縮率、製膜性，Κ及成型品的透明 性、光澤、剛性、柔軟性、耐衝擊性，尤指低溫耐衝擊 性、抗拉強度、熔接強度等機械特性，及其間的平衡性 均優。 本發明丙烯系.組成物（Α),只要能符合上述諸特性， 可用任何方法製造。例如將分別製造的丙烯均聚物（ΡΡ) 和丙烯-乙烯共聚物（RC),使用混合裝置混合製成，惟 採用本發明製法製造更好。 本發明丙烯系組成物（Α)之製法特徵為，在大粒徑含 鈦固體觸媒（a)、有機鋁化合物（b)和有機矽化合物U) 構成的立體規則性觸媒存在下，於氣相中第一階段製造 /V 丙烯均聚物（第一聚合步驟），接著在第二階段製造丙 烯-乙烯共聚物（第二聚合步驟）。 一 10 - (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 486501 A7 ________ΪΒ7 五、發明説明（9 ) 本發明製法中，含钛固體觸媒成份（a)已知使用在鎂 化合物、氧化矽化合物、氧化鋁等無機載體，或聚苯乙 烯等有機載體上，承載鈦化合物者，和必要時，令醚類 、酯類之電子給予體化合物對此承載物反應所得者。 例如有噴鎂化合物之醇溶液，將固體成份部份乾燥， 然後Μ鹵化鈦和電子給予體化合物處理乾燥固體成份， 而得含钛固體觸媒成份（特開平3-1 1 9003號公報），&gt;乂及 令鎂化合物溶於四氫呋喃/醇/電子給予體，KTiCl4 單獨或與電子給予體化合物組合析出的鎂單體，利用鹵 化鈦和電子給予體化合物處理，而得含钛固體觸媒成份 (特開平4-103604號公報）。 含鈦固體觸媒成份（a)使用平均粒徑為25〜300 &amp; in, 以30〜15G#in為佳。含鈦觸媒成份的平均粒徑在25 aroM下時，所製造丙烯糸組成物（A)的粉末流動性明 顯受損，因附著於聚合器的器壁或攪拌葉Μ等而污染聚 合系內，而且難以輸送從聚合器排出的粉末等，對安定 操作大有妨礙。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 另外，含鈦觸媒成份（a )在常態分佈的均勻度以 2.0 K下為佳。均勻度超過2時，丙烯系組成物（A)的 粉末流動性會惡化，難Μ將第一聚合步驟和第二聚合步 驟連續安定操作。 有機鋁化合物（b)可用通式1R Xq 所示有機鋁化合 m i-m 物，式中RigCi -20烴基，X為鹵素原子，m為32 m&gt; 1.5的正數。 -11- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（10)。 具體例有三甲基鋁，三乙基·鋁，三正丙基鋁，三正丁 基鋁，三異丁基鋰，二甲基氯化鋁，二乙基氯化鋁，甲 基三氯化二鋁，二正丙基單氯化鋁，乙基三氯化二鋁， 乙基二氯化鋁，二乙基碘化鋁，乙氧基二乙基鋁等，K 三乙基鋁為佳。 此等有機鋁化合物可用一種單獨或二種以上混合物。 有機矽化合物（C)可用通式R2 R3 Si(0R4) 所示 Λ. JL 2f 有機矽化合物，其中R2和R4為烴基，R3為烴基或含 雜原子的烴基，X , Y和Z為0蠤X蠤2, 1SYS3, 1蠤Z έ 3,且 X + Y + Z = 4。 具體例有甲基三甲氧基矽烷，乙基三甲氧基矽烷，正 丙基三甲氧基矽烷，苯基甲基二甲氧基矽烷，特丁基三 甲氧基矽烷，特丁基三乙氧基矽烷，苯基三乙氧基矽烷 •，甲基乙基二甲氧基矽烷，甲基苯基二乙氧基矽烷，二 甲基二甲氧基矽烷，二甲基二乙氧基矽烷，二異丙基二 甲氧基矽烷，二異丁基二甲氧基矽烷，二特丁基二甲氧 基矽烷，二苯基二甲氧基矽烷，三甲基甲氧基矽烷，環 己基甲基二甲氧基矽烷，三甲基乙氧基矽烷等，而Μ二 異丁基二甲氧基矽烷，二異丙基二甲氧基矽烷，二特丁 基二甲氧基矽烷，環己基甲基甲氧基矽烷，和二苯基二 甲氧基矽烷為佳。 此等有機矽化合物可用單獨一種，或Μ二種Μ上混合 物使用。 本發明丙烯系組成物（A)的製法，宜採用預活化處理 -12 - (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 486501 A7 B7 五、發明説明（11 ) ，即在第一聚合步驟的丙烯單獨聚合之前，令含钛固體 觸媒成份U),在有機鋁化合物（b’）和必要時有機矽化 合物（C’）存在下，將α-烯烴·預先反應。 在含鈦固體觸媒成份（a)的預活化處理中，有機鋁化 合物（b’）的使用量沒有特別限制，惟通常相對於含钛固 體觸媒成份中的钛原子1莫耳，使用0. 1〜40莫耳，K 0.3〜20莫耳範圍為佳，令a-烯烴在10〜80¾經10分鐘 至48小時，相對於含鈦固體觸媒成份1克，K0.1〜100 克，最好0. 5〜50克反應。 在預活化處理中，預先使用有矽烷化合物（c’），相對 於有機鋁化合物1莫耳，使用0.01〜10莫耳，K0.05〜 5莫耳範圍為佳。 上述預活化處理所用有機鋁（bl,有聚合時所用前例 所示有機鋁（b)。此（B ’）有機鋁化合物（b f ),與聚合所 用有機鋁化合物（b)同種或不同種均可用，而K三乙基 鋁為佳。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 預活化處理時視需要所用的有機矽化合物U’），有與 前述列舉有機矽化合物（c)同種者。此有機矽化合物 ((^)則與聚合所用有機矽化合物U)同種或不同種均可 。以使用二異丁基二甲氧基矽烷，二異丙基二甲氧基矽 烷，二特丁基二甲氧基矽烷，環己基甲基二甲氧基矽烷 ，和二苯基二甲氧基砂燒為佳。 •含钦固體觸媒成份U)預活化處理所用烯烴，有乙烯 ，丙烯，1-丁烯，1-戊烯，1-己烯，1-辛烯，1-癸烯， 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 486501 A7 B7 五、發明説明（l2 ) 1-十二碳烯，1-十四碳烯，1-十六碳烯，1-十八碳烯， 1-二十碳烯，4-甲基-1-戊烯，3-甲基-1-戊讎等。此等 烯烴不但單用，遷可與其他烯烴一種或二種K上混用。 聚合時可併用氫等分子量調節劑，Μ調節聚合物分子量。 含鈦固體觸媒成份U)預活化處理所用惰性溶劑，有 對己烷，庚烷，辛烷，癸烷，十二烷，與流動性鐽烷烴 等液狀飽和烴，或具有二甲基聚矽氧烷構造之矽光油等 聚合反應無顯著影響的惰性溶劑。此等惰性溶劑可為一 t 種單獨溶劑，或二種以上的混合溶劑。 此等惰性溶劑使用時，宜除去對聚合有不良影響的水 份、硫化合物等雜質後才用。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 本發明丙烯系組成物（A)製法中，是在上述預活化處 理所得含钛固體觸媒成份U)存在下，在氣相中將丙烯 聚合，K生成丙烯均聚物（PP)的第一聚合步驟，接著將 乙烯和丙烯共聚合，K生成丙烯-乙烯共聚物（RC)的第 二聚合步驟，加Μ連績實施。第一聚合步驟不限在氣相 聚合，亦可採用漿液聚合或塊狀聚合，惟接縝的第二聚 合步驟Μ氣相聚合為佳，故第一聚合步驟亦採用氣相聚 合為佳。第二聚合步驟採用漿液聚合或塊狀聚時，丙烯 -乙烯共聚物（RC)會從溶液中溶出，難Κ繼縯安定操作。 丙烯均聚物（ΡΡ)的聚合條件因聚合形式而異，Μ氣相 聚合法而言，在一定量粉末的混合搜拌中，在預活化處 理的含钛固體觸媒成份U),有機鋁成份（b)和有機矽 化合物（c)組成的立體規則性觸媒存在下，K聚合溫度 -14- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 486501 A7 B7 五、發明説明（15 ) 20〜120*0，最好40〜100C,聚合壓力在大氣壓〜9.9 MPa,最好0.59〜5.OMPa條件，供應丙烯加Μ聚合，生 成丙烯均聚物（Α)。有機鋁化合物（b)和含钛固體觸媒 成份（a)使用率為Al/Ti=l〜500(莫耳比），M10〜300 為佳。在此情況，含鈦固體觸媒成份U)的莫耳數，係 指實質上含钛固體觸媒成份U)中的鈦克原子數。 有機矽化合物（c)和有機鋁化合物（b)的使用率為 b/c =1〜1〇(莫耳比），以ι·5〜8為佳。 b/c莫耳過大時，丙烯均聚物（P P)的结晶性降低，則 成型品（D)的剛性不足。另外，b/c莫耳比過小時，聚 合活性明顯降低，生產性下降。 丙烯均聚物（PP)的分子量調節，可在聚合時使用氫等 分子量調節劑實施，使丙烯均聚物（PP)的極限黏度符合 本發明的要件。在丙烯均聚物（PP)聚合後，取出所生成 粉末的一部份，提供極限黏度（[η Ipp),熔體流量 (MFR pp) , 20 1C二甲苯可溶物份量和等規分率（P)的測 定，Μ及觸媒每單位重量的聚合產量。 / 經濟部中央標準局員工消費合作社印裝 (請先閱讀背面之注意事項再填寫本頁) 第一聚合步驟的丙烯單獨聚合後，接著實施第二聚合 步驟，即在聚合溫度20〜120¾，最好40〜100C，聚合 壓力在大氣壓〜9.9MPa, Μ0·59〜5.0MPa的條件下，將 乙烯和丙烯的混合單體加Μ共聚合，Μ生成丙烯-乙烯 共聚物（RC)。丙烯-乙烯共聚物（RC)中的乙烯單位含量 ，可控制共聚物氣體中乙烯單體與丙烯單體的氣體莫耳 比，調節成丙烯-乙烯共聚物（RC)中的乙烯單位含量為 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 486501 A7 B7 五、發明説明（14 ) 25〜55重量S!。 另方面，與丙烯均聚物（PP)重量相對比，丙烯-乙烯 共聚物（RC)的重量，使用聚合時間的調節，或一氧化碳 、硫化氫等觸媒的聚合活性調節劑，調節至丙烯-乙烯 共聚物（RC)重量為22〜40重量。再者，丙烯-乙烯共 聚物（RC)的分子量，係在丙烯-乙烯共聚物聚合時，調 節氫等分子量調節劑，使丙烯-乙烯共聚物（RC)的極限 黏度符合丙烯系組成物（A)的要件。另外，氫的供應方 法是供應到丙烯系組成物（A)的Q值（Mw / Mn ),符合 丙烯系組成物（A )的要件。 聚合方式可K採用分批式，反連續式或連績式，工業 上K連續式聚合為佳。 第二聚合步驟完成後，從聚合系除去單體，即可得粒 狀聚合物。所得聚合物可供測量極限黏度（[η ] ), 20C二甲苯可溶物份量，Q值（Mw/Mn )和乙烯含量， • Μ及觸媒每單位重量的聚合產量。 本發明聚丙烯系組成物（C),係採用前述丙烯系組成 物（Α)為基質樹脂，視成型品的要求特性和成型方法， 混配相對應所需添加成份所得組成物。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 本發明聚丙烯系組成物（C)通常所用添加劑，可為聚 烯烴組成物之一般性各種添加劑，例如抗氧化劑，例如 酚系、硫醚糸、磷系抗氧化劑等；分散劑或中和劑，有 例如硬脂酸鈣等高级脂肪酸鹽類（金屬肥皂類）等；光安 定劑；聚金屬鈍化劑（銅害防止劑）；透明化劑；/3晶核 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 486501 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（15 ) 劑；潤滑劑，例如硬脂酸醯胺等；抗靜電劑，例如單硬 脂酸甘油酯等脂肪酸酯類等；防霧劑；無滴劑；難燃劑 ;難燃助劑；顔料；鹵素捕集劑；有機系或無機系抗菌 劑；無機充填劑和封阻防止劑，例如滑粉，雲母、黏土 、矽灰石、沸石、高嶺土、皂土、珠光體、砂藻土、石 棉、碳酸鈣，碳酸鎂、氫氧化鋁、氫氧化鎂、水合滑石 、鹸性羥基碳酸鋁鋰水合物、二氧化矽、二氧化钛、氧 化鋅、氧化鎂、氧化鈣、氧化鋅、硫酸鋇、硫酸鎂、矽 酸鈣、矽酸鋁、玻璃纖維、鈦酸鉀、碳纖、碳黑、石墨 和金屬纖維等，偶合劑，例如矽烷系、鈦酸鹽糸、硼系 、鋁酸鹽系、鋁酸IS糸等，及K此表面處理過的無機充 填劑或有機充填劑，例如木粉、紙漿、舊紙、合成纖維 、天然纖維等，通常含量K不損本發明目的為度。 一般而言，於聚丙烯糸組成物（C)添加硬脂酸鈣，做 為酚系抗氧化劑和/或磷酸系抗氧化劑K及中和劑（分 散劑）。 於本發明的前述聚烯烴做為一般添加劑混配的聚丙烯 条組成物（C),適用原狀射出成型用聚丙烯系組成物 (Ci)、片材成型用聚丙烯糸組成物（Cs),和膜成型用聚 丙烯糸組成物（Cf)。 又，在上述聚丙烯系組成物（Ci)中，相對於丙烯系組 成物（A) 100重量份，混配〇(晶核劑〇.〇〇〇1〜1重量份， M0.001〜0.8重量份為佳，可進一步提高射出成型品的 剛性和低溫耐衝擊性。 -17- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 B7 五、發明説明（l6 ) ot晶核劑有滑粉、明礬、氧化矽、氧化鈦、氧化鈣、 氧化鎂、碳黑、黏土礦物等無機化合物；丙二酸、丁二， / 酸、己二酸、馬來酸、壬二酸、癸二酸、十二烷二酸、 檸檬酸、丁三酸、丁四酸、環烷酸、環戊烷羧酸、1-甲 基環戊烷羧酸、2 -甲基環戊烷羧酸、環己烷後酸、1-甲 基環己烷羧酸、4-甲基環己烷羧酸、3,5-二甲基環己烷 羧酸、4-丁基環己烷羧酸、4-辛基環己烷羧酸、4-環己 烷-1,2-二羧酸、苯甲酸、苯乙酸、二甲苯酸、乙基苯 甲酸、4-特丁基苯甲酸、水楊酸、苯二甲酸、苯偏三酸 、苯均四酸等脂肪族單羧酸以外的羧酸；前述非脂肪酸 單羧酸之鋰、鈉、鉀、鎂、鈣、緦、鋇、鋅、鋁等正鹽 或鹼性鹼；1·2,3·4-二苄叉山梨糖醇、1,3-苄叉-2· 4-對甲基苄叉山梨糖醇、1,3-苄叉-2· 4-對乙基午叉山梨 糖醇、1,3-對甲基苄叉-2· 4-苄叉山梨糖醇、1,3-對乙 基苄叉-2· 4-苄叉山梨糖醇、1,3-對乙基苄叉-2· 4-對 甲基苄叉山梨糖醇、1·3, 2· 4-雙（對甲基苄叉）山梨糖 醇、1· 3,2· 4-(對乙基苄叉）山梨糖醇、1· 3,2· 4-雙 (對正丙基苄叉）山梨糖醇、1· 3,2· 4-雙（對異丙基苄叉） 山梨糖醇、1· 3,2· 4-雙（對正丁基苄叉）山梨糖醇、 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 1· 3,2· 4-雙（對次丁基苄叉）山梨糖醇、1· 3,2· 4-雙 (對特丁基苄叉）山梨糖醇、1· 3-(2’· 4f-二甲基苄叉） - 2· 4-苄叉山梨糖醇、1· 3-苄叉-2· 4-(2，· 4·-二甲 基苄叉）山梨糖醇、1· 3,2· 4-雙（2’· 4二甲基苄叉） 山梨糖醇、1· 3,2· 4 -雙（3*· 4’-二甲基苄叉）山梨糖 -18 一 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 _ B7五、發明説明（Η) 醇、1· 3,2· 4-雙（對甲氧基苄叉）山梨糖醇、1· 3,2· 4-(對乙氧基苄叉）山梨糖醇、1· 3-苄叉-2· 4-對氯苄 叉山梨糖醇、1· 3-對氯苄叉一2· 4-苄叉山梨糖醇、1· 3- 對氯苄叉_2 · 4-對甲基苄叉山梨糖醇、1· 3-對氯苄 叉-2 · 4-對乙基苄叉山梨糖醇、1· 3-對甲基苄叉-2 · 4- 對氯苄叉山梨糖醇、和1· 3,2· 4-雙（對氯苄叉）山梨 糖醇等二苄叉山梨糖醇系化合物；雙（4-特丁基苯基）磷 酸鋰、雙（4-特丁基苯基）磷酸納、雙（4-特祜基苯基）磷 酸鋰、雙（4-特祜基苯基）磷酸納、雙（4-特丁基苯基）磷 酸鉀、單（4_特丁基苯基）磷酸鈣、雙（4-特丁基苯基）磷 酸鈣、單（4-特丁基苯基）磷酸鎂、雙（4-特丁基苯基）磷 酸鎂、單（4-特丁基苯基）磷酸鋅、雙（4-特丁基笨基）磷 酸鋅、羥基（4-特丁基苯基）磷酸鋁、羥基（4-特丁基笨 基）磷酸鋁、三（4-特丁基苯基）磷酸鋁、2,2夂亞甲雙（4 ,6-二特丁基苯基）磷酸鈉、2,2’-乙叉雙（4,6-二特丁基 苯基）磷酸鈉、2,2’-亞甲雙（4-祜基-6-特丁基苯基）磷 酸納、2,2’-亞甲雙（4,6-二特丁基苯基）磷酸鋰、2,2^ 乙叉雙（4, 6-二特丁基苯基）磷酸鋰、2,2’-亞甲雙（4-祜 基-6-特丁基苯基）磷酸鋰、2,2’-乙叉雙（4-異丙基-6-特丁基苯基）磷酸納、2,2’-亞甲雙（4-甲基-6-特丁基苯 基）磷酸鋰、2,2f-亞甲雙（4-乙基-6-特丁基苯基）磷酸 鋰、2, 2’-丁叉雙（4,6_二甲基苯基）磷酸納、2,2’-丁叉 雙（4,6-二特丁基苯基）磷酸鈉、2,2’-特辛基亞甲雙（4, 6-二甲基苯基）磷酸納、2,2’-特辛基亞甲雙（4,6-二特 一 19 一 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 486501 A7 B7 五、發明説明（18 ) 丁基苯基）磷酸鈉、2,2’-亞甲雙（4-甲基-6-特丁基笨基） 磷酸鈉、2,2’-亞甲雙（4-乙基-6-特丁基苯基）磷酸納、 (4,二甲基-6,6·-二特丁基-2,2’-二苯基）磷酸納、 2,2’-乙叉雙（4_次丁基-6-特丁基苯基）磷酸納、2,2f-亞甲雙（4,6-二甲基苯基）磷酸鈉、2,2’-亞甲雙（4,6-二 乙基苯基）磷酸納、2,2’-乙叉雙（4,6-二特丁基苯基）磷 酸鉀、雙[2,2’-亞甲雙（4,6-二特丁基苯基）磷酸]鈣、 雙[2,2’-亞甲雙（4,6-二特丁基苯基）磷酸]鎂、雙[2,2’ 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) -亞甲雙（4,6-二特丁基苯基）磷酸]鋅、三[2,2* -亞甲雙 (4,6-二特丁基苯基）磷酸]鋁、雙[2,2’-亞甲雙U-甲基 - 6-特丁基苯基）磷酸]鈣、雙[2,2^乙叉雙（4,6-二特丁 基笨基）磷酸]鈣、雙[2,2’-硫代雙（4_甲基-6-特丁基苯 基）磷酸]鈣、雙[2,2’-硫代雙（4-乙基-6-特丁基苯基） 磷酸]鈣、雙[2,2^硫代雙（4, 6-二特丁基苯基）磷酸]鈣 、雙[2,2’-硫代雙（4,6-二特丁基苯基）磷酸]鎂、雙[2, 2’-硫代雙（4-特辛基苯基）磷酸]鎂、雙[2,21-亞甲基雙 (4 ,6-二特丁基苯基）磷酸]鋇、雙[(4, 4 -二甲基-6，6’-二特丁基-2,2’-二苯基）磷酸]鈣、雙[2,2’-乙叉雙（4,6 -二特丁基苯基）磷酸]鎂、雙[2,2’-乙叉雙（4,6-二特丁 基苯基）磷酸]鋇、三[2,2^乙叉雙（4,6-二特丁基苯基） 磷酸]鋁、二羥基-2,2f_亞甲雙（4,6-二特丁基苯基）磷 酸鋁、二羥基-2,亞甲雙（4-祜基-6-特丁基苯基）磷 酸鋁、羥基雙[2,2’-亞甲雙（4,6-二特丁基苯基）磷酸] 鋁、羥基雙[2,2’-亞甲雙（4-枯基-6-特丁基苯基）磷酸] 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 486501 A7 __B7___ 五、發明説明（19 ) 鋁、二羥基雙[2,2’-亞甲·雙（4,6-二特丁基苯基）磷酸] 钛、二經基雙[2,2·-亞甲雙（4,6-二特丁基苯基）磷酸] 經濟部中央標準局員工消費合作杜印製 錫、氧代雙[2,2’-亞甲雙（4,·6-二特丁基苯基）磷酸]_ 、二羥基-2,2’-亞甲雙（4-甲基-6-特丁基苯基）鱗酸鋁 、二羥基-2,2’-亞甲雙（4-甲基-6-特丁基苯基）磷酸鋁 、二羥基-2, 2*-乙叉雙（4,6-二特丁基苯基）磷酸鋁、羥 基雙[2,2^乙叉雙（4 ,6-二特丁基苯基）磷酸]鋁等芳基 磷酸鹽糸化合物；前述芳基磷酸鹽系化合物內，瓌狀多 價金屬芳基磷酸鹽糸化合物與乙酸、乳酸、丙酸、丙烯 酸、辛酸、異辛酸、壬酸、癸酸、月桂酸、十四烷酸、 棕櫚酸、硬脂酸、油酸、亞油酸、亞麻酸、12-羥基硬 脂酸、蓖麻酸、山¥酸、芥酸、裼媒酸、峰花酸、硬脂 醯乳酸、/3 - Ν-月桂基氨基丙酸、/Ϊ-Ν-甲基-Η-月桂醯 氨基丙酸等脂肪酸族單羧酸之鋰、鈉或鉀鹽等脂肪酸族 單羧酸鹼金屬鹽，或與鹼性羥基碳酸鋁鋰水合物之混合 物；聚3-甲基-1-丁烯、聚3-甲基-1-戊烯、聚3-乙基-1-戊烯、聚4-甲基-1-戊烯、聚4-甲基-1-己烯、聚4，4-二甲基-1-戊烯、聚4,4-二甲基-1-己烯、聚4_乙基-1-己烯、聚3 -乙基-1-己烯、聚烯丙基萘、聚烯丙基原莰 烷、雜連聚乙烯、間規聚乙烯、聚二甲基苯乙烯、聚乙 烯基#、聚烯丙基苯、聚烯丙基甲苯、聚乙烯基環戊烷 、聚乙烯基環己烷、聚乙烯基環庚烷、聚乙烯基三甲基 矽烷、聚烯丙基三甲基矽烷等高分子化合物等。 其中尤Μ滑粉、羥基雙（4-特丁基苯甲酸）鋁、1· 3， 486501 A7 B7 五、發明説明（20) 2· 4-二苄叉山梨糖醇、1· 3,2· 4-雙（對甲基苄叉）山 梨糖醇、1· 3,2· 4-雙（對乙基苄叉）山梨糖醇、1· 3, 2· 4-雙（2·,4*-二甲基苄叉）·山梨糖醇、1· 3,2· 4-雙 (3、4’-二甲基苄叉）山梨糖醇、1· 3-對氯苄叉-2· 4-對甲基苄叉山梨糖醇、1· 3,2· 4-雙（對氯苄叉）山梨糖 醇、雙（4-特丁基苯基）磷酸納、2,2’-亞甲基雙（4,6-二 特丁基苯基）磷酸納、2,2’-亞甲基雙（4,6_二特丁基苯 基）磷酸鈣、2,2夂亞甲雙（4,6-二特丁基苯基）磷酸鋁 、二羥基-2,2’-亞甲雙（4,6-二特丁基苯基）磷酸鋁、或 或羥基雙[2,2’-亞甲雙（4,6-二特丁基苯基）磷酸丁鋁等 環狀多價金屬芳基磷酸鹽糸化合物與脂肪酸單羧酸鹼金 屬鹽之混合物、聚3-甲基-1-丁烯、聚乙烯基環己烷、 或聚烯丙基三甲基矽烷為佳。 此等α晶核劑可單獨使用自不待言，亦可二種K上的 α晶核劑併用。 本發明前述聚丙烯糸組成物（Ci),可再混配自由基發 生劑和或结晶性丙烯均聚物（PHP),進一步改善射出 成型品之抗白化。 經濟部中央標準局員工消費合作社印製 所混配結晶性丙烯均聚物（Ρ Η P )係密度0 . 9 1〜0 . 8 9 g / cm 3 ,且丙烯系組成物（A)與結晶性丙烯均聚物（P HP) 之熔體流量比/ MFRph )0.5〜2,最好0.8〜 1 . 2之丙烯均聚物。 在此組成物中，丙烯糸組成物（A)與結晶性丙烯均聚 物（Ph)之MFR比。影響成型品之抗白化性，無論太大 一22 - 486501 A7 B7 五、發明説明（2：L ) 或太小，其抗白化性不足。 结晶性丙烯系組成物（Ρ Η P )的混配比，為樹脂之1 0〜 95重量％ ，丙烯系組成.物（Α)·的含量，就成型品之剛性 和耐衝擊性的平衡言，為樹脂之5〜90重量S：範圍。 即在此組成物內，丙烯糸組成物（Α)有防止成型品白 化的抗白化劑作用，故此組成物適於鉸鐽或容器栓塞等 具有折曲部的成型品之成型用。 另方面，自由基發生劑可提高混配物流動化，顯著改 善成型性。 自由基發生劑為了獲得均勻組成物，最好分解溫度不 要太低，為得半衰期10小時，溫度在70t!K上，KlOOt： Κ上為佳。有例如苯甲藤過氧、過苯甲酸特丁酯\過乙 酸特丁酯、過氧異丙基碳酸特丁酯、2,5-二甲基-2,5 -二（特苯甲醯過氧）己烷、2,5-二甲基-2,5-二（特苯甲醸 氧基）己炔-3、二過Β二酸特丁酯、過氧-3,5,5-三甲基 己酸特丁酯、丁酮過氧、環己酮過氧、二特丁基過氧、 二枯基過氧、2,5-二甲基-2,5-二（特丁基過氧）己烷、 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 2,5_二甲基-2,5-二（特丁基過氧）己炔_3、1,3-雙（特丁 基過氧異丙基）苯、特丁基祜基過氧、1,1-雙（特丁基過 氧）-3,3,5-三甲基環己烷、1,1-雙（特丁基過氧）環己烷 、2,2-雙（特丁基過氧丁烷）、對荃烷過氧氫、二異丙基 苯過氧氫、祜烯過氧氫、特丁基過氧氫、對徹花烴過氧 氫、1,1,3,3-四甲基丁基過氧氫、和2,5-二甲基-2,5-二（過氧氫）己烷等有機過氧化物。尤Κ2,5-二甲基-2,5 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 486501 A7 B7 五、發明説明（22 ) - 2(特丁基過氧）己烷、2,5-二甲基-2,5-二（特丁基過 氧）己炔-3、和1 , 3-雙（特丁基過氧異丙基）苯為佳。此 等自由基發生劑可單獨使用，*亦可二種Μ上併用。於本 發明前述聚烯烴混配一般性添加劑的聚丙烯系組成物 (C),亦可用做中空成型品成型用聚丙烯系組成物（Cb)。 於此聚丙烯系組成物（Cb),相對於丙烯糸組成物（A) 100重量份，可混配可塑化成份5〜20重量份，對成型 品賦予柔軟性。 可塑化成份（Ps)通常總稱低密度聚乙婦，有密度0.910 〜0.93〇g / cm3,結晶融點（Tm)100〜115C，熔體流量 (MFR: 190Ρ; 21·18Ν)0·1 〜5g/10·,最好 0.1 〜lg/ 10’之二乙烯均聚物和乙烯-α-烯烴共聚物，Μ及密度 0.92〜0.935g/Cm3,结晶融點（Tm)90〜10810,熔體流 量（MFR: 1901; 21·18Ν)0·1 〜5g/10f,最好 0·1 〜lg /1(Γ之乙烯-乙酸乙烯酯共聚物。 由於可塑化成份的混配，可對成型品賦予柔軟性，故 此聚丙烯系組成物（Cb),適於具有蛇腹構造的中空成型 品和膜之成型用。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 上述本發明各聚丙烯糸組成物，係將丙烯系組成物 (A)和視需要而定之各添加成份，利用高速混合裝置， 例如，Henschel混合器（商品名）、條帶式混拌器、震動 混合器等加以混合，以單軸壓出機、雙軸壓出機、混練 機等，在150〜300¾，最好200〜2501熔混而製粒，K 供各種成型品之成型用。 一24 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 B7 五、發明説明（25 ) 本發明成型品是使用前述各聚丙烯系組成物，按各種 成型法加以成型之成型品。 第一具體例之成型品為射出成型品。具體而言，為前 述各聚丙烯系組成物顆粒射出成型所得成型品，例如片 狀成型品、容器和容器栓塞、附設鉸件的成型品等。 射出成型用聚丙烯系組成物，凡前逑均可用，惟K使 用射出成型用聚丙烯系組成物（Ci)為佳。 由於成型對象的成型品及所需求特性，可Μ使用混配 有自由基發生劑和/或結晶性丙烯均聚物等之組成物。 由於使用此等聚丙烯系組成物（Ci),可製造成折曲部 (鉸件構造部等）的抗白化性、透明性、光澤、性、耐 衝擊性，尤其是低溫耐衝擊性，成型時的成型收縮率， 及其平衡性均優的射出成型品。 本發明第二具體例之成型品為Η材，就片材的印刷性 和柔軟性觀點言，片材在2310的縱向楊氏係數200〜450 MPa, Κ300〜400MPa為佳，且501C的縱向抗拉屈腋點強 度15MPa以上，W17MPa Κ上為佳。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 本發明Η材雖可採用任何已知片材成型法製造，惟因 生產性良好，Μ壓出成型或砑光成型為佳。具體而言， 可利用使用具有壓出機、Τ模具、磨光輥（冷卻輥）、導 輥、捲輥、修剪器、遮蔽器、定長裁切器、堆叠機等步 驟的裝置（Τ模具片材成型機）之Τ模具法，Κ及利用具 有班伯黑混合器、混合輥、蝸輪輥、壓出機、砑光輥、 冷卻輥、修剪器、遮蔽器、定長裁切器、捲取機等步驟 -25- 486501 A7 B7 五、發明説明（24) 之裝置（砑光成型機）成型片材。 更好是利用本發明片材製法，即T模具法，將前述聚 丙烯系組成物（C),最好是前逑射出成型所揭示同樣的 聚丙烯糸組成物（Cs),在樹脂溫度180〜3001C壓出，設 定冷卻輥溫度於5〜80¾，且與樹脂溫度相差120¾ Κ上 ,K片材速度0 . 1〜1 0 0 m / in i η 〇 樹脂溫度在180〜300 1C範圍時，聚丙烯系組成物（Cs) 可充分融化，且在不會熱劣化的範圍，故可得保持片材 融化張力的良好成型性，且可得片材表面無鯊魚皮狀、 外觀優良的片材。 冷卻輥溫度在5CK上時，冷卻混不會結露，片材表 面不發生班點狀圖案，而在801CK下時，片材可充分冷 卻，成卷片材解捲時，不會發生線狀圖案，可得良好的 外觀片材。 片材的分子導向弱，因此縱向和横向的熱收縮率差小 ，樹脂溫度與冷卻輥溫度間保持下式所示關係： 樹脂溫度-冷卻輥溫度 g 120¾ 可得成型性優良的片材。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 片材的成型速度在O.la/rainM上時，厚度均勻且不 良率少的片材，可得充分的生產速度，另方面在loom/ fflinK下時，片材可充分冷卻，成卷的片材解捲時，可 防止發生線狀圖案，獲得良好外觀的片材。 本發明第三具體例之成型品，係於使用前述聚丙烯系 組成物（C),最好是丙烯系組成物（A),混配一般聚烯 一 26 一 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（25 ) 烴所用添加劑所得聚丙烯系組成物（C),加以成型之膜 。此膜包含未延伸、單軸延伸和雙軸延伸的膜。 未延伸膜利用通常製造聚烯烴膜所用T模具法，或吹 脹法，而單軸延伸和雙軸延伸膜，可藉將前述方法所得 未延伸膜以展延方式單軸延伸和逐次雙軸延伸，或者K 管狀方式同時雙軸延伸法加K延伸製造。 此等膜由於使用Μ本發明丙烯系組成物為基質樹脂之 聚丙烯系組成物（C),故低溫耐衝擊性、耐熱性和抗拉 強度均優。 本發明膜的其他具體例，有在上述膜的單面或兩面積 曆功能性聚合物層而成的積層膜。 本發明積層膜只要在上述聚丙烯系組成物（C)構成的 膜積層可賦予功能之聚合物層，無特別限制，惟至少有 熱封性層。 熱封性層可用密度0.89〜0.91g / era3 ,结晶融點165 〜160 υ的丙烯均聚物，和/或密度0.89〜0.91 g / cm3 ，結晶融點159〜llOC的丙烯-烯烴均聚物。 於此等熱封性層所用聚合物的熔體流量（2301 ; 21. 18N),從膜成型時的成型性，所得膜的外觀方面言， 為0.1〜50g/10’，K1〜20g/10’為佳。與丙烯共聚合 的α-烯烴，有例如乙烯、丁烯-1、戊烯-1等。 丙烯-α -烯烴共聚物有例如乙烯成份含量為0.2〜10 重量％的乙烯、丙烯共聚物，乙烯成份含量0.2〜10重量 ，丁烯-1成份含量0.4〜5重量！《的乙烯-丙烯-丁烯-1共 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 __B7_五、發明説明（26 ) 聚物等。 丙烯均聚物的結晶融點，就欲得表面光澤、表面硬度 、剛性優良的多層膜方面言，·為165〜160¾。 又，丙烯-α-烯烴聚合物的結晶融點，從欲得熱封性 優良的積層膜觀點言，為159〜llOTC, W140〜11010為 佳0 此等丙烯均聚物和丙烯烯烴共.聚物，可由使用含 至少鎂、钛和鹵素的複合物，周期表第1至第3族金屬 的有機金屬化合物，和電子給予體所形成觸媒，按習知 聚合方法，將丙烯單獨聚合，或將丙烯與α-烯烴共聚 合製成。 本發明多層膜，具有使用聚丙烯系組成物層和前述功 能性聚合物層，為未延伸、單軸延伸和雙軸延伸的多層 膜。多層膜的層構造有例如具備功能性聚合物層/聚丙. 烯系組成物層的二種二層，具備功能性聚合物層/聚丙 烯系組成物層/功能性聚合物層的二種三層或三種三曆 。其中丙烯均聚物層/聚丙烯系組成物層/丙烯-烯 烴共聚物層構成的積層膜，在所得積層膜的附熱性、熱 封性方面較佳。 積層膜的厚度雖無特別限制，惟就膜的成型性而言， Μ10〜100//為佳，而Κ15〜70//更好。另外，積層膜 的各層厚度亦無特別限制，惟就低溫耐衝擊性、耐熱性 、抗拉強度方面言。丙烯糸組成物層厚度要佔膜全厚的 3 0 〜9 0 S： Κ 5 0 〜9 0 »：為佳。 -28- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 486501 A7 _ B7 五、發明説明（27 ) 積層膜之製法有例如多曆壓出成型法、乾式積層法、 壓出積層法等，多層壓出成型法有例如通常聚烯烴膜製 造用的丁 T模具法或吹脹法。而延伸方法有例如利用展 延方式的逐次雙軸延伸法，或利用管狀方式的同時雙軸 延伸法等。 K上述已知方法製造積曆膜時，構成各層的聚丙烯系 組成物和功能性聚合物之熔體流量（MFR),無特別限制 ,惟從膜的成型性和製品膜的外觀言，聚丙烯条組成物 與功能性聚合物的MFR比為0.1〜10, M0, 5〜2為佳。 ^^本發明積層膜可利用乾式積層等方法，藉黏著劑，與 Β0ΡΡ膜、PET膜、尼龍膜、 EVAL 膜等透明基材膜積 層製成。 本發明膜和積層膜為賦有印刷性、積曆適用性、金屬 蒸著特性之目的，可利用通常工業上採用的方法，再加 Μ電翬放電處理、火焰處理、電漿處理等表面處理。 本發明第四具體例的成型品，係由前述聚丙烯系組成 物（C)，尤指在丙烯系組成物混配可塑化成份所得組成 物（Cb),製得的中空成型品。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 此中空成型品K具有蛇腹構造為佳。 本發明中空成型品，可供應聚合物系組成物（C)至吹 氣成型機之壓出機，壓出中空圓柱狀，利用吹氣成型法 即可容易製造。又，成型機的金屬模型因採用具有凹凸 面（蛇腹面）的金屬模型，即可容易製成具有蛇腹構造的 中空成型品。 -29- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 86501 經濟部中央標準局員工消費合作社印製 A7 __B7_五、發明説明（28 ) 本發明中空成型品的其他具體例，有具備蛇腹構造的 中空成型品部份，與剛性、耐衝擊性優良的聚烯烴系組 成物（P0)製成的中空成型品部份，接績而成的複合中空 成型品。 與此蛇腹構造接續的中空成型品部份所用聚烯烴系組 成物（P0),有包括含乙烯聚合單元25〜55重量3：,最好 35〜55重量的乙烯-丙烯共聚物1〜20重量χ , K10〜 20重量為佳，Κ及丙烯均聚物99〜80重量之組成物 ，為賦予剛性可在無損本發明目的的範圍内添加無機填 料，有例如滑粉、碳酸鈣、矽酸鈣等。無機填料的混配 比，Κ組成物重量基準的20重量Μ下為佳。 此中空成型品可用蓄積式吹氣成型機，包括一組模型 緊緊裝置，一個水壓機汽缸，和至少二台壓出機，於其 中一壓出機供應本發明聚丙烯系組成物（C),另一壓出 機供應前述聚烯烴系·組成物（Ρ0),先由一壓出機將融化 組成物積蓄於水壓機汽缸，再利用另一壓出機將融化組 成物積蓄於水壓機汽缸。接著，設定成融化聚丙烯系組 成物（C)的型坯，導入具有凹凸面（蛇腹面）的金羼模型 部，利用水壓機汽缸壓出型坯，在型坯内部吹入0 . 5〜1 MPa的加壓空氣而製成。 奩_例 玆Μ實施例和比較例進一步詳细說明本發明如下。 Α.丙烯糸組成物（Α)之合成 ⑴各種物性的測定 -30- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 _B7五、發明説明（29 ) 在丙烯系組成物的合成過程中，有關中間生成物和最 終生成物之諸物性，可由下述方法測定。 合成條件和測定結果如表l·和表2所示。 (a) 含鈦的固體觸媒成份（a)的平均粒徑（//ία):由 利用主分級器（MALVERH公司製品）測得之粒度分佈算出。 (b) 含钛的固體觸媒成份U)的均勻度：由利用主分 级器（MALVERN公司製品）測得之粒度分佈所得60S：篩下 的粒徑，除以10¾篩下的粒徑算出。 (c) 觸媒每單位重量的聚合物生成量：利用試料中Mg 衍生鐽電漿發光分析（IPC法）測定。 (d) 聚丙烯分子鏈中等規五價物分率P:根據 &lt;〈巨分子〉〉 8687(1975),使用 GC-HMR 測定。 (e) 乙烯單位含畺（重量S：):利用紅外線吸收譜法測 定0 (f) 極限黏度（dl/g):在萘滿（四氫萘）溶劑中，135 υ溫度條件下，使用自動黏度測定裝置（AVS2型，三井東 壓公司製品）測定。 (g) 熔體流量（g/ΙΟ’）：根據JIS Κ 6760測定。 (h) 平均分子量Q值（Mn / Mw):就溶解於135t!鄰 二氯苯的試料，使用GPC裝置（凝膠滲透層析，150 C型 ，俄塔斯公司製品，使用管柱：TSK GEL GMH 6-HT)測 定0 (i) 2〇υ二甲苯可溶成份量（重量Si ):根據IS0/DIS 1 873-1 測定。 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 _ B7 五、發明説明（50) (j)粉末流動性：根據下式算出粉末的壓縮度。 凝固表觀密度-鬆弛表觀密度 壓縮度 =--- X 100 凝固表觀密度 壓縮度值愈高，粉末流動性愈差。 ⑵含钛固體觸媒成份（a)之調製 U)含钛固體觸媒成份：a-1 於氮氣排淨的$113製壓熱器，加入無水》18(：1295.3克 、乾燥EtOH352毫升，此混合物在攪拌下加熱至105C溶 化。攪拌1小時後，將此溶液加熱至105υ, Μ加壓氮 (l.IMPa)送入二流體噴嘴。氮氣流量381/inin。於噴塔 中導入冷卻用液氮，塔内溫度保持-151C。生成物集在 導入塔內底部的冷卻己烷中，得25 6克。生成物的分析 結果，此載體的組成和出發溶液同為MgCl 2 · 6EtOH。 為了用做載體，篩選45〜212/iin粒徑的球形載體205 克。所得載體在室溫，使用31/min流量的氮通氣乾燥 181小時，得組成為MgC 1 2 · 1 . 7EtOH的乾燥載體。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 在玻璃燒瓶中，將乾燥載體20克、四氯化鈦160毫升 、精製1,之-二氯乙烷240毫升混合，攪拌下加熱至100 υ。其次加苯二甲酸二異丁酯6.8毫升，再於100¾加 熱2小時後，傾析除去液相部份。再加四氯化钛160毫 升和精製1,2 -二氯乙烷320毫升，在1001C加熱保持1 小時。利用傾析除去液相部，Μ精製己烷洗淨後，乾燥 而得含鈦固體觸媒成份a-1 。所得含鈦固體觸媒成份 本紙張尺度適用中國國家標準（〇奶）八4規格（210父297公釐）· 486501 A7 B7 五、發明説明（51) a-1的平均粒徑為115/im,其分析值為Mgl9.5重量S：, 1^1.6重量》!,(：159.0重量％,笨二甲酸二異丁酯4,5重 量龙。 . (b) 含钛固體觸媒成份：a-2 於氮氣排淨的SUS製壓熱器，加入精製燈油1 , 050毫 升，無水^^(：1215克，乾燥乙醇36.3克，和界面活性劑 (商品名Emulsol 320,花王Atlas公司製品）4·5克後， 將此混合物於80〇rpin攪拌中升溫至1201C,保持30分鐘 。融混物Μ高速攪拌中，使用内徑5πιπι的鐵弗龍製管， 移送至附設攪拌的3000毫升燒瓶，預裝冷卻至-101C的 精製燈油1500毫升，生成物過滤後，Κ己烷充分洗淨， 得載體〇 . 載體1 5克在至溫下懸浮於四氯化鈦3 0 0毫升後，添加 苯二甲酸二異丁酯2.6毫升，混合物溶液升溫到120它 。在1 20 TC溫度混合攪拌2小時後，過滤固體物，再懸 浮於300毫升的四氯化鈦中。懸浮液在130£〇混合搜拌 2小時後，過滤固體物，Μ精製己烷充分洗淨，得含钛 固體觸媒成份a-2 。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 所得含鈦固體觸媒成份a-2的平均粒徑72 u in,分析 值為Mg21.1重量％ , Ti2.4重量X , C164.15重量％ ,苯 二甲酸二異丁酯5.3重量％ 。 (c) 含鈦固體觸媒成份：a-3 取乙氧化鎂300克、2 -乙基己醇550毫升，和甲苯 600毫升的混合物，在0 e20MPa的二氧化碳氛圍氣體下 本纸張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 _ B7 五、發明説明（52) ，於931C攪拌3小時。再加甲苯800毫升#和正癸烷800 毫升，得碳酸鎂溶液。 於甲苯800毫升、氯苯60毫升、四乙氧基矽烷18毫升 、四氯化鈦17毫升，和Iso paj G(平均碳原子數10個的 異鏈烷烴，沸點1 5 6〜1 7 6 TC ) 2 0 0毫升，在3 0 υ攪拌5分 鐘當中，添加前述調製的碳酸鎂溶液100毫升。 再攪拌5分鐘後，添加四氫呋喃44毫升，在60毫1C攪 拌1小時。停止攪拌，除去上澄液後，生成的固體用甲 苯100毫升洗淨，於所得固體添加氯苯200毫升和四氯 化鈦200毫升，在135 υ攪拌1小時。停止攪拌，除去 上澄液，加氯苯500毫升、四氯化鈦200毫升和苯二甲 酸二正丁酯4.2毫升，在13 5C攪拌1.5小時。除去上 澄液後，依序用甲苯1 200毫升，Isopar G 1 600毫升， 己烷80 0毫升洗淨固體，採取比較用含钛固體觸媒成份 a -3 。所得含鈦固體觸媒成份a-3的平均粒徑18.5ium, 其分析值為Mgl7,0重量％ , Ti2.3重量ίΚ , C155.0重量％ ，苯二甲酸二正丁酯7.5重量％ 。 (3)含鈦固體觸媒成份U )的預活化處理 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 容量15公升附設傾設翼的不銹鋼製反應器，Κ氮化排 淨後，在室溫添加40 υ時動黏度為7. 3厘史托克的飽和 烴溶劑(CRYST0L-52, ΕΧΧ0石油公司製品）8,3公升，三 乙基鋁525毫莫耳，二異丙基二甲氧基矽烷80毫莫耳， 在前項調製的含鈦固體觸媒成份70 0克後，加溫到40¾ ,令丙烯在分壓0 . 1 5 Μ P a反應7小時，進行預活化處理 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 _B7_ 五、發明説明（55 ) 。分析结果，每克含鈦固體觸媒成份有丙烯3.0克反應。 ⑷丙烯均聚物（P鈐的合成：第一聚合步驟 在附第3圖所示流程圖中，·於具有攪拌翼的横型聚合器 1 (L/ D = 6,容量100公升），連縝供應預活化處理過之 含鈦固體觸媒成份0.5g/h, K及三乙基鋁做為有機鋁 化合物（b)和二異丙基二甲氧基矽烷做為有機矽化合物 U),使呈表1和表2所示Al / Si比。連續供應丙烯， Μ維持反應溫度70TC,反應壓力2.5MPa,攪拌速度40rpm 的條件，再由循環管路2連鑕供應氫氣，K調節所生成 丙烯均聚物分子量，於反應器氣相中的氫濃度，控制所 生成丙烯均聚物的極限黏度。 反應熱是利用管路3所供應原料丙烯的氣化熱除去。 從聚合.器排出的未反應氣體通過管哆4 ,在反應器系外 冷卻、凝結，回流到聚合器1 。 在聚合器1所得丙烯均聚物，從聚合器1通過管路5 連續抽出，供至第二聚合步驟聚合器10,以保持聚合物 液位在反應容量的50容量％ 。此時，從管路5間敗抽出 部份丙烯均聚物，做為樣品Μ測定等規五價物分率（P) 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 、201C二甲苯可溶物份量、極限黏度（[η ]ρρ)和觸媒每 單位重量的聚合物產量。 (5)丙烯-乙烯共聚物（RC)的合成：第二聚合步驟 於具有撹拌翼的横型聚合器10 (L / D = 6 ,容量100公升） ，連續供應來自第一聚合步驟的丙烯均聚物和乙烯-丙 烯混合氣體，進行乙烯與丙烯的共聚合。反應條件為攪 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 B7 五、發明説明（54 ) 拌速度40rpm溫度601C，壓力2.1MPa,氣相的氣體組成 調節成乙烯/丙烯莫耳比和氫/乙烯莫耳比如表1和表 2所示。從管路7分別供應一氧化碳，做為聚合活性抑 制劑，K調節生成丙烯-乙烯共聚物聚合量，和供應氫 氣，K調節生成丙烯-乙烯共聚物分子量。 反應熱係利用管路6所供應原料液狀丙烯氣化熱除去。 從聚合器排出的未反應氣體，通過管路8 ,在反應器 系外冷卻、凝結、回流至共聚合步驟。共聚合步驟所生 成丙烯糸組成物（A) , K管路9從聚合器9抽出，使聚 合物保持液位為反應容量的50容量！C 。 丙烯系組成物（A)的生產速度為8〜12kg/hr。 從抽出的丙婦系組成物（A)除去單體，一部份供測定 極限黏度（U ] WHOLE ) , Q值（Mw / ) , 20它二甲苯 可溶物份量，和丙烯-乙烯共聚物中的乙烯，Μ及丙烯-乙烯共聚物的聚合比率。再者，評估丙烯系組成物（A) 的粉末流動性。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 改變所含鈦固體觸媒成份（a)的種類，第一聚合步驟 中Al/Si莫耳比和氫/丙烯莫耳比，第二聚合步驟中乙 烯/丙烯莫耳比和氫/乙烯莫耳比，得本發明樣品A-1 至A-14和比較樣品CA-1至eA-14。 反應條件和諸物性的測定结果，將本發明丙烯系組成 物的製造條件及其特性列於表1 ,而丙烯糸比較用組成 物的製造條件及特性列於表2 。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 B7 五、發明説明（$ ) 經濟部中央標準局員工消費合作社印製 表1 丙烯系組成物之製造 组成物製造實施例諕次 1 ^ 2 3 4 5. 6 7 含鈦固體觸媒成份(a)號次 a-1 a-1 a-1 a-1 a-1 a-2 a-1 平均粒徑· μαι 115 115 115 115 115 115 115 均勻度 1.74 1.74 1.74 1. 74 1.74 1.73 1.74 預活化處理 Al/Ti/Si 莫耳比 2/1/0.3 2/1/0. 3 2/1/0· 3 ‘ 2/1/0.3 2/1/0.3 2/1/0.3 2/1/0.3 烯烴 /otVy r〇t&gt;y MV/ /otvy r〇h&gt;y Μ» ：r_ . 反應量 gfh-/g触媒 3 3 3 3 3 3 3 第一聚合步驟 Al/Si 莫耳比 3 6 2 3 3 3 聚合壓力 MPa 2.5 2.5 2.5 2.5 2.5 2.5 2.5 聚合溫度. 70 70 70 : 70 70 70 70 h2/c3 莫耳比 0.03 0.06 0.026 0.003 0.01 0.04 生成丙烯均聚物(PP) 生成量ΟΤρρ) wtX 71.5 71.0 71.3 69.7 63.7 72.5 70.8 等規五價物分率(Ρ) % 0.963 0.964 0.973 0.964 0.967 0.972 0.968 極限黏度(U]PP) dl/g 2.5 2.3 1.8 2.6 2. 07 2.4 1.75 熔體流量'(MFRpp.) g/l〇分 0.8 1.5 6.0 0.7 2.6 1.0 7.2 第二聚合步驟 聚合壓力 MPa 2.1 2.1 2.1 2.1 2.1 2.1 2.1 聚合溫度 60 60 60 60 60 60 60 C2/C3 莫耳比 0.23 0.23, 0.23 0.3 0. 42 0.23 H2/C2 莫耳比 0.18 0.25 0. 57 0. 25 0.32 0.2 生成PP-ET共聚物(RC) 生成量(he) wtX 28.5 29.0 28.7 30.3 36.3 27.5 29.2 乙烯含量 wtX 35 35 35 41 48 35 34 ^ 極限黏度0&gt;]RC) dl/g 2.5 2.3 1.8 2.4 2.17 2.4 1.9 熔體流量（MFRRC) g/10分 0.8 1.5 6.0 1.5 2.3 1.0 4.1 二甲莉Γ溶成份(cxsRC)⑽ 94 94 95- 90 86 94 86 丙烯系組成物(A)號次 A-1 A-2 A-3 A-4 A-5 A-6 A-7 PP/R_&amp; αΡ&quot;ϊπ) 2.51 2.45 2.48 2.3 1.75 2.46 2.42 極限黏度（[]whole) dl/g 2.5 2.3 1.8 2.3 2.09 2.4 1.8 極限黏度比〔[r?W[77]PP) 1.0 1.0 1.0 0. 92 1.05 1.0 1.09 ([Ή ]rc/[ 77 ]ρρ) X (Wpp/WRCy 2.51 2. 45 2.48 2.1 1.83 2. 46 2.63 體流量（MFRwH〇uE)g/10分 0.8 1.5 6.0 1.4 2.5 1.0 6.0 分子量分散Q值 （Mw/Mn) 3.7 3.8 4:0 3.8 4.3 3.9 4.2 粉末流動性 鬆弛密度 g/ml 0.36 0. 36 0. 36 0.36 0.34 0.42 凝固密度 g/ml 0.36 0.36 0.36 0. 36 0.35 0.43 粉末壓縮度 X 0 0 0 0 2.9 2.3 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） -37- (請先閱讀背面之注意事項再填寫本頁) 486501 A7 B7 五、發明説明（私） 表1 丙烯系組成物之製造（績） 姐成物製造實施例號次 含钛固體觸媒成份(a)號次 平均粒徑 &quot;m 均勻度 湏活化處理 Al/Ti/Si 烯烴 反應量 莫耳比 g#片_/g触媒 第一聚合步驟 Al/Si 聚合壓力 聚合溫度h2/c3 莫耳比 HPa 莫耳比 8 9 11 12 13 a-1 115 1. 74 a-l 115 1.74 a-1 115 1.74 a-1 115 1.74 a-1 115 1.74 a-2 115 1.74 a-1 115 1.74 2/1/0. 3 /ahV/ 2/1/0.3 /otvy 3 2/1/0.3 /otuy 3 2/1/0.3 7〇h*i/y 3 2/1/0. 7.〇tV/ 3 ?/!/0. 3 7*〇t&gt;y 3 7/1/0.3 Tobl/y 3 2.5 70 2.5 70 2.5 70 2.5 70 2.5 70 2.5 70 2.5 70 (#,先聞讀背面之注意事項再填寫本頁) 生成丙烯均聚物(PP) 生成童(胃pp) wtx 等規五價物分率(P) X 極限黏度a&gt;]PP) di/g 熔體流量、(MFRPP) g/l〇分 70.3 0. 969 1.8 6· 1 71. 1 0.970 2. 05 2.8 75.0 0. 971 1.8 6.2 62.2 0. 967 1.8 6.5 69.7 0.970 1.8 6.2 68.9 0. 969 1.8 6.0 72.3 0. 955 1.8 6.1 第二聚合步驟 聚合壓力 MPa 聚合溫度 t： c2/c3 莫耳比 H2/C2 莫耳比 2. 1 60 2. 1 60 2. 1 60 2· 1 60 2. 1 60 2. 1 60 2. 1 60 生成PP-ΕΤ共聚物(RC) 生成量(WRC) wt% 乙締含量 wtX 極限黏度(U]Rc) dl/g 熔體流量（MFRrc) g/l〇分 二甲苯可溶成份（CXSrc) wtx 29.7 35 1.8 6.0 89 28.9 35 1.6 10.6 90 25.0 36 L8 6. 1 87 37.8 33 1.8 6.5 88 30.3 28 1.8 6.0 92 31. 1 41 1.8 6· 1 86 27.7 36 1.8 6.2 87 經濟部中央標準局員工消費合作社印製 丙烯条組成物(Α)號次 PP/RC重量比（W1TRC) 極限黏度（[^7]whole) dl/g 極限黏度比〔U]RC/U]Pi&gt;) ([Ή ]rc/[ Tj ]pp) X (Wpp/Wrc) 食谷體流量（MFRwhol E)g/10分 分子量分散Q值 (Mw/Hn) 粉末流動性 鬆弛密度 g/ml 凝固密度 g/ml 粉末壓縮度 % Λ-8 2.37 1.8 1.00 2.37 6. 1 4.2 Λ-9 2.46 1.93 0.78 1.92 4.0 4.2 A-10 3.00 1.8 1.00 3.00 6.2 4.2 Λ-11 1.65 1.8 1.00 1.65 G. 5 4.2 Λ-12 2. 30 1.8 1.00 2.30 G. 2 4.2 A-13 2.22 1.8 LOO 2.22 6.0 4· 2 Λ-14 2.61 1.8 LOO 2.61 6. 1 4.2 一38- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 486501 A7 _B7 五、發明説明（幻） 表2 丙烯系比較組成物之製造 經濟部中央標準局員工消費合作社印製 组成物製造實施例號次 1 2 3 4 5 6 7 含钛固體觸媒成份(a)號次 a_l a-1 a-2 a-3 a-1 a-1 a-1 平均粒徑 //ΙΠ 115 115 115 18.5 115 115 115 均勻度 1.74 1.74 * 1.74 2. 07 1.74 1.74 1.74 預活化處理 Al/Ti/Si 莫耳比 2/1/0. 3 2/1/0. 3 2/1/0.3 2/1/0.3 2/1/0.3 2/1/0.3 ?/t/0. 3 烯烴 mvj /Dt*uy T〇t*i/y rab^y 7*at&gt;y 7*ati/y mvj 反應量 gf1 片-/g触媒 3 3 3 3 3 3 3 第一聚合步驟 Al/Si 莫耳比 14 3 3 3 3 3 3 聚合壓力 MPa 2.5 2.5 2.5 2.5 2.5 2.5 2.5 聚合溫度 ^ 70 70 70 70 70 70 70 h2/c3 莫耳比 0.007 0.055 0.006 0. 003 0. 022 0.055 0.003 生成丙烯均聚物(PP) 生成量〇ΤΡΡ) WtX 80.5 80.5 86.8 69.7 75.6 75.3 46.3 等規五價物分率(P) X 0.949 0. 972 0.964 0.961 0.971 0.974 0. 962 極限黏度([]pp) dl/g 2.3 1.6 2.3 2.6 1.84 1.52 2.5 熔體流量、(MFRPP) g/l〇分 2.1 14.5 1.4 0.7 5.3 16.8 0.8 第二聚合步驟 聚合壓力 MPa 2.1 2.1 2.1 2.1 2.1 2. 1 2.1 聚合溫度 t 60 60 60 60 60 60 60 C2/C3 莫耳比 0.35 0. 36 0.3 0.28 0.36 0.43 0.23 H2/C2 莫耳比 0.3 0.12 0.25 0.25 0.10 0.02 0.15 生成PP-ΕΤ共聚物(RC) 生成 η% 19.5 19.5 13.2 30.3 24.4 24.7 53.7 乙婦含量 wtX 45 45 41 41 46 49 35 極限黏度([^7]rc) dl/g 2.0 2.9 2.3 2.4 3.0 4.9 2.6 熔體流量（MFRrc) g/10分 3.4 0.4 1.4 1.5 0.3 0.02 0.6 二甲苯可溶成份（CXSRC) WtX 88 88 90 90 85 84 93 丙烯系組成物(A)號次 cA-1 cA-2 cA - 3 cA-4 cA-5 cA-6 cA-7 PP/RCMS比(iP&quot;fRC) 4. 13 4. 13 6.57 2.3 3. 1 3.1 0.8G 極限黏度（[^7]whole) dl/g 2. 1 L9 2.3 2.3 2. 1 2.0 2. G 極限黏度比〔[77 ] R c/[ 7? ] p p) 0.87 2.1 1.0 0.92 l.G 3.2 1.0 ([V ]rc/[ 77 ]pp) X (Wpp/Wrc) 3. 59 7.7 6.57 2.14 5.0 9.7 0.86 fe 體流量（MFRwH〇LE)g/10 分 2.3 7.0 1.4 1.4 2.7 3.0 0.7 分子量分散Q值 （Mw/Mn) 4.4 6.7 3.8 3.8 5. 1 8.2 个5 粉末流動性 鬆弛密度 g/ml 0.35 0.36 0.36 0./16 0.36 0.36 0.34 凝固岔度 .g/ml 0. 34 0.36 0. 36 0. 37 0.3G 0. 3G 0. 36 粉末壓縮度 X 2.9 0 0 19.6 0 0 5.6 -39- (請先閲讀背面之注意事項再填寫本頁) 本纸張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 _B7 五、發明説明（妨） 經濟部中央標準局員工消費合作社印製 表2 丙烯系比較組成物之製造（壤） 姐成物製造實施例號次 8 9 10 11 12 13 14 含鈦固體觸媒成份(a)號次 a-1 a-1 9-1 a-1 a-1 a-1 a-1 平均粒徑 μιη 115 115 115 115 115 115 115 均勻度 1. 74 1.74 * 1.74 1.74 1.74 1.74 1.74 預活化處理 Al/Ti/Si 莫耳比 2/1/0. 3 2/1/0.3 2/1/0. 3 2/1/0. 3 2/1/0.3 2/1/0.3 ?/!/0.3 烯烴 /atvy /at*uy /uhly MV/ 反應量 gm-/g触媒 3 3 3 3 3 3 3 第一聚合步驟 Al/Si 莫耳比 聚合壓力 MPa 2.5 2.5 2.5 2.5 2.5 2.5 2.5 聚合溫度 ec 70 70 70 70 70 70 70 H2/C3 莫耳比 生成丙烯均聚物(PP) 生成量(Wpp) wtX 70,8 69.5 82.4 56.1 70.3 68.8 70.4 等規五價物分率(P) % 0.971 0.968 0.968 0.966 0.971 0.969 0.941 極限黏度([?7]pp) dl/g 1.4 2.3 1.8 1.8 1,8 1.8 1.8 熔體流量、(MFRPP)以1〇分 34.0 1.5 6.2 6.1 6.2 6.1 6.0 第二聚合步驟 聚合壓力 MPa 2.1 2.1 2.1 2.1 2.1 2.1 2.1 聚合溫度 T 60 60 60 60 60 60 60 C2/C3 莫耳比 h2/c2 莫耳比 生成PP-ΕΤ共聚物(RC) 生成 l:(WRc) wtX 29.2 30.5 17.7 43.9 29.7 31.2 29.6 乙婦含量 wtX 36 36 34 35 21 64 35 極限黏度（[t?]rc) dl/g 2.8 1.4 1.8 1.8 1.8 1.8 1.8 熔體流量（MFRrc) g/l〇分 0.41 27.3 5.9 6. 1 5.9 6.0 6.0 二甲爾溶成份(CXSRC)咐 85 89 90 87 86 83 89 丙烯系組成物(A)號次 cA-8 cA-9 cA-10 » cA-ll cA-12 cA-13 cA-14 PP/RC爾暈比（iPP/fRC) 2.42 2.28 4.66 1.28 2.37 2.21 2.38 極限黏度（[]WH(5LE) dl/g 1.79 2.0 1.8 1.8 1.8 1.8 1.8 極限黏度比〔U]RC/U]PP) 2. 00 0.61 1.0 1.0 1.0 1.0 1.0 ([]rc/[ 7] ]pp)x (Ipr/iRc) 4.84 1.39 f 4.66 1.28 2.37 2.21 2.38 熔體流量（MFRWHOUE)g/l〇分 6.2 3.0 6.2 6. 1 G.2 G. 1 6.0 分子量分散Q值 （Mw/Mn) 6.2 5.5 4.2 4.3 4.3 4.4 4.3 粉末流動性 鬆弛密度 g/ml 凝固密度 · g/ml 粉末壓縮度 X — 4 0 — (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 486501 A7 B7 五、發明説明（59 ) B.射出成型用聚丙烯糸組成物（Ci)及射出成型品 ⑴聚丙烯系組成物 於本發明丙烯系組成物A-1·至A-6和比較組成物CA-1 至CA-7各粉末，加各種添加成份，使用髙速攪拌式混合 器（Henschel混合器），在室溫下混合5〜10分鐘，混合 物使用螺桿口徑40mm的壓出製粒機，K汽缸設定溫度 23〇υ製粒，K調製顆粒。 表3和表4分別列出本發明射出成型用聚丙烯系組成 物Ci-Ι至Ci-12和Ci-13至Ci-18,表5和表6分別列出 比較組成物cCi = l至cCi-7和cCi_8至cCi-13各添加成份 及其添加量。 使用添加成份及表中簡稱如下： 而烯询聚物 PHP1:使用含鈦固體觸媒成份，在Al/Si莫耳比2 、 氫/丙烯莫耳比〇.〇3、聚合壓力2.5MPa、聚合溫度70t! 的條件，將丙烯單獨聚合所得熔體流量MFRpHpl、结晶 融點1 6 3它的結晶性丙烯均聚物。 ΡΗΡ2:使用含钛固體觸媒成份，在Al/Si莫耳比2 、 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 氫/丙烯莫耳比〇.〇1,聚合壓力2.5MPa和聚合溫度701 條件下，將丙烯單獨聚合所得熔體流量MFRpHp 1.9、融 點1 6 4 1C的結晶性丙烯均聚物。 ΡΗΡ3:使用含鈦固體觸媒成份，在Al/Si莫耳比2 、 氫/丙烯莫耳比〇.〇55、聚合壓力2.5»^3、聚合溫度70 υ條件下，將丙烯單獨聚合所得熔體•流量MFRPHP6、融 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 Α7 Β7 五、發明説明（40 ) 點1641的结晶性丙烯均聚物（比較用）。 抗蓋北1 P h - 1 :酚糸熱安定劑 ·486501 A7 ____B7_ V. Description of the invention (1) The chain link of the present invention is based on propylene-based compositions, especially those composed of propylene homopolymers and propylene-ethylene copolymers, and their preparation methods. Polypropylene-based compositions containing M as the main component, and molded articles made of these compositions, especially injection molded articles, extruded sheets, films, and hollow molded articles. Technology back. 景 __ Polypropylene resin is cheaper and has excellent characteristics, so it is used in various molded products, such as sheet, container, plug, etc., M and injection molded products with hinge structure, film, duct, etc. Various types of hollow molded products. Membrane materials are widely used as packaging materials such as food and fiber products due to their organic, optical, and thermal properties. In accordance with the characteristics required for molding applications, propylene homopolymers, propylene and α-olefins, especially copolymers with ethylene, M and copolymers of propylene homopolymers and propylene-cT-olefins are mainly used. Polypropylene based composition. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) General propylene homopolymers have high rigidity, excellent heat resistance, insufficient flexibility, impact resistance, especially low temperature impact resistance , M and film tear strength is poor. The propylene-ot-olefin copolymer is excellent in transparency and flexibility, but inferior in heat resistance and low temperature impact resistance. The known composition has excellent heat resistance and low temperature impact resistance, and has been widely used in various industries such as automobiles and home appliances. However, its transparency and gloss are inferior to homopolymers, and its molding shrinkage is as large as homopolymers. On the other hand, tear strength and softness are inferior to copolymers. Observing the whitening phenomenon caused by impact or bending plus K, the whitening resistance was insufficient. 1 3-This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 B7 V. Description of the invention (2) In order to improve these inadequate characteristics, there are polymers, copolymers or sisters Methods for changing properties, M and methods using additives. For example, a general method is to use an inorganic substance M such as filling powder to improve the molding shrinkage rate of the finished product. However, in order to increase the molding shrinkage rate, a large amount of inorganic substances such as powder powder must be added, which greatly increases the weight of the molded product and makes the grandparent Significant deterioration. On the other hand, it is possible to reduce the ethylene content in the copolymer in the composition and increase the transparency or gloss. However, it is generally desired to reduce the ethylene content in the copolymer to increase the gloss and lower the impact resistance and rigidity at low temperature. Japanese Patent Application Laid-Open No. 60-28411 discloses a method for producing a highly rigid ethylene-propylene copolymer, that is, a propylene-based sister product. The ethylene-propylene copolymer is divided into three stages, and the ethylene content is changed to sequentially copolymerize. The finished product obtained by this method not only has high rigidity, but also has excellent whitening resistance, impact resistance, heat resistance, etc., but the transparency, gloss, outer skin, and molding shrinkage of the molded product are still to be improved. . Japanese Patent Publication No. 7-30 1 45 discloses a propylene block copolymer, that is, a propylene strip composition, which is obtained by using a crystalline polypropylene portion and an ethylene-propylene random copolymerization block. The crystalline polypropylene content is 55. ~ 95% by weight Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). The limiting viscosity ratio ([π] Ep / U] ρρ) of the two components is 〇.  5 ~ 2 · 0, and the glass transition temperature of the ethylene-propylene random copolymer block is at -30 μM. The limiting viscosity ratio of this sister product to the ethylene-propylene copolymer component and the copolymerization component with the propylene homopolymer are in about the same range, and have excellent mechanical properties such as impact resistance and rigidity. Transparency, gloss, appearance, etc., especially the anti-whitening properties of molded products. 4- This paper size applies to China National Standard (CNS) A4 specification (210X 297 mm) 486501 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (5) K and molding shrinkage during molding still need to be improved. Japanese Patent Laid-Open No. 6-9306 proposes a polypropylene block copolymer, which polymerizes a propylene-based polymer at a total polymerization amount of 60 to 80 weight X, and then an ethylene content of 20 to 50 weight: "Ethylene- The propylene copolymerization section was added with a block copolymer obtained by W polymerization, and the limiting viscosity (U) b) of the ethylene-propylene copolymerization section was 2. 0dl / gK, and the limiting viscosity ratio ([n] B / U] A) of the two components is a block copolymer at 1.8M. The content M of the ethylene-propylene copolymerization component of this composition and the limiting viscosity ratio of the copolymerization component with the propylene homopolymer are also in the same range. Although it has excellent low-temperature impact resistance, sealing resistance, appearance, etc., The mechanical properties such as rigidity and the molding shrinkage during molding need to be improved. Japanese Patent Application Laid-Open No. 6-328640 proposes a multi-calendar film in which a polypropylene resin is applied to two areas of a straight low-density polyethylene layer to greatly improve the tear strength. In this multilayer film, the compatibility between the laminated low-density polyethylene and the polypropylene-based resin is not good. When the film is to be formed by melting, fish eyes are liable to occur. Japanese Patent Application Laid-Open No. 52-1 26450 discloses a three-component mixture including an ethylene-?-Olefin copolymer rubber, polypropylene or high-density polyethylene, K, and a paraffinic or naphthenic oil. This mixture is excellent in softness, but its heat resistance is reduced. Japanese Patent Application Laid-Open No. 4-282232 proposes a resinous tubular body in which a rigid portion formed of a rigid polyolefin resin and a flexible portion formed of a thermoplastic elastomer are added. connection. The rigid part and the flexible part of this tubular body have insufficient adhesive strength. -5 I (Please read the precautions on the back before filling this page) The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 486501 A7 B7 V. Description of the invention (4 The purpose of the present invention The purpose is to provide an acrylic resin composition and a method for preparing the same, which are suitable as matrix resins for polypropylene-based compositions. The impact resistance of various molded products, especially low-temperature impact resistance, rigidity, crack strength, heat resistance, and transparency Various characteristics such as properties, gloss, whitening resistance, and the molding shrinkage rate during molding are excellent, and the balance therebetween is also excellent. Another object of the present invention is to provide a polypropylene composition based on the above-mentioned propylene-based composition. It is a matrix resin. Another object of the present invention is to provide various molded articles using the above polypropylene-based composition and a method for producing the same. Details of the invention; printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back first) (Fill in this page again) In order to achieve the above purpose, the present inventors have conducted intensive research results. In the presence of a stereoregular catalyst using a large particle size titanium-containing solid catalyst component, the hairpin separates propylene, and then successively vapor-phase polymerizes the propylene and ethylene mixture to obtain a propylene homopolymer and a propylene-ethylene copolymer. Composition of propylene-based composition, the limiting viscosity of the propylene-ethylene copolymer, the limiting viscosity ratio of the two components, M and the product of the limiting viscosity ratio and the weight ratio of the two components, within a certain range, impact resistance, especially The invention has excellent low-temperature impact resistance, rigidity, transparency, gloss, whitening resistance, molding shrinkage during molding, and the balance among them, and completed the present invention. The propylene composition U) of the present invention is composed of polypropylene (PP) and propylene-ethylene copolymer (RC), and is characterized in that the limiting viscosity ([n] RG) of the propylene-ethylene copolymer (RC) is 1 . 7 ~ 2. 8dl / g; limiting viscosity ratio of propylene-ethylene copolymer (RC) to propylene homopolymer (PP) ([η] Re / [η] pp -6 A paper size applies to Chinese National Standard (CNS) A4 specifications ( 210X 297 mm) 486501 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 __ ^ _ B7 _ ^ _ V. Invention Description (5) is 0, 7 ~ 1. 2; and the weight ratio of propylene homopolymer (PP) to propylene-ethylene copolymer (RC) (Wpp / &gt; and its limiting viscosity ratio ([r?] ^ / [R?]) Π KC RC pp product ( [r?] RC / U] pp) x (· νρρ / WRC) is in the range of 1 · 0 ~ 3 · 0. Another invention is the method for producing the aforementioned propylene-based composition (A), which is characterized by including the first Polymerization step, that is, a titanium-containing solid catalyst component (a) with an average particle diameter of 25 to 300, a general formula A1R 1 (where R1 is a melon 5-m C 1 -20 hydrocarbon group, and X is a halogen atom, ia is 3 ^ n &gt; 1. A positive number of 5) The organoaluminum compound (b) shown; and the general formula R2xR3YSi (0R4) z (where R2 and R4 are hydrocarbon groups, R3 is a hydrocarbon group or a heteroatom-containing hydrocarbon group, X, Y, and Z are OSXS2, 1SYS3, IS ZS 3, and X + Y + Z = 4) organosilicon compound U); in the presence of the stereoregular catalyst, propylene is polymerized separately in the gas phase to produce a total weight of 78-60 weight. Propylene homopolymerization (PP); followed by the second polymerization step, ethylene and propylene are copolymerized, the ethylene unit content of the polymer is 25 ~ 55 weight S; propylene-ethylene copolymer (RC), to produce a full weight 22 ~ 40 weight S! Yet another invention is a polypropylene fluorene composition (C), and the aforementioned propylene composition (A) is a main component, and contains additives as needed. Yet another invention is a molded product (D) using the polypropylene-based composition, especially an injection molded product, a sheet, a film, and a hollow molded product.搿 明 夕 管 觖 形 鲔 In the propylene-based composition (A) of the present invention, a propylene homopolymer (PP) is an isotactic pentavalent fraction (P) 0. 95M on, and 0. Above 955 is the best high crystallinity, that is, three-dimensional regular polypropylene, propylene homopolymer (PP) -7- (Please read the precautions on the back before filling this page) This paper size applies to Chinese national standards (CNS ) A4 specification (210X 297 mm) 486501 A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. The isotactic pentad fraction (P) of the description of the invention (6) affects the rigidity of the molded product (D), Mechanical properties such as heat resistance, the larger the value, the greater the rigidity and heat resistance. On the other hand, propylene-ethylene copolymers (!? (:) are K-propylene-ethylene copolymers (RC) based on 簠 content, containing 25 to 55 weight χ, and preferably 30 to 55 weight. Random copolymer of propylene. The ethylene polymerization unit in the propylene-ethylene copolymer (RC) affects the rigidity, softness, and impact resistance of the molded product (D), especially low-temperature impact resistance and whitening resistance, which are so large as to be possible. Improve the softness and impact resistance, but if it is too large, it will affect the dispersibility of propylene-ethylene copolymer (RC) in propylene homopolymer (PP), and make the molded product (D) transparent, shiny and whitening resistant. And so on. Furthermore, the limiting viscosity ([T7] R (3) is 1. 7 ~ 2. 8dl / g range, and the limiting viscosity ratio ([π] only υ / [π] pp) between the limiting viscosity ([π]%) measured under the same conditions as the propylene homopolymer (PP) is 0.7 · 1 · 2, K0. 8 to 1. 2 range is better. Because the limiting viscosity ([π] RCJ) of propylene-ethylene copolymer (RC) cannot be measured directly, it is determined by the limiting viscosity ([η] pp) of propylene homopolymer (PP), which can be directly measured, and the propylene preparation composition. (A) The total limiting viscosity ([nlwHOM;) and the weight χ (ΐισ) of the propylene-ethylene copolymer (RC) are obtained by the following formula: [77] RC = ([n] WHOLE-(b%). / 100 ^ 77] PP) / (tfRC / 1 0 0) The limiting viscosity of the propylene-ethylene copolymer (RC) ([77] RC!), Which affects the molding cycle of the polypropylene resin composition (C) and manufactures films Film forming properties of the material, mechanical properties such as rigidity and heat buildup of the molded product (D), limiting viscosity ratio (U) aQ -8- of propylene-ethylene copolymer (RC) and propylene homopolymer (PP) Please read the notes on the back before filling in this page) This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 B7 V. Description of the invention (7) / [r?] Pp), affecting acrylic -Dispersibility of ethylene copolymer (RC) in propylene homopolymer (PP). The larger the limiting viscosity ([n] Ra) of propylene-ethylene copolymer (RC), the more it can improve the mechanical properties of the molded product (D). However, the molding cycle of the polypropylene-based composition (C) is reduced, and even if the limiting viscosity ratio ([n] Re / [77] pi &gt;) to the propylene homopolymer (PP) is too large or too small, the molded product ( D) Impact resistance and whitening resistance at low temperature are still insufficient. When it is too small, the flexibility of the molded product (D) is insufficient. When it is too large, the molding shrinkage of the polypropylene strip composition (C) and the molded product (D ) The transparency improvement effect is reduced, and the desired characteristics are not achieved. Propylene-ethylene copolymer (RC) M Propylene-ethylene copolymer (RC) weight is based on 80% by weight ": On M, the weight of M85 is the best 201C xylene Soluble. 20 重量 xylene soluble weight S of propylene-ethylene copolymer (RC); (cxsRa) is not determined directly, but is based on the 20% xylene soluble weight% of propylene homopolymer (PP). (CXSpp), and the composition (A &gt; the total 20¾ xylene solubles weight 3: (CXS ^ mjj), K and the weight% (WRe) of propylene-ethylene copolymer (RC)), calculated by the following formula: CXSRC = {CXSra〇LE- (l-WRC / 100) CXSpp} / (WRC / 100) Printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the note on the back first) Please fill in this page again) In the propylene-based composition (A) of the present invention, the weight ratio of propylene homopolymer (PP) to propylene-ethylene copolymer (RC) (Wpp /, and the limiting viscosity ratio of the first two components ( The product of [π] βσ / [77), ([n] RC / [r?] pp) x (Wp; p / W RC), is in the range of 1 · 0 x 3 · 0. The product of the two-component weight ratio and the limiting viscosity ratio is an index indicating the molding shrinkage of the polypropylene-based composition (C). If the value is small, the molding shrinkage ratio M and the tensile strength and weld strength of the molded product (D) have been improved, but the molding-9- This paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 486501 Ministry of Economic Affairs A7 printed by the Consumer Standards Cooperative of the Central Bureau of Standards __B7_ V. Description of the invention (8) The reduction in heat resistance or rigidity of the product (D) will increase. On the other hand, the larger the value, the lower the whitening resistance, and the target shrinkage rate. It is difficult to improve the tensile strength and welding strength. _ The specific composition of the propylene-based composition (A) and the weight of the M-component (A). Based on the propylene-ethylene copolymer (RC), it is preferably 22 to 40 weights, and KK 25 to 40 weights is preferably X. In addition, the acrylic product (Α) has a Q value (Mw / Mn) under 5 Μ, preferably 4. Narrow dispersive molecular weight distribution at 5K. The larger the molecular weight distribution, the lower the gloss and weld strength of the molded product (D). Since the propylene-based composition (A) of the present invention can satisfy the above-mentioned characteristics, it is suitable for use as a matrix resin of the polypropylene-based composition (C), a molded article made therefrom, a molding shrinkage rate and film-forming property during molding, and κ And the transparency, gloss, rigidity, flexibility, and impact resistance of molded products, especially low temperature impact resistance, tensile strength, welding strength and other mechanical properties, and the balance between them are excellent. This invention is acrylic. The composition (A) can be produced by any method as long as it meets the above-mentioned characteristics. For example, propylene homopolymer (PP) and propylene-ethylene copolymer (RC), which are separately produced, are mixed using a mixing device, but it is better to use the method of the present invention. The production method of the propylene-based composition (A) of the present invention is characterized in that in the presence of a three-dimensional regular catalyst composed of a large-diameter titanium-containing solid catalyst (a), an organoaluminum compound (b), and an organosilicon compound U), The first phase in the gas phase produces / V propylene homopolymers (first polymerization step), followed by the second phase to produce propylene-ethylene copolymers (second polymerization step). I-10-(Please read the precautions on the back before filling this page) This paper size applies the Chinese National Standard (CNS) A4 specification (210X297mm) 486501 A7 ________ ΪB7 V. Description of the invention (9) The method of the invention contains titanium The solid catalyst component (a) is known to be used on inorganic carriers such as magnesium compounds, silicon oxide compounds, alumina, or organic carriers such as polystyrene to support titanium compounds, and if necessary, make electrons of ethers and esters The donor compound is obtained by reacting to this support. For example, an alcohol solution of a magnesium compound is sprayed, and the solid component is partially dried, and then the titanium solid halide and the electron donor compound are processed to dry the solid component to obtain a titanium-containing solid catalyst component (Japanese Patent Application Laid-Open No. 3-1 1 9003). &gt; and dissolving magnesium compound in tetrahydrofuran / alcohol / electron donor, KTiCl4 alone or in combination with the electron donor compound, the magnesium monomer precipitated, treated with titanium halide and electron donor compound to obtain a titanium-containing solid catalyst component (Japanese Patent Application Laid-Open No. 4-103604). The titanium-containing solid catalyst component (a) uses an average particle size of 25 ~ 300 & preferably 30 ~ 15G # in. When the average particle diameter of the titanium-containing catalyst component is 25 aroM, the powder flowability of the produced acrylonitrile composition (A) is significantly impaired, and the polymerization system is contaminated due to adhesion to the wall of the polymerizer or stirring blade M In addition, it is difficult to convey the powder and the like discharged from the polymerizer, which greatly hinders the stable operation. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) In addition, the uniformity of the titanium-containing catalyst component (a) in the normal distribution is 2. 0 K is preferred. When the uniformity exceeds 2, the powder flowability of the propylene-based composition (A) is deteriorated, and it is difficult to continuously and stably operate the first polymerization step and the second polymerization step. The organoaluminum compound (b) may be an organoaluminum compound m i-m represented by the general formula 1R Xq, where RigCi-20 hydrocarbon group, X is a halogen atom, and m is 32 m &gt; 1. A positive number of 5. -11- This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) 486501 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (10). Specific examples are trimethylaluminum, triethylaluminum, tri-n-propylaluminum, tri-n-butylaluminum, triisobutyllithium, dimethylaluminum chloride, diethylaluminum chloride, methyltrichloride Di aluminum, di-n-propyl aluminum monochloride, ethyl aluminum dichloride, ethyl aluminum dichloride, diethyl aluminum iodide, ethoxy diethyl aluminum, etc., K triethyl aluminum is preferred . These organoaluminum compounds may be used singly or as a mixture of two or more. The organosilicon compound (C) can be represented by the general formula R2 R3 Si (0R4) Λ.  JL 2f organic silicon compound, in which R2 and R4 are hydrocarbon groups, R3 is a hydrocarbon group or a heteroatom-containing hydrocarbon group, X, Y and Z are 0 蠤 X 蠤 2, 1SYS3, 1 蠤 Z 3 3, and X + Y + Z = 4. Specific examples are methyltrimethoxysilane, ethyltrimethoxysilane, n-propyltrimethoxysilane, phenylmethyldimethoxysilane, tert-butyltrimethoxysilane, tert-butyltriethoxy Silane, phenyltriethoxysilane, methylethyldimethoxysilane, methylphenyldiethoxysilane, dimethyldimethoxysilane, dimethyldiethoxysilane, Isopropyldimethoxysilane, diisobutyldimethoxysilane, ditert-butyldimethoxysilane, diphenyldimethoxysilane, trimethylmethoxysilane, cyclohexylmethyl Dimethoxysilane, trimethylethoxysilane, etc., while M diisobutyldimethoxysilane, diisopropyldimethoxysilane, ditert-butyldimethoxysilane, cyclohexylmethyl Phenylmethoxysilane and diphenyldimethoxysilane are preferred. These organosilicon compounds may be used singly or as a mixture of two or more kinds. The preparation method of the propylene-based composition (A) of the present invention should preferably be pre-activated. -12-(Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297) (Centi) 486501 A7 B7 5. Description of the invention (11), that is, before the first polymerization of propylene alone, the titanium-containing solid catalyst component U), the organoaluminum compound (b ') and, if necessary, the organosilicon compound ( C ') Preliminarily react the α-olefin. In the pre-activation treatment of the titanium-containing solid catalyst component (a), the use amount of the organoaluminum compound (b ') is not particularly limited, but it is usually 1 mole relative to the titanium atom in the titanium-containing solid catalyst component, and 0 .  1 ~ 40 Mor, K 0. The range of 3 to 20 moles is better, so that the a-olefin is 10 to 80 ¾ over 10 minutes to 48 hours, relative to 1 g of the titanium-containing solid catalyst component, K0. 1 ~ 100 grams, preferably 0.  5 to 50 grams of reaction. In the pre-activation treatment, a silane compound (c ') is used in advance, and 0. 01 ~ 10 Mor, K0. A range of 05 to 5 moles is preferred. The organoaluminum used in the above pre-activation treatment (bl, the organoaluminum (b) shown in the previous example used during polymerization. This (B ') organoaluminum compound (bf) may be the same or different from the organoaluminum compound (b) used in the polymerization. K triethylaluminum is preferred. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). The organosilicon compound U 'used as required during pre-activation treatment. The aforementioned are the same as the organosilicon compound (c). The organosilicon compound ((^) may be the same or different from the organosilicon compound U) used for polymerization. To use diisobutyldimethoxysilane, diisopropyldimethoxysilane, ditert-butyldimethoxysilane, cyclohexylmethyldimethoxysilane, and diphenyldimethoxy Sand burning is preferred. • Contains solid catalyst component U) The olefins used in pre-activation treatment are ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-octene, 1-decene. This paper is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 486501 A7 B7 V. Description of the invention (l2) 1-dodecene, 1-tetradecene, 1-hexadecene, 1-octadecene Ene, 1-eicosene, 4-methyl-1-pentene, 3-methyl-1-pentamidine and the like. These olefins are not only used alone, but can also be mixed with other olefins in one or two kinds of K. During polymerization, a molecular weight regulator such as hydrogen may be used in combination, and M may be used to adjust the molecular weight of the polymer. Titanium-containing solid catalyst component U) Inert solvents used for pre-activation treatment, such as p-hexane, heptane, octane, decane, dodecane, liquid saturated hydrocarbons such as liquid alkylene, or dimethyl polymer An inert solvent that does not have a significant effect on the polymerization reaction, such as silicone varnish, which is a structure of silicone. These inert solvents may be one single solvent or a mixture of two or more solvents. When using these inert solvents, it is advisable to remove impurities such as water and sulfur compounds that have an adverse effect on the polymerization. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) In the method for producing the propylene-based composition (A) of the present invention, the titanium-containing solid catalyst component U obtained in the above pre-activation treatment) In the presence of, propylene is polymerized in the gas phase, K is a first polymerization step of propylene homopolymer (PP), then ethylene and propylene are copolymerized, K is a second polymerization step of propylene-ethylene copolymer (RC), Add M consecutive performance. The first polymerization step is not limited to gas phase polymerization, and slurry polymerization or block polymerization can also be used. However, the second polymerization step M is preferably a gas phase polymerization, so the first polymerization step is also preferably a gas phase polymerization. When slurry polymerization or block polymerization is used in the second polymerization step, the propylene-ethylene copolymer (RC) will dissolve from the solution, and it is difficult to continue the stabilization operation. The polymerization conditions of propylene homopolymer (PP) vary depending on the polymerization form. In terms of the gas phase polymerization method, in a certain amount of powder mixing, the pre-activated titanium-containing solid catalyst component U), the organoaluminum component (B) and organosilicon compound (c) in the presence of a stereoregular catalyst, K polymerization temperature -14- This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 486501 A7 B7 V. Description of the invention (15) 20 ~ 120 * 0, preferably 40 ~ 100C, polymerization pressure at atmospheric pressure ~ 9. 9 MPa, preferably 0. 59 ~ 5. At a pressure of 0 MPa, propylene was added and polymerized to produce a propylene homopolymer (A). The use rate of the organoaluminum compound (b) and the titanium-containing solid catalyst component (a) is Al / Ti = 1 to 500 (molar ratio), and M10 to 300 is preferred. In this case, the molar number of the titanium-containing solid catalyst component U) means the number of titanium atoms in the titanium-containing solid catalyst component U). The use rate of the organosilicon compound (c) and the organoaluminum compound (b) is b / c = 1 to 10 (molar ratio), preferably ι · 5 to 8. When the b / c mole is too large, the crystallinity of the propylene homopolymer (P P) decreases, and the rigidity of the molded article (D) becomes insufficient. In addition, if the b / c mole ratio is too small, the polymerization activity is significantly reduced, and the productivity is decreased. The molecular weight of the propylene homopolymer (PP) can be adjusted by using a molecular weight modifier such as hydrogen during polymerization, so that the limiting viscosity of the propylene homopolymer (PP) conforms to the requirements of the present invention. After the polymerization of propylene homopolymer (PP), a part of the resulting powder was taken out to provide the limiting viscosity ([η Ipp), melt flow rate (MFR pp), 20 1C xylene solubles content and isotactic fraction (P) Measurement, polymerization yield per unit weight of M and catalyst. / Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). After the propylene is polymerized separately in the first polymerization step, the second polymerization step is performed, that is, at a polymerization temperature of 20 ~ 120¾. Good 40 ~ 100C, polymerization pressure is at atmospheric pressure ~ 9. 9MPa, Μ59.59 ~ 5. Under the condition of 0 MPa, a mixed monomer of ethylene and propylene was copolymerized with M to produce a propylene-ethylene copolymer (RC). The ethylene unit content in the propylene-ethylene copolymer (RC) can control the gas mole ratio of the ethylene monomer to the propylene monomer in the copolymer gas, and is adjusted to the ethylene unit content in the propylene-ethylene copolymer (RC). Paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 B7 V. Description of the invention (14) 25 ~ 55 weight S !. On the other hand, compared with the weight of propylene homopolymer (PP), the weight of propylene-ethylene copolymer (RC) is adjusted to propylene using the polymerization time adjustment or the polymerization activity modifier of catalysts such as carbon monoxide and hydrogen sulfide. The ethylene copolymer (RC) has a weight of 22 to 40 weight. Moreover, the molecular weight of the propylene-ethylene copolymer (RC) is based on the adjustment of molecular weight regulators such as hydrogen during the polymerization of the propylene-ethylene copolymer so that the limiting viscosity of the propylene-ethylene copolymer (RC) conforms to the propylene-based composition (A ). In addition, the method of supplying hydrogen is a Q value (Mw / Mn) supplied to the propylene-based composition (A), which meets the requirements for the propylene-based composition (A). The polymerization method can be batch, anti-continuous or continuous, and K continuous polymerization is preferred in the industry. After the second polymerization step is completed, the monomer is removed from the polymerization system to obtain a granular polymer. The obtained polymer can be used to measure the limiting viscosity ([η]), the 20C xylene solubles content, the Q value (Mw / Mn), and the ethylene content, and the polymerization yield per unit weight of the catalyst and catalyst. The polypropylene-based composition (C) of the present invention is a composition obtained by using the aforementioned propylene-based composition (A) as a matrix resin, and mixing the corresponding added ingredients according to the required characteristics and molding method of the molded product. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page) The additives commonly used in the polypropylene composition (C) of the present invention can be general additives for polyolefin compositions, such as Antioxidants, such as phenol-based, thioether phosphonium, and phosphorus-based antioxidants; dispersants or neutralizers, such as higher fatty acid salts (metal soaps) such as calcium stearate; light stabilizers; polymetal deactivators (Copper harm preventive agent); transparent agent; / 3 crystal core This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (15) agents; lubricants, such as ammonium stearate, etc .; antistatic agents, such as fatty acid esters such as glyceryl monostearate, etc .; antifog agents; no drops; flame retardants; flame retardant additives; Pigments; halogen trapping agents; organic or inorganic antibacterial agents; inorganic fillers and blocking preventives, such as slip powder, mica, clay, wollastonite, zeolite, kaolin, bentonite, pearlite, diatomaceous earth, stone Cotton, calcium carbonate, magnesium carbonate, aluminum hydroxide, magnesium hydroxide, hydrated talc, alkaline lithium aluminum carbonate hydrate, silicon dioxide, titanium dioxide, zinc oxide, magnesium oxide, calcium oxide, zinc oxide, barium sulfate, sulfuric acid Magnesium, calcium silicate, aluminum silicate, glass fiber, potassium titanate, carbon fiber, carbon black, graphite, and metal fiber, etc. Coupling agents, such as silane, titanate, boron, aluminate, aluminate IS 糸, etc., and this surface-treated inorganic filler or organic filler, such as wood flour, pulp, used paper, synthetic fibers, natural fibers, etc., usually the content K does not impair the purpose of the present invention. Generally speaking, calcium stearate is added to the polypropylene resin composition (C) as a phenol-based antioxidant and / or a phosphate-based antioxidant K and a neutralizer (dispersing agent). The aforementioned polyolefin used in the present invention is a polypropylene strip composition (C) compounded as a general additive, and is suitable for the polypropylene composition (Ci) for injection molding and the polypropylene resin composition (Cs) for sheet molding. Polypropylene resin composition (Cf) for film formation. In addition, in the polypropylene-based composition (Ci), 0 (crystal nucleating agent 0. 100%) is blended with respect to 100 parts by weight of the propylene-based composition (A). 〇〇〇1 ~ 1 parts by weight, M0. 001 ~ 0. 8 parts by weight is preferred to further increase the rigidity and low temperature impact resistance of the injection molded product. -17- (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 size (210X 297 mm) 486501 A7 B7 V. Description of the invention (l6) Powder, alum, silicon oxide, titanium oxide, calcium oxide, magnesium oxide, carbon black, clay minerals and other inorganic compounds; malonic acid, succinic acid, / acid, adipic acid, maleic acid, azelaic acid, sebacic acid , Dodecanedioic acid, citric acid, succinic acid, succinic acid, naphthenic acid, cyclopentanecarboxylic acid, 1-methylcyclopentanecarboxylic acid, 2-methylcyclopentanecarboxylic acid, cyclohexane Post-alkane acid, 1-methylcyclohexanecarboxylic acid, 4-methylcyclohexanecarboxylic acid, 3,5-dimethylcyclohexanecarboxylic acid, 4-butylcyclohexanecarboxylic acid, 4-octyl Cyclohexanecarboxylic acid, 4-cyclohexane-1,2-dicarboxylic acid, benzoic acid, phenylacetic acid, xylene acid, ethylbenzoic acid, 4-tert-butylbenzoic acid, salicylic acid, benzenedicarboxylic acid Carboxylic acids other than aliphatic monocarboxylic acids such as formic acid, trimellitic acid and pyromellitic acid; lithium, sodium, potassium, magnesium, calcium, rubidium, barium, zinc, aluminum and other normal salts of the aforementioned non-fatty acid monocarboxylic acids or Basic base; 1,2,3 · 4-dibenzylidene Sorbitol, 1,3-benzylidene-2 · 4-p-methylbenzylidene sorbitol, 1,3-benzylidene-2 · 4-p-ethylpentaidene sorbitol, 1,3-p-formyl Benzylidene-2 · 4-benzylidene sorbitol, 1,3-p-ethylbenzylidene-2 · 4-benzylidene sorbitol, 1,3-p-ethylbenzylidene-2 · 4-p-formyl Benzylidene Sorbitol, 1.3, 2, 4-bis (p-methylbenzylidene) sorbitol, 1.3, 2 · 4- (p-ethylbenzylidene) sorbitol, 1.3, 2 · 4-bis (p-n-propylbenzylidene) sorbitol, 1 · 3,2 · 4-bis (p-isopropylbenzylidene) sorbitol, 1 · 3,2 · 4-bis (paired Butyl benzyl fork) Sorbitol, printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) 1 · 3,2 · 4-bis (p-butyl benzyl fork) Sugar alcohol, 1, 3, 2 · 4-bis (p-tert-butyl benzylidene) sorbitol, 1. 3- (2 '· 4f-dimethylbenzylidene)-2 · 4-benzylidene sorbitol , 1, 3-benzylidene-2, 4- (2, 4 · -dimethylbenzylidene) sorbitol, 1, 3, 2 · 4-bis (2 '· 4 dimethylbenzylidene) sorbitol Sugar alcohol, 1 · 3,2 · 4 -bis (3 * · 4'-dimethylbenzyl fork) sorbose-18 One paper size Applicable to China National Standard (CNS) A4 specification (210X 297 mm) 486501 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 _ B7 V. Description of the invention (、) Alcohol, 1 · 3,2 · 4-double (pair A Oxybenzyl) sorbitol, 1 · 3,2 · 4- (p-ethoxybenzyl fork) sorbitol, 1 · 3-benzyl fork-2 · 4-p-chlorobenzyl fork sorbitol, 1 · 3-p-chlorobenzylidene-2 · 4-benzylidene sorbitol, 1 · 3-p-chlorobenzylidene_2 · 4-p-methylbenzylidene sorbitol, 1 · 3-p-chlorobenzylidene-2 · 4-p-ethylbenzylidene sorbitol, 1.3-p-methylbenzylidene-2.4-p-chlorobenzylidene sorbitol, and 1.3,2.4-bis (p-chlorobenzylidene) sorbitol Dibenzylidene sorbitol compounds such as sugar alcohols; lithium bis (4-tert-butylphenyl) phosphate, sodium bis (4-tert-butylphenyl) phosphate, lithium bis (4-tert-phenylphenyl) phosphate , Sodium bis (4-tert-phenylphenyl) phosphate, potassium bis (4-tert-butylphenyl) phosphate, calcium mono (4-tert-butylphenyl) phosphate, bis (4-tert-butylphenyl) Calcium phosphate, mono (4-tert-butylphenyl) magnesium phosphate, bis (4-tert-butylphenyl) magnesium phosphate, zinc mono (4-tert-butylphenyl) phosphate Bis (4-tert-butylbenzyl) zinc phosphate, hydroxy (4-tert-butylphenyl) aluminum phosphate, hydroxy (4-tert-butylbenzyl) aluminum phosphate, tris (4-tert-butylphenyl) phosphate Aluminum, 2,2'methylene bis (4,6-di-tert-butylphenyl) phosphate, sodium 2,2'-ethylidene bis (4,6-di-tert-butylphenyl) phosphate, 2,2 '-Methylenebis (4-fluorenyl-6-tert-butylphenyl) sodium phosphate, 2,2'-Methylenebis (4,6-ditert-butylphenyl) lithium phosphate, 2,2 ^ ethyl Lithium bis (4,6-ditert-butylphenyl) phosphate, lithium 2,2'-methylenebis (4-fluorenyl-6-tert-butylphenyl) phosphate, 2,2'-ethylidenebis (4-isopropyl-6-tert-butylphenyl) sodium phosphate, 2,2'-methylenebis (4-methyl-6-tert-butylphenyl) lithium phosphate, 2,2f-methylenebis (4-ethyl-6-tert-butylphenyl) lithium phosphate, 2,2'-butylidenebis (4,6-dimethylphenyl) sodium phosphate, 2,2'-butylidenebis (4, 6-Di-tert-butylphenyl) sodium phosphate, 2,2'-Texylmethylenebis (4,6-dimethylphenyl) sodium phosphate, 2,2'-Tyctylmethylenebis (4 , 6- 二 特 一 19 1 (Please read the notes on the back before filling this page) This paper size is applicable to China Standard (CNS) A4 (210X297 mm) 486501 A7 B7 V. Description of the invention (18) Butylphenyl) sodium phosphate, 2,2'-methylenebis (4-methyl-6-tert-butylbenzyl) ) Sodium phosphate, 2,2'-methylenebis (4-ethyl-6-tert-butylphenyl) sodium phosphate, (4, dimethyl-6,6 · -ditert-butyl-2,2 ' -Sodium diphenyl) sodium phosphate, 2,2'-Ethylene bis (4-_butylene-6-tert-butylphenyl) sodium phosphate, 2,2f-Methylenebis (4,6-dimethylbenzene) Methyl) sodium phosphate, sodium 2,2'-methylenebis (4,6-diethylphenyl) phosphate, potassium 2,2'-ethylidenebis (4,6-di-tert-butylphenyl) phosphate, Bis [2,2'-methylenebis (4,6-di-tert-butylphenyl) phosphate] calcium, bis [2,2'-methylenebis (4,6-di-tert-butylphenyl) phosphate] Magnesium, bis [2,2 'Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page)-Methylenebis (4,6-di-tert-butylphenyl) phosphate] Zinc , Tris [2,2 * -methylenebis (4,6-di-tert-butylphenyl) phosphate] aluminum, bis [2,2'-methylenebisU-methyl-6-tert-butylphenyl) Phosphate] calcium, bis [2,2 ^ ethylidenebis (4,6-di-tert-butylbenzyl) phosphate] calcium, bis [2,2'- Bis (4-methyl-6-tert-butylphenyl) phosphate] calcium, bis [2,2'-thiobis (4-ethyl-6-tert-butylphenyl) phosphate] calcium, bis [ 2,2 ^ thiobis (4,6-di-tert-butylphenyl) phosphate] calcium, bis [2,2'-thiobis (4,6-di-tert-butylphenyl) phosphate] magnesium, bis [2, 2'-thiobis (4-teoctylphenyl) phosphate] magnesium, bis [2,21-methylenebis (4,6-di-tert-butylphenyl) phosphate] barium, bis [ (4, 4-dimethyl-6,6'-di-tert-butyl-2,2'-diphenyl) phosphate] calcium, bis [2,2'-ethylidene bis (4,6-ditert-butyl) Phenyl) phosphate] magnesium, bis [2,2'-ethylidenebis (4,6-di-tert-butylphenyl) phosphate] barium, tris [2,2 ^ ethylidenebis (4,6-diterephthalate) Butylphenyl) phosphoric acid] aluminum, dihydroxy-2,2f_methylenebis (4,6-di-tert-butylphenyl) aluminum phosphate, dihydroxy-2, methylenebis (4-fluorenyl-6- Tert-butylphenyl) aluminum phosphate, hydroxybis [2,2'-methylenebis (4,6-ditert-butylphenyl) phosphate] aluminum, hydroxybis [2,2'-methylenebis (4- Cumyl-6-tert-butylphenyl) phosphoric acid] This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 486501 A7 __B7___ V. Description of the invention ( 19) Aluminum, dihydroxybis [2,2'-methylene · bis (4,6-di-tert-butylphenyl) phosphoric acid] titanium, dibasic bis [2,2 · -methylenebis (4,6 -Di-tert-butylphenyl) phosphoric acid] Consumption cooperation between employees of the Central Bureau of Standards of the Ministry of Economic Affairs, printed tin and oxobis [2,2'-methylenebis (4, · 6-di-tert-butylphenyl) phosphoric acid] _, Dihydroxy-2,2'-methylenebis (4-methyl-6-tert-butylphenyl) aluminium phosphonate, dihydroxy-2,2'-methylenebis (4-methyl-6- Tert-butylphenyl) aluminum phosphate, dihydroxy-2, 2 * -ethylidene bis (4,6-ditert-butylphenyl) aluminum phosphate, hydroxybis [2,2 ^ ethylidenebis (4,6- Ditert-butylphenyl) phosphate] aryl phosphate rhenium compounds such as aluminum; among the aforementioned aryl phosphate-based compounds, fluorene-like polyvalent metal aryl phosphate rhenium compounds and acetic acid, lactic acid, propionic acid, acrylic acid, caprylic acid, Isooctanoic acid, nonanoic acid, decanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, 12-hydroxystearic acid, ricinic acid, mountain acid, mustard Acid, moronic acid, peak flower acid, stearyl lactic acid, / 3-N-laurylaminopropionic acid, / Ϊ-N-methyl-fluorene-lauric acid aminopropionic acid Alkali metal salts of fatty acid monocarboxylic acids, such as lithium, sodium or potassium salts of fatty acid monocarboxylic acids, or mixtures with basic lithium aluminum hydroxycarbonate hydrates; poly3-methyl-1-butene, poly3-methyl 1-pentene, poly 3-ethyl-1-pentene, poly 4-methyl-1-pentene, poly 4-methyl-1-hexene, poly 4,4-dimethyl-1 -Pentene, poly 4,4-dimethyl-1-hexene, poly 4-ethyl-1-hexene, poly 3-ethyl-1-hexene, polyallyl naphthalene, polyallyl Orthopane, heteropolyethylene, syndiotactic polyethylene, polydimethylstyrene, polyvinyl #, polyallylbenzene, polyallyltoluene, polyvinylcyclopentane, polyvinylcyclohexane Polymer compounds such as alkane, polyvinylcycloheptane, polyvinyltrimethylsilane, polyallyltrimethylsilane, etc. Among them, MU powder, aluminum bis (4-tert-butylbenzoate), 1, 3, 486501 A7 B7 5. Description of the invention (20) 2, 4-dibenzylidene sorbitol, 1, 3, 2 · 4-bis (p-methylbenzylidene) sorbitol, 1.3 · 2 · 4-bis (p-ethylbenzylidene) sorbitol, 1.3 · 2 · 4-bis (2 ·, 4 *- Dimethylbenzyl fork) · Sorbitol, 1 · 3,2 · 4-bis (3,4'-dimethylbenzylidene) sorbitol, 1 · 3-P-chlorobenzyl fork-2 · 4-pair Methyl benzyl sorbitol, 1 · 3,2 · 4-bis (p-chlorobenzyl fork) sorbitol, sodium bis (4-tert-butylphenyl) phosphate, 2,2'-methylenebis ( Sodium 4,6-di-tert-butylphenyl) phosphate, 2,2'-methylenebis (4,6-di-tert-butylphenyl) calcium phosphate, 2,2 夂 Methylenebis (4,6- Ditert-butylphenyl) aluminum phosphate, dihydroxy-2,2'-methylenebis (4,6-ditert-butylphenyl) aluminum phosphate, or hydroxybis [2,2'-methylenebis ( Mixtures of cyclic polyvalent metal aryl phosphate phosphonium compounds such as 4,6-di-tert-butylphenyl) butyl aluminum phosphate and fatty acid monocarboxylic acid alkali metal salts, poly3-methyl-1-butene, polyethylene Cyclohexane or polyallyltrimethylsilane is preferred . It is needless to say that these α crystal nucleating agents may be used alone, or two kinds of α crystal nucleating agents on K may be used in combination. In the aforementioned polypropylene fluorene composition (Ci), a radical generator and a crystalline propylene homopolymer (PHP) can be further blended to further improve the whitening resistance of the injection molded product. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. The density of the compounded crystalline propylene homopolymer (P P) is 0.  9 1 ~ 0.  8 9 g / cm 3, and the melt flow ratio of the propylene-based composition (A) and the crystalline propylene homopolymer (P HP) / MFRph) 0. 5 ~ 2, preferably 0. 8 ~ 1.  2 propylene homopolymer. In this composition, the MFR ratio of the propylene fluorene composition (A) to the crystalline propylene homopolymer (Ph). Affects the whitening resistance of the molded product, whether it is too large-22-486501 A7 B7 V. Description of the invention (2: L) or too small, its whitening resistance is insufficient. The mixing ratio of the crystalline propylene-based composition (P Η P) is 10 to 95% by weight of the resin, the propylene-based composition. The content of the substance (A) · is 5 to 90 weight S: range of the resin in terms of the balance between rigidity and impact resistance of the molded product. That is, in this composition, the acrylonitrile composition (A) has an anti-whitening agent function to prevent whitening of the molded product. Therefore, the composition is suitable for molding a molded product having a bent portion such as a hinge or a container plug. On the other hand, the radical generator can improve the fluidization of the compound and significantly improve the moldability. In order to obtain a homogeneous composition, the decomposition temperature of the free radical generator should not be too low. In order to obtain a half-life of 10 hours, the temperature is preferably at 70t! K, K100t: K. For example, benzoate peroxy, tert-butyl perbenzoate, tert-butyl peracetate, tert-butyl peroxyisopropyl carbonate, 2,5-dimethyl-2,5-di (terbenzylperoxy ) Hexane, 2,5-dimethyl-2,5-di (terbenzylideneoxy) hexyne-3, tert-butyl diperoxydiacetate, peroxy-3,5,5-trimethyl Tert-butylhexanoate, methyl ethyl ketone peroxide, cyclohexanone peroxy, di-tert-butyl peroxy, dicumyl peroxy, 2,5-dimethyl-2,5-di (tert-butyl peroxy ) Hexane, printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) 2,5_dimethyl-2,5-di (tert-butylperoxy) hexyne_ 3.1,3-bis (tert-butylperoxyisopropyl) benzene, tert-butylfluorenylperoxy, 1,1-bis (tert-butylperoxy) -3,3,5-trimethylcyclohexane , 1,1-bis (tert-butylperoxy) cyclohexane, 2,2-bis (tert-butylperoxybutane), p-quatane hydroperoxide, diisopropylbenzeneperoxyhydrogen, pinene Hydrogen peroxide, tert-butyl hydroperoxide, p-perhydrocarbon hydroperoxide, 1,1,3,3-tetramethylbutyl hydroperoxide, and 2,5-dimethyl-2,5-di (Hydrogen peroxide) Organic peroxides such as hexane. You K2,5-dimethyl-2,5 This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 486501 A7 B7 V. Description of the invention (22)-2 (tert-butylperoxy) hexane 2,5-dimethyl-2,5-di (tert-butylperoxy) hexyne-3, and 1,3-bis (tert-butylperoxyisopropyl) benzene are preferred. These free radical generating agents may be used alone or in combination of two kinds. The polypropylene-based composition (C) compounded with the general additives in the polyolefin of the present invention can also be used as a polypropylene-based composition (Cb) for molding hollow molded products. Here, the polypropylene-based composition (Cb) may be blended with 5 to 20 parts by weight of a plasticizable component relative to 100 parts by weight of the propylene acryl composition (A) to impart flexibility to a molded product. Plasticizable ingredients (Ps) are generally referred to as low-density polyethylene, with a density of 0. 910 to 0. 93〇g / cm3, crystalline melting point (Tm) 100 ~ 115C, melt flow rate (MFR: 190Ρ; 21 · 18N) 0.1 ~ 5g / 10 ·, preferably 0. 1 ~ lg / 10 ′ ethylene homopolymer and ethylene-α-olefin copolymer, M and density 0. 92 ~ 0. 935g / Cm3, crystalline melting point (Tm) 90 ~ 10810, melt flow rate (MFR: 1901; 21 · 18N) 0 · 1 ~ 5g / 10f, preferably 0 · 1 ~ lg / 1 (Γ of ethylene-vinyl acetate Ester copolymer. The blend of plasticizable ingredients can impart flexibility to the molded product, so this polypropylene-based composition (Cb) is suitable for molding hollow molded products and films with a bellows structure. Central Bureau of Standards, Ministry of Economic Affairs Printed by employee consumer cooperatives (please read the precautions on the back before filling out this page) The above polypropylene stilbene composition of the present invention is a propylene-based composition (A) and each additional component as required, using a high-speed mixing device For example, Henschel mixer (trade name), ribbon mixer, vibrating mixer, etc. are used for mixing, using single-shaft extruder, double-shaft extruder, kneader, etc., 150 ~ 300¾, preferably 200 ~ 2501 is melt-blended and granulated, K is used for molding of various molded products.-24-This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 B7 V. Description of the invention (25) The invention Molded products are made of various polypropylene-based compositions in various molding methods. Molded product. The molded product of the first specific example is an injection molded product. Specifically, it is a molded product obtained by injection molding of the aforementioned polypropylene-based composition particles, such as a sheet-shaped molded product, a container and a container plug, and a hinge. Polypropylene-based composition for injection molding can be used for all fronts, but K is best to use polypropylene-based composition (Ci) for injection molding. Due to the molding object and the required characteristics, Μ uses a composition in which a radical generator and / or a crystalline propylene homopolymer is mixed. By using these polypropylene-based compositions (Ci), it is possible to manufacture a bent portion (a hinge structure portion, etc.) Injection molded products with excellent whitening resistance, transparency, gloss, properties, and impact resistance, especially low temperature impact resistance, molding shrinkage during molding, and their balance. The molded product of the second specific example of the present invention is In terms of printability and softness of the sheet, the sheet has a Young's coefficient of 2310 in the longitudinal direction of 200 to 450 MPa, preferably 300 to 400 MPa, and a 501C longitudinal tensile flexion axillary point strength of 15 MPa or more, W17 MPa κ Better. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Education (please read the precautions on the back before filling out this page). Although the sacrificial material of the present invention can be manufactured by any known sheet molding method, due to its good productivity, M extrusion molding or Calendering is better. Specifically, it can be used with an extruder, T mold, polishing roller (cooling roller), guide roller, roll roller, trimmer, masker, fixed-length cutter, stacker, etc. Step device (T mold sheet forming machine) of the T mold method, K and use of a Banbury black mixer, mixing roller, worm roller, extruder, calender roller, cooling roller, trimmer, masker, stator Steps such as long cutter, winder, etc.-25- 486501 A7 B7 V. Description of the invention (24) The device (calender molding machine) forms the sheet. More preferably, using the sheet manufacturing method of the present invention, that is, the T-die method, the aforementioned polypropylene-based composition (C), preferably the same polypropylene-based composition (Cs) as disclosed by injection molding, is at a resin temperature of 180. Extrude ~ 3001C, set the cooling roller temperature to 5 ~ 80¾, and the temperature difference from the resin is 120¾ Κ, K sheet speed 0.  1 to 100 m / in i η 〇 When the resin temperature is in the range of 180 to 300 1C, the polypropylene composition (Cs) can be fully melted, and in a range that will not be thermally deteriorated, the melting tension of the sheet can be maintained Good formability, and a sheet with no sharkskin surface and excellent appearance can be obtained. When the temperature of the cooling roller is above 5CK, there will be no condensation on the cooling mixture, and no spot-like pattern will occur on the surface of the sheet, while under 801CK, the sheet can be sufficiently cooled, and no linear pattern will occur when the roll sheet is unrolled , Can get a good appearance sheet. The molecular orientation of the sheet is weak, so the difference in longitudinal and transverse thermal shrinkage is small. The relationship between the resin temperature and the cooling roller temperature is as follows: Resin temperature-cooling roller temperature g 120¾ A sheet with excellent formability can be obtained. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) The forming speed of the sheet is O. When la / rainM is used, the sheet with uniform thickness and low defect rate can obtain sufficient production speed. On the other hand, under loom / fflinK, the sheet can be sufficiently cooled. When the rolled sheet is unrolled, it can be prevented from occurring. Linear pattern to obtain a sheet with good appearance. The molded product of the third specific example of the present invention is based on the use of the aforementioned polypropylene-based composition (C), preferably the propylene-based composition (A), and the blending of general polyenes 26. The paper size is applicable to Chinese national standards ( CNS) A4 specification (210X 297 mm) 486501 A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (25) Polypropylene composition (C) obtained from additives used in hydrocarbons, and formed into a film. This film includes unstretched, uniaxially stretched, and biaxially stretched films. The unstretched film uses the T-die method or inflation method commonly used in the manufacture of polyolefin films. For uniaxially stretched and biaxially stretched films, the unstretched film obtained by the aforementioned method can be uniaxially stretched and successively biaxially stretched in a stretching manner. , Or K-tubular method with simultaneous biaxial extension and K-extension manufacturing. These films are excellent in low-temperature impact resistance, heat resistance and tensile strength because the polypropylene-based composition (C) using the propylene-based composition of the present invention as a matrix resin is used. Another specific example of the film of the present invention is a laminated film in which a functional polymer layer is formed on one or both sides of the film. The laminated film of the present invention is not particularly limited as long as it is a polymer layer capable of imparting a function to the film laminated layer composed of the polypropylene-based composition (C), but it has at least a heat-sealable layer. The heat-sealable layer is available with a density of 0. 89 ~ 0. 91g / era3, propylene homopolymer with crystalline melting point of 165 ~ 160 υ, and / or density of 0. 89 ~ 0. A propylene-olefin homopolymer of 91 g / cm3 and a crystalline melting point of 159 ~ 11OC. Melt flow rate of polymers used in these heat-sealable layers (2301; 21.  18N), from the moldability at the time of film formation, the appearance of the resulting film is 0. 1 to 50 g / 10 ', preferably K1 to 20 g / 10'. Examples of the? -Olefin copolymerized with propylene include ethylene, butene-1, pentene-1 and the like. The propylene-α-olefin copolymer has, for example, an ethylene content of 0. 2 ~ 10% by weight of ethylene, propylene copolymer, ethylene content of 0. 2 ~ 10 weight, butene-1 content 0. 4 ~ 5 weight! "Ethylene-propylene-butene-1 (please read the notes on the back before filling this page) This paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm) 486501 Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Print A7 __B7_ V. Description of the invention (26) Polymer and so on. The crystalline melting point of the propylene homopolymer is 165 to 160 ¾ in order to obtain a multilayer film with excellent surface gloss, surface hardness, and rigidity. Also, the crystalline melting point of propylene-α-olefin polymer, from the viewpoint of obtaining a laminated film with excellent heat sealability, is 159 ~ llOTC, W140 ~ 11010 is better. These propylene homopolymers and propylene olefins are co-existing. The polymer may be a catalyst formed by using a compound containing at least magnesium, titanium, and a halogen, an organometallic compound of a metal of Groups 1 to 3 of the periodic table, and an electron donor, and polymerizing propylene separately according to a conventional polymerization method. Or made by copolymerizing propylene with α-olefin. The multilayer film of the present invention includes a multilayer film using a polypropylene-based composition layer and the functional polymer layer described above, which are unstretched, uniaxially stretched, and biaxially stretched. The layer structure of the multilayer film includes, for example, a functional polymer layer / polypropylene.  The two types of two layers of the olefin-based composition layer include two types of three layers or three types of three-layers of a functional polymer layer / polypropylene-based composition layer / functional polymer layer. Among them, a laminated film composed of a propylene homopolymer layer / a polypropylene-based composition layer / a propylene-olefin copolymer layer is preferable in terms of heat-adhesiveness and heat-sealability of the obtained laminated film. Although the thickness of the laminated film is not particularly limited, in terms of film formability, M10 to 100 // is preferable, and K15 to 70 // is more preferable. In addition, the thickness of each layer of the laminated film is not particularly limited, but in terms of low-temperature impact resistance, heat resistance, and tensile strength. The thickness of the acrylic resin composition layer should account for 30 to 9 0 S of the total thickness of the film: κ 5 0 to 9 0 »: preferably. -28- (Please read the precautions on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 486501 A7 _ B7 V. Description of the invention (27) Laminated film manufacturing method There are, for example, a multiple calendar extrusion molding method, a dry lamination method, an extrusion lamination method, and the like, and a multilayer extrusion molding method includes, for example, a T-die method or an inflation method for general polyolefin film production. Examples of the stretching method include a sequential biaxial stretching method using a stretching method, and a simultaneous biaxial stretching method using a tubular method. K When manufacturing the accumulative film by the above-mentioned known method, the melt flow rate (MFR) of the polypropylene-based composition and the functional polymer constituting each layer is not particularly limited, but from the moldability of the film and the appearance of the film, The MFR ratio of the propylene strip composition to the functional polymer is 0. 1 ~ 10, M0, 5 ~ 2 are preferred. ^^ The laminated film of the present invention can be made by laminating using a dry lamination method and the like with a transparent substrate film such as a BOP film, a PET film, a nylon film, an EVAL film, and the like through an adhesive. The film and the laminated film of the present invention are provided with printability, accumulative applicability, and metal vapor deposition characteristics, and the surface treatments such as M electro-discharge treatment, flame treatment, and plasma treatment can be applied by a method generally used in industry. The molded product according to the fourth specific example of the present invention is a hollow molded product made of the aforementioned polypropylene-based composition (C), especially a composition (Cb) obtained by mixing a plasticizable component with a propylene-based composition. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) This hollow molded product K has a bellows structure. The hollow molded product of the present invention can be supplied to the extruder of a blow molding machine by supplying the polymer-based composition (C), and the hollow cylindrical shape can be extruded, which can be easily manufactured by the blow molding method. In addition, since the metal model of the molding machine is a metal model having a concave-convex surface (a bellows surface), a hollow molded product having a bellows structure can be easily produced. -29- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 86501 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 __B7_ V. Description of the invention (28) Specific examples include a composite hollow molded product having a hollow molded product portion having a bellows structure and a hollow molded product portion made of a polyolefin-based composition (P0) having excellent rigidity and impact resistance. The polyolefin-based composition (P0) used in the hollow molded part following this bellows structure includes an ethylene-containing polymerization unit of 25 to 55 weight 3: preferably 35 to 55 weight of an ethylene-propylene copolymer of 1 to 20 weight χ, K10 ~ 20 weight is preferred. Composition of K and propylene homopolymer 99 ~ 80 weight. In order to impart rigidity, inorganic fillers can be added within the range that does not impair the purpose of the present invention. Examples include slip powder, calcium carbonate, and calcium silicate. Wait. The mixing ratio of the inorganic filler is preferably at 20 wtM based on the weight of the K composition. This hollow molded product can be an accumulation type blow molding machine, including a set of model tightening devices, a hydraulic press cylinder, and at least two extruders, and one of the extruders supplies the polypropylene-based composition (C) of the present invention, Another extruder supplies the aforementioned polyolefin-based composition (PO), and the extruder first stores the melted composition in a hydraulic press cylinder, and then uses another extruder to accumulate the melted composition in a hydraulic press cylinder. Next, a parison set to melt the polypropylene-based composition (C) was introduced, and a gold mold model portion having a concave-convex surface (a serpentine surface) was introduced. The parison was extruded by a hydraulic cylinder, and 0 was blown into the parison.  5 to 1 MPa of pressurized air. Example Examples and Comparative Examples are provided to further illustrate the present invention in detail as follows. Α. Synthesis of Acrylic Acrylic Composition (Α), Determination of Various Physical Properties -30- (Please read the precautions on the back before filling out this page) This paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 486501 Economy Printed by A7 _B7 of the Consumer Standards Cooperative of the Ministry of Standards and Administration of the People's Republic of China. 5. Description of Invention (29) During the synthesis of propylene-based composition, the physical properties of intermediate products and final products can be measured by the following methods. The synthesis conditions and measurement results are shown in Tables 1 and 2. (a) Titanium-containing solid catalyst component (a) Average particle size (/ ία): Calculated from the particle size distribution measured by a main classifier (product of MALVERH). (b) Uniformity of titanium-containing solid catalyst component U): Calculated from the particle size distribution of 60S: particle size under the sieve obtained by the particle size distribution measured by the main classifier (product of Malvern). (c) The amount of polymer produced per unit weight of the catalyst: determined by the Mg-derived europium plasma emission analysis (IPC method) in the sample. (d) Isotactic pentavalent fraction P of polypropylene molecular chain: according to &lt; <Giant molecule> 8687 (1975), measured by GC-HMR. (e) Ethylene in fluorene unit (weight S :): determined by infrared absorption spectroscopy 0 (f) limiting viscosity (dl / g): in naphthalene (tetrahydronaphthalene) solvent at 135 υ temperature, using automatic Viscosity measuring device (AVS2 type, manufactured by Mitsui Toyo Co., Ltd.). (g) Melt flow rate (g / lO '): measured according to JIS K 6760. (h) Q value of average molecular weight (Mn / Mw): the sample dissolved in 135t! o-dichlorobenzene, using a GPC device (gel permeation chromatography, 150 C type, products of Otas Corporation, using a column: TSK GEL GMH 6-HT) Determination of 0 (i) 2〇υ xylene soluble content (weight Si): measured according to ISO / DIS 1 873-1. (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 _ B7 V. Description of the invention (50) (j) Powder flowability: according to The degree of compression of the powder is calculated by the following formula. Apparent Density-Relax Apparent Density Compression = --- X 100 Apparent Density during Solidification The higher the compression value, the worse the powder flowability.调制 Modification of titanium-containing solid catalyst component (a) U) Titanium-containing solid catalyst component: a-1 $ 113 autoclave purged with nitrogen, add anhydrous "18 (: 1295.3 g, 352 ml dry EtOH, this mixture Heat to 105C under stirring. After stirring for 1 hour, heat the solution to 105 ° M, pressurized nitrogen (1.1MPa) and send it to the two-fluid nozzle. Nitrogen flow rate is 381 / inin. Into the spray tower, liquid nitrogen for cooling is introduced. The temperature in the column was maintained at -151C. The product was collected in cooled hexane introduced into the bottom of the column to obtain 256 g. As a result of the analysis of the product, the composition and starting solution of this carrier were both MgCl 2 · 6EtOH. As a carrier, 205 g of a spherical carrier having a particle size of 45 to 212 / iin was screened. The obtained carrier was dried at room temperature under a nitrogen flow of 31 / min for 181 hours to obtain a dry carrier having a composition of MgC 1 2 · 1. 7 EtOH. Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Bureau of Standards (please read the precautions on the back before filling this page) In a glass flask, place 20 g of dry carrier, 160 ml of titanium tetrachloride, and 240 ml of refined 1, -dichloroethane Mix and heat to 100 υ with stirring. Next add xylylene 6.8 ml of diisobutyl ester, and then heated at 100¾ for 2 hours, and then decanted to remove the liquid phase portion. Then add 160 ml of titanium tetrachloride and 320 ml of refined 1,2-dichloroethane, and heat and hold at 1001C for 1 hour. The liquid phase is removed by decantation, and the purified hexane is washed and dried to obtain a titanium-containing solid catalyst component a-1. The obtained titanium-containing solid catalyst component is in accordance with Chinese national standard (〇 奶) 8 4 Specifications (210 mm 297 mm) · 486501 A7 B7 V. Description of the invention (51) The average particle size of a-1 is 115 / im, and its analytical value is Mgl9.5 weight S :, 1 ^ 1.6 weight "!, ( : 159.0% by weight, diisobutyl benzyl dicarboxylate 4,5 by weight. (B) Titanium-containing solid catalyst component: a-2 SUS autoclave purged with nitrogen, and 1,050 ml of refined kerosene added , Anhydrous ^^ (: 1215 g, 36.3 g of dry ethanol, and 4.5 g of a surfactant (trade name Emulsol 320, product of Kao Atlas), the mixture was heated to 1201 C with 80 rpin stirring and maintained at 30 Min. For high-speed stirring of the mixture M, use a Teflon tube with an inner diameter of 5 μm to transfer to a 3000-ml flask with stirring and pre-fill the cold 1500 ml of refined kerosene to -101C. After filtering the product, K-hexane was thoroughly washed to obtain a carrier 0.5 g of the carrier was suspended in 300 ml of titanium tetrachloride at room temperature, and then diphthalic acid was added. 2.6 ml of isobutyl ester, and the temperature of the mixture solution was raised to 120 ° C. After mixing and stirring at 120 ° C. for 2 hours, the solid matter was filtered and resuspended in 300 ml of titanium tetrachloride. After the suspension was mixed and stirred at 130 ° C for 2 hours, the solid matter was filtered, and the purified hexane was thoroughly washed to obtain a titanium-containing solid catalyst component a-2. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) The average particle size of the titanium-containing solid catalyst component a-2 is 72 u in, and the analysis value is Mg21.1% by weight. Ti2.4 weight X, C164.15 weight%, diisobutyl phthalate 5.3 weight%. (c) Titanium-containing solid catalyst components: a-3 Take a mixture of 300 g of magnesium ethoxide, 550 ml of 2-ethylhexanol, and 600 ml of toluene under a carbon dioxide atmosphere of 0 e20 MPa. This paper applies to China. National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 _ B7 V. Description of the invention (52), stir at 931C for 3 hours. 800 ml of toluene # and 800 ml of n-decane were added to obtain a magnesium carbonate solution. 800 ml of toluene, 60 ml of chlorobenzene, 18 ml of tetraethoxysilane, 17 ml of titanium tetrachloride, and Iso paj G (isoparaffin with an average carbon number of 10, boiling point 1 5 6 ~ 1 7 6 TC ) 200 ml. While stirring at 30 υ for 5 minutes, add 100 ml of the magnesium carbonate solution prepared above. After stirring for another 5 minutes, 44 ml of tetrahydrofuran was added and the mixture was stirred at 60 mC for 1 hour. After the stirring was stopped and the supernatant liquid was removed, the resulting solid was washed with 100 ml of toluene, 200 ml of chlorobenzene and 200 ml of titanium tetrachloride were added to the obtained solid, and the mixture was stirred at 135 υ for 1 hour. The stirring was stopped, the supernatant liquid was removed, 500 ml of chlorobenzene, 200 ml of titanium tetrachloride, and 4.2 ml of di-n-butyl phthalate were added, and the mixture was stirred at 13 5 C for 1.5 hours. After removing the supernatant, the solids were sequentially washed with 1,200 ml of toluene, 1,600 ml of Isopar G, and 800,000 ml of hexane, and a titanium-containing solid catalyst component a -3 was taken for comparison. The average particle diameter of the obtained titanium-containing solid catalyst component a-3 was 18.5ium, and its analytical values were Mgl7,0% by weight, Ti2.3% by weight K, C155.0% by weight, and di-n-butyl phthalate 7.5% by weight. (3) Titanium-containing solid catalyst component U) Pre-activated processing Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) 15-liter stainless steel reactor with tilting wings After K-nitriding, the saturated hydrocarbon solvent (CRYST0L-52, manufactured by Εχχ0 Petroleum Corporation) with a kinematic viscosity of 7.3 centimeters when adding 40 υ at room temperature was added. 8,3 liters of triethylaluminum 525 milliliter Moore, diisopropyldimethoxysilane 80 millimoles. After 70 g of the titanium-containing solid catalyst component prepared in the preceding paragraph, the temperature was increased to 40¾, so that propylene reacted at a partial pressure of 0.15 MPa. Pre-activated for 7 hours. The paper size is in accordance with Chinese National Standard (CNS) A4 (210X 297 mm) 486501 A7 _B7_ V. Description of the invention (55). As a result of the analysis, 3.0 g of propylene reacted per gram of the titanium-containing solid catalyst component. ⑷Polypropylene homopolymer (synthesis of P 钤: the first polymerization step is shown in the flow chart shown in Figure 3), in a horizontal polymerizer 1 with agitating wings (L / D = 6, capacity 100 liters), even 缜Supply pre-activated titanium-containing solid catalyst component 0.5g / h, K and triethylaluminum as organoaluminum compound (b) and diisopropyldimethoxysilane as organosilicone compound U), so that The Al / Si ratios shown in Tables 1 and 2 are shown. Continuous supply of propylene, maintaining the reaction temperature of 70 TC, reaction pressure of 2.5 MPa, and stirring speed of 40 rpm, and then supplying hydrogen from the circulation pipeline 2 continuously, K adjusted the molecular weight of the propylene homopolymer produced, and the hydrogen in the gas phase of the reactor Concentration to control the limiting viscosity of the propylene homopolymer formed. The reaction heat is removed by the heat of vaporization of the raw material propylene supplied from the pipeline 3. The unreacted gas discharged from the polymerization reactor passes through the tube 4 and is cooled, condensed outside the reactor system, and returned to the polymerization reactor 1. The propylene homopolymer obtained in the polymerizer 1 was continuously withdrawn from the polymerizer 1 through the pipeline 5 and supplied to the polymerizer 10 in the second polymerization step to maintain the polymer liquid level at 50% by volume of the reaction capacity. At this time, part of the propylene homopolymer was drawn from the 5 pipelines and used as a sample M. The isovalent pentad fraction (P) was printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back first) Fill out this page again), 201C xylene solubles content, limiting viscosity ([η] ρρ) and polymer yield per unit weight of catalyst. (5) Synthesis of propylene-ethylene copolymer (RC): The second polymerization step is in a horizontal polymerizer 10 (L / D = 6 with a capacity of 100 liters) with a mixing blade, and the propylene homopolymerization from the first polymerization step is continuously supplied. And ethylene-propylene mixed gas to copolymerize ethylene and propylene. The reaction conditions are that the paper size is Chinese National Standard (CNS) A4 (210X 297 mm) 486501 A7 B7 V. Description of the invention (54) Mixing speed 40rpm temperature 601C, pressure 2.1MPa, gas composition of the gas phase is adjusted to ethylene The propylene / mole ratio and hydrogen / ethylene mol are shown in Tables 1 and 2. Carbon monoxide was supplied from line 7 as a polymerization inhibitor, and K adjusted the amount of polymerization of the propylene-ethylene copolymer, and K supplied hydrogen and adjusted the molecular weight of the propylene-ethylene copolymer. The reaction heat is removed by using the raw material liquid propylene vaporization heat supplied from the pipeline 6. The unreacted gas discharged from the polymerizer is cooled, condensed, and refluxed to the copolymerization step outside the reactor system through a line 8. The propylene hydrazone composition (A) produced in the copolymerization step, and the K line 9 is drawn out from the polymerizer 9 so that the polymer maintains the liquid level to 50 capacity of the reaction capacity! C. The production rate of the propylene-based composition (A) is 8 to 12 kg / hr. The monomer was removed from the extracted C. spp. Composition (A), and a part was used to determine the limiting viscosity (U) WHOLE, Q value (Mw /), 20 xylene solubles content, and propylene-ethylene copolymer Polymerization ratio of ethylene, M and propylene-ethylene copolymers. The powder flowability of the propylene-based composition (A) was evaluated. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling this page) Change the type of titanium solid catalyst component (a), Al / Si mole ratio and hydrogen in the first polymerization step / Propylene mole ratio, ethylene / propylene mole ratio and hydrogen / ethylene mole ratio in the second polymerization step, to obtain samples A-1 to A-14 and comparative samples CA-1 to eA-14 of the present invention. The reaction conditions and the measurement results of various physical properties are shown in Table 1 for the production conditions and characteristics of the propylene-based composition of the present invention, and Table 2 for the production conditions and characteristics of the propylene-based comparative composition. This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) 486501 A7 B7 V. Description of the invention ($) Printed by the Central Consumers Bureau of the Ministry of Economic Affairs of the Consumer Cooperatives Table 1 Manufacturing of propylene-based components Example 1 ^ 2 3 4 5. 6 7 Titanium-containing solid catalyst component (a) Number a-1 a-1 a-1 a-1 a-1 a-2 a-1 average particle size μαι 115 115 115 115 115 115 115 Uniformity 1.74 1.74 1.74 1. 74 1.74 1.73 1.74 Pre-activated Al / Ti / Si Molar ratio 2/1 / 0.3 2/1/0. 3 2/1/0 · 3 '2 / 1 / 0.3 2/1 / 0.3 2/1 / 0.3 2/1 / 0.3 olefin / otVy r〇t> y MV / / otvy r〇h> y Μ »: r_. Reaction amount gfh- / g catalyst 3 3 3 3 3 3 3 First polymerization step Al / Si molar ratio 3 6 2 3 3 3 Polymerization pressure MPa 2.5 2.5 2.5 2.5 2.5 2.5 2.5 Polymerization temperature. 70 70 70: 70 70 70 70 h2 / c3 Molar ratio 0.03 0.06 0.026 0.003 0.01 0.04 Generated propylene homopolymer (PP) Production amount ΤΤρρ) wtX 71.5 71.0 71.3 69.7 63.7 72.5 70.8 Isotactic pentad fraction (P)% 0.963 0.964 0.973 0.964 0.967 0.972 0.968 Limiting viscosity (U) PP) dl / g 2.5 2.3 1.8 2.6 2. 07 2.4 1.75 Melt flow rate '(MFRpp.) G / l0 minutes 0.8 1.5 6.0 0.7 2.6 1.0 7.2 Polymerization pressure in the second polymerization step MPa 2.1 2.1 2.1 2.1 2.1 2.1 2.1 Polymerization temperature 60 60 60 60 60 60 60 C2 / C3 Molar ratio 0.23 0.23, 0.23 0.3 0. 42 0.23 H2 / C2 Molar ratio 0.18 0.25 0. 57 0. 25 0.32 0.2 Production of PP-ET copolymer (RC) Production amount (he) wtX 28.5 29.0 28.7 30.3 36.3 27.5 29.2 Ethylene content wtX 35 35 35 41 48 35 34 ^ Limit viscosity 0 &gt;) RC) dl / g 2.5 2.3 1.8 2.4 2.17 2.4 1.9 Melt flow rate (MFRRC) g / 10 minutes 0.8 1.5 6.0 1.5 2.3 1.0 4.1 Sulfur-soluble ingredients (cxsRC) 94 94 95- 90 86 94 86 Acrylic composition (A) No. A-1 A-2 A-3 A-4 A-5 A-6 A-7 PP / R_ &amp; αΡ &quot; ϊπ) 2.51 2.45 2.48 2.3 1.75 2.46 2.42 Limit viscosity ([] whole) dl / g 2.5 2.3 1.8 2.3 2.09 2.4 1.8 Limit viscosity ratio [[r? W [77] PP) 1.0 1.0 1.0 0. 92 1.05 1.0 1.09 ([Ή] rc / [77] ρρ) X (Wpp / WRCy 2.51 2. 45 2.48 2.1 1.83 2. 46 2.63 Mass flow rate (MFRwHOuE) g / 10 minutes 0.8 1.5 6.0 1.4 2.5 1.0 6.0 Molecular weight dispersion Q Value (Mw / Mn) 3.7 3.8 4: 0 3.8 4.3 3.9 4.2 Powder flowability relaxation density g / ml 0.36 0. 36 0. 36 0.36 0.34 0.42 Solidification density g / ml 0.36 0.36 0.36 0. 36 0.35 0.43 Powder compactness X 0 0 0 0 2.9 2.3 This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) -37- (Please read the notes on the back before filling this page) 486501 A7 B7 V. Description of the invention (private) Table 1 Composition of acrylic system Production (Results) Example of the production of finished products Example of titanium-containing solid catalyst component (a) Number average particle size &quot; m Uniformity 湏 Activation treatment Al / Ti / Si olefin reaction amount Morr ratio g # 片 _ / g catalyst first polymerization step Al / Si polymerization pressure polymerization temperature h2 / c3 mole ratio HPa mole ratio 8 9 11 12 13 a-1 115 1. 74 al 115 1.74 a-1 115 1.74 a-1 115 1.74 a -1 115 1.74 a-2 115 1.74 a-1 115 1.74 2/1/0. 3 / ahV / 2/1 / 0.3 / otvy 3 2/1 / 0.3 / otuy 3 2/1 / 0.3 7〇h * i / y 3 2/1/0. 7.〇tV / 3? /! / 0. 3 7 * 〇t> y 3 7/1 / 0.3 Tobl / y 3 2.5 70 2.5 70 2.5 70 2.5 70 2.5 70 2.5 70 2.5 70 2.5 70 (#, first read the notes on the back and then fill out this page) (PP) produced child (stomach pp) wtx isotactic pentad fraction (P) X limiting viscosity a &gt;) PP) di / g melt flow rate, (MFRPP) g / l0 minutes 70.3 0. 969 1.8 6 1 71. 1 0.970 2. 05 2.8 75.0 0. 971 1.8 6.2 62.2 0. 967 1.8 6.5 69.7 0.970 1.8 6.2 68.9 0. 969 1.8 6.0 72.3 0. 955 1.8 6.1 Polymerization pressure in the second polymerization step MPa Polymerization temperature t: c2 / c3 Mole ratio H2 / C2 Mole ratio 2. 1 60 2. 1 60 2. 1 60 2 · 1 60 2. 1 60 2. 1 60 2. 1 60 Amount of PP-ET copolymer (RC) produced (WRC) wt% Ethylene content wtX Limiting viscosity (U) Rc) dl / g Melt flow rate (MFRrc) g / l0 xylene soluble component (CXSrc) wtx 29.7 35 1.8 6.0 89 28.9 35 1.6 10.6 90 25.0 36 L8 6. 1 87 37.8 33 1.8 6.5 88 30.3 28 1.8 6.0 92 31. 1 41 1.8 6 · 1 86 27.7 36 1.8 6.2 87 Printed acrylic strip composition (Α) by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs PP / RC weight ratio (W1TRC) limiting viscosity ([^ 7] whole) dl / g limiting viscosity ratio [U] RC / U] Pi &gt;) ([Ή] rc / [Tj] pp) X (Wpp / Wrc) food Valley flow (MFRwhol E) g / 10 molecular weight dispersion Q value (Mw / Hn) powder flowability relaxation density g / ml solidification density g / ml powder compaction% Λ-8 2.37 1.8 1.00 2.37 6. 1 4.2 Λ-9 2.46 1.93 0.78 1.92 4.0 4.2 A-10 3.00 1.8 1.00 3.00 6.2 4.2 Λ-11 1.65 1.8 1.00 1.65 G. 5 4.2 Λ-12 2. 30 1.8 1.00 2.30 G. 2 4.2 A-13 2.22 1.8 LOO 2.22 6.0 4 · 2 Λ-14 2.61 1.8 LOO 2.61 6. 1 4.2 One 38- This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) 486501 A7 _B7 V. Description of Invention (Fantasy) Table 2 Manufacturing of Propylene-based Comparative Compositions Ministry of Economic Affairs Central Standards Bureau Employees' Cooperatives Printing Compositions Manufacturing Example No. 1 2 3 4 5 6 7 Titanium Solid catalyst component (a) number a_l a-1 a-2 a-3 a-1 a-1 a-1 average particle size 115 115 115 18.5 115 115 115 uniformity 1.74 1.74 * 1.74 2. 07 1.74 1.74 1.74 Pre-activated Al / Ti / Si molar ratio 2/1/0. 3 2/1/0. 3 2/1 / 0.3 2/1 / 0.3 2/1 / 0.3 2/1 / 0.3? / t / 0. 3 olefin mvj / Dt * uy T〇t * i / y rab ^ y 7 * at &y; y 7 * ati / y mvj reaction amount gf1 sheet- / g catalyst 3 3 3 3 3 3 3 first polymerization Step Al / Si Morr ratio 14 3 3 3 3 3 3 Polymerization pressure MPa 2.5 2.5 2.5 2.5 2.5 2.5 2.5 Polymerization temperature ^ 70 70 70 70 70 70 70 h2 / c3 mole ratio 0.007 0.055 0.006 0. 003 0. 022 0.055 0.003 propylene homopolymer (PP) produced 〇TPP) WtX 80.5 80.5 86.8 69.7 75.6 75.3 46.3 isotactic price Material fraction (P) X 0.949 0.9972 0.964 0.961 0.971 0.974 0.9962 Limit viscosity ([] pp) dl / g 2.3 1.6 2.3 2.6 1.84 1.52 2.5 Melt flow rate, (MFRPP) g / l0 minutes 2.1 14.5 1.4 0.7 5.3 16.8 0.8 Polymerization pressure in the second polymerization step MPa 2.1 2.1 2.1 2.1 2.1 2. 1 2.1 Polymerization temperature t 60 60 60 60 60 60 60 C2 / C3 mole ratio 0.35 0. 36 0.3 0.28 0.36 0.43 0.23 H2 / C2 mole Ratio 0.3 0.12 0.25 0.25 0.10 0.02 0.15 Generate PP-ET copolymer (RC) Generate η% 19.5 19.5 13.2 30.3 24.4 24.7 53.7 Ethyl content wtX 45 45 41 41 46 49 35 Limit viscosity ([^ 7] rc) dl / g 2.0 2.9 2.3 2.4 3.0 4.9 2.6 Melt flow rate (MFRrc) g / 10 minutes 3.4 0.4 1.4 1.5 0.3 0.02 0.6 Xylene soluble component (CXSRC) WtX 88 88 90 90 85 84 93 Acrylic composition (A) No. cA -1 cA-2 cA-3 cA-4 cA-5 cA-6 cA-7 PP / RCMS ratio (iP &quot; fRC) 4. 13 4. 13 6.57 2.3 3. 1 3.1 0.8G Limiting viscosity ([^ 7] whole) dl / g 2. 1 L9 2.3 2.3 2. 1 2.0 2. G limiting viscosity ratio [[77] R c / [7?] pp) 0.87 2.1 1.0 0.92 lG 3.2 1.0 ([V] rc / [77] pp) X (Wpp / Wrc) 3. 59 7.7 6.57 2.14 5.0 9.7 0.86 fe Mass flow (MFRwHOLE) g / 10 points 2.3 7.0 1.4 1.4 2.7 3.0 0.7 Q value of molecular weight dispersion (Mw / Mn) 4.4 6.7 3.8 3.8 5 1 8.2 5 powders fluidity relaxation density g / ml 0.35 0.36 0.36 0./16 0.36 0.36 0.34 solidification fork. G / ml 0. 34 0.36 0. 36 0. 37 0.3G 0. 3G 0. 36 powder compaction Degree X 2.9 0 0 19.6 0 0 5.6 -39- (Please read the notes on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 _B7 V. Invention Explanation (may) Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, Table 2 Manufacturing of propylene-based comparative composition (soil) Example of the manufacture of finished products 8 9 10 11 12 13 14 Titanium-containing solid catalyst components (a) Number a-1 a-1 9-1 a-1 a-1 a-1 a-1 average particle size μ 115 115 115 115 115 115 115 115 Uniformity 1. 74 1.74 * 1.74 1.74 1.74 1.74 1.74 Pre-activated Al / Ti / Si Morr ratio 2 1/0. 3 2/1 / 0.3 2/1/0. 3 2/1/0. 3 2/1 / 0.3 2/1 / 0.3? /! / 0.3 olefin / atvy / at * uy / uhly MV / Reaction amount gm- / g catalyst 3 3 3 3 3 3 3 First polymerization step Al / Si Molar ratio polymerization pressure MPa 2.5 2.5 2.5 2.5 2.5 2.5 2.5 Polymerization temperature ec 70 70 70 70 70 70 70 H2 / C3 Molar ratio Homogeneous propylene (PP) yield (Wpp) wtX 70,8 69.5 82.4 56.1 70.3 68.8 70.4 Isotactic pentad fraction (P)% 0.971 0.968 0.968 0.966 0.971 0.969 0.969 0.941 Limiting viscosity ((? 7) pp) dl / g 1.4 2.3 1.8 1.8 1, 8 1.8 1.8 Melt flow rate (MFRPP) at 10 minutes 34.0 1.5 6.2 6.1 6.2 6.1 6.0 Polymerization pressure in the second polymerization step MPa 2.1 2.1 2.1 2.1 2.1 2.1 2.1 Polymerization temperature T 60 60 60 60 60 60 60 C2 / C3 Mole ratio h2 / c2 Mole ratio to form PP-ET copolymer (RC) to generate 1: (WRc) wtX 29.2 30.5 17.7 43.9 29.7 31.2 29.6 Ethyl content wtX 36 36 34 35 21 64 35 Limiting viscosity ([t?] Rc) dl / g 2.8 1.4 1.8 1.8 1.8 1.8 1.8 Melt flow rate (MFRrc) g / l0 min 0.41 27.3 5.9 6. 1 5.9 6.0 6.0 Dimethyol content (CXSRC) 85 89 90 87 86 83 89 Number of acrylic composition (A) cA-8 cA-9 cA -10 »cA-ll cA-12 cA-13 cA-14 PP / RC Halo Ratio (iPP / fRC) 2.42 2.28 4.66 1.28 2.37 2.21 2.38 Limiting viscosity ([] WH (5LE) dl / g 1.79 2.0 1.8 1.8 1.8 1.8 1.8 Limiting viscosity ratio [U] RC / U] PP) 2. 00 0.61 1.0 1.0 1.0 1.0 1.0 1.0 ([] rc / [7]] pp) x (Ipr / iRc) 4.84 1.39 f 4.66 1.28 2.37 2.21 2.38 Melt Flow rate (MFRWHOUE) g / l0 minutes 6.2 3.0 6.2 6. 1 G.2 G. 1 6.0 Molecular weight dispersion Q value (Mw / Mn) 6.2 5.5 4.2 4.3 4.3 4.4 4.3 Powder flowability relaxation density g / ml Solidification density · g / ml powder compactness X — 4 0 — (Please read the notes on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 486501 A7 B7 V. Description of the invention (59) B. Polypropylene composition (Ci) for injection molding and injection molded product: Polypropylene composition in each of the propylene composition A-1 · to A-6 and the comparative compositions CA-1 to CA-7 of the present invention Powder, add various added ingredients, use a high-speed stirring mixer (Henschel mixer), mix at room temperature for 5 to 10 minutes, and use an extruder granulator with a screw diameter of 40mm K cylinder set temperature 23〇υ granulation, K modulation particles. Tables 3 and 4 list the polypropylene-based compositions Ci-1 to Ci-12 and Ci-13 to Ci-18 for injection molding of the present invention, respectively. Tables 5 and 6 list the comparative compositions cCi = 1 to cCi, respectively. -7 and cCi_8 to cCi-13 each added ingredients and their added amounts. The added ingredients and abbreviations in the table are as follows: And the olefin polymer PHP1: using titanium-containing solid catalyst components, at Al / Si mole ratio 2, hydrogen / propylene mole ratio 0.03, polymerization pressure 2.5MPa, polymerization Under the conditions of a temperature of 70 t !, a propylene homopolymer having a melt flow rate of MFRpHpl and a crystalline melting point of 16 3 was obtained by separately polymerizing propylene. ΡΡΡ2: Printed using titanium-containing solid catalyst components at Al / Si Mor2 ratio, and at the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). 〇 Under the conditions of a polymerization pressure of 2.5 MPa and a polymerization temperature of 701, a crystalline propylene homopolymer having a melt flow rate MFRpHp of 1.9 and a melting point of 16 4 1C obtained by separately polymerizing propylene. ΡΡΡ3: Using titanium-containing solid catalyst components, under the conditions of Al / Si mole ratio 2, hydrogen / propylene mole ratio 0.05, polymerization pressure 2.5 »^ 3, polymerization temperature 70 υ, the molten polymer obtained by the polymerization of propylene alone Volume • Flow rate MFRPHP6, Fusion paper size applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 486501 Α7 B7 V. Description of the invention (40) Point 1641 crystalline propylene homopolymer (comparative). Anti-Gabei 1 P h-1: Phenol hydrazone stabilizer

Ph-2:四（亞甲-3_(3’，5’-二特丁基-4’-羥苯基）丙酸 酯）甲烷Ph-2: Tetra (methylene-3_ (3 ′, 5’-di-tert-butyl-4’-hydroxyphenyl) propionate) methane

Of 晶核_ 0( -1:羥基雙（4_特丁基苯甲酸）鋁 〇(-2: 1·3,2·4-雙（對甲基苄叉）山梨糖醇 α - 3: 2,2’-亞甲雙（4,6-二特丁基苯基）磷酸納 自由某搿牛_ 1,3-雙（特丁基過氧異丙基）苯 中和削 硬脂酸鈣 (請先閱讀背面之注意事項再填寫本頁) 訂 #1. 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐） 486501 A7 B7 五、發明説明（心） i8ss βιΜ m—Μ SS0aii. i^.goo- (230°) IB 200- ia % n s$ MPa J/曰 J/白 J/曰Μ 载舛 截&quot;A 000 «趙 Μφ 識遛 Μφ __φ a纈 _寒 000 48 004 〇Of nucleus_ 0 (-1: hydroxybis (4-tert-butylbenzoate) aluminum 〇 (-2: 1.3 · 2 · 4-bis (p-methylbenzylidene) sorbitol α-3: 2 , 2'-Methylene bis (4,6-di-tert-butylphenyl) phosphate is free from a yak_ 1,3-bis (tert-butylperoxyisopropyl) benzene neutralizes calcium stearate ( Please read the notes on the back before filling in this page) Order # 1. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs This paper is printed in accordance with Chinese National Standard (CNS) A4 (210 × 297 mm) 486501 A7 B7 V. Invention Explanation (Heart) i8ss βιΜ m—Μ SS0aii. I ^ .goo- (230 °) IB 200- ia% ns $ MPa J / JJ / WhiteJ / YM Loading Intercept &quot; A 000 «赵 Ｍφ φ Μφ __φ aval_cold 000 48 004 〇

Ph丨一 0.1 0·1 0·96 670 120 100Ph 丨 A 0.1 0 · 1 0 · 96 670 120 100

Ci丨一 All 45 84 〇Ci 丨 一 All 45 84 〇

Ph丨一 0·1 0·1 0·9οο 6000 110Ph 丨 一 0 · 1 0 · 1 0 · 9οο 6000 110

Ci丨2 Α丨2 100 ---------镳丨丨 (請先閱讀背面之注意事項再填寫本頁) 44007 〇 ph—1 pl 0.1 0.99 720 60Ci 丨 2 Α 丨 2 100 --------- 镳 丨 丨 (Please read the notes on the back before filling this page) 44007 〇 ph—1 pl 0.1 0.99 720 60

Ci丨3 r3 100 55003 ΔCi 丨 3 r3 100 55003 Δ

ph—l0.1Q.l 0·99 700HG CI I 100ph—l0.1Q.l 0 · 99 700HG CI I 100

、1T 57003 Δ1T 57003 Δ

Ph丨一 0.1 Q.l 0.75 590HGPh 丨 A 0.1 Q.l 0.75 590HG

Ci-5 A丨5 100 50 86 〇Ci-5 A 丨 5 100 50 86 〇

Ph丨一 0.1 Q.l 0.99 6000 UOPh 丨 A 0.1 Q.l 0.99 6000 UO

Ci丨6 A~6 100 103 41 007 PT2 0·1 0.1LO 810 α丨一 0.15Ci 丨 6 A ~ 6 100 103 41 007 PT2 0 · 1 0.1LO 810 α 丨 a 0.15

Ci丨7 ΑΛ 100 455 34 009 1.1 720 P丨2 0·1 0.1 a丨2 0.3Ci 丨 7 ΑΛ 100 455 34 009 1.1 720 P 丨 2 0 · 1 0.1 a 丨 2 0.3

Ci丨8 A丨一 100 經濟部中央標準局員工消費合作社印製 200 37 007. NB 57 85 NB 55 85Ci 丨 8 A 丨 一 100 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 200 37 007. NB 57 85 NB 55 85

oo CD cn 之 cn 〇α ph—2 0.1 0·1 1.1 740oo CD cn cn 〇α ph—2 0.1 0 · 1 1.1 740

Ph丨2 0.1 Q.l 0.OO5 740 0.OO5 690 g c= oo ph—2 0·1 0. 1Ph 丨 2 0.1 Q.l 0.OO5 740 0.OO5 690 g c = oo ph—2 0 · 1 0. 1

I 0.2 a -1 0. 15 a丨2 0·3 —4 3 — 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ci—9 All 100I 0.2 a -1 0. 15 a 丨 2 0 · 3 —4 3 — This paper size applies to China National Standard (CNS) A4 (210X297 mm) ci—9 All 100

Ci 丨 10 A—5 100 C.-11 A丨5 100 »—* O CD &gt;- *-· O I I cn 10 11 486501 A7 B7 五、發明説明uo 經濟部中央標準局員工消費合作社印製 表4 射出成型用姐成物及射出成型品（E ) 射出成型實施例號次 13 •14 15 16 17 18 聚丙烯糸組成物(Ci) 號次 Ci-13 Ci-14 Ci-15 Ci-16 Ci-17 Ci-18 丙烯糸組成物(A) 號次 A-l A-1 A-l A-5 A-5 A-5 重量份 100 50 50 100 50 50 丙烯均聚物 種類 一- PHP-1 PIIP-1 -- PUP 2 ΙΊΙΡ 2 重量份 50 50 — 50 50 α晶核劑 種類 一一 — 一一 __ ' 一鱗 重量份 -- -- 一 一一 一一 __ 白由劑發生劑 重量份 0. 02 -- 0. 02 0.01 — 0.01 抗氧化劑 種類 Ph-1 Ph-1 Ph-1 Ph-1 Ph-1 Ph -1 重量份 0. 02 0.02 0. 02 0.02 0.02 0.02 中和劑硬脂酸15 重量份 0.02 0. 02 0.02 0.02 0.02 0.02 物 性 熔體流量(MFR) g/10f 10 1 11 12 2.3 14 成型收縮率 X 0.96 1.23 1.2 0.75 1. 12 1. 1 屈曲彈性率. MPa 670 850 825 590 820 810 耐衝擊性(-20°C) J/m -- 一 — — — (23°C) J/ra NB 90 70 NB 100 70 懸爵梁式衝繫值卜30。〇 J/m2 — -- -- — — -- 涠濁度 X 48 60 59 57 63 65 光澤 % 84 87 87 83 86 85 抗白化性 〇 〇 〇 〇 〇 〇 -44- 本紙乐尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） ------：--，丨-- (請先閲讀背面之注意事項再填寫本頁) 486501 A7 B7 五、發明説明（β) 經濟部中央標準局員工消費合作社印製 表5 射出成型用比較姐成物及射出成型品（I ) 射出成型實施例號次 1 2· 3 4 5 6 7 聚丙烯糸姐成物(Ci) 號次 cCi -1 cCi - 2 cCi-3 cCi-4 cCi-5 cCi-6 cCi - 7 丙烯系組成物(A) 號次 cA-1 cA-2 cA-3 cA-4 cA-5 cA-6 cA - 7 重量份 100 100 100 100 100 100 100 丙烯均聚物 種_ — — — — — — 重量份 — α晶核劑 種類 一一 重量份 __ 白由劑發生劑 _重量份 —一 一一 抗氧化劑 種類 Ph -1 Ph -1 Ph-1 Ph-1 Ph-i Ph-1 Ph-1 重量份 0.1 o.i · 0.1 0· 1 0· l 0· 1 0· 1 中和劑硬脂酸鈣 重量份 0.1 0.1 0.1 0.1 0.1 0.1 0.1 成型品物性 成型收縮率 % 1. 08 1.42 1.41 0.98 1.38 1.56 0. 62 屈曲彈性率. MPa 800 900 1100 710 750 770 370 耐衝擊性(-20°C) J/in 70 70 * 45 400 120 140 NB (23°C) J/m — 頸梁式衝擊值(~30oC) W — 渾濁度 % 50 75 65 57 66 58 53 光澤 % 88 96 90 85 93 96 77 抗白化性 Δ X 〇 △ X X 〇 (請先閲讀背面之注意事項再填寫本頁) 訂 -45- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X：297公釐） 486501Ci 丨 10 A—5 100 C.-11 A 丨 5 100 »— * O CD &gt;-*-· OII cn 10 11 486501 A7 B7 V. Description of the inventionuo Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economy 4 Product for injection molding and injection molded product (E) Example of injection molding No. 13 • 14 15 16 17 18 Polypropylene resin composition (Ci) No. Ci-13 Ci-14 Ci-15 Ci-16 Ci- 17 Ci-18 Acrylic acid composition (A) No. Al A-1 Al A-5 A-5 A-5 parts by weight 100 50 50 100 50 50 Propylene homopolymer type 1-PHP-1 PIIP-1- 02-PUP 2 ΙΊΙΡ 2 parts by weight 50 50 — 50 50 α types of crystal nucleating agents one by one — one by one __ 'one scale by weight-one by one by one by one __ white by agent generating agent 0. 02- -0. 02 0.01 — 0.01 Antioxidant type Ph-1 Ph-1 Ph-1 Ph-1 Ph-1 Ph-1 Ph parts 0. 02 0.02 0. 02 0.02 0.02 0.02 Neutralizer stearic acid 15 parts by weight 0.02 0. 02 0.02 0.02 0.02 0.02 Physical melt flow rate (MFR) g / 10f 10 1 11 12 2.3 14 Molding shrinkage rate X 0.96 1.23 1.2 0.75 1. 12 1. 1 Flexural modulus of elasticity. MPa 670 850 825 590 820 810 Impact resistance (-20 ° C) J / m -One — — — (23 ° C) J / ra NB 90 70 NB 100 70 The value of the cantilever beam punching system is 30. 〇J / m2 —--— —-turbidity X 48 60 59 57 63 65 gloss% 84 87 87 83 86 85 whitening resistance 〇〇〇〇〇〇-44- This paper music standards apply Chinese national standards (CNS) A4 specification (210 X 297 mm) ------:-, 丨-(Please read the notes on the back before filling out this page) 486501 A7 B7 V. Description of the invention (β) Ministry of Economy Printed by the Central Bureau of Standards Consumer Cooperatives. 5 Comparison of injection molding products and injection molded products (I) Injection molding example No. 1 2 · 3 4 5 6 7 Polypropylene finished product (Ci) No. cCi -1 cCi-2 cCi-3 cCi-4 cCi-5 cCi-6 cCi-7 Acrylic composition (A) No. cA-1 cA-2 cA-3 cA-4 cA-5 cA-6 cA-7 100 parts by weight 100 100 100 100 100 100 100 propylene homopolymer species _ — — — — — — parts by weight — α nucleating agent types-11 parts by weight __ whitening agent generator _ parts by weight-one by one antioxidant types Ph -1 Ph -1 Ph-1 Ph-1 Ph-i Ph-1 Ph-1 parts by weight 0.1 oi · 0.1 0 · 1 0 · l 0 · 1 0 · 1 neutralizer calcium stearate parts by weight 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Molded product physical molding shrinkage% 1. 08 1.42 1.41 0.98 1.38 1.56 0. 62 Flexural modulus of elasticity. MPa 800 900 1100 710 750 770 370 Impact resistance (-20 ° C) J / in 70 70 * 45 400 120 140 NB (23 ° C) J / m — neck beam impact value (~ 30oC) W — turbidity% 50 75 65 57 66 58 53 gloss% 88 96 90 85 93 96 77 whitening resistance Δ X 〇 △ XX 〇 (Please read the precautions on the reverse side before filling out this page) RE-45- This paper size applies to Chinese National Standard (CNS) A4 (210X: 297 mm)

7 7 A B 經濟部中央標準局員工消費合作社印製 五、發明説明（蚪）7 7 A B Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of Invention (蚪)

表6 射出成型用比較組成物及射出成塱品（I ) 射出成_實施例號次 8 9 10 11 12 13 聚丙烯系姐成物(Ci) 號次 cCi-8 cCi - 9 cCi-10 cCi-11 cCi-12 cCi-13 丙烯糸組成物(A) 號次 cA - 2 * cA-2 cA-2 cA~2 cA - 2 cA-2 重量份 100 100 100 100 50 50 丙烯均聚物 f類 Ρ11Γ-3 ΓΙΙΓ 3 ‘最份 — — — 50 50 α論劑 i癍 a -1 α -2 a _3 -- — — 重量份 0. 15 0.3 0.2 — — — 白由劑發生劑 重量份 -- — — 0.005 — 0.005 抗氧化劑 種類 Ph-2 Ph-2 Ph-2 Ph-1 Ph-1 Ph-1 重量份 0.1 0· 1 0· 1 0.02 0.02 0.02 中和劑硬脂酸鈣 重Μ份 0· 1 0.1 0· 1 0.02 0. 02 0.02 成型品物性 熔體流量(MFR) s/10. 一一 30 7 35 成型收縮率 % 1.4 1.4 1.5 1.42 1.46 1.45 屈曲彈性率. MPa 1150 1070 1100 900 1000 1050 耐衝擊性(-200 J/m — -- -- — — — (23。〇 J/m — -- — 120 80 50 梁式衝繫值do! w 101 101 98 — — 渾濁度 % 91 91 91 96 70 70 光澤. % 66 60 63 75 77 78 抗白化性 — — — X X X (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 486501 A7 _ B7 五、發明説明（45 ) ⑵射出成型 將上述調製的各顆粒，K射出成型機設定熔化樹脂溫 度23〇°G,金屬模型溫度50^0/製作JIS形試片和諸物性 測定用試片。 試片在濕度50¾ ，室溫231C的室内調整72小時狀態後 ，利用下述方法測定諸物性值。 U)成型收縮率：從成型機的金屬模型全長，減所調 製抗拉試片（JIS K 7113 1號抗拉試片）全長，與金屬 模型相比之100倍，由下式算出： (金屬模型全長-試片全長） 成型收縮率 =-X 1〇〇 (金屬模型全長） (b) 屈曲彈性率（MPa):根據J IS K 7203測定。 (c) 耐衝擊性：根據JIS K 7110,在-20t：和231〇測 定。 β (d) 懸臂梁式衝擊強度（J/M2):根據JIS Κ7110, 在-30¾測定。 (e) 湩濁度：由25X5〇xlmm平板狀試片，根據ASTM D 1 0 0 3測定。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) (f) 光澤：根據ASTM D 5 23鏡面光澤度法，Μ指示角 60度測定。 (g) 抗白化性：使用具有鉸件構造的試片，在鉸件部 份折曲，目視觀察白化程度，按下述三階段評估。 〇：铰件部份顔色與其他部份同等， 一 47- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X297公釐） 經濟部中央標準局員工消費合作社印製 486501 A7 B7 五、發明説明（46 ) △:鉸件部份顔色較其他部份稍白， X :鉸件部份顔色較其他部份顯著白， 測定結果如表3〜表6所示。表中衝擊試驗數據中NB ，表示試片在設定條件未受破壞。 又，本發明試料Ci-1至Ci-6和比較試料cCi-Ι至cCi-6 的丙烯均聚物和丙烯-乙烯共聚物之極佩黏度與重量比 乘積，對成型收縮率的關係如第1圖，屈曲彈性率如第 2圖所示。 C.片材成型用聚丙烯系組成物（Cs)及片材之製造 W聚丙烯系組成物 於本發明丙烯系組成物A-1至A-6和比較組成物cA-1 、3 、5和7各粉末，添加各種添加成份，使用高速攪 拌式混合器（Henschel混合器），在室溫下混合5〜10分 鐘，混合物使用螺桿口徑40ma的壓出製粒機，在汽缸設 定溫度230 t：製粒，調製顆粒。 本發明聚丙烯系組成物Cs-Ι至Cs-6和比較組成物cCS-1 至cCs-4各添加成份及添加量，如表7和表8所示。 所用添加成份及表中簡稱如下： 杭氬化_ P - 1 :磷系熱安定劑 P - 2:三（2,4-二特丁基苯基）磷酸酯 中和割：同前述。 一 4 8 - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) .鳝.Table 6 Comparative composition for injection molding and injection molding (I) Injection molding _ Example No. 8 9 10 11 12 13 Polypropylene based product (Ci) No. cCi-8 cCi-9 cCi-10 cCi -11 cCi-12 cCi-13 Acrylic acid composition (A) Order cA-2 * cA-2 cA-2 cA ~ 2 cA-2 cA-2 100 parts by weight 100 100 100 100 50 50 Propylene homopolymer f Ρ11Γ-3 ΓΙΙΓ 3 'Most parts — — — 50 50 α on the agent i 癍 a -1 α -2 a _3-— — parts by weight 0. 15 0.3 0.2 — — — parts by weight of the white generating agent-— — 0.005 — 0.005 Type of Antioxidant Ph-2 Ph-2 Ph-2 Ph-1 Ph-1 Ph-1 0.1 parts by weight 0.1 0 · 1 0 · 1 0.02 0.02 0.02 Neutralizer Calcium Stearate M parts by weight 0.1 0.1 0 · 1 0.02 0. 02 0.02 Molded product physical melt flow rate (MFR) s / 10. One-one 30 7 35 Molding shrinkage% 1.4 1.4 1.5 1.42 1.46 1.45 Flexural modulus of elasticity. MPa 1150 1070 1100 900 1000 1050 Impact resistance (-200 J / m —--— — — — (23.〇J / m —-— 120 80 50 Beam punching value do! W 101 101 98 — — Turbidity% 91 91 91 96 70 70 Gloss .% 66 60 63 75 77 78 Anti-whitening — — — XXX (Please read the notes on the back before filling out this page) This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 486501 A7 _ B7 V. Description of the invention (45) ⑵ Injection molding will For each of the granules prepared as described above, a K injection molding machine was set to a melting resin temperature of 23 ° G and a metal mold temperature of 50 ^ 0 / to produce JIS-shaped test pieces and test pieces for measuring various physical properties. The test pieces were placed in a room with a humidity of 50¾ and a room temperature of 231C. After adjusting the state for 72 hours, the physical properties were measured by the following method: U) Molding shrinkage: From the full length of the metal model of the molding machine, subtract the full length of the prepared tensile test piece (JIS K 7113 No. 1 tensile test piece), and Compared with the metal model, it is calculated by the following formula: (full length of the metal model-full length of the test piece) Molding shrinkage = -X 100 (full length of the metal model) (b) Flexural modulus (MPa): According to J IS K 7203 determination. (c) Impact resistance: Measured at -20t: and 2310 according to JIS K 7110. β (d) Izod impact strength (J / M2): Measured at -30¾ according to JIS K7110. (e) Radon turbidity: Measured from a 25 × 50 × lmm flat test piece in accordance with ASTM D 1 0 03. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) (f) Gloss: measured according to ASTM D 5 23 specular gloss method, with M indicator angle 60 degrees. (g) Whitening resistance: A test piece having a hinge structure was used to bend the hinge portion, and the degree of whitening was visually observed, and evaluated in the following three stages. 〇: The color of the hinge part is the same as the other parts. 47- This paper size applies the Chinese National Standard (CNS) A4 (210 X297 mm). Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 486501 A7 B7 5. Invention Explanation (46) △: The color of the hinge part is slightly whiter than the other parts, X: The color of the hinge part is significantly whiter than the other parts, and the measurement results are shown in Tables 3 to 6. NB in the impact test data in the table indicates that the test piece is not damaged under the set conditions. In addition, the extremely viscosities of the propylene homopolymers and propylene-ethylene copolymers of the samples Ci-1 to Ci-6 and the comparative samples cCi-1 to cCi-6 of the present invention have extremely high viscosity and weight ratio products. Fig. 1 shows the buckling modulus as shown in Fig. 2. C. Production of polypropylene-based composition (Cs) for sheet molding and sheet W polypropylene-based composition in the propylene-based compositions A-1 to A-6 of the present invention and comparative compositions cA-1, 3, 5 And 7 powders, adding various added ingredients, using a high-speed stirring mixer (Henschel mixer), mixing at room temperature for 5 to 10 minutes, using a screw diameter of 40ma extruder granulator, set the temperature in the cylinder 230 t : Granulation, granulation. The added components and amounts of the polypropylene-based compositions Cs-1 to Cs-6 and the comparative compositions cCS-1 to cCs-4 of the present invention are shown in Tables 7 and 8. The added ingredients and abbreviations in the table are as follows: Hang argonized P_1: Phosphorous heat stabilizer P-2: Tris (2,4-di-tert-butylphenyl) phosphate Neutralization cut: Same as above. 1 4 8-This paper size applies Chinese National Standard (CNS) Α4 specification (210X 297 mm) (Please read the precautions on the back before filling this page). 鳝.

、1T 486501, 1T 486501

7 7 A B 經濟部中央標準局員工消費合作社印製 五、發翏夢明4材7 4型用姐成物及Η材 Η材成型實施例藥次 1 2 3 4 5 6 聚丙烯系組成物(Cs) Cs-1 Cs-1 Cs-1 Cs-1 Cs-1 Cs-1 丙烯条組成物(A) 號次 A-2 A-2 A-2 A-2 A-2 A-2 重量部 100 100 100 100 100 100 抗氧化劑 種類 P-2 .P-1 P-l P-l P-l P-1 重量部 0. 1 0· 1 0. 1 0. 1 ().1 U. 1 中和劑硬脂酸鈣 重量份 0.1 0.1 0.1 0.1 0.1 0.1 成型條件 樹脂溫度 °C 230 230 230 230 230 190 冷卻輥溫度 V 60 20 80 60 60 GO 成型速度 m/分 5 5 5 0.5 40 5 Η材物性 抗拉屈腋強度（50°C) MPa 15.4 — — — -- 一一 楊氏係數(23°C) MPa 382 — — ~ -- 一一 打孔衝擊強度 (0°C) J 折曲白化 min φ 印刷性 〇 — -- — — -- H材成型實施例號次 7 8 9 10 11 12 聚丙烯系組成物(Cs) Cs-1 Cs - 2 Cs-3 Cs-4 Cs-5 Cs-6 丙烯系組成物(A) 號次 A-2 A-5 A-l A-3 A-4 A-6 重量部 100 100 100 100 100 100 抗氧化劑 種類 P-l P-2 P-2 P-2 P-2 P-2 重量部 0.1 0.1 0.1 0.1 0.1 0.1 中和劑硬脂酸S丐 重量份 0.1 0.1 0.1 0.1 0.1 0.1 成型條件 樹脂溫度 270 230 230 230 230 230 冷卻輥溫度 °C 60 60 60 60 60 60 成型速度 m/分 5 5 5 5 5 5 Η材物性 抗拉屈服強度（50°C) MPa — 15.6 18.7 15.5 15.2 18.7 楊氏係數(23t) MPa — 331 376 404 393 382 打孔衝擊強度 ore) j S3 — 一一 一 折曲白化 mm φ -- __ —— __ 印刷性 — 〇 o 〇 〇 〇 -49- (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X2^、_ ) 486501 β Α7 Β7 五'發明説明（从） 經濟部中央標準局員工消費合作社印製7 7 AB Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5 、 Fameng Mengming 4 materials. 7 Type 4 female products and sapwood materials. Example Example 1 2 3 4 5 6 Polypropylene composition ( Cs) Cs-1 Cs-1 Cs-1 Cs-1 Cs-1 Cs-1 Propylene composition (A) No. A-2 A-2 A-2 A-2 A-2 A-2 Weight part 100 100 100 100 100 100 Antioxidant type P-2 .P-1 Pl Pl Pl P-1 Weight part 0. 1 0 · 1 0. 1 0. 1 (). 1 U. 1 Neutralizer calcium stearate weight 0.1 0.1 0.1 0.1 0.1 0.1 Molding conditions Resin temperature ° C 230 230 230 230 230 190 Cooling roller temperature V 60 20 80 60 60 GO Molding speed m / min 5 5 5 0.5 40 5 ° C) MPa 15.4 — — —-One by one Young's coefficient (23 ° C) MPa 382 — — ~-One punch impact strength (0 ° C) J Bending whitening min φ Printability 0-- — — — H material molding example No. 7 8 9 10 11 12 Polypropylene-based composition (Cs) Cs-1 Cs-2 Cs-3 Cs-4 Cs-5 Cs-6 Propylene-based composition (A) A-2 A-5 Al A-3 A-4 A-6 Weight 100 100 100 100 100 100 Antioxidant Chemical type Pl P-2 P-2 P-2 P-2 P-2 Weight 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Neutralizer stearic acid 0.1 parts by weight 0.1 0.1 0.1 0.1 0.1 0.1 Molding conditions Resin temperature 270 230 230 230 230 230 Cooling roller temperature ° C 60 60 60 60 60 60 Molding speed m / min 5 5 5 5 5 5 Physical properties Tensile yield strength (50 ° C) MPa — 15.6 18.7 15.5 15.2 18.7 Young's coefficient (23t) MPa — 331 376 404 393 382 punching impact strength ore) j S3 — one by one bending whitening mm φ-__ —— __ printability — 〇o 〇〇〇-49- (Please read the precautions on the back before (Fill in this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210X2 ^, _) 486501 β Α7 Β7 Description of the 5 'invention (from) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

表8 Η材成型用比較組成物及片材 片材成型實施例諕次 .1 2 3 4 聚丙烯系組成物(Cs) cCs -1 cCs-2 cCs-3 cCs-4 丙烯系組成物(A) 號次 cA -1 cA-5 cA - 3 cA-7 重量部 100 100 100 100 抗氧化劑 種類 P-2 P-2 P-2 P-2 重量部 0· 1 0· 1 0· 1 0· 1 中和劑磾脂 重量份 0. 1 0.1 0.1 0.1 j成型條件 樹脂溫度 °C 230 230 230 230 冷卻輥溫度 ec 60 60 60 60 成型速度 ffl/分 5 5 5 5 Η材物性 抗拉屈腋強度（5(TC) MPa 18.6 17.3 22.2 12. 1 楊氐係數(23°C) MPa 510 480 617 208 打孔衝擊強度 （0°C) J -- 一一 折曲白化 ΠΗΠ φ 15 20 一一 — 印刷性 〇 〇 〇 X (請先閱讀背面之注意事項再填寫本頁) — 50 — 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 486501 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（49 ) 1 1 ⑵ 片 材 成 型 1 1 將 上 述 調 製 的 各 組 成 物 $ 使 用 具 有 T 模 具 和 磨 光輥 的 1 1 片 材 成 型 機 9 如 表 9 和 表 10所 示 f Μ 汽 缸 設 定 溫 度、 冷 —V 請 1 先 Γ m 溫 度 和 成 型 速 度 赘 成 型 厚 度 5 61 m 的 片 材 〇 閱 讀 1 I 4 成 型 片 材 在 濕 度 50% 室 溫 23 υ 的 室 内 調 整72小時狀 態 背 1 I 之 9 測 定 下 列 物 性 〇 成 型 條 件 和 物 性 測 定 结 果 如 表 7和 表 注 意 1 I 8 所 示 〇 事 項 Γ (a ) 抗 拉 屈 服 點 強 度· (MPa ) 在 50 t! 恆 溫 槽 中 放置 30 再 填 寫 本 f 分 鐘 Κ 上 9 根 據 ASTM D 882 測 定 〇 頁 1 I (b) 楊 氏 係 數 (MPa ) • 在 23 室 內 放 置 48小 時 Κ上 後 1 1 t 根 據 ASTM D 882 測 定 〇 1 1 (c ) 打 孔 衝 擊 強 度 (J) : 根 據 ASTM D 781 測 定 〇 1 訂 (d) 折 曲 白 化 性 (m m Φ ) · 將 寬 10 Ifi HI 9 長 120di ^的Η材 打 孔 &gt; 做 為 試 片 將 此 試 片 兩 端 漸 漸 趨 近 折 曲 9 測定 彎 1 I 曲 部 發 生 白 化 時 的 曲 率 $ 算 出 與 此 曲 率 相 對 應 的 圓形 直 1 I 徑 f 即 為 折 曲 白 化 性 9 做 為 抗 白 化 性 的 指 標 〇 1 1 (e ) 印 刷 性 ： 使 用 照 相 凹 版 印 刷 m 9 在 乾 燥 溫 度5C )V f K 印 刷 速 度 5 m / mi η進行三色印刷， 目視觀察印刷不 1 1 I 勻 Ο 1 1 〇 ♦ • 無 印 刷 不 勻 I X ♦ 有 明 顯 的 印 刷 不 勻 1 L 表 7 和 表 8 表 示 成 型 條 件 和 物 性 測 定 結 果 〇 1 1 D · 膜 用 聚 丙 烯 系 組 成 物 (Cf ) 及 膜 之 製 造 1 I 聚 丙 烯 系 組 成 物 1 -51- 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 B7 五、發明説明（50 ) 於本發明丙烯糸組成物A-7至14, 2 , 4和5 ，K及 丙烯系比較組成物cA8至cA14 , 5和6 ，混配各添加成 份，MHenschel混合器（商品·名）混合後，使用單軸壓出 機（口徑40min^)熔混粒化，調製成膜用聚丙烯系組成物 cCf·1至12M及比較組成物cCfl至9 。 聚丙烯系組成物和比較組成物，如表9和表10所示。 所用添加成份及表中簡稱如下述： 杭氬化颧Table 8 Comparative Compositions for Sheet Metal Forming and Sheet Sheet Forming Examples. 1 2 3 4 Polypropylene-based composition (Cs) cCs -1 cCs-2 cCs-3 cCs-4 Acrylic-based composition (A ) Number cA -1 cA-5 cA-3 cA-7 Weight part 100 100 100 100 Antioxidant type P-2 P-2 P-2 P-2 Weight part 0 · 1 0 · 1 0 · 1 0 · 1 Neutralizer weight part 0.1 0.1 0.1 j Molding conditions Resin temperature ° C 230 230 230 230 Cooling roller temperature ec 60 60 60 60 Molding speed ffl / min 5 5 5 5 5 (TC) MPa 18.6 17.3 22.2 12. 1 Young's coefficient (23 ° C) MPa 510 480 617 208 Punch impact strength (0 ° C) J-one by one bending whitening ΠΗΠ φ 15 20 one by one — printability 〇〇〇X (Please read the notes on the back before filling out this page) — 50 — This paper size applies to China National Standard (CNS) A4 specifications (210X 297 mm) 486501 A7 B7 Preparation 5. Description of the invention (49) 1 1 成型 Sheet molding 1 1 Finished product $ 1 1 sheet forming machine with T mold and polishing roller 9 As shown in Table 9 and Table 10 f Μ cylinder set temperature, cold-V Please 1 Γ m temperature and molding speed redundant thickness 5 61 m sheet 〇Reading 1 I 4 The molding sheet is adjusted in a room with a humidity of 50% at room temperature 23 υ for 72 hours. Back 1 I 9 The following physical properties are measured. 0 The molding conditions and physical property measurement results are shown in Table 7 and Table 1 1 8 〇Items shown Γ (a) Tensile yield point strength (MPa) Place in a 50 t! Thermostatic bath for 30 minutes and fill in this f minutes K on 9 Measured according to ASTM D 882 Page 1 I (b) Young's coefficient ( MPa) • 1 t after standing for 48 hours in a 23-ch room. Measured according to ASTM D 882. 0 1 1 (c) Punch impact strength (J): Measured according to ASTM D 781. (d) Flexibility and whiteness ( mm Φ) Ifi HI 9 Perforated with a length of 120di ^ and as a test piece, the two ends of the test piece are gradually approached to bend 9 Measure the bend 1 I Curvature when whitening occurs in the curved portion $ Calculate a circle corresponding to this curvature Straight 1 I diameter f is the bending whitening property 9 as an index of whitening resistance 〇1 1 (e) printability: using gravure printing m 9 at a drying temperature 5C) V f K printing speed 5 m / mi η Three-color printing, visual observation of printing unevenness 1 1 I uniformity 0 1 1 〇 • No printing unevenness IX ♦ Significant printing unevenness 1 L Table 7 and Table 8 show molding conditions and physical property measurement results 〇 1 1 D · Film Manufactured from polypropylene-based composition (Cf) and film 1 I Polypropylene-based composition 1 -51- 1 1 1 This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 B7 V. Invention Description (50) In the present invention C糸 Compositions A-7 to 14, 2, 4, and 5, K and propylene-based comparative compositions cA8 to cA14, 5, and 6, mix each added component, and use a MHenschel mixer (product name) to mix, then use a single shaft An extruder (caliber 40 min ^) was melt-mixed and granulated to prepare polypropylene-based compositions cCf · 1 to 12M for film and comparative compositions cCfl to 9. The polypropylene composition and the comparative composition are shown in Tables 9 and 10. The added ingredients and abbreviations in the table are as follows:

Ph - 2:四[亞甲（3,5-二特丁基-4-羥基苯基）丙酸酯] 甲烷 P - 2: 三（2,4-二特丁基苯基）磷酸酷 中和劑：硬脂酸鈣 阻塞防止劑：氧化矽 潤滑劑：油酸醯胺 (請先閱讀背面之注意事項再填寫本頁) - 訂 經濟部中央標準局員工消費合作社印製 一52- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 486501 A7 B7 五、發明説明（5| ) 經濟部中央標準局員工消費合作社印製 mnmmn fe bt κ a ^ g s冰谇赛 illll I lliS m I « a w 23次1次 ^iil ^fil 霄 ^ ^ g a梗鞔弒 ^ # Et S Φ # IS冰漭藏 _ιρ m δ 锻 〇° 〇° ί ^ _ . m 鐽薛丑贫贫 21 a 琏敝®濟雜 MM 爸臣菡磨遵 nm 藏碧s ““ b a 藤潰隳下？ 豸豸 SI cr 3¾ ^ to 0 ο 脚1卿脚1脚1脚1 Λ载說 ΙΦ _ tti _ ώ _ 膜成型實施例號次 1 1 1 1 till 1 1 ! *—1 1 GO tvD tvD cz5 cr&gt; ^ Cf-1 A-7 99.49 0. 03 0. 08 0.1 0.2 0.1 »—j* lilt 1 1 1 1 1 1 ί »—* 1 co to CD cn cn ^ CD CDC5CZ&gt;CDCDC〇&gt;-Q V-^tNDk-^CZ5&lt;Z?J^O〇t0 oo CO CO to lilt 1 1 1 1 ! 1 ! 1 co to cn cd cn cn cr&gt; Cf-3 A-9 99.49 0.03 0.08 0.1 0.2 0.1 CO ! i i i tilt ! 1 ! &gt;—1 1 CO CO to cn cd cn to Cf-4 A-10 99.49 0.03 0.08 0.1 0.2 0.1 •Cw i 1 1 1 till 丨丨! ί ^ 1 to to CT&gt; C=? C=&gt; CD 〇1 oo Cf-5 A -11 99.49 0. 03 0.08 0.1 0.2 0.1 cn till 1 1 1 1 ! ! 1 ^ 1 CO CO oo CD cn CO OJ to Cf - 6 A-12 99.49 0.03 0.08 0.2 0.1 cn 1 1 1 1 1 1 1 1 ! 1 ί 14.3 40 -25 130 Cf-7 A-13 99.49 0. 03 0. 08 0.1 0.2 0.1 till 1 1 1 1 ! ί 1 一 1 tO to A cn cn jtw to Cf - 8 A-14 99.49 0.03 0.08 0.1 0.2 0.1 oo to oo cd &lt;Z? CO 12,4 130 135 ! ί ί 1 Cf - 9 A-2 99.49 0.03 0.08 0.1 0.2 -0.1 CJD to CjD cn -q cd o co cn cn co 15.0 130 130 ；1 1 1 Cf -10 A_4 99.49 0.03 0.08 0.1 0.2 0.1 1~‘ 1 9.8 12.6 1140 230 17.8 110 130 till 1 1 1 1 Cf-11 A-5 99.49 0.03 0. 08 0.1 0.2 0.1 1~^ μ—* :ί ί ί ί 1 1 1 1 1 1 1 1 1 1 CM2 A-6 99.49 0. 03 .0.08 0.1 0.2 0.1 to 姍9ffigtlla薛铒豸涔悃s藏 (請先閲讀背面之注意事項再填寫本頁) -53- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）Ph-2: Tetra [methylene (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] Methane P-2: Tris (2,4-di-tert-butylphenyl) phosphate is neutralized Agent: Calcium stearate blocker: Silicon oxide Lubricant: Ammonium oleate (Please read the precautions on the back before filling out this page)-Order Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 52- This paper size Applicable to China National Standard (CNS) A4 specification (210X297 mm) 486501 A7 B7 V. Description of invention (5 |) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs mnmmn fe bt κ a ^ gs Moraine illll I lliS m I «Aw 23 times 1 time ^ iil ^ fil xiao ^ ^ ga 梗 鞔 弑 ^ # Et S Φ # IS 冰 漭 藏 _ιρ m δ smith 0 ° 〇 ° ί ^ _. M济 Miscellaneous MM Dad and Honor Zunnm Tibetan Tibetan s "" ba vine rush?豸 豸 SI cr 3¾ ^ to 0 ο foot 1 clear foot 1 foot 1 foot 1 Λ contains said IΦ _ tti _ free _ film forming example number 1 1 1 1 till 1 1! * -1 1 GO tvD tvD cz5 cr &gt; ^ Cf-1 A-7 99.49 0. 03 0. 08 0.1 0.2 0.1 »—j * lilt 1 1 1 1 1 1 ί» — * 1 co to CD cn cn ^ CD CDC5CZ &gt; CDCDC〇 &gt; -Q V -^ tNDk- ^ CZ5 &lt; Z? J ^ O〇t0 oo CO CO to lilt 1 1 1 1! 1! 1 co to cn cd cn cn cr &gt; Cf-3 A-9 99.49 0.03 0.08 0.1 0.2 0.1 CO! iii tilt! 1! &gt; —1 1 CO CO to cn cd cn to Cf-4 A-10 99.49 0.03 0.08 0.1 0.2 0.1 • Cw i 1 1 1 till 丨 丨! ί ^ 1 to CT &gt; C =? C = &gt; CD 〇1 oo Cf-5 A -11 99.49 0. 03 0.08 0.1 0.2 0.1 cn till 1 1 1 1!! 1 ^ 1 CO CO oo CD cn CO OJ to Cf-6 A-12 99.49 0.03 0.08 0.2 0.1 cn 1 1 1 1 1 1 1 1! 1 ί 14.3 40 -25 130 Cf-7 A-13 99.49 0. 03 0. 08 0.1 0.2 0.1 till 1 1 1 1! ί 1 1 1 tO to A cn cn jtw to Cf-8 A-14 99.49 0.03 0.08 0.1 0.2 0.1 oo to oo cd &lt; Z? CO 12,4 130 135! Ί ί 1 Cf-9 A-2 99.49 0.03 0.08 0.1 0.2 -0.1 CJD to CjD cn -q cd o co cn cn co 15.0 130 130; 1 1 1 Cf -10 A_4 99.49 0.03 0.08 0.1 0.2 0.1 1 ~ '1 9.8 12.6 1140 230 17.8 110 130 till 1 1 1 1 Cf-11 A-5 99.49 0.03 0. 08 0.1 0.2 0.1 1 ~ ^ μ-*: ί ί ί ί 1 1 1 1 1 1 1 1 1 1 CM2 A-6 99.49 0. 03 .0.08 0.1 0.2 0.1 to Shan 9ffigtlla Xue Zangsang (Please read the precautions on the back before filling this page) -53- This paper Applicable to China National Standard (CNS) A4 specification (210X297 mm)

486501 A7 B7 五、發明説明（ίΡ·) 經濟部中央標準局員工消費合作社印製486501 A7 B7 V. Description of Invention (ίΡ ·) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

挺 時冰K S薛 _ S bt阵苕 1 _1§馨 illsi m S ^ ^ 1 ac 、 23 ^ I 次 )€ a輮鞔罃 b &amp; m 缕bf漭：g ® s ^ 1義_ 薩 。。裒$ m m m ^ m :您徽e s笤 #薛e阵鍤 h? )¾ ® ^ # 蹇靈辟 m δ 〇° 〇° ί ^ 筠 銬固ΐ贫贫 a 51 洚敝苕ft濟 荔薛 ^ ^ m mm bm 薄墅舔““ BB m mm ύ ^ 莛兹 ^ ^ gg 鷓細1鷗鞣鞣 趨 _ 喊 ΐΕΐϋ _ _ ^ ^ ^ )&gt;ir 藏 gt 塒 察 衷 m 1 1 1 f 1 1 1 1 ! ! ! 1 to ^ OO cn »—* i—^ —3 C&gt;C5CZ&gt;CZ5CZ&gt;S&gt;- f-*CsD^CDC=&gt;^d〇V-^ OO CO CO I~ι 1 1 1 1 ί ί ! 1 ^ cn ^ CD CO CD ⑺ o o CDCDCDCDCDcS'i&quot; Q ^ tSD CZ5 CZ&gt; ，C〇 CO CO CO to 1 1 1 1 1 1 1 1 ! ! ! CD CD ί—^ OO C=&gt;C&gt;C3CDC=5S&gt;-Ck 一 t〇 一 CDC5*fcw 丄 丄 OO CO CO CD CO lilt ! ! ! 1 CO OO tsD cz&gt; cd cn ⑺ &lt;^&gt;CZ&gt;CDCDC&gt;CjD&gt;.iIs 一 tv〇i~»CD&lt;3&gt;*r^M 丄 OO CO CO »» 1 1 1 1 1 1 1 1 ! ! ! 1 cn oo »—i CO oqcjcdcdSS-Q *—1tN0^CDO^»-^CJ1 OO OO CO CO cn till ! ! ! 1 CsD ^ J CJ1 CD »fc^ CZ&gt;p&gt;C3p&gt;CDc〇&gt;.^ V-*tNDH-*CZ&gt;OJ^»-!^CT&gt; 〇〇 CO CO CO cr&gt; 1 1 1 1 till 1~1 一 1 cn t^D cn cn ^ o CDC=5CZ5CZ&gt;C=5S&gt;-S ......1 1 OO CO CO 〇〇 OO CO CZD C5 to CD to 1~^ »—k CD Ο &lt;Ζ&gt; CO 1 till 1 1 1 C5&lt;〇CZ5CDCr&gt;S&gt;-i^ OD CO CO OO »—1 CO ① c_o cn CZ5 CZ5 »^ »—A cr&gt; co 1* 1* »—4 CD CJ5 CD CD CD OO 1 1 1 1 1 1 \ 1 C=5 c=&gt; CZ5 c=5 CD CO &gt;- ^ ►—^NDv—^OCD^ckcjD OO CO CO CO 紲一〇 藏Ellsatbs薛a聲卸《麵藏 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 B7 五、發明説明（55) ⑵單層膜的成型 U)無延伸膜 使用具備T模具的單層壓出機（口徑65mm炎），將Cf-1 至8和cCf-1至7 ,在壓出溫度230¾加K壓出，Μ空氣 室和表面溫度30C的冷卻輥驟冷，得厚度25/im的無延 伸膜。 (b) 雙軸延伸膜 使用具備T模具的單層壓出機（口徑40fflm4),將Cf-9 至11, cCf-δ和9 ,在壓出溫度230 1壓出，Μ空氣刀和 表面溫度30C的冷卻輥冷卻凝固，成型為厚度2.0ιβιβ的 未延伸片材。其次，所得未延伸片使用分批式雙軸延伸 機，在延伸溫度157C,雙軸延伸（壓出方向5.0倍，橫 向8.0倍），得厚度50^ιη的雙軸延伸膜。 (c) 單軸延伸膜 使用具備T模具的單層壓出機（口徑4Οηιιη0),將Cf - 9 至11, cCf-8和9 ,在壓出溫度23〇υ壓出，以空氣刀和 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 表面溫度601C之冷卻輥冷卻凝固，成型為厚度0.25mm的 未延伸片。其次，所得未延伸片使用分批式雙軸延伸機 ，在延伸溫度1201C,於壓出方向單軸延伸5.0倍，得 厚度50 w ®的單軸延伸膜。 (3)積層膜的成型 U)無延伸膜 調製本發明聚丙烯糸組成物Cf-2和4 Μ及比較組成物 cCf-Ι和6 ，與下述聚烯烴系組成物之二種三層和三種 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（S4 ) 三層無延伸膜。 聚烯烴集甜成物 P0-1:於密度0.90g/citt3·、結晶融點163°C、熔點流 量（MFRH.Og/liT的丙烯均聚物9 9.4 9重量％ ，混配四 [亞甲（3, 5-二特丁基-4-羥基苯基）丙酸酯]甲烷0.03重 量％ 、三（2,4-二特丁基苯基）磷酸酯0、08重量3；,硬脂 酸鈣〇·1重量X ，氧化矽（阻塞防止劑）D.2重量％ ，和 油酸醯胺（潤滑劑）〇·1重量5：，以Henschel混合器（商 品名）混合後，使用單軸壓出機（口徑40iftin9S )融混粒化 所得組成物。 P0-2··於密度（K90g/cm3、結晶融點132°C、熔體流 量0?1〇6.{^/1^的丙烯-乙烯-丁烯-1共聚物99.4 9重 量％ ,混配四[亞甲（3,5-二特丁基-4-羥基苯基）丙酸酯] 甲烷0.03重量％ 、三（2, 4_二特丁基苯基）磷酸酯0.08重 量％ 、硬脂酸鈣〇 · 1重量％ 、氧化矽（阻塞防止劑）0 · 2 重量％ ，和油酸醯胺（潤滑劑）0 . 1重量％ ，以H e n s c h e 1 混合器（商品名）混合後，使用單軸壓出機（口徑400 mia多） 融混粒化所得組成物。 使用具備多層T模具的三種三層壓出機（口徑65iam^ 的中間層用單軸壓出機一部，口徑5Omni0的表層用單軸 壓出機二部），於中間層用單軸壓出機供前述聚丙烯条 組成物，於表層用單軸壓出機供應前述聚烯烴糸組成物 ，在230 °C融化，進行二種三層或三種三層的多層共壓 出，以空氣室和表面溫度3 0 °C的冷卻棍加以冷卻凝固， -56- (請先閱讀背面之注意事項再填寫本頁) 衣. 、1Τ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 __B7_五、發明説明（55 ) 得厚30// m(厚度構成比=1:4:1)構成的二種三層或三種 三層無延伸膜。 層構造如表11和表12所示。 (b)雙層延伸膜 使用具備多層T模具的三種三層壓出機（口徑65min必 的中間層用單軸壓出機一部，口徑5 0 πιιοφ的表層用單軸 壓出機二部），於中間層用單軸壓出機供應聚丙烯系組 成物Cf-12和cCf-8,於表層用單軸壓出機供應前述聚烯 烴系組成物，在230 ¾融化，進行二種三曆的多層共壓 出，K空氣刀和表面溫度30笱的冷卻輥冷卻凝固，成型 為厚度2.Omni(厚度構成比=1/18/1)的二種三層未延伸 片材〇其次，所得二種三層未延伸Η材使用分批式雙軸 延伸機，於延伸溫度157¾雙軸延伸（壓出方向5.0倍， 橫向8.0倍），得厚度50/iio的雙軸延伸膜。 層構成如表11和表12所Tfc。 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 -57 二 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 486501 A7 B7 五、發明説明（％ ) 表Π 積層膜（實施例） 經濟部中央標準局員工消費合作社印製 膜成型實施例號次 13 14 15 16 17 18 層構成 中間層聚丙烯組成物(Cf) Cf - 2 • Cf-4 Cf-2 Cf-4 Cf-12 Cf-12 表皮層1聚鋪烴組成物 P0-2 -PO-2 PO-1 PO-1 PO-1 PO-2 表皮層2聚烯烴組成物 P0 - 2 PO-2 PO-2 PO-2 PO-1 TO 2 無延伸多層膜物性 透明性(渾濁） % 2.2 1.8 2.3 1.8 -- —— 光澤 % 115 119 116 119 — 一一 壓出方向撕裂強度 Ν/πππ 40 23 38 23 一- 一一 附寒溫度 °c -25 -20 -20 -15 — — 酎熱性 X： 135 140 140 145 一 一一 熱封溫度 °c -- 一 130 130 一 一一 雙軸延伸膜物性 透明性(潭濁） % -- — -- — 0.2 1.8 MPa — 150 130 熱封溫度 °c — — — — — 130 表12 積層膜（比較例） 膜成型實施例號次 10 11 12 13 14 層構成 中間層聚丙烯組成物(Cf) cCf -1 cCF - 6 cCF-6 cCF-8 cCf - 8 表皮層1聚烯烴组成物 •PO-2 PO-2 PO-1 PO-1 PO-2 表皮廇2聚烯烴組成物 PO-2 PO-2 PO-2 PO-1 PO-2 無延伸多層膜物性 透明性(潭濁） % 4.2 6.7 6.8 一一 — 光澤 % 90 81 80 -- —— 壓出方向撕裂強度 N/mra 10 8 8 -- 一 附寒溫度 °c -25 -25 -20 -- — 附熱性 °c 135 135 140 —— __ 熱封溫度 °C -- — 130 — 一一 雙軸延伸膜物性 透明性(潭濁） % — — — 12. 7 10./1 MPa -- -- 110 90 熱封溫度 — -- — 130 本紙張尺度適用中國國家標準（€奶）人4規格（210乂297公釐）-58- (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 486501 A7 B7 五、發明説明（Μ ) ⑷膜物性 就上述調製的單層膜和積層膜評估如下物性。 (a )透明性U ):根據A S T M D 1 0 0 3 ,測定膜的渾濁， 做為透明性的基準。 (b )光澤U ):根據A S T M D 5 2 3，以2 0度指示角測定 膜光澤度。 (c)撕裂強度（N/mm):根據ASTM D 1 9 2 2 ,測定膜的 埃爾曼多夫撕裂強度。 (d )抗拉斷裂強度（Μ P a ):根據A S T M D 8 8 2 ,測定膜的 抗拉斷裂強度。 (e)抗拉斷裂伸長率（MPa):根據ASTM D 8 8 2，測定 膜的抗拉斷裂伸長率。 (f )耐塞溫度（°C ) ··膜在恆溫槽中保持1 5分鐘後，裉 據A S T M D 7 8 1，測定膜的衝擊強度，可得（K 5 J以上衝擊 強度的膜保持溫度。 (g) 耐熱性（°C):將膜切成lOXlOOfflBi長方形試樣， 在設定於預定溫度的矽光油槽保持1 G分鐘後，測定縱向 長度，以收縮長度對初期長度的百分率表示之值超過U 時的溫度。 (h) 熱封溫度（°C):雙軸延伸聚丙烯膜（20#)，與 使用黏箸劑進行乾式積層之膜，在密封溫度1 3 0〜1 9 0 °C 範圍，每隔5°C (計8個溫度條件），以密封壓力2MPa, 密封時間（K5秒，熱封寬度lOrom後，切成15mro寬度的長 方形試樣，在各密封溫度進行密封部9 0 °C剝離試驗，利 -59- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 訂 486501 A7 __B7_—五、發明説明（5.8 ) 用抗拉試驗機，Μ抗拉速度300®/miri測定，顯示0.5N / 15ιαιαΜ上剝離強度的最低密封溫度。 單層膜的評估結果列於表&amp;和表10,積層膜的評估结 果列於表11和表1 2中。 E.中空成型品用聚丙烯系組成物（Cb)及中空成型品 |⑴聚丙烯糸組成物 於本發明丙烯系組成物A-1 、2及比較組成物cA-3, 混配各種添加成份，使用Henschel混合器加K混合，利 用設定於250¾的壓出機，進行融混和壓出，調節粒狀 聚丙烯系組成物Cb-Ι至7 Μ及比較組成物cCb-Ι至4 。 聚丙烯系組成物和比較組成物，如表13和表14所示。 所用添加成份及表中簡稱如下述： 可塑彳h成份 1^0£:熔體流量（&quot;『1〇 0.48/10’，結晶融點110£0, 密度0.920g/cro3的低密度聚乙烯。 EVAC:熔體流量（MFR) 0.5g/10、結晶融點104υ, 密度0.925g/c®3乙酸丁酯含量3重量％的乙烯-乙酸 乙烯酯共聚物。 杭氯化割和中和:同前沭。 (請先閱讀背面之注意事項再填寫本頁) ··· 訂 經濟部中央標準局員工消費合作社¥製 -6〇- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 486501 A7 ___ B7 五、發明説明（W ) 經濟部中央標準局員工消費合作社印製 衾13 中空成型品成型用組成物及中空成型品 中空成型品實關號次 1 2 3 4 5 6 聚丙烯系組成物(Cf)號次 Cb-1 .Cb-2 Cb - 3 Cb-4 Cb - 5 Cb - 6 丙烯系組成物(A) 號次 A-1 • A-1 A-1 A-2 A-2 A-2 重量部 100 100 100 100 100 100 可塑化成分 種類 —- LDPE LDPE — EVAC EVAC 重量部 -- 10 15 — 10 15 抗氧化劑：Ph-2 重量部 0.15 0.15 0.15 0.15 0.15 0.15 抗氧化劑:P-2 重量部 0.05 0. 05 0. 05 0. 05 0. 05 0.05 中和劑硬脂酸鈣 重量份 0· 1 0.1 0:1 0.1 0. 1 0.1 接合樹脂組成物 — — — — — 一一 中空成型品物性 成型性 A A A A A A 柔軟性 B A A B Λ A 衝擊白化性 A A A A A A 酎熱性 A A A A B B 熔接特性 A A A A A A 接合強度 — — — — — — 中空成型品實施例號次 7 8 9 10 11 12 聚丙烯系组成物(Cf)號次 Cb-1 Cb-1 Cb - 2 Cb-2 Cb - 7 Cb - 7 _丙烯系組成物(A) 號次 A-1 A-1 A-1 A-1 A-1 A-1 重量部 100 100 100 100 100 100 可塑化成分 種類 — LDPE LDPE EVAC EVAC 重量部 — -- 10 10 10 10 抗氧化劑：Ph-2 重量部 0. 15 0.15 0. 15 0. 15 0. 15 0. 15 抗氧化劑：P-2 重量部 0.05 0. 05 0.05 0.05 0.05 0.05 中和劑硬脂酸鈣 重量份 0. 1 0. 1 0. 1 0· 1 0· 1 0· 1 接合樹脂組成物 EP-1 EP-2 EP-1 EP-2 EP-1 EP-2 中空成型品物性 成型性 Λ A A A A A 柔軟性 Β B A Λ A A 衝擊白化性 Λ A Λ Λ Λ Λ 耐熱性 A A Λ Λ A Λ 熔接特性 A A Λ A Λ Λ 接合強度 Λ A A Λ Λ Λ — 61 — (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 4|86501 五、發明説明（6。） A7 B7 經濟部中央標準局員工消費合作社印製Ting Shibing K S Xue _ S bt array 1 1 §§ illsi m S ^ ^ 1 ac, 23 ^ I times) a 輮 鞔 罃 b &amp; m bbf 漭: g ® s ^ 1 . Mm $ mmm ^ m: your emblem es ## 薛 e 阵 锸 h?) ¾ ® ^ # 蹇 灵 沛 m δ 〇 ° 〇 ° ί ^ Shackled to poverty or poverty a 51 m mm bm Boshu licking "" BB m mm ^ 莛 ^ ^ ^ gg 鹧 1 gu tan tanning trend _ shout ΐϋΕΐϋ _ _ ^ ^ ^) &gt; ir Tibetan gt 埘 察 心 m 1 1 1 f 1 1 1 1!!! 1 to ^ OO cn »— * i— ^ —3 C &gt; C5CZ &gt; CZ5CZ &gt; S &gt;-f- * CsD ^ CDC = &gt; ^ d〇V- ^ OO CO CO I ~ ι 1 1 1 1 ί ί! 1 ^ cn ^ CD CO CD ⑺ oo CDCDCDCDCDcS'i &quot; Q ^ tSD CZ5 CZ &gt;, C〇CO CO CO to 1 1 1 1 1 1 1 1 1!!! CD CD ί— ^ OO C = &gt; C &gt; C3CDC = 5S &gt; -Ck one t〇 one CDC5 * fcw 丄 丄 OO CO CO CD CO lilt!!! 1 CO OO tsD cz &gt; cd cn ⑺ &lt; ^ &gt; CZ &gt; CDCDC &gt; CjD &gt; .iIs one tv〇i ~ »CD &lt; 3 &gt; * r ^ M 丄 OO CO CO» »1 1 1 1 1 1 1 1!!! 1 cn oo» —i CO oqcjcdcdSS-Q * —1tN0 ^ CDO ^ »-^ CJ1 OO OO CO CO cn till!!! 1 CsD ^ J CJ1 CD »fc ^ CZ &gt; p &gt; C3p &gt; CDc〇 &gt;. ^ V- * tNDH- * CZ &gt; OJ ^»-! ^ CT &gt; 〇〇CO CO CO cr &gt; 1 1 1 1 till 1 ~ 1-1 cn t ^ D cn cn ^ o CDC = 5CZ5CZ &gt; C = 5S &gt; -S. ..... 1 1 OO CO CO 〇〇OO CO CZD C5 to CD to 1 ~ ^ »—k CD Ο &lt; Z &gt; CO 1 till 1 1 1 C5 &lt; 〇CZ5CDCr &gt; S &gt; -i ^ OD CO CO OO »—1 CO ① c_o cn CZ5 CZ5» ^ »—A cr &gt; co 1 * 1 *» —4 CD CJ5 CD CD CD OO 1 1 1 1 1 1 \ 1 C = 5 c = &gt; CZ5 c = 5 CD CO &gt;-^ ►— ^ NDv— ^ OCD ^ ckcjD OO CO CO CO 〇 一 藏 Ellsatbs Xuea Sheng unloading "Noodle (please read the precautions on the back before filling this page) This paper size is applicable to China Standard (CNS) A4 specification (210X 297 mm) 486501 A7 B7 V. Description of the invention (55) ⑵Single-layer film molding U) Non-stretch film using a single-layer extruder with a T mold (diameter 65mm inflammation), will Cf-1 to 8 and cCf-1 to 7 were extruded at a pressing temperature of 230¾ plus K, and the air chamber and the cooling roller at a surface temperature of 30C were quenched to obtain an unstretched film having a thickness of 25 / im. (b) Biaxially stretched film using a single laminating machine (caliber 40fflm4) with T mold, Cf-9 to 11, cCf-δ, and 9 at an extrusion temperature of 230 1 and an air knife and surface temperature The cooling roller at 30C was cooled and solidified to form an unstretched sheet having a thickness of 2.0 μm. Next, the obtained unstretched sheet was biaxially stretched at a stretching temperature of 157C using a batch-type biaxial stretching machine (5.0 times in the extrusion direction and 8.0 times in the transverse direction) to obtain a biaxially stretched film having a thickness of 50 μm. (c) Uniaxial stretch film using a single laminating machine with a T mold (caliber 4〇ηιη0), Cf-9 to 11, cCf-8 and 9 are extruded at an extruding temperature of 23 °, with an air knife and economical Printed by the Consumer Standards Cooperative of the Ministry of Standards and Standards (please read the precautions on the back before filling this page). The cooling roller with a surface temperature of 601C is cooled and solidified, and formed into an unextended sheet with a thickness of 0.25mm. Next, the obtained unstretched sheet was uniaxially stretched 5.0 times in the extrusion direction at a stretching temperature of 1201C using a batch-type biaxial stretching machine to obtain a uniaxially stretched film having a thickness of 50 w ®. (3) Molding of laminated film U) Non-stretch film preparation of the polypropylene fluorene compositions Cf-2 and 4M of the present invention and the comparative compositions cCf-1 and 6 with two three-layer and Three paper sizes are applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 486501 A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (S4) Three-layer non-stretch film. Polyolefine sweetener P0-1: at a density of 0.90g / citt3 ·, crystalline melting point of 163 ° C, melting point flow rate (MFRH.Og / liT of propylene homopolymer 9 9.4 9% by weight, mixed with four [methylene (3,5-Di-tert-butyl-4-hydroxyphenyl) propionate] 0.03% by weight of methane, tris (2,4-di-tert-butylphenyl) phosphate 0,08 by weight 3; stearic acid Calcium 0.1 weight X, silica (blocking preventive agent) D. 2% by weight, and ammonium oleate (lubricant) 0.1 weight 5: After mixing with a Henschel mixer (trade name), use a single shaft An extruder (caliber 40iftin9S) was used to melt and granulate the composition obtained. P0-2 .. Propylene at a density (K90g / cm3, crystalline melting point of 132 ° C, melt flow rate of 0 to 106. {^ / 1 ^ propylene -Ethylene-butene-1 copolymer 99.4 9% by weight, compounded with tetra [methylene (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] 0.03% by weight of methane, tris (2, 4 _Ditert-butylphenyl) phosphate 0.08% by weight, calcium stearate 0.1% by weight, silica (blocking preventive agent) 0.2% by weight, and ammonium oleate (lubricant) 0.1% by weight %, After mixing with Hensche 1 mixer (trade name), use Shaft extruder (caliber 400 mia or more) Melt and granulate the composition. Three types of three-layer extruder with a multi-layer T die (a diameter of 65iam ^ and a uniaxial extruder for the middle layer, a surface of 5Omni0 Use a uniaxial extruder (two parts), use a uniaxial extruder to supply the polypropylene strip composition in the middle layer, and use a uniaxial extruder to supply the aforementioned polyolefin rhenium composition on the surface layer, and melt at 230 ° C. Two types of three layers or three layers of three layers are co-extruded, and cooled and solidified by an air chamber and a cooling rod with a surface temperature of 30 ° C. -56- (Please read the precautions on the back before filling this page). 1T This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 486501 A7 __B7_ V. Description of the invention (55) The thickness is 30 // m (thickness composition ratio = 1: 4: 1) A three-layer or three-layer non-stretch film. The layer structure is shown in Table 11 and Table 12. (b) Three-layer three-layer extruder with multi-layer T mold is used for the middle layer. One shaft extruder, two single-shaft extruder for the surface layer with a diameter of 5 0 πιοφ), in the middle layer A uniaxial extruder was used to supply the polypropylene-based compositions Cf-12 and cCf-8, and the aforementioned polyolefin-based composition was supplied to the surface layer using a uniaxial extruder, which was melted at 230 ¾ and subjected to two types of three-calendar co-pressing. Out, the K air knife and the cooling roller with a surface temperature of 30 ° were cooled and solidified, and formed into two kinds of three-layer unstretched sheets having a thickness of 2.Omni (thickness composition ratio = 1/18/1). Second, the two kinds of three-layers were obtained. The unstretched cymbals are batch-type biaxially stretched. The biaxially stretched film is stretched at a temperature of 157¾ (5.0 times in the extrusion direction and 8.0 times in the transverse direction) at a stretching temperature of 50 / iio. The layer structure is as shown in Table 11 and Table 12 Tfc. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs -57 Two paper sizes are applicable to Chinese National Standards (CNS) A4 specifications (210X 297 mm) 486501 A7 B7 V. Invention Explanation (%) Table Π Laminated film (Example) Printed film molding example of employee consumer cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs No. 13 14 15 16 17 18 Layers constitute the intermediate layer polypropylene composition (Cf) Cf-2 • Cf -4 Cf-2 Cf-4 Cf-12 Cf-12 Epidermal layer 1 polymer hydrocarbon composition P0-2 -PO-2 PO-1 PO-1 PO-1 PO-1 PO-2 Epidermal layer 2 Polyolefin composition P0- 2 PO-2 PO-2 PO-2 PO-1 TO 2 Physical properties of non-stretched multilayer film Transparency (turbidity)% 2.2 1.8 2.3 1.8-—— Gloss% 115 119 116 119 — Tear strength in the direction of extrusion / πππ 40 23 38 23 One-one with cold temperature ° c -25 -20 -20 -15 — — 酎 Heat X: 135 140 140 145 One one one heat seal temperature ° c-one 130 130 one one one pair Axis stretch film physical transparency (tan turbidity)%----0.2 1.8 MPa — 150 130 Heat sealing temperature ° c — — — — 130 Table 12 Laminated film (comparative example) Film molding example No. 10 11 12 13 14 Layers constitute the intermediate layer polypropylene composition (Cf) cCf -1 cCF-6 cCF-6 cCF-8 cCf-8 Skin layer 1Polyolefin composition PO-2 PO-2 PO-1 PO-1 PO-2 Epidermal 廇 2 Polyolefin composition PO-2 PO-2 PO-2 PO-1 PO-2 Non-stretched multilayer film Physical properties Transparency (Tank turbidity)% 4.2 6.7 6.8-one-gloss% 90 81 80-—— tearing strength in the direction of extrusion N / mra 10 8 8-one attached cold temperature ° c -25 -25 -20--attached Thermal ° c 135 135 140 —— __ Heat-sealing temperature ° C-— 130 — Physical properties transparency of biaxially stretched film (tan turbidity)% — — — 12. 7 10./1 MPa--110 90 Heat-sealing temperature — 130 — This paper size is applicable to Chinese national standard (milk) 4 specifications (210 乂 297 mm) -58- (Please read the precautions on the back before filling this page) Central Bureau of Standards, Ministry of Economic Affairs Printed by the employee consumer cooperative 486501 A7 B7 5. Description of the invention (M) ⑷ Film physical properties The following physical properties are evaluated for the single-layer film and laminated film prepared as described above. (a) Transparency U): The turbidity of the film was measured according to A S T M D 1 0 0 3 as a reference for transparency. (b) Gloss U): The film gloss was measured at an angle of 20 degrees according to A S T M D 5 2 3. (c) Tear strength (N / mm): The Hermandorf tear strength of the film was measured according to ASTM D 1 9 2 2. (d) Tensile breaking strength (M P a): The tensile breaking strength of the film was measured according to A S T M D 8 8 2. (e) Tensile elongation at break (MPa): The tensile elongation at break of the film was measured according to ASTM D 8 8 2. (f) Plugging temperature (° C) ··· After the film is held in a constant temperature bath for 15 minutes, the impact strength of the film is measured according to ASTM D 7 8 1 to obtain (K 5 J or higher film holding temperature for impact strength). (g) Heat resistance (° C): The film was cut into lOXlOOfflBi rectangular specimens, and the length was measured in a silicon oil bath set at a predetermined temperature for 1 G minutes. The value expressed as a percentage of the contracted length to the initial length exceeded Temperature at U. (h) Heat-sealing temperature (° C): Biaxially stretched polypropylene film (20 #), dry-laminated film with adhesive, sealing temperature 1 3 0 ~ 19 0 ° C Range, every 5 ° C (8 temperature conditions), sealing pressure 2MPa, sealing time (K5 seconds, heat-sealing width 10 rom, cut into 15mro width rectangular samples, sealing at each sealing temperature 9 0 ° C peel test, Li-59- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling this page) Order 486501 A7 __B7_—V. Description of the invention ( 5.8) Measured with a tensile tester, M tensile speed 300® / miri, showing 0.5N / 15ι Minimum sealing temperature of peeling strength on αιΜ. The evaluation results of single-layer film are shown in Tables & 10, and the evaluation results of laminated film are shown in Table 11 and Table 12. E. Polypropylene composition for hollow molded products (Cb) and hollow molded product | ⑴Polypropylene 糸 Composition in the propylene-based composition A-1, 2 and the comparative composition cA-3 of the present invention, mix various additives, and use the Henschel mixer and K to mix, use the setting In an extruder of 250¾, melt blending and extrusion are performed to adjust the granular polypropylene-based composition Cb-1 to 7M and the comparative composition cCb-1 to 4. The polypropylene-based composition and the comparative composition are shown in Table 13 See Table 14. The added ingredients used and the abbreviations in the table are as follows: Mouldable ingredients: 1 ^ 0 £: Melt flow rate (&quot; "1〇0.48 / 10 ', crystalline melting point 110 £ 0, density 0.920g / cro3 low density polyethylene. EVAC: Melt flow rate (MFR) 0.5g / 10, crystalline melting point 104υ, density 0.925g / c®3 butyl acetate content 3% by weight of ethylene-vinyl acetate copolymer. Hang chlorine Chemical cutting and neutralization: same as before (Please read the notes on the back before filling this page) ··· Set the central standard of the Ministry of Economic Affairs Bureau Consumer Consumption Cooperative System ¥ 60- This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) 486501 A7 ___ B7 V. Description of Invention (W) Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 衾 13 Hollow molded product molding composition and hollow molded product hollow molded product No. 1 2 3 4 5 6 Polypropylene-based composition (Cf) No. Cb-1 .Cb-2 Cb-3 Cb-4 Cb-5 Cb-6 Acrylic composition (A) No. A-1 • A-1 A-1 A-2 A-2 A-2 Weight part 100 100 100 100 100 100 Type of plasticizing component — LDPE LDPE — EVAC EVAC Weight part-10 15 — 10 15 Antioxidant: Ph-2 Weight part 0.15 0.15 0.15 0.15 0.15 0.15 0.15 Antioxidant: P-2 Weight part 0.05 0. 05 0. 05 0. 05 0. 05 0.05 Neutralizer stearin 0.1 parts by weight of calcium acid 0 · 1 0.1 0: 1 0.1 0. 1 0.1 Bonding resin composition — — — — — One hollow molded product Physical properties Moldability AAAAAA Softness BAAB Λ A Impact whitening AAAAAA Heat resistance AAAABB Welding characteristics AAAAAA bonding Strength — — — — — — Example of hollow molded product 7 8 9 10 11 12 Polypropylene composition (Cf) grade Cb-1 Cb-1 Cb-2 Cb-2 Cb-7 Cb-7 _ Polypropylene composition (A) grade A-1 A-1 A-1 A-1 A-1 A-1 Weight part 100 100 100 100 100 100 Type of plasticizing ingredient — LDPE LDPE EVAC EVAC Weight part —-10 10 10 10 Antioxidant: Ph-2 Weight part 0. 15 0.15 0. 15 0. 15 0. 15 0. 15 Antioxidant: P-2 0.05 part by weight 0.05 0. 0.05 0.05 0.05 0.05 0.05 parts by weight of neutralizer calcium stearate 0.1 1 0. 1 0. 1 0 · 1 0 · 1 0 · 1 Bonding resin composition EP-1 EP-2 EP-1 EP-2 EP-1 EP-2 Hollow molded product Physical properties Moldability Λ AAAAA Flexibility Β BA Λ AA Impact whitening Λ A Λ Λ Λ Λ Heat resistance AA Λ Λ A Λ Welding characteristics AA Λ A Λ Λ Bonding strength Λ AA Λ Λ Λ — 61 — (Please read the precautions on the back before filling out this page) This paper size applies Chinese National Standard (CNS) A4 specifications ( 210X297 mm) 4 | 86501 V. Description of the invention (6. ) A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

表14 中空成型品成型用比較組成物及中空成型品 中空成型品實施例號次 1 2 · 3 4 5 6 7 聚丙烯系组成物(Cf)號次 cCb-l cCb-2 Cb-3 Cb-1 cCb-1 cCb-2 cCb-4 丙烯系組成物(A) 號次 cA-3 cA-3 A-1 cA-3 cA - 3 cA-3 cA - 3 重量部 100 100 100 100 100 100 100 可塑化成分 種類 — LDPE EVAC 一一 LDPF F.VAC 重量部 10 15 10 10 一抗氧化劑：Ph-2 重量部 0.15 0.15 0.15 0.15 0.15 0.15 0.15 抗氧化劑：p-2 mmm 0.05 0.05 0.05 0.05 0.05 0.05 0.05 中和劑硬脂酸鈣 重量份 0.1 0.1 0.1 0.1. 0.1 0.1 0.1 接合樹脂組成物 一 EP -1 EP-2 EP-1 EP-2 中空成型品物性 成型性 A A A A A A A 柔軟性 B A A B B A A 衝擊白化性 C C C C C C C 耐熱性 A A A Λ B A A 熔接特性 C C C C C C C 接合強度 — — — C C C C (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 4§6501 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明 ( 61 ) 1 I (2) 中 空 成 型 品 之 成 型 1 1 (a ) 中 空 成 型 品 (單品） -' · 1 I 將 上 述 調 節 的 粒 狀 聚丙烯 系組成物Cb -1 至 6 和 cCb-1 請 1 先 Γ 至 3 $ 供 至 中 空 成 型 機（SN - 5 0布拉優公 司製品）的壓出 閲 讀 1 機 9 於 2 0 0 υ壓出型坯，此型坯在調至3 0 υ的金屬模型 背 I i 之 1 I 内 吹 氣 9 成 型 為 側 面 部具有 蛇腹構造部的圓柱形中空成 注 意 I 蛇腹構造7螺節 事 L 型 品 (60 沴 &gt; c 300 X 1 . 6 ffl Bl t / 在中央部， 項 I t 環 節 間 10 m m f 溝 深 1 0 m ffl , 蛇腹部平均 厚度 0.9fli®t)。 再 填 寫 本 嘁 把 上 面 和 底 面 切 斷 9 即得中 空成型品。 頁 1 I (b) 中 空 成 型 品 (複合品） I 1 將 粒 狀 聚 丙 烯 Ά 組 成物Cb-1 、 2和7 ，或比較組成 I 1 物 cCb-1 Λ 2 和 4 9 供至具 有壓出機二 部的中空成型機 1 訂 之 壓 出 4m 耀 f 另 壓 出機則 供應下述聚 合物組成物之一 1 $ 先 利 用 前 — 壓 出 機 K2001C壓出型坯， 再Μ後一壓出 1 I 機 在 2 0 0 t壓出型坯， 二組成物連结製成型坯，此型坯 1 | 在 調 至 3 0 的 金 屬 模 型內吹 氣，成型為 側面部具有蛇腹 1 I 構 造 部 的 圓 柱 狀 中 空 成型品 (60沴 X 300 X / 在中 # 央 部 9 蛇 腹 構 造 7 螺 距，螺 距間1 0 πι m , 溝深10mi,蛇腹 1 1 1 部 平 均 厚 度 0 , 9 1 [1 t )&lt; &gt;此時， 由前述壓出機壓出的型坯 1 1 $ 進 行 調 節 到 蛇 腹 部 。將上 面和底面切 斷，得中空成型 1 I 品 (複合品） 〇 1 1 EP -1 结 晶 融 點 1651,屈曲彈性係數l,100MPa, MFR 1 1 0 . 6£ i g / 1 〇， 9 乙 烯 含 量59重 量Si的乙烯 -丙烯共聚物 1 I 12.1 7重 量 % f 和 丙 烯 均聚物 87 , 3重量％ ，所構成丙烯糸 1 - 63 - 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） «6501 A7 B7 五、發明説明（62 ) 組成物100重量份，添加三（2, 4-二特丁基笨基）磷酸酯 0,05重量份，四[亞甲（3 , 5-二特丁基-4-經ί氫化肉桂 酸酯）]甲烷0. U重量份，硬腊酸鈣〇· 1重量份所得聚合 物組成物。 ΕΡ-2:於100重量份的ΕΡ -1-,混配平均粒徑的 滑粉10重量份，所得屈曲彈性係數2,100HPa、MPR 0.72 g/l(T之聚合物組成物。 將聚丙烯糸組成物和聚合物組成物加以組合，列於表 1 3和表1 4中。 (3)中空成型品的評估 關於上逑調製的中空成型品，K下述特性和評估基準 評估。 U)成型性：在成型溫度200T：、螺桿徑50多、螺桿 轉數40rpm,將融態型坯壓出（模具徑21mm,芯徑19mia) ，測定型坯垂下至12c®和50cm為止的速度，从二者垂下 速度差（到50cni的速度一到12cm的速度）判定。 A:懸垂小，速度差在5!KM下 B:懸垂速度差5〜20Si C:懸垂速度差在20¾ K上 經濟部中央標準局員工消費合作社印裝 (請先閱讀背面之注意事項再填寫本頁) (b)柔軟性：在23 土 21室内，將中空成型品的一端 固定，Μ —邊加1公斤負荷時的變肜量角度加从判定。 Α:變形量30度Κ上 Β:變形量20度Κ上，30度Κ下 C :變形量10度以上，20度Κ下 -6 4 - 本紙浪尺度適用中固國家標準（CNS ) Α4規格（210Χ 297公釐） 486501 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（G ) D :變形量1 G度以下 (c )耐衝擊白化性：在2 0〜2 5 °C環境下，將中空成型 品放手，於成型品（聚丙烯条.組成物使用部位）前端，設 有半徑6 · 3 5 ni m的擊芯（1 9 G克），令5 0 0克的負荷從5 0 c m 高度；落到擊芯上，測定擊芯周圍發生的白化面。 A :擊芯部見損傷，惟未見白化 B :擊芯部白化在8 m m 0以下 C :擊芯部白化在8〜1 5 m m多中間 D :擊芯部白化在1 5 m ®於以上 (d)耐熱性·.成型品在150 °C烘箱中放置500小時 ，目視觀察變形和外觀。 A .·無變形和外觀異常 B :尺寸變化在2 以下，外觀幾無變化 C :尺寸變化在2 %以上，外觀有變化（劣化） (e)熔接強度··將成型品的熔接部壓縮（5Gflim)，目視 觀察型坯沿壓出方向的白化和龜裂。 A :不發生白化和龜裂 B :發生白化和龜裂 (f )結合強度，從筒狀成型品切出聚合物組成物及其 他組成物結合部試Η，測定抗拉強度，其值與下述標準 品值比較。 標準品：從中空成型品由聚丙烯条組成物構成部份切 出試Η。 一 65- (請先閱讀背面之注意事項再填寫本頁) 4 、1Τ #1 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） 486501 A7 B7 五、發明説明（64 ) 經濟部中央標準局員工消費合作社印製 A:強度超出標準品的85S： 、 B:強度為標準品的85-70¾ C:強度在標準品的70¾ K下 在表13和表14中列出各物性的評估結果。 發明效果 本發明丙烯系組成物適用聚丙烯糸組成物之基質樹脂 ,可製得成型性、成型收縮率、剛性、柔軟性、耐衝擊 性，尤指低溫附衝擊性、透明性、光澤、抗白化性均優 ，且其平衡性亦優的各種成型品。 使用Μ本發明丙烯系組成物為基質樹脂的聚丙烯糸組 成物所得射出成型品，如第1圖和第2圖所示，構成丙 烯糸組成物的丙烯-乙烯共聚物（RC )與丙烯均聚物（ΡΡ ) | 的極限黏土和重量比的乘積（[π ] Ra / [ η ]pp ) X (Wpp / Wkg ),在1.〇χ3.0範圍時，成型收縮率大約1 ，顯示高 度屈曲彈性係數（剛性），又如表3和表5所示，呈規優 良的低溫耐衝擊性、透明性、光澤和抗白化性。再者， 在混合α晶核劑的聚丙烯系組成物C i -7至1 2中，進一步 改善低溫耐衝擊性/又如表4和表6所示，混配自由基 發生劑和/或高結晶性丙烯均聚物之聚丙烯系組成物 Ci - 13至18中，進一步改善抗白化性。 另外，使用此等聚丙烯糸組成物，不但各種片狀成型 品，亦可射出成型製造複雜構造之成型品，例如容器及 其栓塞，以及具有鉸件構造的成型品等。 使用以本發明丙烯系組成物為基質樹脂的聚丙烯系組 一 66 一 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 486501 A7 B7 五、發明説明（65 ) 成物之片材，由於其成型方法的組合，如表7和表8所 示，可得打孔衝擊強度，折曲抗白化性和印细性均優， 且抗拉屈腋點強度和楊氐係數的平衡性均優的片材。 使用本發明K丙烯糸組成物為基質樹脂的聚丙烯系組 成物成型之單曆膜，如表9和表10所示，其透明性和耐 熱性均優，可提供撕裂強度、抗拉斷裂強度、斷裂伸長 率和低溫耐衝擊性等機械特性平衡優異的無延伸、雙軸 延伸和單軸延伸膜。另外，此聚丙烯系組成物和聚烯烴 系組成物之積層膜，如表11和表12所示，除維持上逑單 層薄特性外，具有優良熱封性。 此等膜適用做食品包裝用為有的各種包裝用膜。 使用本發明丙烯系組成物為基質樹脂的聚丙烯系組成 物成型之中空成型品，尤指具有蛇腹構造的中空成型品 ，如表13和表14所示，成型性、柔軟性、衝擊抗白化性 、耐熱性、熔接特性均優，尤指在添加可塑化成份的聚 丙烯糸組成物Cb_2、3 、5和7中，可進一步改善柔軟 性。另外，與其他聚合物組成物结合的複合品中，具有 高度結合強度。 經濟、那中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 具有此等蛇腹構造的中空成型品及其複合品，適合做 風管等。 本發明提供丙烯系組成物，適於做為各種成型品成型 所用聚丙烯糸組成物及其基質樹脂，在此範圍極具意義。 鼦忒簡a說明 第1圔為相對於丙烯-乙烯共聚物（RC)和丙烯均聚物 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X 297公釐） 486501 A7 B7 五、發明説明（66 ) (PP)的極限黏度和重量比乘積（[η ]Ra/ [ η bp ) X (vpp / WR(3 )之成型收縮率曲線； 第2圖為栢對於丙烯-乙烯共聚物（RC)和丙烯均聚物 (PP)的極限黏度和重量比乘積（[r? ] / [ ^ ]pj&gt; ) X ( Wpp / WRG )之屈曲彈性係數曲線； 第3圖為實施例所用丙烯系組成物連續聚合裝置之流 程圔。 符猇說明 1、10:聚合器，2:氫管路，3:原料丙烯管路，4、8: 未反應氣體管路，5、9:聚合物排出管路，6:原料混合 氣體管路。 ----------樣II (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印製 一 6 8 _ 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X 297公釐）Table 14 Comparative composition for hollow molded product molding and hollow molded product Hollow molded product Example No. 1 2 · 3 4 5 6 7 Polypropylene-based composition (Cf) No. cCb-l cCb-2 Cb-3 Cb- 1 cCb-1 cCb-2 cCb-4 Acrylic composition (A) Number cA-3 cA-3 A-1 cA-3 cA-3 cA-3 cA-3 Weight 100 100 100 100 100 100 100 Plastic Chemical Composition Types-LDPE EVAC-LDPF F.VAC Weight 10 10 10 10 Antioxidant: Ph-2 Weight 0.15 0.15 0.15 0.15 0.15 0.15 0.15 Antioxidant: p-2 mmm 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Agent calcium stearate 0.1 parts by weight 0.1 0.1 0.1 0.1. 0.1 0.1 0.1 Bonding resin composition 1 EP -1 EP-2 EP-1 EP-2 Hollow molded product Physical properties Moldability AAAAAAA Softness BAABBAA Impact whitening CCCCCCC Heat resistance AAA Λ BAA Welding characteristics CCCCCCC Joining strength — CCCC (Please read the notes on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 4§6501 A7 B7 Central Bureau of Standards, Ministry of Economic Affairs Printed by Employee Consumer Cooperative V. Description of the invention (61) 1 I (2) Molding of hollow molded product 1 1 (a) Hollow molded product (single product)-'· 1 I The granular polypropylene composition Cb -1 to 6 adjusted as described above And cCb-1 Please 1 First Γ to 3 $ For the extrusion of the hollow forming machine (SN-50 Brau company) 1 Read out the parison at 2 0 0 υ, this parison is being adjusted to 3 0 υ metal model back I i 1 I Inner blow 9 Molded into a cylindrical hollow with a bellows structure on the side. Note I bellows structure 7 screw joints L-shaped product (60 沴> c 300 X 1. 6 ffl Bl t / in the central part, 10 mmf between the I t links, groove depth 10 m ffl, mean thickness of snake belly 0.9fli®t). Fill in this book again and cut the top and bottom sides 9 to obtain a hollow molded product. Page 1 I (b) Hollow molded product (composite product) I 1 The granular polypropylene Ά composition Cb-1, 2 and 7 or the comparative composition I 1 product cCb-1 Λ 2 and 4 9 The hollow molding machine 1 of the second part of the machine is ordered to extrude 4m, and the extruder provides one of the following polymer compositions. 1 $ Before use—extruder K2001C extrudes the parison, and then extrudes it. The 1 I machine extrudes the parison at 2000 t, and the two components are connected to form a parison. This parison 1 | is blown in a metal model adjusted to 30, and is shaped into a side with a bellows 1 I structure Cylindrical hollow molded products (60 沴 X 300 X / 在 中 # 部 部 9 Corrugated belly structure 7 pitch, pitch 10 to 10 m, groove depth 10mi, corrugated belly 1 1 1 part average thickness 0, 9 1 [1 t) &lt; &gt; At this time, the parison 1 1 $ extruded by the aforementioned extruder was adjusted to the snake belly. Cut the top and bottom surfaces to obtain a hollow molded 1 I product (composite product) 〇1 1 EP -1 Crystal melting point 1651, buckling modulus 1,100MPa, MFR 1 1 0.6 ig / 1 〇, 9 ethylene content 59 weight Si ethylene-propylene copolymer 1 I 12.1 7% by weight f and propylene homopolymer 87, 3% by weight, which constitutes propylene 1-63-1 1 1 This paper size applies to China National Standard (CNS) A4 specifications (210X 297 mm) «6501 A7 B7 V. Description of the invention (62) 100 parts by weight of the composition, adding 0,05 parts by weight of tris (2,4-di-tert-butylbenzyl) phosphate, and four [methylene ( 3, 5-Di-tert-butyl-4-hydrogenated cinnamate)] methane 0.5 U parts by weight, calcium stearate 0.1 parts by weight of the polymer composition obtained. EP-2: 100 parts by weight of EP -1-, compounded with 10 parts by weight of a powder having an average particle diameter, and obtained a polymer composition having a flexural modulus of 2,100 HPa and MPR of 0.72 g / l (T. Polypropylene The composition and the polymer composition are combined and listed in Tables 13 and 14. (3) Evaluation of the hollow molded product For the hollow molded product prepared by the above process, the following characteristics and evaluation criteria are evaluated. U) Molding Properties: At a molding temperature of 200T :, a screw diameter of more than 50 and a screw revolution of 40 rpm, the molten parison is extruded (mold diameter 21mm, core diameter 19mia), and the speed at which the parison hangs down to 12c® and 50cm is measured. The difference between the drooping speed (a speed of 50cni and a speed of 12cm). A: The droop is small, the speed difference is below 5! KM B: The droop speed is 5 ~ 20Si C: The drap speed is 20¾ K printed on the staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling in this Page) (b) Softness: In the 23 soil 21 room, one end of the hollow molded product is fixed, and the angle of the variable amount when a load of 1 kg is applied to the side is determined. Α: Deformation at 30 ° K Β: Deformation at 20 ° K, at 30 ° K C: Deformation at 10 ° or more, at 20 ° K-6-4-This paper applies the China National Standard (CNS) Α4 specification (210 × 297 mm) 486501 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (G) D: Deformation less than 1 G degree (c) Impact whitening resistance: at 20 ~ 2 5 ° C In the environment, let go of the hollow molded product. At the front end of the molded product (polypropylene strip. Composition using part), a core with a radius of 6.35 nim (19 G grams) is set to make a load of 500 grams. From a height of 50 cm; drop onto the core and measure the whitening surface that occurs around the core. A: Damage to the core part, but no whitening B: Whitening of the core part is below 8 mm 0 C: Whitening of the core part is more than 8 to 15 mm in the middle D: Whitening of the core part is above 15 m ® (d) Heat resistance .. The molded article was left in a 150 ° C oven for 500 hours, and the deformation and appearance were visually observed. A. No deformation and abnormal appearance B: The dimensional change is less than 2 and there is almost no change in the appearance C: The dimensional change is 2% or more, the appearance is changed (deteriorated) (e) Welding strength ·· The welded part of the molded product is compressed ( 5Gflim), visually observe the whitening and cracking of the parison along the extrusion direction. A: No whitening and cracking occurred. B: Whitening and cracking occurred. (F) Bonding strength. Cut out the polymer composition and other components from the cylindrical molded product and test the tensile strength. The tensile strength was measured. The comparison of standard values. Standard product: A test piece was cut out of a hollow molded product composed of a polypropylene strip composition. 65- (Please read the notes on the back before filling in this page) 4 、 1Τ # 1 This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 486501 A7 B7 V. Description of invention (64) Ministry of Economy Printed by the Consumer Standards Cooperative of the Central Bureau of Standards A: 85S exceeding the standard:, B: 85-70 ¾ of the standard, C: The strength is 70 ¾ of the standard, and the physical properties are listed in Tables 13 and 14 evaluation result. Effects of the Invention The propylene-based composition of the present invention is suitable for a matrix resin of a polypropylene resin composition, and can obtain moldability, mold shrinkage, rigidity, flexibility, and impact resistance, especially low-temperature impact resistance, transparency, gloss, and Various molded products with excellent whitening properties and excellent balance. As shown in FIG. 1 and FIG. 2, an injection molded product obtained by using a polypropylene resin composition in which the propylene-based composition of the present invention is a matrix resin is a propylene-ethylene copolymer (RC) and a propylene resin which constitute a polypropylene resin composition. Polymer (PP) | The product of the ultimate clay and weight ratio ([π] Ra / [η] pp) X (Wpp / Wkg), in the range of 1.0 × 3.0, the molding shrinkage is about 1 and the height is displayed The coefficient of flexural elasticity (rigidity), as shown in Tables 3 and 5, is excellent in low-temperature impact resistance, transparency, gloss, and whitening resistance. Furthermore, in the polypropylene-based compositions C i -7 to 12 in which the α crystal nucleating agent is mixed, the low-temperature impact resistance is further improved / as shown in Tables 4 and 6, a radical generator and / or The polypropylene composition Ci-13 to 18 of the highly crystalline propylene homopolymer further improves the whitening resistance. In addition, by using these polypropylene concrete compositions, not only various sheet-shaped molded products, but also molded products with complicated structures such as containers and plugs thereof, and molded products with hinge structures can be produced by injection molding. A polypropylene series using the propylene-based composition of the present invention as a matrix resin 66. A paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) 486501 A7 B7 V. Description of the invention (65) Due to the combination of the forming methods, as shown in Tables 7 and 8, the punching impact strength, bending resistance, whitening resistance and printability are excellent. A sheet with excellent balance between tensile flexion axillary point strength and poplar coefficient. As shown in Tables 9 and 10, a single calendar film formed of a polypropylene-based composition using the K acrylic resin composition of the present invention as a matrix resin has excellent transparency and heat resistance, and can provide tear strength and tensile fracture. Non-stretched, biaxially stretched, and uniaxially stretched films with excellent balance of mechanical properties such as strength, elongation at break, and low temperature impact resistance. In addition, as shown in Tables 11 and 12, the laminated film of the polypropylene-based composition and the polyolefin-based composition has excellent heat-sealability in addition to maintaining the thinness of the upper single layer. These films are suitable for various packaging films for food packaging. Hollow molded articles molded from polypropylene-based compositions using the propylene-based composition of the present invention as a matrix resin, especially hollow molded products having a bellows structure, as shown in Tables 13 and 14, moldability, softness, and impact resistance to whitening It is excellent in heat resistance, heat resistance, and welding properties, especially in the polypropylene resin compositions Cb_2, 3, 5, and 7 with plasticizable components, which can further improve the flexibility. In addition, composites bonded to other polymer compositions have high bonding strength. Economy, printed by the Consumer Standards Cooperative of the Central Bureau of Standards (please read the precautions on the back before filling out this page) Hollow molded products and composite products with these bellows structures, suitable for air ducts, etc. The present invention provides a propylene-based composition, which is suitable as a polypropylene resin composition for molding various molded articles and a matrix resin thereof, and has a significant meaning in this range.鼦 忒 简 aExplanation No. 1 is relative to propylene-ethylene copolymer (RC) and propylene homopolymer. This paper applies Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 486501 A7 B7 V. Description of the invention ( 66) (PP) limiting viscosity and weight ratio product ([η] Ra / [η bp) X (vpp / WR (3) molding shrinkage curve; Figure 2 shows the cypress for propylene-ethylene copolymer (RC) Curve of the product of the limiting viscosity and the weight ratio of propylene homopolymer (PP) ([r?] / [^] Pj &gt;) X (Wpp / WRG); Figure 3 shows the propylene-based composition used in the examples. The flow of continuous polymerization device: 猇 Description: 1, 10: polymerizer, 2: hydrogen pipeline, 3: raw material propylene pipeline, 4, 8: unreacted gas pipeline, 5, 9: polymer discharge pipeline, 6: Raw material mixed gas pipeline. ---------- Sample II (please read the precautions on the back before filling this page) Order the printed copy of the Central Consumers Bureau of the Ministry of Economic Affairs's Consumer Cooperatives 6 8 _ This paper Standards are applicable to China National Standard (CNS) A4 specifications (21〇X 297 mm)

Claims (1)

486501 丨公告本六、申請專利範圍 第85 1 14348號「丙烯系組成物、其製法、聚丙烯系組成物及 成型品」專利案 ，一一-----------__ ；· 彳 A. :r | f91啤υίτ丨曰修正：》 六、申請專利範圍： 1 · 一種丙烯系組成物，其特徵爲係由丙烯均聚物和丙 烯-乙烯共聚物所構成，丙烯-乙烯共聚物的極限 黏度（U ]RC)在1.7〜2.8dl/g範圍，丙烯-乙烯共聚 物與丙烯均聚物的極限黏度（[;? ]Rc/U ]PP)在0.7〜 1.2範圍；而丙烯-乙烯共聚物含乙烯聚合單元之含 量範圍爲丙烯-乙烯共聚物重量之25〜55重量％，且 丙烯均聚物與丙烯-乙烯共聚物重量比（WPP/WRC：)及其 極限黏度比（[7? ]RC/[7? ]pp)之乘積（WPP/WRC)X ([7? ]RC/[々 ]pp)在 1·0 〜3.0 範圍者。 2 .如申請專利範圍第1項之丙烯系組成物，其中丙烯 均聚物具有等規五價物分率（Ρ)在0.95以上者。 3 .如申請專利範圍第1項之丙烯系組成物，其中丙烯 -乙烯共聚物含20°C二甲苯可溶成份，其含量爲丙烯 -乙嫌共聚物重量之80重量％以上者。 4 .如申請專利範圍第1項之丙烯系組成物，其中丙烯 -乙烯共聚物含量爲丙烯系組成物重量之22〜40® 量％者。 5 .如申請專利範圍第1項之丙烯系組成物，其中丙燒 系組成物具有Q値（Mw/Mn)在5以下者。 486501 六、申請專利範圍 6 . —種如申請專利範圍第1項之丙烯系組成物之製法， 包括第一聚合步驟，係在由平均粒徑25〜300 // m 的含鈦固體觸媒成份（a ); 通式AlR\X3_m(式中R1爲CV20烴基，X爲鹵素原 子，m爲3 g m - 1 · 5之整數）所示有機鋁化合物（b ); 和 通式R2xR3YSi(OR4)z (式中R2和R4爲烴基，R3爲烴 基或含雜原子的烴基，X，Y和Z爲0SXS2，1SY S3，1SZS3，且具有X + Y + Z = 4之關係）所示有機矽 化合物（c ); 所構成立體規則性烯烴聚合觸媒存在下，於氣相 中，將丙烯單獨聚合，生成佔總重量之78〜60重量 %的丙烯均聚物； 其次爲第二聚合步驟，將乙烯和丙烯共聚合，生 成乙烯單元含量25〜55重量％之丙烯-乙烯共聚物 者。 7 ·如申請專利範圍第6項之丙烯系組成物之製法，其 中在第一聚合步驟之前，另包含立體規則性烯烴聚 合觸媒之預活化處理步驟者。 8 .如申請專利範圍第6項之丙烯系組成物之製法，其 中含鈦固體觸媒成份U)粒子的均勻度在2.0以下 者。 9 ·如申請專利範圍第6項之丙烯系組成物之製法，其486501 丨 Announcement VI. Patent Application No. 85 1 14348 "Patents of propylene-based composition, its manufacturing method, polypropylene-based composition and molded products", one by one -----------__; · 彳 A.: r | f91 beer υίτ 丨 said: "6. Application for patent scope: 1 · A propylene-based composition characterized by a propylene homopolymer and a propylene-ethylene copolymer, propylene-ethylene The limiting viscosity (U) RC of the copolymer ranges from 1.7 to 2.8 dl / g, and the limiting viscosity ([;?] Rc / U] PP) of the propylene-ethylene copolymer and propylene homopolymer ranges from 0.7 to 1.2; and The content of propylene-ethylene copolymer containing ethylene polymerization units ranges from 25 to 55% by weight based on the weight of the propylene-ethylene copolymer, and the weight ratio of propylene homopolymer to propylene-ethylene copolymer (WPP / WRC :) and its limiting viscosity ratio The product of ([7?] RC / [7?] Pp) (WPP / WRC) X ([7?] RC / [々] pp) is in the range of 1 · 0 to 3.0. 2. The propylene-based composition according to item 1 of the scope of patent application, wherein the propylene homopolymer has an isotactic pentad fraction (P) of 0.95 or more. 3. The propylene-based composition according to item 1 of the scope of the patent application, wherein the propylene-ethylene copolymer contains 20 ° C xylene solubles, and the content is 80% by weight or more of the weight of the propylene-ethylene copolymer. 4. The propylene-based composition according to item 1 of the scope of patent application, wherein the content of the propylene-ethylene copolymer is 22 to 40% by weight of the propylene-based composition. 5. The propylene-based composition according to item 1 of the patent application scope, wherein the propylene-based composition has a Q 値 (Mw / Mn) of 5 or less. 486501 VI. Application for Patent Scope 6. — A method for preparing a propylene-based composition such as the one in the scope of patent application, including the first polymerization step, based on a titanium-containing solid catalyst component with an average particle diameter of 25 ~ 300 // m (A); an organoaluminum compound (b) represented by the general formula AlR \ X3_m (where R1 is a CV20 hydrocarbon group, X is a halogen atom, and m is an integer of 3 gm-1 · 5); and general formula R2xR3YSi (OR4) z (Where R2 and R4 are hydrocarbon groups, R3 is a hydrocarbon group or a heteroatom-containing hydrocarbon group, X, Y, and Z are OSXS2, 1SY S3, 1SZS3, and have a relationship of X + Y + Z = 4) as shown in the organosilicon compound ( c); in the presence of the stereoregular olefin polymerization catalyst, propylene is separately polymerized in the gas phase to produce 78 to 60% by weight of the propylene homopolymer; the second step is to polymerize ethylene Copolymerized with propylene to produce a propylene-ethylene copolymer with an ethylene unit content of 25 to 55% by weight. 7 · The method for preparing a propylene-based composition according to item 6 of the patent application, which includes a pre-activation treatment step of a stereoregular olefin polymerization catalyst before the first polymerization step. 8. The method for preparing a propylene-based composition according to item 6 of the scope of patent application, wherein the titanium-containing solid catalyst component U) has a uniformity of less than 2.0. 9 · If the propylene-based composition of the patent application No. 6 method, 六、申請專利範圍 中有機矽化合物（C )與有機鋁化合物（b )之莫耳比 (b/c) 在1〜1〇範圍者。 1 〇 · —種聚丙烯系組成物，內含申請專利範圍第1項 之丙烯系組成物爲基質樹脂者。 1 1 ·如申請專利範圍第丨〇項之聚丙烯系組成物，其中 聚丙烯系組成物含有抗氧化劑和中和劑者。 1 2 .如申請專利範圍第丨丨項之聚丙烯系組成物，其中 ί几氧化劑爲酣系熱安定劑和/或鱗系熱安定劑，而 中和劑爲硬脂酸鈣者。 1 3 .如申請專利範圍第10至1 2項中任一項之聚两燒系 組成物，其中又含有α晶核劑0.0 〇 〇 1〜1重量％者。 1 4 ·如申請專利範圍第1 3項之聚丙烯系組成物，其中 α晶核劑有滑粉、芳香族羧酸金屬鹽、二；叉山梨 糖醇系化合物、芳香族磷酸金屬鹽、聚3 -甲基了 烯、聚乙烯基環己烷、聚烯丙基三甲基矽院，及其 混合物者。 1 5 ·如申請專利範圍第1 0項之聚丙烯系組成物，其中 又含有自由基發生劑者。 1 6 ·如申請專利範圍第1 5項之聚丙烯系組成物，其中 自由基發生劑爲有機過氧化物者。 1 7 ·如申請專利範圍第1 0項之聚丙烯系組成物，其中 又含有密度0 · 9 1〜0 · 89g/ cm3，且與丙烯系組成物的 熔體流量比在0 · 5〜2範圍之丙烯均聚物，含量爲樹 486501 六、申請專利範圍 脂基準之10〜95重量％者。 1 8 ·如申請專利範圍第1 〇項之聚丙烯系組成物，其中 相對於申請專利範圍第1項聚丙烯系組成物1 〇〇重 量份，又含有可塑化成份5〜20重量份者。 1 9 .如申請專利範圍第1 8項之聚丙烯系組成物，其中 可塑化成份係密度〇 · 910〜〇 · 930g/ cm3，結晶融點 (Tm)100〜115°C之乙烯均聚物或乙烯-α -烯烴共聚 物，和/或密度0 . 92〜0 · 93 5g / cm3，結晶融點 (Tm)90〜l〇8°C，乙酸乙烯酯單元含量1〜10重量％ 之乙烯-乙酸乙烯酯共聚物者。 20 . —種成型品，係由申請專利範圍第1 0至1 9項中任 一項之聚丙烯系組成物製成者。 2 1 · —種如申請專利範圍第20項之成型品之製法，係 由申請專利範圍第1 〇至1 9項中任一項之聚丙烯系 組成物構成的顆粒，加以射出成型者。 22 . —種片材，係由申請專利範圍第1 〇至1 9項中任一 項之聚丙烯系組成物製成者。 23 . —種如申請專利範圍第22項之片材之製法，係將 申請專利範圍第1 〇至1 9項中任一項之聚丙烯系組 成物構成的顆粒，在樹脂溫度180〜300°C，冷卻輥 溫度5〜8(TC，且樹脂溫度-冷卻輥溫度-120°C， 以及成型速度0.1〜l〇〇m/mi η條件下，利用T模 具法壓出成型者。 -4- 486501 六、申請專利範圍 24 . —種膜，係由申請專利範圍第1〇項之聚西儲系組 成物製成者。 25 . —種多層膜，係在申請專利範圍第24項之膜而成 之膜層中，層合功能性聚合物層而成者’其中功能 性聚合物層爲密度0.89〜〇·91 g/cm3，結晶融點 (Tm) 165〜160 °C的丙烯均聚物和所需添加劑所構成 之層，和/或密度0.89〜〇 . 9 1 g/ cm3，結晶融點 (Tm ) 1 5 9〜1 1 0 °C的丙烯-α -烯烴共聚物和所需添加 劑構成之熱封層者。 26 . —種中空成型品，係由申請專利範圍第1 〇項之聚 丙烯系組成物製成者。 27. 如申請專利範圍第26項之中空成型品，具有伸縮 囊構造者。 28. —種中空成型品，係由具有伸縮囊構造的申請專利 範圍第27項之中空成型品所構成之部位；與 含乙烯單元25〜55重量％的乙烯-丙烯共聚物之 1〜20重量％、丙烯均聚物99〜80重量％，及另含視 所需之添加劑的聚烯烴系組成物之中空成型品所構 成的其他部位； 兩部位結合而成者。6. Scope of patent application The molar ratio (b / c) of organosilicon compound (C) and organoaluminum compound (b) is in the range of 1 ~ 10. 〇 · —A polypropylene-based composition containing a propylene-based composition as the matrix resin in the first patent application. 1 1 · The polypropylene-based composition according to the scope of the patent application, wherein the polypropylene-based composition contains an antioxidant and a neutralizer. 1 2. The polypropylene-based composition according to the scope of the application for patent, wherein the oxidizing agent is a fluorene-based thermal stabilizer and / or a scale-based thermal stabilizer, and the neutralizing agent is calcium stearate. 1 3. The polymerized two-burner composition according to any one of claims 10 to 12 in the scope of the patent application, which further comprises an alpha crystal nucleating agent of 0.0 to 1 to 1% by weight. 1 4 · The polypropylene-based composition according to item 13 of the scope of the patent application, wherein the α-nucleating agent includes slip powder, aromatic carboxylic acid metal salt, di; sorbitan-based compound, aromatic metal phosphate salt, poly 3-methylene, polyvinylcyclohexane, polyallyltrimethylsilicon, and mixtures thereof. 15 · A polypropylene-based composition such as the one in the scope of patent application No. 10, which contains a radical generator. 16 · The polypropylene composition according to item 15 of the patent application scope, wherein the radical generator is an organic peroxide. 1 7 · The polypropylene-based composition according to item 10 of the scope of patent application, which also contains a density of 0. 9 1 to 0. 89 g / cm3, and the melt flow ratio to the propylene-based composition is 0. 5 to 2 The content of propylene homopolymer is within the range of 486501. 6 、 Applicable for the patent range of 10 to 95% by weight. 18 · If the polypropylene-based composition of the scope of patent application No. 10 is 1,000 parts by weight relative to the polypropylene-based composition of scope of the patent application No. 1 and contains 5 to 20 parts by weight of a plasticizable component. 19. Polypropylene-based composition according to item 18 of the scope of patent application, wherein the plasticizable component is an ethylene homopolymer having a density of 0.910 to 930 g / cm3 and a crystalline melting point (Tm) of 100 to 115 ° C. Or ethylene-α-olefin copolymer, and / or a density of 0.92 to 0.95 g / cm3, a crystalline melting point (Tm) of 90 to 108 ° C, and a vinyl acetate unit content of 1 to 10% by weight of ethylene -Vinyl acetate copolymer. 20. A molded product made of a polypropylene-based composition according to any one of claims 10 to 19 in the scope of patent application. 2 1-A method for manufacturing a molded article such as the scope of patent application No. 20, which is a pellet composed of a polypropylene-based composition according to any one of the scope of patent applications No. 10 to 19, and is injected into a mold. 22. A kind of sheet material, which is made of a polypropylene-based composition according to any one of claims 10 to 19. 23. — A method for manufacturing a sheet such as the scope of patent application No. 22, which is a particle composed of a polypropylene-based composition according to any of the scope of patent applications No. 10 to 19, at a resin temperature of 180 to 300 ° C, the temperature of the cooling roller is 5 ~ 8 (TC, and the resin temperature-the temperature of the cooling roller-120 ° C, and the molding speed is 0.1 ~ 100 m / mi η, using the T die method to extrude the molding. -4- 486501 VI. Application scope of patent 24.-Seed film, which is made of Juxi storage system composition with the scope of patent application No. 10 25.-Multi-layer film, which is the membrane with scope of patent application No. 24 In the formed film layer, a functional polymer layer is laminated, wherein the functional polymer layer is a propylene homopolymer having a density of 0.89 to 0.91 g / cm3 and a crystalline melting point (Tm) of 165 to 160 ° C. And the layer formed by the desired additive, and / or a density of 0.89 to 0.91 g / cm3, a crystalline melting point (Tm) of propylene-α-olefin copolymer of 5 9 to 1 10 ° C and the required additive Those who constitute the heat-seal layer. 26. — A hollow molded product made of a polypropylene-based composition in the scope of patent application No. 10. 27. Rushen The hollow molded product with the scope of the patent No. 26, which has a bellows structure. 28.-a hollow molded product, which is composed of the hollow molded article with the scope of the patented scope of the patent application No. 27; and an ethylene-containing unit 25 to 55% by weight of 1 to 20% by weight of an ethylene-propylene copolymer, 99 to 80% by weight of a propylene homopolymer, and a hollow molded product of a polyolefin-based composition containing optional additives as required A combination of two parts.
TW85114348A 1996-04-02 1996-11-21 Propylenic composition, preparation thereof, polypropylenic composition and molded article TW486501B (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP10636596 1996-04-02
JP17417896 1996-06-13
JP18114196 1996-06-21
JP20903096 1996-07-18
JP20903196 1996-07-18

Publications (1)

Publication Number Publication Date
TW486501B true TW486501B (en) 2002-05-11

Family

ID=27526275

Family Applications (1)

Application Number Title Priority Date Filing Date
TW85114348A TW486501B (en) 1996-04-02 1996-11-21 Propylenic composition, preparation thereof, polypropylenic composition and molded article

Country Status (1)

Country Link
TW (1) TW486501B (en)

Similar Documents

Publication Publication Date Title
JP3470337B2 (en) Propylene composition, method for producing the same, polypropylene composition and molded article
JP3270056B2 (en) Resin molding
CN107840980B (en) Articles containing polypropylene resin with broad molecular weight distribution
JPWO1997019135A1 (en) Propylene-based composition, its manufacturing method, polypropylene-based composition, and molded article
CN1863830B (en) Polypropylene composition for air quenched blown films
TW564254B (en) Polypropylene film, multilayered polypropylene film and application thereof
EP3160713B1 (en) High melt strength polypropylene and extrusion process for preserving melt strength
CN104136525B (en) Propylene-ethylene copolymers resin combination with and formed body, film and sheet material
CN108219295A (en) Polypropene composition, polypropylene film-making material and its manufacturing method and secondary forming body
JP3852326B2 (en) PROPYLENE COMPOSITION AND PROCESS FOR PRODUCING THE SAME, POLYPROPYLENE COMPOSITION AND MOLDED ARTICLE
WO2014054673A1 (en) Propylene resin composition for retort pouch-packaging film
JP6144045B2 (en) Polypropylene resin composition and method for producing the same, polypropylene sheet and biaxially oriented polypropylene film
TW201831578A (en) Polypropylene composition
JP7014819B2 (en) Propylene resin compositions, moldings and containers
JP2018095699A (en) Polypropylene composition, method for producing the same and polypropylene sheet
CN105408112B (en) Heat-sealable polyolefins film and sheet material
JP2020158652A (en) Propylene-based polymer composition and its molded product
JP2015000960A (en) Polypropylene resin composition for sheet molding
JP3800181B2 (en) PROPYLENE COMPOSITION AND PROCESS FOR PRODUCING THE SAME, POLYPROPYLENE COMPOSITION AND MOLDED ARTICLE
TW486501B (en) Propylenic composition, preparation thereof, polypropylenic composition and molded article
CN103665727B (en) Polypropylene-based resin composition and the mechanograph being made from it
JP4759235B2 (en) Polypropylene-based laminated film
CN107428872A (en) Propylene-based terpolymers
JP6235805B2 (en) Polypropylene resin composition for biaxially stretched film
JP5252478B2 (en) Foamed resin composition for air-cooled inflation and air-cooled inflation foam film using the same

Legal Events

Date Code Title Description
GD4A Issue of patent certificate for granted invention patent
MK4A Expiration of patent term of an invention patent