TW497140B - Process system for plasma etching and chemical vapor deposition - Google Patents
Process system for plasma etching and chemical vapor deposition Download PDFInfo
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- TW497140B TW497140B TW90124915A TW90124915A TW497140B TW 497140 B TW497140 B TW 497140B TW 90124915 A TW90124915 A TW 90124915A TW 90124915 A TW90124915 A TW 90124915A TW 497140 B TW497140 B TW 497140B
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- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000005229 chemical vapour deposition Methods 0.000 title claims abstract description 20
- 238000001020 plasma etching Methods 0.000 title claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 claims abstract description 25
- 239000007789 gas Substances 0.000 claims description 105
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 235000012431 wafers Nutrition 0.000 description 13
- 238000010586 diagram Methods 0.000 description 7
- 238000005530 etching Methods 0.000 description 5
- 238000005086 pumping Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000000427 thin-film deposition Methods 0.000 description 1
- 210000003437 trachea Anatomy 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
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Abstract
Description
497140 五、發明說明(l) ---——' 本發明關於一種適用於積體電路(IC)生產製程中電漿 蝕刻及化學氣相沉積(CVD)之電漿製程系統。本發明更關水 於可補償中央/邊緣(Center —τ〇一Edge)及邊/邊^仏卜。 -Edge)不對稱之沉積或蝕刻之電漿製程系統。 習知電漿蝕刻或CVD大多使用單一之氣體供應裝置為 標準設計’將氣體均勻的灑於平台表面。然而在~關鍵尺…寸 (Critical Dimension)及整體一致之結果控制上,卻有一 些未能解決之問題。以下將對這些問題’概略敘述。 第1圖為習知餘刻或CVD反應室概略結構圖。習知之鍅 刻及CVD製程利用喷頭(Sh〇wer Head)或喷氣器( 灑下均勻的氣體以進行晶圓之蝕刻或膜薄沉積,如第i圖 上方所示。然而,反應室中有多項不對稱的環境存在,例 如:晶圓進出需要有抓晶圓的通道(Wafer Passage),如第 1圖右側編號4所示;另外,也需要一側邊抽氣裝置 (Side Pumping )將廢氣經通道排出,如第1圖左側編號 2所示即使氣體之供給為完全均勻的,但是遇到這種不 均句的條件’就會造成不良的結果。在尺寸小的晶圓中, 對稱的要求不需要太精確。但現在晶圓尺寸的增加,伴隨 的是須要更精確的控制。因此,上述之反應室抽氣或晶圓 進出的結構,造成的不均勻的邊/邊差異效果(Side — T〇 -Side Effect)可能造成低良率(L〇w Yield)或根本不能量 產。此外,由於上述抽氣及抓晶圓進出之該等工具,造成 反應室為不對稱之環境。 另外’即使將钱刻及CVD工具均勻化,尚有前製程的497140 V. Description of the invention (l) ------- 'The present invention relates to a plasma process system suitable for plasma etching and chemical vapor deposition (CVD) in integrated circuit (IC) production processes. The present invention is more relevant for compensating for the center / edge (Center-τ〇-Edge) and the edge / edge. -Edge) asymmetric plasma processing system for deposition or etching. Conventional plasma etching or CVD mostly uses a single gas supply device as a standard design. The gas is evenly sprayed on the surface of the platform. However, there are still some unresolved issues in the critical dimensional dimension and overall consistent results control. These problems' will be briefly described below. Fig. 1 is a schematic diagram of a conventional or CVD reaction chamber. The conventional engraving and CVD processes use a shower head or a jet (spray uniform gas to etch wafers or thin film deposition, as shown in the upper part of Figure i. However, there are A number of asymmetrical environments exist, for example: a wafer pass-through needs a wafer passage (Wafer Passage), as shown in Figure 4 on the right side of Figure 1; in addition, a side pumping device (Side Pumping) to exhaust gas It is discharged through the channel, as shown in No. 2 on the left side of Figure 1. Even if the gas supply is completely uniform, it will cause bad results when it encounters the condition of this uneven sentence. In the small-size wafer, symmetrical The requirement does not need to be too precise. But the increase in wafer size is accompanied by the need for more precise control. Therefore, the structure of the above-mentioned reaction chamber extraction or wafer in and out causes uneven side / edge difference effects (Side — T〇-Side Effect) may cause a low yield (L0w Yield) or no energy production at all. In addition, the above-mentioned pumping and grasping of wafers in and out of these tools may cause the reaction chamber to be asymmetrical. In addition, 'Even with money CVD tool and homogenized, before the manufacturing process there
0503 - 6498TW; TSMC200l-0198;Hui.ptd 497140 五、發明說明(2) -----— =。例如:微影製作肖’中央及邊緣因水平的問題產生 差異。晶片曝光後,於烘烤(Baking)的程序中置於 及邊/邊刀佈差異疋無法避免的’也是現時欲解決的問題 總括上述,習知電漿製程系統包含兩項問題: (1) 由前製程及機台本身差異所造成之中央/邊緣之 一致性。 + (2) 晶圓本身之邊/邊不對稱之蝕刻及沉積率。 有鑑於此,本發明的主要目的,在於提供一種可 CVD及蝕刻製程中,中央/邊緣及邊/邊/邊不對稱之氣體= 應系統。 、 為獲致上述之目的,本發明提出一適用於積體電路 (1C)生產製程之電漿蝕刻及化學氣相沉積(Chemi Vapor Deposition)處理程序之電漿製程系統,包含:一亨 體供應裝置,用以供應複數之氣體支流,並對於該等氣^ 支流之輸出分別獨立控制;及一反應室,具有複數之區 以供該等氣體支流輸出。 °°㉟ 該氣體供應裝置包含一控制閥或複數氣體供應單位, 用以根據一輸入配方(K e y - I n R e c i p e )之氣體支流量比例 ’對於反應室中央/邊緣或邊/邊不均勻對稱之條件,以頂 端供應氣體(Top Gas Feed)或頂端及底部供應氣體 (Bottom Gas Feed)之方式進行補償。 圖式之簡單說明:0503-6498TW; TSMC200l-0198; Hui.ptd 497140 V. Description of the invention (2) ------ =. For example: the difference between the center and the edge of the lithography production xiao due to the level problem. After the wafer is exposed, the difference between the edge / edge knife cloth in the baking process and the unavoidable 'is also the current problem to be summarized. The conventional plasma process system includes two problems: (1) Central / peripheral consistency caused by pre-process and machine differences. + (2) Asymmetric etching / deposition rate of the wafer itself. In view of this, the main object of the present invention is to provide a gas / response system with asymmetric center / edge and edge / edge / edge in CVD and etching processes. In order to achieve the above-mentioned object, the present invention proposes a plasma process system suitable for plasma etching and chemical vapor deposition (Chemi Vapor Deposition) processing procedures of the integrated circuit (1C) production process, including: a body supply device To supply a plurality of gas tributaries, and to independently control the output of these gas tributaries; and a reaction chamber having a plurality of zones for the output of these gas tributaries. °° ㉟ The gas supply device includes a control valve or a plurality of gas supply units, which are used for the proportion of the gas tributary flow of an input recipe (K ey-I n R ecipe) to the center / edge or edge / edge of the reaction chamber. Symmetrical conditions are compensated by means of a Top Gas Feed or a Bottom Gas Feed. Brief description of the schema:
497140 五、發明說明(3) ----- 為使本發明之上述目的、特徵和優點能更明顯易懂, 下文特舉一較佳實施例,並配合所附圖式,作詳細說明如 下·· 圖7F彡兄明: 第1圖為習知蝕刻或CVD反應室概略結構圖。 第2圖為本發明實施例之系統結構示意圖。 第3圖本發明解決中央/邊緣分佈差異之另一實施例示 意結構圖。 ’ 第4圖為本發明另一實施例之結構示意圖。 第5圖為使用不同的氣體供應單位控制調整氣體支流 量的方法示意圖。 符號說明: 1 〇〜氣體供應裝置; 1 2〜反應室; 14〜氣體混合器; 1 6〜控制閥; 18〜中央嘴氣器(Gas Injector)或喷頭; 2〇邊緣喷氣器(Gas j njector) 或喷頭; 20〜氣體供應裝置; 2 2〜反應室; 24〜氣體混合器; 26〜控制閥; 50〜氣體供應裝置; 52,54〜氣體供應單位。497140 V. Description of the invention (3) ----- In order to make the above-mentioned objects, features, and advantages of the present invention more comprehensible, a preferred embodiment is given below in conjunction with the accompanying drawings to make a detailed description as follows Fig. 7F Xiongming Ming: Fig. 1 is a schematic diagram of a conventional etching or CVD reaction chamber. FIG. 2 is a schematic diagram of a system structure according to an embodiment of the present invention. Fig. 3 is a schematic structural diagram of another embodiment of the present invention for solving the difference in center / edge distribution. Figure 4 is a schematic structural diagram of another embodiment of the present invention. Fig. 5 is a schematic diagram of a method for controlling and adjusting the gas tributary flow by using different gas supply units. Explanation of symbols: 1 0 ~ gas supply device; 1 2 ~ reaction chamber; 14 ~ gas mixer; 16 ~ control valve; 18 ~ central nozzle (gas injector) or nozzle; 20 edge jet (gas j njector) or nozzle; 20 ~ gas supply device; 2 ~ reaction chamber; 24 ~ gas mixer; 26 ~ control valve; 50 ~ gas supply device; 52,54 ~ gas supply unit.
0503-6498TW;TSMC2001-0198;Hui .ptd 第6頁 4971400503-6498TW; TSMC2001-0198; Hui .ptd Page 6 497140
實施例: 尺寸二;=及CVD來說’調整變數找出可影響關鍵 二:=:rsion)的因素。如溫度,壓力及電源 供應造成不同電漿;澧庶辇。眘& ^Example: size two; = and for CVD, adjust the variables to find the factors that can affect the key two: =: rsion). Such as temperature, pressure and power supply cause different plasma; 澧 庶 辇. Shen & ^
Ba 包水/辰度寺貫驗結果發現,氣體支流量對 = 最大。本發明為達成補償中央/邊緣或邊) 乃之不;勻’在輸入(Key—In)_分流控制閥上的配方 (Recipe)時,調整各支流氣體的流量比率, 不均勻條件的問題。 $ π ^ h 因此本發明提出一種適用生產積體電路之電漿製程系 、、先本發月之電漿製程係統如第2圖所示包含一氣體供應 裝置1 0肖以供應複數之氣體支流,並對於該等氣體支流 之輸出流I分別獨立控制,及一用以對晶圓丨丨進行電漿蝕 刻,CJD化學氣相沉積之反應室丨2,具有複數之區域以供 該等氣體支流輸出。氣體供應裝置包1〇包含一氣體混合器 (Mixer)14及一控制閥(Valve)16。在半導體之製程應用上 二通常會以混合氣體進行濺鍍或蝕刻。因此先於氣體混合 器1 4將複數之氣體1,2及3混合。控制閥1 6為一分流控制 單位’將氣體混合器14之氣體分流並輸出至反應室丨2中。 控制閥16根據一配方(Recipe)調整各分流氣體之輸出 控制。為了解決中央/邊緣氣體支流分佈不一致之問題。 本發明提出中央/邊緣雙區(Dual Zone)氣體支流量控 制之方法。如第2圖所示,反應室中央具有中央喷氣器 (Gas Injector)或喷頭(Shower Head)18,其邊緣具有邊 緣喷氣器(Edge Gas Injector)或噴頭20,將反應室分為The results of Ba Baoshui / Chendu Temple found that the gas branch flow pair = maximum. In the present invention, the problem of compensating the center / edge or edge) is achieved; when the formula (Key-In) _Recipe on the split control valve is input, the flow ratio of each tributary gas is adjusted, and the problem of uneven conditions is adjusted. $ π ^ h Therefore, the present invention proposes a plasma process system suitable for the production of integrated circuits. The plasma process system of the present invention includes a gas supply device 10 as shown in FIG. 2 to supply a plurality of gas tributaries. And independently control the output stream I of these gas tributaries, and a reaction chamber for plasma etching of the wafers, CJD chemical vapor deposition, and a plurality of areas for the gas tributaries Output. The gas supply device package 10 includes a gas mixer 14 and a control valve 16. In semiconductor process applications, sputtering or etching is usually performed with a mixed gas. Therefore, a plurality of gases 1, 2 and 3 are mixed before the gas mixer 14 is mixed. The control valve 16 is a split control unit 'that splits the gas from the gas mixer 14 and outputs it to the reaction chamber 2. The control valve 16 adjusts the output control of each split gas according to a recipe. In order to solve the problem of inconsistent distribution of central / edge gas tributaries. The invention proposes a method for controlling the central / peripheral dual zone gas tributary flow. As shown in Fig. 2, the center of the reaction chamber is provided with a central injector or shower head 18, and the edge thereof is provided with an edge gas injector or shower head 20 to divide the reaction chamber into
497140 五、發明說明(5) 兩圈區域。控制閥1 6對於中央及邊緣分流之氣體支流量根 據上述配方分別進行獨立控制。例如:8〇%氣體經由中央喷 氣器18及2 0%經邊緣喷氣器20由反應室頂端兩圈區分別麗 出。採取頂端氣體供應(Top Gas Feed)方式由反應室頂 端供應氣體。 第3圖為本發明解決中央/邊緣分佈差異之另一實施例 概略結構圖。為克服氣體由頂端供應之本徵特性 (Intrinsic),即氣流的曲線(prof丨le)’具一特性,就算將 氣體流量加倍也不會完全解決。請參閱第3圖,本發明以 2:2頂端氣體供應(Top Gas Feed)對底部氣體供應(Bottom497140 V. Description of the invention (5) Two-circle area. The control valve 16 independently controls the branch gas flows of the center and the edge according to the above formula. For example: 80% of the gas is extracted from the top two zones of the reaction chamber via the central injector 18 and 20% via the edge injector 20 respectively. The top gas feed is used to supply gas from the top of the reaction chamber. FIG. 3 is a schematic structural diagram of another embodiment of the present invention to solve the difference in center / edge distribution. In order to overcome the intrinsic characteristics of the gas supplied from the top (Intrinsic), that is, the curve of the air flow has a characteristic, even if the gas flow is doubled, it will not be completely solved. Referring to FIG. 3, the present invention uses a 2: 2 top gas feed to a bottom gas supply (bottom
Gas Feed)區域比例分別由反應室頂端及底部供應氣體。 參照第3圖,氣體由反應室22頂端之中央喷氣器或噴 頭及底部兩侧進入反應室中。控制閥2 6根據一為補償中央 /邊緣差異之問題所輸入之配方對於分流氣體之輸出流量 進行獨立控制。控制閥2 6先將混合單元2 4輸出之氣體分流 ,並根據一氣體支流量比例配方對各分流氣體進行輸出流 量控制’以頂端氣體供給及底部氣體供給方式將氣體釋出 至反應室’均勻的對晶圓11進行電漿蝕刻4CVI)化學氣相 沉積。 有些製程不均為偏向一側之不對稱,即反應室中邊/ 邊之差異;有可能是前製程結果或機台本身之晶圓進出通 道(wafer passage)或側邊抽氣(Side Pumping)造成的。 这樣的情況很難去針對反應室邊/邊的不對稱的差異 做補償。為解決此問題,請參照第4圖,本發明提出另一The Gas Feed) area ratio is supplied from the top and bottom of the reaction chamber. Referring to Fig. 3, the gas enters the reaction chamber from a central jet or nozzle at the top of the reaction chamber 22 and both sides of the bottom. The control valve 26 independently controls the output flow of the split gas according to a formula entered to compensate for the center / edge difference. The control valve 26 first divides the gas output from the mixing unit 24, and controls the output flow of each divided gas according to a gas branch flow ratio formula. 'The gas is released to the reaction chamber by the top gas supply and the bottom gas supply.' The wafer 11 is plasma-etched (4CVI) chemical vapor deposition. Some processes are not asymmetric to one side, that is, the edge / side difference in the reaction chamber; it may be the result of the previous process or the wafer passage or side pumping of the machine itself. Caused. In this case, it is difficult to compensate for the asymmetry difference between the sides of the reaction chamber. In order to solve this problem, please refer to FIG. 4, the present invention proposes another
〇503*6498TWF;TSMC2001-0198;Hui.ptd 第8頁 ^7140 五、發明說明(6) ~---—-- 實%例。控制閥將輸出之氣流分為中央區1及邊緣區2, 4及5,由控制閥各別進行流量之控制。中央及頂端整 -之面積比例可依需要而不同,例如1 ·· 5,2 ·· 5或3 ·· 5等。 如第4圖所示,本發明採用1:5區域中央及頂端整體之 面積比例為例。各區域釋出之氣體支流量經輸入控制閥 =比例配方而注入反應室3 2。例如··氣流釋出的時候,區 域3為一流量,而區域1,2,4及5為另一流量。那一側需 要補償,就調整該側之氣體支流量,因此對晶圓丨丨均勻進 行電漿蝕刻或CVD化學氣相沉積。 时另外一種調整氣體支流量的方法的是用不同的氣體供 應單位供應不同之氣體,如第5圖所示。氣體供應裝置5〇、 包含氣體供應單位52及54 ,用以分別對氣體A 進行輸出 控制;其中,氣體A,B及C為氧體1,2及3之混合。上述本 發明頂端或頂端/底部供應氣體之電漿製程系統,以第5圖 之氣體供應單位52及54替代第2圖之控制閥ι6以控制氣體 支流量之輸出,達成上述不均勻對稱之補償作用。另'外, 上述第5圖之實施例並可應用於第3圖之頂端/底部供應氧 體之電漿製程系統。上述之供應氣體可為單一氣體或混合 氣體,例如:溴化氫(HBr)及矽烷(S i H4)。 ° 本發明之電漿製程系統適用於積體電路(IC)生產製程 之電漿餘刻及化學氣相沉積(Chemical Vapor Deposition)處理程序〇 因此,本發明提供之電漿製程系統在設計上具有可調 整的彈性。其一,中央/邊緣之蝕刻沉積速率需可分別調〇503 * 6498TWF; TSMC2001-0198; Hui.ptd Page 8 ^ 7140 V. Description of the invention (6) ~ --- --- Real examples. The control valve divides the output air flow into the central zone 1 and the edge zones 2, 4 and 5, and the control valves each control the flow. The area ratio of the center and the top can be different according to needs, such as 1 ·· 5, 2 ·· 5 or 3 ·· 5 and so on. As shown in Fig. 4, the present invention uses the area ratio of the center and the entire top of the 1: 5 area as an example. The tributary gas released from each zone is injected into the reaction chamber 32 through the input control valve = proportional formula. For example, when the airflow is released, area 3 is a flow, and areas 1, 2, 4, and 5 are another flow. To compensate on that side, adjust the gas tributary flow on that side, so plasma etching or CVD chemical vapor deposition is performed on the wafer uniformly. Another method to adjust the gas branch flow rate is to use different gas supply units to supply different gases, as shown in Figure 5. The gas supply device 50 includes gas supply units 52 and 54 for output control of the gas A, respectively; wherein the gases A, B and C are a mixture of the oxygen gas 1, 2 and 3. In the plasma processing system for supplying gas at the top or top / bottom of the present invention, the gas supply units 52 and 54 in FIG. 5 are used to replace the control valve ι6 in FIG. 2 to control the output of the gas tributary flow to achieve the above-mentioned uneven and symmetrical compensation effect. In addition, the embodiment of FIG. 5 described above can be applied to the plasma processing system for supplying oxygen at the top / bottom of FIG. 3. The above supply gas can be a single gas or a mixed gas, such as: hydrogen bromide (HBr) and silane (S i H4). ° The plasma processing system of the present invention is suitable for plasma plasma etching and chemical vapor deposition (Chemical Vapor Deposition) processing procedures of integrated circuit (IC) production processes. Therefore, the plasma processing system provided by the present invention has Adjustable elasticity. First, the etching rate of the center / edge needs to be adjustable separately
0503-6498TWF;TSMC2001-0198;Hui.ptd 第 9 頁 497l4〇0503-6498TWF; TSMC2001-0198; Hui.ptd Page 9 497l4〇
整 其 此特殊情況=二殊:整兄至如:氣管處,主少需有能力將 -方面補償前製程所造成求最:=勻的、-果。 身不均句的料,如抓曰曰;化,另-方面對機台本 A本發明雖以一較心==氣孔等加以調整。 疋本發明,任何熟習此項技蓺者=上,然其並非用以限 和範圍内,當可做些許的S =離本發明之精 範圍當視後附之申請專利範圍二者=本發明之4This is the special case = two special: the whole brother is like: at the trachea, the master needs to have the ability to compensate for the-process caused by the previous process: = uniform,-fruit. The material of the uneven sentence, such as catching and saying; changing, on the other hand, the machine A. Although the present invention is adjusted with a heart == air holes and so on.疋 In the present invention, anyone who is familiar with this technique = above, but it is not intended to be used within the scope and range. When it can be done a little S = away from the fine scope of the present invention. When both of the attached patent scopes are attached = the present invention Of 4
Claims (1)
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| TW90124915A TW497140B (en) | 2001-10-09 | 2001-10-09 | Process system for plasma etching and chemical vapor deposition |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8445075B2 (en) | 2006-03-31 | 2013-05-21 | Applied Materials, Inc. | Method to minimize wet etch undercuts and provide pore sealing of extreme low k (k<2.5) dielectrics |
| TWI424498B (en) * | 2006-03-31 | 2014-01-21 | 應用材料股份有限公司 | Method for improving step coverage and pattern loading of dielectric films |
-
2001
- 2001-10-09 TW TW90124915A patent/TW497140B/en not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8445075B2 (en) | 2006-03-31 | 2013-05-21 | Applied Materials, Inc. | Method to minimize wet etch undercuts and provide pore sealing of extreme low k (k<2.5) dielectrics |
| TWI424498B (en) * | 2006-03-31 | 2014-01-21 | 應用材料股份有限公司 | Method for improving step coverage and pattern loading of dielectric films |
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