TW515839B - Azeotropic or azeotrope-like compositions and processes for producing aerosol, refrigeration and thermoset or thermoplastic foam using the same - Google Patents

Azeotropic or azeotrope-like compositions and processes for producing aerosol, refrigeration and thermoset or thermoplastic foam using the same Download PDF

Info

Publication number: TW515839B
Authority: TW; Taiwan
Prior art keywords: hfc; weight percent; weight; composition; fluoro
Prior art date: 1996-11-04

Application number

TW86116360A

Other languages

English (en)

Chinese (zh)

Inventor

Vinci Martinez Felix

Barbara Haviland Minor

Allen Capron Sievert

Original Assignee

Du Pont

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-11-04

Filing date

1997-11-04

Publication date

2003-01-01

1997-11-04 Application filed by Du Pont filed Critical Du Pont

2003-01-01 Application granted granted Critical

2003-01-01 Publication of TW515839B publication Critical patent/TW515839B/zh

Links

239000000203 mixture Substances 0.000 title claims abstract description 164
238000000034 method Methods 0.000 title claims description 11
239000000443 aerosol Substances 0.000 title claims description 8
238000005057 refrigeration Methods 0.000 title description 4
239000006260 foam Substances 0.000 title description 2
229920001169 thermoplastic Polymers 0.000 title description 2
239000004416 thermosoftening plastic Substances 0.000 title description 2
229920001187 thermosetting polymer Polymers 0.000 title 1
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims abstract description 67
UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 claims abstract description 64
NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims abstract description 30
LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims abstract description 28
PRNZBCYBKGCOFI-UHFFFAOYSA-N 2-fluoropropane Chemical compound CC(C)F PRNZBCYBKGCOFI-UHFFFAOYSA-N 0.000 claims abstract description 16
NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 claims abstract description 14
GSMZLBOYBDRGBN-UHFFFAOYSA-N 2-fluoro-2-methylpropane Chemical compound CC(C)(C)F GSMZLBOYBDRGBN-UHFFFAOYSA-N 0.000 claims abstract description 13
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 45
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 40
235000013847 iso-butane Nutrition 0.000 claims description 23
239000001282 iso-butane Substances 0.000 claims description 22
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 21
239000001273 butane Substances 0.000 claims description 20
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 20
239000001294 propane Substances 0.000 claims description 20
WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 claims description 11
-1 2-fluoro-2 -fluorenyl propane Chemical compound 0.000 claims description 11
238000001704 evaporation Methods 0.000 claims description 6
FYIRUPZTYPILDH-UHFFFAOYSA-N 1,1,1,2,3,3-hexafluoropropane Chemical compound FC(F)C(F)C(F)(F)F FYIRUPZTYPILDH-UHFFFAOYSA-N 0.000 claims description 5
230000000694 effects Effects 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
OQLZINXFSUDMHM-UHFFFAOYSA-N Acetamidine Chemical compound CC(N)=N OQLZINXFSUDMHM-UHFFFAOYSA-N 0.000 claims 1
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
229910052731 fluorine Inorganic materials 0.000 claims 1
239000011737 fluorine Substances 0.000 claims 1
125000003784 fluoroethyl group Chemical group [H]C([H])(F)C([H])([H])* 0.000 claims 1
239000003795 chemical substances by application Substances 0.000 abstract description 16
229930195733 hydrocarbon Natural products 0.000 abstract description 16
150000002430 hydrocarbons Chemical class 0.000 abstract description 16
239000003507 refrigerant Substances 0.000 abstract description 15
239000012530 fluid Substances 0.000 abstract description 14
239000003380 propellant Substances 0.000 abstract description 10
239000004215 Carbon black (E152) Substances 0.000 abstract description 7
239000012459 cleaning agent Substances 0.000 abstract description 5
239000002274 desiccant Substances 0.000 abstract description 5
239000003989 dielectric material Substances 0.000 abstract description 5
229920002635 polyurethane Polymers 0.000 abstract description 5
239000004814 polyurethane Substances 0.000 abstract description 5
238000012546 transfer Methods 0.000 abstract description 5
239000003082 abrasive agent Substances 0.000 abstract description 4
238000006116 polymerization reaction Methods 0.000 abstract description 4
238000006073 displacement reaction Methods 0.000 abstract description 2
229920000098 polyolefin Polymers 0.000 abstract description 2
238000009835 boiling Methods 0.000 description 39
239000007788 liquid Substances 0.000 description 33
238000011049 filling Methods 0.000 description 25
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 22
230000002079 cooperative effect Effects 0.000 description 21
150000001875 compounds Chemical class 0.000 description 19
238000009472 formulation Methods 0.000 description 18
239000004615 ingredient Substances 0.000 description 16
XPDWGBQVDMORPB-UHFFFAOYSA-N trifluoromethane acid Natural products FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 16
239000012855 volatile organic compound Substances 0.000 description 12
238000010586 diagram Methods 0.000 description 10
239000000126 substance Substances 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
239000007789 gas Substances 0.000 description 7
238000005259 measurement Methods 0.000 description 6
239000002304 perfume Substances 0.000 description 6
230000007797 corrosion Effects 0.000 description 5
238000005260 corrosion Methods 0.000 description 5
230000008020 evaporation Effects 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
230000009257 reactivity Effects 0.000 description 5
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
238000004821 distillation Methods 0.000 description 4
238000007710 freezing Methods 0.000 description 4
230000008014 freezing Effects 0.000 description 4
239000002245 particle Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
239000012298 atmosphere Substances 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
238000004140 cleaning Methods 0.000 description 3
239000002781 deodorant agent Substances 0.000 description 3
239000000499 gel Substances 0.000 description 3
239000008266 hair spray Substances 0.000 description 3
239000000314 lubricant Substances 0.000 description 3
238000005457 optimization Methods 0.000 description 3
238000005498 polishing Methods 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000000779 smoke Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000007921 spray Substances 0.000 description 3
WGCJTTUVWKJDAX-UHFFFAOYSA-N 1-fluoro-2-methylpropane Chemical compound CC(C)CF WGCJTTUVWKJDAX-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000001166 anti-perspirative effect Effects 0.000 description 2
239000003213 antiperspirant Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
239000002826 coolant Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
239000003599 detergent Substances 0.000 description 2
PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 2
235000019404 dichlorodifluoromethane Nutrition 0.000 description 2
238000001035 drying Methods 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
239000004088 foaming agent Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
230000014759 maintenance of location Effects 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
229920002120 photoresistant polymer Polymers 0.000 description 2
238000007639 printing Methods 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011347 resin Substances 0.000 description 2
235000013599 spices Nutrition 0.000 description 2
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
FCBJLBCGHCTPAQ-UHFFFAOYSA-N 1-fluorobutane Chemical compound CCCCF FCBJLBCGHCTPAQ-UHFFFAOYSA-N 0.000 description 1
VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 1
JKTORXLUQLQJCM-UHFFFAOYSA-N 4-phosphonobutylphosphonic acid Chemical compound OP(O)(=O)CCCCP(O)(O)=O JKTORXLUQLQJCM-UHFFFAOYSA-N 0.000 description 1
239000004604 Blowing Agent Substances 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
239000004338 Dichlorodifluoromethane Substances 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
241000238631 Hexapoda Species 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000002386 air freshener Substances 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000009530 blood pressure measurement Methods 0.000 description 1
NBXNPQXGMZGZOR-UHFFFAOYSA-N butane ethane 2-methylpropane propane Chemical compound CC.CCC.CCCC.CC(C)C NBXNPQXGMZGZOR-UHFFFAOYSA-N 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
229920006026 co-polymeric resin Polymers 0.000 description 1
230000001351 cycling effect Effects 0.000 description 1
238000005238 degreasing Methods 0.000 description 1
239000000645 desinfectant Substances 0.000 description 1
238000011161 development Methods 0.000 description 1
229940008099 dimethicone Drugs 0.000 description 1
239000004205 dimethyl polysiloxane Substances 0.000 description 1
235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
238000000227 grinding Methods 0.000 description 1
230000009931 harmful effect Effects 0.000 description 1
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
229910000271 hectorite Inorganic materials 0.000 description 1
150000007857 hydrazones Chemical class 0.000 description 1
238000003384 imaging method Methods 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012946 outsourcing Methods 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
229920001281 polyalkylene Polymers 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000007348 radical reaction Methods 0.000 description 1
238000007665 sagging Methods 0.000 description 1
229910000679 solder Inorganic materials 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000009331 sowing Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008107 starch Substances 0.000 description 1
238000010025 steaming Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
229940029284 trichlorofluoromethane Drugs 0.000 description 1
238000010792 warming Methods 0.000 description 1

Landscapes

Detergent Compositions (AREA)

TW86116360A 1996-11-04 1997-11-04 Azeotropic or azeotrope-like compositions and processes for producing aerosol, refrigeration and thermoset or thermoplastic foam using the same TW515839B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US2997196P	1996-11-04	1996-11-04

Publications (1)

Publication Number	Publication Date
TW515839B true TW515839B (en)	2003-01-01

Family

ID=27803580

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW86116360A TW515839B (en)	1996-11-04	1997-11-04	Azeotropic or azeotrope-like compositions and processes for producing aerosol, refrigeration and thermoset or thermoplastic foam using the same

Country Status (3)

Country	Link
ID (1)	ID21960A (id)
MY (1)	MY123864A (id)
TW (1)	TW515839B (id)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN113845884A (zh) *	2005-03-04	2021-12-28	科慕埃弗西有限公司	包含氟代烯烃的组合物

1997
- 1997-11-03 ID IDW990290A patent/ID21960A/id unknown
- 1997-11-04 MY MYPI97005209A patent/MY123864A/en unknown
- 1997-11-04 TW TW86116360A patent/TW515839B/zh not_active IP Right Cessation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN113845884A (zh) *	2005-03-04	2021-12-28	科慕埃弗西有限公司	包含氟代烯烃的组合物
CN113845884B (zh) *	2005-03-04	2024-02-02	科慕埃弗西有限公司	包含氟代烯烃的组合物

Also Published As

Publication number	Publication date
ID21960A (id)	1999-08-19
MY123864A (en)	2006-06-30

Legal Events

Date	Code	Title	Description
2003-05-22	GD4A	Issue of patent certificate for granted invention patent
2010-10-11	MM4A	Annulment or lapse of patent due to non-payment of fees

Publication	Publication Date	Title
US5785883A (en)	1998-07-28	Hydrofluorocarbon compositions with tetrafluoroethane and cyclopropane
KR100208112B1 (ko)	1999-07-15	비점이 일정한 불소화 탄화수소 조성물
US5616276A (en)	1997-04-01	Azeotrope-like refrigerants with chlorodifluoromethane, pentafluoroethane, and C2 -C4 hydrocarbon
CA2509506C (en)	2009-09-15	Hydrofluorocarbon compositions
EP0610424B1 (en)	1998-01-07	Compositions of difluoromethane and tetrafluoroethane
US6001273A (en)	1999-12-14	Binary azeotropes of difluoromethane and hydrocarbons
JP2714486B2 (ja)	1998-02-16	ヘキサフルオロプロパンを含む組成物
TW515839B (en)	2003-01-01	Azeotropic or azeotrope-like compositions and processes for producing aerosol, refrigeration and thermoset or thermoplastic foam using the same
AU774247B2 (en)	2004-06-24	Hydrofluorocarbon compositions
MXPA99004151A (en)	2000-02-02	Hydrofluorocarbon compositions
EP1179579B1 (en)	2009-03-11	Hydrofluorocarbon compositions
HK1002432B (en)	1998-08-21	Compositions of difluoromethane and tetrafluoroethane