TW563189B - Method for forming self-aligned metal oxide semiconductor transistor - Google Patents
Method for forming self-aligned metal oxide semiconductor transistor Download PDFInfo
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- TW563189B TW563189B TW90121547A TW90121547A TW563189B TW 563189 B TW563189 B TW 563189B TW 90121547 A TW90121547 A TW 90121547A TW 90121547 A TW90121547 A TW 90121547A TW 563189 B TW563189 B TW 563189B
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- 238000000034 method Methods 0.000 title claims abstract description 44
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract description 5
- 150000004706 metal oxides Chemical class 0.000 title claims abstract description 5
- 239000004065 semiconductor Substances 0.000 title abstract description 4
- 238000000151 deposition Methods 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 239000002184 metal Substances 0.000 claims description 39
- 239000000758 substrate Substances 0.000 claims description 15
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 11
- 238000005468 ion implantation Methods 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 238000005229 chemical vapour deposition Methods 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 claims description 5
- 238000005530 etching Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical group N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000010432 diamond Substances 0.000 claims 1
- 229910003460 diamond Inorganic materials 0.000 claims 1
- 229910021332 silicide Inorganic materials 0.000 abstract description 4
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 abstract description 4
- 229910008310 Si—Ge Inorganic materials 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- KZNMRPQBBZBTSW-UHFFFAOYSA-N [Au]=O Chemical compound [Au]=O KZNMRPQBBZBTSW-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021334 nickel silicide Inorganic materials 0.000 description 1
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052861 titanite Inorganic materials 0.000 description 1
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- Electrodes Of Semiconductors (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
Description
563189 五、發明說明(1) 5 - 1發明領域:563189 V. Description of the invention (1) 5-1 Field of invention:
有介 是之 別準 特對 ,我 法自 方一 的有 體具 晶上 電極。 半閘法 氧其方 金在的 成且積 形體面 1 晶表 關電極 有半閘 是氧加 明金增 發一以 本成質 形物 ΠΓ5Ξ!^¾ IV,^H 5 - 2發明背景: 傳統形成MOS電晶體的方法通常包含下列步驟:首先 0 ,如第一 A圖所示,提供一底材1 0,然後在底材1 0上形成 一閘極氧化層1 5。其次’再形成一閘極2 0於閘極氧化層1 5 上。之後,以閘極2 0為一幕罩,進行一離子植入以形成輕 摻雜沒極2 5與輕摻雜源極3 0。然後形成閘極2 0之側壁4 0, 如第一 B圖所示。再以閘極2 0與側壁4 0作為幕罩,進行另 一次離子植入以形成汲極4 5與源極5 0。如此便完成一 MOS 電晶體的製作。然而,當積體電路的尺寸越來越小時,閘 極也需變小。如此,將使得閘極上與導線間接觸的面積變 小,而使得電阻增加,以致於降低MOS電晶體的效率。一 種解決的方法是增加閘極的導電性。而現今的技術是在閘_ 極表面上形成一層石夕化金屬層,比如石夕化鈦、石夕化始、或 矽化鎳,以降低閘極的電阻值。此方法首先沈積一金屬層 5 5,比如鈦、始、或錄,以覆蓋MOS電晶體表面,如第一 D 圖所示。然後,進行一加熱步驟,使得閘極2 0、沒極2 5、There is a medium. You can't do it right. We have a body-on-crystal electrode. The half-gate method of oxygen and square gold formation and decent shape of the 1 crystal surface of the electrode has a half-gate is oxygen plus bright gold issuance of an original material ΠΓ5Ξ! ^ ¾ IV, ^ H 5-2 Background of the invention: Traditional The method for forming a MOS transistor usually includes the following steps: first, as shown in the first A diagram, a substrate 10 is provided, and then a gate oxide layer 15 is formed on the substrate 10. Next, a gate 20 is formed on the gate oxide layer 15 again. After that, the gate electrode 20 is used as a mask, and an ion implantation is performed to form a lightly doped electrode 25 and a lightly doped source electrode 30. Then, a side wall 40 of the gate electrode 20 is formed, as shown in the first B diagram. The gate electrode 20 and the side wall 40 are used as a curtain, and another ion implantation is performed to form a drain electrode 45 and a source electrode 50. This completes the fabrication of a MOS transistor. However, as the size of integrated circuits becomes smaller, the gates also need to be smaller. In this way, the contact area between the gate electrode and the wire will be reduced, and the resistance will increase, so that the efficiency of the MOS transistor will be reduced. One solution is to increase the conductivity of the gate. The current technology is to form a layer of petrified metal on the surface of the gate electrode, such as titanium titanite, petrified silicon or nickel silicide, to reduce the resistance of the gate. This method first deposits a metal layer 55, such as titanium, silicon, or silicon, to cover the surface of the MOS transistor, as shown in the first D diagram. Then, a heating step is performed, so that the gates 20, 50 and 5,
第4頁 563189 五、發明說明(2) 與源極3 0之表面的多晶矽均與金屬起作用,而形成矽化金 屬層(60,65,70),如第一 E圖所示。最後,再除去此 金屬層55,如第一 F圖所示。 然而,上述的方法雖然能降低閘極電阻值,但是在製 作導線連結時則仍會因為閘極尺寸變小而遭遇困難。因此 ,另一種解決的方法便是如何有效地增加閘極的表面積。 5 - 3發明目的及概述 本發明的一目的是提供一方法以金氧半電晶體。 本發明的另一目的是提供一方法以增加閘極的表面積 本發明的再一目的是提供一方法以降低閘極的電阻值 根據以上目的,本發明提出一有效的方法,其至少包鲁 含如下步驟:首先,提供一結構,其至少包含一底材、一 閘極氧化層在此底材上;以及一閘極在此閘極氧化層上。 然後,進行離子植入以形成輕摻雜汲極與輕摻雜源極。其 次,沈積一第一介電層,比如氧化石夕層或氮化石夕層,覆蓋Page 4 563189 V. Description of the invention (2) Both the polycrystalline silicon on the surface of the source 30 and the metal interact with the metal to form a silicide metal layer (60, 65, 70), as shown in the first E diagram. Finally, the metal layer 55 is removed, as shown in the first F diagram. However, although the above-mentioned method can reduce the gate resistance value, it still encounters difficulties when the size of the gate is reduced when the wire connection is made. Therefore, another solution is how to effectively increase the surface area of the gate. 5-3 Objects and Summary of the Invention An object of the present invention is to provide a method for gold-oxygen semitransistor. Another object of the present invention is to provide a method to increase the surface area of the gate electrode. Another object of the present invention is to provide a method to reduce the resistance value of the gate electrode. The following steps: First, a structure is provided, which includes at least a substrate, a gate oxide layer on the substrate; and a gate on the gate oxide layer. Then, ion implantation is performed to form a lightly doped drain and a lightly doped source. Second, a first dielectric layer is deposited, such as an oxide stone layer or a nitride stone layer, to cover
563189 五、發明說明(3) 此閘極、閘極氧化層、輕摻雜沒極與輕摻雜源極。然後, 進行一蝕刻步驟除去部分第一介電層以裸露出閘極上端的 一部份區域。之後,選擇性沈積一第二介電層,比如複晶 矽鍺,於該裸露的閘極上端的一部份區域之表面上。此第 二介電層的表面積與寬度均較該裸露的閘極部分區域為大 。值得注意的是此第二介電層只會沉積在以多晶矽為材質 的閘極上,而不會沉積在第一介電層上。因此,此步驟是 具有自我對準的。此沈積步驟可以化學氣相沈積法在約 5 0 (TC至7 0 0°C進行。然後,以此第二介電層為幕罩除去部 分第一介電層,以裸露出輕摻雜汲極與輕摻雜源極,而部 分受到此第二介電層遮蔽而剩餘的第一介電層則作為閘極 之側壁。然後,進行一離子植入步驟以形成沒極與源極。 此外,更可沈積一金屬層,比如鈦、始、與錄,以覆蓋此 第二介電層、汲極、與源極。然後進行一加熱步驟使此第 二介電層、汲極、與源極表面上的多晶矽均與金屬反應, 而生成矽化金屬層。此矽化金屬層可以降低閘極、汲極、 與源極的電阻值。上述沈積金屬層的步驟可以是以離子化 金屬電漿(I MP)法來進行。如此形成之金氧半電晶體具有 一較大表面積及較低電阻值的閘極。 5 - 4發明詳細說明: 本發明的較佳實施例將詳細討論如後。實施例乃是用563189 V. Description of the invention (3) This gate, gate oxide layer, lightly doped electrode and lightly doped source electrode. Then, an etching step is performed to remove a part of the first dielectric layer to expose a part of the upper end of the gate. After that, a second dielectric layer, such as polycrystalline silicon germanium, is selectively deposited on the surface of a part of the upper end of the exposed gate. The surface area and width of the second dielectric layer are larger than those of the exposed gate region. It is worth noting that this second dielectric layer will only be deposited on the gate made of polycrystalline silicon and will not be deposited on the first dielectric layer. Therefore, this step is self-aligning. This deposition step can be performed by chemical vapor deposition at about 50 ° C. to 700 ° C. Then, a portion of the first dielectric layer is removed by using the second dielectric layer as a mask to expose the lightly doped drain. Electrode and lightly doped source electrode, and partially shielded by this second dielectric layer and the remaining first dielectric layer is used as the sidewall of the gate. Then, an ion implantation step is performed to form the anode and source. A metal layer such as titanium, starting, and recording can be deposited to cover the second dielectric layer, the drain, and the source. Then, a heating step is performed to make the second dielectric layer, the drain, and the source The polycrystalline silicon on the electrode surface reacts with the metal to form a silicided metal layer. This silicided metal layer can reduce the resistance values of the gate, the drain, and the source. The step of depositing the metal layer may be an ionized metal plasma I MP) method. The metal-oxide semiconductor transistor thus formed has a gate having a larger surface area and a lower resistance value. 5-4 Detailed description of the invention: The preferred embodiments of the present invention will be discussed in detail later. Implementation Example is to use
第6頁 563189 五、發明說明(4) 以描述使用本發明的一特定範例,並非用以限定本發明的 範圍。 本發明提出一方法可以有效地增加閘極表面積,其詳 細步驟如下:首先,如第二A圖所示,提供一底材1 0,然 後在一底材1 0上形成一閘極氧化層1 5。其次,再沉積一多 晶矽層於閘極氧化層1 5上,再蝕刻此多晶矽層以形成一閘 極2 0。之後,以閘極2 0為一幕罩,進行一離子植入以形成 輕摻雜汲極2 5與輕摻雜源極3 0。而每個MOS電晶體之間以 場氧化層3 5隔開,如第二A圖所示。然後沈積一第一介電φ 層7 5,比如氧化矽層或氮化矽層,覆蓋此閘極2 0、閘極氧 化層1 5,輕摻雜汲極2 5、與輕摻雜源極3 0,如第二B圖所 示。然後,進行一蝕刻步驟除去部分的第一介電層7 5,以 裸露出閘極上端的一部份區域,如第二C圖所示。之後, 以化學氣相沈積法在約5 0 0°C至7 0 0°C之間,沈積一第二介 電層8 0覆蓋此裸露出的閘極上端的一部份區域,如第二D 圖所示。此第二介電層8 0的材質主要是一種具有選擇性沈 積的物質,比如複晶石夕鍺,其只會沈積在材質為多晶石夕的 閘極2 0表面上,而不會沈積在第一介電層7 5之上,故此為 一種具有自我對準之沈積方法。如第二D圖所示,我們可_ 以發現此第二介電層8 0的表面積與寬度均較原本閘極2 0的 該部份區域的面積更大。因此,有利於閘極與導線間的連 接與增加接觸的面積。然後,以此第二介電層8 0為一幕罩 ,進行一非等向性蝕刻除去部分第一介電層7 5,以裸露出Page 6 563189 V. Description of the Invention (4) To describe a specific example of using the present invention, it is not intended to limit the scope of the present invention. The present invention proposes a method that can effectively increase the gate surface area. The detailed steps are as follows: First, as shown in Figure A, a substrate 10 is provided, and then a gate oxide layer 1 is formed on a substrate 10. 5. Next, a polycrystalline silicon layer is deposited on the gate oxide layer 15 and the polycrystalline silicon layer is etched to form a gate electrode 20. After that, the gate electrode 20 is used as a mask, and an ion implantation is performed to form a lightly doped drain electrode 25 and a lightly doped source electrode 30. Each MOS transistor is separated by a field oxide layer 35, as shown in the second A diagram. Then deposit a first dielectric φ layer 75, such as a silicon oxide layer or a silicon nitride layer, to cover the gate 20, the gate oxide layer 15, the lightly doped drain 25, and the lightly doped source 3 0, as shown in the second B figure. Then, an etching step is performed to remove a part of the first dielectric layer 75 to expose a part of the upper end of the gate electrode, as shown in the second C diagram. Afterwards, a second dielectric layer 80 is deposited by chemical vapor deposition between about 500 ° C and 700 ° C to cover a part of the upper end of the exposed gate, such as the second D As shown. The material of the second dielectric layer 80 is mainly a substance having selective deposition, such as polycrystalline silicon germanium, which can only be deposited on the surface of the gate 20 made of polycrystalline silicon, and will not be deposited. Above the first dielectric layer 75, it is therefore a self-aligned deposition method. As shown in the second D diagram, we can find that the surface area and width of the second dielectric layer 80 are larger than the area of the partial area of the gate 20 originally. Therefore, it is beneficial to the connection between the gate and the conductor and to increase the contact area. Then, using this second dielectric layer 80 as a mask, an anisotropic etching is performed to remove a portion of the first dielectric layer 75 to expose it.
第7頁 563189 五、發明說明(5) 輕摻雜汲極2 5與輕摻雜源極3 0的大部份。位於第二介電層 8 〇下方之部分未被除去之第一介電層則作為閘極2 0之側壁 8 5,如第二E圖所示。之後,再以第二介電層8 0作為幕罩 進行一離子植入以產生汲極9 0與源極9 5,如第二F圖所示 。然後,以離子化金屬電漿法(I MP)沈積一金屬層1 0 〇, 比如鈦、鈷或鎳,以覆蓋MOS電晶體、汲極90與9 5源極表 面’如第二G圖所示。然後,進行一加熱步驟,使得第二 介電層8 0、汲極9 0、與源極9 5之表面均與金屬起作用,而 形成矽化金屬層(1 0 5、1 1 0、1 1 5),如第二Η圖所示。此 石夕化金屬層(1 0 5、1 1 0、1 1 5)可以降低閘極2 0、汲極9 0、 與源極9 5的電阻值,故可避免因為尺寸縮小而產生的問題 。最後,再除去此金屬層,如第二I圖所示,便完成本發 明之MOS電晶體。 以上所述僅為本發明之較佳實施例而已,並非用以限 定本發明之申請專利範圍;凡其它未脫離本發明所揭示之 精神下所完成之等效改變或修飾,均應包含在下述之申請 專利範圍内。Page 7 563189 V. Description of the invention (5) Most of lightly doped drain 25 and lightly doped source 30. The portion of the first dielectric layer that has not been removed below the second dielectric layer 80 is used as the sidewall 85 of the gate electrode 20, as shown in the second E diagram. Then, an ion implantation is performed with the second dielectric layer 80 as a curtain to generate a drain electrode 90 and a source electrode 95, as shown in the second F diagram. Then, a metal layer 100, such as titanium, cobalt, or nickel, is deposited by an ionized metal plasma method (I MP) to cover the surface of the MOS transistor, the drain electrodes 90 and 95, as shown in the second G diagram. Show. Then, a heating step is performed so that the surfaces of the second dielectric layer 80, the drain electrode 90, and the source electrode 95 all interact with the metal to form a silicided metal layer (1 0 5, 1 1 0, 1 1 5), as shown in the second figure. The petrified metal layer (1 0 5, 1 1 0, 1 1 5) can reduce the resistance values of the gate electrode 20, the drain electrode 90, and the source electrode 95, so that problems caused by the reduction in size can be avoided. . Finally, the metal layer is removed, and the MOS transistor of the present invention is completed as shown in FIG. 2I. The above are merely preferred embodiments of the present invention, and are not intended to limit the scope of patent application for the present invention; all other equivalent changes or modifications made without departing from the spirit disclosed by the present invention shall be included in the following Within the scope of patent application.
第8頁 563189 圖式簡單說明 、 如本說明之附圖中所示: 第一 A圖至第一 F圖 傳統形成一具有矽化金屬層之金 氧半電晶體之各階段的截面示意圖; 第二A圖至第二I圖 本發明形成一具自我對準之金氧 半電晶體之一實施例於各階段之截面示意圖; 主要部分之代表符號: 10 底材 φ 15 閘極氧化層 2 0 閘極 2 5 輕摻雜沒極 3 0 輕摻雜源極 3 5 場氧化層 40 側壁 4 5 汲極 5 0 源極 55 金屬層 6 0 閘極之矽化金屬層 鲁 6 5 汲極之石夕化金屬層 7 0 源極之矽化金屬層 75 第一介電層 80 第二介電層Page 563189 Brief description of the drawings, as shown in the drawings of this description: Figures A to F: Traditional sectional views of various stages of forming a gold-oxygen semi-transistor with a silicided metal layer; Figures A to II. The present invention forms a cross-sectional schematic diagram of an embodiment of a self-aligned metal-oxide semiconductor transistor at each stage. Representative symbols of the main part: 10 substrate φ 15 gate oxide layer 2 gate Electrode 2 5 lightly doped electrode 3 0 lightly doped source electrode 3 5 field oxide layer 40 sidewall 4 5 drain electrode 5 0 source electrode 55 metal layer 6 0 gate silicided metal layer 6 5 drain electrode Metal layer 7 0 Source silicided metal layer 75 First dielectric layer 80 Second dielectric layer
563189 圖式簡單說明 85 側壁 90 汲極 9 5 源極 1 0 0金屬層 1 0 5閘極之矽化金屬層 1 1 0汲極之矽化金屬層 1 1 5源極之石夕化金屬層563189 Brief description of the diagram 85 Side wall 90 Drain 9 5 Source 1 0 0 Metal layer 1 0 5 Silicide metal layer at the gate 1 1 0 Silicide metal layer at the drain 1 1 5 Petrified metal layer at the source
第10頁Page 10
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| TW90121547A TW563189B (en) | 2001-08-31 | 2001-08-31 | Method for forming self-aligned metal oxide semiconductor transistor |
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| TW90121547A TW563189B (en) | 2001-08-31 | 2001-08-31 | Method for forming self-aligned metal oxide semiconductor transistor |
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