TW565638B - Seat-use three-dimensional knit fabric - Google Patents
Seat-use three-dimensional knit fabric Download PDFInfo
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- TW565638B TW565638B TW91106357A TW91106357A TW565638B TW 565638 B TW565638 B TW 565638B TW 91106357 A TW91106357 A TW 91106357A TW 91106357 A TW91106357 A TW 91106357A TW 565638 B TW565638 B TW 565638B
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/14—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes
- D04B21/16—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes incorporating synthetic threads
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2403/00—Details of fabric structure established in the fabric forming process
- D10B2403/02—Cross-sectional features
- D10B2403/021—Lofty fabric with equidistantly spaced front and back plies, e.g. spacer fabrics
- D10B2403/0213—Lofty fabric with equidistantly spaced front and back plies, e.g. spacer fabrics with apertures, e.g. with one or more mesh fabric plies
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2403/00—Details of fabric structure established in the fabric forming process
- D10B2403/02—Cross-sectional features
- D10B2403/024—Fabric incorporating additional compounds
- D10B2403/0241—Fabric incorporating additional compounds enhancing mechanical properties
- D10B2403/02411—Fabric incorporating additional compounds enhancing mechanical properties with a single array of unbent yarn, e.g. unidirectional reinforcement fabrics
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2403/00—Details of fabric structure established in the fabric forming process
- D10B2403/02—Cross-sectional features
- D10B2403/024—Fabric incorporating additional compounds
- D10B2403/0241—Fabric incorporating additional compounds enhancing mechanical properties
- D10B2403/02412—Fabric incorporating additional compounds enhancing mechanical properties including several arrays of unbent yarn, e.g. multiaxial fabrics
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/08—Upholstery, mattresses
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
- Y10T442/45—Knit fabric is characterized by a particular or differential knit pattern other than open knit fabric or a fabric in which the strand denier is specified
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
- Y10T442/488—Including an additional knit fabric layer
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Knitting Of Fabric (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Ceramic Products (AREA)
Abstract
Description
565638 A7 B7 五、發明説明(} 〔產業上之利用領域〕 (請先閲讀背面之注意事項再填寫本頁) 本發明是有關適合使用於汽車、鐵道車輛、.航空機、 嬰兒座椅、嬰兒車、家具、事務用等的座墊用緩衝材、寢 具、床舖、床墊、床防止偏位墊、枕頭、睡墊等緩衝材、 衣料用等的隔片、保型材、緩衝材、保溫材、鞋子用的上 墊材、中墊材、或者是支撐具或保護具等的立體編物。 〔先前之技術〕 由表裏二層的針織物及連結該二層的針織物的連結線 所構成的立體編物,活用其緩衝性、通氣性、保溫性、體 壓分散性等的功能,而被利用在各種的緩衝材用途。 經濟部智慈財產局員工消費合作社印製 這些立體編物,藉由在構成中間層的連結線使用單 絲,活用單絲的彎曲彈性而在立體編物的厚度方向附與緩 衝性。提高立體編物的緩衝性、壓縮回復性的方法,在曰 本特開平1 1 — 2 6 9 7 4 7號公報中,係揭示:在連結 線使用彈性回復性良好的單絲,使立體編物的壓縮回復性 良好的立體編物。但是,因未考慮連結線的單絲的形狀, 所以無法獲得具有彈力感的緩衝性,且返覆或長時間使用 的情況時,會產生彈力感降低或厚度減少的問題。而且, 因爲未考慮立體編物的表背的針織物的伸長特性或壓縮撓 屈特性,所以作成吊床式的座墊的狀況時,無法獲得良好 的緩衝性。又,日本特開2 0 0 1 — 8 7 0 7 7號公報 中,雖揭示將立體編物張設在座墊架,來作爲吊床式的座 墊使用,但返覆使用的情況時的緩衝性的耐久性並不充 氏張尺度適用中國國家標準(CNS ) Α4規格(210Χ 297公瘦") 565638 A7 ____B7 五、發明説明(j 分。 (請先閲讀背面之注意事項再填寫本頁) 本發明的目的是在於解決前述問題點,並提供具有含 有彈力感的緩衝性,即使返覆或長時間使用也不容易損害 彈力感,且緩衝性的耐久性佳的立體編物。本發明的更具 體的目的:特別是,使用在吊床式座墊的情況時,顯示具 有反彈感的緩衝性,並且,對人體的貼身感良好,且坐後 不會回復至原來的形狀,也就是彈性復原少形態保持性佳 的立體編物。本發明的進一步的目的爲提供高頻率的振動 減衰性佳的立體編物。 〔發明的揭示〕 本發明,是針對由組合連結立體編物的表背的針織物 的單絲的直徑及彎曲形狀、立體編物的壓縮特性、壓縮撓 屈特性及纖維素材所構成的立體編物的構造,經反覆硏 究,始獲得本發明。 經濟部智慧財產局員工消費合作社印製 也就是說,本發明的體編物5針對由表背二層的針 織物、及連結該二層的針織物的單絲的連結線所構成的立 體編物,其特徵爲:立體編物中的單絲的曲率爲〇 . 〇 1 〜1 · 6 ,立體編物的5 0 %壓縮時的單絲的彎曲伸長率 爲2 0 %以下。 〔實施例〕 茲佐以圖面說明本發明之座墊用立體編物。 由圓型針織機編機、雙圓針織機、橫針織機編成立體 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐) 565638 經濟部智慧財產局員工消費合作杜印製 A7 B7五、發明説明(3) 編物的情況時,連結表背的針織物的連結線,必定在朝某 一方向彎曲的狀態下編入。因此,在立體編物加上厚度方 向的力量的話,已彎曲的連結線會更彎曲,但放開力量的 話,會連結線回復至原來的狀態。這時所產生的連結線的 彎曲及回復的舉動大大影響立體編物的緩衝性。本發明即 是依據此知識。 本發明的立體編物,在連結表背二層的針織物的連結 線的至少一部分必需使用單絲,且使位在立體編物的表背 的針織物之間的單絲的曲率成爲0 · 0 1〜1 · 6地編成 立體編物,並後處理加工。在此.,所謂的單絲的曲率,是 在立體編物中使單絲呈最大彎曲的部分的單絲的中心線所 形成的圓弧的曲率。第1圖是顯示從沿著立體編物1的縱 列的切斷面所看的單絲的中心線5的一例。單絲的曲率, 最好是0 · 03〜1 · 0,但0 · 05〜0 · 7更佳。單 絲的曲率未滿0 . 〇 1的話,當在立體編物1的厚度方向 加上負荷的情況時,表面的針織物及背面的針織物會朝立 體編物的長度方向(沿著縱列的方向)偏移而容易發生剪 斷變形,而成爲回復時的滯延損耗大的無彈力感的緩衝 性。且,藉由返覆壓縮使該傾向會更增長。單絲的曲率r i 超過1 · 6的話,雖不容易產生剪斷變形,但也成爲無彈 力感的緩衝性。 且,本發明的立體編物,將立體編物5 0 %壓縮時的 單絲的彎曲伸長率爲2 〇 %以下較佳。1 5 %以下更佳, 1 0 %以下最佳。在此,所謂的單絲的彎曲伸長率,是在 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐1 " (請先閲讀背面之注意事項再填寫本頁} 565638 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明(4) 將立體編物5 0 %壓縮的狀態下使單絲呈最大彎曲處的凸 側表面的伸長率。第2圖雖是將立體編物1呈5 0 %壓縮 的狀態下的沿著編物的縱列的切斷面圖’但顯示單絲呈最 大彎曲的凸側表面6的一例。單絲的彎曲伸長率超過2〇 %的話,會成爲壓縮立體編物之後的殘留變形大,且壓縮 回復性差的立體編物’並且’返復或長時間壓縮後,無法 維持具有彈力感緩衝性。 立體編物的單絲的彎曲伸長率,7 5 %壓縮時爲2 0 %以下的話’可以提高壓縮回復性、緩衝性的耐久性而更 佳。 爲了將立體編物的單絲的曲率、及5 0 %壓縮時的單 絲的彎曲伸長率位在前述適當的範圍內,必需最適化:作 爲立體編物1的單絲的直徑、立體編物中的單絲的編組織 (連結表背的針織物時的寬方向的擺動寬)、編成時的單 絲的供給量、立體編物的後處理加工方向(擴幅率、過給 率),並將後處理加工後的單絲作成適當形狀。其中,對 於單絲的編組織及立體編物的厚度的關係,藉由將連結線 朝針織物的寬方向傾斜地連結表面及背面的針織物,並以 適當的擴幅率後處理加工,如第3圖所示的沿著橫列的切 斷面圖,使從壓縮前的立體編物1的厚度T Q ( m m )減去 表面和背面的地的厚度的連結線長Η 1 ( m m )及第4圖 所示的5 0 %壓縮後的連結線長Η 2 ( m m )的關係成爲 H1/H2-0 · 55的原因,是因爲將立體編物1的 5〇%壓縮時的彎曲伸長率作成2 0 %時的情況較佳。這 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 565638 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(5) 時,連結線長Η 1及Η 2,如第3、4圖所示地將立體編 物1從沿著橫列的切斷面來看時,是表針織物2及背針織 物3之間的連結線4的外表上的長度,是沿著橫列的切斷 面攝影並測量後所獲的的長度。 將連結線沿著橫列方向傾斜的情況時,與傾斜的連結 線相反的傾斜方向也將連結線傾斜,而將連結線作成後述 的構架構造或交叉構造較佳。 立體編物的曲率爲0 · 0 1〜1 . 6,5 0 %壓縮時 的彎曲伸長率爲2 0 %以下的單絲的連結線的比率,必需 是立體編物的單位面積中連結表背的針織物的單絲的全條 數之中的20%以上,最好是40%以上,60%以上更 佳。 立體編物的連結線,若全部是單絲會較佳,但依據需 要編成時交編單絲以外的纖維也可以。例如:交織復絲假 捻絲等的話,可以減低壓縮時單絲彼此發生摩擦所產生的 令人不快的聲音。 爲了將5 0 %壓縮時的滯延損耗降爲5 0 %以上,使 連結線的單絲的彎曲伸長率成爲2 0 %以上地適正化:立 體編物的厚度、單絲的直徑、單絲的傾斜狀態等,是很重 要。另外,將彎曲回復時的滯延損耗爲〇 · 〇 5 c Ν · c m / y a r η以下的單絲使用在連結線上較佳。 〇.〇3〇1^.(:111/:73]:]1以下更佳,而〇.〇1 c N . c m / y a r η以下且接近0最佳。且,單絲的直 徑D ( m m )及立體編物的厚度T q ( m m )的關係可滿足 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 565638 A7 B7 五、發明説明(β) 下式的關係較佳。 T 〇 / D ^ 2 0 在此,立體編物的厚度To(mm),是負荷49〇 P a時所測量的厚度。 本發明的立體編物,進一步提高坐時的彈力感及瞬間 的壓縮回復性,並在5 0 %壓縮的狀態下持續1分鐘後的 應力緩和率爲4 0 %以下較佳,而應力緩和率爲3 0 %以 下更佳。應力緩和率爲4 0 %以下的話,即使人坐在立體 編物上一定時間,也可以有良好的瞬間的回復性。 本發明的立體編物當作吊床式的座墊使用的情況時, 壓縮撓屈量爲1 0 m m以上8 0 m m以上的話,可以獲得 與人體的貼身感而可以獲得較佳的坐感。在這所謂的吊床 式座墊,是指藉由使立體編物的周圍或至少2邊,在座墊 框或椅子的框呈緊張狀態或鬆弛狀態下拉開,而使立體編 物呈帆的狀態形成座墊的坐部或背靠部。 又’所謂壓縮撓屈量,是將切成四角的立體編物的周 圍固定在框上,且對於立體編物的表面在直角方向施加負 荷時的立體編物的撓屈量,且決定於立體編物的表背的伸 長特性。撓屈量未滿1 0 m m的話,當人坐時的下陷量過 少,立體編物的座墊面無法貼身在人體上,而使貼身感較 硬。撓屈量超過8 0 m m的話,貼身感雖佳,但坐後會容 易發生無法回復原來形狀的彈性復原,而使形態保持性不 充分。壓縮撓量最好是1 5 m m以上7 0 m m以下,1 5 m m以上6 0 m m以下更佳。 本紙張尺度適用中國國家標準(CNS ) A4規格(210x^7^7 ---------— (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 565638 A7 B7 五、發明説明(7) (請先閱讀背面之注意事項再填寫本頁) 爲了使壓縮撓屈特性在適當的範圍內,其立體編物的 縱方向(沿著縱列的方向)及橫方向(沿著橫列的方向) 的伸長特性、及厚度方向的壓縮特性變得很重要,但本發 明的立體編物的縱方向及橫方向的伸長率爲3 %以上5 0 %以下的原因,是因爲可以獲得下陷量較多且可以提高對 人體的貼身性的吊床式座墊。5 %以上4 5 %以下更佳。 又,爲了獲得反彈感較強且坐後的彈性復原少且形態保持 性良好的吊床式座墊,立體編物的的縱方向及橫方向的伸 長率爲0 . 5%以上2 0%以下較佳。1%以上1 5%以 下更佳。 經濟部智慧財產局員工消費合作社印製 然而,立體編物伸長時的縱方向及橫方向的伸長殘留 變形,爲了減少坐在吊床式座墊後的彈性復原,最好是 1 0%以下。7%以下更佳,5%以下最佳。爲了使立體 編物的縱方向及橫方向的伸長率及伸長殘留變形在適當的 範圍內,立體編物的表背的編組織及後處理加工方法變得 很重要。表背的編組織是網目等的多孔組織的話,構成1 網目的組織数(横列数)設爲1 2横列以下較佳,後處理 加工方法是取得縦方向及横方向的伸長率的平衡,且將横 方向擴幅並熱定形較佳。表背的至少一方的編組織是非多 孔的平坦組織或凹凸組織的話,所有橫列可以使用:由針 織弧所形成的編組織、或針織弧組織及插入組織的複合組 織等。爲了在吊床式座墊獲得下陷量多且貼身性良好的緩 衝性,而將立體編物的伸長率增爲較大的話,所有橫列不 進行無形成針織弧的插入編,而在至少所有橫列的一半以 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) * 565638 A7 B7 五、發明説明(a) (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 上的橫列進行形成針織弧的編組織較佳。又,爲了在吊床 式座墊顯示具有反彈感的緩衝性,且返覆或長時間坐後的 形態保持性良好的特性,而將立體編物的伸長率減爲較少 的話,將插入線呈直線狀地插入立體編物的表背的至少一 方的針織物的縱方向及/或橫方向較佳。因爲將插入線呈 直線狀地插入縱方向及/或橫方向,使立體編物的縱方向 及/或橫方向的伸長特性,不會大大地影響表背的針織物 的組織的變形或網目形態的變形,而由插入線本身的伸長 特性所決定。也就是說,因爲人坐上,而使朝呈吊床式張 設的立體編物表面幾乎垂直的外力作用,並使立體編物的 表背的針織物伸延時,因不容易產生由組織形態或網目形 態的變形所產生的纖維間的偏離,而使返覆或長時間坐後 的形態保持性良好。在此,所謂將插入線呈直線狀地插入 表背的至少一方的針織物,當縱方向的情況時,是指在由 鎖編或經平組織編織等的組織所編成的底線的針織弧及沉 降弧之間,以每一橫列2針橫移以下的橫移寬插入的狀 態’或是指,在連結於立體編物的長度方向的地糸的沉降 弧之間上下地插入的狀態下,橫跨立體編物的全長使插入 線呈接近直線的形態下插入的狀態。又,當橫方向的情況 時,是指在由編鏈組織或經平組織編織等的組織所編成的 底線的針織弧及沉降弧之間,使橫跨立體編物的全寬地將 插入線呈接近直線形態插入的狀態。這時,使用於插入線 的纖維最好使用聚對苯二甲酸丙二醇酯纖維或聚酯系高彈 體纖維等的彈性回復性良好的纖維,若是單絲的話,最好 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ΓΤΠ ~ 565638 A7 ____B7 五、發明説明(9) (請先閱讀背面之注意事項再填寫本頁) 減少因單纖維之間的摩擦阻力所產生的伸長回復性的阻 害。又,插入線爲了防止與底線的滑動,最好由熱融合或 樹脂接點等與底線接合。 插入線的插入方法,從縱方向插入的話,可以利用編 組織插入,從橫方向插入的話,可以使用設有緯線插入裝 置的雙羅素斜紋針織機進行緯線插入。 立體編物的表背的編組織,不需要相同,雖可以是不 同的編組織、不同的伸長特性,但背側的針織物的伸長率 比表側的針織物的伸長率少的話,可以更增加人坐時的由 單絲所產生的彈力感,且對人體的貼身性良好。將插入線 朝縱方向及/又橫方向呈直線狀插入的情況時,也是插入 立體編物的背側的針織物較佳。 經濟部智慧財產局員工消費合作社印製 而且,立體編物的壓縮撓屈時的滯延損耗爲6 5 %以 下的話,當使用作吊床式座墊的情況時,因具有反彈感的 緩衝性,而較佳。6 0 %以下更佳,最好是5 0 %以下接 近0。又,立體編物的壓縮撓屈時的殘留變形量爲3 0 m m以下的話,長時間或返覆坐後彈性復原少而有助於提 高形態保持性。2 0 %以下更佳。最好是1 5 %以上接近 0 ° 爲了減少立體編物的壓縮撓屈時的滯延損耗及殘留變 形量,將構成表背纖維在0 %以上的伸長率進行伸長熱處 理的方法等,就可以達成。熱處理,可以在原線製造的階 段、或假捻、流體噴射加工等的線加工階段以欠給進行熱 處理,或也可以在針織物的階段進行伸長熱處理。在針織 本紙張尺度適用中國國家標準(CNS ) A4規格(210X:Z97公釐) 565638 A7 _____B7___ 五、發明説明(4 物進行熱處理的情況時,在寛方向5 %以上的伸長率進行 熱處理較佳。 (請先閱讀背面之注意事項再填寫本頁) 而且’本發明的立體編物,在常温下的壓縮回復率爲 9 0%以上,7 〇它氣雰下的壓縮回復率爲7 〇%以上較 佳。最好是在常溫下的壓縮回復率爲9 5 %以上,7 0 °C 氣雰下的壓縮回復率爲7 5%以上。因爲在常溫下的壓縮 回爲9 0 %以上的話,正常使用的狀態下的彈性復原少且 具有良好的緩衝性。又,因爲7 0 °C氣雰下的壓縮回復率 爲7 0 %以上的話,即使在高溫嚴酷的環境下使用後,也 可以保持良好的彈性復原少的緩衝性。 經濟部智慈財產局8工消費合作社印製 本發明的立體編物的連結線所使用的單絲,雖可以使 用:聚對苯二甲酸丙二醇酯纖維、聚對苯二甲酸丁二醇酯 纖維、聚對苯二甲酸乙二醇酯纖維、聚醯胺纖維、聚丙烯 纖維、聚氯乙烯纖維、聚酯系高彈體纖維等的任意素材的 纖維,但其中連結線的一部分使用聚對苯二甲酸丙二醇酯 纖維的話,會具有含有彈力感的緩衝性,且返覆或長時間 壓縮後的緩衝性的耐久性良好。又,使用在立體編物的表 背的針織物的纖維,若使用:聚對苯二甲酸乙二醇酯纖維、 聚對苯二甲酸丙二醇酯纖維、聚對苯二甲酸丁二醇酯纖維 等的聚酯系纖維、聚醯胺系纖維、聚丙烯系纖維、聚丙烯 系纖維等的合成纖維、綿、麻、毛等的天然纖維、銅銨人 造絲、糊膠人造絲、哩優細魯(卩3七少)等的再生纖維 等的任意的纖維的話,當將立體編物使用在吊床式座墊的 情況時,可以增大壓縮撓屈量,而使行程感、貼身感良好。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 565638 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(1)1 而且,在聚對苯二甲酸丙二醇酯纖維爲〇 %以上的伸長率 下,在原線製造、線加工、或針織物的階段進行伸長熱處 理的話,因可以壓縮撓屈時的滯延損耗及殘留變形量,而 較佳。又,針織物的情況時在5 %以上的擴幅率進行伸長 熱處理的話更佳。製造剖面形狀,也可以是圓型、三角 型、L型、T型、Y型、W型、八葉型、偏平型、夾頭型 等的多角型、多葉型、中空型或不定型。纖維的形態,也 可以採用.:未加工線、紡績線、捻線、假捻加工線、流體 噴射加工線等的任一種,復絲或單絲雖皆可,但爲了不使 連結線的單絲露出針織物表面地提高覆蓋率,最好在立體 編物的至少片側面使用復絲的假捻加工線、紡績線等的膨 鬆線。又,爲了在立體編物附與有力的伸長性或壓縮撓屈 性及回復性,最好至少在片側的針織物固定單絲。然而, 單絲爲並列等的複合線的話,更可提高伸長性及回復性。 又,立體編物以聚酯系纖維1 0 0 %構成表背線及連結線 的話,廢棄時利用分解回復至原狀,而可以再利用,且, 即使燃燒也可以防止有害氣體的發生。 在本發明中,最好使用的聚對苯二甲酸丙二醇酯纖 維,是以聚對苯二甲酸丙二醇酯單位爲主要的返覆單位的 聚酯纖維,包含聚對苯二甲酸丙二醇酯單位爲5 0莫耳% 以上者,最好是70莫耳%以上,80莫耳%更佳,9〇 莫耳%最佳。因此,第三成分是包含聚對苯二甲酸丙二醇 酯的含有他的酸成分及/或乙二醇成分的合計量爲5 0莫 耳%以下者,最好3 0莫耳%以下,2 0莫耳%更佳, (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS〉A4規格(210X 297公釐) 565638 A7 B7 五、發明説明(4 1 0莫耳%最佳。 (請先閲讀背面之注意事項再填寫本頁) 聚對苯二甲酸丙二醇酯,是將聚對苯二甲酸或其他機 能的誘導體、及三甲撐二醇或其他機能的誘導體,在有觸 媒存在的情況下,以適當的反應條件下結合而合成。此合 成過程中,也可以適當地添加一種或二種以上的第三成分 作爲共聚聚酯。個別合成聚對苯二甲酸乙二醇酯、聚對苯 二甲酸丁二醇酯等的聚對苯二甲酸丙二醇酯以外的聚酯、 耐綸及聚對苯二甲酸丙二醇酯後,也可以混合、或作成複 紡線(鞘心、並列等)。 關於複合紡線,如日本特公昭4 3 - 1 9 1 0 8號公 報、日本特開平1 1 一 1 8 9 9 2 3號公報、日本特開 2000-239927號公報、日本特開2000— 經濟部智慧財產局S工消骨合作社印製 2 5 6 9 1 8號公報等所例示的,第一成分使用聚對苯二 甲酸丙二醇酯,第二成分使用聚對苯二甲酸丙二醇酯、聚 對苯二甲酸乙二醇酯、聚對苯二甲酸丁二醇酯等的聚酯、 或耐綸,並將這些並列配置的並列型或偏心地配置的偏心 鞘心型形成複合紡線者等。特別是,聚對苯二甲酸丙二醇 酯及共聚聚對苯二甲酸丙二醇酯的組合、或極限粘度不同 的二種類的聚對苯二甲酸丙二醇酯的組合較佳,其中,如 曰本特開2 0 0 0 — 2 3 9 9 2 7號公報所例示的,使用 極限粘度不同的二種類的聚對苯二甲酸丙二醇酯,且使低 粘度側包高粘度側地使接合面形狀彎曲的並列型形成複合 紡線者,因爲兼具高度的伸長回復性,所以使用在立體編 物的表背的針織物較佳。 5 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 565638 經濟部智慈財產局員工消f合作社印製 A7 B7五、發明説明(ώ 添加的第三成分,有:脂肪族二羧(草酸、肥酸 等)、脂環族二羧(環己烷二甲酸等)、芳香族二羧(異 苯二甲酸、磺基異苯二甲酸鈉等)、脂肪族乙二醇(乙二 醇、1 ,2 -丙二醇、丁二醇等)、脂環族二羧(·環己烷 二甲醇等)、含芳香族的脂肪族二羧(1 ,4 一雙(/3 - 羧基乙氧基)苯等)、聚酯撐二醇(聚乙二醇、聚丙撐二 醇等)、脂肪族羥酸(ω -羥基己酸等)、芳香族羥酸 (Ρ —羥基苯甲酸等)等。且,具有1個或3個以上的酯 形成性官能基的化合物(苯甲酸或丙三醇等),在聚合物 爲實質的線狀的範圍內也可以使用。 而且,也可以含有:二氧化鈦等的艷消劑、磷酸等的 安定劑、羧基二苯甲酮誘導體等的紫外線吸收劑、滑石等 的結晶化核劑、阿耶羅吉魯(7工口、少)等的易滑劑、 阻滞酚誘導體等的抗氧化劑、難燃劑、制電劑、顏料、螢 光增白劑、紅外線吸收劑、消泡劑等。 聚對苯二甲酸丙二醇酯纖維的單絲,可以由日本特願 2 0 0 0 - 9 3 7 2 4號公報所記載的方法製造。也就是 說,可以由:將聚對苯二甲酸丙二醇酯從紡口吐出,並在 冷卻浴中急冷後由第1滾子捲取,接著在溫水中或乾熱氣 雰下由過給進行放鬆處理並由第3滾子捲取的方法等製 造。纖維的剖面形狀,雖可以是圓型、三角型、L型、Τ 型、Υ型、W型、八葉型、偏平型、夾頭型等的多角型、 多葉型、中空型或不定型,但爲了立體編物的緩衝性的耐 久性,圓型剖面較佳。 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) :" (請先閲讀背面之注意事項再填寫本頁) 565638 經濟部智慧財產局8工消費合作社印製 A7 _____B7五、發明説明(& 本發明的表背的針織物或連結線的單絲所使用的纖 Μ ’最好是有著色。著色方法,雖可以由:將未著色的線 &絞狀或筒狀線染的方法(先染)、紡線前的原液中混入 顏料、染料等著色的方法(原液著色)、以立體編物狀染 &或印刷的方法等著色,但以立體編物狀染色的話,不容 易維持立體形狀且加工性差,所以先染或原液著色較佳。 連結線所使用的單絲的纖度,通常,可以使用2 0〜 1 5 0 〇分特的粗細。爲了附與立體編物具有彈力感的更 佳的緩衝性,單絲的粗細爲1 〇 〇〜1 〇 〇 〇分特較佳, 2 0 0〜9 0 0分特更佳。又,表背的針織物所使用的復 絲等的纖維中,通常,可以使用5 0〜2 5 0 0的粗細, 且絲數量可以任意設定。這時,編機的針1根所需的單絲 的纖度Τ (分特)及全復絲的纖度d (分特)爲T / d ^ 〇 · 9的原因是,以復絲覆蓋單絲,防止往立體編物表面 的單絲的露出,利用單絲固有的光澤抑制立體編物表面閃 閃發光,並且,且表面的感覺良好。 本發明的立體編物,可以由具有相對的2列的針床的 編機編成,且也可以由:雙羅素斜紋針織機、雙圓型針織 機、具有V型皮帶的橫式針織機等編成,但爲了獲得尺寸 安定性佳的立體編物,最好是使用雙羅素斜紋針織機。編 機的隔距最好使用9隔距至2 8隔距。 立體編物的表背的針織物,作成4角、6角等的網目 針織物、薄紗羅針織物等的具有複數的開口部的針織物, 可以提高輕量性、通氣性,且作成表面平坦的組織也可以 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 565638 A7 B7 五、發明説明(ώ 使肌膚貼身感良好。藉由使表面起毛,可以獲得更好的肌 膚貼身感。 (請先閲讀背面之注意事項再填寫本頁) 有關連結線的密度,當將立體編物2 . 5 4 c m平方 的面積中的連結線的條數設爲N (條/ 2 · 5 4 c m平 方)、連結線的分特設爲T ( g / 1 X 1 0 6 )、連結線的 比重設爲p Q ( g / c m 3 )時,立體編物2 _ 5 4 c m平 方的面積中的連結線的總剖面積(N · T / 1 X 106 · p〇)爲 0 · 03 〜0 · 35cm2 較佳, 〇·05〜0·25更佳。藉由設定在此範圍,使立體編 物因具有適度的剛性而具有良好的緩衝性。 經濟部智慈財產局員工消費合作社印製 連結線,在表背的針織物中也可以形成弧狀的組織, 也可以是在表背針織物呈插入組織狀地拉引的構造,但使 至少2條的連結線將表背的針織物朝相互相反的方向傾斜 並呈交叉狀(X狀)或構架狀連結,是可以提高立體編物 的形態安定性而較佳。構架構造的情況時,第5圖的沿著 針織物1的橫列的切斷面所示,由2條的連結線4、4所 形成的角度0 ^爲4 0〜1 6 0度的話,立體編物的形態安 定性會增加。且,交叉構造的情況,如第6圖的沿著針織 物1的橫列的切斷面圖所示,由2條的連結線4、4所形 成的角度Θ 2爲1 5〜1 5 0度的話較佳。這時,構架構造 及交叉構造的2條連結線,皆以表或背面返折1條的同一 連結線,並表面上成爲2條的情況也可以。又2條的連結 線,不需要在同一橫列內形成構架構造或交叉構造,只要 在5橫列以內形成構架構造或交叉構造即可。 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 565638 A7 B7 五、發明説明(4 (請先閱讀背面之注意事項再填寫本頁) 1Δ ft編牧/的厚度、目付(日本織物單位面積的重 里)’雖可以依據目的任意地設定,但最好使用厚度3〜 3 ◦ m m °未滿3 m m的話,會有緩衝性不足的傾向,超 過3 0 m m的話,立體編物的最後加工會變得困難。目付 爲 150 〜30〇〇g/m2,2〇〇 〜2〇〇〇g/m2 較佳。 AL體編物的最後加工方法,當使用先染線或原液著色 線的立體編物的情況時,可以藉由精製、熱定型等的過程 後處理还布。虽連結線或表背線的任一爲未著色的立體編 物的情況時’可以藉由精製、染色、熱定型等的過程後處 理坯布。 最後加工後的立體編物,利用融合、縫製、樹脂加工 等的手段處理端部,或利用熱成形等作成預定的形狀,而 可以應用在吊床式座墊或床舖等的各種用途.。 〔最佳實施例〕 經濟部智慧財產局員工消費合作社印製 以下,雖以具體實施例說明本發明,但本發明不限定 於本實施例。 立體編物的各種物性的測量方法係如以下所述。 (1 )單絲的曲率c i : 從對於單絲所彎曲成的圓弧(半圓)的垂直方向撮影 立體編物的連結線的單絲的彎曲狀態的放大寫真。當連結 線呈傾斜狀態的情況時,配合傾斜的角度撮影。用掃描器 -19 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 565638 A7 B7___ 五、發明説明(☆ (請先閲讀背面之注意事項再填寫本頁) 將放大寫真讀入電腦,並用高精細畫像解析系統I p 1 0 0 0 P C (商品名、旭化成(株)製)的畫像解析軟 體,畫出單絲的彎曲最大處的內接圓(單絲的凹側)及外 接圓(單絲的凸側),分別算出各圓的半徑的平均値(換 算實際尺寸的値),求得對於單絲的中心線的曲率半徑r i (m m )後,由下式算出曲率。 C 1 = 1 / r 1 (2 )單絲的彎曲伸長率S ( % ): 施加4 9 0 P a的負荷並測量立體編物的厚度T 〇 ( mm),使立體編物的厚度成爲T 〇/ 2地將立體編物壓縮 成5 0 %的狀態下,從對於由單絲的彎曲所形成的圓弧 (半圓)的垂直方向撮影立體編物的連結線的單絲的彎曲 狀態的放大寫真。用掃描器將放大寫真讀入電腦,並如前 述,求得對於單絲的彎曲最大處的單絲的中心線所形成的 圓弧的曲率半徑r 2 ( m m ),由下式算出彎曲伸長率S (% ) 〇 經濟部智慧財產局員工消资合作社印製 S (%) = 5〇D/r2 但是,D爲單絲的直徑(m m )。然而,撮影5 Ο % 壓縮狀態的放大寫真時,從經5 0 %壓縮的立體編物的繞 編側的端部,撮影彎曲突出的單絲的話,也容易撮影已傾 斜的單絲。又,爲了容易撮影,也可以將立體編物的5 0 %壓縮後的狀態由樹脂硬化。 -2u- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ 297公釐) 經.濟部晳慧財產总員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(2l〇x297公釐) 56563S A? B7 克、發明説明(tb (3 ) 5 0 %壓縮回復時的滯後損耗L ( % ): 使用島津自動圖表AG - B型(島津製作所製),並 由直徑1 〇 〇 m m的圓盤狀壓縮工具,將放置在剛體面上 的1 5 c m四方、厚度T 〇 ( m m )的立體編物,以1〇 fB Hi / in i η的速度壓縮至T。/ 2的厚度,達到預定的厚 度後,馬上以1 0 m m/m i η的速度放開。 由這時所得的第7圖所示的立體編物的負荷-變形量 曲線圖,求得:去(壓縮)的曲線及變形量軸(X軸)所 形成的面積Α。( c m 2 )、及回(回復)的曲線及變形量 軸(X軸)所形成的面積A 1 ( c m 2 ),並由下式算出滯 損耗損L ( % )。 L(%) = {(A〇-Ai)/A〇}xl〇〇 (4 ) 5 0 %壓縮後的殘留變形ε ( % ): 在(3 )的方法中,壓縮·開放隨後的殘留變形ε (% )是由下式算出。 ε ( % ) = { ( Τ 〇 - Τ 1 ) / Τ 〇 } X 1 〇 〇 但是,τ 1 ( m m )是解放隨後的在4 9 0 P a的負 _下的立體編物的厚度。 (5 )壓縮撓屈量E ( m m )、壓縮撓屈時的滯延損耗Q (% )、壓縮撓屈時的殘留變形量E i ( m m ): 在4角安裝有高1 5 cm的腳的,內徑爲一邊3 Ο c: m且外徑爲一邊4 1 c m的四角形的板狀的金屬框(在 -21 - (請先閲讀背面之注意事項再填寫本頁) 訂 565638 經濟部智慧財產局8工消費合作社印製 A7 ___B7五、發明説明(A 上面貼有4 0號的砂紙而附與止滑性)及內徑爲一邊3 0 c m且外徑爲一邊4 1 c m的四角形的板狀的金屬框(在 下面貼有4 0號的砂紙而附與止滑性)之間,使立體編物 不會鬆弛地挾住,並將周圍以老虎鉗固定。 使用島津自動圖表AG - B型(島津製作所製),並 由直徑1 0 0 m m的圓盤狀壓縮工具,將已張設的立體編 物的中央部以1 0 0 m m /m i η的速度進行壓縮,達到 2 4 5 Ν的負荷後,以同速回到原位。從這時所獲得的第 7圖所示的立體編物的負荷-變形量曲線,將2 4 5 Ν負 荷時的變形量爲撓屈量E ( m m ),回復曲線的負荷成爲 0或的變形量爲殘留撓屈量E i ( m m )。又,去(壓縮) 的曲線及變形量軸(X軸)所形成的面積爲a 〇 ( cm2),回(回復)的曲線及變形量軸(X軸)所形成的 面積爲a i ( c m 2 )時,以下式算出滯延損耗Q ( % )。 Q { % ) = { (a〇-ai)/a〇}xl〇〇 (6 )伸長率I ( % )、伸長殘留變形B ( % ): 將已最後加工的立體編物切成3 0 c m X 5 c m (寬)並製作成試驗片,並在試驗片的2 0 c m的間隔劃 上記號。試驗片係採取縱方向(沿著縱列的方向)及橫方 向(沿著橫列的方向)。將試驗片的一端以夾具固定吊 起,並在另一端將3 Ο N的負荷以夾具固定吊起。5分鐘 後測量記號之間的長度L 1 ( c m ),之後除去負荷,並 測量1分鐘後的記號之間的長度L 2 ( c m ),並由下式 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X297公釐) ~ (請先閲讀背面之注意事項再填寫本頁) 565638 經濟部智慧財產局員工消費合作社印製 A7 B7 __五、發明説明(2¾ 算出伸長率、伸長殘留變形。 I ( % ) — { (LI - 2 0 )/20}xl0〇 B (%) = [ (L2- 20)/20}χ100 (7 )壓縮回復率R ( % ): 在使厚度To (mm)的立體編物成爲T。/ 2 ( m m )的5 0 %壓縮狀態下,在常溫下(2 3 土 0 · 5 % )或7 0 °C ( ± 0 · 5 °C )的氣雰下放置2 2小時。 2 2小時後放開壓縮並在常溫下放置3 〇分鐘後’在 4 9 0 P a的負荷下測量立體編物的厚度T2 ’並由下式算 出壓縮回復率R ( % )。 R (%) = (T2//T〇)x 100 (8 )返復壓縮殘留變形e ( % ): 使用泡沬橡膠返覆壓縮試驗機A型(T E S T E R產 業株式會社製),使立體編物的厚度T。(mm) 50%壓 縮成T 〇/ 2的厚度的過程返覆2 5萬次後’測量在4 9 0 P a的負荷下的厚度T 3 ( m m ),並由下式算出返覆壓縮 殘留ε ( % )。 ε ( % ) = ί ( 丁 〇 - Τ 3 ) / Τ 〇 } X 1 0 0 (9 )單絲的彎曲回復時的滯延損耗2 Η Β ( % ): 將2 6條的單絲以1 m m間隔並呈片狀地並列,並使 成爲1 1 m m的樣品長度地將單絲片的兩端的上下面介由 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) Γ2ΤΙ - (請先閲讀背面之注意事項再填寫本頁) 565638 經濟部智慧財產局員工消費合作社印製 A7 __B7五、發明説明(分 雙面膠帶以厚紙固定作爲夾住部。兩端的夾住部爲2〇 m m 長、3 0 m m 寬。 使用K E S - F B 2純彎曲試驗機(KATOTECH 製),將單絲的片狀樣品朝正及反方向彎曲至曲率2 . 5 ,並測量曲率1之彎曲回復的滯延損耗2 Η B ( c N · c m /" y a r η ) 0 (10)振動衰減性 使用加振機F — 3 00BM/A (EMIKU社 製),將1 0 c m四方的立體編物,在平板狀的加振部上 使背面朝下地放置,並從上方放置直徑1 〇 〇 m m的圓柱 狀的2 k g的砝碼。以磁石將測量輸出加速度的加速度計 (德B & K社製,4 3 7 1型)固定在加速度拾波器上部 中央,介由擴大器(德B & K社製,2 6 9 2 A〇S I ) 連接在F F T分析器(小野測器株式會社,D S 2 0 0 0 型)。± 1 m m的一定變形下,以加速度〇 _ 1 G、頻率 1〇〜2 0 0 Η z、正弦波記錄掃描的條件來測量輸出加 速度,而獲得加速度-頻率曲線。該曲線中,將加速度傳 達率(d Β )成爲最大的頻率作爲共振頻率,並求得在共 振頻率的加速度傳達率及在2 0 0 Η z的加速度傳達率。 這時,加速度傳達率越小,表示立體編物的振動衰性良 好。 (1 1 )緩衝性(彈力感) 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) :24 : ' ---------^^衣-- (請先閱讀背面之注意事項再填寫本頁) 訂 565638 A7 B7 五、發明説明(必 (請先閲讀背面之注意事項再填寫本頁) 將立體編物放置在桌上’並從上方以手指尖(3根) 輕按立體編物3次,由下列基準以感官評價彈力感。且在 返覆壓縮前後評價。 ◎:彈力感高 〇:彈力感稍高 △:彈力感低 X :幾乎無彈力感 (1 2 )吊床座墊的緩衝性(反彈感、貼身感)·· 將立體編物的周圍緊緊地縫製及螺絲固定地張設在座 部爲4 0 c m四方的四角金屬框所作成的椅子(4腳,無 背靠)的框架,由體重6 5 k g的男性1 〇次,每次5分 鐘坐著,並由◎:貼身感高、〇:貼身感稍高、△:貼身 感低、X :幾乎無貼身感的4階段,以感官評價貼身性。 (1 3 )吊床座墊的形態保持性: 經濟部智慧財產局員工消骨合作社印製 上述(1 2 )的試驗之後,由外觀評價張設在椅子的 立體編物的彈性復原狀態,且以◎:完全無彈性復原、 〇:幾乎無彈性.復原、△:稍微彈性復原、X :彈性復原 大的4階段評價。 參考例 (聚對苯二甲酸丙二醇酯單絲的製造) 實施例中所使用的聚對苯二甲酸丙二醇酯單絲,是由 本紙張尺度適用中國國家標準(CNS )八4規格(210X 297公釐) 565638 A7 --—_ _____B7 五、發明説明(七 以下方法製造。 (請先閲讀背面之注意事項再填寫本頁} 將々s p / C = 〇 · 9 2 (以〇 -氯代苯酚爲溶媒在 3 5 °C測定)的聚對苯二甲酸丙二醇酯在紡線溫度2 6 5 C下從紡口吐出後,導入4 〇它的冷卻浴中一邊冷卻一邊 由以1 6 · 〇 m / m i η的速度轉動的第1滾子群所拉引 而形成細化的未延伸單絲後,在溫度5 5艺的延伸浴中一 邊伸長至5倍一邊由以8 0 · 〇m/m i η的速度轉動的 第2滾子群所拉引,之後,在1 2 〇它的蒸氣浴中施行弛 緩熱處理,經過以7 2 · 0 m / m i η轉動的第3滾子群 後’由與第3滾子群同速的捲取機捲取,而製成2 8 0分 特的延伸單絲。也以同樣方法製造8 8 0分特的延伸單 絲。 實施例1 使用裝備有6片筘的1 8隔距且花紋間隔爲1 2 m m 的雙羅素斜紋針織機,從形成表側的針織物的3片筘( L 1 、L 2、L 3 )使1 6 7分特4 8絲的聚對苯二甲酸 經濟部智慧財產局8工消費合作社印製 丙二醇酯纖維假捻加工線(旭化成株式社製,商標r S〇R〇」假ί念加工線,黑色先染線)的任何一個皆以全 進的配列進行供給,從形成背側的針織物的2片的筘( L 5、L 6 )將3 3 4分特9 6絲的聚對苯二甲酸丙二醇 酯纖維假捻加工線(旭化成株式社製’商標「S〇R〇」 假捻加工線1 6 7分特4 8絲的黑色先染線,2條合絲) 以L 5導引中1進1出的配列,L 6導引中1出1進的配 -26 - 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) 565638 A7 _B7565638 A7 B7 V. Description of the invention () [Industrial fields of use] (Please read the precautions on the back before filling out this page) This invention is about suitable for use in automobiles, railway vehicles, etc. Cushioning materials for seat cushions of aircrafts, baby seats, strollers, furniture, office use, bedding, bedding, mattresses, cushioning materials such as cushions for preventing cushions, cushions such as pillows and sleeping pads, spacers for clothing, etc. Retaining profiles, cushioning materials, thermal insulation materials, upper cushion materials for shoes, middle cushion materials, or three-dimensional knitted fabrics such as supports or protectors. [Previous technology] The three-dimensional knitted fabric composed of the knitted fabrics on the front and back layers and the connecting lines connecting the knitted fabrics on the two layers uses the functions of cushioning, air permeability, heat retention, and body pressure dispersion, etc. Used in various buffer materials. These three-dimensional knitted fabrics are printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The monofilament is used in the connecting line forming the middle layer, and the bending elasticity of the single filament is used to provide cushioning in the thickness direction of the three-dimensional knitted fabric. A method for improving the cushioning property and compression recovery property of three-dimensional knitted fabrics is disclosed in Japanese Patent Application Laid-Open No. 1 1-2 6 9 7 4 7 in which a monofilament with good elastic recovery properties is used for the connection line to make the three-dimensional knitted fabrics more flexible. Three-dimensional knitted fabric with good compression recovery. However, because the shape of the monofilament of the connecting wire is not taken into account, cushioning properties with elasticity cannot be obtained, and when it is used over a long period of time, the elasticity or thickness may be reduced. In addition, since the elongation characteristic and the compression flexion characteristic of the knitted fabric on the front and back of the three-dimensional knitted fabric are not taken into consideration, when a hammock-type seat cushion is made, good cushioning properties cannot be obtained. In addition, Japanese Patent Laid-Open No. 2000-1 8 7 0 7 7 discloses that a three-dimensional knitted fabric is set on a seat cushion frame to be used as a hammock-type seat cushion, but the cushioning property in the case of repeated use is disclosed. The durability does not apply to the Chinese standard (CNS) A4 specification (210 × 297 male thin ") 565638 A7 ____B7 5. Description of the invention (j points. (Please read the precautions on the back before filling this page) The object of the present invention is to solve the aforementioned problems and provide a three-dimensional knitted fabric having cushioning properties including elasticity, which is not easy to damage the elasticity even after repeated use or long-term use, and has excellent cushioning durability. Specific purpose: In particular, when used in a hammock-type seat cushion, it exhibits a cushioning property with a rebound feel, and has a good personal fit, and does not return to its original shape after sitting, that is, it has less elastic recovery. Three-dimensional knitted fabric with excellent shape retention. A further object of the present invention is to provide a three-dimensional knitted fabric with high frequency vibration attenuation. [Disclosure of the Invention] The present invention is directed to a three-dimensional knitted fabric connected by a combination. The diameter and bending shape of the monofilament of the knitted fabric on the front and back of the object, the compression characteristics of the three-dimensional knitted fabric, the compression and flexion characteristics, and the structure of the three-dimensional knitted fabric composed of the fibrous material have been repeatedly studied to obtain the invention. Printed by the Consumer Cooperative of the Property Bureau. In other words, the knitted fabric 5 of the present invention is a three-dimensional knitted fabric composed of a knitted fabric on the front and back layers and a connection line of monofilaments connecting the knitted fabric on the two layers. : The curvature of the monofilament in the three-dimensional knitting is 0. 〇 1 to 1.6, the bending elongation of the monofilament at 50% compression of the three-dimensional knitted fabric is 20% or less. [Example] A three-dimensional knitted fabric for a seat cushion of the present invention will be described with reference to the drawings. Formed by circular knitting machine knitting machine, double circular knitting machine and cross knitting machine. The paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). B7 V. Description of the invention (3) In the case of knitting, the connecting line connecting the knitted fabric on the front and back must be knitted in a state bent in a certain direction. Therefore, if a force in the thickness direction is added to the three-dimensional knitted fabric, the bent connecting line will be more bent, but if the force is released, the connecting line will return to its original state. At this time, the bending and recovery of the connecting line greatly affects the cushioning property of the three-dimensional knitted fabric. The present invention is based on this knowledge. In the three-dimensional knitted fabric of the present invention, it is necessary to use a monofilament in at least a part of the connecting line connecting the two-layer knitted fabric on the front and back surfaces, and the curvature of the monofilament positioned between the knitted fabric on the front and back surfaces of the three-dimensional knitted fabric becomes 0 · 0 1 ~ 1 · 6 places are assembled into body fabrics and processed afterwards. here. The so-called curvature of the monofilament is the curvature of an arc formed by the centerline of the monofilament in the portion where the monofilament is most bent in the three-dimensional knitted fabric. FIG. 1 shows an example of the centerline 5 of the monofilament as viewed from the cut surface along the vertical line of the three-dimensional knitted fabric 1. As shown in FIG. The curvature of the monofilament is preferably 0 · 03 to 1 · 0, but more preferably 0 · 05 to 0 · 7. The curvature of the monofilament is less than 0. 〇1, if a load is applied to the thickness direction of the three-dimensional knitted fabric 1, the knitted fabric on the front surface and the knitted fabric on the back surface will be shifted toward the longitudinal direction of the three-dimensional knitted fabric (in the direction of the vertical column), and shearing may occur easily. Deformation and cushioning properties without elasticity due to large hysteresis loss during recovery. Moreover, this tendency will be further increased by repeated compression. When the curvature r i of the monofilament exceeds 1 · 6, it is difficult to cause shear deformation, but it also has cushioning properties without elasticity. The three-dimensional knitted fabric of the present invention preferably has a bending elongation of a monofilament of 50% or less when the three-dimensional knitted fabric is compressed by 50%. Less than 15% is more preferred, and less than 10% is most preferred. Here, the so-called bending elongation of the monofilament is the Chinese national standard (CNS) A4 specification (210X 297 mm 1 " (Please read the precautions on the back before filling this page) at the paper size} 565638 Ministry of Economy Printed by the Consumer Property Cooperative of the Intellectual Property Bureau A7 B7 V. Description of the invention (4) The elongation of the convex side surface of the monofilament where the monofilament has the largest bend under the condition of 50% compression of the three-dimensional knitted fabric. 1 is a cross-sectional view along a longitudinal line of the knitted fabric in a 50% compressed state, but shows an example of a convex side surface 6 where the monofilament has the largest bend. If the monofilament has a bending elongation exceeding 20%, After becoming a compressed three-dimensional knitted fabric, the residual deformation is large, and the three-dimensional knitted fabric with poor compression recovery is not able to maintain the elastic cushioning property after being returned or compressed for a long time. The bending elongation of the monofilament of the three-dimensional knitted fabric, 75% compression When it is 20% or less, 'the compression recovery and cushioning durability can be improved, and the curvature of the monofilament of the three-dimensional knitted fabric and the bending elongation of the monofilament at 50% compression are appropriately set as described above. Fan Within the range, it is necessary to optimize: the diameter of the monofilament as the three-dimensional knitted fabric 1, the weaving structure of the monofilament in the three-dimensional knitted fabric (the swing width in the width direction when the front and back knitted fabrics are connected), and the supply amount of the monofilament when knitted. 3, the post-processing direction of the three-dimensional knitted fabric (amplification rate, overfeed rate), and the monofilament after the post-processing processing into an appropriate shape. Among them, the relationship between the knitted structure of the monofilament and the thickness of the three-dimensional knitted fabric, by The connecting line connects the knitted fabric on the front and the back diagonally to the wide direction of the knitted fabric, and is post-processed with an appropriate expansion ratio. As shown in FIG. 3, the cross-sectional view along the horizontal row makes the The relationship between the thickness TQ (mm) of the three-dimensional knitted fabric 1 minus the thickness of the ground on the front and back sides Η 1 (mm) and the 50% compression of the connection line Η 2 (mm) shown in Figure 4 The reason why it is H1 / H2-0 · 55 is because it is better to make the flexural elongation at 50% compression of the three-dimensional knitted fabric 1 20%. This (Please read the precautions on the back before filling this page ) This paper size applies to China National Standard (CNS) A4 specification (210X2 97 mm) 565638 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. When the description of the invention (5), the connecting lines are long Η 1 and Η 2. As shown in Figures 3 and 4, the three-dimensional knitting 1 When viewed from the horizontal cut surface, it is the length on the outer surface of the connecting line 4 between the front knitted fabric 2 and the back knitted fabric 3, and is obtained by photographing and measuring along the horizontal cut surface. Length. When the connecting line is inclined in the horizontal direction, the inclined direction opposite to the inclined connecting line also inclines the connecting line, and it is preferable to make the connecting line into a structure or a cross structure described later. The curvature of the three-dimensional knitted fabric 0 · 0 1 ~ 1. 6,50% Compression bending elongation rate is less than 20% of the ratio of the connection lines of the monofilament, must be 20% of the total number of monofilaments connected to the front and back knitted fabric per unit area of the three-dimensional knitted fabric. % Or more, preferably 40% or more, and more preferably 60% or more. It is better if the connecting threads of the three-dimensional knitted fabric are all monofilaments, but fibers other than monofilaments may be interlaced as required. For example, interlaced multi-filament and false-twisted yarn can reduce the unpleasant sound produced by the friction between the monofilaments during compression. In order to reduce the hysteresis loss during 50% compression to more than 50%, the bending elongation of the monofilament of the connecting wire is adjusted to be more than 20%: the thickness of the three-dimensional knitted fabric, the diameter of the monofilament, and the Tilt status is important. In addition, it is preferable to use a monofilament having a hysteresis loss at the time of bending recovery of 0 ·· 5 c Ν · cm / y a r η or less on the connection line. 〇. 〇3〇1 ^. (: 111 /: 73]:] 1 or less is better, and 〇. 〇1 c N. It is best that c m / y a r η is close to 0. In addition, the relationship between the diameter D (mm) of the monofilament and the thickness T (mm) of the three-dimensional knitted fabric can be satisfied (please read the precautions on the back before filling this page) This paper size applies the Chinese National Standard (CNS) Α4 specification ( 210 × 297 mm) 565638 A7 B7 V. Description of the invention (β) The relationship of the following formula is better. T 〇 / D ^ 2 0 Here, the thickness To (mm) of the three-dimensional knitted fabric is a thickness measured at a load of 49 〇 Pa. The three-dimensional knitted fabric of the present invention further improves the feeling of elasticity and instantaneous compression recovery when sitting, and the stress relaxation rate after 40 minutes of compression for 1 minute is preferably less than 40%, and the stress relaxation rate Below 30% is better. If the stress relaxation rate is 40% or less, even if a person sits on the three-dimensional knitted fabric for a certain period of time, it can have good instantaneous recovery. When the three-dimensional knitted fabric of the present invention is used as a hammock-type seat cushion, if the compression deflection amount is 10 m m or more and 80 m m or more, a close-fitting feeling with the human body can be obtained and a better sitting feeling can be obtained. The so-called hammock-type seat cushion means that the three-dimensional knitted fabric is formed in the state of a sail by pulling the periphery or at least two sides of the three-dimensional knitted fabric in a state of tension or relaxation in the frame of the cushion or chair. The seat or backrest of a seat cushion. Also, the so-called "compressive deflection amount" refers to the amount of deflection of a three-dimensional knitted fabric when the periphery of the three-dimensional knitted fabric cut into four corners is fixed to a frame and a load is applied to the surface of the three-dimensional knitted fabric in a right angle direction. Back elongation characteristics. If the amount of flexion is less than 10 mm, the amount of sag when the person sits is too small, and the seat cushion surface of the three-dimensional knitted fabric cannot fit on the human body, which makes the fit more rigid. If the amount of flexion exceeds 80 mm, the fit will be good, but after sitting, it will be easy to recover elastically without returning to its original shape, and the shape retention will be insufficient. The compressive deflection is preferably 15 mm to 70 mm, and more preferably 15 mm to 60 mm. This paper size applies to China National Standard (CNS) A4 specifications (210x ^ 7 ^ 7 ---------— (Please read the notes on the back before filling out this page) Order the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed 565638 A7 B7 V. Description of the invention (7) (Please read the precautions on the back before filling in this page) In order to make the compression and flexure characteristics within the appropriate range, the vertical direction of the three-dimensional knitted fabric (in the direction of the vertical column) ) And lateral (direction along the horizontal direction) elongation characteristics and thickness direction compression characteristics are important, but the three-dimensional knitted fabric of the present invention has a longitudinal and lateral elongation of 3% or more and 50% or less. The reason is that it is possible to obtain a hammock-type seat cushion that has a large amount of depression and can improve the fit to the human body. It is more preferably 5% to 45%. In addition, in order to obtain a strong rebound feeling and less elastic recovery after sitting, And the shape-retaining hammock-type seat cushion, the three-dimensional knitting longitudinal and lateral elongation is 0. Above 5% and below 20% are preferred. Above 1% and below 15% are more preferred. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. However, when the three-dimensional knitted fabric is stretched, the longitudinal and lateral elongation distortions are reduced. In order to reduce the elastic recovery after sitting in a hammock-type seat cushion, it is preferably less than 10%. Below 7% is better, below 5% is best. In order to make the longitudinal and transverse elongation and residual deformation of the three-dimensional knitting within an appropriate range, the front and back knitting structure and post-processing method of the three-dimensional knitting become important. If the weave structure on the front and back is a porous structure such as a mesh, the number of structures (number of rows) constituting 1 mesh is preferably 12 or less. The post-processing method is to achieve a balance of elongation in the 縦 direction and the horizontal direction, and It is better to expand in the horizontal direction and heat set. If the knitting structure on at least one of the front and back is a non-porous flat or uneven structure, all the rows can be used: knitting structure formed by knitting arc, or knitting arc structure and composite tissue inserted into the tissue. In order to obtain a large amount of depression in the hammock-type seat cushion and a good snug cushioning property, if the elongation of the three-dimensional knitted fabric is increased, all the rows are not inserted without forming a knitting arc, but at least all the rows. Half of the paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) * 565638 A7 B7 V. Description of the invention (a) (Please read the notes on the back before filling this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs The knitting organization of the rows printed on the consumer cooperatives to form a knitting arc is better. In addition, in order to show the cushioning characteristics of the rebounding feeling in the hammock-type seat cushion and the good shape retention after repetition or sitting for a long time, if the elongation of the three-dimensional knitted fabric is reduced, the insertion line will be straight. The knitted fabric is preferably inserted in the longitudinal direction and / or lateral direction of at least one of the front and back of the three-dimensional knitted fabric. Because the insertion line is linearly inserted into the longitudinal direction and / or the transverse direction, the longitudinal and / or transverse elongation characteristics of the three-dimensional knitted fabric will not greatly affect the deformation of the knitted fabric on the front and back or the mesh shape. Deformation is determined by the elongation characteristics of the insertion wire itself. That is, because a person sits on, the external force acting almost perpendicularly to the surface of the three-dimensional knitted fabric that is laid out in a hammock, and delays the knitted fabric on the front and back of the three-dimensional knitted fabric, because it is not easy to produce a tissue shape or a mesh shape. Deformation between fibers caused by the deformation, so that the shape retention after reversing or sitting for a long time is good. Here, the knitted fabric in which the insertion thread is linearly inserted into at least one of the front and the back refers to a knitting arc and a knitting loop of a bottom thread knitted by a structure such as a lock knit or a plain weave in the longitudinal direction. Between the settlement arcs, the state is inserted with a traverse width of less than 2 stitches per row, or when the settlement arcs are inserted up and down between the settlement arcs connected to the floor of the three-dimensional knitted fabric in the longitudinal direction. The insertion line is inserted across the entire length of the three-dimensional knitted fabric so that the insertion line is close to a straight line. In the case of the horizontal direction, the knitting arc and the settling arc of the bottom line formed by a knitting organization or a plain weaving organization are used to make the insertion line span the full width of the three-dimensional knitted fabric. Inserted into a nearly linear pattern. At this time, the fiber used for the insertion thread is preferably a fiber with good elastic recovery properties such as polytrimethylene terephthalate fiber or polyester elastomer fiber. If it is a monofilament, it is best to apply the Chinese national standard to this paper size (CNS) A4 specification (210X297 mm) ΓΤΠ ~ 565638 A7 ____B7 V. Description of the invention (9) (Please read the precautions on the back before filling this page) Reduce the elongation recovery caused by the friction resistance between the single fibers Obstruction. In addition, in order to prevent slippage with the bottom thread, the insertion thread is preferably joined to the bottom thread by thermal fusion or resin contact. The insertion method of the insertion thread can be inserted in a longitudinal direction using a knitting structure, and can be inserted in a horizontal direction using a double Russell twill knitting machine equipped with a weft insertion device. The knitted structure of the front and back of the three-dimensional knitted fabric does not need to be the same. Although it can be a different knitted structure and different elongation characteristics, if the elongation of the knitted fabric on the back side is less than that of the knitted fabric on the front side, it can increase the number of people. The elasticity produced by the monofilament when sitting, and the fit to the human body is good. When the insertion thread is inserted linearly in the longitudinal direction and / or the lateral direction, it is also preferable to insert the knitted fabric on the back side of the three-dimensional knitted fabric. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. If the hysteresis loss of the three-dimensional knitted fabric is 65% or less, when it is used as a hammock-type seat cushion, it has a cushioning effect of rebound. Better. 60% or less is more preferable, and 50% or less is preferably close to 0. In addition, when the amount of residual deformation during compression flexion of the three-dimensional knitted fabric is 30 mm or less, the elastic recovery is reduced for a long time or after sitting, which contributes to improvement of form retention. Below 20% is better. It is preferable that it is more than 15% and close to 0 °. In order to reduce the hysteresis loss and residual deformation of the three-dimensional knitted fabric during compression and flexion, a method of elongating heat treatment of the elongation of the surface back fiber above 0% can be achieved. . The heat treatment may be performed by under-feeding at the stage of the original thread manufacturing, or at the thread processing stage such as false twisting, fluid jet processing, or the elongation heat treatment may be performed at the stage of the knitted fabric. The Chinese paper (CNS) A4 specification (210X: Z97 mm) is applicable to the paper size of knitting paper. 565638 A7 _____B7___ V. Description of the Invention (4) When heat treatment is performed on the paper, it is better to perform heat treatment at an elongation of 5% or more in the 寛 direction (Please read the precautions on the back before filling in this page.) Moreover, the three-dimensional knitted fabric of the present invention has a compression recovery rate of more than 90% at room temperature, and a compression recovery rate of 70% or more under its atmosphere. It is better that the compression recovery rate at room temperature is more than 95%, and the compression recovery rate at 70 ° C atmosphere is more than 75%. If the compression recovery rate is more than 90% at normal temperature, Under normal use, there is less elastic recovery and good cushioning. Moreover, if the compression recovery rate is more than 70% in a 70 ° C atmosphere, it can be maintained even after being used in a severe high temperature environment. Good elasticity and low cushioning. The monofilament used for printing the connection thread of the three-dimensional knitted fabric of the present invention by the Ministry of Economic Affairs, the Intellectual Property Office of the 8th Industrial Cooperative, can be used: polytrimethylene terephthalate fiber, benzene Butyl formate fiber, polyethylene terephthalate fiber, polyamide fiber, polypropylene fiber, polyvinyl chloride fiber, polyester elastomer fiber, etc. If polytrimethylene terephthalate fiber is used in part, it will have cushioning properties with elasticity, and the cushioning properties after repeated or long-term compression will be good. In addition, knitted fabrics used for the front and back of three-dimensional knitted fabrics If used, polyester-based fibers such as polyethylene terephthalate fibers, polytrimethylene terephthalate fibers, polybutylene terephthalate fibers, polyamide fibers, Any of synthetic fibers such as acrylic fibers, polypropylene fibers, natural fibers such as cotton, linen, and wool, copper ammonium rayon, rayon rayon, and rayon fine (卩 37 七) regenerated fibers, etc. If the three-dimensional knitted fabric is used in the case of a hammock-type cushion, the amount of compression and flexion can be increased, so that the feeling of travel and fit is good. This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 565638 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (1) 1 Moreover, at the elongation of polytrimethylene terephthalate fiber of 0% or more, If elongation heat treatment is performed at the processing or knitted fabric stage, it is preferable because the hysteresis loss and residual deformation amount at the time of flexion can be compressed. In the case of knitted fabrics, elongation heat treatment is performed at an expansion rate of 5% or more. It is better to manufacture the cross-sectional shape, which can also be round, triangular, L-shaped, T-shaped, Y-shaped, W-shaped, octave-shaped, flat-shaped, chuck-shaped, polygonal, multi-lobed, hollow, or Unshaped. The shape of the fiber can also be used. : Raw yarn, spinning yarn, twisted yarn, false twisted yarn, fluid jet yarn, etc. Although multifilament or monofilament is acceptable, the coverage of the monofilament of the connecting yarn is not increased to expose the surface of the knitted fabric. It is preferable to use a bulky thread such as a false twist processing line or a spinning line of a multifilament on at least the side of the three-dimensional knitted fabric. Further, in order to attach strong stretchability or compression flexure and recovery to the three-dimensional knitted fabric, it is preferable to fix the monofilament to the knitted fabric at least on the side of the sheet. However, when the monofilament is a composite yarn such as a juxtaposition, elongation and recovery properties can be further improved. In addition, if the three-dimensional knitted fabric is composed of 100% of polyester-based fibers, the front and back lines and connecting lines can be decomposed and restored to their original state when discarded, and can be reused, and even if burning, harmful gases can be prevented. In the present invention, the polytrimethylene terephthalate fiber which is preferably used is a polyester fiber whose main unit is the polytrimethylene terephthalate unit, and the polytrimethylene terephthalate unit is 5 Above 0 mole%, more preferably 70 mole%, more preferably 80 mole%, and most preferably 90 mole%. Therefore, the third component is a polytrimethylene terephthalate-containing acid component and / or a glycol component containing a total amount of 50 mol% or less, preferably 30 mol% or less, 20 Morse% is better, (Please read the notes on the back before filling this page) This paper size applies to Chinese national standards (CNS> A4 specification (210X 297 mm) 565638 A7 B7 V. Description of the invention (4 1 0 Mor % Is the best. (Please read the precautions on the back before filling in this page.) Polytrimethylene terephthalate is an inducer of polyterephthalic acid or other functions, and an inducer of trimethylene glycol or other functions In the presence of a catalyst, it is synthesized by combining under appropriate reaction conditions. During this synthesis, one or two or more third components can also be appropriately added as a copolyester. Individually synthesized polyparaphenylenes Polyesters other than polyethylene terephthalate such as polyethylene formate and polybutylene terephthalate, nylon, and polytrimethylene terephthalate can be mixed or made into multi-spun yarn (Sheath, juxtaposition, etc.) About Synthetic yarns, such as Japanese Patent Publication No. 4 3-1 9 1 08, Japanese Patent Application No. 1 1 1 9 9 2 3, Japanese Patent Application No. 2000-239927, Japanese Patent Application No. 2000-Ministry of Economic Affairs Printed by the Intellectual Property Bureau S Industrial Bone Cooperative Co., Ltd. and published in Bulletin No. 2 5 6 9 1 8 etc., the first component uses polytrimethylene terephthalate, and the second component uses polytrimethylene terephthalate, polyparaphenylene Polyesters such as ethylene dicarboxylate and polybutylene terephthalate, or nylon, and these are formed in a side-by-side arrangement or an eccentric sheath-centered arrangement that is eccentrically arranged to form a composite yarn. Yes, a combination of a polytrimethylene terephthalate and a copolymerized polytrimethylene terephthalate, or a combination of two types of polytrimethylene terephthalates having different limiting viscosities is preferable, such as Japanese Patent Application Laid-Open No. 20 0 0 — 2 3 9 9 2 7 illustrates the use of two types of poly (trimethylene terephthalate) having different limiting viscosities, and a low-viscosity side and a high-viscosity side are formed to form a side-by-side curved shape of the joint surface. Composite spinner, because it has a high degree of elongation recovery It is better to use knitted fabric on the back of the three-dimensional knitted fabric. 5-This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 565638 Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the cooperative A7 B7 V. Description of the Invention (The third ingredient added to the formula includes: aliphatic dicarboxylic acid (oxalic acid, fatty acid, etc.), alicyclic dicarboxylic acid (cyclohexanedicarboxylic acid, etc.), aromatic dicarboxylic acid (isophthalic acid, isophthalic acid, Sodium sulfoisophthalate, etc.), aliphatic ethylene glycol (ethylene glycol, 1,2-propylene glycol, butanediol, etc.), cycloaliphatic dicarboxylic acid (· cyclohexanedimethanol, etc.), aromatic-containing Aliphatic dicarboxylates (1, 4-bis (/ 3-carboxyethoxy) benzene, etc.), polyester diols (polyethylene glycol, polypropylene glycol, etc.), aliphatic hydroxy acids (ω-hydroxyhexane Acids, etc.), aromatic hydroxy acids (P-hydroxybenzoic acid, etc.), etc. In addition, a compound (such as benzoic acid, glycerol, etc.) having one or three or more ester-forming functional groups can also be used within the range where the polymer is substantially linear. In addition, it may contain a brightening agent such as titanium dioxide, a stabilizer such as phosphoric acid, an ultraviolet absorber such as a carboxybenzophenone inducer, a crystallization nucleating agent such as talc, Ayelogiru (7 gong, Less) and other slip agents, anti-oxidants such as block phenol inducers, flame retardants, electricity-generating agents, pigments, fluorescent whitening agents, infrared absorbers, defoamers, etc. The monofilament of the polytrimethylene terephthalate fiber can be produced by the method described in Japanese Patent Application No. 2000- 9 3 74 2. That is to say, the polytrimethylene terephthalate can be discharged from the spinning mouth, and then rapidly cooled in a cooling bath, and then taken up by the first roller, and then subjected to relaxation treatment in warm water or dry heat atmosphere. Manufactured by the third roller winding method. The cross-sectional shape of the fiber can be round, triangular, L-shaped, T-shaped, W-shaped, W-shaped, octave-shaped, flat-shaped, chuck-shaped, polygonal, multi-lobed, hollow, or indefinite. However, for the cushioning durability of the three-dimensional knitted fabric, a circular cross section is preferred. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm): " (Please read the precautions on the back before filling out this page) 565638 Printed by A7 _____B7, Intellectual Property Bureau, Ministry of Economic Affairs Explanation (& The fiber M ′ used for the monofilament of the front and back knitted fabrics or connecting threads of the present invention is preferably colored. Although the coloring method may include: uncolored threads & twisted or cylindrical threads Dyeing method (first dyeing), dyeing method by mixing pigments and dyes into the original solution before spinning (coloring of the original solution), dyeing with three-dimensional knitting & printing method, etc., but dyeing with three-dimensional knitting It is easy to maintain the three-dimensional shape and the processability is poor, so it is better to dye first or the original solution. The fineness of the monofilament used for the connection line can usually be 20 ~ 150 dtex thickness. In order to attach the three-dimensional knitted fabric with elasticity For better cushioning properties, the thickness of the monofilament is preferably 1,000 to 10,000 dtex, and more preferably 2000 to 900 dtex. Also, the multifilament used for the front and back knitted fabrics And other fibers, usually, The thickness is from 50 to 2 500, and the number of filaments can be arbitrarily set. At this time, the fineness T (dtex) of the monofilament and the fineness d (dtex) of the full multifilament are required for one needle of the knitting machine. The reason for T / d ^ 0.9 is that the monofilament is covered with multifilament, preventing the exposure of the monofilament to the surface of the three-dimensional knitted fabric, and the inherent luster of the monofilament is used to suppress the glittering of the surface of the three-dimensional knitted fabric. The three-dimensional knitted fabric of the present invention may be knitted by a knitting machine having two rows of needle beds opposite to each other, and may also be knitted by a double Russell twill knitting machine, a double circular knitting machine, a horizontal knitting machine with a V-belt, and the like. However, in order to obtain a three-dimensional knitted fabric with good dimensional stability, it is best to use a double Russell twill knitting machine. The spacing of the knitting machine is preferably 9 to 28. The knitted fabric on the back of the three-dimensional knitted fabric is made into 4 Knitted fabrics with multiple openings, such as mesh knits and six-cornered knit fabrics, can be used to improve lightweight and air permeability, and to make flat surface tissues (please read the note on the back first) Please fill in this page for more details) Applicable to China National Standard (CNS) A4 specification (210 × 297 mm) 565638 A7 B7 V. Description of the invention (Free skin makes the skin feel good. By raising the surface, you can get a better skin skin feel. (Please read the back first Note for this page, please fill in this page) For the density of the connection line, when the three-dimensional knitting 2. The number of connecting lines in an area of 5 4 cm square is set to N (bar / 2 · 5 4 cm square), the decitex of the connecting line is set to T (g / 1 X 1 0 6), and the specific gravity of the connecting line is set to In the case of p Q (g / cm 3), the total cross-sectional area (N · T / 1 X 106 · p〇) of the connecting lines in the area of the three-dimensional knitted 2-5 4 cm square is preferably 0 · 03 ~ 0 · 35 cm 2 , 〇05 ~ 0 · 25 is more preferable. By setting it within this range, the three-dimensional knitted fabric has good cushioning properties due to its moderate rigidity. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the connection line can also form an arcuate structure on the front and back knitted fabrics, and it can also be a structure that is pulled in by inserting the organization on the front and back knitted fabrics. The two connecting lines connect the knitted fabric on the front and back sides in opposite directions and are connected in a cross shape (X shape) or a frame shape, which can improve the shape stability of the three-dimensional knitted fabric and is preferable. In the case of a frame structure, as shown in the cross section of the knitted fabric 1 in FIG. 5, the angle 0 ^ formed by the two connecting lines 4 and 4 is 4 0 to 16 0 degrees, Morphological stability of three-dimensional knitting will increase. In the case of the cross structure, as shown in the cross-sectional view taken along the course of the knitted fabric 1 in FIG. 6, the angle θ 2 formed by the two connecting lines 4 and 4 is 1 5 to 1 5 0 Degree is better. In this case, the two connection lines of the frame structure and the cross structure may be folded back on the same connection line on the front or back, and may be two on the surface. The two connecting lines do not need to form a frame structure or a cross structure in the same row, but only need to form a frame structure or a cross structure within 5 rows. -This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 565638 A7 B7 V. Description of the invention (4 (Please read the precautions on the back before filling this page) The weight per unit area of Japanese fabric) 'Although it can be set arbitrarily according to the purpose, it is best to use a thickness of 3 ~ 3 ◦ mm ° less than 3 mm, there will be a tendency to lack cushioning. If it exceeds 30 mm, the three-dimensional knitted fabric's The final processing will become difficult. The net payment is 150 ~ 300g / m2, and 2000 ~ 2000g / m2 is preferred. The final processing method of AL body fabrics, when using the first dyeing line or the original liquid coloring line In the case of three-dimensional knitting, it can be post-processed by processes such as refining and heat setting. Although either the connection line or the front and back lines are uncolored three-dimensional knitting, it can be refined, dyed, and heat-set. After the process, the gray fabric is processed. The final processed three-dimensional knitted fabric can be processed into a predetermined shape by fusion, sewing, resin processing, etc., or thermoformed, and can be applied to a hammock-type cushion or bed. And other various applications. . [Best embodiment] Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Although the present invention will be described with reference to specific embodiments, the present invention is not limited to this embodiment. The measurement methods of various physical properties of the three-dimensional knitted fabric are as follows. (1) Curvature c i of the monofilament: A magnified photo of the bending state of the monofilament of the connection line of the three-dimensional knitted fabric from the vertical direction of the arc (semicircle) formed by the monofilament. When the connection line is inclined, take a picture with the angle of inclination. Scanner-19-This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 565638 A7 B7___ 5. Description of the invention (☆ (Please read the precautions on the back before filling this page) Read the enlarged photo into Computer and high-resolution image analysis system I p 1 0 0 0 PC (trade name, manufactured by Asahi Kasei Co., Ltd.) image analysis software to draw the inscribed circle (the concave side of the monofilament) where the maximum bending of the monofilament and The circumscribed circle (convex side of the monofilament) is respectively calculated as the average 値 (converted to the actual size) of the radius of each circle, and the curvature radius ri (mm) of the centerline of the monofilament is obtained, and then the curvature is calculated by the following formula. C 1 = 1 / r 1 (2) Bending elongation S (%) of the monofilament: A load of 4 9 0 P a is applied and the thickness of the three-dimensional knitted fabric is measured T 〇 (mm), so that the thickness of the three-dimensional knitted fabric becomes T 〇 / In a state where the three-dimensional knitted fabric is compressed to 50% in two places, an enlarged photo of the bending state of the monofilament of the connection line of the three-dimensional knitted fabric is taken from a vertical direction with respect to an arc (semicircle) formed by the bending of the monofilament. Scan The device reads the enlarged photo into the computer, and finds it as described above. For the radius of curvature r 2 (mm) of the arc formed by the centerline of the monofilament where the monofilament is at its maximum bend, the bending elongation S (%) is calculated from the following formula. S (%) = 5〇D / r2 However, D is the diameter (mm) of the monofilament. However, when taking an enlarged photo of a 50% compressed state, the end of the three-dimensional knitted compressed by 50% compression is taken from the end It is also easy to take pictures of tilted monofilaments when taking pictures of bent monofilaments. For easy photographing, the 50% compressed state of the three-dimensional knitted fabric can also be hardened by resin. -2u- This paper size applies to China National Standard (CNS) Α4 specification (210 × 297 mm). The paper size printed by the General Staff Consumer Cooperative of the Ministry of Economic Affairs of China is based on the Chinese National Standard (CNS) A4 (210x297 mm) 56563S A? B7 grams, the invention description (tb (3) 50% compression Hysteresis loss L (%): Using Shimadzu Auto Chart AG-B (manufactured by Shimadzu Corporation) and a disc-shaped compression tool with a diameter of 100 mm, a 15 cm square and a thickness T 〇 placed on a rigid surface (mm) of the three-dimensional knitted fabric, compressed at a speed of 10fB Hi / in i η to T. / 2 thickness, after reaching a predetermined thickness, immediately released at a speed of 10 mm / mi η. The load-deformation curve of the three-dimensional knitted fabric shown in Fig. 7 is obtained: the area A formed by the (compressed) curve and the deformation axis (X-axis) (cm 2), and the return (recovery) The area A 1 (cm 2) formed by the curve and the deformation axis (X-axis), and the hysteresis loss L (%) is calculated from the following formula: L (%) = {(A〇-Ai) / A〇} xl 〇〇 (4) Residual deformation ε (%) after 50% compression: In the method of (3), the residual deformation ε (%) after compression and opening is given by Ε (%) = {(T0-T1) / T0} X 1 〇〇 However, τ 1 (mm) is the thickness of the subsequent three-dimensional knitting under the negative _ of 4 900 Pa. (5) Compression deflection E (mm), hysteresis loss Q (%) during compression deflection, residual deformation E i (mm) during compression deflection: feet with a height of 15 cm are installed at the 4 corners A rectangular plate-shaped metal frame with an inner diameter of 3 Ο c: m and an outer diameter of 4 1 cm on one side (at -21-(Please read the precautions on the back before filling this page) Order 565638 Ministry of Economic Affairs Wisdom A7 printed by the Industrial and Commercial Cooperative of the Property Bureau ___B7 V. Description of the invention (A is affixed with No. 40 sandpaper attached with slip resistance) and a quadrilateral with an inner diameter of 30 cm and an outer diameter of 41 cm A plate-shaped metal frame (40-size sandpaper is attached below to prevent slippage), so that the three-dimensional knitted fabric is not held loosely, and the surrounding area is fixed with a vise. Use Shimadzu automatic chart AG-B type (Made by Shimadzu Corporation), and a disc-shaped compression tool with a diameter of 100 mm was used to perform the center of the three-dimensional knitted fabric at a speed of 100 mm / mi Compression, after reaching a load of 2 4 5 Ν, return to the original position at the same speed. From the load-deformation curve of the three-dimensional knitted fabric shown in Figure 7 obtained at this time, the deformation amount at the load of 2 4 5 Ν is The deflection amount E (mm), and the amount of deformation of the load on the recovery curve is 0 or the residual deflection amount Ei (mm). In addition, the area formed by the (compressed) curve and the amount of deformation axis (X axis) is a 0 (cm2), and the area formed by the return (recovery) curve and the amount of deformation axis (X axis) is ai (cm 2 ), The hysteresis loss Q (%) is calculated by the following formula. Q {%) = {(a〇-ai) / a〇} x100 (6) elongation I (%), residual deformation elongation B (%): cut the three-dimensional knitted fabric that has been processed into 30 cm X 5 cm (width) and make test pieces, and mark the test pieces at 20 cm intervals. The test pieces were taken in the vertical direction (direction along the vertical line) and the horizontal direction (direction along the horizontal line). One end of the test piece was fixed by a fixture, and a load of 30 N was fixed by a fixture at the other end. After 5 minutes, measure the length L 1 (cm) between the marks, then remove the load, and measure the length L 2 (cm) between the marks after 1 minute, and use the following formula. The paper size applies the Chinese National Standard (CNS) A4 specifications (210 X297 mm) ~ (Please read the precautions on the back before filling out this page) 565638 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 __V. Description of the invention (2¾ Calculate the elongation and residual deformation of elongation I (%) — {(LI-2 0) / 20} xl0〇B (%) = [(L2- 20) / 20} χ100 (7) Compression recovery rate R (%): After making the thickness To (mm ) The three-dimensional knitting becomes T. / 2 (mm) in a 50% compressed state, and placed in an atmosphere at normal temperature (2 3 soil 0 · 5%) or 7 0 ° C (± 0 · 5 ° C) 2 2 hours. After 2 hours, release the compression and leave it at room temperature for 30 minutes. 'Measure the thickness T2 of the three-dimensional knitted fabric under a load of 4 900 Pa and calculate the compression recovery rate R (%) from the following formula. R (%) = (T2 // T〇) x 100 (8) Residual compression residual deformation e (%): Foam rubber recompression compression tester type A (manufactured by TESTER Industries, Ltd.) Degree T. (mm) The process of 50% compression to a thickness of T 〇 / 2 is returned after 250,000 times. 'The thickness T 3 (mm) under a load of 490 Pa is measured, and the return is calculated by the following formula. Overlay compression residual ε (%). Ε (%) = ί (丁 〇-Τ 3) / Τ 〇} X 1 0 0 (9) Hysteresis loss during bending recovery of a monofilament 2 Η Β (%): will 2 6 monofilaments are juxtaposed in a sheet shape at 1 mm intervals, and the sample length is 11 mm. The upper and lower ends of both ends of the monofilament sheet are applied to the Chinese National Standard (CNS) A4 specification through this paper size ( 210X297 mm) Γ2ΤΙ-(Please read the notes on the back before filling out this page) 565638 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 __B7 V. Description of the invention (Double-sided tape is fixed with thick paper as the clamping part. Two The clamping portion at the end is 20 mm long and 30 mm wide. Using a KES-FB 2 pure bending tester (made by KATOTECH), the sheet-like sample of the monofilament is bent to a curvature of 2. 5 and measure the hysteresis loss of the bending recovery of the curvature 1 2 Η B (c N · cm / " yar η) 0 (10) Vibration attenuation using a vibration booster F — 3 00BM / A (made by EMIKU), A 10 cm square three-dimensional knitted fabric was placed on a flat plate-shaped vibration part with its back face down, and a cylindrical 2 kg weight with a diameter of 100 mm was placed from above. An accelerometer (manufactured by De B & K, 4 3 7 1) measuring the output acceleration with a magnet is fixed at the center of the upper part of the acceleration pickup, and an amplifier (manufactured by De B & K, 2 6 9 2) A〇SI) is connected to the FFT analyzer (Ono Koki Co., Ltd. DS 2000 Model). Under a certain deformation of ± 1 mm, the acceleration of the output is measured under the conditions of acceleration _ 1 G, frequency 10 ~ 2 0 0 Η z, and sine wave recording scan to obtain the acceleration-frequency curve. In this curve, the frequency at which the acceleration transmission rate (d B) becomes the maximum is used as the resonance frequency, and the acceleration transmission rate at the resonance frequency and the acceleration transmission rate at 2 0 Η z are obtained. In this case, the smaller the acceleration transmission rate, the better the vibration attenuation of the three-dimensional knitted fabric. (1 1) Buffering (elasticity) This paper size applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm): 24: '--------- ^^ 衣-(Please read the back first Please fill in this page before ordering) Order 565638 A7 B7 V. Description of the invention (must (please read the notes on the back before filling this page) Place the three-dimensional knitting on the table 'and use your fingertips (3) from above Three-dimensional knitting was performed three times, and the elasticity was evaluated sensory by the following criteria. It was evaluated before and after compression. ◎: High elasticity. 0: A little higher elasticity. △: Low elasticity. X: Almost no elasticity. (1 2) Hammock Cushion cushioning (rebound, close-fitting feeling) ·· A chair made of a four-corner metal frame with a 40 cm square seat and tightly sewn around the three-dimensional knitted fabric and screwed up. (Reliable) frame, made by a male with a weight of 65 kg 10 times, sitting for 5 minutes each time, and by ◎: high fitting, 〇: slightly higher fitting, △: low fitting, X: almost no fitting The four stages of evaluation are based on sensory evaluation. (1 3) The shape retention of the hammock cushion: Intellectual property of the Ministry of Economic Affairs Status dimensional knitted elastic recovery after bone cooperative employees elimination test print (12) above, evaluation by a stretched appearance of the chair, and at ◎: completely inelastic restored ○: almost inelastic. Recovery, △: Slightly elastic recovery, X: Elastic recovery. Four-stage evaluation. Reference example (manufacturing of poly (trimethylene terephthalate) monofilament) The poly (trimethylene terephthalate) monofilament used in the examples is based on this paper and applies the Chinese National Standard (CNS) 8-4 (210X 297 mm) ) 565638 A7 ---_ _____B7 5. Description of the invention (manufactured by the following methods. (Please read the notes on the back before filling out this page) 々sp / C = 〇 · 9 2 (with 〇-chlorophenol as the solvent Polytrimethylene terephthalate (measured at 35 ° C) was ejected from the spun end at a spinning temperature of 2 65 ° C, and then introduced into a cooling bath of 40 ° C while cooling at 16 ° m / mi. After being drawn by the first roller group rotating at a speed of η to form a fine unstretched monofilament, it was stretched to 5 times in an extension bath at a temperature of 55 ° C, and the temperature was increased by 80 ·· m / mi η. The second roller group rotating at a speed is pulled, and then a relaxation heat treatment is performed in a steam bath of 120. After passing through the third roller group rotating at 7 2 · 0 m / mi η, The roller group is wound at the same speed by a winder to form an extended monofilament of 280 dtex. The same method is used to produce 880 Example 1 Using a double Russell twill knitting machine equipped with a 18-gauge, 6-gauge, and 12-mm pattern interval, 3 front-side knitted fabrics (L 1, L 2 , L 3) Printed propylene glycol fiber false twisting processing line (manufactured by Asahi Kasei Co., Ltd., with the trademark r S〇R〇) to make 167 dtex 4 8 filaments of polyterephthalic acid. Any one of the false processing lines, black first dyeing lines) is supplied in a full-feed arrangement, and 3 3 4 dtex 9 6 will be supplied from the two pieces of 筘 (L 5, L 6) forming the knitted fabric on the back side. Polypropylene terephthalate fiber false twist processing line (Asahi Kasei Co., Ltd.'s trademark "SOR0" false twist processing line 1 6 7 dtex 4 8 black black dyed yarn, 2 plied yarns) Alignment of 1 in 1 out in L 5 guidance, -26 in 1 out of 1 guidance in L 6-This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 565638 A7 _B7
五、發明説明(A 列進行供給,從形成連結線的L 4的筘將以參考例製造的 2 8 0分特的聚對苯二甲酸丙二醇酯單絲(直徑〇 . 1 6 m m )以全進的配例進行供給。在以下所示的編組織中, 以打入1 5橫列/ 2 _ 5 4 c m的密度編成立體編物的还 布。將所獲得的坯布2 0 %擴幅以1 5 0 °C X 2 m i η乾 熱定型,並使表側的針織物以平坦的組織,且使背側的針 織物以網目組織,使全連結線從與表側的針織物的組織相 對的背側的組織將相隔3縱列的組織傾斜地連結,而獲得 形成X構造的立體編物。表1係顯示所獲得的立體編物的 諸物性。 (編組織) L1 :2322/1011/ L2 :1011/2322/ L3 : 1000/0111/ L4 : 1043/6734/ L5:2210/1123/ L6:2232/1101/ 實施例2 將由參考例所製造的2 8 0分特的聚對苯二甲酸丙二 醇酯單絲更經過以3 %的過給率且乾熱1 6 0 °C的溫度連 續弛緩熱處理。所獲得的聚對苯二甲酸丙二醇酯單絲之彎 曲回復時滯延損耗爲0 . 0 0 2 c N . c m/ y a r η。 - ---------衣— (請先閱讀背面之注意事項再填寫本頁) -訂 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X297公釐) 565638 Α7 Β7 經濟部智慧財產局員工消費合作社印製 五、發明説明(4 除了從形成連結線的L 4的筘所供給的之外,令此單 絲與實施例1同樣,獲得如表1所示的諸物性的立體編 物。 實施例3 在實施例1中,除了從形成表側的針織物的3片的筘 (L 1、L 2、L 3 )供給1 6 7分特4 8絲的聚對苯二 甲酸丙二醇酯纖維假捻加工線(旭化成株會社製,黑色先 染線),且從形成背側的針織物的2片的筘(L 5、 L 6 )供給3 3 4分特9 6絲的聚對苯二甲酸丙二醇酯纖 維假捻加工線(旭化成株式會社製聚對苯二甲酸丙二醇酯 纖維假捻加工線1 6 7分特4 8絲的黑色先染線,2條合 絲)之外,與實施例1同樣地編成立體編物的坯布。將所 獲得的坯布1 2 %擴幅並以1 5 0 °C X 2 m i η乾熱定 型,而獲得如表1所示的諸物性的立體編物。 實施例4 將2 8 0分特的聚對苯二甲酸丙二醇酯單絲(旭化成 株式會社製),與實施例2同樣地進行連續弛緩熱處理, 而獲得彎曲回復時的滯延損耗爲0 . 〇 2 5 c Ν · c m / y a r η的單絲。 除了從形成連結線的L 4的筘所供給的之外,令此單 絲與實施例3同樣,獲得如表1所示的諸物性的立體編 物0 ---------^^衣-- (請先閱讀背面之注意事項再填寫本頁) 訂 本紙張尺度適用中國國家標準(CNS ) Α4規格(210 X 297公釐) -Zb - 565638 A7 ____ _B7 五、發明説明(全 實施例5 (請先閱讀背面之注意事項再填寫本頁) 使用裝備了 6片筘的9隔距,花紋間隔爲1 3 m m的 雙羅素斜紋針織機,從形成表側的針織物的3片的筘( 經濟部智慧財產局員工消費合作社印製 L 1、L 2、L 3 )任何一條以全進供給3 3 4分特9 6 絲的聚對苯二甲酸丙二醇酯纖維假捻加工線(旭化成株會 社製的聚對苯二甲酸丙二醇酯假捻加工線1 6 7分特4 8 絲的黑色先染線,2條合絲),並從形成背側的針織物的 2片的筘(L 5、L 6 )將1 0 0 2分特2 8 8絲的聚對 苯二甲酸丙二醇酯纖維假捻加工線(旭化成株式會社聚對 苯二甲酸丙二醇酯纖維假捻加工線1 6 7分特4 8絲的黑 色先染線,6條合絲),在L 5導引中以1進1出的配 列’在L 6導引中以1出1進的配例進行供給,並從形成 連結線的L 4的筘將由參考例製造的8 8 0分特的聚對苯 二甲酸丙二醇酯單絲(直徑〇 . 2 9 m m )以全進的配列 進行供給。將連結線變更成以下之外,由與實施例1同樣 的編組織’以緯密1 〇橫列/ 2 · 5 4 c m的密度編成立 體編物的坯布。將所獲得的坯布1 〇 %擴幅以1 5 0 °C X 2 m i η乾熱定型,使全連結線從與表側的針織物的組織 相對的背側的組織隔有2縱列的組織傾斜連結,而獲得形 成X構造的立體編物。所獲得的立體編物的諸物性如表1 所示。 (編組織) 本紙張尺度適财關家辟((:叫44祕(21(^297公釐) 565638 A7 B7 五、發明説明(如 L4 : 1032/4523/ (請先閱讀背面之注意事項再填寫本頁) 實施例6 將雙羅素斜紋針織機的花紋間隔設成5 m m,並將連 結線的編組織如以下變更,除了使全連結線從與表側的針 織物的組織相對的背側的組織隔有2縱列的組織傾斜連結 而形成X構造之外,與實施例3同樣地獲得的立體編物的 諸物性如表1所示。 (編組織) L4 · 1032/4523/ 實施例7 除了在達結線使用與實施例4同樣的2 8 0分特的聚 對苯二甲酸丙二醇酯的連續弛緩熱處理線之外,與實施例 6同樣地獲得的立體編物的諸物性如表1所示。 經濟部智慧財產局員工消費合作社印製 實施例8 除了將立體編物的坯布的最後加工方法2 5 %擴幅乾 熱定型之外,與實施例1同樣地獲得的立體編物的諸物性 如表1所示。 實施例9 除了將立體編物的坯布的最後加工方法不擴幅而以原 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 565638 A7 _ B7_ 五、發明説明(如 有寬度乾熱定型之外’與實施例3同樣地獲得的立體編物 的諸物性和表1所示。 實施例1 0 除了將立體編物的坯布的最後加工方法不擴幅而以原 有寬度乾熱定型之外,與實施例1同樣地獲得的立體編物 的諸物性和表1所示。 實施例1 1 使用9隔距、花紋間隔1 3 m m且裝備有7片的筘及 緯線插入裝置的雙羅素斜紋針織機,從形成表側的針織物 的2片的筘(L 1、L 2 )將1 0 0 2分特2 8 8絲聚對 苯二甲酸丙二醇酯纖維假捻加工線(旭化成株會社製聚對 苯二甲酸丙二醇酯纖維假捻加工線1 6 7分特4 8絲的黑 色先染線,6條合絲),在L 1導引中以2進2出的配 列’且在L 2導引中2出2進的配列地進行供給,且形成 背側的針織物的3片的筘(L 5、L 6、L 7 )之中,以 全進的配列從L 5、L 7導引供給5 0 1分特1 4 4絲聚 對苯二甲酸丙二醇酯纖維假捻加工線(旭化成株會社製聚 對苯二甲酸丙二醇酯纖維假捻加工線1 6 7分特4 8絲的 黑色先染線,3條合絲),從L 6導引供給2 0 0 4分特 5 7 6絲的聚對苯二甲酸丙二醇酯纖維假捻加工線(旭化 成株會社製,商標「S〇R〇」假捻加工線1 6 7分特 4 8的黑色先染線,1 2條合絲),且從形成連結線的2 -3T- '-- I-------^^衣-- (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 565638 Α7 Β7 五、發明説明(如 片的筘(L 3、L 4 )將由參考例製造的8 8 0分特的聚 對苯二曱酸丙二醇酯單絲,在L 3中以2進2出的配列, 在L 4導引中以2出2進的配列進行供給。在以下所示的 編組織中將插入線(L 6 )朝背側的針織物的縱方向插 入,且在背側的針織物的各橫列中緯線插入2 0 0 4分特 5 7 6絲的聚對苯二甲酸丙二醇酯纖維(旭化成株會社 製,商標「S〇R〇」假捻加工線1 6 7分特5 8絲的黑 色先染線,1 2條合捻線),並以緯密1 2橫列/ 2 · 5 4 c m的密度編成立體編物的坯布。將獲得的坯布 以原有寬1 5 0 °C X 2 m i η乾熱定型,使插入線插入背 側的縱方向及橫方向,且使全連結線傾斜連結從與表側的 針織物的組織相對的背側的組織隔有2縱列的組織,而獲 得形成X構造的立體編物。所獲得的立體編物的諸物性如 表1所示。且,評價立體編物的壓縮撓屈特性時,使橫方 向的插入線不會滑動地熔合立體編物的試驗片的周圍。 I--------^^衣-- (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局S工消費合作社印製 織 1 組 L 編V. Description of the invention (Supply in row A, from the L 4 形成 forming the connection line, the polytrimethylene terephthalate monofilament (diameter 0.16 mm) manufactured in the reference example will be used in full In the knitting organization shown below, the cloth was knitted with a density of 15 rows / 2 _ 5 4 cm into a knitting fabric. The obtained grey fabric was expanded by 20% to 1 5 0 ° CX 2 mi η dry heat setting, make the knitted fabric on the front side have a flat structure, and the knitted fabric on the back side with a mesh structure, so that the full connection line is from the back side opposite to the structure of the knitted fabric on the front side. Tissues are arranged at an interval of 3 vertical rows to obtain three-dimensional knits that form an X structure. Table 1 shows the physical properties of the three-dimensional knits obtained. (Knitting structure) L1: 2232/1011 / L2: 1011/2322 / L3 : 1000/0111 / L4: 1043/6734 / L5: 2210/1123 / L6: 2232/1101 / Example 2 The 280-dtex polytrimethylene terephthalate monofilament manufactured by the reference example was further passed through Continuous relaxation heat treatment at an overfeed rate of 3% and a dry heat of 160 ° C. The obtained poly (trimethylene terephthalate) The hysteresis loss of the monofilament is 0. 0 0 2 c N. Cm / yar η.---------- 衣 — (Please read the precautions on the back before filling this page)-Order Printed by the Intellectual Property Bureau of the Ministry of Economy ’s Consumer Cooperatives The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X297 mm) 565638 Α7 Β7 Printed by the Intellectual Property Bureau ’s Employees ’Cooperatives of the Ministry of Economic Affairs Except for the supply of L 4 of the connecting wire, this monofilament was made the same as in Example 1 to obtain three-dimensional knitted fabrics with various properties as shown in Table 1. Example 3 In Example 1, except that the surface side Three pieces of reeds (L 1, L 2, L 3) of knitted fabrics are supplied with 1 6.7 dtex 4 8 filaments of polytrimethylene terephthalate fiber false twist processing line (manufactured by Asahi Kasei Co., Ltd., black dyeing thread) 3, 4 dtex, 9 6 filaments of polytrimethylene terephthalate fiber false twist processing line (Poly pair manufactured by Asahi Kasei Co., Ltd.) was supplied from two reeds (L 5, L 6) forming the back knitted fabric. Polypropylene terephthalate fiber false twist processing line 1 6 7 dtex 4 8 silk black first dyed yarn, 2 plied yarns) In addition, a grey fabric was knitted into a fabric in the same manner as in Example 1. The obtained grey fabric was expanded by 12% and dried at 150 ° CX 2 mi η to obtain a three-dimensional physical property as shown in Table 1. Example 4 Polytetramethylene terephthalate monofilament (manufactured by Asahi Kasei Co., Ltd.) of 280 dtex was subjected to continuous relaxation heat treatment in the same manner as in Example 2 to obtain a hysteresis loss at the time of bending recovery. 〇 2 5 c Ν · cm / yar η monofilament. This monofilament was obtained in the same manner as in Example 3, except that it was supplied from 筘, which forms the connection line. The three-dimensional knitted fabric of various physical properties shown in Table 1 was obtained. 0 --------- ^^ Clothing-(Please read the precautions on the back before filling in this page) The size of the paper used in this edition applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) -Zb-565638 A7 ____ _B7 V. Description of the invention (full implementation Example 5 (Please read the precautions on the back before filling in this page) Using a double Russell twill knitting machine equipped with a 9-gauge, 6-gauge, 13-mm pattern interval, from a 3-gauge quilt forming the front side knitted fabric (Printed by L1, L2, L3 from the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs) Any one of the polytrimethylene terephthalate fiber false twist processing lines that supply 3 3 4 dtex 9 6 silk with full feed (Asahi Kasei Co., Ltd. Polytrimethylene terephthalate false twist processing line manufactured by the company 1 6 7 dtex 4 8 (black first dyed thread, 2 plied yarns), and 2 pieces of 筘 (L 5 , L 6) Twist processing of polyethylene terephthalate fiber with 1 0 2 dtex 2 8 8 yarns (Asahi Kasei Co., Ltd. Polypropylene terephthalate fiber false twist processing line 1 6 7 dtex 4 8 silk black dyeing line, 6 plied yarns), in the L 5 guide with a 1-in-1 exit arrangement 'in the L 6 guide It is supplied in a 1-out, 1-in configuration, and from the L 4 which forms the connection line, 880 dtex polytrimethylene terephthalate monofilament (diameter 0.29 mm) manufactured by the reference example is supplied to A full-feed array is supplied. The connection line is changed to the following, and the same knitting structure as in Example 1 is used to weave a fabric of a knitted fabric at a weft density of 10 lines / 2 · 5 4 cm. The obtained fabric is obtained. 10% expansion of the gray fabric is set at 150 ° CX 2 mi η dry heat, so that the full connection line is obliquely connected from the tissue on the back side opposite to the tissue on the front side of the knitted fabric with 2 vertical rows of tissue. The three-dimensional knitting structure with X structure is formed. The physical properties of the three-dimensional knitting obtained are shown in Table 1. (Editing organization) The paper size is suitable for financial affairs and family management ((: called 44 secret (21 (^ 297 mm) 565638 A7 B7 V. Description of the invention (such as L4: 1032/4523 / (please read the precautions on the back before filling this page) Example 6 Double Russell Twill Knitting The pattern interval is set to 5 mm, and the knitting structure of the connection line is changed as follows, except that the full connection line is diagonally connected from the tissue on the back side opposite to the structure of the knitted fabric on the front side to form X. With the exception of the structure, the physical properties of the three-dimensional knitted fabric obtained in the same manner as in Example 3 are shown in Table 1. (Organization) L4 · 1032/4523 / Example 7 The same 2 8 0 as in Example 4 was used except for the knot line. Table 1 shows the physical properties of the three-dimensional knitted fabric obtained in the same manner as in Example 6 except for the continuous relaxation heat treatment line of Dentex's polytrimethylene terephthalate. Printed in Example 8 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, except that the final processing method of the gray fabric of the three-dimensional knitted fabric is 25% expanded dry heat setting. The physical properties of the three-dimensional knitted fabric obtained in the same manner as in Example 1 are shown in Table 1. As shown. Example 9 Except that the final processing method of the three-dimensional knitted fabric is not expanded, the Chinese national standard (CNS) A4 specification (210X297 mm) is applied at the original paper size. 565638 A7 _ B7_ V. Description of the invention (if there is a dry heat setting of the width) Except for the physical properties of the three-dimensional knitted fabric obtained in the same manner as in Example 3 and shown in Table 1. Example 1 0 Except that the final processing method of the three-dimensional knitted fabric was not expanded, and the original width was dry-heat set, The physical properties of the three-dimensional knitted fabric obtained in the same manner as in Example 1 are shown in Table 1. Example 1 1 A double Russell twill knitting machine using a 9-pitch, 13-mm pattern interval, and equipped with a 7-prong reed and weft insertion device From a two-prong reed (L 1, L 2) forming a knitted fabric on the front side, a 1 20 dtex 2 8 8 silk polytrimethylene terephthalate fiber false twist processing line (Polyparaphenylene, manufactured by Asahi Kasei Corporation) Propylene glycol diformate false twisting processing line 1 6 7 dtex 4 8 silk black dyeing line, 6 stitches), in the L 1 guide with a 2 in 2 output arrangement 'and in the L 2 guide It is supplied in a two-out, two-in arrangement and forms three pieces of knitted fabric on the back side.筘 (L 5, L 6, L 7), to guide the supply of 5 0 1 dtex 1 4 4 silk poly (trimethylene terephthalate) fiber false twisting processing line from L 5, L 7 in a fully advanced arrangement ( Asahi Kasei Co., Ltd. polytrimethylene terephthalate fiber false twist processing line 1 6 7 dtex 4 8 black black dyeing thread, 3 plied yarns), guided from L 6 to supply 2 0 4 dtex 5 7 6-thread polytrimethylene terephthalate fiber false-twist processing line (manufactured by Asahi Kasei Co., Ltd. under the trademark "SORO" false-twist processing line 1 6 7 dtex 4 8 black pre-dyeing line, 1 2 composite yarn ), And from the 2 -3T- '-I ------- ^^ clothes that form the connecting line-(Please read the precautions on the back before filling this page) Order the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs The printed paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210X 297 mm) 565638 A7 B7 V. Description of the invention (such as tablets of 筘 (L 3, L 4) will be manufactured by the reference example of 8 80 dtex Poly (trimethylene terephthalate) monofilament is fed in a 2 in 2 out arrangement in L 3 and in a 2 out 2 in arrangement in L 4 guide. The thread will be inserted in the weaving structure shown below (L 6) Insert the knitted fabric on the back side in the longitudinal direction, and insert 20.0 4 dtex 5 7 6 silk polytrimethylene terephthalate fibers (made by Asahi Kasei Co., Ltd., trademark) in the middle wefts of each row of the knitted fabric on the back side. "S〇R〇" false twist processing line (16 7 dtex, 5 8 silk black first dyed thread, 12 double twisted thread), and weaving with a density of 12 rows / 2 · 5 4 cm Grey fabric of knitting. The obtained grey fabric was dry-heat-set in the original width of 150 ° CX 2 mi η, inserting the insertion thread into the longitudinal and lateral directions of the back side, and obliquely connecting the full connection line from the knitted fabric to the front side The tissues on the dorsal side opposite to the tissues are separated by two columns of tissues to obtain a three-dimensional knitted fabric forming an X structure. The physical properties of the obtained three-dimensional knitted fabric are shown in Table 1. When evaluating the compression flexure characteristics of the three-dimensional knitted fabric, the surroundings of the test piece of the three-dimensional knitted fabric were fused without slipping the insertion line in the horizontal direction. I -------- ^^ 衣-(Please read the notes on the back before filling out this page) Order Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, S Industrial Consumer Cooperative, Group 1 L
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ο IX τ—I IX / / / / 14 14 14 0 5 0 5 3 2 14 2 3 3 3 2 3 2 2 3 2 5 ο 4 1 2 3 3 2 本紙張尺度適用中國國家標準(CNS ) A4規格(2丨0X297公釐) 565638 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明(如 實施例1 2 在實施例1 1中,除了在從縱方向插入的L 6的筘供 給的纖維、及緯線插入的纖維,使用8 8 0分特的聚對苯 二甲酸丙二醇酯單絲的2條合絲之外,與實施例同樣地獲 得的立體編物的諸物性如表1所示。且,評價立體編物的 壓縮撓屈特性時,使橫方向的插入線不會滑動地熔合立體 編物的試驗片的周圍。 實施例1 3 在實施例1 1中,除了在從縱方向插入的L 6的筘供 給的纖維、及緯線插入的纖維,使用8 8 0分特的聚對苯 二甲酸丙二醇酯單絲的4條合絲之外,與實施例同樣地獲 得的立體編物的諸物性如表1所示。且,評價立體編物的 壓縮撓屈特性時,使橫方向的插入線不會滑動地熔合立體 編物的試驗片的周圍。 比較例1 將實施例6的連結線的編組織如以下變更,除了形成 全連結線不傾斜的構造之外,與實施例6同樣地獲得的立 體編物的諸物性如表1所示。 (編組織)L4*. 1010/0101/ 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) "33 ' " (請先閲讀背面之注意事項再填寫本頁) 565638 A7 _____B7__ 五、發明説明($ 比較例2 (請先閲讀背面之注意事項再填寫本頁) 在比較例1的連結線,除了使用與實施例4同樣的 2 8 0分特的聚對苯二甲酸丙二醇酯的連續弛緩熱處理線 之外,與比較例1同樣地獲得的立體編物的諸物性如表1 所示。 比較例3 在連結線,除了使用2 8 0特分的聚對苯二甲酸丙二 醇酯單絲(旭化成株式會社製)以外,與實施例6同樣地 獲得的立體編物的諸物性如表1所示。 比較例4 雙羅素斜紋針織機的花紋間隔設爲5 m m,並將連結 線的針織組織如以下變更,除了使全連結線橫跨1縱列傾 斜而形成X構造之外,與實施例5同樣地獲得的立體編物 的諸物性如表1所示。 經濟部智慧財產局員工消費合作社印製 (編組織) L4: 1021/2312/ 比較例5 使用裝備了 6片筘的1 8隔距且花紋間隔1 2 m m的 雙羅素斜紋針織機,從形成表側的2片筘(L 5 、L 6 ) -34 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 565638 A7 _____ B7 五、發明説明(釦 (請先閲讀背面之注意事項再填寫本頁) 將3 3 4分特9 6絲的聚對苯二甲酸丙二醇酯纖維假捻力口 工線(旭化成株式會社製聚對苯二甲酸丙二醇酯聚對苯二 甲酸丙二醇酯纖維假捻加工線1 6 7分特4 8絲的黑色先 染線,2條合絲)在L 1 、L 5導引中以2進2出的配 列,在L 2、L 6導引中以2出2進的配列進行供給,且 從形成連結線的2片筘(L 3、L 4 )將由參考例所製造 的2 8 0分特的聚對苯二甲酸丙二醇酯單絲(直徑 0 . 16mm),在L 3導引中以2進2出的配列,在 L 4導引中以2出2進的配列進行供給。以下所示的組織 中,以緯密1 4橫列/ 2 · 5 4 c m的密度編成立體編物 的坯布。將獲得的坯布擴幅4 0 %並以1 5 0 °C X 2 m i η乾熱定形,使表背的針織物的組織呈傾斜連,結,而 獲得形成X構造的的立體編物。所獲得的立體編物的諸牧j 性如表1所示。且,所獲得的立體編物的連結線,容胃寧月 針織物的長度方向(沿著縱列的方向)傾斜。 (編組織) 經濟部智慧財產局員工消費合作社印製 L1 : 4544/2322/1011/3233/ L2 : 1011/3233/4544/2322/ L3 ·· 3254/2310/2301/3245/ L4 : 2301/3245/3254/2310/ L5 · 4423/2210/1132/3345/ L6 · 1132/3345/4423/2210/ 本紙張尺度適用中.國國家標準(CNS ) Α4規格(210Χ297公疫) 565638 A7 B7 五、發明説明(如 經濟部智慧財產局員工消費合作社印製 I — I漱 實施例 10 £ PTT280 £ oo oo 0.26 ο 11.9 0.012 23.9 P ― 80.5 ε 31.2 13.9 58.9 o on 15.3 95.0 ! 74.9 r-· 1 1 1 ◎ ◎ X ◎ X 實施例9 PET PTT280 PET 5 0.26 oo 11.2 0.012 24.3 cn ! 67.3 60.7 26.0 cn σ< 50.5 r-· r-H 11.4 95.1 75.0 VO 1 1 1 ◎ ◎ <] ◎ <] 實施例8 ㈢ PTT280 2 0.22 oo cn 1/Ί 〇< 0.012 23.4 ON cn 48.6 49.6 14.9 15.3 42.6 cn cn Ό VO 95.7 Γ 75.2 v〇 寸· 1 1 1 ◎ ◎ ◎ 〇 〇 卜 舾 1_' PET ! PTT280 熱處理 1 PET p ― 10-52 I 3 un ON 1 0.025 1 | 41.7 I cn vo 50·7 L 54.5 1 1_18.9 1 cn σ< 14^7 I O) r-^ S 90.8 I 72.5 1 卜· 63.3 I 12.2 -15.0 I <] <] 〇 〇 〇 Ό 握 | PET 1 PTT280 1 PET 1 p I__1 | 10.2 1 | 18.7 I ! 0.012 1 I 37.2 I oo 51.4 1 i___1 18.0 1 cK 42.1 | r-H CN m vd 94.0 | 74.5 1 CN v〇 60.3 I 13.3 1 υη vd 〇 〇 〇 〇 〇 實施例5 1 PET 1 PTT280 1 PET 1 __1 σ\ 1 0.039 Π | 39.2 | 1 42.6 1 un od 36.7 | i/Ί 〇\ 93.2 | 73.8 1 CO VO 1 1 1 〇 〇 ◎ 〇 〇 寸 1 PET 1 PTT280 熱處理 1 PET 1 2 1 0.26 I 寸 un _^__ 1 0.025 1 1 39.8 | 2 _5L8__ _^_ 1 18.0 1 ON _lL〇_ 〇0 _?l〇__ 72.6 1 5 1 1 1 〇 〇 〇 ◎ 〇 實施例3 1 PET | PTT280 | PET 1 <N OO | 0.26 I o _^_ 1 0.012 1 | 23.9 | ― ___ _^_ VO υη cK | 42.3 1 ON r-( 3 _^_ 75.3 1 v〇 寸· 1 1 1 ◎ ◎ 〇 ◎ 〇 m 揖 * PTT280 熱處理 £ oo od 1 0.23 1 v〇 寸· _m__ 1 0.002 1 __ CN cn 60.2 _513_ _m_ __ __ ON § _^_ __ p 守· 1 1 1 ◎ ◎ 〇 ◎ 〇 實施例1 £ PTT280 oo 0.25 r- __ 0.012 _^_ ON rn _^__ _5iZ_ __^_ _lil__ _^_ cn oo ____ 1 1 1 ◎ ◎ 〇 ◎ 〇 I表線 I 連結線 1背線 1 厚度(mm) I單絲的曲率 1 m 缇 m 虔 175%壓縮時 1單絲的滯後損耗(%) | |50%壓縮時的滯後損耗(%) | 150%壓縮後的殘留變形㈤ 1 壓縮撓屈量(mm) I壓縮撓屈時的滯後損耗(%) 1 壓縮撓屈時的殘留變形量(mm) m 錯 m 常溫下 |70°C氣氛下 g Vitu 1共振頻率(Hz) I 共振點加速度傳達率_ 200Hz加速度傳達率(dB) 反覆壓縮前 I反覆壓縮後 I I反彈感 I 1貼身感 |在吊床式座墊的形態保持性 I 各線 1性量 1 φ 租 if s tt a- 長率(%) I 伸長率(%) 伸長殘留變形 g 壓縮回復率 g m m m m 蹈j 鹏 振動減衰性 緩衝性 |(彈力感) | 在吊床式座墊 的緩衝性 | (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 565638 A7 B7 五、發明説明(如 經濟部智慈財產局員工消費合作社印製 比較例5 | PTT280 ρ 卜· 0.009 | ON C-: S 0.012 1 寸 S 卜 Μ o cn σ< On cn CN CN c4 ρ o CN ON S ON r—^ 1 1 I <] X <1 <1 <1 寸 jj PTT880 S Oh — oo Γ- ΓΟ CN CN 〇 0.035 | 寸· un τ—^ oo ο oj cn v〇 S CN wn Ο; r—« 〇\ oo CO 3 1 1 1 <3 <1 <] <J <] 比較例3 | S PET280 δ CL. ON c-: s c> CS S cn 0.071 | 寸 〇〇 1/Ί oo VO VO (Μ un Γ—H ON cn σ< to oo un p ON s oo CN S 寸 cn CN cn X X <1 X <] 比較例2 | S PBT280 熱處理 s PL, ON c-: 2 m cn o\ 〇 oo m 0.025 1 m cn i〇 cn r-H ΟΝ σ< 寸 CO un OO m σ< σ\ ON ON un CN oo Os v〇 寸 CN 1 1 1 X X <] X <3 比較例1 I a PTT280 00 cn C<J 2 cn 寸 cn 0.012 1 CN s 〇 OO 〇· un c-: m oo oo S S v〇 ON 1—( as σ< 1 1 1 <] X <1 <1 0 m 揖 麵 PTT880 Oh CU CN o v〇 s MD S 0.039 | r- vd m in — VO cn oo cn v〇 CN 〇 旅 o VO 1 1 1 〇 〇 ◎ < ◎ CN 握 Μ ΡΤΓ880 o o cJ oo v〇 ;〇s !〇〇 0.039 | O Ρί v〇 ΟΝ r—^ r—« un oo <N o m 00 cn v〇 1 1 1 〇 〇 ◎ 〇 ◎ 捱 m PTT880 CN o v〇 CD v〇 00 0.039 1 oo vd m un 卜 (Ν cn ON oo cK cn CO ON cn cs CN cn CN VO 1 1 1 〇 〇 ◎ 〇 ◎ 表線 1 連結線 背線 厚度(mm) | 1單絲的曲率 1 s m 豳 75%壓縮時 丨 1單絲的滯後損耗(%) 1 150%壓縮時的滯後損耗(%) 1 150%壓縮後的殘留變形(%) 1 |·縮撓屈量(mm) 1 S' u a 班 m s s m 3S m 麵 1壓縮撓屈時的殘留變形量(mm) 1 橥 m m I常溫下 I |70〇C氣氛下 1 1返覆壓縮殘留變形(%) 1 1共振頻率(Hz) 1 1共振點加速度傳達率(dB) I s 3 Μ- m it m ln/> ftS -¾ 8 CN 淀 m 趣j 鹏 1反覆壓縮後 |反彈感 1貼身感 在吊床式座墊的形態保持性 各線 性量 s: i ir ^ ss 踅视 » 1« 伸長率(%) 伸長殘留變形 (%) 壓縮回復率 (%) 振動減衰性 緩衝性 1 觸力感) 在吊床式座墊 的緩衝性 --------—(請先閱讀背面之注意事項再填寫本頁) 訂 本紙張尺度適用中國國家標率(CNS ) Α4規格(210X297公釐) 565638 A7 _____ B7_ 五、發明説明(釦 〔產業上之利用可能性〕 (請先閲讀背面之注意事項再填寫本頁) 本發明的立體編物,具有富彈力性的緩衝性,瞬時的 壓縮回復性良好’即使返覆或長時間使用也不容易使彈力 性損失,在緩衝性的耐久性佳。特別是,使用在吊床式座 墊的情況時,顯示富彈力感的緩衝性且對人體的貼身感良 好’而且,即使返覆或長時間坐後,彈性復原少,形態保 持性良好。進一步,本發明的立體編物,高頻率的振動衰 減性良好,適合作爲振動環境的座墊,例如:車載用座墊 的緩衝材。 〔圖面之簡單說明〕 第1圖係爲從沿著立體編物的縱列的切斷面所看的單 絲中心線的一例。 第2圖係顯示從沿著立體編物的縱列的切斷面所看 的’將立體編物壓縮5 0 %的狀態的單絲的彎曲狀態的一 例。 第3圖係顯示沿著立體編物的橫列的切斷面圖。 經濟部智慧財產局S工消费合作社印製 第4圖係顯示立體編物的5 0 %壓縮時的沿著橫列的 切斷面圖。 第5圖係顯示沿著立體編物的橫列的切斷面圖的連結 線的構架構造的一例。 第6圖係顯示沿著立體編物的橫列的切斷面圖的連結 線的交叉構造的一例。 第7圖係顯示立體針織物的負荷-變形曲線的一例。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 565638 A7 B7 五、發明説明(如 明物 說織 圖 · · 物物 面 織織線線表. 針針 結心側 表背連中凸 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)ο IX τ—I IX / / / / 14 14 14 0 5 0 5 3 2 14 2 3 3 3 2 3 2 2 3 2 5 ο 4 1 2 3 3 2 This paper size applies to China National Standard (CNS) A4 specifications (2 丨 0X297 mm) 565638 Printed by A7 B7 of the Consumer Cooperatives of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (as in Example 1 2 In Example 11, except for the supply of 6 of L 6 inserted in the vertical direction Table 1 shows the physical properties of the three-dimensional knitted fabric obtained in the same manner as in the example, except that the fibers and the fibers inserted in the weft are made of two plied polyterephthalate monofilaments of 880 dtex. In addition, when evaluating the compression and flexion characteristics of the three-dimensional knitted fabric, the circumference of the test piece of the three-dimensional knitted fabric was fused so that the insertion line in the horizontal direction did not slip. Example 1 3 In Example 11, except for the L inserted from the vertical direction, The physical properties of the three-dimensional knitted fabric obtained in the same manner as in the example were as follows: except that the fiber supplied by 筘 and the fiber inserted into the weft were 4 polyfilament yarns of 880 dtex monofilament monofilament; The results are shown in Table 1. In the evaluation of the compression flexion characteristics of the three-dimensional knitted fabric, the horizontal insertion was performed. The periphery of the test piece of the three-dimensional knitted fabric was not fused with sliding. Comparative Example 1 The knitting structure of the connection line of Example 6 was changed as follows, except that the structure of the full connection line was not inclined, and was obtained in the same manner as in Example 6. The physical properties of three-dimensional knitting are shown in Table 1. (Editing organization) L4 *. 1010/0101 / This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) " 33 '" (Please read the back first Please note this page before filling in this page) 565638 A7 _____B7__ V. Description of the invention ($ Comparative Example 2 (Please read the notes on the back before filling this page) The connection line in Comparative Example 1 is the same as in Example 4 except that 2 The physical properties of the three-dimensional knitted fabric obtained in the same manner as in Comparative Example 1 are shown in Table 1 except for a continuous relaxation heat treatment line of 80 dtex polytrimethylene terephthalate. Comparative Example 3 In the connection line, 2 8 is used The physical properties of the three-dimensional knitted fabric obtained in the same manner as in Example 6 except for polytrimethylene terephthalate monofilament (manufactured by Asahi Kasei Co., Ltd.) of 0 points are shown in Table 1. Comparative Example 4 Pattern of a double Russell twill knitting machine interval It is 5 mm, and the knitting structure of the connection line is changed as follows. The physical properties of the three-dimensional knitted fabric obtained in the same manner as in Example 5 are as shown in Table 1, except that the full connection line is inclined across one column to form an X structure. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (organization) L4: 1021/2312 / Comparative Example 5 Using a double Russell twill knitting machine equipped with 6 pieces of 8-gauge 18-gauge and 12-mm pattern spacing, from Form two pieces of 筘 on the front side (L 5, L 6) -34-This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 565638 A7 _____ B7 5. Description of the invention (deduction (please read the note on the back first) Please fill in this page again) Threaded 3 3 4 dtex 9 6 filaments of polytrimethylene terephthalate fiber false twist (Polytrimethylene terephthalate polytrimethylene terephthalate fiber manufactured by Asahi Kasei Corporation) False twist processing line 1 6 7 dtex 4 8 silk black first dyeing line, 2 plied yarns) In the L 1 and L 5 guides, the arrangement is 2 in and 2 out, and in the L 2 and L 6 guides, 2 out of 2 in line for supply, and from the 2 pieces of L (L 3, L 4) forming the connecting line will be referenced The 280 dtex polytrimethylene terephthalate monofilament (0.16 mm in diameter) was manufactured in a 2 in 2 out arrangement in the L 3 guide, and 2 out 2 in the L 4 guide. For the supply. In the structure shown below, a grey fabric was knitted into a knitted fabric at a weft density of 14 rows / 2 · 5 4 cm. The obtained gray fabric was expanded by 40% and subjected to dry heat setting at 150 ° C X 2 m i η, so that the structure of the knitted fabric on the front and back was inclined and connected, and a three-dimensional knitted fabric forming an X structure was obtained. The properties of the obtained three-dimensional knitted fabrics are shown in Table 1. In addition, the connecting line of the obtained three-dimensional knitted fabric is inclined in the longitudinal direction (direction along the vertical line) of the Rongwei Ningyue knitted fabric. (Editing organization) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs L1: 4544/2322/1011/3233 / L2: 1011/3233/4544/2322 / L3 ·· 3254/2310/2301/3245 / L4: 2301/3245 / 3254/2310 / L5 · 4423/2210/1132/3345 / L6 · 1132/3345/4423/2210 / This paper size is applicable. National National Standard (CNS) Α4 specification (210 × 297 public epidemic) 565638 A7 B7 V. Invention Description (such as printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs I — I Example 10 £ PTT280 £ oo oo 0.26 ο 11.9 0.012 23.9 P ― 80.5 ε 31.2 13.9 58.9 o on 15.3 95.0! 74.9 r- · 1 1 1 ◎ ◎ X ◎ X Example 9 PET PTT280 PET 5 0.26 oo 11.2 0.012 24.3 en! 67.3 60.7 26.0 en σ < 50.5 r- · rH 11.4 95.1 75.0 VO 1 1 1 ◎ ◎ <] ◎ <] Example 8 ㈢ PTT280 2 0.22 oo cn 1 / Ί 〇 < 0.012 23.4 ON cn 48.6 49.6 14.9 15.3 42.6 cn cn VO 95.7 Γ 75.2 v 0 inch · 1 1 1 ◎ ◎ ◎ 〇〇 卜 舾 1_ 'PET! PTT280 heat treated 1 PET p ― 10-52 I 3 un ON 1 0.025 1 | 41.7 I cn vo 50 · 7 L 54.5 1 1_18.9 1 cn σ < 14 ^ 7 IO) r- ^ S 90.8 I 72.5 1 BU · 63.3 I 12.2 -15.0 I <] <] 〇〇〇Ό grip | PET 1 PTT280 1 PET 1 p I__1 | 10.2 1 | 18.7 I! 0.012 1 I 37.2 I oo 51.4 1 i___1 18.0 1 cK 42.1 | rH CN m vd 94.0 | 74.5 1 CN v〇60.3 I 13.3 1 vn 〇〇〇〇〇 Example 5 1 PET 1 PTT280 1 PET 1 __1 σ \ 1 0.039 Π | 39.2 | 1 42.6 1 un od 36.7 | i / Ί 〇 \ 93.2 | 73.8 1 CO VO 1 1 1 〇〇 ◎ 〇〇 inch 1 PET 1 PTT280 heat treated 1 PET 1 2 1 0.26 I inch un _ ^ __ 1 0.025 1 1 39.8 | 2 _5L8__ _ ^ _ 1 18.0 1 ON _lL〇_ 〇0 _? L〇__ 72.6 1 5 1 1 1 〇〇〇 ◎ 〇 Example 3 1 PET | PTT280 | PET 1 < N OO | 0.26 I o _ ^ _ 1 0.012 1 | 23.9 | ― ___ _ ^ _ VO υη cK | 42.3 1 ON r- (3 _ ^ _ 75.3 1 v〇inch · 1 1 1 ◎ ◎ ◎◎ PTT280 Heat treatment £ oo od 1 0.23 1 v〇inch · _m__ 1 0.002 1 __ EN en 60.2 _513_ _m_ __ __ ON § _ ^ _ __ p Shou · 1 1 1 ◎ ◎ ◎ ○ Example 1 £ PTT280 oo 0.25 r- __ 0.012 _ ^ _ ON rn _ ^ __ _5iZ_ __ ^ _ _lil__ _ ^ _ cn oo ____ 1 1 1 ◎ ◎ 〇 ◎ 〇I table line I link line 1 back 1 Thickness (mm) I Curvature of a monofilament 1 m Tm m 1175 Hysteresis loss (%) when compressing 1 | Hysteresis loss (%) at 50% compression | 150% residual deformation after compression ㈤ 1 Compression deflection amount (mm) I Hysteresis loss during compression deflection (%) 1 Residual deformation amount during compression deflection (mm) m Wrong m at normal temperature | 70 ° C atmosphere g Vitu 1 resonance frequency (Hz) I Resonance point acceleration transmission rate _ 200Hz acceleration transmission rate (dB) before repeated compression I after repeated compression II rebound feeling I 1 close-fitness | shape retention in a hammock-type cushion I each line 1 sexual quantity 1 φ rent if s tt a- Elongation (%) I Elongation (%) Residual deformation in elongation g Compression recovery rate gmmmm jj Peng vibration attenuation attenuation cushioning | (elasticity) | cushioning in a hammock cushion | (Please read the precautions on the back first (Fill in this page again) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 565638 A7 B7 V. Description of invention (such as Comparative Example 5 printed by the Consumer Cooperatives of the Intellectual Property Office of the Ministry of Economic Affairs | PTT280 ρ bu · 0.009 | ON C-: S 0.012 1 inch S BM o cn σ < On cn CN CN c4 ρ o CN ON S ON r— ^ 1 1 I <] X < 1 < 1 < 1 inch jj PTT880 S Oh — oo Γ- ΓΟ CN CN 〇0.035 | inch · un τ— ^ oo ο oj cn v〇 S CN wn Ο; r— «〇 \ oo CO 3 1 1 1 < 3 < 1 <] < J <] Comparative Example 3 | S PET280 δ CL. ON c-: s c > CS S cn 0.071 | Inch 〇〇1 / 1 / oo VO VO (Μ un Γ—H ON cn σ < to oo un p ON s oo CN S Inch CN CN cn XX < 1 X <] Comparative Example 2 | S PBT280 Heat treatment s PL, ON c-: 2 m cn o \ 〇oo m 0.025 1 m cn i〇cn rH ΟΝ σ < inch CO un OO m σ < σ \ ON ON un CN oo Os v〇inch CN 1 1 1 XX < ] X < 3 Comparative Example 1 I a PTT280 00 cn C < J 2 cn inch cn 0.012 1 CN s 〇OO 〇 · un c-: m oo oo SS v〇ON 1— (as σ < 1 1 1 < ] X < 1 < 1 0 m facet PTT880 Oh CU CN ov〇s MD S 0.039 | r- vd m in — VO cn oo cn v〇CN 〇Travel o VO 1 1 1 〇〇 ◎ < ◎ CN Hold Μ ΡΤΓ880 oo cJ oo v〇; 〇s! 〇〇0.039 | O Ρί v〇〇Ν r— ^ r— «un oo < N om 00 cn v〇1 1 1 〇〇 ◎ 〇 ◎ CN ov〇CD v〇00 0.039 1 oo vd m un Bu (N cn ON oo cK cn CO ON cn cs CN cn CN VO 1 1 1 〇〇 ◎ 〇 ◎ Table line 1 Back line thickness (mm) | 1 Curvature of monofilament 1 sm 豳 75% compression 1 Hysteresis loss of monofilament (%) 1 Hysteresis loss (%) of 150% compression 1 150% Residual deformation after compression (%) 1 (mm) 1 S 'ua class mssm 3S m Surface 1 Residual deformation during compression and deflection (mm) 1 橥 mm I At room temperature I | 70 ° C atmosphere 1 1 Residual compression residual deformation (%) 1 1 Resonance Frequency (Hz) 1 1 Resonance point acceleration transmission rate (dB) I s 3 Μ- m it m ln / > ftS -¾ 8 CN 淀 m 趣 j Peng 1 After repeated compression | rebound feeling 1 Close feeling in the hammock seat Mat linear retention s: i ir ^ ss contempt »1« Elongation (%) Residual deformation after elongation (%) Compression recovery rate (%) Vibration attenuation attenuation cushioning 1 touch feeling) In a hammock seat The cushioning of the pad --------— (Please read the notes on the back before filling in this page) The size of the paper is applicable to China National Standards (CNS) Α4 specification (210X297 mm) 565638 A7 _____ B7_ 5 ,invention Ming (deduction [industrial use possibility] (please read the precautions on the back before filling in this page) The three-dimensional knitted fabric of the present invention has elastic cushioning and good compression recovery in a short time. It is also not easy to lose elasticity over time, and has good cushioning durability. In particular, when it is used in a hammock-type seat cushion, it exhibits a cushioning property that is rich in elasticity and has a good fit to the human body '. Moreover, even after repetition or sitting for a long time, there is less elastic recovery and good shape retention. Furthermore, the three-dimensional knitted fabric of the present invention has good vibration attenuation at high frequencies, and is suitable as a cushion for a vibration environment, for example, a cushion material for a vehicle-mounted cushion. [Brief Description of Drawings] Fig. 1 is an example of the centerline of the monofilament as viewed from the cut surface along the vertical line of the three-dimensional knitted fabric. Fig. 2 shows an example of the bent state of the monofilament in a state where the three-dimensional knitted fabric is compressed by 50%, as viewed from the cut surface along the vertical line of the three-dimensional knitted fabric. FIG. 3 is a cross-sectional view showing a horizontal line of the three-dimensional knitted fabric. Printed by Intellectual Property Bureau of the Ministry of Economic Affairs, S-Consumer Cooperative. Figure 4 is a cross-sectional view of the three-dimensional knitted fabric when compressed at 50%. Fig. 5 shows an example of a frame structure along a connecting line of a cross-sectional view of a three-dimensional knitted fabric. Fig. 6 shows an example of an intersecting structure of a connection line along a cross-sectional view of a row of a three-dimensional knitted fabric. Fig. 7 shows an example of a load-deformation curve of a three-dimensional knitted fabric. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 565638 A7 B7 V. Description of the invention (such as the illustration of the weaving pattern of the object · · surface weaving thread table. Needle knot heart side table back connection Convex (Please read the notes on the back before filling out this page) Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm)
Claims (1)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001096126 | 2001-03-29 | ||
| JP2001146914 | 2001-05-16 | ||
| JP2001157723 | 2001-05-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW565638B true TW565638B (en) | 2003-12-11 |
Family
ID=27346399
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW91106357A TW565638B (en) | 2001-03-29 | 2002-03-29 | Seat-use three-dimensional knit fabric |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6644070B2 (en) |
| EP (1) | EP1426473B1 (en) |
| JP (1) | JP4056885B2 (en) |
| KR (1) | KR100549771B1 (en) |
| CN (1) | CN100523345C (en) |
| AT (1) | ATE466983T1 (en) |
| CA (1) | CA2442331C (en) |
| DE (1) | DE60236300D1 (en) |
| TW (1) | TW565638B (en) |
| WO (1) | WO2002079558A1 (en) |
Cited By (1)
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|---|---|---|---|---|
| TWI677608B (en) * | 2017-09-18 | 2019-11-21 | 黛莉股份有限公司 | Fabric |
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2002
- 2002-03-28 US US10/107,301 patent/US6644070B2/en not_active Expired - Lifetime
- 2002-03-29 WO PCT/JP2002/003231 patent/WO2002079558A1/en not_active Ceased
- 2002-03-29 CA CA002442331A patent/CA2442331C/en not_active Expired - Lifetime
- 2002-03-29 TW TW91106357A patent/TW565638B/en not_active IP Right Cessation
- 2002-03-29 JP JP2002577956A patent/JP4056885B2/en not_active Expired - Lifetime
- 2002-03-29 CN CNB028077172A patent/CN100523345C/en not_active Expired - Lifetime
- 2002-03-29 DE DE60236300T patent/DE60236300D1/en not_active Expired - Lifetime
- 2002-03-29 KR KR1020037012691A patent/KR100549771B1/en not_active Expired - Lifetime
- 2002-03-29 EP EP02707264A patent/EP1426473B1/en not_active Expired - Lifetime
- 2002-03-29 AT AT02707264T patent/ATE466983T1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI677608B (en) * | 2017-09-18 | 2019-11-21 | 黛莉股份有限公司 | Fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030092033A (en) | 2003-12-03 |
| US6644070B2 (en) | 2003-11-11 |
| CA2442331A1 (en) | 2002-10-10 |
| ATE466983T1 (en) | 2010-05-15 |
| CN100523345C (en) | 2009-08-05 |
| DE60236300D1 (en) | 2010-06-17 |
| CA2442331C (en) | 2007-11-06 |
| EP1426473A4 (en) | 2004-08-04 |
| JP4056885B2 (en) | 2008-03-05 |
| EP1426473B1 (en) | 2010-05-05 |
| JPWO2002079558A1 (en) | 2004-07-22 |
| US20030033838A1 (en) | 2003-02-20 |
| EP1426473A1 (en) | 2004-06-09 |
| WO2002079558A1 (en) | 2002-10-10 |
| KR100549771B1 (en) | 2006-02-08 |
| CN1639403A (en) | 2005-07-13 |
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