TW589372B - Aqueous liquid detergent compositions - Google Patents
Aqueous liquid detergent compositions Download PDFInfo
- Publication number
- TW589372B TW589372B TW089121098A TW89121098A TW589372B TW 589372 B TW589372 B TW 589372B TW 089121098 A TW089121098 A TW 089121098A TW 89121098 A TW89121098 A TW 89121098A TW 589372 B TW589372 B TW 589372B
- Authority
- TW
- Taiwan
- Prior art keywords
- alkyl
- surfactant
- fatty acid
- weight
- patent application
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 239000003599 detergent Substances 0.000 title claims abstract description 14
- 239000007788 liquid Substances 0.000 title claims abstract description 5
- -1 long-chain fatty acid glycol ester Chemical class 0.000 claims abstract description 42
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 7
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 4
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 3
- 239000012459 cleaning agent Substances 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- 229960003237 betaine Drugs 0.000 claims 1
- 150000008050 dialkyl sulfates Chemical class 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 15
- 229920001296 polysiloxane Polymers 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 9
- 239000002932 luster Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000002453 shampoo Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 229920006317 cationic polymer Polymers 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- RCJRCAFDVCTPLU-UHFFFAOYSA-N 1-prop-2-enoylpyrrolidine-2,5-dione Chemical compound C=CC(=O)N1C(=O)CCC1=O RCJRCAFDVCTPLU-UHFFFAOYSA-N 0.000 description 1
- VGCZCJQRGDELDD-UHFFFAOYSA-N 2,2-dioxo-1,3,2-dioxathiepane-4,7-dione Chemical class O=C1CCC(=O)OS(=O)(=O)O1 VGCZCJQRGDELDD-UHFFFAOYSA-N 0.000 description 1
- 125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N Caprolactam Natural products O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 206010016334 Feeling hot Diseases 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 244000125380 Terminalia tomentosa Species 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 1
- 125000006350 alkyl thio alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000000539 amino acid group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000008395 clarifying agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- NIKLARYSRFBLLS-UHFFFAOYSA-N ethene;1h-imidazole Chemical compound C=C.C1=CNC=N1 NIKLARYSRFBLLS-UHFFFAOYSA-N 0.000 description 1
- GSKMLYYTVSPGAO-UHFFFAOYSA-N ethyl benzoate;sodium Chemical compound [Na].CCOC(=O)C1=CC=CC=C1 GSKMLYYTVSPGAO-UHFFFAOYSA-N 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
589372
五、發明說明（1) a)發明之領域 本發明係關於清潔劑組合物，其各I 珠光劑的分散％定性良好。 ，、有珍珠光澤，並且 b)相關技術之說明 在如洗髮精、洗面乳、及沐浴乳等、夫* 其外觀改變成具有珍珠光澤，以便能ς潔劑中，習慣常將 價值。 ：其賦予額外的商業
現在’具有珍珠光澤的清潔劑組合 固態的長鏈脂肪酸乙二醇酯，或類似主要利用在室溫為 潔劑製造時於室溫下將珠光劑加入，=為珠光劑，在% 2 熱的混合物冷卻回溫，使得珠为 劑^0曰而或者利用事先已經由熔化珠光劑再冷卻回溫 而：且Ϊ t珠光澤之黏稠分散劑和清潔劑成分於室溫下 t Γ二：論使用何種方法’珠光劑以細微結晶分散妒 最終組合物中。 a刀狀7、 然而，如上述獲得具有 足以提供分散的珠光劑穩 某些情況下可能會分離2 本發明之目的為提供— 散穩定性良好，並具有持 本發明人已發現運用〜 光劑能得到一種清潔劑誕 珍珠光澤的傳統清潔劑組合物不 定性，特別是當長時間儲存，在 長出沉澱。 jg之概述 種清潔劑組合物，其珠光劑的分 久性美麗的珍珠光澤。 種特定的甘油醚和一種特殊的珠 合物，其珠光劑的分散穩定性良
第6頁 589372
好，且即使長時間儲存，也不 久性美麗的珍珠光澤。' 因此本發明提供—種水性液態清潔劑 成分（A)、（B)及（C): 奶包3下列 (A) 1至5 0重1 %之_種界面活性劑，由陰離 劑、非離子界面活性南丨-V * ^ ^ 界面活性 q r去旦片、或兩性界面性劑之中選出； • · 5重s %之長鏈脂肪酸乙二醇酯，以下式（1)代 表· # R1 -C-(〇CH2CH2)n —〇一 a (1) 其中R1代表直鏈或支鏈之具有13至23個 基，η代表_的一個整數，及A代表纟/子子❹的说基或細
II 「置由 pl - C - R1 I 〃干K具有和上面定義相同的意義）；及 ()·1至10重里％之具有一或多個直鏈或支 碳原子的貌基或稀基之甘油醚。 2们 、根據本發明的清潔劑組合物包含珠光劑於穩定的分散形 式，具有美麗的珍珠光澤，此外，經長時間仍保持穩定。 因此’此清潔劑組合物給使用者豐富感及溫暖感。 明及較佳具體例之詳細說巧 在本^月中使用做成份（A )的界面活性劑是由陰離子界 面活〖生劑、非離子界面活性劑或兩性界面活性劑之中選
苐7頁 589372 五、發明說明（3) 出。 陰離子界面活性劑的較佳實例可包括硫酸鹽、碏酸臨 羧酸鹽。例子有烷基硫酸鹽、聚氧化伸烷基烷基醚硫； 鹽、聚氧化伸烷基烯基醚硫酸鹽、烷基磺醯基琥： 烷基聚氧化伸烷基磺醯基琥珀酸鹽、烷苯磺酸鹽、/、 績酸鹽、聚氧化伸烧基院基苯基喊硫酸鹽、甘^ 細 鹽：胺醚硫酸鹽、高碳脂肪酸鹽、院續酸鹽、及：二 醯基脂肪酸酯鹽。 a α -石頁 在這些陰離子界面活性劑中，烷基硫 基烷基醚硫酸鹽及聚氧化伸# ^ 水乳化伸烷 更較佳的疋烷基硫酸鹽，以 」钗佳 院基烧基醚硫酸鹽及聚氧化伸=)代表’同時聚氧化伸 (3)代表： 土歸基醚硫酸鹽以下式 R2〇S03M (2) R3 0 ( C H2 C H2 Q )m S 03 Μ (3 ) 其中R2代表具有10至18個碳原 18個碳原子的烷基或烯基， 、^ 土，R代表具有ίο至 原子、.銨離子、烷醇胺殘基::金屬原子、鹼土金屬 量平均代表1到5的一個整數1 胺基酸殘基，m按照重 非離子界面活性劑的實例可产 聚氧化伸烷基脂肪酸酯、聚氧祜、水虱化伸烷基烷基醚、 酯、脂肪酸烷醇醯胺（脂肪萨伸烷基山梨糖醇脂肪酸 酿胺等）、及烧基聚餹脊。乙，酸胺、脂肪酸二乙醇 化伸烷基烷基醚特別較佳/、，脂肪酸烷醇醯胺及聚氧 /之
ί1 有基或烯基。較佳的實例可包括 丁基、三级有4至12個碳原子的烷基，如正丁基、異 庚基、正辛臭土、正戊基、異戊基、正已基、異己基、·^ /或正月桂美土。乙基己基、正壬基、異壬基、正癸基及 基，特別9 土 、別較佳的為甘油醚包含有一或雨個烷 個碳原子，姓個院基具有4至11個石炭原子，更佳的是6至1 ] ，、子特別是8個碳原子。 可传用一斗、办
組合物的醚作為成分（〇 1分（C)量為整低 5重量％。因為 里％丄=佳為0. 5至5重量％，特別是1 ^ 圍為較佳。‘要到的珍珠光澤及良好的穩定性此範 的ϊ:i f:的清潔劑組合物可進-步包含聚矽氧，產 物可導致優越的調節效果。在傳統的水性 物中穩定地包含聚石夕氧曾為困難。然而在 ，月中内含甘油醚作為成分（C)得以穩定地分散聚矽 氧。 聚石夕氧的實例可包括： 〇)二甲基聚矽氧烷，以下式代表：
(Me3)Si〇~(Me2SiO)n-Si(Me3) 其中Me代表一個甲基，n代表從3到2〇, 〇〇〇的一個數字。 (2)胺基修飾的聚矽氧： 雖然許多胺基修飾的聚矽氧為可用的，特別佳的為在,， 國際化粧品成分詞典及手冊第三版"（由美國化妝品、化妝 用品、及香料協會（CTFA，Cosmetic，Toiletry, and
589372
五、發明說明（6)
Fragrance Association))中描述的名稱 M A m 〇 d i m e t h i c ο n e lf之胺基修飾的聚石夕氧。此等胺美彳灰飾、 聚矽氧較佳可以水性乳狀液的形式運用，其市售^ : σ的 括，例如，"SM 8 70 4C1’（商品名，脫雷聚矽氧有限公"司"包 產品）及"DC 9 2 9Π (商品名，道康寧公司冬產品）。 (3)此外，聚醚修飾的聚矽氧、甲基苯基聚矽氧院、脂 肪一峻修飾的聚矽氧、醇類修飾的聚矽氧、烧氧修飾的% 矽氧、環氧修飾的聚矽氧、氟修飾的聚矽氧、環聚石夕氧+ 烷基修飾的聚矽氧。
在這些中，二曱基聚矽氧烷為特別較佳。 此等聚碎氧可單獨或組合使用，量可為整個組合物的 〇. 2至5重量％，特別是0. 5至2重量％。 σ 根據本發明的清潔劑組合物可進一步包含陽離子聚人 物，產生的清潔劑組合物可導致極好的調節效果。陽離子 聚合物的貝例可包括·陽離子纖維素衍生物、陽離子殿 粉、陽離子古亞膠衍生物、二烯丙第四級銨鹽的同元聚合 物、二烯丙第四級銨鹽/丙烯醯胺共聚合物、四級聚乙烯 吡咯酮·衍生物、聚乙二醇多元胺縮合產物、三氣化乙烯咪 唑/乙烯吼17各酮共聚合物、羥乙基纖維素/氣化二曱基二稀 丙銨共聚合物、乙烯吡咯酮/四級二甲胺乙基曱基丙稀酸 酯共聚合物、聚乙烯吡咯酮/烷基胺基丙烯酸酯共聚合 物、聚乙稀吡咯酮/烷基胺基丙烯酸酯/乙烯己内醯胺共聚 合物、乙稀吼咯酮/曱基丙烯胺丙基氣化三甲基銨共聚合 物、炫基丙稀醯胺/丙烯酸酯/烷胺基烷基丙烯醯胺/聚乙
第11頁 589372 五、發明說明（7) 甲胺基羥丙基乙 二醇甲基丙稀酸酯共聚合物、己二酸/ 烯三胺共聚合物（"Cartaretin” ，商標；美國三多士 ^二 公司的產品）、及揭示於日本專利⑸一丨3 9 73‘或日予 生物為特別較佳。 〜i何 個陽離子聚合物可單獨或組合使用，較佳的量可 是0 ! ,1= 置％，特別是〇.05至U重量％ , i·'甘 以比例…=離子聚合物結合使用分別、 水為：ί ：t劑組合物是以水性液態的形式，利用 的成：例：可=卜…用於-般清潔劑組上: 醚、山梨糖醇、及多^丙一醇、甘油、二乙二醇單乙 劑如甲基纖維素、，；著色劑如染料及色素；黏度控制 醆及氫氧化鉀；及:—醇、及乙醇；酸鹼調節劑如檸檬 毒劑、鉗合劑、維:頦如氣化鈉、植物萃取、防腐劑、消 染料、紫外光吸收素、抗發炎劑、抗頭皮屑劑、香料、 根據本發明的清:,氧化劑’等等。 法製造，可以配制=M組合物可以此技術中原本已知的方 洗面乳及洗手乳中/人^清^劑配方如洗髮精、沐浴乳、 實例1 製造示於表中的、、主咖 程度。結果同樣示:漂劑組合物配方，並歸類其貨架穩定 (步驟） …、於表1。
第12頁 589372 五、發明說明（9) 實例2 以下說明之配方的調理型洗髮精是以此技術中原本已知 的方式製造。 如此得到的洗髮精具有均勻的珍珠光澤，即使儲存1個 月後仍保持不變及穩定。 (成分） (重量％) Ρ 0 Ε ( 2 )月桂醚硫酸鈉 10 月桂硫酸納 5 正辛基甘油鍵 3 乙二醇二硬脂酸酯 2 聚矽氧乳化劑 2 (包含25%高度聚合之二 甲基聚矽氧烷； # "BY-22-062 π為其商品名，道康寧脫雷 聚矽氧有限公司之產品） 1 0. 3 0. 5 調整至ρΗ6 差額 乙醇 苯曱酸鈉 香料 檸檬酸水溶液 純水 實例3 以下說明之配方的調理型洗髮精是以此技術中原本已知 的方式製造。 如此得到的洗髮精具有均勻的珍珠光澤，即使儲存1個 月後仍保持不變及穩定。
第14頁 589372 五、發明說明（11) P〇E(16)月桂醚 正癸基甘油醚 二乙二醇單硬脂酸酯 氯化十六烷基三甲基銨 聚矽氧乳化劑 (ΠΒΥ_22-062 ”為其商品名，道康寧脫雷 聚矽氧有限公司之產品） 陽離子聚合物 (nMerquat 100” ，商品名 乙醇 二鈉乙二胺四乙酸 香料 檸檬酸水溶液 純水 2 1 2 0 3 0. 卡共公司的產品） 2 0. 0. 調整至pH6 差額 Φ %
第16頁
Claims (1)
- 589372 案號 89121098 公告年本 曰 六、申請專利範圍 1 . 一種水性液態清潔劑組合物 (B)及（C):包含下列成分（A) (A ) 1至5 0重量％之選自陰離子界面活性劑、非離子界面 活性劑、或兩性界面活性劑之界面活性劑，由； (B ) 0 · 3至5重量％之長鏈脂肪酸乙二醇酯，以下式（1 )代 表： 〇 (1 -C-（〇CH2CH2)n-〇-A 睿 其中R1代表直鏈或支鏈之具有13至23個碳原子的烷基或-烯 g基，η代表1到3之整數，及A代表〇 % 示 - C-R1 ?、其中R1具有和上面定義相同的意義）；及 i (C)0.1至10重量％之具有一或多個直鏈或支鏈之4至12個 |暖原子的烷基或烯基之甘油醚。 ^ 2. 根據申請專利範圍第1項之清潔劑組合物，其中該陰 ^離子界面活性劑為聚氧乙烯烧基醚硫酸鹽、聚氧乙烯稀基 硫酸鹽、或烷基硫酸鹽。 更3. 如申請專利範圍第1項之清潔劑組合物，其中該成分 f A)包含陰離子界面活性劑與脂肪酸醯胺基丙基甜菜鹼、 g脂肪酸烷醇醯胺或聚氧伸烷基烷基醚。 iO:\66\66877-920226.ptc 第18頁
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28987799A JP3404337B2 (ja) | 1999-10-12 | 1999-10-12 | 水性液状洗浄剤組成物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW589372B true TW589372B (en) | 2004-06-01 |
Family
ID=17748937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW089121098A TW589372B (en) | 1999-10-12 | 2000-10-09 | Aqueous liquid detergent compositions |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6417146B1 (zh) |
| EP (1) | EP1092761B1 (zh) |
| JP (1) | JP3404337B2 (zh) |
| CN (1) | CN1194080C (zh) |
| DE (1) | DE60008335T2 (zh) |
| TW (1) | TW589372B (zh) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3371098B2 (ja) | 1999-11-04 | 2003-01-27 | 花王株式会社 | 洗浄剤組成物 |
| JP3958123B2 (ja) | 2002-06-14 | 2007-08-15 | 花王株式会社 | 水性液体洗浄剤組成物 |
| US20040001797A1 (en) * | 2002-06-21 | 2004-01-01 | Abel Saud | Antimicrobial compositions, products and methods employing same |
| US7569530B1 (en) | 2003-06-20 | 2009-08-04 | The Procter & Gamble Company | Antimicrobial compositions, products and methods employing same |
| JP3625458B2 (ja) * | 2002-08-09 | 2005-03-02 | 花王株式会社 | 洗浄剤 |
| JP3617838B2 (ja) * | 2003-01-28 | 2005-02-09 | 花王株式会社 | 液体洗浄剤組成物 |
| TWI337200B (en) | 2003-01-28 | 2011-02-11 | Kao Corp | Liquid detergent composition |
| DE602004020010D1 (de) * | 2003-04-08 | 2009-04-30 | Kao Corp | Flüssiges Reinigungsmittel |
| JP3987028B2 (ja) * | 2003-12-12 | 2007-10-03 | 花王株式会社 | 液体洗浄剤組成物 |
| US20050260243A1 (en) * | 2004-04-26 | 2005-11-24 | The Procter & Gamble Company | Method of treating microbial plant diseases |
| US7098175B2 (en) * | 2004-06-08 | 2006-08-29 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Aqueous detergent composition containing ethoxylated fatty acid di-ester |
| US7205268B2 (en) * | 2005-02-04 | 2007-04-17 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Low-foaming liquid laundry detergent |
| KR101222646B1 (ko) * | 2005-02-28 | 2013-01-16 | 가오 가부시키가이샤 | 계면활성제 조성물 |
| JP4965821B2 (ja) * | 2005-06-08 | 2012-07-04 | 花王株式会社 | 界面活性剤組成物 |
| JP4831609B2 (ja) * | 2006-05-31 | 2011-12-07 | 株式会社 資生堂 | 洗浄剤組成物 |
| JP4827236B2 (ja) * | 2005-09-15 | 2011-11-30 | 株式会社 資生堂 | 洗浄剤組成物 |
| WO2007032333A1 (ja) * | 2005-09-15 | 2007-03-22 | Shiseido Company, Ltd. | 洗浄剤組成物 |
| US7291582B2 (en) * | 2005-09-20 | 2007-11-06 | Conopco, Inc., D/B/A Unilever | Liquid laundry detergent with an alkoxylated ester surfactant |
| US20070111914A1 (en) * | 2005-11-16 | 2007-05-17 | Conopco, Inc., D/B/A Unilever, A Corporation Of New York | Environmentally friendly laundry method and kit |
| ES2355604T3 (es) * | 2006-06-08 | 2011-03-29 | Unilever N.V. | Detergente líquido de colada con tensoactivo de éster alcoxilado y urea. |
| WO2012177886A2 (en) | 2011-06-23 | 2012-12-27 | The Procter & Gamble Company | Process of forming crystals for use in a personal care composition |
| CN108030742A (zh) * | 2018-01-24 | 2018-05-15 | 合肥华盖生物科技有限公司 | 一种性温抑菌去污护肤洗手液及其制备方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2091162A (en) | 1933-04-11 | 1937-08-24 | Deutsche Hydrierwerke Ag | Fixing agents for perfumes and other volatile compounds |
| US2157022A (en) | 1933-04-15 | 1939-05-02 | Unichem Chemikalien Handels A | Superfatted soap |
| US2900346A (en) | 1956-02-20 | 1959-08-18 | Shell Dev | Foaming detergent compositions |
| CA1081574A (en) | 1975-12-24 | 1980-07-15 | Kenneth L. Jones | Detergent compositions |
| US4178382A (en) | 1978-06-19 | 1979-12-11 | Uniroyal, Inc. | N-substituted triorganostannylhydro-carbylcarboxylic acid hydrazides |
| US4430237A (en) | 1981-10-16 | 1984-02-07 | Colgate-Palmolive Co. | Liquid detergent having high grease removal ability |
| US5011681A (en) | 1989-10-11 | 1991-04-30 | Richardson-Vicks, Inc. | Facial cleansing compositions |
| GB9024162D0 (en) | 1990-11-07 | 1990-12-19 | Unilever Plc | Detergent composition |
| GB9025248D0 (en) | 1990-11-20 | 1991-01-02 | Unilever Plc | Detergent compositions |
| DE4140474C2 (de) | 1991-12-09 | 1995-07-13 | Schuelke & Mayr Gmbh | Hautpflegeadditiv |
| DE4339368A1 (de) | 1993-11-18 | 1995-05-24 | Henkel Kgaa | Glycerinoctylether in Tensidmischungen |
| DE19500688A1 (de) | 1995-01-12 | 1996-07-18 | Henkel Kgaa | Nichtionische Tenside |
| DE19508857A1 (de) | 1995-03-11 | 1996-09-12 | Henkel Kgaa | Verfahren zur Kristallisationsinhibierung von Tensidkonzentraten |
| FR2755852B1 (fr) | 1996-11-15 | 1998-12-24 | Oreal | Utilisation d'un alkylether de glycerol dans une composition cosmetique et/ou dermatologique comme actif pour le traitement de la seborrhee et de l'acne |
| JP4237359B2 (ja) | 1999-10-12 | 2009-03-11 | 花王株式会社 | 洗浄剤組成物 |
-
1999
- 1999-10-12 JP JP28987799A patent/JP3404337B2/ja not_active Expired - Fee Related
-
2000
- 2000-10-09 TW TW089121098A patent/TW589372B/zh not_active IP Right Cessation
- 2000-10-11 US US09/685,083 patent/US6417146B1/en not_active Expired - Fee Related
- 2000-10-12 CN CNB001314041A patent/CN1194080C/zh not_active Expired - Fee Related
- 2000-10-12 EP EP00121387A patent/EP1092761B1/en not_active Expired - Lifetime
- 2000-10-12 DE DE60008335T patent/DE60008335T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE60008335D1 (de) | 2004-03-25 |
| DE60008335T2 (de) | 2004-12-02 |
| EP1092761B1 (en) | 2004-02-18 |
| EP1092761A3 (en) | 2001-08-01 |
| JP3404337B2 (ja) | 2003-05-06 |
| US6417146B1 (en) | 2002-07-09 |
| CN1194080C (zh) | 2005-03-23 |
| CN1291637A (zh) | 2001-04-18 |
| EP1092761A2 (en) | 2001-04-18 |
| JP2001114652A (ja) | 2001-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW589372B (en) | Aqueous liquid detergent compositions | |
| TW592720B (en) | Stabilized hair care products | |
| US8293220B2 (en) | Hair cosmetic | |
| JP2005187359A (ja) | ノンエアゾール型泡吐出容器用毛髪洗浄組成物 | |
| WO2014073456A1 (ja) | シャンプー組成物 | |
| TW200936174A (en) | Hair cosmetic composition | |
| JP2002284627A (ja) | 外用組成物 | |
| TWI338580B (en) | Hair detergent compositions | |
| TW201922215A (zh) | 毛髮化粧料 | |
| TW200404006A (en) | Hair cleansing compositions | |
| US20100168253A1 (en) | Method For Selecting Perfume Ingredient, Method For Formulating Fragrance, And Preference-Enhancing Agent | |
| JPWO2014208162A1 (ja) | シャンプー組成物 | |
| JP2011136966A (ja) | 水中油型乳化化粧料 | |
| JP6952402B2 (ja) | 頭皮用クレンジング化粧料 | |
| TWI331923B (en) | Hair cleansing compositions | |
| JP2008150359A (ja) | 毛髪化粧料 | |
| JP2007169230A (ja) | 整髪剤組成物 | |
| JPH0433999A (ja) | 低刺激性洗浄剤組成物 | |
| JP2006316035A (ja) | シャンプー組成物及びその製造方法 | |
| JP2001131580A (ja) | 洗浄剤組成物 | |
| JP2006298916A (ja) | 毛髪洗浄剤組成物 | |
| JP5192871B2 (ja) | 洗浄剤組成物 | |
| JP2002370941A (ja) | 毛髪化粧料 | |
| JPH0971516A (ja) | 毛髪化粧料 | |
| JP2002121131A (ja) | 安定なパール感を有する洗浄料 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |