TWI278542B - Polytrimethylene terephthalate conjugate fiber and method of preparing the same - Google Patents
Polytrimethylene terephthalate conjugate fiber and method of preparing the same Download PDFInfo
- Publication number
- TWI278542B TWI278542B TW092106147A TW92106147A TWI278542B TW I278542 B TWI278542 B TW I278542B TW 092106147 A TW092106147 A TW 092106147A TW 92106147 A TW92106147 A TW 92106147A TW I278542 B TWI278542 B TW I278542B
- Authority
- TW
- Taiwan
- Prior art keywords
- fiber
- ptt
- viscosity
- poly
- intrinsic viscosity
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 57
- -1 Polytrimethylene terephthalate Polymers 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 23
- 229920002215 polytrimethylene terephthalate Polymers 0.000 title claims abstract description 21
- 238000009987 spinning Methods 0.000 claims abstract description 31
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 21
- SFHBJXIEBWOOFA-UHFFFAOYSA-N 5-methyl-3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical compound O=C1OC(C)COC(=O)C2=CC=C1C=C2 SFHBJXIEBWOOFA-UHFFFAOYSA-N 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 6
- 235000021419 vinegar Nutrition 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002009 diols Chemical class 0.000 claims description 3
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Substances OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- 238000012360 testing method Methods 0.000 claims description 3
- 239000000052 vinegar Substances 0.000 claims description 3
- 229920000265 Polyparaphenylene Polymers 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229960002380 dibutyl phthalate Drugs 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 229920000470 poly(p-phenylene terephthalate) polymer Polymers 0.000 claims 1
- AYEFIAVHMUFQPZ-UHFFFAOYSA-N propane-1,2-diol;prop-2-enoic acid Chemical compound CC(O)CO.OC(=O)C=C AYEFIAVHMUFQPZ-UHFFFAOYSA-N 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 11
- 229920000728 polyester Polymers 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 210000004209 hair Anatomy 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- FGRBYDKOBBBPOI-UHFFFAOYSA-N 10,10-dioxo-2-[4-(N-phenylanilino)phenyl]thioxanthen-9-one Chemical compound O=C1c2ccccc2S(=O)(=O)c2ccc(cc12)-c1ccc(cc1)N(c1ccccc1)c1ccccc1 FGRBYDKOBBBPOI-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Natural products CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 241000272194 Ciconiiformes Species 0.000 description 1
- 206010011469 Crying Diseases 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- NHLPZIWAVXUJIM-UHFFFAOYSA-N [Bi].C(C(C)O)O Chemical compound [Bi].C(C(C)O)O NHLPZIWAVXUJIM-UHFFFAOYSA-N 0.000 description 1
- 150000001622 bismuth compounds Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical group O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 description 1
- 229930004069 diterpene Natural products 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- PFGBJNZEYAOYJA-UHFFFAOYSA-N formic acid;prop-1-ene Chemical group CC=C.OC=O PFGBJNZEYAOYJA-UHFFFAOYSA-N 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- GULAEPPQYOTQDE-UHFFFAOYSA-N phthalic acid;propane-1,2-diol Chemical compound CC(O)CO.OC(=O)C1=CC=CC=C1C(O)=O GULAEPPQYOTQDE-UHFFFAOYSA-N 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- OJTDGPLHRSZIAV-UHFFFAOYSA-N propane-1,2-diol Chemical compound CC(O)CO.CC(O)CO OJTDGPLHRSZIAV-UHFFFAOYSA-N 0.000 description 1
- 229940116423 propylene glycol diacetate Drugs 0.000 description 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
- D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
- D02G1/0213—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting after drawing the yarn on the same machine
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
- D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
- D02G1/022—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting while simultaneously drawing the yarn
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
- D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
- D02G1/0266—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting false-twisting machines
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Multicomponent Fibers (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2002-0029202A KR100481296B1 (ko) | 2002-05-27 | 2002-05-27 | 폴리트리메틸렌테레프탈레이트 복합섬유 및 그 제조방법 |
| KR1020020064897A KR20040036094A (ko) | 2002-10-23 | 2002-10-23 | 고권축 특성을 갖는 폴리트리메틸렌테레프탈레이트복합가연섬유 및 그 제조방법 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200408739A TW200408739A (en) | 2004-06-01 |
| TWI278542B true TWI278542B (en) | 2007-04-11 |
Family
ID=29586086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW092106147A TWI278542B (en) | 2002-05-27 | 2003-03-20 | Polytrimethylene terephthalate conjugate fiber and method of preparing the same |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20050233140A1 (fr) |
| EP (1) | EP1518012A4 (fr) |
| JP (1) | JP2005527715A (fr) |
| CN (1) | CN1656261A (fr) |
| TW (1) | TWI278542B (fr) |
| WO (1) | WO2003100143A1 (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100573077B1 (ko) * | 2003-12-19 | 2006-04-24 | 주식회사 효성 | 폴리트리메틸렌테레프탈레이트, 상기폴리트리메틸렌테레프탈레이트의 제조방법 및 상기폴리트리메틸렌테레프탈레이트로 제조한폴리트리메틸렌테레프탈레이트 섬유 |
| WO2005100651A1 (fr) * | 2004-03-23 | 2005-10-27 | Solutia, Inc. | Fibre polyester etiree electroconductrice a deux composants et son procede de fabrication |
| US7447826B2 (en) * | 2004-03-31 | 2008-11-04 | Intel Corporation | Receive buffer in a data storage system |
| US7366802B2 (en) * | 2004-10-29 | 2008-04-29 | Intel Corporation | Method in a frame based system for reserving a plurality of buffers based on a selected communication protocol |
| US7310932B2 (en) * | 2005-02-11 | 2007-12-25 | Invista North America S.A.R.L. | Stretch woven fabrics |
| CN101490318B (zh) * | 2006-07-27 | 2012-09-05 | 欧瑞康纺织有限及两合公司 | 用于制造卷曲的合成丝线的方法 |
| US20160167334A1 (en) | 2014-11-06 | 2016-06-16 | The Procter & Gamble Company | Crimped Fiber Spunbond Nonwoven Webs/Laminates |
| WO2016073727A1 (fr) | 2014-11-06 | 2016-05-12 | The Procter & Gamble Company | Articles absorbants comprenant des stratifiés face au vêtement |
| KR101943989B1 (ko) | 2015-06-05 | 2019-01-30 | 삼성전자주식회사 | 데이터를 송수신하는 방법, 서버 및 단말기 |
| WO2018152272A1 (fr) | 2017-02-16 | 2018-08-23 | The Procter & Gamble Company | Articles absorbants avec des substrats ayant des motifs répétitifs d'ouvertures comprenant une pluralité d'unités récurrentes |
| US12127925B2 (en) | 2018-04-17 | 2024-10-29 | The Procter & Gamble Company | Webs for absorbent articles and methods of making the same |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1075689A (en) * | 1964-07-24 | 1967-07-12 | Du Pont | Textile yarn |
| KR19980046754U (ko) * | 1996-12-28 | 1998-09-25 | 박병재 | 원 터치식 윈드쉴드 글래스 제습장치 |
| KR19980049300U (ko) * | 1996-12-30 | 1998-10-07 | 김영귀 | 키이 실린더 장착구조 |
| JP2000017575A (ja) * | 1998-06-24 | 2000-01-18 | Toray Ind Inc | 改質ポリエステル系繊維構造物およびその製造方法 |
| JP2000017576A (ja) * | 1998-06-26 | 2000-01-18 | Toray Ind Inc | 改質ポリエステル系繊維構造物およびその製造方法 |
| DE19834008C2 (de) * | 1998-07-29 | 2000-11-30 | Johns Manville Int Inc | Monofile Bikomponentenfäden des Kernmanteltyps, Verfahren zu deren Herstellung und deren Verwendung |
| ES2322125T3 (es) * | 2000-05-18 | 2009-06-17 | Asahi Kasei Kabushiki Kaisha | Hilo teñido. |
| CN1243861C (zh) * | 2001-02-02 | 2006-03-01 | 旭化成株式会社 | 后加工性能优良的复合纤维及其制造方法 |
| EP1394296B1 (fr) * | 2001-04-17 | 2011-01-12 | Teijin Fibers Limited | Fil texture par fausse torsion en fibre de polyester composite et procede de production |
| CN1273659C (zh) * | 2001-09-18 | 2006-09-06 | 旭化成纤维株式会社 | 聚酯系复合纤维纬纱管及其制造方法 |
| US6846560B2 (en) * | 2002-05-27 | 2005-01-25 | Asahi Kasei Kabushiki Kaisha | Conjugate fiber and method of producing same |
| US6641916B1 (en) * | 2002-11-05 | 2003-11-04 | E. I. Du Pont De Nemours And Company | Poly(trimethylene terephthalate) bicomponent fibers |
| MXPA04012278A (es) * | 2002-12-23 | 2005-02-25 | Du Pont | Proceso de fibra bicomponente de poli(tereftalato de trimetileno). |
-
2003
- 2003-03-11 JP JP2004507580A patent/JP2005527715A/ja active Pending
- 2003-03-11 EP EP03708717A patent/EP1518012A4/fr not_active Withdrawn
- 2003-03-11 US US10/516,235 patent/US20050233140A1/en not_active Abandoned
- 2003-03-11 CN CN03811542.5A patent/CN1656261A/zh active Pending
- 2003-03-11 WO PCT/KR2003/000470 patent/WO2003100143A1/fr not_active Ceased
- 2003-03-20 TW TW092106147A patent/TWI278542B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2003100143A8 (fr) | 2005-03-24 |
| EP1518012A4 (fr) | 2006-12-06 |
| EP1518012A1 (fr) | 2005-03-30 |
| TW200408739A (en) | 2004-06-01 |
| US20050233140A1 (en) | 2005-10-20 |
| JP2005527715A (ja) | 2005-09-15 |
| CN1656261A (zh) | 2005-08-17 |
| WO2003100143A1 (fr) | 2003-12-04 |
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