TWI322200B - - Google Patents

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Publication number: TWI322200B
Authority: TW; Taiwan
Prior art keywords: copper; layer; magnesium alloy; cyanide; aqueous solution
Prior art date: 2006-07-07

Application number

TW95124895A

Other languages

English (en)

Chinese (zh)

Other versions

TW200639279A (en

Original Assignee

Univ Chang Gung

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-07-07

Filing date

2006-07-07

Publication date

2010-03-21

2006-07-07 Application filed by Univ Chang Gung filed Critical Univ Chang Gung

2006-07-07 Priority to TW095124895A priority Critical patent/TW200639279A/zh

2006-11-16 Publication of TW200639279A publication Critical patent/TW200639279A/zh

2010-03-21 Application granted granted Critical

2010-03-21 Publication of TWI322200B publication Critical patent/TWI322200B/zh

Links

229910000861 Mg alloy Inorganic materials 0.000 claims description 39
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 36
229910052802 copper Inorganic materials 0.000 claims description 36
239000010949 copper Substances 0.000 claims description 36
238000000034 method Methods 0.000 claims description 31
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 29
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 27
229910001431 copper ion Inorganic materials 0.000 claims description 26
239000007864 aqueous solution Substances 0.000 claims description 21
238000004070 electrodeposition Methods 0.000 claims description 20
229910052751 metal Inorganic materials 0.000 claims description 20
239000002184 metal Substances 0.000 claims description 20
239000000203 mixture Substances 0.000 claims description 19
238000007747 plating Methods 0.000 claims description 15
229910052759 nickel Inorganic materials 0.000 claims description 14
238000005260 corrosion Methods 0.000 claims description 13
239000000243 solution Substances 0.000 claims description 11
239000002253 acid Substances 0.000 claims description 10
239000000654 additive Substances 0.000 claims description 10
230000000996 additive effect Effects 0.000 claims description 10
229910045601 alloy Inorganic materials 0.000 claims description 10
239000000956 alloy Substances 0.000 claims description 10
230000007797 corrosion Effects 0.000 claims description 9
239000003795 chemical substances by application Substances 0.000 claims description 7
238000005406 washing Methods 0.000 claims description 7
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
150000003839 salts Chemical class 0.000 claims description 6
239000000758 substrate Substances 0.000 claims description 6
229910000365 copper sulfate Inorganic materials 0.000 claims description 5
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 5
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 4
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
238000005238 degreasing Methods 0.000 claims description 4
PEVJCYPAFCUXEZ-UHFFFAOYSA-J dicopper;phosphonato phosphate Chemical compound [Cu+2].[Cu+2].[O-]P([O-])(=O)OP([O-])([O-])=O PEVJCYPAFCUXEZ-UHFFFAOYSA-J 0.000 claims description 4
HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 4
239000001488 sodium phosphate Substances 0.000 claims description 4
239000001433 sodium tartrate Substances 0.000 claims description 4
229960002167 sodium tartrate Drugs 0.000 claims description 4
235000011004 sodium tartrates Nutrition 0.000 claims description 4
239000011975 tartaric acid Substances 0.000 claims description 4
235000002906 tartaric acid Nutrition 0.000 claims description 4
229910052719 titanium Inorganic materials 0.000 claims description 4
239000010936 titanium Substances 0.000 claims description 4
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
229910000406 trisodium phosphate Inorganic materials 0.000 claims description 4
235000019801 trisodium phosphate Nutrition 0.000 claims description 4
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
239000007788 liquid Substances 0.000 claims description 3
239000011707 mineral Substances 0.000 claims description 3
AVTYONGGKAJVTE-OLXYHTOASA-L potassium L-tartrate Chemical compound [K+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O AVTYONGGKAJVTE-OLXYHTOASA-L 0.000 claims description 3
LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 claims description 3
239000001472 potassium tartrate Substances 0.000 claims description 3
229940111695 potassium tartrate Drugs 0.000 claims description 3
235000011005 potassium tartrates Nutrition 0.000 claims description 3
239000001476 sodium potassium tartrate Substances 0.000 claims description 3
235000011006 sodium potassium tartrate Nutrition 0.000 claims description 3
229960001367 tartaric acid Drugs 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 2
239000010439 graphite Substances 0.000 claims description 2
229910002804 graphite Inorganic materials 0.000 claims description 2
239000004519 grease Substances 0.000 claims description 2
FKWSMBAMOQCVPV-UHFFFAOYSA-N magnesium dicyanide Chemical compound [Mg+2].N#[C-].N#[C-] FKWSMBAMOQCVPV-UHFFFAOYSA-N 0.000 claims description 2
229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 2
239000010935 stainless steel Substances 0.000 claims description 2
229910001220 stainless steel Inorganic materials 0.000 claims description 2
238000004381 surface treatment Methods 0.000 claims description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
239000011230 binding agent Substances 0.000 claims 1
235000015165 citric acid Nutrition 0.000 claims 1
238000000151 deposition Methods 0.000 claims 1
239000002019 doping agent Substances 0.000 claims 1
239000002659 electrodeposit Substances 0.000 claims 1
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 1
239000007784 solid electrolyte Substances 0.000 claims 1
SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 claims 1
239000010410 layer Substances 0.000 description 24
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 11
239000011248 coating agent Substances 0.000 description 8
238000000576 coating method Methods 0.000 description 8
238000009713 electroplating Methods 0.000 description 8
238000002203 pretreatment Methods 0.000 description 8
238000005516 engineering process Methods 0.000 description 6
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 6
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
231100000614 poison Toxicity 0.000 description 4
239000003440 toxic substance Substances 0.000 description 4
XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 3
229910000831 Steel Inorganic materials 0.000 description 3
230000006378 damage Effects 0.000 description 3
238000001035 drying Methods 0.000 description 3
QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000010959 steel Substances 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
206010036790 Productive cough Diseases 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
238000013461 design Methods 0.000 description 2
238000011161 development Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000007772 electroless plating Methods 0.000 description 2
238000003912 environmental pollution Methods 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
230000010287 polarization Effects 0.000 description 2
210000003802 sputum Anatomy 0.000 description 2
208000024794 sputum Diseases 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
241000282412 Homo Species 0.000 description 1
240000007594 Oryza sativa Species 0.000 description 1
235000007164 Oryza sativa Nutrition 0.000 description 1
239000005708 Sodium hypochlorite Substances 0.000 description 1
125000002015 acyclic group Chemical group 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011247 coating layer Substances 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
-1 copper metal complex ions Chemical class 0.000 description 1
238000005536 corrosion prevention Methods 0.000 description 1
230000005611 electricity Effects 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000005242 forging Methods 0.000 description 1
238000009472 formulation Methods 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
230000003779 hair growth Effects 0.000 description 1
230000017525 heat dissipation Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000005065 mining Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
238000010422 painting Methods 0.000 description 1
239000011148 porous material Substances 0.000 description 1
235000009566 rice Nutrition 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
239000013585 weight reducing agent Substances 0.000 description 1

Landscapes

Electroplating And Plating Baths Therefor (AREA)
Electroplating Methods And Accessories (AREA)
ing And Chemical Polishing (AREA)

TW095124895A 2006-07-07 2006-07-07 A composition and a method of aqueous solution for an electrodeposited copper layer of cyanide-free compound magnesium alloy surface TW200639279A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
TW095124895A TW200639279A (en)	2006-07-07	2006-07-07	A composition and a method of aqueous solution for an electrodeposited copper layer of cyanide-free compound magnesium alloy surface

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
TW095124895A TW200639279A (en)	2006-07-07	2006-07-07	A composition and a method of aqueous solution for an electrodeposited copper layer of cyanide-free compound magnesium alloy surface

Publications (2)

Publication Number	Publication Date
TW200639279A TW200639279A (en)	2006-11-16
TWI322200B true TWI322200B (fr)	2010-03-21

Family

ID=45073921

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW095124895A TW200639279A (en)	2006-07-07	2006-07-07	A composition and a method of aqueous solution for an electrodeposited copper layer of cyanide-free compound magnesium alloy surface

Country Status (1)

Country	Link
TW (1)	TW200639279A (fr)

2006
- 2006-07-07 TW TW095124895A patent/TW200639279A/zh not_active IP Right Cessation

Also Published As

Publication number	Publication date
TW200639279A (en)	2006-11-16

Legal Events

Date	Code	Title	Description
2017-12-21	MM4A	Annulment or lapse of patent due to non-payment of fees

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