TWI337632B - - Google Patents
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- TWI337632B TWI337632B TW96142089A TW96142089A TWI337632B TW I337632 B TWI337632 B TW I337632B TW 96142089 A TW96142089 A TW 96142089A TW 96142089 A TW96142089 A TW 96142089A TW I337632 B TWI337632 B TW I337632B
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
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- 239000005977 Ethylene Substances 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
1337632 九、發明說明: 【發明所屬之技術領域】 本發明係有關-種機紐纖維、其製法及以該纖維製成 品’尤指-種採用機於丨生微粒、熱可塑彈性體⑽)與聚、細 二次混練,及熔融抽絲而製成纖維,並可以該纖維織製:二:經 而具有除臭、抗菌、防霉、或可產生負離子或遠紅外線的功处、 增進織品過濾.效果並提升空氣品質。 ' b 【先前技術】 由於環境污染越來越嚴重,空氣中·子數越來越少,再者 -般人每天生活在室内環境中時間幾乎佔了百分之八十,在有/ 空間内’確做魅氣品質實為生活之必要,而室_境中及與 人體接近的網材例如空氣_、紗窗網等則變成維護人體健康^ 很重要原因m氣過濾網來改善^氣品質,為目前已知最經 濟有效方式之-。含機能性.如可產生負離子的紡織產品,: 於對於人體健康雜大幫助,已受顺織錢細關的重視和 關注。惟因目前舰紡織技術尚棚發出較佳而可製出可有效產 生負離子的織物,因而大部份健採用負離子產生器來產生_ 子。然而’負離子產生器會產生臭氧(〇3),對人體有害,必需低 於〇.12Ppm以下,而且所產生負離子範圍僅在一米以内,且負離 子之時效性也有限。 因鑑於習用無一種具有較佳機能性的纖維及織物的製造技 術,本發明人等乃積極投入研發,且已研發多年,並不斷改良與 進步。多年削研發而有-定成果,才於20叫提出第一代的專利 申請,其技術如台灣申請第93丨2_號專利案,該案目前已獲准 專利。此外,在經過多次的試驗與改良又有新研發技術產出,乃 又申請美國專利謂⑽號案。近來又有新的技術研發完成, 因而提出本案之申請。 目前習用也有抗菌除臭的織品或纖維技術,例如美國第 4,784,909號專利案’為抗菌除臭纖維的技術,其主要是在纖維内 添加=美國第6,观斯號專利案,係為抗_品的技術,其 主要疋以織品製成紐,齡νσ則包括有熱雜娜樹脂及抗菌 劑。美國第5, 690, 922號專利案,為除臭纖維的技術,其纖維包 括四價的金__和二·金屬氫氧化物。然而,該等前案技 術均與本㈣技補徵利。本發㈣树日狀料研究及製造 經驗的研發成果’且經實驗證明確具實用功效,已符合專利要件, 爰提出專利申請,以保障研發心血。 本發明係為改善現有環境污染而針對改善室内空氣品負 lAQUnd⑽AirQuaiity)、維護健康、養生舒親境目的進而则 改善現有纖維結構,而發展出—種長效型多機能性自减網,^ 2能性纖維能有效_環境中風、光、水、鮮自然物理基礎景 曰’而错由空氣流動及冷熱差、纖維震動摩擦、光觸媒催化制 理而激發纖維中多功能機能性錄本身壓電效應、熱電效應、^ 電效應、催化賴、顧效應、_效應简航分有效殺菌 抗i、防霉、防蜗、產生負離子、遠紅外線、防火、抗靜電、右 1337632 , 電磁波及排除異味、毛髮、TV〇Cs、ρΜχ、C〇、c〇2、曱醛(HCHO)、 臭氧(〇3)、氨氣(NH3)、乙醛(ch3cho)、醋酸(ch3cooh)等污染 物等符合健康自動淨化空氣功效。 【發明内容】1337632 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a machine-made fiber, a method for producing the same, and a product made of the fiber, in particular, a machine for producing twin particles, a thermoplastic elastomer (10), and Poly, fine secondary mixing, and melt spinning to make fibers, and can be woven by the fiber: Second: deodorizing, antibacterial, anti-mildew, or can produce negative ions or far infrared rays, enhance fabric filtration The effect and improve the air quality. ' b 【Prior Art】 As the environmental pollution is getting more and more serious, the number of children in the air is getting less and less. In addition, the average person lives in the indoor environment for almost 80% of the time, in / space. 'It is really necessary to make masculine quality, and the mesh material in the room _ and the human body close to the human body, such as air _, screen window net, etc., becomes the maintenance of human health ^ very important reason m gas filter to improve the quality of the gas, For the most cost-effective way known at present. Including functional properties. For example, textile products that can produce negative ions: For the help of human health, it has been paid attention to and paid attention to by the money. However, because the current ship textile technology is still better, it can produce fabrics that can effectively produce negative ions. Therefore, most of them use negative ion generators to generate _ sub. However, the negative ion generator produces ozone (〇3), which is harmful to the human body, must be lower than 〇.12Ppm, and the negative ion range generated is only within one meter, and the time-dependent nature of the negative ion is also limited. The present inventors have actively invested in research and development, and have been researching and developing for many years, and have continuously improved and improved, in view of the fact that there is no manufacturing technique for fibers and fabrics having a better function. After many years of research and development, the company has filed a first-generation patent application, and its technology, such as Taiwan's application for the 93rd-2_ patent case, has been approved. In addition, after several trials and improvements, there were new developments in technology production, and it was applied for the US patent (10). Recently, new technology research and development has been completed, and the application for this case has been filed. At present, there are also antibacterial and deodorizing fabrics or fiber technologies, such as the US Patent No. 4,784,909, which is an antibacterial and deodorizing fiber technology, which is mainly added in the fiber = the sixth in the US, the patent application, the anti- The technology of the product is mainly made of fabric, and the age of νσ includes thermal resin and antibacterial agent. U.S. Patent No. 5,690,922, which is a technique for deodorizing fibers, includes fibers of tetravalent gold and titanium hydroxide. However, these prior art techniques are complementary to this (4) technique. The research and development results of the research and manufacturing experience of the tree (4) tree materials have been verified and have practical effects. They have met the patent requirements and have filed patent applications to protect the research and development. The invention develops a long-acting multi-functional self-reduction net for improving the existing environmental pollution, aiming at improving the indoor air product negative lAQUnd (10) AirQuaiity), maintaining health, maintaining health and comforting the living environment, and improving the existing fiber structure, ^ 2 Energy fiber can be effective _ environment stroke, light, water, fresh natural physical basis 而 而 由 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气 空气, thermoelectric effect, electro-electric effect, catalytic reliance, Gu effect, _ effect, simple voyage, effective bactericidal anti-i, anti-mildew, anti-worm, negative ion, far infrared, fire, anti-static, right 1367362, electromagnetic wave and eliminate odor, hair , TV〇Cs, ρΜχ, C〇, c〇2, furfural (HCHO), ozone (〇3), ammonia (NH3), acetaldehyde (ch3cho), acetic acid (ch3cooh) and other contaminants in line with healthy automatic purification Air efficiency. [Summary of the Invention]
本發明之第一目的,在於提供一種可製成具較佳機能性纖維 的方法。其方法特徵,係採用多功能機能性微粒、熱可塑彈性體 (TPE)與料類(pGiyGlefine)以較佳㈣麻煉及減製成纖維, 藉由熱可塑彈性體的彈性作用,*使其機能性微粒得以發揮最佳 的效果本發明方法所製成的纖維含有佔整體母粒重量之1〜45 %重量百分比的多功能機能性微粒(如電氣石、奈米金屬粒子光 觸媒酵素、微膠囊等微粒),以該纖維織製成網體,並組成機 能性纖維,可使室内空氣品質『IAQ』,藉由空氣流動及冷熱差、 纖維震動摩擦等原理而激發多功能機能性微粒本身壓電效應、熱 電放應、催化效應、光電效應、催化效應、觸媒效應、緩釋效應、 ^味中和以達到充分有效殺菌、抗菌、防霉、_、產生負離子、 遠、·工外線、防火、抗靜電、抗電磁波及異味、毛m〇Cs、 ΡΜχ等污祕康自動淨化空氣功效。 尽《之第二目的’在於提供—種可製成轉效益較高而可 2負離子之纖_方法。其方法特徵,係所_的機能性微粒 電氣石,藉由熱可塑雜體的彈性伽,使纖維所織成 有效她亀動,触物峨石得以 7 的方之第二目的’在於提供一種可製成具抗菌效能之纖維 '其方法特徵’係所採用的機能性微粒可為奈米銀,亦可 為酵素。 t 乡本&明之第四目的’在於提供—種可持久產生植物芳香之纖 I的方法。其方法特徵,係所制的雜性微粒為微膠囊,且於 微膠囊内包財祕萃取精油,藉由熱可娜性體適當的阻擋精 油的釋放’故可達到使纖維㈣持久的目的。 A如上述健康養生需求,藉由空紐動、冷熱差、纖維震動摩 ir、等原理或m轉,*使乡功賴雛微喊雜產生各類 功效而形成長效型可水洗機能性健康養生自淨淚網。 【實施方式] 本發明主要讀對具有機能性之纖_研發與試驗。其基本 特欲的技術係本發明的纖維由包括有聚稀類㈣㈣e如e)、熱可 塑彈f·生體(TPE)、多舰機能性微粒絲材混賴成機能性纖維, 藉由空氣流動、冷熱差、纖維震鱗擦、陽光照射等原理,而強 化激發多魏機祕錄本身壓f效應、熱電效應、光雜效應、 觸媒效應、緩釋效應等以達到充分有效殺菌、抗菌、防霉、防蜗、 產生負離子、遠紅外線、防火、抗靜電、抗電磁波及排除異味、 毛髮、TVOCs、PMx等污染物等徤康自動淨化空氣功效。利用其 纖維織成濾材3D結構、蜂巢式等並能降低風阻、提高承載能力、 提高過雜能、絲花粉、塵埃,而達成長效型可水洗魏、驗 等環境需求及環保節能等功效者。 1337632 為便於審查貞了解本發明的可躲,轉具體實關詳細說明 如后。 _ A·本發明的基本技射特徵 本發明主要是針财有機紐之_做研發與試驗。其基本 特徵的技術,係本發明的纖維由包括有機能性微粒、熱可塑彈性 體與聚烯類所共混製造而成,進崎纖維具有縣賴能性,並 可供織造成織品等。其巾,該織品可以是空氣過濾網 、或鞋塾、 或帽子、或紗窗、或窗簾、或電視護目罩。 B·關於本發明的纖維 本發明之纖維,主要為包括機能性微粒(該機能性微粒可為次 微米電氣石粒子、郷覆齡萃取精油、奈米銀粒子、或酵 素)熱可塑彈性體(TPE)與聚烯類(p〇iy〇iefme)(例如聚丙烯或聚乙 烯)共混而成的纖維,藉由熱可塑彈性體的添加,而使本發明之纖 維具有較佳的與摩擦雜’進崎縣加的航性微粒產生 較佳的效能。 本發明第一種具體實施例,機能性微粒採用粒徑為1微米至 100奈米之範圍内的電氣石,所製成的纖維線徑為〇〇1111111〜 3mm。其中,電氣石粒子含量佔整個纖維的1〜1〇%重量百分比的 $il圍内,電氣石的遠紅外輻射率:〇 948哗(3 4刺〇2w/m2),粒徑 分佈:D50(平均粒徑493nm) ’經實驗發現電氣石粒子佔整個纖維 的3%重量百分比的經濟效益最佳。藉以使透過其纖維所織成的網 體具有產生負離子、遠紅外線、自淨、除臭、抗靜電、防電磁波 9 f337632 等功效。並可加入奈㈣炭、氧化鋅、氧化銅、氧化鐵、氧化石夕、 氧化鶴、氧化猛、氧化録、氧化錄等—種或多種微㈣淨因子。 本發明第二種具體實施例,機能性微粒採用奈米銀粒子,藉 以產生抗菌、防霉魏,其所添加的奈練佔整個纖料1〜· 重量百分比。藉贿其纖賴織成的哺具有難、抗菌、防霉、。 眺等健康功能1可加入甲殼素、酵素、奈米貴金屬銅、辞、 金、鉑、鈀、鈮等一種或多種微粒殺菌、抗菌、防霉因子。 本發明製造機祕人造纖_:^法,主要是準備製造母粒的 材料,包括複數個笫一聚烯類(p〇ly〇lefme;^^片作為基材其第一 聚烯類佔整體母粒重量之20%〜95%重量百分比,其可以是分子 里為3·15χ10 g/mole的聚丙稀’或是分子量為1 $〜2 5x!〇5g/ mole的聚乙烯碎片(其中,本發明以下各項試驗係以聚丙烯佔8〇 %重量百分比為具體實施例做說明),和佔整體母粒重量之1%〜 45 %重量百分比的機能性微粒(本段以次微米電氣石粒子為例做 s兒明)’及佔整體母粒重量之1%〜40%重量百分比的熱可塑彈性 體(TPE或EPDM),以雙螺桿混練造粒而製成複數個母粒,再取該 複數個母粒及額外且相同於第一聚烯類的第二聚烯類,將該複數 個母粒與該第二聚烯類混練而成一合成材料,使該合成材料卡的 最終機能性微粒和熱可塑彈性體的含量為佔整體合成材料重量之 1〜32%重量百分比(其中電氣石的含量為佔整體合成材料重量之 1〜10%的重量百分比),再使該合成材料經抽絲、冷卻、熱延伸、 1337632 加熱定型製成纖維。其中,抽絲溫度為20(TC〜300。(:的範圍内(本 發明具體操作之實施例中抽絲溫度聚丙烯2〇〇t:〜25(TC增溫,聚 乙烯25〇°C〜3〇〇。〇 ’牵伸倍率3〜8倍(本發明具體操作的實施例 中牽伸倍率為6倍)1熱延伸溫度1〇〇〜i6〇〇C (本發明具體操作之 實施例中係以l〇(TC熱水延伸),加熱定型溫度為冗勺〜丨⑽。c。 上述熔融抽絲是將該合成材料加熱熔融,熔融從噴絲孔擠出 進入空氣,在空氣中冷卻的同時,以一定速度捲曲,在該階段合 成材料熔體細化的同時凝固,即形成纖維,再進行熱拉伸,以提 高纖維的力科性能。親抽絲工程,是將在聚合工序製得的具 有可纺性的聚合物在其·以上的溫度從柄板細孔擠出 ,冷卻 細化成絲狀固體,同時進行卷繞。 不赞明機能性微粒的實施例 本發明為了能賴維產生負離子,其所_的機能性微粒為 次微米電氣石粒子。本發明為了能產生抗防霉效果,其所採 用的機能性錄為奈練奸,灿后崎示的試驗結果顯示本 發明亦具雜韻抗狀哺絲。財,树日㈣了能產生盆 他機能效果,在纖射混練添加⑽祕微㈣微職(在本發明 實驗例中是含有微膠囊1%重量A first object of the present invention is to provide a method of making fibers having better functional properties. The method features a multi-functional functional particle, a thermoplastic elastomer (TPE) and a material (pGiyGlefine) to better (4) numb and reduce the fiber, by the elastic action of the thermoplastic elastomer, The functional microparticles can exert the best effect. The fiber produced by the method of the invention contains 1-45% by weight of multifunctional functional particles (such as tourmaline, nano metal photocatalyst, microcapsules). The particles are woven into the mesh body and composed of functional fibers, which can make the indoor air quality "IAQ", and stimulate the multi-function functional particles by the principle of air flow, cold and heat difference, fiber vibration friction and the like. Electrical effect, thermoelectric discharge, catalytic effect, photoelectric effect, catalytic effect, catalytic effect, slow release effect, neutralization of taste to achieve full and effective sterilization, antibacterial, anti-mildew, _, negative ion, far, outside line, Fireproof, anti-static, anti-electromagnetic wave and odor, hair m〇Cs, sputum and other smudges automatically purify the air. The second purpose of the invention is to provide a fiber-making method that can be made into a high-yield and two-negative ion. The method is characterized in that the functional particulate tourmaline, by means of the elastic gamma of the thermoplastic hybrid, allows the fiber to be woven into effective swaying, and the second purpose of the touchstone is to provide a The functional microparticles that can be made into antibacterial fibers can be either nano silver or an enzyme. t Township & Ming's fourth purpose is to provide a method for producing a long-lasting plant fragrance. The method is characterized in that the prepared micro-capsules are microcapsules, and the micro-capsules are encapsulated with the essential oil for extracting the essential oil, and the release of the essential oil is appropriately blocked by the thermonic body, so that the fiber (four) can be sustained. A. As mentioned above, the health and health needs, through the principle of air movement, cold and heat, fiber vibration, ir, etc., or m turn, * make the township squatting and shouting to produce various effects and form a long-lasting type of washable functional health and self-cleaning Tears. [Embodiment] The present invention mainly reads the development and testing of functional fibers. The basic technical skill of the present invention is that the fibers of the present invention are composed of a polythene (four) (four) e such as e), a thermoplastic elastomer f. (TPE), and a multi-ship functional particulate material, which are mixed into functional fibers by air. The principles of flow, cold and heat, fiber scale rubbing, sun exposure, etc., and strengthen the excitation of the multi-wei machine secrets itself f pressure effect, thermoelectric effect, photo-electric effect, catalytic effect, slow release effect, etc. to achieve full effective sterilization, antibacterial , anti-mildew, anti-worm, negative ion, far infrared, fire, anti-static, anti-electromagnetic wave and eliminate odor, hair, TVOCs, PMx and other pollutants, such as Kang Kang automatic air purification. The use of fiber woven into the filter material 3D structure, honeycomb type, etc. can reduce wind resistance, improve load carrying capacity, improve excess energy, silk pollen, dust, and achieve long-acting water washing, inspection and other environmental requirements and environmental protection and energy saving effects . 1337632 For the purpose of reviewing, you can understand the hiding of the present invention, and the specific details are as follows. _ A· The basic technical characteristics of the present invention The present invention is mainly for the development and testing of the affluent organic xin. The technique of the basic feature is that the fiber of the present invention is produced by blending organic energy particles, a thermoplastic elastomer, and a polyolefin. The mesh fiber has a county property and can be woven into a fabric. The towel may be an air filter, or a shoe last, or a hat, or a screen, or a curtain, or a TV goggle. B. Regarding the fiber of the present invention, the fiber of the present invention mainly comprises a thermoplastic microparticle (including functional microparticles, sub-micron tourmaline particles, strontium-coated essential oil, nano-silver particles, or an enzyme). TPE) a fiber blended with a polyene (for example, polypropylene or polyethylene), the fiber of the present invention has a better blend of friction and friction by the addition of a thermoplastic elastomer. 'The advancing particles of the Jinqi County add better performance. In the first embodiment of the present invention, the functional particles are made of tourmaline having a particle diameter of from 1 μm to 100 nm, and the fiber diameter is 〇〇1111111 to 3 mm. Among them, the content of tourmaline particles accounts for 1 to 1% by weight of the entire fiber in the range of $ il, the far infrared radiance of tourmaline: 〇 948 哗 (3 4 locust 2w / m2), particle size distribution: D50 ( Average particle size 493 nm) 'The experimental results show that tourmaline particles account for 3% by weight of the entire fiber. Therefore, the mesh woven through the fibers has the effects of generating negative ions, far infrared rays, self-cleaning, deodorizing, antistatic, and anti-electromagnetic waves 9 f337632. It can be added to na (4) carbon, zinc oxide, copper oxide, iron oxide, oxidized stone, oxidized crane, oxidized, oxidized, oxidized, etc. - or a plurality of micro (four) net factors. In a second embodiment of the present invention, the functional microparticles are made of nano-silver particles, thereby producing antibacterial and anti-mildew, and the added naphtha is 1% by weight of the entire fiber. It is difficult, antibacterial, and mildewproof to borrow bribes.健康 and other health functions 1 can be added to chitin, enzymes, nano precious metal copper, rhodium, gold, platinum, palladium, ruthenium and other micro-organisms, antibacterial, anti-mold factors. The invention discloses a machine-made rayon fiber _: method, which is mainly a material for preparing a masterbatch, and includes a plurality of fluorene-based olefins (p〇ly〇lefme; 20% to 95% by weight of the weight of the masterbatch, which may be 3·15χ10 g/mole of polypropylene in the molecule or a piece of polyethylene having a molecular weight of 1 $2 to 2 5x!〇5g/mol (wherein The following tests are based on a specific example of polypropylene in an amount of 8 % by weight, and 1% to 45 % by weight of functional particles of the total weight of the masterbatch (this sub-micron tourmaline particles) For example, _ _ _ _ _ and the total weight of the masterbatch weight of 1% ~ 40% by weight of thermoplastic elastomer (TPE or EPDM), two-screw mixing granulation to make a plurality of masterbatch, and then take a plurality of masterbatches and a second polyolefin which is additionally and identical to the first polyolefin, and the plurality of masterbatch and the second polyolefin are kneaded to form a synthetic material, so that the final functional particles of the synthetic material card And the content of the thermoplastic elastomer is from 1 to 32% by weight based on the total weight of the composite material ( The content of the tourmaline is 1% to 10% by weight based on the weight of the total synthetic material, and the synthetic material is subjected to spinning, cooling, heat extension, and heat treatment of 1337632 to form a fiber, wherein the spinning temperature is 20 ( TC ~ 300. (In the range of the specific operation of the present invention, the spinning temperature of the polypropylene 2 〇〇 t: ~ 25 (TC warming, polyethylene 25 〇 ° C ~ 3 〇〇. 〇 ' drafting The magnification is 3 to 8 times (the draw ratio in the specific operation example of the present invention is 6 times) 1 The heat extension temperature is 1 〇〇 to i6 〇〇 C (In the specific operation example of the present invention, the TC hot water is used. Extension), the heating setting temperature is cumulus ~ 丨 (10). c. The above-mentioned melt drawing is to heat and melt the synthetic material, and the melt is extruded from the spinning hole into the air, and is cooled in the air while being curled at a certain speed. At this stage, the melt of the synthetic material is solidified at the same time, that is, the fiber is formed, and then the heat is stretched to improve the mechanical properties of the fiber. The pro-stranding process is a spinnable polymer which is obtained in the polymerization process. Extrusion from the pores of the handle plate at a temperature above it, cooling refinement Filamentous solids are simultaneously wound. Examples of functional microparticles are not distinguished. In order to generate negative ions, the functional microparticles of the present invention are submicron tourmaline particles. The present invention is capable of producing anti-mold resistance. The function of the function is recorded as Nai, and the test results of Can Houqi show that the invention also has a rhyme-resistant silk-feeding. Cai, Shuri (4) can produce potting effects, added in the fiber mixing (10) Miwei (4) Micro-position (in the experimental example of the present invention, microcapsules contain 1% by weight
b),且在微膠囊内包覆機能 性材枓’其中该微耀囊的材料可A甲M 抬減U Μ素,"^峨紐材料可為 植物卒取精油,藉以使本發明具 ▲生方香的效果,而如后所示 的试I果顯示本㈣具有使料持久的縣。此外 採用的機能性微粒亦可為酵素,其 " 、對人體都有—定的幫助。 1337632 D.本發明之實驗例 本發明之實驗例’係以分子量為3.i5xl〇5g/m〇le的聚丙烯做 為基材’先取聚丙烯佔20%重量百分比·,與以下的材料:⑴機能 性微粒為防火材料且佔15%重量百分比;(2)機能性微粒為次微米 電氣石且佔10°/。重量百分比;(3)機能性微粒為抗菌防霉材料且佔 整體重量的5%;(4)機能性微粒為除臭材料(氣體去除)且佔10%重 量百分比;(5)機能性微粒為抗靜電抗電磁波材料且佔重量百 分比,·及(6)熱可塑彈性體(TPE)且佔35%重量百分比,將上述材料 以雙螺桿混練造粒而製成複數個母粒。再取該複數個母粒4〇%及 額外的聚丙烯60%,再將母粒與該額外的聚丙烯混練成一合成材 料,使忒合成材料中的最終機能性微粒和熱可塑彈性體(TpE)的含 量為佔整體合成材料重量之32%重量百分比。再將該合成材料經 抽絲、冷卻、熱延伸、加熱定型製成纖維。其中,抽絲溫度為240〇C 範圍内’牽伸倍率5-6倍’熱延伸溫度100。。,加熱定型溫度為85 V。 為了做具體的實驗,本發明再取上述的纖維紡織成織品,即 以複數條呈經向延伸_維及複數條延伸的纖維編織成織 ,其樣本尺寸為101.6 mm * 203.2 mm (4 in * 8 in),經向纖維的 單位長度分佈數量為每射42條,辑域_單位長度分佈數 量為每英吋34條。 a•本發明之機械性試驗 本号X明上述樣本之各項機械性試驗結果如下 12 1337632 (1)抗拉強度(ASTMD4632 : Grasp-型抗拉強度試驗) 表 1 (kgf/cm2)b), and coating the functional material in the microcapsules, wherein the material of the micro-gray can be used to aggravate the U-muthin, and the material can be a plant stroke essential oil, so that the present invention has ▲The effect of raw square incense, and the test I shown in the following shows that (4) has a county with a long-lasting material. In addition, the functional particles used can also be enzymes, which have a certain help for the human body. 1337632 D. Experimental Example of the Invention The experimental example of the present invention is based on a polypropylene having a molecular weight of 3.i5xl〇5g/m〇le as a substrate. 'Firstly taking polypropylene as 20% by weight··, and the following materials: (1) Functional particles are fireproof materials and account for 15% by weight; (2) Functional particles are submicron tourmaline and account for 10°/. Percentage by weight; (3) functional particles are antibacterial and anti-mold materials and account for 5% of the total weight; (4) functional particles are deodorizing materials (gas removal) and account for 10% by weight; (5) functional particles are Antistatic anti-electromagnetic wave material and percentage by weight, and (6) Thermoplastic elastomer (TPE) and 35% by weight, the above materials are granulated by twin-screw kneading to form a plurality of masterbatch. Then take the plurality of masterbatch 4%% and the additional polypropylene 60%, and then mix the masterbatch with the additional polypropylene to form a synthetic material, so that the final functional particles and the thermoplastic elastomer in the bismuth composite material (TpE The content is 32% by weight based on the weight of the overall synthetic material. The synthetic material is then subjected to spinning, cooling, heat extension, and heat setting to form fibers. Among them, the spinning temperature is in the range of 240 〇C, and the drawing ratio is 5-6 times, and the heat stretching temperature is 100. . The heat setting temperature is 85 V. In order to carry out a specific experiment, the present invention further fabricates the above-mentioned fiber into a fabric, which is woven into a plurality of fibers extending in a warp direction and a plurality of strips, and has a sample size of 101.6 mm * 203.2 mm (4 in *). 8 in), the number of distributions per unit length of the meridional fibers is 42 per shot, and the number of distributions per unit length is 34 per inch. a•Mechanical test of the present invention The results of the mechanical tests of the above samples are as follows: 12 1337632 (1) Tensile strength (ASTMD4632: Grasp-type tensile strength test) Table 1 (kgf/cm2)
~___L 217娜 21.5762 21.1652 由表2 =知,本發明織品的破裂強度也隨著電氣石含量增加而 ^ γ在電,石含I丨%重量百分比時經向破裂強度下降約5%, 電氣石含里5%重量百分比時經向破裂強度下降約8挪,但仍 2持相#高的破料度。因此,電氣石添加1·5%«百分比之 範圍内,並不影響破裂強度。 ⑶水洗牛度娜(職時條件:财鄕,溫度29。〇 : 13~___L 217 Na 21.5762 21.1652 From Table 2 = know that the rupture strength of the fabric of the present invention also increases with the tourmaline content γ γ in electricity, the stone contains I 丨 % by weight, the warp rupture strength decreases by about 5%, tourmaline In the case of 5% by weight of 5% by weight, the warp rupture strength decreased by about 8 ft, but still had a high degree of breaking. Therefore, the addition of tourmaline in the range of 1.5% «% does not affect the burst strength. (3) Washed Niu Du Na (time conditions: financial, temperature 29. 〇 : 13
丄/UJZ 表 3 (I〇n/cc)丄/UJZ Table 3 (I〇n/cc)
b.本發明負離子釋放分析 (1)負離子靜態釋放性能分析: 靜態模式負離子釋放性能分析,環境條件 濕度58%,溫b. Negative ion release analysis of the present invention (1) Analysis of negative ion static release performance: Static mode negative ion release performance analysis, environmental conditions Humidity 58%, temperature
度 28°C 電氣石添加量 一層濾網 二層濾網 =層漶網 1重量% 265 412 532 2重量% 350 523 652 ' 3重量% 412 589 756 _ 4 a% __465 652 852 ^-ΊΕΕΙΙΑ 489 712 由表4分析可以得知電氣石添加量跟層數都為顯著影響因 ^層數疋其主要影響因子。次鮮錢石聚丙烯過濾材在一 尽I"不同含量下負離子釋放265_489個I〇n/cc,在含量1%重量 I分比次微米f氣石聚丙烯過着離子· 265_712個Μα,= 者間,差了 223個I〇nyec。在相同體積含有電氣石數下,在負離子 釋放里上,層數的增加較添加率的增加有效D (2)負離子動態釋放性能分析: 動驗子釋錄能分析’魏餅:财6攸,溫度 29 C 〇 1337632Degree 28 °C tourmaline addition amount one layer filter two layer filter = layer mesh 1% by weight 265 412 532 2 weight% 350 523 652 '3 weight% 412 589 756 _ 4 a% __465 652 852 ^-ΊΕΕΙΙΑ 489 712 It can be seen from Table 4 that the amount of tourmaline added and the number of layers are significantly affected by the number of layers and their main influence factors. The secondary fresh money stone polypropylene filter material releases 265_489 I〇n/cc at a different content of I", at a content of 1% by weight, I minute, submicron, f, gas, polypropylene, ion, 265_712, Μα, = Between the two, 223 I〇nyec. In the same volume containing tourmaline, in the negative ion release, the increase of the number of layers is more effective than the increase of the addition rate. D (2) Analysis of the dynamic release performance of negative ions: The release of the test can analyze 'Wei cake: Cai 6攸, Temperature 29 C 〇1337632
•電氣石添加量 由上表5中可看出在動態負離子釋放量上來說… 及過遽層數都是重要m素,但過麟數為主要重要因素 c.本發明除臭及抗菌效能試驗 本發明纖維賴織成的織品的除臭及抗菌效麟驗,結果如 下。表6疋分別以本發明織品,依舰^撕㈣試法對於測量 (NH3)及乙搭(CHsCHO)之濃度,再測試醋酸(CH3c〇〇H)之濃^ 的消除效能而得之結果。由表6發現本發明織品具有較佳的除臭 效能。 、 表6 項目Item 氨氣nh3 乙搽ch3cho 醋酸 CHsCOOH 起始漢度The beginning 24.00PPM concentration 8.00PPM 0.20PPM 30 分鐘後濃度 The concentration 4.00PPM after 30 minutes 1.00PPM 0.04PPM 各污染成分去除率the removing rate of multi pollution 84.33% 87.50% 80.00% 總去除率 Total Removing Rate 丄實驗例三 84.58%• The amount of tourmaline added can be seen from the above table 5 in terms of the amount of dynamic anion release... and the number of layers is too important, but the number of over-mining is the main important factor. c. Deodorization and antibacterial efficacy test of the present invention The deodorant and antibacterial effect of the fabric woven by the fiber of the present invention are as follows. Table 6 shows the results of the elimination of the concentration of acetic acid (CH3c〇〇H) by measuring the concentration of (NH3) and ethylene (CHsCHO) by the fabric of the present invention. From Table 6, it was found that the fabric of the present invention has a better deodorizing performance. Table 6 Item Item Ammonia gas nh3 Acetyl ch3cho Acetic acid CHsCOOH Starting Hanting The beginning 24.00PPM concentration 8.00PPM 0.20PPM After 30 minutes Concentration The concentration 4.00PPM after 30 minutes 1.00PPM 0.04PPM The removal rate of each pollutant component Multi pollution 84.33% 87.50% 80.00% Total removal rate 丄Experimental example 3 84.58%
本發明纖維所編織成的織品的抗菌效能試驗結果如下。 表7 測試菌種 0 Initial Inoculation(CFU/ml) 0小時接菌量 Contact Time 作用 1 小時(1 hr later) Reduction抗菌效果(%) 1 小時(1 hr later) 15 1337632The results of the antibacterial efficacy test of the fabric woven by the fiber of the present invention are as follows. Table 7 Test strains 0 Initial Inoculation (CFU/ml) 0 hour inoculation amount Contact Time Effect 1 hour (1 hr later) Reduction antibacterial effect (%) 1 hour (1 hr later) 15 1337632
JISZ 2911 黑敎菌 ATCC9642 MS Z 2911 奔霉菌屬 ATCC9849JISZ 2911 sorghum ATCC9642 MS Z 2911 genus ATCC9849
._金黃色葡萄球菌 Ι.ΟχΙΟ3 大腸棵« 2.1x10s 肺炎桿菌 7.3 x10s 表9 測試項目 抗菌防霉環 金黃色葡萄球鏟 10mm 大腸桿i 4.5mm 肺炎桿鏟 3 Smm 金黃色葡茵玻諂 1 — 大腸桿菌._Staphylococcus aureus Ι.ΟχΙΟ3 Large intestines « 2.1x10s Klebsiella pneumoniae 7.3 x10s Table 9 Test items Antibacterial mildew ring Golden yellow grape ball shovel 10mm Large intestine rod i 4.5mm Pneumonia rod shovel 3 Smm Golden yellow Portuguese glass 谄 1 — E.coli
由表 7 得知以 ASTME2149-〇1^h κ * 聰加及ASTMG21_96試驗法,及表8得知以 時,纖維具有較佳的抗菌及防霉效能。由加有奈米銀粒子 驗法,本㈣添加有“ 1鱗:也具有較試 ,:維所編織成的織:的香二^ 明的製法及所製成的纖維,可⑽方纽果,足證本發 的持久性。 確保所添加微膠囊中精油之芳香 表1〇 : 試驗項目 :添加含有精油的微膠囊的芳香持久測試 氣味官能評估 試驗結果(初始測試) 3.4 驗結果(三個月後再測試) 4,0 1337632 · 再者’藉由GC-MS測試本發明網體纖維内含有天然精油成分 而得下表的結果。 由表11發現本發明網體能有效含有天然精油成分清淨能力。It is known from Table 7 that the fibers have better antibacterial and antifungal properties by the ASTME2149-〇1^h κ* Congjia and ASTM G21_96 test methods, and Table 8. In addition to the method of adding nano silver particles, this (4) adds "1 scale: also has a test, the weaving of the weave: the method of making the fragrance and the fiber made, (10) square fruit Persistence of the hair of the hair. Ensure the fragrance of the essential oil in the microcapsules added. Table 1: Test item: Adding the aromatics of the microcapsules containing essential oils to test the odor functional evaluation test results (initial test) 3.4 Test results (three Tested after the month) 4,0 1337632 · Again, the results of the following table were obtained by GC-MS testing the natural fiber components contained in the fiber of the present invention. It is found from Table 11 that the mesh of the present invention can effectively contain natural essential oil components. ability.
表11Table 11
f.本發明抗靜電效能試驗 依據AATCC 76-1995溫度20¾溼度4〇%RH由下表 明纖維所織成_體有良好的抗靜電效能能^ 見本^ 表12f. Antistatic performance test of the present invention According to AATCC 76-1995 temperature 203⁄4 humidity 4〇% RH, the following table shows that the fiber is woven into a body with good antistatic performance. ^ See Table 12
17 1337632 織物表面電阻(Ω/square) >E+li g·本發明抗電磁波效能試驗 依據AATCC D4935-1999 ’由表13發現本發明纖維所織成的 網體有良好的抗電磁波效能能力。 ° 表13 試驗項目 試驗結果 電磁波遮蔽效果DB/分貝 300MHZ 0.2 電磁波遮蔽效果DB/分貝 1800MHZ 0.1 h.本發明防火效能試驗 依UL 94-97方法由下表發現本發明鞋墊有長久防火能力 VTM-0。 表14 : 轼驗項目 試片一 試片- 試片= 試片四 試片五 VTM-0要求 試片厚廑 2.95mm 2.82mm 2.84mm 2.91mm 2.85mm 母一試片餘焰時間tl sec 0 0 0 0 0 <10秒 每一試片餘焰時間t2 sec 0 0 0 0 0 <10秒 每五片一组總餘焰時間 (五片各个tl+t2的總和) 0 £50秒 每試片第二次點火燃燒後的餘焰加餘 燼的時間t2+t3 0 0 0 0 0 S30秒 任一試片的餘焰或餘燼燃燒到夾具 否 否 否 否 否 否 棉花被燃燒颗粒或熔滴物點燃 否 否 否 否 否 否 i.主要實驗例測試結果總表 本發明主要貫驗例測試結果總表及檢測單位一覽如表15。 表15 : 功能 功效 方法/種類 效果 檢測單位 奈米銀 殺鏟 ASTM2149-01 金色珀萄球趄(ATCO/6538) 作用時間 一小時 94.8 SGS臺灣桧驗科技 ASTM 2149-01 大腸桿 a(ATCC#8739) ?9.2 SGS臺灣檢驗科技 ASTM2149-01Z 肺炎桿苗(ATCC#4352) 95,8 SGS臺灣桧驗科技 殺霉 把乙291丨黑麴袅八丁0:%42 〇無生長 SGS臺灣檢驗科技 JISZ2911 青霉盏屬 ATCC9849 〇無生長 SGS臺灣檢驗科技 HS Z 291 丨球毛殼 ATCC6205 〇無生長 SGS臺灣檢驗科技 18 1337632 JISZ2911 袍漆趄 ATCC卯95 0無生長 SGS臺灣檢驗科技 ASTM <52 卜96 癬霉线 ATCC9533 0無生長 SGS查灣檢驗科技 功能 功效 方法/種類 抗雄力% 神缠環mm 侩列箪位 眸素 5?i A.A.T.C.C M7·丨的8金色葡萄球g(ATCC卵538) m% 10mm SGS臺灣檢驗科技 A.A.T.C.C 14*M998 金色*5碚球g(ATCC#6538) m% 13 mm EPA美0¾保署 A.A.T.CC M7-丨998 大膀桿苗(ATCC#8739) 100% 4.5 mm SGS臺灣檢鴉科技 A.A.T.C.C 】47·丨998 Λ脒桿3(ATCC邱739) m% ]mm EPA美囯现《署 A.A.T.C.C147-1998 肺炎桿菌(ATCC#4352) 100% 3.5 mm SGS臺渖檢驗科拮 A A.T.C.C Η7·〗998 肺炎桿 |§(ATCC#«52) 100% 6 mm EPA美0¾保署 霉 AATCC 30 PAPT m 黑麴苗 ATCC6275 〇無生長 臺灣檢驗科技 負離子含 量 遠紅外辕 氧負銥子 能黃 4M*4M*4M負離子釋放量含量 1856(Ion/cc) TTRIM織綜合所 工研花能資所 1956(Ion/cc) l983(Ion/cc) 水洗實驗(水洗二十次) 遠红外線攻射率(S0sc)4測3-15μηι平均放射率 雎持站%以上 0948~|平均放射率 Ε·本發明的特點 1.本發明纖維添加機能性微粒(如次微米電氣石粒子),其所製 成之滤網的機械強度,僅些微的減低,但無太大影绝。 2·本發明纖維添加機能性微粒(如次微米電氣石粒子),經水洗 牛度試驗,仍保有一定的功能。 3‘本發明添加熱可塑彈性體及次微米電氣石粒子,一方面在過濾 效能方面,因電氣石帶負電效果,在「靜電吸附原理」下而能 有效增加提升過濾效能,另方面因熱可塑彈性體,所製成之濾 材不僅具有較佳彈性、雜性,由於貞離子特殊额·熱電性、 壓電性加速水分解負離子(叫-汗,彈性振動頻率高,、、雜力 較大’動態模式下便可大量釋放出負離子量,而能確實符;;人 體健康的需求量〇_-2_ ion / cc)。經實驗發現,本發财 4m*4m*4m的容積中負離子的釋放量含量約 1856〜1983(Ion/cc),具有良好的釋放量。 1337632 4.本發縣加包含有精油的微膠囊時,時添加有熱可 體^由彈性體的作用可避免精靖快速揮發,而可使精油以接 近疋里的方式釋出,避免浪費及增進耐久性。 乂本發明於纖維中添加奈米銀粒子時,使得本發明的翻具有一 定的抗菌效果。 6. 本發明於纖維中添加酵素時,經實驗證明本發明具有良好的抑 菌及防霉效果。 7. 而使用本發明纖維所製成之濾材,經實驗證明,室内空氣品質 传以有效提升如表15所示。 以上所述,僅為本發明之可行實施例,並非用以限定本發明 之專利範圍,舉凡依據下列申請專利範圍所述之内容、特徵以及 其精神而為之其他變化的等效實施,皆應包含於本發明的專利範 圍内。17 1337632 Fabric surface resistance (Ω/square) > E+li g· The electromagnetic wave resistance test of the present invention According to AATCC D4935-1999', it is found from Table 13 that the mesh woven by the fiber of the present invention has good electromagnetic wave resistance. ° Table 13 Test results Test results Electromagnetic wave shielding effect DB / decibel 300MHZ 0.2 Electromagnetic wave shielding effect DB / decibel 1800MHZ 0.1 h. Fire safety test of the present invention According to the UL 94-97 method, the insole of the present invention has long-term fire resistance VTM-0 according to the following table. . Table 14: Test piece test piece test piece - test piece = test piece four test piece five VTM-0 required test piece thickness 廑 2.95mm 2.82mm 2.84mm 2.91mm 2.85mm mother one test piece afterflame time tl sec 0 0 0 0 0 <10 seconds each test piece afterflame time t2 sec 0 0 0 0 0 <10 seconds every five sets of total afterflame time (the sum of five pieces of each tl+t2) 0 £50 seconds per test The time after the second ignition and the remaining flame of the piece is t2+t3 0 0 0 0 0 S30 seconds The residual flame or ember of any test piece is burned to the jig. No No No No No Cotton is burned particles or droplets Ignition No No No No No No i. Main Experimental Example Test Results Summary Table The main results of the main test cases of the present invention are summarized in Table 15. Table 15: Functional Efficacy Method/Type Effect Detection Unit Nano Silver Shovel ASTM2149-01 Golden Peuge Ball AT (ATCO/6538) Action Time One hour 94.8 SGS Taiwan Test Technology ASTM 2149-01 Large Intestine Rod a (ATCC#8739 9.2 SGS Taiwan Inspection Technology ASTM2149-01Z Pneumonia Rod Seedling (ATCC#4352) 95,8 SGS Taiwan Inspection Technology Killing B 291 丨 Black 麴袅 丁 0:%42 〇 No Growth SGS Taiwan Inspection Technology JISZ2911 Penicillium盏 ATCC9849 〇 no growth SGS Taiwan inspection technology HS Z 291 丨 ball shell ATCC6205 〇 no growth SGS Taiwan inspection technology 18 1337632 JISZ2911 robes 趄 趄 ATCC 卯 95 0 no growth SGS Taiwan inspection technology ASTM < 52 卜 96 癣 线 line ATCC9533 0 No growth SGS Chawan test technology function method / type anti-male force % God wrap ring mm 侩 箪 眸 5 5? i AATCC M7 · 丨 8 gold grape ball g (ATCC egg 538) m% 10mm SGS Taiwan Inspection Technology AATCC 14*M998 Gold*5 Shuttlecock g(ATCC#6538) m% 13 mm EPA US 03⁄4 Security Department AATCC M7-丨998 Big Bang Miao (ATCC#8739) 100% 4.5 mm SGS Taiwan Inspection Crow Technology AATCC 】47·丨998 Mast 3 (ATCC 739) m% ]mm EPA US Department of AATCC147-1998 Klebsiella pneumoniae (ATCC#4352) 100% 3.5 mm SGS Taiwan Department of Clinical Laboratory ACCCC Η7·〗 998 Pneumonia rod|§(ATCC#«52) 100% 6 mm EPA US 03⁄4 FDA AATCC 30 PAPT m Black sapling ATCC6275 〇 no growth Taiwan inspection technology negative ion content far infrared 辕 oxygen negative scorpion energy yellow 4M*4M*4M negative ion release content 1856 (Ion / cc) TTRIM weaving 1956(Ion/cc) l983(Ion/cc) Washing experiment (washing 20 times) Far-infrared attack rate (S0sc) 4 measuring 3-15μηι average emissivity holding station% above 0948 ~|Average emissivity Ε·Features of the invention 1. The fiber of the present invention adds functional particles (such as sub-micron tourmaline particles), and the mechanical strength of the filter made by the fiber is only slightly reduced, but not much shadow Absolutely. 2. The fiber of the present invention is added with functional particles (such as sub-micron tourmaline particles), and has a certain function after being washed by a bovine degree test. 3' The invention adds a thermoplastic elastomer and a sub-micron tourmaline particle. On the one hand, in terms of filtration efficiency, the tourmaline has a negative electric effect, and can effectively increase the filtration efficiency under the "electrostatic adsorption principle", and the other is thermally plasticized. Elastomer, the filter material made not only has better elasticity and impurity, but also has a special amount of pyroelectricity, pyroelectricity, and piezoelectricity to accelerate water decomposition of negative ions (called - sweat, high elastic vibration frequency, and high impurity force) In dynamic mode, a large amount of negative ions can be released, which can be confirmed; the demand for human health is 〇_-2_ ion / cc). It has been found through experiments that the release amount of negative ions in the volume of 4m*4m*4m is about 1856~1983 (Ion/cc), which has a good release amount. 1337632 4. When adding microcapsules containing essential oils in Benfa County, the hot body can be added. The effect of the elastomer can avoid the rapid evaporation of the Jingjing, and the essential oil can be released in a manner close to the sputum to avoid waste. Improve durability. When the present invention adds nano silver particles to the fibers, the present invention has a certain antibacterial effect. 6. When the enzyme is added to the fiber of the present invention, the invention has been proved to have good antibacterial and antifungal effects. 7. Using the filter material made of the fiber of the present invention, it has been experimentally proved that the indoor air quality is effectively improved as shown in Table 15. The above is only a possible embodiment of the present invention, and is not intended to limit the scope of the patents of the present invention, and the equivalent implementations of other changes described in the following claims are intended to be It is included in the scope of the patent of the present invention.
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| TWI575125B (en) * | 2014-08-19 | 2017-03-21 | kai li Huang | Green energy-saving fiber, its preparation method and the fabric made of the fiber |
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| TWI732556B (en) * | 2020-05-18 | 2021-07-01 | 張文禮 | Nano-pretreatment long-term functional composite material and its fabric |
| TWI739613B (en) * | 2020-09-29 | 2021-09-11 | 銓程國際股份有限公司 | Antibacterial nano-copper, fiber yarn manufacturing method |
| CN113144750A (en) * | 2021-04-08 | 2021-07-23 | 珠海市昇恒贸易有限公司 | Functional filter and fiber incorporating functional ingredients |
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