TWI489623B - Semiconductor structure and manufacturing method of the same - Google Patents
Semiconductor structure and manufacturing method of the same Download PDFInfo
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- 239000004065 semiconductor Substances 0.000 title claims description 41
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 34
- 239000002184 metal Substances 0.000 claims description 34
- 239000011810 insulating material Substances 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 25
- 239000003989 dielectric material Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 23
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000004020 conductor Substances 0.000 claims description 17
- 229910001507 metal halide Inorganic materials 0.000 claims description 4
- 150000005309 metal halides Chemical class 0.000 claims description 4
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 239000010410 layer Substances 0.000 description 128
- 238000005530 etching Methods 0.000 description 18
- 230000004888 barrier function Effects 0.000 description 17
- 230000008569 process Effects 0.000 description 12
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 10
- 229910052721 tungsten Inorganic materials 0.000 description 10
- 239000010937 tungsten Substances 0.000 description 10
- 238000009413 insulation Methods 0.000 description 6
- 229920002120 photoresistant polymer Polymers 0.000 description 6
- 239000011247 coating layer Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 4
- 229920005591 polysilicon Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- NZIHMSYSZRFUQJ-UHFFFAOYSA-N 6-chloro-1h-benzimidazole-2-carboxylic acid Chemical compound C1=C(Cl)C=C2NC(C(=O)O)=NC2=C1 NZIHMSYSZRFUQJ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- CXXKWLMXEDWEJW-UHFFFAOYSA-N tellanylidenecobalt Chemical compound [Te]=[Co] CXXKWLMXEDWEJW-UHFFFAOYSA-N 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000005055 memory storage Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SEOYNUHKXVGWFU-UHFFFAOYSA-N mu-oxidobis(oxidonitrogen) Chemical compound O=NON=O SEOYNUHKXVGWFU-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
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Description
本發明是有關於一種半導體結構及其製造方法,且特別是有關於一種用於三維記憶裝置之半導體結構及其製造方法。The present invention relates to a semiconductor structure and a method of fabricating the same, and more particularly to a semiconductor structure for a three-dimensional memory device and a method of fabricating the same.
近年來半導體元件的結構不斷地改變,且元件的記憶體儲存容量也不斷增加。記憶裝置係使用於許多產品之中,例如MP3播放器、數位相機、電腦檔案等等之儲存元件中。隨著應用的增加,對於記憶裝置的需求也趨向較小的尺寸、較大的記憶容量。In recent years, the structure of semiconductor elements has been constantly changing, and the memory storage capacity of the elements has also been increasing. Memory devices are used in many products, such as MP3 players, digital cameras, computer files, and the like. As applications increase, so does the demand for memory devices toward smaller sizes and larger memory capacities.
設計者們開發一種提高記憶裝置密度的方法係使用三維堆疊記憶裝置,藉以達成更高的記憶容量,同時降低每一位元之成本。然而,製作此種記憶裝置時,需針對位於堆疊結構中不同層的各個位元層分別製作接觸點,並且亦需針對不同的元件製作接觸點,例如串選擇線、接地選擇線及源極接點,此種記憶裝置複雜的結構也使得製造方法變得複雜。Designers have developed a way to increase the density of memory devices by using a three-dimensional stacked memory device to achieve higher memory capacity while reducing the cost per bit. However, when making such a memory device, it is necessary to separately make contact points for each bit layer located in different layers in the stacked structure, and also need to make contact points for different components, such as string selection line, ground selection line and source connection. The complex structure of such a memory device also complicates the manufacturing method.
本發明係有關於一種半導體結構及其製造方法,可應用於記憶裝置。根據本揭露內容之實施例,以兩段式的方式形成半導體結構之多個接觸結構,可以在同一個製程中製作多個具有不同高度的接觸結構,具有簡化製程步驟、 以及減少製程時間及成本的效果。The present invention relates to a semiconductor structure and a method of fabricating the same, which can be applied to a memory device. According to an embodiment of the present disclosure, a plurality of contact structures of a semiconductor structure are formed in a two-stage manner, and a plurality of contact structures having different heights can be fabricated in the same process, which has a simplified process step, And the effect of reducing process time and cost.
根據本發明之一方面,係提出一種半導體結構。半導體結構包括複數個堆疊結構以及複數個接觸結構,其中各堆疊結構包括複數個導電條與複數個絕緣條,導電條與絕緣條係交錯設置(interlaced),各接觸結構分別電性連接於各堆疊結構。接觸結構包括一第一導電柱(conductive pillar)、一介電材料層、一金屬矽化物層及一第二導電柱。介電材料層環繞第一導電柱的側面,金屬矽化物層形成於第一導電柱之上表面上,第二導電柱形成於金屬矽化物層上,該些第一導電柱之上表面係為同平面。According to an aspect of the invention, a semiconductor structure is proposed. The semiconductor structure includes a plurality of stacked structures and a plurality of contact structures, wherein each of the stacked structures includes a plurality of conductive strips and a plurality of insulating strips, and the conductive strips and the insulating strips are interlaced, and the contact structures are electrically connected to the stacks respectively. structure. The contact structure includes a first conductive pillar, a dielectric material layer, a metal telluride layer, and a second conductive pillar. The dielectric material layer surrounds the side of the first conductive pillar, the metal telluride layer is formed on the upper surface of the first conductive pillar, and the second conductive pillar is formed on the metal telluride layer, and the upper surface of the first conductive pillar is Same plane.
根據本發明之另一方面,係提出一種半導體結構的製造方法。半導體結構的製造方法包括下列步驟:形成複數個堆疊結構,其中包括形成複數個導電條與複數個絕緣條,導電條與絕緣條係交錯設置(interlaced);以及形成複數個接觸結構,各接觸結構分別電性連接於各堆疊結構。形成各接觸結構包括下列步驟:形成一第一導電柱(conductive pillar);形成一介電材料層,環繞第一導電柱的側面;形成一金屬矽化物層於第一導電柱之上表面上;及形成一第二導電柱於金屬矽化物層上,其中該些第二導電柱之高度係為相同。According to another aspect of the present invention, a method of fabricating a semiconductor structure is proposed. The manufacturing method of the semiconductor structure comprises the steps of: forming a plurality of stacked structures, comprising forming a plurality of conductive strips and a plurality of insulating strips, the conductive strips and the insulating strips are interlaced; and forming a plurality of contact structures, each of the contact structures They are electrically connected to each stack structure. Forming each contact structure includes the steps of: forming a first conductive pillar; forming a layer of dielectric material surrounding the side of the first conductive pillar; forming a metal telluride layer on the upper surface of the first conductive pillar; And forming a second conductive pillar on the metal telluride layer, wherein the heights of the second conductive pillars are the same.
根據本發明之再一方面,係提出一種半導體結構的製造方法。半導體結構的製造方法包括下列步驟:形成複數個堆疊結構,其中包括形成複數個導電條與複數個絕緣條,導電條與絕緣條係交錯設置;形成一絕緣材料層,絕緣材料層係包覆堆疊結構;形成複數個凹孔於絕緣材料層 中,凹孔係曝露出各堆疊結構之一部分;形成複數個介電材料層分別於凹孔之側壁上;填入一導電材料於凹孔中以形成複數個第一導電柱;形成複數個金屬矽化物層於第一導電柱之上表面上;以及形成複數個第二導電柱於金屬矽化物層上,其中該些第二導電柱之高度係為相同。According to still another aspect of the present invention, a method of fabricating a semiconductor structure is proposed. The manufacturing method of the semiconductor structure comprises the steps of: forming a plurality of stacked structures, comprising forming a plurality of conductive strips and a plurality of insulating strips, the conductive strips and the insulating strips are staggered; forming an insulating material layer, and the insulating material layer is coated and stacked Structure; forming a plurality of recessed holes in the layer of insulating material a recessed hole exposes a portion of each of the stacked structures; a plurality of dielectric material layers are formed on the sidewalls of the recessed holes; a conductive material is filled in the recessed holes to form a plurality of first conductive pillars; and a plurality of metals are formed The telluride layer is on the upper surface of the first conductive pillar; and a plurality of second conductive pillars are formed on the metal telluride layer, wherein the heights of the second conductive pillars are the same.
為了對本發明之上述及其他方面有更佳的瞭解,下文特舉較佳實施例,並配合所附圖式,作詳細說明如下:In order to better understand the above and other aspects of the present invention, the preferred embodiments are described below, and in conjunction with the drawings, the detailed description is as follows:
在此揭露內容之實施例中,係提出一種半導體結構及其製造方法。根據本揭露內容之實施例,以兩段式的方式形成半導體結構之多個接觸結構,可以在同一個製程中製作多個具有不同高度的接觸結構,具有簡化製程步驟、以及減少製程時間及成本的效果。需注意的是,圖式係已簡化以利清楚說明實施例之內容,圖式上的尺寸比例並非按照實際產品等比例繪製,因此並非作為限縮本發明保護範圍之用。並且,實施例所提出的細部結構和製程步驟僅為舉例說明之用,並非對本發明欲保護之範圍做限縮。具有通常知識者當可依據實際實施態樣的需要對該些步驟加以修飾或變化。In the embodiments disclosed herein, a semiconductor structure and a method of fabricating the same are presented. According to an embodiment of the present disclosure, a plurality of contact structures of a semiconductor structure are formed in a two-stage manner, and a plurality of contact structures having different heights can be fabricated in the same process, which has a simplified process step, and reduces process time and cost. Effect. It is to be noted that the drawings have been simplified to clearly illustrate the contents of the embodiments, and the dimensional ratios in the drawings are not drawn to the scale of the actual products, and thus are not intended to limit the scope of the present invention. Further, the detailed structure and process steps set forth in the embodiments are for illustrative purposes only and are not intended to limit the scope of the present invention. Those having ordinary knowledge may modify or change the steps as needed according to the actual implementation.
第1圖繪示依照本發明之一實施例之半導體結構之俯視示意圖,第2A圖繪示沿第1圖之剖面線2A-2A’之剖面示意圖,第2B圖繪示沿第1圖之剖面線2B-2B’之剖面 示意圖,第2C圖繪示沿第1圖之剖面線2C-2C’之剖面示意圖。1 is a top plan view of a semiconductor structure in accordance with an embodiment of the present invention, FIG. 2A is a cross-sectional view taken along line 2A-2A' of FIG. 1, and FIG. 2B is a cross-sectional view along FIG. Section of line 2B-2B' Fig. 2C is a schematic cross-sectional view taken along line 2C-2C' of Fig. 1.
請參照第1及2A~2C圖。半導體結構100包括複數個堆疊結構110以及複數個接觸結構120。各個堆疊結構110包括複數個導電條111與複數個絕緣條113,導電條111與絕緣條113係交錯設置(interlaced)。各個接觸結構120分別電性連接於各個堆疊結構110之第一端110a。各個接觸結構120包括第一導電柱(conductive pillar)121、介電材料層123、金屬矽化物層125及第二導電柱127。介電材料層123環繞第一導電柱121的側面,金屬矽化物層125形成於第一導電柱121之上表面121a上,第二導電柱127形成於金屬矽化物層125上。多個接觸結構120的第一導電柱121之上表面121a係為同平面。實施例中,導電條111的材質包括含矽材料,例如是多晶矽;絕緣條113的材質包括氧化物,例如是二氧化矽;然實際應用時,該些材質亦視應用狀況作適當選擇,並不以前述材料為限。Please refer to Figures 1 and 2A~2C. The semiconductor structure 100 includes a plurality of stacked structures 110 and a plurality of contact structures 120. Each of the stacked structures 110 includes a plurality of conductive strips 111 and a plurality of insulating strips 113, and the conductive strips 111 and the insulating strips 113 are interlaced. Each of the contact structures 120 is electrically connected to the first end 110a of each of the stacked structures 110. Each contact structure 120 includes a first conductive pillar 121, a dielectric material layer 123, a metal telluride layer 125, and a second conductive pillar 127. The dielectric material layer 123 surrounds the side of the first conductive pillar 121, the metal telluride layer 125 is formed on the upper surface 121a of the first conductive pillar 121, and the second conductive pillar 127 is formed on the metal halide layer 125. The upper surface 121a of the first conductive pillar 121 of the plurality of contact structures 120 is in the same plane. In an embodiment, the material of the conductive strips 111 includes a germanium-containing material, such as polysilicon, and the material of the insulating strips 113 includes an oxide, such as cerium oxide. However, in practical applications, the materials are also appropriately selected depending on the application. Not limited to the aforementioned materials.
實施例中,如第2B圖所示(請同時參照第1圖),接觸區BLP中,多個第二導電柱127之高度127H例如係為相同,多個第一導電柱121之高度121H1~121H8例如係為不同,舉例來說,第一導電柱121之高度121H1與其餘第一導電柱121之高度121H2~121H8係為不同。如此一來,如第2B圖所示,接觸區BLP中的多個接觸結構120係形成階梯狀的整體結構。In the embodiment, as shown in FIG. 2B (please refer to FIG. 1 at the same time), in the contact region BLP, the heights 127H of the plurality of second conductive pillars 127 are, for example, the same, and the heights of the plurality of first conductive pillars 121 are 121H1~ 121H8 is different, for example, the height 121H1 of the first conductive pillar 121 is different from the heights 121H2 to 121H8 of the remaining first conductive pillars 121. As such, as shown in FIG. 2B, the plurality of contact structures 120 in the contact region BLP form a stepped overall structure.
實施例中,第一導電柱121之材料與第二導電柱127之材料例如係為不同。第一導電柱121之材料例如是多晶 矽(polysilicon),第二導電柱127之材料例如是鎢。金屬矽化物層125的材質例如是矽化鎳或矽化鈷,具有降低第一導電柱121之阻抗的效果。然實際應用時,該些材質亦視應用狀況作適當選擇,並不以前述材料為限。In the embodiment, the material of the first conductive pillar 121 is different from the material of the second conductive pillar 127, for example. The material of the first conductive pillar 121 is, for example, polycrystalline Polysilicon, the material of the second conductive pillar 127 is, for example, tungsten. The material of the metal telluride layer 125 is, for example, nickel telluride or cobalt telluride, and has an effect of lowering the impedance of the first conductive pillar 121. However, in actual application, the materials are also appropriately selected depending on the application conditions, and are not limited to the aforementioned materials.
實施例中,如第2A圖所示,介電材料層123亦形成於堆疊結構110之兩側壁110s上。介電材料層123包括電荷捕捉材料(charge trapping material),例如可具有多層結構,例如是ONO複合層或ONONO複合層或BE-SONOS複合層,或是包括例如由氧化矽與氮化矽交錯堆疊形成的ONO結構。In the embodiment, as shown in FIG. 2A, the dielectric material layer 123 is also formed on the two sidewalls 110s of the stacked structure 110. The dielectric material layer 123 includes a charge trapping material, for example, may have a multilayer structure such as an ONO composite layer or an ONONO composite layer or a BE-SONOS composite layer, or may include, for example, a stack of yttrium oxide and tantalum nitride. The formed ONO structure.
實施例中,如第2A~2B圖所示,各接觸結構120係經由各第一導電柱121分別電性連接於各堆疊結構110之多個導電條111其中之一。In the embodiment, as shown in FIG. 2A to FIG. 2B , each contact structure 120 is electrically connected to one of the plurality of conductive strips 111 of each stacked structure 110 via each of the first conductive pillars 121 .
一實施例中,如第1及2A圖所示,半導體結構100可更包括複數個條狀導電結構130和130’,此些條狀導電結構130和130’形成於堆疊結構110上及多個堆疊結構110之間,且條狀導電結構130和130’的延伸方向D1係垂直於堆疊結構110的延伸方向D2。In one embodiment, as shown in FIGS. 1 and 2A, the semiconductor structure 100 may further include a plurality of strip-shaped conductive structures 130 and 130' formed on the stacked structure 110 and a plurality of Between the stacked structures 110, and the extending direction D1 of the strip-shaped conductive structures 130 and 130' is perpendicular to the extending direction D2 of the stacked structure 110.
一實施例中,半導體結構100可更包括絕緣結構140。如第1圖所示,絕緣結構140形成於多個條狀導電結構130/130’之間。如第2B圖所示,絕緣結構140亦形成於多個接觸結構120之間,此些接觸結構120係以絕緣結構140彼此分隔開。實施例中,絕緣結構140的材質例如包括氧化物。In an embodiment, the semiconductor structure 100 may further include an insulating structure 140. As shown in Fig. 1, an insulating structure 140 is formed between the plurality of strip-shaped conductive structures 130/130'. As shown in FIG. 2B, the insulating structure 140 is also formed between the plurality of contact structures 120, and the contact structures 120 are separated from each other by the insulating structure 140. In the embodiment, the material of the insulating structure 140 includes, for example, an oxide.
一實施例中,如第2C圖所示,半導體結構100可更 包括複數個導電塊150,導電塊150電性連接於堆疊結構110。實施例中,各個導電塊150形成於各堆疊結構110相對於第一端110a之第二端110b。如第2C圖所示,接觸結構120更可形成於導電塊150上。In one embodiment, as shown in FIG. 2C, the semiconductor structure 100 can be further A plurality of conductive blocks 150 are included, and the conductive blocks 150 are electrically connected to the stacked structure 110. In an embodiment, each of the conductive bumps 150 is formed on each of the stacked structures 110 relative to the second end 110b of the first end 110a. As shown in FIG. 2C, the contact structure 120 can be formed on the conductive block 150.
一實施例中,如第2B圖所示,半導體結構100可更包括阻障層(barrier layer)160,阻障層160例如是設置於接觸結構120之間。實施例中,阻障層160的材質例如包括金屬氮化物,然實際應用時,該些材質亦視應用狀況作適當選擇,並不以前述材料為限。In an embodiment, as shown in FIG. 2B , the semiconductor structure 100 may further include a barrier layer 160 , and the barrier layer 160 is disposed between the contact structures 120 , for example. In the embodiment, the material of the barrier layer 160 includes, for example, a metal nitride. However, in actual application, the materials are also appropriately selected depending on the application conditions, and are not limited to the foregoing materials.
一實施例中,如第1圖所示,半導體結構100可更包括複數個導電塊170,導電塊170電性連接於堆疊結構110。實施例中,各個導電塊170係電性連接於對應的各個接觸結構120。In one embodiment, as shown in FIG. 1 , the semiconductor structure 100 may further include a plurality of conductive blocks 170 electrically connected to the stacked structure 110 . In the embodiment, each of the conductive blocks 170 is electrically connected to the corresponding respective contact structures 120.
一實施例中,以半導體結構100為一三維記憶裝置(3D memory device)為例,如第1~2C圖所示,堆疊結構110例如是位元線(bit line,BL),接觸區BLP上方的接觸結構120例如是位元線襯墊(bit line pad,BLP),條狀導電結構130例如是字元線(word line,WL),條狀導電結構130’例如是接地選擇線(ground select line,GSL),導電塊150例如是源極接點(source contact,SC),導電塊170例如是串列選擇線(string select line)SSL,藉由接觸區BLP中階梯狀排列的多個接觸結構120而能夠通往堆疊結構110中不同層的導電條111。In one embodiment, the semiconductor structure 100 is a 3D memory device. As shown in FIGS. 1~2C, the stacked structure 110 is, for example, a bit line (BL), above the contact area BLP. The contact structure 120 is, for example, a bit line pad (BLP), the strip conductive structure 130 is, for example, a word line (WL), and the strip conductive structure 130' is, for example, a ground selection line (ground select line) Line, GSL), the conductive block 150 is, for example, a source contact (SC), and the conductive block 170 is, for example, a string select line SSL, and a plurality of contacts arranged in a stepped manner in the contact region BLP. The structure 120 is capable of leading to the conductive strips 111 of different layers in the stacked structure 110.
一般製作三維記憶裝置的作法,先形成堆疊結構110末端的階梯結構後,再蝕刻階梯結構上方的氧化層而形成 多個接觸孔,接著填入鎢金屬而形成多個具有不同高度的鎢插拴(tungsten plug)。然而,連接至不同導電條111的不同鎢插拴具有不同高度,因此針對各個插拴所需的蝕刻深度必須不同,而會造成增加製程的步驟、時間以及成本。並且,記憶裝置中尚有其他接點需要製作接觸插拴(contact plug),例如源極接點及串列選擇線,基於相似於上述的理由,更不可能同時在一個步驟做好記憶裝置所需要的所有接觸插拴。相對地,本揭露內容之實施例中,多個接觸結構120的第一導電柱121之上表面121a係為同平面,接著可在一次製程中形成多個第二導電柱127(接觸插拴,例如是鎢插拴),因此,記憶裝置之製程的步驟、時間以及成本均可有效降低。Generally, a three-dimensional memory device is fabricated by first forming a stepped structure at the end of the stacked structure 110, and then etching the oxide layer above the stepped structure to form an oxide layer. A plurality of contact holes are then filled with tungsten metal to form a plurality of tungsten plugs having different heights. However, the different tungsten inserts connected to the different conductive strips 111 have different heights, so the etch depth required for each plug must be different, which can result in increased process steps, time, and cost. Moreover, there are other contacts in the memory device that need to make contact plugs, such as source contacts and tandem select lines. For similar reasons, it is even more impossible to do the memory device in one step at the same time. All contact plugs needed. In contrast, in the embodiment of the disclosure, the upper surface 121a of the first conductive pillar 121 of the plurality of contact structures 120 is in the same plane, and then a plurality of second conductive pillars 127 may be formed in one process (contact plug, For example, tungsten plugging), therefore, the steps, time and cost of the process of the memory device can be effectively reduced.
以下係提出實施例之一種半導體結構之製造方法,然該些步驟僅為舉例說明之用,並非用以限縮本發明。具有通常知識者當可依據實際實施態樣的需要對該些步驟加以修飾或變化。請參照第3圖至第23C圖。第3圖至第23C圖繪示依照本發明之一實施例之一種半導體結構之製造方法示意圖。需注意的是,圖式係已簡化以利清楚說明實施例之內容,圖式上的尺寸比例並非按照實際產品等比例繪製,因此並非作為限縮本發明保護範圍之用。The following is a method of fabricating a semiconductor structure of the embodiments, which are for illustrative purposes only and are not intended to limit the invention. Those having ordinary knowledge may modify or change the steps as needed according to the actual implementation. Please refer to Figures 3 to 23C. 3 to 23C are schematic views showing a method of fabricating a semiconductor structure in accordance with an embodiment of the present invention. It is to be noted that the drawings have been simplified to clearly illustrate the contents of the embodiments, and the dimensional ratios in the drawings are not drawn to the scale of the actual products, and thus are not intended to limit the scope of the present invention.
首先,請參照第3~7C圖,形成複數個堆疊結構110,其中包括形成複數個導電條111與複數個絕緣條113,導電條111與絕緣條113係交錯設置(interlaced)。並且,於堆疊結構110的一端形成具有階梯狀結構的接觸區BLP。 並且,形成複數個導電塊150於多個堆疊結構110相對於接觸區BLP端之另一端,且導電塊150電性連接於堆疊結構110。First, referring to FIGS. 3-7C, a plurality of stacked structures 110 are formed, including forming a plurality of conductive strips 111 and a plurality of insulating strips 113, and the conductive strips 111 and the insulating strips 113 are interlaced. Also, a contact region BLP having a stepped structure is formed at one end of the stacked structure 110. Moreover, a plurality of conductive blocks 150 are formed on the other end of the plurality of stacked structures 110 with respect to the end of the contact region BLP, and the conductive blocks 150 are electrically connected to the stacked structure 110.
形成堆疊結構110、接觸區BLP及導電塊150的製造方法例如包括以下步驟。The manufacturing method of forming the stacked structure 110, the contact region BLP, and the conductive bump 150 includes, for example, the following steps.
如第3及4A~4B圖所示(第4A圖繪示沿第3圖之剖面線3A-3A’之剖面示意圖,第4B圖繪示沿第3圖之剖面線3B-3B’之剖面示意圖),形成複數個導電層111a與複數個絕緣層113a,導電層111a與絕緣層113a係交錯設置(interlaced),並且形成複數個導電塊150於由導電層111a與絕緣層113a所構成的複合層中。接著,於選定的接觸區BLP中移除部分導電層111a與部分絕緣層113a以形成如第4B圖所示之階梯結構,例如是利用硬式光罩(hard mask)HM1以光罩蝕刻方式移除部分導電層111a與部分絕緣層113a。As shown in Figures 3 and 4A-4B (Fig. 4A is a cross-sectional view taken along line 3A-3A' of Fig. 3, and Fig. 4B is a cross-sectional view taken along line 3B-3B' of Fig. 3. a plurality of conductive layers 111a and a plurality of insulating layers 113a are formed. The conductive layer 111a and the insulating layer 113a are interlaced, and a plurality of conductive blocks 150 are formed on the composite layer composed of the conductive layer 111a and the insulating layer 113a. in. Then, a portion of the conductive layer 111a and a portion of the insulating layer 113a are removed from the selected contact region BLP to form a step structure as shown in FIG. 4B, for example, by mask etching using a hard mask HM1. Part of the conductive layer 111a and a portion of the insulating layer 113a.
如第5A~5B圖所示(第5A圖繪示沿第3圖之剖面線3A-3A’之剖面示意圖,第5B圖繪示沿第3圖之剖面線3B-3B’之剖面示意圖),移除硬式光罩HM1後,形成阻障材料層160a於導電層111a、絕緣層113a及導電塊150上,阻障材料層160a可以作為後續製程中的蝕刻阻擋層。接著設置硬式光罩HM2覆蓋阻障材料層160a,再設置圖案化光阻層PR1於硬式光罩HM2上。As shown in Figures 5A-5B (Fig. 5A shows a cross-sectional view along section line 3A-3A' of Fig. 3, and Fig. 5B shows a cross-sectional view along section line 3B-3B' of Fig. 3) After the hard mask HM1 is removed, the barrier material layer 160a is formed on the conductive layer 111a, the insulating layer 113a and the conductive block 150, and the barrier material layer 160a can serve as an etching barrier layer in a subsequent process. Next, a hard mask HM2 is disposed to cover the barrier material layer 160a, and a patterned photoresist layer PR1 is disposed on the hard mask HM2.
如第6~7C圖所示(第7A圖繪示沿第6圖之剖面線6A-6A’之剖面示意圖,第7B圖繪示沿第6圖之剖面線6B-6B’之剖面示意圖,第7C圖繪示沿第6圖之剖面線 6C-6C’之剖面示意圖),例如以光罩蝕刻方式,根據圖案化光阻層PR1蝕刻導電層111a與絕緣層113a,以形成複數個堆疊結構110。同時,蝕刻製程之後,阻障材料層160a亦被蝕刻而形成阻障層160於堆疊結構110、導電塊150及接觸區BLP上。As shown in Figures 6-7C (Fig. 7A is a cross-sectional view taken along line 6A-6A' of Fig. 6, and Fig. 7B is a cross-sectional view taken along line 6B-6B' of Fig. 6, Figure 7C shows the section line along Figure 6. A cross-sectional view of 6C-6C'), for example, etching the conductive layer 111a and the insulating layer 113a according to the patterned photoresist layer PR1 in a mask etching manner to form a plurality of stacked structures 110. At the same time, after the etching process, the barrier material layer 160a is also etched to form the barrier layer 160 on the stacked structure 110, the conductive block 150 and the contact region BLP.
接著,請參照第8A~23C圖,形成複數個接觸結構120,各接觸結構120分別電性連接於各堆疊結構110,例如是電性連接於各堆疊結構110之第一端110a。接觸結構120亦可形成於導電塊150和170上。形成一個接觸結構120的製造方法包括:形成第一導電柱121;形成介電材料層123,介電材料層123環繞第一導電柱121的側面;形成金屬矽化物層125於第一導電柱121之上表面121a上;以及形成第二導電柱127於金屬矽化物層125上,其中多個第二導電柱127之高度127H係為相同。Next, referring to FIGS. 8A to 23C , a plurality of contact structures 120 are formed. Each of the contact structures 120 is electrically connected to each of the stacked structures 110 , for example, electrically connected to the first ends 110 a of the stacked structures 110 . Contact structure 120 may also be formed on conductive bumps 150 and 170. The manufacturing method for forming a contact structure 120 includes: forming a first conductive pillar 121; forming a dielectric material layer 123, the dielectric material layer 123 surrounding the side of the first conductive pillar 121; forming a metal telluride layer 125 on the first conductive pillar 121 On the upper surface 121a; and forming a second conductive pillar 127 on the metal telluride layer 125, wherein the heights 127H of the plurality of second conductive pillars 127 are the same.
形成多個第一導電柱121及對應的多個介電材料層123的製造方法例如包括以下步驟。The manufacturing method of forming the plurality of first conductive pillars 121 and the corresponding plurality of dielectric material layers 123 includes, for example, the following steps.
如第8A~8C圖所示(第8A圖繪示沿第6圖之剖面線6A-6A’之剖面示意圖,第8B圖繪示沿第6圖之剖面線6B-6B’之剖面示意圖,第8C圖繪示沿第6圖之剖面線6C-6C’之剖面示意圖),形成絕緣材料層140a於整個結構的表面上。絕緣材料層140a覆蓋堆疊結構110、導電塊150及接觸區BLP。實施例中,絕緣材料層140a例如是金屬氧化物。As shown in Figs. 8A-8C (Fig. 8A is a cross-sectional view taken along line 6A-6A' of Fig. 6, and Fig. 8B is a cross-sectional view taken along line 6B-6B' of Fig. 6, 8C is a cross-sectional view taken along line 6C-6C' of FIG. 6 to form an insulating material layer 140a on the surface of the entire structure. The insulating material layer 140a covers the stacked structure 110, the conductive bumps 150, and the contact regions BLP. In the embodiment, the insulating material layer 140a is, for example, a metal oxide.
如第9~10C圖所示(第10A圖繪示沿第9圖之剖面線9A-9A’之剖面示意圖,第10B圖繪示沿第9圖之剖面線 9B-9B’之剖面示意圖,第10C圖繪示沿第9圖之剖面線9C-9C’之剖面示意圖),形成複數個凹孔(hole)121h於絕緣材料層140a中,且此些凹孔121h係位於堆疊結構110連接至接觸區BLP之一端110a之上。如第9~10C圖所示,亦形成複數個凹孔150h和170h及複數個凹槽(trench)130t和130t’於絕緣材料層140a中,凹槽130t和130t’的延伸方向D1係垂直於堆疊結構110的延伸方向D2。實施例中,凹槽130t和130t’係與凹孔121h、150h和170h同時形成。實施例中,例如以蝕刻方式形成凹孔及凹槽,阻障層160可作為蝕刻阻擋層,使得堆疊結構110之間的絕緣材料層140a完全被移除,而堆疊結構110受到保護並未被蝕刻,並且,凹孔121h、150h和170h底部的阻障層160係薄化而並未被完全移除,使得凹孔121h、150h和170h下方的導電條111不會受到蝕刻破壞,並且也清楚定義出堆疊結構110。As shown in Figures 9 to 10C (Fig. 10A shows a cross-sectional view along section line 9A-9A' of Fig. 9, and Fig. 10B shows a section line along Fig. 9. 9B-9B' is a schematic cross-sectional view, and FIG. 10C is a cross-sectional view taken along line 9C-9C' of FIG. 9 to form a plurality of holes 121h in the insulating material layer 140a, and the recessed holes 121h is located above stacking structure 110 connected to one end 110a of contact area BLP. As shown in FIGS. 9-10C, a plurality of recessed holes 150h and 170h and a plurality of trenches 130t and 130t' are formed in the insulating material layer 140a, and the extending directions D1 of the recesses 130t and 130t' are perpendicular to The extending direction D2 of the stacked structure 110. In the embodiment, the grooves 130t and 130t' are formed simultaneously with the recessed holes 121h, 150h and 170h. In an embodiment, the recessed holes and the recesses are formed, for example, by etching, and the barrier layer 160 can serve as an etch barrier layer, so that the insulating material layer 140a between the stacked structures 110 is completely removed, and the stacked structure 110 is protected. Etching, and the barrier layer 160 at the bottom of the recesses 121h, 150h, and 170h is thinned without being completely removed, so that the conductive strips 111 under the recesses 121h, 150h, and 170h are not damaged by etching, and are also clear A stacked structure 110 is defined.
實施例中,以半導體結構100為一三維記憶裝置,此些凹孔與凹槽係分別用來定義後續形成的字元線、接地選擇線、串列選擇線、源極接點及位元線襯墊的接觸插拴的形狀、位置及範圍。因此,本揭露內容實施例中,可以在一次製程中一起定義出多個元件的接觸插拴的位置,具有簡化記憶裝置之製程步驟、以及減少製程時間及成本的優點。In the embodiment, the semiconductor structure 100 is a three-dimensional memory device, and the recessed holes and the recesses are respectively used to define subsequently formed word lines, ground selection lines, serial selection lines, source contacts, and bit lines. The shape, position and extent of the contact plug of the pad. Therefore, in the embodiment of the disclosure, the position of the contact plug of the plurality of components can be defined together in one process, which has the advantages of simplifying the processing steps of the memory device and reducing the processing time and cost.
如第11A~11C圖所示(第11A圖繪示沿第9圖之剖面線9A-9A’之剖面示意圖,第11B圖繪示沿第9圖之剖面線9B-9B’之剖面示意圖,第11C圖繪示沿第9圖之剖面線 9C-9C’之剖面示意圖),形成介電材料塗佈層123a於堆疊結構110上及凹孔121h內。實施例中,介電材料塗佈層123a完全覆蓋阻障層160、堆疊結構110、凹槽130t和130t’、以及凹孔121h、150h和170h。As shown in FIG. 11A to FIG. 11C (FIG. 11A is a cross-sectional view taken along line 9A-9A′ of FIG. 9 , and FIG. 11B is a cross-sectional view taken along line 9B-9B′ of FIG. 9 . Figure 11C shows the section line along Figure 9. A cross-sectional view of the 9C-9C' is formed to form a dielectric material coating layer 123a on the stacked structure 110 and in the recess 121h. In the embodiment, the dielectric material coating layer 123a completely covers the barrier layer 160, the stacked structure 110, the grooves 130t and 130t', and the recessed holes 121h, 150h, and 170h.
如第12A~12C圖所示(第12A圖繪示沿第9圖之剖面線9A-9A’之剖面示意圖,第12B圖繪示沿第9圖之剖面線9B-9B’之剖面示意圖,第12C圖繪示沿第9圖之剖面線9C-9C’之剖面示意圖),蝕刻介電材料塗佈層123a及阻障層160,凹孔121h曝露出各堆疊結構110之一部份,例如是各堆疊結構110之第一端110a(位於接觸區BLP內之一端的導電條111),而形成介電材料層123於凹孔121h之側壁上。實施例中,介電材料層123亦形成於凹孔150h和170h之側壁上、凹槽130t和130t’之側壁上及堆疊結構110之間,凹孔150h曝露出各導電塊150。實施例中,例如是以非等向性(anisotropic)蝕刻方式進行全面性的蝕刻。As shown in Figures 12A-12C (Fig. 12A is a cross-sectional view taken along line 9A-9A' of Fig. 9, and Fig. 12B is a cross-sectional view taken along line 9B-9B' of Fig. 9, 12C is a cross-sectional view of the cross-sectional line 9C-9C' along the ninth drawing, etching the dielectric material coating layer 123a and the barrier layer 160, and the recess 121h exposes a part of each of the stacked structures 110, for example, The first end 110a of each of the stacked structures 110 (the conductive strips 111 at one end of the contact regions BLP) forms a dielectric material layer 123 on the sidewalls of the recessed holes 121h. In the embodiment, a dielectric material layer 123 is also formed on the sidewalls of the recesses 150h and 170h, between the sidewalls of the recesses 130t and 130t' and between the stacked structures 110, and the recess 150h exposes the respective conductive bumps 150. In the examples, for example, a comprehensive etching is performed by an anisotropic etching method.
如第13A~13C圖所示(第13A圖繪示沿第9圖之剖面線9A-9A’之剖面示意圖,第13B圖繪示沿第9圖之剖面線9B-9B’之剖面示意圖,第13C圖繪示沿第9圖之剖面線9C-9C’之剖面示意圖),填入導電材料於凹孔121h中並形成導電材料層1320。實施例中,導電材料亦填入於凹孔150h和170h中、凹槽130t和130t’中及堆疊結構110之間。實施例中,填入導電材料於凹槽130t和130t’中與填入導電材料於凹孔121h、150h和170h中例如係同時進行。實施例中,導電材料層1320完全覆蓋堆疊結構110及接觸區BLP。導電材料層1320例如是未摻雜多晶矽 (undoped polysilicon)。As shown in Figs. 13A-13C (Fig. 13A is a cross-sectional view taken along line 9A-9A' of Fig. 9 and Fig. 13B is a cross-sectional view taken along line 9B-9B' of Fig. 9, 13C is a cross-sectional view taken along line 9C-9C' of FIG. 9 and filled with a conductive material in the recess 121h to form a conductive material layer 1320. In the embodiment, a conductive material is also filled in the recesses 150h and 170h, in the recesses 130t and 130t', and between the stacked structures 110. In the embodiment, the filling of the conductive material in the grooves 130t and 130t' is performed simultaneously with filling the conductive material in the recesses 121h, 150h and 170h, for example. In an embodiment, the conductive material layer 1320 completely covers the stacked structure 110 and the contact region BLP. The conductive material layer 1320 is, for example, an undoped polysilicon (undoped polysilicon).
如第14~15C圖所示(第15A圖繪示沿第14圖之剖面線14A-14A’之剖面示意圖,第15B圖繪示沿第14圖之剖面線14B-14B’之剖面示意圖,第15C圖繪示沿第14圖之剖面線14C-14C’之剖面示意圖),移除部分導電材料層1320以曝露出絕緣材料層140a的上表面140a1,至此形成多個第一導電柱121。實施例中,多個第一導電柱121例如是形成於接觸區BLP的階梯結構上方以及導電塊150之上。實施例中,例如是以化學機械研磨(CMP)的方式移除部分導電材料層1320以形成多個第一導電柱121。實施例中,平坦化後形成的第一導電柱121之上表面121a實質上與絕緣材料層140a的上表面140a1位於同一平面。As shown in Figures 14 to 15C (Fig. 15A is a cross-sectional view taken along line 14A-14A' of Fig. 14, and Fig. 15B is a cross-sectional view taken along line 14B-14B' of Fig. 14, 15C is a cross-sectional view of the section line 14C-14C' taken along line 14 of FIG. 14 and a portion of the conductive material layer 1320 is removed to expose the upper surface 140a1 of the insulating material layer 140a, thereby forming a plurality of first conductive pillars 121. In an embodiment, the plurality of first conductive pillars 121 are formed over the stepped structure of the contact region BLP and over the conductive bumps 150, for example. In an embodiment, a portion of the conductive material layer 1320 is removed, for example, by chemical mechanical polishing (CMP) to form a plurality of first conductive pillars 121. In the embodiment, the upper surface 121a of the first conductive pillar 121 formed after planarization is substantially in the same plane as the upper surface 140a1 of the insulating material layer 140a.
實施例中,移除部分導電材料層1320以曝露出絕緣材料層140a的上表面140a1亦形成複數個條狀導電結構130及130’於凹槽130t及130t’中,條狀導電結構130及130’的延伸方向D1係垂直於堆疊結構110的延伸方向D2。實施例中,形成條狀導電結構130及130與形成第一導電柱121例如係同時進行。實施例中,移除部分導電材料層1320以曝露出絕緣材料層140a的上表面140a1亦形成複數個導電塊170於凹孔170h中。In an embodiment, removing a portion of the conductive material layer 1320 to expose the upper surface 140a1 of the insulating material layer 140a also forms a plurality of strip-shaped conductive structures 130 and 130' in the recesses 130t and 130t', and the strip-shaped conductive structures 130 and 130 The extending direction D1 of ' is perpendicular to the extending direction D2 of the stacked structure 110. In the embodiment, forming the strip-shaped conductive structures 130 and 130 is performed simultaneously with forming the first conductive pillars 121, for example. In an embodiment, removing a portion of the conductive material layer 1320 to expose the upper surface 140a1 of the insulating material layer 140a also forms a plurality of conductive bumps 170 in the recess 170h.
一實施例中,以半導體結構100為一三維記憶裝置為例,條狀導電結構130例如是字元線,位於條狀導電結構130兩側的條狀導電結構130’例如是接地選擇線,導電塊150上的第一導電柱121例如是源極接點的接觸插拴,導電塊170例如是串列選擇線,導電塊170經由導電條111 電性連接於接觸結構120。實施例中,條狀導電結構130形成於間隔開的凹槽130t中,因此條狀導電結構130之間具有良好的絕緣性。也就是說,各個條狀導電結構130獨立地鑲嵌於間隔開的凹槽130t中並彼此間隔開,如此一來,各個條狀導電結構130之間不會有殘留的導電材料,而能夠具有良好的絕緣性,進而提高後續完成的記憶裝置之可靠性。In one embodiment, the semiconductor structure 100 is a three-dimensional memory device. The strip-shaped conductive structure 130 is, for example, a word line. The strip-shaped conductive structures 130 ′ on both sides of the strip-shaped conductive structure 130 are, for example, ground selection lines. The first conductive pillar 121 on the block 150 is, for example, a contact plug of a source contact, and the conductive block 170 is, for example, a tandem selection line, and the conductive block 170 is via the conductive strip 111. Electrically connected to the contact structure 120. In the embodiment, the strip-shaped conductive structures 130 are formed in the spaced apart grooves 130t, so that the strip-shaped conductive structures 130 have good insulation between them. That is to say, the strip-shaped conductive structures 130 are independently embedded in the spaced apart recesses 130t and spaced apart from each other, so that there is no residual conductive material between the strip-shaped conductive structures 130, and can have good The insulation improves the reliability of the subsequently completed memory device.
形成金屬矽化物層125的製造方法例如包括以下步驟。然而並不限於此,亦可直接於選定區域上沈積金屬矽化物層125。The manufacturing method of forming the metal telluride layer 125 includes, for example, the following steps. However, it is not limited thereto, and the metal halide layer 125 may be deposited directly on selected regions.
如第16A~16C圖所示(第16A圖繪示沿第14圖之剖面線14A-14A’之剖面示意圖,第16B圖繪示沿第14圖之剖面線14B-14B’之剖面示意圖,第16C圖繪示沿第14圖之剖面線14C-14C’之剖面示意圖),形成金屬層1620於第一導電柱121上。金屬層1620直接接觸第一導電柱121的上表面121a。金屬層1620例如是鈷或鎳。實施例中,金屬層1620實質上形成於整個結構的表面上,覆蓋堆疊結構110、條狀導電結構130和130’及接觸區BLP,並且,金屬層1620直接接觸條狀導電結構130和130’的上表面。As shown in Figs. 16A to 16C (Fig. 16A is a cross-sectional view taken along line 14A-14A' of Fig. 14, and Fig. 16B is a cross-sectional view taken along line 14B-14B' of Fig. 14, 16C is a cross-sectional view taken along line 14C-14C' of FIG. 14 to form a metal layer 1620 on the first conductive pillar 121. The metal layer 1620 directly contacts the upper surface 121a of the first conductive pillar 121. Metal layer 1620 is, for example, cobalt or nickel. In an embodiment, the metal layer 1620 is formed substantially on the surface of the entire structure, covering the stacked structure 110, the strip-shaped conductive structures 130 and 130' and the contact region BLP, and the metal layer 1620 directly contacts the strip-shaped conductive structures 130 and 130' Upper surface.
如第17~18C圖所示(第18A圖繪示沿第17圖之剖面線17A-17A’之剖面示意圖,第18B圖繪示沿第17圖之剖面線17B-17B’之剖面示意圖,第18C圖繪示沿第17圖之剖面線17C-17C’之剖面示意圖),第一導電柱121和條狀導電結構130和130’例如是含矽材料,對金屬層1620進行熱處理後,金屬矽化物層125便形成於第一導電柱121 及條狀導電結構130和130’的上表面上。形成的金屬矽化物層125例如是矽化鎳或矽化鈷。As shown in Figs. 17 to 18C (Fig. 18A is a cross-sectional view taken along line 17A-17A' of Fig. 17, and Fig. 18B is a cross-sectional view taken along line 17B-17B' of Fig. 17, 18C is a cross-sectional view of the section line 17C-17C' along the 17th drawing. The first conductive pillar 121 and the strip-shaped conductive structures 130 and 130' are, for example, germanium-containing materials. After the metal layer 1620 is heat-treated, the metal is deuterated. The layer 125 is formed on the first conductive pillar 121 And on the upper surface of the strip-shaped conductive structures 130 and 130'. The metal halide layer 125 formed is, for example, nickel telluride or cobalt telluride.
形成第二導電柱127於金屬矽化物層125上的製造方法例如包括以下步驟。The method of forming the second conductive pillar 127 on the metal telluride layer 125 includes, for example, the following steps.
如第19A~19C圖所示(第19A圖繪示沿第17圖之剖面線17A-17A’之剖面示意圖,第19B圖繪示沿第17圖之剖面線17B-17B’之剖面示意圖,第19C圖繪示沿第17圖之剖面線17C-17C’之剖面示意圖),形成絕緣材料層140b於整個結構的表面上,換句話說,絕緣材料層140b覆蓋堆疊結構110及接觸區BLP。實施例中,絕緣材料層140b覆蓋所有金屬矽化物層125。實施例中,絕緣材料層140b包括金屬氧化物,例如是層間介電層(interlayer dielectric)。19A to 19C (Fig. 19A is a cross-sectional view taken along line 17A-17A' of Fig. 17, and Fig. 19B is a cross-sectional view taken along line 17B-17B' of Fig. 17, 19C is a cross-sectional view taken along line 17C-17C' of FIG. 17 to form an insulating material layer 140b on the surface of the entire structure. In other words, the insulating material layer 140b covers the stacked structure 110 and the contact region BLP. In an embodiment, the insulating material layer 140b covers all of the metal telluride layers 125. In an embodiment, the insulating material layer 140b comprises a metal oxide, such as an interlayer dielectric.
如第20A~20B圖所示(第20A圖繪示沿第17圖之剖面線17A-17A’之剖面示意圖,第20B圖繪示沿第17圖之剖面線17B-17B’之剖面示意圖),設置硬式光罩HM3覆蓋絕緣材料層140b,再設置圖案化光阻層PR2於硬式光罩HM3上。實施例中,圖案化光阻層PR2的圖案係對應預定形成的多個第二導電柱127。20A-20B (Fig. 20A is a cross-sectional view taken along line 17A-17A' of Fig. 17, and Fig. 20B is a cross-sectional view taken along line 17B-17B' of Fig. 17) A hard mask HM3 is disposed to cover the insulating material layer 140b, and a patterned photoresist layer PR2 is disposed on the hard mask HM3. In an embodiment, the pattern of the patterned photoresist layer PR2 corresponds to a plurality of second conductive pillars 127 that are formed in advance.
如第21A~21C圖所示(第21A圖繪示沿第17圖之剖面線17A-17A’之剖面示意圖,第21B圖繪示沿第17圖之剖面線17B-17B’之剖面示意圖,第21C圖繪示沿第17圖之剖面線17C-17C’之剖面示意圖),形成複數個凹孔127h於絕緣材料層140b中,且此些凹孔127h係曝露出第一導電柱121上的金屬矽化物層125。實施例中,亦形成複數個凹孔150h’於導電塊150上方的絕緣材料層140b中,以 及形成複數個凹孔於導電塊170上方的絕緣材料層140b中,且曝露出位於導電塊150和170上方的金屬矽化物層125。實施例中,例如以光罩蝕刻方式,根據圖案化光阻層PR2蝕刻絕緣材料層140b,以形成凹孔。21A to 21C (FIG. 21A is a cross-sectional view taken along line 17A-17A' of FIG. 17, and FIG. 21B is a cross-sectional view taken along line 17B-17B' of FIG. 21C is a cross-sectional view taken along line 17C-17C' of FIG. 17, and a plurality of recessed holes 127h are formed in the insulating material layer 140b, and the recessed holes 127h expose the metal on the first conductive pillar 121. Telluride layer 125. In the embodiment, a plurality of recessed holes 150h' are also formed in the insulating material layer 140b above the conductive block 150, And forming a plurality of recesses in the insulating material layer 140b over the conductive bumps 170, and exposing the metal telluride layer 125 over the conductive bumps 150 and 170. In an embodiment, the insulating material layer 140b is etched according to the patterned photoresist layer PR2, for example, in a mask etching manner to form recessed holes.
如第22~23C圖所示(第23A圖繪示沿第22圖之剖面線22A-22A’之剖面示意圖,第23B圖繪示沿第22圖之剖面線22B-22B’之剖面示意圖,第23C圖繪示沿第22圖之剖面線22C-22C’之剖面示意圖),填入導電材料於凹孔127h中以形成第二導電柱127。實施例中,第二導電柱127亦形成於導電塊150和170上方的凹孔中。實施例中,更可平坦化絕緣材料層140b及多個第二導電柱127的表面,多個第二導電柱127的高度係為相同。至此,形成半導體結構100。As shown in Fig. 22~23C (Fig. 23A shows a cross-sectional view along section line 22A-22A' of Fig. 22, and Fig. 23B shows a cross-sectional view along section line 22B-22B' of Fig. 22, 23C is a cross-sectional view taken along line 22C-22C' of FIG. 22, and a conductive material is filled in the recess 127h to form a second conductive pillar 127. In an embodiment, the second conductive pillars 127 are also formed in the recesses above the conductive bumps 150 and 170. In the embodiment, the surface of the insulating material layer 140b and the plurality of second conductive pillars 127 are further planarized, and the heights of the plurality of second conductive pillars 127 are the same. So far, the semiconductor structure 100 is formed.
如第22~23C圖所示,絕緣材料層140a和140b形成絕緣結構140,絕緣結構140位於接觸結構120之間,且接觸結構120係以絕緣結構140彼此分隔開。此外,條狀導電結構130和130’之間係以絕緣結構140(絕緣材料層140a)彼此分隔開。As shown in FIGS. 22 to 23C, the insulating material layers 140a and 140b form an insulating structure 140, the insulating structure 140 is located between the contact structures 120, and the contact structures 120 are separated from each other by the insulating structure 140. Further, the strip-shaped conductive structures 130 and 130' are separated from each other by an insulating structure 140 (insulating material layer 140a).
一實施例中,以半導體結構100為一三維記憶裝置為例,導電塊150上方的接觸結構120例如是源極接點的接觸插拴,導電塊170上方的接觸結構例如是串列選擇線的接觸插拴,接觸區BLP上方的接觸結構120例如是位元線襯墊,藉由接觸區BLP中階梯狀排列的多個接觸結構120而能夠電性連接至並選取堆疊結構110中不同層的導電條111。In one embodiment, taking the semiconductor structure 100 as a three-dimensional memory device as an example, the contact structure 120 above the conductive block 150 is, for example, a contact plug of the source contact, and the contact structure above the conductive block 170 is, for example, a tandem selection line. The contact structure 120 above the contact region BLP is, for example, a bit line liner. The plurality of contact structures 120 arranged in a stepped manner in the contact region BLP can be electrically connected to and select different layers in the stacked structure 110. Conductive strip 111.
一般製作多個元件的接觸插拴的作法,先蝕刻階梯結構上方的氧化層而形成多個接觸孔,多個接觸孔的蝕刻深度根據鎢插拴的高度而定,接著填入鎢金屬而形成多個具有不同高度的鎢插拴。然而,當蝕刻深度越深,則越不易將鎢金屬緻密地填入蝕刻孔中,若是鎢插拴的內部因填不滿而有空隙,則很可能會發生接觸不良的問題。並且,為了蝕刻出很深的蝕刻孔,也會發生後續研磨不易的問題,而提高製程的難度。相對地,本揭露內容之實施例中,以兩段式的方式形成接觸結構,也就是說,一個接觸插拴分成兩個步驟蝕刻及填入導電材料,如此一來,可以確保形成的接觸結構具有高緻密性,接觸結構內部不易產生空隙,並且可以在同一個製程中製作多個具有不同高度的接觸結構,因此具有簡化製程步驟、以及減少製程時間及成本的效果。Generally, a contact plug of a plurality of components is formed by first etching an oxide layer above the step structure to form a plurality of contact holes. The etching depth of the plurality of contact holes is determined according to the height of the tungsten plug, and then filled with tungsten metal. A plurality of tungsten inserts having different heights. However, as the etching depth is deeper, it is less likely that the tungsten metal is densely filled in the etching hole, and if the inside of the tungsten intercalation is filled with voids, there is a possibility that contact failure may occur. Moreover, in order to etch a deep etching hole, a problem that subsequent polishing is difficult is also caused, and the difficulty of the process is improved. In contrast, in the embodiment of the present disclosure, the contact structure is formed in a two-stage manner, that is, one contact plug is divided into two steps to etch and fill the conductive material, so that the formed contact structure can be ensured. With high density, voids are not easily generated inside the contact structure, and a plurality of contact structures having different heights can be fabricated in the same process, thereby simplifying the process steps and reducing the process time and cost.
綜上所述,雖然本發明已以實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。In conclusion, the present invention has been disclosed in the above embodiments, but it is not intended to limit the present invention. A person skilled in the art can make various changes and modifications without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.
100‧‧‧半導體結構100‧‧‧Semiconductor structure
110‧‧‧堆疊結構110‧‧‧Stack structure
110a‧‧‧第一端110a‧‧‧ first end
110b‧‧‧第二端110b‧‧‧second end
110s‧‧‧側壁110s‧‧‧ side wall
111‧‧‧導電條111‧‧‧ Conductive strip
111a‧‧‧導電層111a‧‧‧ Conductive layer
113‧‧‧絕緣條113‧‧‧Insulation strip
113a‧‧‧絕緣層113a‧‧‧Insulation
120‧‧‧接觸結構120‧‧‧Contact structure
121‧‧‧第一導電柱121‧‧‧First conductive column
121a、140a1‧‧‧上表面121a, 140a1‧‧‧ upper surface
121H1~121H8、127H‧‧‧高度121H1~121H8, 127H‧‧‧ height
121h、127h、150h、150h’、170h‧‧‧凹孔121h, 127h, 150h, 150h', 170h‧‧‧ recessed holes
123‧‧‧介電材料層123‧‧‧ dielectric material layer
123a‧‧‧介電材料塗佈層123a‧‧‧Dielectric material coating layer
125‧‧‧金屬矽化物層125‧‧‧metal telluride layer
127‧‧‧第二導電柱127‧‧‧second conductive column
130、130’‧‧‧條狀導電結構130, 130'‧‧‧ strip-shaped conductive structure
130t、130t’‧‧‧凹槽130t, 130t’‧‧‧ grooves
140‧‧‧絕緣結構140‧‧‧Insulation structure
140a、140b‧‧‧絕緣材料層140a, 140b‧‧‧ insulating material layer
150、170‧‧‧導電塊150, 170‧‧‧ conductive blocks
160‧‧‧阻障層160‧‧‧Barrier layer
160a‧‧‧阻障材料層160a‧‧‧layer of barrier material
1320‧‧‧導電材料層1320‧‧‧ Conductive material layer
1620‧‧‧金屬層1620‧‧‧metal layer
2A-2A’2B-2B’、2C-2C’、3A-3A’、3B-3B’、6A-6A’、6B-6B’、6C-6C’、9A-9A’、9B-9B’、9C-9C’、14A-14A’、14B-14B’、14C-14C’、17A-17A’、17B-17B’、17C-17C’、22A-22A’、22B-22B’、22C-22C’‧‧‧剖面線2A-2A'2B-2B', 2C-2C', 3A-3A', 3B-3B', 6A-6A', 6B-6B', 6C-6C', 9A-9A', 9B-9B', 9C -9C', 14A-14A', 14B-14B', 14C-14C', 17A-17A', 17B-17B', 17C-17C', 22A-22A', 22B-22B', 22C-22C'‧ ‧ section line
BLP‧‧‧接觸區BLP‧‧‧Contact Zone
D1、D2‧‧‧延伸方向D1, D2‧‧‧ extending direction
HM1、HM2、HM3‧‧‧硬式光罩HM1, HM2, HM3‧‧‧ hard mask
PR1、PR2‧‧‧光阻層PR1, PR2‧‧‧ photoresist layer
第1圖繪示依照本發明之一實施例之半導體結構之俯視示意圖。1 is a top plan view of a semiconductor structure in accordance with an embodiment of the present invention.
第2A圖繪示沿第1圖之剖面線2A-2A’之剖面示意 圖。Fig. 2A is a schematic cross-sectional view taken along line 2A-2A' of Fig. 1 Figure.
第2B圖繪示沿第1圖之剖面線2B-2B’之剖面示意圖。Fig. 2B is a schematic cross-sectional view taken along line 2B-2B' of Fig. 1.
第2C圖繪示沿第1圖之剖面線2C-2C’之剖面示意圖。Fig. 2C is a schematic cross-sectional view taken along line 2C-2C' of Fig. 1.
第3圖至第23C圖繪示依照本發明之一實施例之一種半導體結構之製造方法示意圖。3 to 23C are schematic views showing a method of fabricating a semiconductor structure in accordance with an embodiment of the present invention.
100‧‧‧半導體結構100‧‧‧Semiconductor structure
110a‧‧‧第一端110a‧‧‧ first end
111‧‧‧導電條111‧‧‧ Conductive strip
120‧‧‧接觸結構120‧‧‧Contact structure
121‧‧‧第一導電柱121‧‧‧First conductive column
121a‧‧‧上表面121a‧‧‧ upper surface
121H1~121H8、127H‧‧‧高度121H1~121H8, 127H‧‧‧ height
123‧‧‧介電材料層123‧‧‧ dielectric material layer
125‧‧‧金屬矽化物層125‧‧‧metal telluride layer
127‧‧‧第二導電柱127‧‧‧second conductive column
140‧‧‧絕緣結構140‧‧‧Insulation structure
160‧‧‧阻障層160‧‧‧Barrier layer
Claims (9)
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| TWI550832B (en) * | 2014-10-08 | 2016-09-21 | 旺宏電子股份有限公司 | Semiconductor structure and manufacturing method of the same |
| US9514982B2 (en) | 2014-10-20 | 2016-12-06 | Macronix International Co., Ltd. | Semiconductor structure and manufacturing method of the same |
| TWI635600B (en) * | 2017-08-11 | 2018-09-11 | 旺宏電子股份有限公司 | Three dimensional memory device and method for fabricating the same |
| TWI641111B (en) * | 2017-10-23 | 2018-11-11 | 旺宏電子股份有限公司 | Stair contact structure, manufacturing method of stair contact structure, and memrry structure |
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| TW577126B (en) * | 2002-03-28 | 2004-02-21 | Fujitsu Ltd | Semiconductor device with copper wirings |
| TW201232705A (en) * | 2011-01-18 | 2012-08-01 | Macronix Int Co Ltd | Semiconductor structure and manufacturing method and operating method for the same |
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| TW577126B (en) * | 2002-03-28 | 2004-02-21 | Fujitsu Ltd | Semiconductor device with copper wirings |
| TW201232705A (en) * | 2011-01-18 | 2012-08-01 | Macronix Int Co Ltd | Semiconductor structure and manufacturing method and operating method for the same |
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