TWI569332B - Semiconductor device and fabrication method thereof - Google Patents

Semiconductor device and fabrication method thereof Download PDF

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TWI569332B
TWI569332B TW100136336A TW100136336A TWI569332B TW I569332 B TWI569332 B TW I569332B TW 100136336 A TW100136336 A TW 100136336A TW 100136336 A TW100136336 A TW 100136336A TW I569332 B TWI569332 B TW I569332B
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layer
polysilicon
gate electrode
semiconductor device
metal gate
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TW201316415A (en
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陳界得
鄒世芳
廖俊雄
林義博
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聯華電子股份有限公司
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Description

半導體元件結構及其製造方法 Semiconductor element structure and method of manufacturing same

本發明是有關於一種半導體元件及其製作方法,且特別是有關於一種具有金屬閘極結構的場效應電晶體元件及其製造方法。 The present invention relates to a semiconductor device and a method of fabricating the same, and more particularly to a field effect transistor device having a metal gate structure and a method of fabricating the same.

隨著半導體關鍵尺寸的縮小,場效應電晶體的尺寸以及閘極介電層的厚度也跟著受到限縮。然而,閘極介電層(gate dielectric layer)的厚度縮減將導致漏電流的發生。為了降低露電流的發生,遂有採用高介電係數(high-k)材質來製作閘介電層,同時採用金屬閘電極來置換阻值較高的多晶矽閘電極,藉以增進元件的效能。 As the critical dimensions of the semiconductor shrink, the size of the field effect transistor and the thickness of the gate dielectric layer are also limited. However, the reduction in the thickness of the gate dielectric layer will result in the occurrence of leakage current. In order to reduce the occurrence of dew current, a high dielectric constant (high-k) material is used to fabricate the gate dielectric layer, and a metal gate electrode is used to replace the polysilicon gate electrode with a higher resistance value, thereby improving the performance of the device.

習知製作金屬閘電極電晶體的方法,係先形成多晶矽虛擬閘極(dummy gate eletrode),待完成金屬-氧化物-半導體電晶體主結構之後,再以蝕刻步驟移除多晶矽虛擬閘極,並藉由金屬沉積的方式,取代原來的多晶矽虛擬閘極。 A method for fabricating a metal gate electrode transistor is to form a dummy gate eletrode. After the metal-oxide-semiconductor transistor main structure is completed, the polysilicon dummy gate is removed by an etching step, and The original polysilicon virtual gate is replaced by metal deposition.

然而,移除多晶矽虛擬閘極與金屬沉積製程,很可能會影響電晶體元件與其他半導體元件的製程整合。例如,多晶矽層,通常會被用來製備電晶體的多晶矽虛擬閘電極以及電阻(或其他被動元件)的多晶矽組件層。當進行多晶矽閘極移除蝕刻時,須先以光阻來遮罩多晶矽元件層,方能進行蝕刻。而此舉,常造成被動元件的多晶矽組件層與金屬閘電極之間,產生高低落差。進而,導致後續的金屬沉積以及金屬接觸製程,易 在被動元件的四周產生金屬殘留,影響元件的效能。 However, removing the polysilicon dummy gate and metal deposition process is likely to affect the process integration of the transistor component with other semiconductor components. For example, a polycrystalline germanium layer is typically used to fabricate polycrystalline germanium virtual gate electrodes for transistors and polysilicon stacks of resistors (or other passive components). When the polysilicon gate removal etching is performed, the polysilicon element layer must be masked with photoresist to perform etching. However, this often causes a high and low drop between the polysilicon device layer of the passive component and the metal gate electrode. In turn, resulting in subsequent metal deposition and metal contact processes, Metal residues are generated around the passive components, affecting the performance of the components.

因此有需要提供一種先進半導體元件及其製作方法,有效整合場效應電晶體與被動元件的製程,提高元件工作效能。 Therefore, it is necessary to provide an advanced semiconductor component and a manufacturing method thereof, and effectively integrate the process of the field effect transistor and the passive component to improve the working efficiency of the component.

有鑑於此,本發明提供一種半導體元件結構,包括金屬閘電極、被動元件以及硬罩幕層。被動元件具有一個多晶矽組件層。硬罩幕層覆蓋於金屬閘電極和被動元件上,具有實質共面的一第一開口與一第二開口,以分別將金屬閘電極和多晶矽組件層暴露於外。其中,第一開口與金屬閘電極的距離實質小於第二開口與多晶矽組件層的距離。 In view of this, the present invention provides a semiconductor device structure including a metal gate electrode, a passive component, and a hard mask layer. The passive component has a polycrystalline germanium component layer. The hard mask layer covers the metal gate electrode and the passive component, and has a first opening and a second opening substantially coplanar to expose the metal gate electrode and the polysilicon component layer respectively. Wherein, the distance between the first opening and the metal gate electrode is substantially smaller than the distance between the second opening and the polysilicon assembly layer.

在本發明之一實施例中,半導體元件結構更包括基材、汲極/源極結構以及閘介電層。其中,汲極/源極結構位於基材之中,與金屬閘電極鄰接。閘介電層位於汲極/源極結構與金屬閘電極之間。 In an embodiment of the invention, the semiconductor device structure further includes a substrate, a drain/source structure, and a gate dielectric layer. Wherein the drain/source structure is located in the substrate adjacent to the metal gate electrode. The gate dielectric layer is between the drain/source structure and the metal gate electrode.

在本發明之一實施例中,閘介電層包括:依序堆疊於基材上的介面層(interfacial layer,IL)以及高介電係數材質層。在本發明之一實施例中,被動元件為一電阻。在本發明之一實施例中,半導體元件結構更包括,位於高介電係數材質層與金屬閘電極之間的覆蓋層(capping layer)。 In an embodiment of the invention, the gate dielectric layer includes an interfacial layer (IL) and a high dielectric constant material layer sequentially stacked on the substrate. In one embodiment of the invention, the passive component is a resistor. In an embodiment of the invention, the semiconductor device structure further includes a capping layer between the high-k material layer and the metal gate electrode.

在本發明之一實施例中,半導體元件結構,更包括第一間隙壁以及第二間隙壁。其中,第一間隙壁,位於該金屬閘電極與該硬罩幕層之間;第二間隙壁,位於多晶矽組件層與該硬罩幕層之間。 In an embodiment of the invention, the semiconductor device structure further includes a first spacer and a second spacer. Wherein, a first spacer is located between the metal gate electrode and the hard mask layer; and a second spacer is located between the polysilicon assembly layer and the hard mask layer.

本發明另提供一種半導體元件結構的製造方法,包括下述 步驟:首先提供一個虛擬閘極(dummy gate)以及一個被動元件,其中虛擬閘極具有一個多晶矽閘電極層,且被動元件具有一個多晶矽組件層。接著,於虛擬閘極與被動元件上,形成硬罩幕層。然後,進行第一蝕刻製程,移除一部份硬罩幕層,藉以將一部份多晶矽組件層暴露於外。之後,於虛擬閘極與被動元件上,形成內層介電層(Inner Layer Dielectric,ILD);並以硬罩幕層為研磨終止層,對內層介電層進行平坦化。後續,進行第二蝕刻製程,移除多晶矽閘電極層,並於多晶矽閘電極層原來的位置上,形成金屬閘電極。 The present invention further provides a method of fabricating a semiconductor device structure, including the following Step: First, a dummy gate and a passive component are provided, wherein the dummy gate has a polysilicon gate electrode layer and the passive component has a polysilicon layer. Next, a hard mask layer is formed on the dummy gate and the passive component. Then, a first etching process is performed to remove a portion of the hard mask layer to expose a portion of the polysilicon device layer to the outside. Thereafter, an inner layer dielectric (ILD) is formed on the dummy gate and the passive component; and the inner dielectric layer is planarized by using the hard mask layer as a polishing stop layer. Subsequently, a second etching process is performed to remove the polysilicon gate electrode layer and form a metal gate electrode at the original position of the polysilicon gate electrode layer.

在本發明之一實施例中,第一蝕刻製程還移除了一部份的多晶矽組件層,藉以在被動元件中形成一個凹室,將剩餘的多晶矽組件層暴露於外。 In one embodiment of the invention, the first etch process also removes a portion of the polysilicon assembly layer to form an recess in the passive component to expose the remaining polysilicon component layer.

在本發明之一實施例中,虛擬閘極及被動元件的形成,包括下述步驟:首先依序於基材上形成介電材質層以及多晶矽材質層。接著,圖案化多晶矽材質層以及介電材質層,以於圖案化的介電材質層上,形成多晶矽閘電極以及多晶矽組件層。之後,分別於多晶矽閘電極以及多晶矽組件層之側壁上,形成第一間隙壁與第二間隙壁。 In an embodiment of the invention, the formation of the dummy gate and the passive component comprises the steps of first forming a dielectric material layer and a polysilicon material layer sequentially on the substrate. Next, the polysilicon material layer and the dielectric material layer are patterned to form a polysilicon gate electrode and a polysilicon device layer on the patterned dielectric material layer. Thereafter, a first spacer and a second spacer are formed on the sidewalls of the polysilicon gate electrode and the polysilicon assembly layer, respectively.

在本發明之一實施例中,介電材質層包括:依序堆疊於該基材上的介面層以及高介電係數材質層。在本發明之一實施例中,更包括,於高介電係數材質層以及多晶矽材質層之間,形成覆蓋層。在本發明之一實施例中,在形成金屬閘電極之前,更包括:於覆蓋層上,形成至少一功函數層(working function layer)。 In an embodiment of the invention, the dielectric material layer comprises: an interface layer sequentially stacked on the substrate and a high dielectric constant material layer. In an embodiment of the invention, the method further includes forming a cover layer between the high dielectric constant material layer and the polysilicon material layer. In an embodiment of the invention, before forming the metal gate electrode, the method further comprises: forming at least one working function layer on the cover layer.

在本發明之一實施例中,進行第二蝕刻製程之前,更包括:以虛擬閘極為罩幕,於基材之中形成汲極/源極結構。在 本發明之一實施例中,在形成金屬閘電極之前,更包括:於多晶矽閘電極層原來的位置上,形成高介電係數材質層;且於高介電係數材質層上形成至少一功函數層。 In an embodiment of the present invention, before performing the second etching process, the method further comprises: forming a gate/source structure in the substrate by using a dummy gate to cover the substrate. in In one embodiment of the present invention, before forming the metal gate electrode, the method further comprises: forming a high dielectric constant material layer at an original position of the polysilicon gate electrode layer; and forming at least one work function on the high dielectric constant material layer Floor.

在本發明之一實施例中,第二蝕刻製程包括乾式蝕刻及濕式蝕刻。在本發明之一實施例中,內層介電層的平坦化包括化學機械研磨(Chemical Mechanical Polishing,CMP)。 In an embodiment of the invention, the second etching process includes dry etching and wet etching. In one embodiment of the invention, planarization of the inner dielectric layer includes chemical mechanical polishing (CMP).

根據上述,本發明的實施例是提供一種整合金屬閘電極電晶體與被動元件的半導體元件結構。其製作方式,係先以硬罩幕覆蓋多晶矽虛擬閘電極與被動元件。再對被動元件進行第一次蝕刻製程,以移除一部份硬罩幕,並將被動元件的一部份多晶矽組件層暴露於外。之後,再進行第二次蝕刻製程,以移除多晶矽虛擬閘極。後續再進行金屬閘電極沉積以及平坦化製程,以形成彼此共平面的金屬閘電極以及被動元件。 In accordance with the above, embodiments of the present invention provide a semiconductor device structure that integrates a metal gate electrode transistor with a passive component. The way of making it is to cover the polysilicon virtual gate electrode and the passive component with a hard mask. The passive component is then subjected to a first etching process to remove a portion of the hard mask and expose a portion of the polysilicon component layer of the passive component. Thereafter, a second etching process is performed to remove the polysilicon dummy gate. Metal gate electrode deposition and planarization processes are subsequently performed to form metal gate electrodes and passive components that are coplanar with each other.

藉由兩次蝕刻製程,分別薄化動元件與移除虛擬閘極,可使被動元件與金屬閘電極,能在同一平面上進行後續的金屬接觸製程,減少被動元件多晶矽組件層的金屬殘留,提升元件的效能。 By means of two etching processes, respectively thinning the moving component and removing the dummy gate, the passive component and the metal gate electrode can be subjected to a subsequent metal contact process on the same plane, thereby reducing the metal residue of the passive component polysilicon component layer. Improve the performance of components.

本發明是在提供一種半導體元件結構及其製造方法,可將金屬閘電極電晶體與被動元件加以整合,並提高元件效能。為讓本發明之上述和其他目的、特徵和優點能更明顯易懂,下文特舉數個較佳實施例,並配合所附圖式,作詳細說明如下。 The present invention is to provide a semiconductor device structure and a method of fabricating the same, which can integrate a metal gate electrode transistor with a passive component and improve device performance. The above and other objects, features and advantages of the present invention will become more <RTIgt;

請參照圖1A到圖1G,圖1A到圖1G係根據本發明的一較佳實施例,所繪示之製作半導體元件結構100的一系列製程 結構剖面圖。其中,半導體元件結構100的製造方法,包括下述步驟:首先在基材101上依序形成介電材質層104、覆蓋層120以及多晶矽材質層105(如圖1A所繪示)。在本實施例之中,介電材質層104包括:依序堆疊於基材101上的介面層104a以及高介電係數材質層104b。介面層104a的材質,較佳為二氧化矽、氮化矽、氮氧化矽或氮碳化矽;高介電係數材質層104b的材質,較佳為矽化鉿、氧化鉿、氧化矽鉿或氮氧化矽鉿。覆蓋層120的材質,較佳為氮化鈦(TiN)或氮化鉭(TaN)。在本發明的一些實施例之中,還包括在多晶矽材質層105上,另外形成至少一硬式罩幕層(未繪示)。 Referring to FIG. 1A to FIG. 1G, FIG. 1A to FIG. 1G illustrate a series of processes for fabricating a semiconductor device structure 100 according to a preferred embodiment of the present invention. Structural profile. The method for manufacturing the semiconductor device structure 100 includes the steps of: sequentially forming a dielectric material layer 104, a cap layer 120, and a polysilicon layer 105 (as shown in FIG. 1A) on the substrate 101. In the present embodiment, the dielectric material layer 104 includes an interface layer 104a and a high-k material layer 104b which are sequentially stacked on the substrate 101. The material of the interface layer 104a is preferably cerium oxide, tantalum nitride, lanthanum oxynitride or lanthanum oxynitride; the material of the high dielectric constant material layer 104b is preferably bismuth telluride, cerium oxide, cerium oxide or oxynitride. Hey. The material of the cover layer 120 is preferably titanium nitride (TiN) or tantalum nitride (TaN). In some embodiments of the present invention, further comprising forming at least one hard mask layer (not shown) on the polysilicon material layer 105.

之後,對多晶矽材質層105以及介電材質層104進行圖案化製程,以於圖案化的介電質層104上,形成多晶矽閘電極106以及多晶矽組件層107(其中,位於多晶矽閘電極106下方的圖案化介電質層104,以下稱為閘介電層108)。 Thereafter, the polysilicon material layer 105 and the dielectric material layer 104 are patterned to form a polysilicon gate electrode 106 and a polysilicon device layer 107 on the patterned dielectric layer 104 (wherein the polysilicon gate electrode 106 is located under the polysilicon gate electrode 106). The patterned dielectric layer 104, hereinafter referred to as the gate dielectric layer 108).

再藉由沉積及蝕刻製程,分別於多晶矽閘電極106以及多晶矽組件層107之側壁上,形成第一間隙壁109與第二間隙壁110。進而,於基材101上提供一個虛擬閘極(dummy gate)102以及一個被動元件103。其中,被動元件103較佳為電阻。 The first spacers 109 and the second spacers 110 are formed on the sidewalls of the polysilicon gate electrode 106 and the polysilicon device layer 107, respectively, by a deposition and etching process. Further, a dummy gate 102 and a passive component 103 are provided on the substrate 101. Among them, the passive component 103 is preferably a resistor.

而在形成第一間隙壁109與第二間隙壁110之前,還包括,以多晶矽閘電極106和閘介電層108為罩幕,進行複數個輕摻雜製程,藉以在基材101之中形成輕摻雜汲極(Light Doped Drain,LDD)結構,並與閘介電層108鄰接。在形成第一間隙壁109與第二間隙壁110之後,再以虛擬閘極102作為罩幕,對輕摻雜汲極結構進行一連串的離子植入製程,於基材101之中形成汲極/源極結構119(如圖1B所繪示)。 Before forming the first spacers 109 and the second spacers 110, the method further includes: using the polysilicon gate electrode 106 and the gate dielectric layer 108 as a mask, performing a plurality of light doping processes, thereby forming in the substrate 101. A Light Doped Drain (LDD) structure is adjacent to the gate dielectric layer 108. After forming the first spacer 109 and the second spacer 110, the dummy gate 102 is used as a mask to perform a series of ion implantation processes on the lightly doped gate structure to form a drain in the substrate 101. The source structure 119 (as shown in FIG. 1B).

接著,於虛擬閘極102與被動元件103上,形成硬罩幕層111,並於硬罩幕層111上形成一圖案化光阻層112,將位於多晶矽組件層107上方的一部分硬罩幕層111暴露出來(如圖1C所繪示)。然後,進行第一蝕刻製程,以移除一部份硬罩幕層111,藉以於硬罩幕層111上定義出開口111a,將一部份多晶矽組件層107暴露於外。 Then, on the dummy gate 102 and the passive component 103, a hard mask layer 111 is formed, and a patterned photoresist layer 112 is formed on the hard mask layer 111 to place a portion of the hard mask layer above the polysilicon component layer 107. 111 is exposed (as shown in Figure 1C). Then, a first etching process is performed to remove a portion of the hard mask layer 111, whereby an opening 111a is defined on the hard mask layer 111 to expose a portion of the polysilicon device layer 107.

在本發明的一些實施例之中,硬罩幕層111可以是由單層或多層的氮化矽(SiN)、碳化矽(SiC)或碳氮化矽(SiCN)等材質,所構成的接觸蝕刻停止層(Contact Etch Stop Layer,CESL)。較佳地為可施加應力之氮化矽多層。 In some embodiments of the present invention, the hard mask layer 111 may be a single layer or a plurality of layers of tantalum nitride (SiN), tantalum carbide (SiC) or tantalum carbonitride (SiCN). Contact Etch Stop Layer (CESL). Preferably, a layer of tantalum nitride which can be stressed is applied.

在本發明的一些實施例之中,第一蝕刻製程113,較佳還會將一部份的多晶矽組件層107移除,藉以在被動元件103中,形成一個凹室113,將剩餘的多晶矽組件層107由開口111a暴露於外(如圖1D所繪示)。 In some embodiments of the present invention, the first etching process 113 preferably further removes a portion of the polysilicon component layer 107, thereby forming an recess 113 in the passive component 103, and the remaining polysilicon components. Layer 107 is exposed to the outside by opening 111a (as depicted in Figure ID).

後續,於虛擬閘極102與被動元件103上,形成內層介電層114,並填充凹室113。之後,再以硬罩幕層111為研磨終止層,對內層介電層114進行平坦化(如圖1E所繪示)。在本發明的較佳實施例中,內層介電層114的平坦化,包括化學機械研磨製程。 Subsequently, on the dummy gate 102 and the passive component 103, an inner dielectric layer 114 is formed and the recess 113 is filled. Thereafter, the inner dielectric layer 114 is planarized by using the hard mask layer 111 as a polishing stop layer (as shown in FIG. 1E). In a preferred embodiment of the invention, the planarization of the inner dielectric layer 114 includes a chemical mechanical polishing process.

之後,以覆蓋層120作為蝕刻終止層,進行第二蝕刻製程,以移除覆蓋於虛擬閘極102上的一部份硬罩幕層111,以及位於虛擬閘極102中的多晶矽閘電極106,藉以在硬罩幕層111上定義出開口111b,並在虛擬閘極102之中形成凹室115,讓覆蓋層120經由凹室115和開口111b暴露於外(如圖1F所繪示)。 Thereafter, using the capping layer 120 as an etch stop layer, a second etching process is performed to remove a portion of the hard mask layer 111 overlying the dummy gate 102, and the polysilicon gate electrode 106 located in the dummy gate 102, The opening 111b is defined on the hard mask layer 111, and the recess 115 is formed in the dummy gate 102, and the cover layer 120 is exposed to the outside via the recess 115 and the opening 111b (as shown in FIG. 1F).

在本發明的一些實施例之中,第二蝕刻製程可同時使用乾 式蝕刻以及濕式蝕刻兩種蝕刻方式。在本實施例之中,則係先採用乾式蝕刻來移除硬罩幕層111;再採用濕式蝕刻來移除多晶矽閘電極106。 In some embodiments of the invention, the second etching process can be used simultaneously Etching and wet etching are two etching methods. In the present embodiment, the hard mask layer 111 is first removed by dry etching; the polysilicon gate electrode 106 is removed by wet etching.

之後,於凹室115中的覆蓋層120上,形成至少一個功函數層116,例如氮化鈦或鈦鋁合金(TiAl);再於功函數層116上沉積金屬層,並對金屬層進行平坦化步驟,而形成包含有金屬閘電極117的金屬閘極結構118,完成半導體元件結構100的製備(如圖1G所繪示)。後續再於金屬閘極結構118和被動元件103上,進行金屬接觸製程,形成複數個與金屬內連線電性接觸的金屬接觸(未繪示)。 Thereafter, on the cover layer 120 in the recess 115, at least one work function layer 116, such as titanium nitride or titanium aluminum alloy (TiAl), is formed; a metal layer is deposited on the work function layer 116, and the metal layer is flattened. The metal gate structure 118 including the metal gate electrode 117 is formed to complete the fabrication of the semiconductor device structure 100 (as shown in FIG. 1G). Subsequent to the metal gate structure 118 and the passive component 103, a metal contact process is performed to form a plurality of metal contacts (not shown) that are in electrical contact with the metal interconnects.

請參照圖2A到圖2G,圖2A到圖2G係根據本發明的另一較佳實施例,繪示製作半導體元件結構200的一系列製程結構剖面圖。其中,半導體元件結構200的製造方法,包括下述步驟:首先在基材201上依序形成介電材質層204以及多晶矽材質層205(如圖2A所繪示)。在本實施例之中,介電材質層204較佳為二氧化矽、氮化矽、氮氧化矽或氮碳化矽。 Referring to FIG. 2A to FIG. 2G, FIG. 2A to FIG. 2G are cross-sectional views showing a series of process structures for fabricating the semiconductor device structure 200 according to another preferred embodiment of the present invention. The method for manufacturing the semiconductor device structure 200 includes the steps of: sequentially forming a dielectric material layer 204 and a polysilicon material layer 205 (as shown in FIG. 2A ) on the substrate 201 . In the present embodiment, the dielectric material layer 204 is preferably hafnium oxide, hafnium nitride, hafnium oxynitride or niobium nitrite.

之後,對多晶矽材質層205以及介電材質層204進行圖案化製程,以於圖案化的介電材質層204上形成多晶矽閘電極206以及多晶矽組件層207。再藉由沉積與蝕刻製程,分別於多晶矽閘電極206以及多晶矽組件層207之側壁上,形成第一間隙壁209與第二間隙壁210。進而,於基材201上提供一個虛擬閘極202以及一個被動元件203(較佳為電阻)。 Thereafter, the polysilicon material layer 205 and the dielectric material layer 204 are patterned to form a polysilicon gate electrode 206 and a polysilicon device layer 207 on the patterned dielectric material layer 204. A first spacer 209 and a second spacer 210 are formed on the sidewalls of the polysilicon gate electrode 206 and the polysilicon device layer 207, respectively, by a deposition and etching process. Further, a dummy gate 202 and a passive component 203 (preferably a resistor) are provided on the substrate 201.

而在形成第一間隙壁209與第二間隙壁210之前,還包括,以多晶矽閘電極206和閘介電層208為罩幕,進行複數個輕摻雜製程,藉以在基材201之中形成輕摻雜汲極結構,與閘 介電層108鄰接。之後,再以虛擬閘極202為罩幕,於基材201之中形成汲極/源極結構219(如圖2B所繪示)。 Before the first spacer 209 and the second spacer 210 are formed, the polysilicon gate electrode 206 and the gate dielectric layer 208 are used as a mask to perform a plurality of light doping processes to form a substrate 201. Lightly doped bungee structure, with gate Dielectric layer 108 is contiguous. Then, with the dummy gate 202 as a mask, a drain/source structure 219 is formed in the substrate 201 (as shown in FIG. 2B).

接著,於虛擬閘極202與被動元件203上,形成硬罩幕層211,並於硬罩幕層211形成一圖案化光阻層212,將位於多晶矽組件層207上方的一部分硬罩幕層211暴露出來(如圖2C所繪示)。在本發明的一些實施例之中,硬罩幕層211可以是由單層或多層的氮化矽、碳化矽或碳氮化矽材質,所構成的接觸蝕刻停止層。較佳地為可施加應力之氮化矽多層。 Next, a hard mask layer 211 is formed on the dummy gate 202 and the passive component 203, and a patterned photoresist layer 212 is formed on the hard mask layer 211 to place a portion of the hard mask layer 211 above the polysilicon component layer 207. Exposed (as shown in Figure 2C). In some embodiments of the present invention, the hard mask layer 211 may be a contact etch stop layer composed of a single layer or a plurality of layers of tantalum nitride, tantalum carbide or tantalum carbonitride. Preferably, a layer of tantalum nitride which can be stressed is applied.

然後,進行第一蝕刻製程,以移除一部份硬罩幕層211及一部份的多晶矽組件層207,藉以在硬罩幕層211上定義出開口211a,並且在被動元件203之中,形成一個凹室213,將剩餘的多晶矽組件層207經由開口211a暴露於外(如圖2D所繪示)。 Then, a first etching process is performed to remove a portion of the hard mask layer 211 and a portion of the polysilicon device layer 207, thereby defining an opening 211a on the hard mask layer 211, and among the passive components 203, An alcove 213 is formed to expose the remaining polysilicon component layer 207 to the outside via the opening 211a (as shown in FIG. 2D).

後續,於虛擬閘極202與被動元件203上,形成內層介電層214,並填充凹室213。之後,再以硬罩幕層211為研磨終止層,對內層介電層214進行平坦化(如圖2E所繪示)。在本發明的較佳實施例中,內層介電層214的平坦化,包括化學機械研磨製程。 Subsequently, on the dummy gate 202 and the passive component 203, an inner dielectric layer 214 is formed and the recess 213 is filled. Thereafter, the inner dielectric layer 214 is planarized by using the hard mask layer 211 as a polishing stop layer (as shown in FIG. 2E). In a preferred embodiment of the invention, the planarization of the inner dielectric layer 214 includes a chemical mechanical polishing process.

之後,以介電材質層204作為蝕刻終止層,進行第二蝕刻製程,移除覆蓋於虛擬閘極202上的一部份硬罩幕層211,以及位於虛擬閘極202中的多晶矽閘電極206,藉以以在硬罩幕層211上定義出開口211b,並在虛擬閘極202之中形成凹室215,讓介電材質層204經由凹室215及開口211b暴露於外(如圖2F所繪示)。 Thereafter, a second etching process is performed using the dielectric material layer 204 as an etch stop layer to remove a portion of the hard mask layer 211 overlying the dummy gate 202, and the polysilicon gate electrode 206 located in the dummy gate 202. Therefore, the opening 211b is defined on the hard mask layer 211, and the concave chamber 215 is formed in the dummy gate 202, so that the dielectric material layer 204 is exposed to the outside through the concave chamber 215 and the opening 211b (as shown in FIG. 2F). Show).

在本發明的一些實施例之中,第二蝕刻製程可同時使用乾式蝕刻以及濕式蝕刻兩種蝕刻方式。在本實施例之中,則係先 採用乾式蝕刻來移除硬罩幕層211;再採用濕式蝕刻來移除多晶矽閘電極206。 In some embodiments of the present invention, the second etching process may use both dry etching and wet etching. In this embodiment, it is first The hard mask layer 211 is removed by dry etching; the polysilicon gate electrode 206 is removed by wet etching.

移除多晶矽閘電極206之後,在經由凹室215及開口211b暴露於外的介電材質層204上,形成具有高介電係數的閘介電層208。在本實施例之中,閘介電層208。包括:依序堆疊於介面材質層204上的高介電係數材質層208a以及覆蓋層208b。 After the polysilicon gate electrode 206 is removed, a gate dielectric layer 208 having a high dielectric constant is formed on the dielectric material layer 204 exposed through the recess 215 and the opening 211b. In the present embodiment, the gate dielectric layer 208. The method includes: a high-k material layer 208a and a cover layer 208b stacked on the interface material layer 204 in sequence.

接著,於高介電係數材質層208a上形成至少一個功函數層216;再於功函數層216上沉積金屬層;並對金屬層進行平坦化步驟,藉以形成包含金屬閘電極217的金屬閘極結構218,完成半導體元件結構200的製備(如圖2G所繪示)。後續再進行金屬接觸製程,形成複數個金屬接觸,與金屬內連線電性接觸(未繪示)。 Next, at least one work function layer 216 is formed on the high dielectric constant material layer 208a; a metal layer is deposited on the work function layer 216; and the metal layer is planarized to form a metal gate including the metal gate electrode 217. Structure 218 completes the fabrication of semiconductor device structure 200 (as depicted in Figure 2G). Subsequent metal contact processes are performed to form a plurality of metal contacts that are in electrical contact with the metal interconnects (not shown).

請再參照圖2G,半導體元件結構200,包括金屬閘極結構218、硬罩幕層211以及被動元件203。其中,硬罩幕層211,覆蓋於金屬閘極結構218和被動元件203的側壁上,與金屬閘極結構218和被動元件203的第一間隙壁209與第二間隙壁210共形。 Referring again to FIG. 2G, the semiconductor device structure 200 includes a metal gate structure 218, a hard mask layer 211, and a passive component 203. The hard mask layer 211 covers the metal gate structure 218 and the sidewalls of the passive component 203, and conforms to the metal gate structure 218 and the first spacer 209 of the passive component 203 and the second spacer 210.

另外,硬罩幕層211具有兩個開口,例如開口211a與211b,可分別用來將金屬閘極結構218的金屬閘電極217和被動元件203的多晶矽組件層207暴露於外。雖然,開口211a和211b係分別藉由兩個不同的蝕刻製程所定義出來。但是,由於在兩個不同的蝕刻製程之後,硬罩幕層211還會再經歷至少一道平坦化步驟,使得開口211a和211b彼此實質共面。亦即是說,金屬閘極結構218和被動元件203二者,能在同一平面上進行後續的金屬接觸製程。 In addition, the hard mask layer 211 has two openings, such as openings 211a and 211b, for respectively exposing the metal gate electrode 217 of the metal gate structure 218 and the polysilicon component layer 207 of the passive component 203 to the outside. Although openings 211a and 211b are defined by two different etching processes, respectively. However, since after two different etching processes, the hard mask layer 211 will again undergo at least one planarization step such that the openings 211a and 211b are substantially coplanar with each other. That is to say, both the metal gate structure 218 and the passive component 203 can perform subsequent metal contact processes on the same plane.

又,由於構成被動元件203的多晶矽組件層207,在進行 第一次蝕刻製程時,遭到部份移除,使得多晶矽組件層207的厚度,小於置換多晶矽閘電極206之金屬閘電極217、閘介電層208與功函數層216三者的厚度。因此,當金屬閘電極217、閘介電層208與功函數層216三者經過金屬平坦化步驟之後,多晶矽組件層207與開口211b之間,仍會存在一個高度落差H。,也就是說,雖然暴露金屬閘電極217和多晶矽組件層207的開口211b和211a,彼此實質共平面,但開口211b與金屬閘電極217之間的距離,仍實質小於開口211a與多晶矽組件層207之間的距離。 Further, since the polysilicon component layer 207 constituting the passive component 203 is being carried out During the first etching process, partial removal is performed such that the thickness of the polysilicon device layer 207 is less than the thickness of the metal gate electrode 217, the gate dielectric layer 208, and the work function layer 216 of the replacement polysilicon gate electrode 206. Therefore, after the metal gate electrode 217, the gate dielectric layer 208 and the work function layer 216 pass through the metal planarization step, there is still a height drop H between the polysilicon component layer 207 and the opening 211b. That is, although the openings 211b and 211a exposing the metal gate electrode 217 and the polysilicon device layer 207 are substantially coplanar with each other, the distance between the opening 211b and the metal gate electrode 217 is substantially smaller than the opening 211a and the polysilicon component layer 207. the distance between.

根據上述,本發明的實施例是提供一種整合金屬閘電極電晶體與被動元件的半導體元件結構。其製作方式,係先以硬罩幕覆蓋多晶矽虛擬閘電極與被動元件。再對被動元件進行第一次蝕刻製程,以移除一部份硬罩幕,並將被動元件的一部份多晶矽組件層暴露於外。之後,再進行第二次蝕刻製程,以移除多晶矽虛擬閘極。後續再進行金屬閘電極沉積以及平坦化製程,以形成彼此共平面的金屬閘電極以及被動元件。 In accordance with the above, embodiments of the present invention provide a semiconductor device structure that integrates a metal gate electrode transistor with a passive component. The way of making it is to cover the polysilicon virtual gate electrode and the passive component with a hard mask. The passive component is then subjected to a first etching process to remove a portion of the hard mask and expose a portion of the polysilicon component layer of the passive component. Thereafter, a second etching process is performed to remove the polysilicon dummy gate. Metal gate electrode deposition and planarization processes are subsequently performed to form metal gate electrodes and passive components that are coplanar with each other.

藉由兩次蝕刻製程,分別薄化被動元件與移除虛擬閘極,可使被動元件與金屬閘電極,能在同一平面上進行後續的金屬接觸製程,減少被動元件多晶矽組件層的金屬殘留,提升元件的效能。 By thinning the passive component and removing the dummy gate by two etching processes, the passive component and the metal gate electrode can perform subsequent metal contact processes on the same plane, and reduce the metal residue of the passive component polysilicon component layer. Improve the performance of components.

雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 While the present invention has been described in its preferred embodiments, the present invention is not intended to limit the invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application.

100‧‧‧半導體元件結構 100‧‧‧Semiconductor component structure

101‧‧‧基材 101‧‧‧Substrate

102‧‧‧虛擬閘極 102‧‧‧virtual gate

103‧‧‧被動元件 103‧‧‧ Passive components

104‧‧‧介電材質層 104‧‧‧Dielectric material layer

104a‧‧‧介面層 104a‧‧‧Interface

104b‧‧‧高介電係數材質層 104b‧‧‧High dielectric constant material layer

105‧‧‧多晶矽材質層 105‧‧‧ Polysilicon layer

106‧‧‧多晶矽閘電極 106‧‧‧Polysilicon gate electrode

107‧‧‧多晶矽組件層 107‧‧‧ Polysilicon component layer

108‧‧‧閘介電層 108‧‧‧gate dielectric layer

109‧‧‧第一間隙壁 109‧‧‧First gap

110‧‧‧第二間隙壁 110‧‧‧Second gap

111‧‧‧硬罩幕層 111‧‧‧hard mask layer

111a‧‧‧開口 111a‧‧‧ openings

111b‧‧‧開口 111b‧‧‧ openings

112‧‧‧圖案化光阻層 112‧‧‧ patterned photoresist layer

113‧‧‧凹室 113‧‧ ‧ alcove

114‧‧‧內層介電層 114‧‧‧ Inner dielectric layer

115‧‧‧凹室 115‧‧ ‧ alcove

116‧‧‧功函數層 116‧‧‧Work function layer

117‧‧‧金屬閘電極 117‧‧‧Metal gate electrode

118‧‧‧金屬閘極結構 118‧‧‧Metal gate structure

119‧‧‧汲極/源極結構 119‧‧‧汲polar/source structure

120‧‧‧覆蓋層 120‧‧‧ Coverage

200‧‧‧半導體元件結構 200‧‧‧Semiconductor component structure

201‧‧‧基材 201‧‧‧Substrate

202‧‧‧虛擬閘極 202‧‧‧virtual gate

203‧‧‧被動元件 203‧‧‧ Passive components

204‧‧‧介電材質層 204‧‧‧Dielectric material layer

205‧‧‧多晶矽材質層 205‧‧‧ Polysilicon layer

206‧‧‧多晶矽閘電極 206‧‧‧Polysilicon gate electrode

207‧‧‧多晶矽組件層 207‧‧‧ Polysilicon component layer

208‧‧‧閘介電層 208‧‧‧gate dielectric layer

208a‧‧‧高介電係數材質層 208a‧‧‧High dielectric constant material layer

208b‧‧‧覆蓋層 208b‧‧‧ Coverage

209‧‧‧第一間隙壁 209‧‧‧ first gap wall

210‧‧‧第二間隙壁 210‧‧‧Second gap

211‧‧‧硬罩幕層 211‧‧‧ Hard mask layer

211a‧‧‧開口 211a‧‧‧ openings

211b‧‧‧開口 211b‧‧‧ openings

212‧‧‧圖案化光阻層 212‧‧‧ patterned photoresist layer

213‧‧‧凹室 213‧‧ ‧ alcove

214‧‧‧內層介電層 214‧‧‧ Inner dielectric layer

215‧‧‧凹室 215‧‧ ‧ alcove

216‧‧‧功函數層 216‧‧‧Work function layer

217‧‧‧金屬閘電極 217‧‧‧Metal gate electrode

218‧‧‧金屬閘極結構 218‧‧‧Metal gate structure

219‧‧‧汲極/源極結構 219‧‧‧Bunging/source structure

H‧‧‧高度落差 H‧‧‧ height drop

圖1A到圖1G係根據本發明的一較佳實施例,繪示製作半導體元件結構的一系列製程結構剖面圖。 1A through 1G are cross-sectional views showing a series of process structures for fabricating a semiconductor device structure in accordance with a preferred embodiment of the present invention.

圖2A到圖2G係根據本發明的另一較佳實施例,繪示製作半導體元件結構的一系列製程結構剖面圖。 2A through 2G are cross-sectional views showing a series of process structures for fabricating a semiconductor device structure in accordance with another preferred embodiment of the present invention.

200‧‧‧半導體元件結構 200‧‧‧Semiconductor component structure

201‧‧‧基材 201‧‧‧Substrate

203‧‧‧被動元件 203‧‧‧ Passive components

204‧‧‧介電材質層 204‧‧‧Dielectric material layer

207‧‧‧多晶矽組件層 207‧‧‧ Polysilicon component layer

208‧‧‧閘介電層 208‧‧‧gate dielectric layer

208a‧‧‧高介電係數材質層 208a‧‧‧High dielectric constant material layer

208b‧‧‧覆蓋層 208b‧‧‧ Coverage

209‧‧‧第一間隙壁 209‧‧‧ first gap wall

210‧‧‧第二間隙壁 210‧‧‧Second gap

211‧‧‧硬罩幕層 211‧‧‧ Hard mask layer

211a‧‧‧開口 211a‧‧‧ openings

211b‧‧‧開口 211b‧‧‧ openings

214‧‧‧內層介電層 214‧‧‧ Inner dielectric layer

216‧‧‧功函數層 216‧‧‧Work function layer

217‧‧‧金屬閘電極 217‧‧‧Metal gate electrode

218‧‧‧金屬閘極結構 218‧‧‧Metal gate structure

219‧‧‧汲極/源極結構 219‧‧‧Bunging/source structure

H‧‧‧高度落差H‧‧‧ height drop

Claims (14)

一種半導體元件結構,包括:一金屬閘極結構,具有一金屬閘電極;一被動元件,位於一隔離結構上且與該金屬閘極結構相鄰,具有一多晶矽組件層,其中該被動元件為一電阻;以及一硬罩幕層,覆蓋於該金屬閘極結構與該被動元件上,且具有實質共面的一第一開口與一第二開口,以分別將該金屬閘電極和該多晶矽組件層暴露於外;其中該金屬閘電極之一上表面與該多晶矽組件層之一上表面具有一高度落差。 A semiconductor device structure comprising: a metal gate structure having a metal gate electrode; a passive component on an isolation structure adjacent to the metal gate structure and having a polysilicon component layer, wherein the passive component is a And a hard mask layer covering the metal gate structure and the passive component, and having a first opening and a second opening substantially coplanar to respectively form the metal gate electrode and the polysilicon component layer Exposed to the outside; wherein an upper surface of the metal gate electrode has a height difference from an upper surface of the polysilicon component layer. 如申請專利範圍第1項所述的半導體元件結構,更包括:一基材;一汲極/源極結構,位於該基材之中,與該金屬閘電極鄰接;以及一閘介電層,位於該汲極/源極結構與該金屬閘電極之間。 The semiconductor device structure of claim 1, further comprising: a substrate; a drain/source structure located in the substrate adjacent to the metal gate electrode; and a gate dielectric layer, Located between the drain/source structure and the metal gate electrode. 如申請專利範圍第2項所述的半導體元件結構,其中該閘介電層包括:依序堆疊於該基材上的一介面層(interfacial layer,IL)以及一高介電係數材質層。 The semiconductor device structure of claim 2, wherein the gate dielectric layer comprises: an interfacial layer (IL) sequentially stacked on the substrate and a high-k material layer. 如申請專利範圍第3項所述的半導體元件結構,更包括一覆蓋層(capping layer),位於該高介電係數材質層與該金屬閘電極之間。 The semiconductor device structure of claim 3, further comprising a capping layer between the high-k material layer and the metal gate electrode. 如申請專利範圍第1項所述的半導體元件結構,更包括:一第一間隙壁,位於該金屬閘電極與該硬罩幕層之間;以及一第二間隙壁,位於該多晶矽組件層與該硬罩幕層之間。 The semiconductor device structure of claim 1, further comprising: a first spacer between the metal gate electrode and the hard mask layer; and a second spacer disposed on the polysilicon assembly layer Between the hard mask layers. 一種半導體元件結構的製造方法,包括:提供一虛擬閘極(dummy gate)結構以及一被動元件,其中該虛擬閘極具有一多晶矽閘電極,且該被動元件具有一多晶矽組件層;於該虛擬閘極與該被動元件上,形成一硬罩幕層;進行一第一蝕刻製程,移除一部份該硬罩幕層,藉以將一部份該多晶矽組件層暴露於外,還移除了一部份的該多晶矽組件層,藉以將剩餘的該多晶矽組件層暴露於外;於該虛擬閘極與該被動元件上,形成一內層介電層(Inner Layer Dielectric,ILD);以該硬罩幕層為研磨終止層,平坦化該內層介電層;進行一第二蝕刻製程,移除該多晶矽閘電極;以及於多晶矽閘電極原來的位置上,形成一金屬閘電極。 A method of fabricating a semiconductor device structure, comprising: providing a dummy gate structure and a passive component, wherein the dummy gate has a polysilicon gate electrode, and the passive component has a polysilicon device layer; Forming a hard mask layer on the passive component; performing a first etching process to remove a portion of the hard mask layer, thereby exposing a portion of the polysilicon component layer to the outside, and removing one Part of the polysilicon component layer, thereby exposing the remaining polysilicon device layer to the outside; forming an inner layer dielectric (ILD) on the dummy gate and the passive component; The curtain layer is a polishing termination layer, planarizing the inner dielectric layer; performing a second etching process to remove the polysilicon gate electrode; and forming a metal gate electrode at the original position of the polysilicon gate electrode. 如申請專利範圍第6項所述之半導體元件結構的製造方法,其中形成該虛擬閘極及該被動元件的步驟,包括:依序於一基材上形成一介電材質層以及一多晶矽材質層;圖案化該多晶矽材質層以及該介電材質層,以於圖案化的該介電材質層上,形成該多晶矽閘電極和該多晶矽組件層;以及 分別於該多晶矽閘電極以及該多晶矽組件層之側壁上,形成一第一間隙壁與一第二間隙壁。 The method for fabricating a semiconductor device structure according to claim 6, wherein the step of forming the dummy gate and the passive component comprises: forming a dielectric material layer and a polysilicon material layer sequentially on a substrate. Patterning the polysilicon material layer and the dielectric material layer to form the polysilicon gate electrode and the polysilicon device layer on the patterned dielectric material layer; A first spacer and a second spacer are formed on the sidewalls of the polysilicon gate electrode and the polysilicon assembly layer, respectively. 如申請專利範圍第7項所述之半導體元件結構的製造方法,其中該介電材質層包括:依序堆疊於該基材上的一介面層以及一高介電係數材質層。 The method of fabricating a semiconductor device structure according to claim 7, wherein the dielectric material layer comprises: an interface layer sequentially stacked on the substrate and a high dielectric constant material layer. 如申請專利範圍第8項所述之半導體元件結構的製造方法,更包括於該高介電係數材質層以及該多晶矽材質層之間,形成一覆蓋層。 The method for fabricating a semiconductor device structure according to claim 8, further comprising forming a cap layer between the high dielectric constant material layer and the polysilicon material layer. 如申請專利範圍第9項所述之半導體元件結構的製造方法,其中在形成該金屬閘電極之前,更包括:於該覆蓋層上,形成至少一功函數層(working function layer)。 The method of fabricating a semiconductor device structure according to claim 9, wherein before forming the metal gate electrode, further comprising: forming at least one work function layer on the cover layer. 如申請專利範圍第7項所述之半導體元件結構的製造方法,其中在進行該第二蝕刻製程之前,更包括:以該虛擬閘極為罩幕,於該基材之中形成一汲極/源極結構。 The manufacturing method of the semiconductor device structure of claim 7, wherein before the performing the second etching process, the method further comprises: forming a drain/source in the substrate by using the dummy gate as a mask Pole structure. 如申請專利範圍第7項所述之半導體元件結構的製造方法,其中在形成該金屬閘電極之前,更包括:於多晶矽閘電極原來的位置上,形成一高介電係數材質層;以及於該高介電係數材質層上形成至少一功函數層。 The method for fabricating a semiconductor device structure according to claim 7, wherein before forming the metal gate electrode, further comprising: forming a high dielectric constant material layer at an original position of the polysilicon gate electrode; At least one work function layer is formed on the high dielectric constant material layer. 如申請專利範圍第6項所述之半導體元件結構的製造方法,其中該第二蝕刻製程包括一乾式蝕刻以及一濕式蝕刻。 The method of fabricating a semiconductor device structure according to claim 6, wherein the second etching process comprises a dry etching and a wet etching. 如申請專利範圍第6項所述之半導體元件結構的製造方法,其中該內層介電層的平坦化包括:一化學機械研磨(Chemical Mechanical Polishing,CMP)。 The method of fabricating a semiconductor device structure according to claim 6, wherein the planarization of the inner dielectric layer comprises: a chemical mechanical polishing (CMP).
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Citations (3)

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Publication number Priority date Publication date Assignee Title
US20100052058A1 (en) * 2008-08-29 2010-03-04 Taiwan Semiconductor Manufacturing Company, Ltd. Downsize polysilicon height for polysilicon resistor integration of replacement gate process
US20100237435A1 (en) * 2009-03-17 2010-09-23 International Business Machines Corporation Method and structure for gate height scaling with high-k/metal gate technology
US20110117710A1 (en) * 2009-11-19 2011-05-19 Yung-Chang Lin Method of fabricating efuse, resistor and transistor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100052058A1 (en) * 2008-08-29 2010-03-04 Taiwan Semiconductor Manufacturing Company, Ltd. Downsize polysilicon height for polysilicon resistor integration of replacement gate process
US20100237435A1 (en) * 2009-03-17 2010-09-23 International Business Machines Corporation Method and structure for gate height scaling with high-k/metal gate technology
US20110117710A1 (en) * 2009-11-19 2011-05-19 Yung-Chang Lin Method of fabricating efuse, resistor and transistor

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