TWI819111B - 短鏈烴在氣相中氫甲醯化的方法 - Google Patents

短鏈烴在氣相中氫甲醯化的方法 Download PDF

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TWI819111B
TWI819111B TW108135852A TW108135852A TWI819111B TW I819111 B TWI819111 B TW I819111B TW 108135852 A TW108135852 A TW 108135852A TW 108135852 A TW108135852 A TW 108135852A TW I819111 B TWI819111 B TW I819111B
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carrier
ceramic material
reactor
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ceramic
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TW202024010A (zh
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珍妮佛 赫賽博
羅伯特 法蘭克
法蘭克 史登革
彼得 凱雷斯
科麗娜 海特
馬克 奧列佛 克里斯敦
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德商贏創運營有限公司
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505Asymmetric hydroformylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • B01J27/22Carbides
    • B01J27/224Silicon carbide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235Nitrogen containing compounds
    • B01J31/0237Amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234Beta-dicarbonyl ligands, e.g. acetylacetonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/038Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78Separation; Purification; Stabilisation; Use of additives
    • C07C45/86Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/02Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • B01J27/22Carbides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW108135852A 2018-10-05 2019-10-03 短鏈烴在氣相中氫甲醯化的方法 TWI819111B (zh)

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EP18198785.0 2018-10-05
EP18198785 2018-10-05

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TWI819111B true TWI819111B (zh) 2023-10-21

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US (1) US10654784B2 (de)
EP (1) EP3632885A1 (de)
JP (1) JP7505870B2 (de)
KR (1) KR102946654B1 (de)
CN (1) CN111004097B (de)
MY (1) MY198398A (de)
SG (1) SG10201909162YA (de)
TW (1) TWI819111B (de)

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WO2020070052A1 (de) 2018-10-05 2020-04-09 Evonik Operations Gmbh Verfahren zur hydroformylierung von kurzkettigen olefinen in der gasphase
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US11008275B2 (en) 2019-06-12 2021-05-18 Evonik Operations Gmbh Process for preparing carboxylic acids or salts thereof from hydrocarbons
EP3945085B1 (de) 2020-07-30 2024-01-03 Evonik Oxeno GmbH & Co. KG Verfahren zur herstellung von aldehyden und abtrennung des katalysatorsystems mittels membrantrennung
US11806669B2 (en) 2020-12-22 2023-11-07 Evonik Operations Gmbh Variable and self-regulating permeate recycling in organophilic nanofiltration
US12296301B2 (en) 2020-12-22 2025-05-13 Evonik Oxeno Gmbh & Co. Kg Variable, self-regulating permeate recycling in organophilic nanofiltration
EP4091712B1 (de) 2021-05-18 2024-05-15 Evonik Oxeno GmbH & Co. KG Verfahren zur regenerierung eines katalysators für die hydroformylierung von olefinen in der gasphase
EP4223737A1 (de) * 2022-02-08 2023-08-09 Evonik Operations GmbH Optimierte thermische trennung durch vorherigen gasaustausch
EP4234525B1 (de) 2022-02-25 2024-01-31 Evonik Operations GmbH Verfahren zur hydrierung von aldehyden in mindestens zwei hydrierstufen
EP4234528A1 (de) 2022-02-25 2023-08-30 Evonik Operations GmbH Verfahren zur hydrierung von c13-aldehyden in mindestens zwei hydrierstufen
EP4234527B1 (de) 2022-02-25 2024-01-31 Evonik Operations GmbH Verfahren zur hydrierung von c9-aldehyden in mindestens zwei hydrierstufen
JP2025523917A (ja) 2022-07-19 2025-07-25 エボニック オクセノ ゲーエムベーハー ウント コー. カーゲー 気相における短鎖オレフィンのヒドロホルミル化プロセス
US20260027559A1 (en) 2022-07-19 2026-01-29 Evonik Oxeno Gmbh & Co. Kg Process for preparing, by hydroformylation, short-chain olefins in the gas phase
EP4389731B1 (de) 2022-12-19 2025-02-12 Evonik Oxeno GmbH & Co. KG Verfahren zur aktivitätserhaltung bei der abstellung der hydroformylierung
EP4574804A1 (de) 2023-12-18 2025-06-25 Evonik Oxeno GmbH & Co. KG Verfahren zur umsetzung von dibuten mit vorheriger destillation
EP4574806A1 (de) 2023-12-18 2025-06-25 Evonik Oxeno GmbH & Co. KG Verfahren zur zweistufigen umsetzung von olefinen mit zwischengeschalteter destillation
EP4574805A1 (de) 2023-12-18 2025-06-25 Evonik Oxeno GmbH & Co. KG Verfahren zur umsetzung von olefinen mit vorheriger auftrennung des feedstroms
EP4574803A1 (de) 2023-12-18 2025-06-25 Evonik Oxeno GmbH & Co. KG Verfahren zur umsetzung von c11- bis c20-olefinen mit vorheriger destillation
EP4574802A1 (de) 2023-12-18 2025-06-25 Evonik Oxeno GmbH & Co. KG Verfahren zur umsetzung von olefinen mit vorheriger destillation
CN118477690B (zh) * 2024-05-07 2026-04-17 中国科学院兰州化学物理研究所 一种聚离子液体锚定活性金属Co单位点非均相催化剂的制备及应用

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CN111004097B (zh) 2023-09-26
JP7505870B2 (ja) 2024-06-25
JP2020059701A (ja) 2020-04-16
KR102946654B1 (ko) 2026-03-31
TW202024010A (zh) 2020-07-01
EP3632885A1 (de) 2020-04-08
SG10201909162YA (en) 2020-05-28
MY198398A (en) 2023-08-28
US10654784B2 (en) 2020-05-19
US20200109101A1 (en) 2020-04-09
KR20200039572A (ko) 2020-04-16
CN111004097A (zh) 2020-04-14

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