TWI819111B - 短鏈烴在氣相中氫甲醯化的方法 - Google Patents
短鏈烴在氣相中氫甲醯化的方法 Download PDFInfo
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- TWI819111B TWI819111B TW108135852A TW108135852A TWI819111B TW I819111 B TWI819111 B TW I819111B TW 108135852 A TW108135852 A TW 108135852A TW 108135852 A TW108135852 A TW 108135852A TW I819111 B TWI819111 B TW I819111B
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/22—Carbides
- B01J27/224—Silicon carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/86—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/22—Carbides
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18198785.0 | 2018-10-05 | ||
| EP18198785 | 2018-10-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW202024010A TW202024010A (zh) | 2020-07-01 |
| TWI819111B true TWI819111B (zh) | 2023-10-21 |
Family
ID=63896046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108135852A TWI819111B (zh) | 2018-10-05 | 2019-10-03 | 短鏈烴在氣相中氫甲醯化的方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10654784B2 (de) |
| EP (1) | EP3632885A1 (de) |
| JP (1) | JP7505870B2 (de) |
| KR (1) | KR102946654B1 (de) |
| CN (1) | CN111004097B (de) |
| MY (1) | MY198398A (de) |
| SG (1) | SG10201909162YA (de) |
| TW (1) | TWI819111B (de) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10647650B2 (en) * | 2018-10-05 | 2020-05-12 | Evonik Operations Gmbh | Process for hydroformylating short-chain olefins using a heterogenized catalyst system without ionic liquid |
| WO2020070052A1 (de) | 2018-10-05 | 2020-04-09 | Evonik Operations Gmbh | Verfahren zur hydroformylierung von kurzkettigen olefinen in der gasphase |
| US11365171B2 (en) | 2019-06-12 | 2022-06-21 | Evonik Operations Gmbh | Process for preparing an ester by alkoxycarbonylation |
| US12064755B2 (en) | 2019-06-12 | 2024-08-20 | Evonik Oxeno Gmbh & Co. Kg | Process for separating one or more components from a mixture |
| US11440863B2 (en) | 2019-06-12 | 2022-09-13 | Evonik Operations Gmbh | Process for preparing an alcohol from hydrocarbons |
| US11008275B2 (en) | 2019-06-12 | 2021-05-18 | Evonik Operations Gmbh | Process for preparing carboxylic acids or salts thereof from hydrocarbons |
| EP3945085B1 (de) | 2020-07-30 | 2024-01-03 | Evonik Oxeno GmbH & Co. KG | Verfahren zur herstellung von aldehyden und abtrennung des katalysatorsystems mittels membrantrennung |
| US11806669B2 (en) | 2020-12-22 | 2023-11-07 | Evonik Operations Gmbh | Variable and self-regulating permeate recycling in organophilic nanofiltration |
| US12296301B2 (en) | 2020-12-22 | 2025-05-13 | Evonik Oxeno Gmbh & Co. Kg | Variable, self-regulating permeate recycling in organophilic nanofiltration |
| EP4091712B1 (de) | 2021-05-18 | 2024-05-15 | Evonik Oxeno GmbH & Co. KG | Verfahren zur regenerierung eines katalysators für die hydroformylierung von olefinen in der gasphase |
| EP4223737A1 (de) * | 2022-02-08 | 2023-08-09 | Evonik Operations GmbH | Optimierte thermische trennung durch vorherigen gasaustausch |
| EP4234525B1 (de) | 2022-02-25 | 2024-01-31 | Evonik Operations GmbH | Verfahren zur hydrierung von aldehyden in mindestens zwei hydrierstufen |
| EP4234528A1 (de) | 2022-02-25 | 2023-08-30 | Evonik Operations GmbH | Verfahren zur hydrierung von c13-aldehyden in mindestens zwei hydrierstufen |
| EP4234527B1 (de) | 2022-02-25 | 2024-01-31 | Evonik Operations GmbH | Verfahren zur hydrierung von c9-aldehyden in mindestens zwei hydrierstufen |
| JP2025523917A (ja) | 2022-07-19 | 2025-07-25 | エボニック オクセノ ゲーエムベーハー ウント コー. カーゲー | 気相における短鎖オレフィンのヒドロホルミル化プロセス |
| US20260027559A1 (en) | 2022-07-19 | 2026-01-29 | Evonik Oxeno Gmbh & Co. Kg | Process for preparing, by hydroformylation, short-chain olefins in the gas phase |
| EP4389731B1 (de) | 2022-12-19 | 2025-02-12 | Evonik Oxeno GmbH & Co. KG | Verfahren zur aktivitätserhaltung bei der abstellung der hydroformylierung |
| EP4574804A1 (de) | 2023-12-18 | 2025-06-25 | Evonik Oxeno GmbH & Co. KG | Verfahren zur umsetzung von dibuten mit vorheriger destillation |
| EP4574806A1 (de) | 2023-12-18 | 2025-06-25 | Evonik Oxeno GmbH & Co. KG | Verfahren zur zweistufigen umsetzung von olefinen mit zwischengeschalteter destillation |
| EP4574805A1 (de) | 2023-12-18 | 2025-06-25 | Evonik Oxeno GmbH & Co. KG | Verfahren zur umsetzung von olefinen mit vorheriger auftrennung des feedstroms |
| EP4574803A1 (de) | 2023-12-18 | 2025-06-25 | Evonik Oxeno GmbH & Co. KG | Verfahren zur umsetzung von c11- bis c20-olefinen mit vorheriger destillation |
| EP4574802A1 (de) | 2023-12-18 | 2025-06-25 | Evonik Oxeno GmbH & Co. KG | Verfahren zur umsetzung von olefinen mit vorheriger destillation |
| CN118477690B (zh) * | 2024-05-07 | 2026-04-17 | 中国科学院兰州化学物理研究所 | 一种聚离子液体锚定活性金属Co单位点非均相催化剂的制备及应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200719947A (en) * | 2005-09-27 | 2007-06-01 | Oxeno Olefinchemie Gmbh | Process for separating off organic transition metal complex catalysts |
| TW201237022A (en) * | 2011-03-04 | 2012-09-16 | Univ Kansas | Single solvent gas expended hydroformylation process |
| CN107266298A (zh) * | 2009-10-16 | 2017-10-20 | 陶氏技术投资有限责任公司 | 气相加氢甲酰化方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4012450A (en) * | 1969-10-01 | 1977-03-15 | Johnson Matthey & Co., Limited | Catalytic reactions |
| US20030036477A1 (en) | 2001-04-20 | 2003-02-20 | Nordquist Andrew Francis | Coated monolith substrate and monolith catalysts |
| DE102010041821A1 (de) | 2010-09-30 | 2012-04-05 | Evonik Oxeno Gmbh | Einsatz von Supported Ionic Liquid Phase (SILP) Katalysatorsystemen in der Hydroformylierung von olefinhaltigen Gemischen zu Aldehydgemischen mit hohem Anteil von in 2-Stellung unverzweigten Aldehyden |
| DE102013217166A1 (de) | 2013-08-28 | 2015-03-05 | Evonik Industries Ag | Verfahren zur Hydroformylierung von ungesättigten Verbindungen durch SILP-Katalyse |
| DE102013217386A1 (de) | 2013-09-02 | 2015-03-05 | Evonik Industries Ag | Verfahren zur Herstellung von Acrylsäure |
| DE102014201756A1 (de) | 2014-01-31 | 2015-08-06 | Evonik Degussa Gmbh | Reinigung chlorverschmutzter Organophosphorverbindungen |
| EP3059005B1 (de) | 2015-02-18 | 2018-10-24 | Evonik Degussa GmbH | Abtrennung eines homogenkatalysators aus einem reaktionsgemisch mit hilfe organophiler nanofiltration unter besonderer berücksichtigung eines membran-leistungsindikators |
| SG10201601501QA (en) | 2015-03-05 | 2016-10-28 | Evonik Degussa Gmbh | Preparation of 2,2`-biaryls in the presence of molybdenum(v) chloride |
| ES2765635T3 (es) | 2016-05-19 | 2020-06-10 | Evonik Operations Gmbh | Producción de n-pentanal a partir de mezclas de sustancias de empleo pobres en buteno |
| US10245578B2 (en) | 2016-11-09 | 2019-04-02 | Evonik Degussa Gmbh | Chromium- and nickel-free hydrogenation of hydroformylation mixtures |
| ZA201808003B (en) | 2017-12-01 | 2019-08-28 | Evonik Degussa Gmbh | Method for obtaining alcohols from aldehydes ii |
| ZA201808002B (en) | 2017-12-01 | 2019-08-28 | Evonik Degussa Gmbh | Method for obtaining alcohols from aldehydes |
| TWI784094B (zh) | 2017-12-01 | 2022-11-21 | 德商贏創運營有限公司 | 自醛獲得醇之方法iii |
| US10647650B2 (en) | 2018-10-05 | 2020-05-12 | Evonik Operations Gmbh | Process for hydroformylating short-chain olefins using a heterogenized catalyst system without ionic liquid |
-
2019
- 2019-09-18 US US16/574,217 patent/US10654784B2/en active Active
- 2019-09-30 EP EP19200442.2A patent/EP3632885A1/de active Pending
- 2019-10-01 KR KR1020190121325A patent/KR102946654B1/ko active Active
- 2019-10-01 SG SG10201909162YA patent/SG10201909162YA/en unknown
- 2019-10-02 MY MYPI2019005802A patent/MY198398A/en unknown
- 2019-10-02 JP JP2019181966A patent/JP7505870B2/ja active Active
- 2019-10-03 TW TW108135852A patent/TWI819111B/zh active
- 2019-10-08 CN CN201910949130.2A patent/CN111004097B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200719947A (en) * | 2005-09-27 | 2007-06-01 | Oxeno Olefinchemie Gmbh | Process for separating off organic transition metal complex catalysts |
| CN107266298A (zh) * | 2009-10-16 | 2017-10-20 | 陶氏技术投资有限责任公司 | 气相加氢甲酰化方法 |
| TW201237022A (en) * | 2011-03-04 | 2012-09-16 | Univ Kansas | Single solvent gas expended hydroformylation process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111004097B (zh) | 2023-09-26 |
| JP7505870B2 (ja) | 2024-06-25 |
| JP2020059701A (ja) | 2020-04-16 |
| KR102946654B1 (ko) | 2026-03-31 |
| TW202024010A (zh) | 2020-07-01 |
| EP3632885A1 (de) | 2020-04-08 |
| SG10201909162YA (en) | 2020-05-28 |
| MY198398A (en) | 2023-08-28 |
| US10654784B2 (en) | 2020-05-19 |
| US20200109101A1 (en) | 2020-04-09 |
| KR20200039572A (ko) | 2020-04-16 |
| CN111004097A (zh) | 2020-04-14 |
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