UA107331C2 - Способ получения нитрильных соединений из этиленненасищеных соединений - Google Patents

Способ получения нитрильных соединений из этиленненасищеных соединений

Info

Publication number
UA107331C2
UA107331C2 UAA201100527A UAA201100527A UA107331C2 UA 107331 C2 UA107331 C2 UA 107331C2 UA A201100527 A UAA201100527 A UA A201100527A UA A201100527 A UAA201100527 A UA A201100527A UA 107331 C2 UA107331 C2 UA 107331C2
Authority
UA
Ukraine
Prior art keywords
ethylenically unsaturated
organic compounds
unsaturated organic
present
nitrile compound
Prior art date
Application number
UAA201100527A
Other languages
English (en)
Ukrainian (uk)
Inventor
Серджіо Мастроянні
Original Assignee
Інвіста Текнолоджіз С.А Р.Л.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Інвіста Текнолоджіз С.А Р.Л. filed Critical Інвіста Текнолоджіз С.А Р.Л.
Publication of UA107331C2 publication Critical patent/UA107331C2/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Данное изобретение относится к способу гидроцианирования этиленненасищеных органических соединений для получения соединений, содержащих, по крайней мере, одну нитрильную функциональную группу. Согласно изобретению предложен способ гидроцианирования углеводородного соединения, содержащего, по крайней мере, одну этиленненасищенную связь путем реакции в жидкой среде с цианистоводородной кислотой в присутствии катализатора, содержащего металлический элемент, выбранный из переходных металлов, и фосфорорганический лиганд, причем фосфорорганический лиганд состоит из смеси, по крайней мере, одного монодентатного органофосфитного соединения и по крайней мере одного органофосфиного соединения. Данное изобретение относится, в частности, синтеза адипонитрила из бутадиена.
UAA201100527A 2008-06-17 2009-06-05 Способ получения нитрильных соединений из этиленненасищеных соединений UA107331C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0803374A FR2932477B1 (fr) 2008-06-17 2008-06-17 Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
PCT/EP2009/056916 WO2009153171A1 (fr) 2008-06-17 2009-06-05 Procédé de fabrication de composés nitriles a partir de composés a insaturation éthylénique

Publications (1)

Publication Number Publication Date
UA107331C2 true UA107331C2 (ru) 2014-12-25

Family

ID=40377709

Family Applications (1)

Application Number Title Priority Date Filing Date
UAA201100527A UA107331C2 (ru) 2008-06-17 2009-06-05 Способ получения нитрильных соединений из этиленненасищеных соединений

Country Status (11)

Country Link
US (1) US9233917B2 (ru)
EP (1) EP2310358B1 (ru)
JP (1) JP2011524394A (ru)
KR (1) KR101308187B1 (ru)
CN (1) CN102089275B (ru)
FR (1) FR2932477B1 (ru)
RU (1) RU2509075C2 (ru)
SG (1) SG191670A1 (ru)
TW (1) TW201004908A (ru)
UA (1) UA107331C2 (ru)
WO (1) WO2009153171A1 (ru)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2926816B1 (fr) * 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2932477B1 (fr) 2008-06-17 2013-01-18 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2937321B1 (fr) 2008-10-21 2010-10-22 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
CN103694136B (zh) * 2014-01-06 2015-11-18 重庆中平紫光科技发展有限公司 丁二烯一步法合成己二腈的方法
CN106999920B (zh) * 2014-11-20 2021-11-02 英威达纺织（英国）有限公司 具有高配体络合活性的镍和制造其的方法
EP3176151A1 (en) * 2015-12-01 2017-06-07 Studiengesellschaft Kohle mbH Process for the catalytic reversible alkene-nitrile interconversion
CN112844474B (zh) * 2020-12-24 2023-04-14 广东新华粤石化集团股份公司 一种用于高碳烯烃氢甲酰化的有机聚合物催化剂及应用
CN113912516B (zh) 2021-10-15 2023-06-27 浙江新和成股份有限公司 一种多齿亚磷酸酯配体在催化合成己二腈中的应用
CN113956180B (zh) * 2021-11-08 2024-04-09 中国天辰工程有限公司 一种己二腈的合成方法

Family Cites Families (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3496215A (en) 1965-11-23 1970-02-17 Du Pont Hydrocyanation of olefins using selected nickel phosphite catalysts
GB1112539A (en) 1965-11-26 1968-05-08 Du Pont Preparation of organic nitriles
FR1529134A (fr) 1966-06-24 1968-06-14 Du Pont Procédé d'addition de l'acide cyanhydrique aux oléfines et produits obtenus par ce procédé
US3496217A (en) 1967-05-23 1970-02-17 Du Pont Hydrocyanation of olefins
FR1599764A (ru) 1967-09-12 1970-07-20
NL6815746A (ru) * 1967-11-06 1969-05-08
US3579560A (en) * 1967-11-06 1971-05-18 Du Pont Isomerization of nitriles
US3694485A (en) * 1967-11-06 1972-09-26 Du Pont Hydrocyanation of olefins
US3655723A (en) * 1969-10-31 1972-04-11 Du Pont Hydrocyanation of olefins
BE757731A (fr) 1969-11-13 1971-04-01 Du Pont Procede de cyanuration des olefines
US3631191A (en) 1970-04-08 1971-12-28 Du Pont Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes
US3766231A (en) 1971-08-02 1973-10-16 Du Pont Compounds of zero valent nickel containing n bonded nitriles
US3766237A (en) * 1972-01-25 1973-10-16 Du Pont Hydrocyanation of olefins
US3773809A (en) 1972-06-28 1973-11-20 Du Pont Separation of organic phosphorus compounds and their metal complexes from organic nitriles in the hydrocyanation of olefins
US3864380A (en) 1974-01-17 1975-02-04 Du Pont Hydrocyanation of Olefins
US4082811A (en) 1977-02-23 1978-04-04 E. I. Du Pont De Nemours And Company Recovery of metal and triarylborane catalyst components from olefin hydrocyanation residue
US4339395A (en) 1981-04-15 1982-07-13 E. I. Du Pont De Nemours And Company Treatment of olefin hydrocyanation products
US4416825A (en) 1982-02-23 1983-11-22 E. I. Du Pont De Nemours & Co. Preparation of zerovalent nickel complexes
US4774353A (en) 1986-06-05 1988-09-27 E. I. Du Pont De Nemours And Company Triorganotin catalyst promoters for hydrocyanation
US4874884A (en) 1988-03-31 1989-10-17 E. I. Du Pont De Nemours And Company Promoter synergism in pentenenitrile hydrocyanation
CA1324613C (en) 1988-03-31 1993-11-23 Ronald J. Mckinney Promoter synergism in pentenenitrile hydrocyanation
FR2710909B1 (fr) * 1993-10-08 1995-12-15 Rhone Poulenc Chimie Procédé d'isomérisation du méthyl-2 butène-3 nitrile.
FR2711987B1 (fr) * 1993-11-03 1995-12-15 Rhone Poulenc Chimie Procédé d'hydrocyanation de nitriles insaturés en dinitriles.
US5512696A (en) 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
IN187044B (ru) 1995-01-27 2002-01-05 Du Pont
FR2739378B1 (fr) * 1995-09-29 1997-10-31 Rhone Poulenc Fibres Procede d'hydrocyanation de composes organiques a insaturation ethylenique
US5693843A (en) 1995-12-22 1997-12-02 E. I. Du Pont De Nemours And Company Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles
IT1286497B1 (it) * 1996-11-20 1998-07-15 Italfarmaco Sud Spa Difosfine di tipo misto eteroariliche-ariliche come leganti chirali, relativi complessi con metalli di transizione e impiego di detti
US5847191A (en) 1997-07-29 1998-12-08 E. I. Du Pont De Nemours And Company Process for the hydrocyanation of monoolefins using bidentate phosphite ligands and zero-valent nickel
US5959135A (en) 1997-07-29 1999-09-28 E. I. Du Pont De Nemours And Company Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions thereof
ZA986374B (en) 1997-07-29 2000-01-17 Du Pont Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.
MY124170A (en) 1997-07-29 2006-06-30 Invista Tech Sarl Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor
ZA986369B (en) 1997-07-29 2000-01-17 Du Pont Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.
ATE269158T1 (de) 1998-04-16 2004-07-15 Du Pont Hydrocyanierung von olefinen und isomerisierung von nichtkonjugierten 2-alkyl-3-monoalken- nitrilen
FR2778915B1 (fr) * 1998-05-20 2000-06-30 Rhone Poulenc Fibres Nouvelles furylphosphines et complexes organometalliques les comprenant
US6229052B1 (en) 1998-05-29 2001-05-08 E. I. Du Pont De Nemours And Company Hydroformylation of olefins using supported bis(phosphorus) ligands
DE19825212A1 (de) 1998-06-05 1999-12-09 Basf Ag Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen
AU4253799A (en) 1998-06-12 2000-01-05 Micrologix Biotech, Inc. Cancer therapy with cationic peptides
US6252121B1 (en) * 1999-07-27 2001-06-26 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US6048996A (en) 1999-08-26 2000-04-11 E. I. Du Pont De Nemours And Company Insoluble promoters for nickel-catalyzed hydrocyanation of monoolefins
DE19953058A1 (de) 1999-11-03 2001-05-10 Basf Ag Phosphite
DE10038037A1 (de) 2000-08-02 2002-04-18 Basf Ag Zur Herstellung von Nitrilen geeigneter Katalysator und Verfahren zur Herstellung von Nitrilen
FR2815344B1 (fr) 2000-10-13 2004-01-30 Rhodia Polyamide Intermediates Procede d'hydrocyanation de composes organiques a insaturation ethylenique
FR2819250B1 (fr) * 2001-01-05 2004-12-03 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
DE10100708A1 (de) 2001-01-10 2002-07-11 Oxeno Olefinchemie Gmbh Neue N-Phenylpyrrolbisphosphanverbindungen und deren Metallkomplexe
DE10136488A1 (de) 2001-07-27 2003-02-06 Basf Ag Ni(O) enthaltendes Katalysatorsystem
FR2830530B1 (fr) 2001-10-08 2004-07-02 Rhodia Polyamide Intermediates Procede de transformation, d'une part, de composes a insaturation ethylenique en nitriles et, d'autre part, de nitriles branches en nitriles lineaires
FR2835833B1 (fr) 2002-02-13 2004-03-19 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2842196B1 (fr) 2002-07-15 2006-01-13 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US6599398B1 (en) 2002-07-17 2003-07-29 E. I. Du Pont De Nemours And Company Recovery of adiponitrile from a mixture of adiponitrile, aminocapronitrile and hexamethylenediamine
FR2845379B1 (fr) 2002-10-04 2004-12-03 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2847898A1 (fr) 2002-12-02 2004-06-04 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2849027B1 (fr) 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
DE10314761A1 (de) 2003-03-31 2004-10-14 Basf Ag Als Katalysator für die Hydrocyanierung von olefinisch ungesättigten Verbindungen geeignetes System
FR2854892B1 (fr) * 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
DE102004052040A1 (de) 2004-10-26 2006-04-27 Basf Ag Liganden zur asymmetrischen Hydroformylierung
FR2926816B1 (fr) 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2932476B1 (fr) 2008-06-17 2010-07-30 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2932477B1 (fr) 2008-06-17 2013-01-18 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2941455B1 (fr) 2009-01-29 2011-02-11 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles

Also Published As

Publication number Publication date
KR20110009248A (ko) 2011-01-27
US20110166376A1 (en) 2011-07-07
RU2011101416A (ru) 2012-07-27
SG191670A1 (en) 2013-07-31
RU2509075C2 (ru) 2014-03-10
TW201004908A (en) 2010-02-01
FR2932477A1 (fr) 2009-12-18
CN102089275B (zh) 2017-06-27
KR101308187B1 (ko) 2013-09-12
EP2310358A1 (fr) 2011-04-20
CN102089275A (zh) 2011-06-08
FR2932477B1 (fr) 2013-01-18
JP2011524394A (ja) 2011-09-01
WO2009153171A1 (fr) 2009-12-23
EP2310358B1 (fr) 2018-09-26
US9233917B2 (en) 2016-01-12

Similar Documents

Publication Publication Date Title
UA107331C2 (ru) Способ получения нитрильных соединений из этиленненасищеных соединений
AR032224A1 (es) Procedimiento de fabricacion de compuestos nitrilos a partir de compuestos de instauracion etilenica
RU2009105092A (ru) Способ получения 3-пентеннитрила путем гидроцианирования бутадиена
Bini et al. Mechanistic studies on hydrocyanation reactions
ATE400548T1 (de) Verfahren zur synthese von nitrilfunktionen enthaltenden verbindungen aus ethylenisch ungesättigtenverbindungen
WO2008008930A3 (en) Hydrocyanation process with reduced yield losses
SA07280379B1 (ar) عملية لمعالجة2-بنتين نيتريل بواسطة سيانيد الهيدروجين
UA101040C2 (ru) Способ получения нитрильных соединений из этиленненасыщенных соединений
TW201129537A (en) Controlling the normal: iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure
WO2007010453A3 (en) Transition metal compounds having a cyclic phosphorus-containing ligand and a cyclic organic ligand for use in metathesis reactions
MY154793A (en) Reactor for preparing hydrogen cyanide by the andrussow process
WO2008008928A3 (en) Process for making 3-pentenenitrile by hydrocyanation of butadiene
MY140569A (en) Extraction of nickel(0) complexes from nitrile mixtures with reduced power formation
AR030990A1 (es) Un procedimiento de hidrocianacion de compuestos organicos de insaturacion etilenica
UA104414C2 (ru) Способ получения соединений, содержащих нитрильные функциональные группы
UA108195C2 (ru) Способ получения соединений, содержащих нитрильные функциональные группы
TW200500329A (en) Hydrocyanation of an olefinically unsaturated compound
TW200505573A (en) Process for the hydrocyanation of unsaturated compounds
Gong et al. Tributylphosphine-catalyzed Stetter reaction of N, N-dimethylacrylamide: synthesis of N, N-dimethyl-3-aroylpropionamides
Laval et al. Reduction of nitriles into aldehydes using a TMDS/V (O)(OiPr) 3 reducing system
UA107333C2 (ru) Способ получения соединений, содержащих нитрильные функциональные группы
ATE410409T1 (de) Verfahren zur herstellung von gesättigten nitrilen
IN2014CN02266A (ru)
UA109410C2 (ru) Способ получения нитрильных соединений из этиленненасыщенных соединений
CN105130845B (zh) 丁二烯法合成己二腈中抑制零价镍降解的方法