UA75919C2 - Multimetallic reforming catalyst and the process for preparation thereof - Google Patents

Multimetallic reforming catalyst and the process for preparation thereof Download PDF

Info

Publication number: UA75919C2
Authority: UA; Ukraine
Prior art keywords: catalyst; metal; carrier; cerium; oxide
Prior art date: 2001-04-28

Application number

UA20031110764A

Other languages

English (en)

Ukrainian (uk)

Original Assignee

China Petroleum & Chemical

Res Inst Petroleum Processing

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-04-28

Filing date

2002-04-24

Publication date

2006-06-15

2002-04-24 Application filed by China Petroleum & Chemical, Res Inst Petroleum Processing filed Critical China Petroleum & Chemical

2006-06-15 Publication of UA75919C2 publication Critical patent/UA75919C2/uk

Links

239000003054 catalyst Substances 0.000 title abstract description 137
238000000034 method Methods 0.000 title abstract description 36
238000002407 reforming Methods 0.000 title abstract description 10
230000008569 process Effects 0.000 title abstract description 9
238000002360 preparation method Methods 0.000 title abstract description 5
229910052751 metal Inorganic materials 0.000 abstract description 50
239000002184 metal Substances 0.000 abstract description 50
230000000694 effects Effects 0.000 abstract description 15
229910052799 carbon Inorganic materials 0.000 abstract description 12
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 11
230000008021 deposition Effects 0.000 abstract description 11
229910052736 halogen Inorganic materials 0.000 abstract description 11
150000002367 halogens Chemical class 0.000 abstract description 11
229910052809 inorganic oxide Inorganic materials 0.000 abstract description 6
239000000203 mixture Substances 0.000 description 26
239000000243 solution Substances 0.000 description 25
230000000052 comparative effect Effects 0.000 description 21
150000001875 compounds Chemical class 0.000 description 20
229910052684 Cerium Inorganic materials 0.000 description 19
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical group [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 19
238000005470 impregnation Methods 0.000 description 18
229910052693 Europium Chemical group 0.000 description 17
OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical group [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 16
150000001491 aromatic compounds Chemical class 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
150000002739 metals Chemical class 0.000 description 12
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 12
239000002253 acid Substances 0.000 description 11
-1 acyclic hydrocarbons Chemical class 0.000 description 11
229910052739 hydrogen Inorganic materials 0.000 description 11
229910052747 lanthanoid Inorganic materials 0.000 description 11
239000007787 solid Substances 0.000 description 11
HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 10
239000001257 hydrogen Substances 0.000 description 10
150000002602 lanthanoids Chemical class 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
239000002994 raw material Substances 0.000 description 8
239000000126 substance Substances 0.000 description 8
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
239000003502 gasoline Substances 0.000 description 7
229930195733 hydrocarbon Natural products 0.000 description 7
239000003921 oil Substances 0.000 description 7
238000011084 recovery Methods 0.000 description 7
238000011156 evaluation Methods 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
229910052697 platinum Inorganic materials 0.000 description 6
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
229910052782 aluminium Inorganic materials 0.000 description 5
239000012298 atmosphere Substances 0.000 description 5
238000009835 boiling Methods 0.000 description 5
230000003197 catalytic effect Effects 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
238000006477 desulfuration reaction Methods 0.000 description 5
230000023556 desulfurization Effects 0.000 description 5
238000001035 drying Methods 0.000 description 5
239000003607 modifier Substances 0.000 description 5
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
239000004215 Carbon black (E152) Substances 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
229910002651 NO3 Inorganic materials 0.000 description 4
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
238000006356 dehydrogenation reaction Methods 0.000 description 4
239000007789 gas Substances 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000000463 material Substances 0.000 description 4
230000008018 melting Effects 0.000 description 4
238000002844 melting Methods 0.000 description 4
239000011734 sodium Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000001833 catalytic reforming Methods 0.000 description 3
150000001805 chlorine compounds Chemical class 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
238000000975 co-precipitation Methods 0.000 description 3
238000005336 cracking Methods 0.000 description 3
238000004821 distillation Methods 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
238000005984 hydrogenation reaction Methods 0.000 description 3
238000006317 isomerization reaction Methods 0.000 description 3
238000002386 leaching Methods 0.000 description 3
239000012263 liquid product Substances 0.000 description 3
239000011148 porous material Substances 0.000 description 3
230000009467 reduction Effects 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
239000003463 adsorbent Substances 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
239000010953 base metal Substances 0.000 description 2
238000001354 calcination Methods 0.000 description 2
238000004364 calculation method Methods 0.000 description 2
239000000969 carrier Substances 0.000 description 2
238000004517 catalytic hydrocracking Methods 0.000 description 2
VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 2
230000008859 change Effects 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
238000009826 distribution Methods 0.000 description 2
GAGGCOKRLXYWIV-UHFFFAOYSA-N europium(3+);trinitrate Chemical compound [Eu+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GAGGCOKRLXYWIV-UHFFFAOYSA-N 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
239000011888 foil Substances 0.000 description 2
YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
150000002601 lanthanoid compounds Chemical class 0.000 description 2
MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
NGXWSRYOFVTCCT-UHFFFAOYSA-L lead(2+);dichlorate Chemical compound [Pb+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O NGXWSRYOFVTCCT-UHFFFAOYSA-L 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
239000011259 mixed solution Substances 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
229910000510 noble metal Inorganic materials 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
229910052703 rhodium Inorganic materials 0.000 description 2
239000010948 rhodium Substances 0.000 description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
239000001119 stannous chloride Substances 0.000 description 2
235000011150 stannous chloride Nutrition 0.000 description 2
IEXRMSFAVATTJX-UHFFFAOYSA-N tetrachlorogermane Chemical class Cl[Ge](Cl)(Cl)Cl IEXRMSFAVATTJX-UHFFFAOYSA-N 0.000 description 2
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 2
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
241000167854 Bourreria succulenta Species 0.000 description 1
244000201986 Cassia tora Species 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
101150105088 Dele1 gene Proteins 0.000 description 1
240000002989 Euphorbia neriifolia Species 0.000 description 1
229910021639 Iridium tetrachloride Inorganic materials 0.000 description 1
241000343235 Maso Species 0.000 description 1
229910052779 Neodymium Inorganic materials 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
WEOYIFRDQDXVKP-UHFFFAOYSA-M O=[Si]=O.[O-2].[OH-].[Ce+3] Chemical compound O=[Si]=O.[O-2].[OH-].[Ce+3] WEOYIFRDQDXVKP-UHFFFAOYSA-M 0.000 description 1
229910000805 Pig iron Inorganic materials 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
229910021604 Rhodium(III) chloride Inorganic materials 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
244000062793 Sorghum vulgare Species 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
239000005864 Sulphur Substances 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
PETQRGMIPYIOSC-UHFFFAOYSA-N [H][Br][Pt] Chemical compound [H][Br][Pt] PETQRGMIPYIOSC-UHFFFAOYSA-N 0.000 description 1
FCUFAHVIZMPWGD-UHFFFAOYSA-N [O-][N+](=O)[Pt](N)(N)[N+]([O-])=O Chemical compound [O-][N+](=O)[Pt](N)(N)[N+]([O-])=O FCUFAHVIZMPWGD-UHFFFAOYSA-N 0.000 description 1
235000011054 acetic acid Nutrition 0.000 description 1
150000001243 acetic acids Chemical class 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000009471 action Effects 0.000 description 1
230000000274 adsorptive effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
150000004645 aluminates Chemical class 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
VIJYFGMFEVJQHU-UHFFFAOYSA-N aluminum oxosilicon(2+) oxygen(2-) Chemical compound [O-2].[Al+3].[Si+2]=O VIJYFGMFEVJQHU-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
229950005499 carbon tetrachloride Drugs 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
239000004359 castor oil Substances 0.000 description 1
235000019438 castor oil Nutrition 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
229910000420 cerium oxide Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
235000019693 cherries Nutrition 0.000 description 1
229910000423 chromium oxide Inorganic materials 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
239000003245 coal Substances 0.000 description 1
238000004939 coking Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
230000020335 dealkylation Effects 0.000 description 1
238000006900 dealkylation reaction Methods 0.000 description 1
QBWXYICYWNSGPT-UHFFFAOYSA-L dichlorotin pentahydrate Chemical compound O.O.O.O.O.Cl[Sn]Cl QBWXYICYWNSGPT-UHFFFAOYSA-L 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
CTCOPPBXAFHGRB-UHFFFAOYSA-N ethanolate;germanium(4+) Chemical compound [Ge+4].CC[O-].CC[O-].CC[O-].CC[O-] CTCOPPBXAFHGRB-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
BJENZJLZGVHMTK-UHFFFAOYSA-N europium hydrochloride Chemical compound Cl.[Eu] BJENZJLZGVHMTK-UHFFFAOYSA-N 0.000 description 1
229910001940 europium oxide Inorganic materials 0.000 description 1
AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 description 1
NNMXSTWQJRPBJZ-UHFFFAOYSA-K europium(iii) chloride Chemical compound Cl[Eu](Cl)Cl NNMXSTWQJRPBJZ-UHFFFAOYSA-K 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
210000003608 fece Anatomy 0.000 description 1
238000011049 filling Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
235000011389 fruit/vegetable juice Nutrition 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
238000001879 gelation Methods 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
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ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
UUBJKHVFGWGJKX-UHFFFAOYSA-N hydrate tetrahydrochloride Chemical compound O.Cl.Cl.Cl.Cl UUBJKHVFGWGJKX-UHFFFAOYSA-N 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
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238000007327 hydrogenolysis reaction Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
230000006872 improvement Effects 0.000 description 1
OZDHQOIPFFBDPL-UHFFFAOYSA-N iridium hydrochloride Chemical compound Cl.[Ir] OZDHQOIPFFBDPL-UHFFFAOYSA-N 0.000 description 1
HTFVQFACYFEXPR-UHFFFAOYSA-K iridium(3+);tribromide Chemical compound Br[Ir](Br)Br HTFVQFACYFEXPR-UHFFFAOYSA-K 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 1
229940046892 lead acetate Drugs 0.000 description 1
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238000011068 loading method Methods 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910052987 metal hydride Inorganic materials 0.000 description 1
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150000004706 metal oxides Chemical class 0.000 description 1
235000019713 millet Nutrition 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
238000006396 nitration reaction Methods 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
125000006353 oxyethylene group Chemical group 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
HIJDQYZZPATXAO-UHFFFAOYSA-N palladium hydrochloride Chemical compound Cl.[Pd] HIJDQYZZPATXAO-UHFFFAOYSA-N 0.000 description 1
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
YTXAYGAYACWVGD-UHFFFAOYSA-N palladium;hydrate Chemical compound O.[Pd] YTXAYGAYACWVGD-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
238000005325 percolation Methods 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
NCAIGTHBQTXTLR-UHFFFAOYSA-N phentermine hydrochloride Chemical compound [Cl-].CC(C)([NH3+])CC1=CC=CC=C1 NCAIGTHBQTXTLR-UHFFFAOYSA-N 0.000 description 1
CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000006057 reforming reaction Methods 0.000 description 1
239000003870 refractory metal Substances 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000004044 response Effects 0.000 description 1
SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 1
238000007363 ring formation reaction Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229910052711 selenium Inorganic materials 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
239000010802 sludge Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
230000001629 suppression Effects 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000010408 sweeping Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
CALMYRPSSNRCFD-UHFFFAOYSA-J tetrachloroiridium Chemical compound Cl[Ir](Cl)(Cl)Cl CALMYRPSSNRCFD-UHFFFAOYSA-J 0.000 description 1
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
229910003452 thorium oxide Inorganic materials 0.000 description 1
LTSUHJWLSNQKIP-UHFFFAOYSA-J tin(iv) bromide Chemical compound Br[Sn](Br)(Br)Br LTSUHJWLSNQKIP-UHFFFAOYSA-J 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical compound Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 description 1
CTDPVEAZJVZJKG-UHFFFAOYSA-K trichloroplatinum Chemical compound Cl[Pt](Cl)Cl CTDPVEAZJVZJKG-UHFFFAOYSA-K 0.000 description 1
UAEJRRZPRZCUBE-UHFFFAOYSA-N trimethoxyalumane Chemical compound [Al+3].[O-]C.[O-]C.[O-]C UAEJRRZPRZCUBE-UHFFFAOYSA-N 0.000 description 1
210000000623 ulna Anatomy 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
239000002699 waste material Substances 0.000 description 1
238000004846 x-ray emission Methods 0.000 description 1
229910001845 yogo sapphire Inorganic materials 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
- B01J27/13—Platinum group metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/135—Halogens; Compounds thereof with titanium, zirconium, hafnium, germanium, tin or lead
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Catalysts (AREA)

UA20031110764A 2001-04-28 2002-04-24 Multimetallic reforming catalyst and the process for preparation thereof UA75919C2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CN01115617A CN1384175A (zh)	2001-04-28	2001-04-28	含铂、锡的多金属重整催化剂及其制备与应用
PCT/CN2002/000289 WO2002087757A1 (fr)	2001-04-28	2002-04-24	Catalyseur de reformage multimetal contenant du platine et de l'etain, sa preparation et son utilisation

Publications (1)

Publication Number	Publication Date
UA75919C2 true UA75919C2 (en)	2006-06-15

Family

ID=4662106

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
UA20031110764A UA75919C2 (en)	2001-04-28	2002-04-24	Multimetallic reforming catalyst and the process for preparation thereof

Country Status (9)

Country	Link
US (1)	US6780814B2 (fr)
EP (1)	EP1390140B1 (fr)
JP (1)	JP4170768B2 (fr)
KR (1)	KR100572922B1 (fr)
CN (2)	CN1384175A (fr)
CA (1)	CA2445321C (fr)
RU (1)	RU2259233C2 (fr)
UA (1)	UA75919C2 (fr)
WO (1)	WO2002087757A1 (fr)

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EP2210929B1 (fr) *	2007-10-31	2016-11-23	China Petroleum & Chemical Corporation	Processus de pre-passivation d'un appareil de reformage en continu
US8309780B2 (en) *	2007-12-21	2012-11-13	Exxonmobil Research And Engineering Company	Process for making olefin oligomers and alkyl benzenes in the presence of mixed metal oxide catalysts
CN101468313B (zh) *	2007-12-28	2014-08-20	中国石油化工股份有限公司	一种重整催化剂的制备方法
FR2947465B1 (fr) *	2009-07-01	2012-05-11	Inst Francais Du Petrole	Catalyseur multi-metallique presentant une proximite de sites optimisee
CN102049267B (zh) *	2009-10-29	2013-01-30	中国石油化工股份有限公司	一种丙烷脱氢制丙烯的催化剂及制备与应用
US8758599B2 (en)	2011-07-15	2014-06-24	Uop Llc	Reforming catalyst and process
US8912110B2 (en) *	2012-03-29	2014-12-16	Uop Llc	Catalyst for conversion of hydrocarbons
CN103372454B (zh) *	2012-04-27	2016-01-13	中国石油化工股份有限公司	一种多金属重整催化剂及其制备与应用
CN103962135B (zh) *	2013-01-30	2017-04-12	中国石油天然气股份有限公司	一种多金属连续重整催化剂及其制备方法
CN103962161B (zh) *	2013-01-30	2016-11-23	中国石油天然气股份有限公司	一种连续重整催化剂及其制备方法
CN104148066B (zh) *	2013-05-15	2016-08-24	中国石油化工股份有限公司	一种多金属重整催化剂及其制备与应用
CN104275198B (zh) *	2013-07-01	2016-04-27	中国石油化工股份有限公司	一种多金属重整催化剂的制备方法
CN104511292B (zh) *	2013-09-27	2017-04-05	中国石油天然气股份有限公司	一种连续重整催化剂及其制备方法
CN105771981A (zh) *	2014-12-24	2016-07-20	中国石油天然气股份有限公司	一种石脑油重整催化剂及其制备方法
FR3039082B1 (fr) *	2015-07-24	2017-07-21	Ifp Energies Now	Catalyseur multi-metallique dope par du phosphore et un lanthanide
CN107152356B (zh) *	2017-06-09	2023-05-26	李秋生	前置式u型机动车燃油催化器
CN109201051B (zh) *	2017-07-05	2021-08-06	中国石油化工股份有限公司	一种多金属连续重整催化剂的制备方法
FR3074062B1 (fr)	2017-11-30	2020-06-26	IFP Energies Nouvelles	Catalyseur multi-metallique dope par du phosphore et de l'yttrium
FR3074063B1 (fr)	2017-11-30	2019-11-01	IFP Energies Nouvelles	Catalyseur multi-metallique dope par du phosphore et de l'ytterbium
CN110064392B (zh) *	2018-01-23	2021-11-30	中国石油天然气股份有限公司	一种氧化态半再生重整催化剂及其制备方法
CN110064418B (zh) *	2018-01-23	2021-11-02	中国石油天然气股份有限公司	一种氧化态重整催化剂及其制备方法
CN110064421B (zh) *	2018-01-23	2021-11-30	中国石油天然气股份有限公司	一种重整催化剂及其制备方法
CN110064422B (zh) *	2018-01-23	2022-01-04	中国石油天然气股份有限公司	一种多金属连续重整催化剂及其制备方法
RU2767882C1 (ru) *	2021-04-29	2022-03-22	Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть")	Катализатор риформинга бензиновых фракций и способ его получения
CN115999540B (zh) *	2021-10-21	2025-02-11	中国石油化工股份有限公司	一种丙烷脱氢制丙烯催化剂及其制备方法
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CN116253814A (zh) *	2022-12-07	2023-06-13	宁波工程学院	一种碳五树脂的催化加氢方法

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2001
- 2001-04-28 CN CN01115617A patent/CN1384175A/zh active Pending
2002
- 2002-04-24 WO PCT/CN2002/000289 patent/WO2002087757A1/fr not_active Ceased
- 2002-04-24 RU RU2003134543/04A patent/RU2259233C2/ru active
- 2002-04-24 EP EP02766599.1A patent/EP1390140B1/fr not_active Expired - Lifetime
- 2002-04-24 CN CNB028090578A patent/CN1234455C/zh not_active Expired - Lifetime
- 2002-04-24 JP JP2002585091A patent/JP4170768B2/ja not_active Expired - Lifetime
- 2002-04-24 CA CA002445321A patent/CA2445321C/fr not_active Expired - Lifetime
- 2002-04-24 UA UA20031110764A patent/UA75919C2/uk unknown
- 2002-04-24 KR KR1020037014067A patent/KR100572922B1/ko not_active Expired - Lifetime
- 2002-04-26 US US10/132,910 patent/US6780814B2/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JP4170768B2 (ja)	2008-10-22
CN1535176A (zh)	2004-10-06
EP1390140B1 (fr)	2014-06-25
US20040011702A1 (en)	2004-01-22
US6780814B2 (en)	2004-08-24
RU2003134543A (ru)	2005-02-27
CN1234455C (zh)	2006-01-04
WO2002087757A1 (fr)	2002-11-07
RU2259233C2 (ru)	2005-08-27
JP2004527371A (ja)	2004-09-09
CA2445321C (fr)	2008-07-15
EP1390140A4 (fr)	2007-04-04
CA2445321A1 (fr)	2002-11-07
KR20040015180A (ko)	2004-02-18
EP1390140A1 (fr)	2004-02-25
KR100572922B1 (ko)	2006-04-24
CN1384175A (zh)	2002-12-11

Publication	Publication Date	Title
UA75919C2 (en)	2006-06-15	Multimetallic reforming catalyst and the process for preparation thereof
US4165276A (en)	1979-08-21	Hydrocarbon conversion with a superactive multimetallic catalytic composite
US5665223A (en)	1997-09-09	Selective bifunctional multimetallic reforming catalyst
RU2605406C2 (ru)	2016-12-20	Катализатор конверсии углеводородов
US6239063B1 (en)	2001-05-29	Selective bifunctional multimetallic reforming catalyst
CN103596681A (zh)	2014-02-19	重整催化剂和方法
CA2214550C (fr)	2006-11-14	Melange catalytique multimetallique, bifonctionnel et selectif pour la conversion d'hydrocarbures; methode pour l'utiliser
US4197188A (en)	1980-04-08	Hydrocarbon conversion with an attenuated superactive multimetallic catalytic composite
PL79529B1 (en)	1975-06-30	Hydrocarbon conversion catalyst and processes for the manufacture and use thereof[gb1256000a]
GB1560368A (en)	1980-02-06	Hydrocarbon refroming process
CN100338189C (zh)	2007-09-19	一种铂、锡系重整催化剂的制备方法
KR20060128039A (ko)	2006-12-13	배기가스 정화용 촉매와 배기가스의 정화 방법
JP6789282B2 (ja)	2020-11-25	リンとランタニドのドープ型多金属触媒
US4246095A (en)	1981-01-20	Hydrocarbon conversion with a sulfided superactive multimetallic catalytic composite
US4231897A (en)	1980-11-04	Attenuated superactive multimetallic catalytic composite
CN103372454B (zh)	2016-01-13	一种多金属重整催化剂及其制备与应用
US4290921A (en)	1981-09-22	Attenuated superactive multimetallic catalytic composite
US4238366A (en)	1980-12-09	Attenuated superactive multimetallic catalytic composite
US4229319A (en)	1980-10-21	Attenuated superactive multimetallic catalytic composite
RU2186622C2 (ru)	2002-08-10	Катализатор конверсии углеводородов, способ каталитического реформинга исходной нафты с использованием катализатора
US4312789A (en)	1982-01-26	Attenuated superactive multimetallic catalytic composite
US4206040A (en)	1980-06-03	Hydrocarbon conversion with an attenuated superactive multimetallic catalytic composite
US4256608A (en)	1981-03-17	Hydrocarbon conversion with an attenuated superactive multimetallic catalytic composite
US4298504A (en)	1981-11-03	Attenuated superactive multimetallic catalytic composite
US4312788A (en)	1982-01-26	Attenuated superactive multimetallic catalytic composite