UA79086C2 - Method for continuous production of acetic acid and/or methyl acetate - Google Patents

Method for continuous production of acetic acid and/or methyl acetate Download PDF

Info

Publication number: UA79086C2
Authority: UA; Ukraine
Prior art keywords: iridium; rhodium; reaction medium; carbonylation; fact
Prior art date: 2001-02-08

Application number

UA2003077209A

Other languages

English (en)

Ukrainian (uk)

Inventor

Daniel Marcel Thiebaut

Daniel Henri Marchand

Philippe Joseph Kalck

Berre Carole Marie Le

Philippe Gilles Serp

Original Assignee

Azetex Chimie

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-02-08

Filing date

2002-05-02

Publication date

2007-05-25

2002-05-02 Application filed by Azetex Chimie filed Critical Azetex Chimie

2007-05-25 Publication of UA79086C2 publication Critical patent/UA79086C2/uk

Links

238000000034 method Methods 0.000 title claims abstract description 82
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 title claims abstract description 33
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 title claims abstract description 33
238000010924 continuous production Methods 0.000 title claims abstract description 14
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title claims description 101
229910052703 rhodium Inorganic materials 0.000 claims abstract description 103
239000010948 rhodium Substances 0.000 claims abstract description 103
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 103
229910052741 iridium Inorganic materials 0.000 claims abstract description 97
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 96
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract description 96
239000012429 reaction media Substances 0.000 claims abstract description 78
230000003197 catalytic effect Effects 0.000 claims abstract description 74
238000005810 carbonylation reaction Methods 0.000 claims abstract description 70
230000006315 carbonylation Effects 0.000 claims abstract description 60
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
238000004519 manufacturing process Methods 0.000 claims abstract description 33
239000003054 catalyst Substances 0.000 claims abstract description 29
239000000203 mixture Substances 0.000 claims abstract description 27
230000008569 process Effects 0.000 claims abstract description 22
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 13
229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 13
239000002815 homogeneous catalyst Substances 0.000 claims abstract description 9
239000007791 liquid phase Substances 0.000 claims abstract description 7
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims abstract description 6
229910052751 metal Inorganic materials 0.000 claims description 58
239000002184 metal Substances 0.000 claims description 58
238000006243 chemical reaction Methods 0.000 claims description 48
150000002739 metals Chemical class 0.000 claims description 37
238000005260 corrosion Methods 0.000 claims description 34
230000007797 corrosion Effects 0.000 claims description 34
150000002504 iridium compounds Chemical class 0.000 claims description 25
238000007792 addition Methods 0.000 claims description 23
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 20
238000009835 boiling Methods 0.000 claims description 10
238000004821 distillation Methods 0.000 claims description 9
238000001704 evaporation Methods 0.000 claims description 9
238000006317 isomerization reaction Methods 0.000 claims description 8
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 8
230000009466 transformation Effects 0.000 claims description 7
229910052697 platinum Inorganic materials 0.000 claims description 4
238000000746 purification Methods 0.000 claims description 4
239000007787 solid Substances 0.000 claims description 4
150000004820 halides Chemical class 0.000 claims description 3
150000002503 iridium Chemical class 0.000 claims description 3
150000003284 rhodium compounds Chemical class 0.000 claims description 3
238000009826 distribution Methods 0.000 claims description 2
150000003058 platinum compounds Chemical class 0.000 claims description 2
230000000737 periodic effect Effects 0.000 claims 2
238000012876 topography Methods 0.000 claims 1
230000001131 transforming effect Effects 0.000 claims 1
-1 methyl halides Chemical class 0.000 abstract description 10
238000009434 installation Methods 0.000 abstract description 8
230000004048 modification Effects 0.000 abstract description 4
238000012986 modification Methods 0.000 abstract description 4
239000002253 acid Substances 0.000 abstract 1
229910052738 indium Inorganic materials 0.000 abstract 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 abstract 1
150000002472 indium compounds Chemical class 0.000 abstract 1
238000002474 experimental method Methods 0.000 description 69
239000000243 solution Substances 0.000 description 26
239000012071 phase Substances 0.000 description 20
230000008901 benefit Effects 0.000 description 12
150000004694 iodide salts Chemical class 0.000 description 9
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
230000008859 change Effects 0.000 description 7
238000004090 dissolution Methods 0.000 description 7
229910052740 iodine Inorganic materials 0.000 description 7
239000011630 iodine Substances 0.000 description 7
INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 7
KXAHUXSHRWNTOD-UHFFFAOYSA-K rhodium(3+);triiodide Chemical compound [Rh+3].[I-].[I-].[I-] KXAHUXSHRWNTOD-UHFFFAOYSA-K 0.000 description 7
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
230000007423 decrease Effects 0.000 description 6
WUHYYTYYHCHUID-UHFFFAOYSA-K iridium(3+);triiodide Chemical compound [I-].[I-].[I-].[Ir+3] WUHYYTYYHCHUID-UHFFFAOYSA-K 0.000 description 6
239000003153 chemical reaction reagent Substances 0.000 description 5
230000008020 evaporation Effects 0.000 description 5
238000006555 catalytic reaction Methods 0.000 description 4
238000000151 deposition Methods 0.000 description 4
230000008021 deposition Effects 0.000 description 4
239000007789 gas Substances 0.000 description 4
229910052742 iron Inorganic materials 0.000 description 4
238000001465 metallisation Methods 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
230000006641 stabilisation Effects 0.000 description 4
238000011105 stabilization Methods 0.000 description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
229910052804 chromium Inorganic materials 0.000 description 3
239000011651 chromium Substances 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000005516 engineering process Methods 0.000 description 3
229910052750 molybdenum Inorganic materials 0.000 description 3
239000011733 molybdenum Substances 0.000 description 3
238000011160 research Methods 0.000 description 3
238000000926 separation method Methods 0.000 description 3
230000007704 transition Effects 0.000 description 3
JLEQUYOQVZXFFW-UHFFFAOYSA-N 2-chlorobenzoate;dimethylazanium Chemical compound C[NH2+]C.[O-]C(=O)C1=CC=CC=C1Cl JLEQUYOQVZXFFW-UHFFFAOYSA-N 0.000 description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
238000007172 homogeneous catalysis Methods 0.000 description 2
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 2
238000005457 optimization Methods 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000009467 reduction Effects 0.000 description 2
229910052707 ruthenium Inorganic materials 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
101710148054 Ketol-acid reductoisomerase (NAD(+)) Proteins 0.000 description 1
101710099070 Ketol-acid reductoisomerase (NAD(P)(+)) Proteins 0.000 description 1
101710151482 Ketol-acid reductoisomerase (NADP(+)) Proteins 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
238000001479 atomic absorption spectroscopy Methods 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
BXEIMFCHLWQKTG-UHFFFAOYSA-N carbon monoxide;methanol Chemical compound OC.[O+]#[C-] BXEIMFCHLWQKTG-UHFFFAOYSA-N 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
235000019994 cava Nutrition 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000013256 coordination polymer Substances 0.000 description 1
238000007872 degassing Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
NNNDJDWZPQHGMB-UHFFFAOYSA-N formic acid;methyl formate Chemical compound OC=O.COC=O NNNDJDWZPQHGMB-UHFFFAOYSA-N 0.000 description 1
239000007792 gaseous phase Substances 0.000 description 1
238000007210 heterogeneous catalysis Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
239000003999 initiator Substances 0.000 description 1
239000003456 ion exchange resin Substances 0.000 description 1
229920003303 ion-exchange polymer Polymers 0.000 description 1
SXRIPRHXGZHSNU-UHFFFAOYSA-N iridium rhodium Chemical compound [Rh].[Ir] SXRIPRHXGZHSNU-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000000622 liquid--liquid extraction Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
239000012528 membrane Substances 0.000 description 1
229910001511 metal iodide Inorganic materials 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
150000003283 rhodium Chemical class 0.000 description 1
238000005070 sampling Methods 0.000 description 1
239000013049 sediment Substances 0.000 description 1
230000007928 solubilization Effects 0.000 description 1
238000005063 solubilization Methods 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

UA2003077209A 2001-02-08 2002-05-02 Method for continuous production of acetic acid and/or methyl acetate UA79086C2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR0101690A FR2820422B1 (fr)	2001-02-08	2001-02-08	Modification du systeme catalytique dans un procede industriel de fabrication d'acide acetique et/ou d'acetate de methyle
PCT/FR2002/000432 WO2002062739A1 (fr)	2001-02-08	2002-02-05	Modification du systeme catalytique dans un procede industriel de fabrication d'acide acetique et/ou d'acetate de methyle

Publications (1)

Publication Number	Publication Date
UA79086C2 true UA79086C2 (en)	2007-05-25

Family

ID=8859758

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
UA2003077209A UA79086C2 (en)	2001-02-08	2002-05-02	Method for continuous production of acetic acid and/or methyl acetate

Country Status (12)

Country	Link
US (1)	US7009070B2 (de)
EP (1)	EP1358145B1 (de)
JP (1)	JP4101059B2 (de)
CN (1)	CN1252025C (de)
AT (1)	ATE308501T1 (de)
DE (1)	DE60207044T2 (de)
ES (1)	ES2252426T3 (de)
FR (1)	FR2820422B1 (de)
RU (1)	RU2275352C2 (de)
TW (1)	TWI247002B (de)
UA (1)	UA79086C2 (de)
WO (1)	WO2002062739A1 (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20060129151A1 (en) *	2002-08-28	2006-06-15	Allen C W	Systems and methods for securing fractures using plates and cable clamps
CA2496839A1 (en)	2004-07-19	2006-01-19	Woodland Chemical Systems Inc.	Process for producing ethanol from synthesis gas rich in carbon monoxide
US8404341B2 (en)	2006-01-26	2013-03-26	Outlast Technologies, LLC	Microcapsules and other containment structures for articles incorporating functional polymeric phase change materials
US9234059B2 (en)	2008-07-16	2016-01-12	Outlast Technologies, LLC	Articles containing functional polymeric phase change materials and methods of manufacturing the same
JP2009532483A (ja) *	2006-04-05	2009-09-10	ウッドランドバイオフュールズインコーポレイテッド	合成ガスを介してバイオマスをエタノールに変換するための方法
CN100450988C (zh) *	2006-06-19	2009-01-14	上海吴泾化工有限公司	一种甲醇羰基合成醋酸的装置
EP2072487A1 (de) *	2007-12-17	2009-06-24	BP p.l.c.	Verfahren zur Umwandlung von Kohlenwasserstoffen in Ethanol
EP2072486A1 (de) *	2007-12-17	2009-06-24	BP p.l.c.	Verfahren zur Umwandlung von Kohlenwasserstoffen in Ethanol
US8221910B2 (en)	2008-07-16	2012-07-17	Outlast Technologies, LLC	Thermal regulating building materials and other construction components containing polymeric phase change materials
CN102093196B (zh) *	2009-12-15	2013-03-06	上海吴泾化工有限公司	一种链烷醇和/或其活性衍生物的羰基化制备羧酸的方法
CN102093198B (zh) *	2009-12-15	2012-12-05	上海吴泾化工有限公司	一种生产乙酸的方法
US8673448B2 (en)	2011-03-04	2014-03-18	Outlast Technologies Llc	Articles containing precisely branched functional polymeric phase change materials
WO2014209170A1 (ru) *	2013-06-26	2014-12-31	Ипхф Ран	Способ переработки природных и попутных газов
RU2538970C1 (ru) *	2013-06-26	2015-01-10	Федеральное государственное бюджетное учреждение науки Институт проблем химической физики Российской академии наук (ИПХФ РАН)	Способ переработки попутных и природных газов
RU2551678C1 (ru) *	2013-11-14	2015-05-27	Федеральное государственное бюджетное учреждение науки Институт проблем химической физики Российской академии наук (ИПХФ РАН)	Способ переработки природных и попутных газов
US10431858B2 (en)	2015-02-04	2019-10-01	Global Web Horizons, Llc	Systems, structures and materials for electrochemical device thermal management
US10003053B2 (en)	2015-02-04	2018-06-19	Global Web Horizons, Llc	Systems, structures and materials for electrochemical device thermal management
CN106518646B (zh) *	2015-09-11	2019-02-01	中国科学院大连化学物理研究所	一种通过甲酸甲酯异构化制备乙酸的方法
USD911961S1 (en)	2017-04-03	2021-03-02	Latent Heat Solutions, Llc	Battery container
CN112939763B (zh) *	2019-12-10	2022-06-03	中国科学院大连化学物理研究所	一种卤甲烷制备乙酸的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2703351A1 (fr) *	1993-03-31	1994-10-07	Rhone Poulenc Chimie	Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium.
FR2711365B1 (fr) *	1993-10-19	1995-12-15	Rhone Poulenc Chimie	Procédé d'hydroxycarbonylation du butadiène.
GB9503382D0 (en) *	1995-02-21	1995-04-12	Bp Chem Int Ltd	Process
FR2750984B1 (fr) *	1996-07-10	1998-11-06	Rhone Poulenc Chimie	Preparation d'acide acetique et/ou d'acetate de methyle par une reaction de carbonylation
US6211405B1 (en) *	1998-10-23	2001-04-03	Celanese International Corporation	Addition of iridium to the rhodium/inorganic iodide catalyst system
FR2785606B1 (fr) *	1998-11-05	2001-01-26	Acetex Chimie	Preparation d'acide acetique et/ou d'acetate de methyle en presence d'iridium et de platine

2001
- 2001-02-08 FR FR0101690A patent/FR2820422B1/fr not_active Expired - Fee Related
2002
- 2002-02-01 TW TW091101826A patent/TWI247002B/zh not_active IP Right Cessation
- 2002-02-05 ES ES02703653T patent/ES2252426T3/es not_active Expired - Lifetime
- 2002-02-05 CN CNB028047125A patent/CN1252025C/zh not_active Expired - Fee Related
- 2002-02-05 EP EP02703653A patent/EP1358145B1/de not_active Expired - Lifetime
- 2002-02-05 DE DE60207044T patent/DE60207044T2/de not_active Expired - Lifetime
- 2002-02-05 JP JP2002562700A patent/JP4101059B2/ja not_active Expired - Fee Related
- 2002-02-05 AT AT02703653T patent/ATE308501T1/de active
- 2002-02-05 WO PCT/FR2002/000432 patent/WO2002062739A1/fr not_active Ceased
- 2002-02-05 RU RU2003125182/04A patent/RU2275352C2/ru not_active IP Right Cessation
- 2002-02-05 US US10/433,474 patent/US7009070B2/en not_active Expired - Fee Related
- 2002-05-02 UA UA2003077209A patent/UA79086C2/uk unknown

Also Published As

Publication number	Publication date
ATE308501T1 (de)	2005-11-15
EP1358145A1 (de)	2003-11-05
JP2004536035A (ja)	2004-12-02
FR2820422B1 (fr)	2003-04-25
CN1252025C (zh)	2006-04-19
RU2003125182A (ru)	2005-03-10
DE60207044D1 (de)	2005-12-08
EP1358145B1 (de)	2005-11-02
TWI247002B (en)	2006-01-11
ES2252426T3 (es)	2006-05-16
JP4101059B2 (ja)	2008-06-11
US7009070B2 (en)	2006-03-07
FR2820422A1 (fr)	2002-08-09
US20040044245A1 (en)	2004-03-04
CN1491198A (zh)	2004-04-21
RU2275352C2 (ru)	2006-04-27
DE60207044T2 (de)	2006-07-20
WO2002062739A1 (fr)	2002-08-15

Publication	Publication Date	Title
UA79086C2 (en)	2007-05-25	Method for continuous production of acetic acid and/or methyl acetate
CA2225142C (en)	2006-12-05	Iridium-catalysed carbonylation process for the production of acetic acid
JP3308392B2 (ja)	2002-07-29	カルボニル化反応方法
EA019325B1 (ru)	2014-02-28	Композиции для получения карбоновой кислоты, способы их получения и применение
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