US10914A - Coating metals - Google Patents
Coating metals Download PDFInfo
- Publication number
- US10914A US10914A US10914DA US10914A US 10914 A US10914 A US 10914A US 10914D A US10914D A US 10914DA US 10914 A US10914 A US 10914A
- Authority
- US
- United States
- Prior art keywords
- bath
- metal
- flux
- coating
- molten metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002184 metal Substances 0.000 title description 30
- 229910052751 metal Inorganic materials 0.000 title description 30
- 239000011248 coating agent Substances 0.000 title description 13
- 238000000576 coating method Methods 0.000 title description 13
- 150000002739 metals Chemical class 0.000 title description 7
- 230000004907 flux Effects 0.000 description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 238000005192 partition Methods 0.000 description 8
- 239000012530 fluid Substances 0.000 description 5
- 238000007654 immersion Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 230000003292 diminished effect Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- BNHGKKNINBGEQL-UHFFFAOYSA-M sodium;5-ethyl-5-(3-methylbutyl)pyrimidin-3-ide-2,4,6-trione Chemical compound [Na+].CC(C)CCC1(CC)C(=O)NC(=O)[N-]C1=O BNHGKKNINBGEQL-UHFFFAOYSA-M 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
Definitions
- the bath When the bath is uniformly heated to a temperature which is found to insure the best adhesion of the coating to the metal being operated on, it is so hot that it discolors the fiux,which in turn stains the high degree of heat inthe bath of molten coating metal at the point at which the metal to be coated enters, and as low a temperature as will keep the bath fluid at the point at which the coated metal emerges from the bath, the hot and cold portions of the mass of metal being so divided that neither they nor the flux on their surfaces will be mixed.
- the highly fluid metal at the hot end of the bath insures the coating of every part of the immersed sheet, and the comparative coolness of the opposite end of the bath insures great tenacity of the coatmg and prevents the burning and greatly diminishes the tendency of the flux to. discoloration, and thus prevents the staining of the coated metal.
- A denotes the bath vessel
- the bath To prepare the bath for operation it is first charged with the proper quantity of zinc or other coating metal say suflicient to fill it within siX inches of the top. Fire is then applied to the end or side, at which the immersion orifice is situate until the metal is melted. The dross is then skimmed oft, and the immersion and emerging surfaces covered with a layer of sal-ammoniac or other flux, and in the trough-like space between the partitions a layer of several inches of sand or other suitable pulverulent matter is placed; as soon as the bath has reached the proper temperature, it is ready for the work of coating to commence by dipping the article to be covered, already prepared in the usual manner, into the hottest end or orifice of the bath, passing it beneath the surface of the melted metal, under the partition and out at the cooler end of the bath, as the flux is consumed with a degree of rapidity corresponding to the heat to which it is subjected, other things being equal, much 'more is used at the immersing than at the emerging or
- Sheets of iron are the only thing; coated so far that require the fiuxing of both orifices of the bath.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating With Molten Metal (AREA)
Description
V '61 G. ROGERS.
BATH FOR COATING METAL WITH OTHER METAL.
No. 10,914. Patented May 16, 1854.
. GEORGE ROGERS, or ENEIELD, ENGLAND.
BATHFO'R COATING METALS WITH OTHER METALS.
T Specification of Letters Patent No. 10,914., dated May 16, 1854.
To all whom it may) concern.- Beit known that I, GEORGE ROGERS, of
Enfield, in the county of Middlesex, England, have invented certain new and useful Improvements in Coating Metals with other Metals, of which the following is a full,
clear, and exact description, reference being had to the accompanying drawings, which form part of this specification, and inwhich t a Figure 1 represents a plan of a bath e1n bracing my improvements, Fig. 2 a longitudinal section of the same.
This invention of improvements in coating metals with other metals refers to improvements made on an invention for which I, in connection with Edmund Morewood obtained Letters Patent in England bearing date the 4th May1843. In the specification of that patent an improvement in the bath for containing the molten metal which is to form the coating for the metallic articles required to be Located, is shown and described. By this improvement we were enabled to insure the proper immersion in the molten metal of the sheet iron or other article under treatment. This object was attained by causingthe sheet iron to pass under a bar stretching from end to end of the bath and placed below the surface of the molten metal. When operating after this manner our practice has been to cover the surface of the molten metal with a body of flux, so that, supposing sheet iron to be under treatment, the sheet as it is passed into the bath is prepared to receive the coating of metal by first being brought into contact with the flux. When the bath is uniformly heated to a temperature which is found to insure the best adhesion of the coating to the metal being operated on, it is so hot that it discolors the fiux,which in turn stains the high degree of heat inthe bath of molten coating metal at the point at which the metal to be coated enters, and as low a temperature as will keep the bath fluid at the point at which the coated metal emerges from the bath, the hot and cold portions of the mass of metal being so divided that neither they nor the flux on their surfaces will be mixed. By this means the highly fluid metal at the hot end of the bath insures the coating of every part of the immersed sheet, and the comparative coolness of the opposite end of the bath insures great tenacity of the coatmg and prevents the burning and greatly diminishes the tendency of the flux to. discoloration, and thus prevents the staining of the coated metal. I found it exceedingly difficult to construct a bath that would fulfil these conditions, anddeemed it impossible to do so until I discovered that inmetal rendered fluid by heat, a circulation is established by the heat, as in the case of other fluids, while its power of conduction during fluidity is greatly diminished. As water in one limb of an inverted siphon may be boiled while that in the other is at the freezing point so I found by actual experiment, the metal in one end or limb ofa bath, resembling an inverted siphon in construction may readily be kept highly heated, while that in. the other limb is barely hot enough to remain fluid. This discovery enabled me at once to construct my bath so as to fulfil in practice the conditions required by theory. All that I had to do was to divide by one or more partitions the upper part of the bath, leaving it undivided below, so that that part of the surface of the bath of molten metal at which the plate or other article to be coated is immersed, may be kept separate from thatat which it emerges.
In the drawings A denotes the bath vessel,
and B the partition bars or plates. Where two bars or plates are used, they are arranged as represented at Figs. 1 and 2. The employment of two partition plates, admits of the contraction of the surface of the immersion and emerging orifices of the bath to a width barely sufliclent for the free entrance and egress of the articles to be coated. This arrangement admits of a further improvement in the bath by which a great saving of flux is effected, and this improvement consists in covering that portion of the surface of the bath between the partition plates with powdered charcoal, sand, or other pulverulent matter which is cheap and a bad conductor of heat, instead of the more. costly fluxes heretofore used to cover the entire surface of the molten metal, to protect it from oxidation, and loss of its heat by radiation. Thus by the substitution of cheap pulverulent matter for expensive flux to cover a large part of the surface of the bath, and the lowering of the temperature of one end. of the bath, the volatilization and consequent waste of flux is materially diminished, with a corresponding diminution of the annoyance to the workmen, produced by the noxious fumes evolved from hot flux.
To prepare the bath for operation it is first charged with the proper quantity of zinc or other coating metal say suflicient to fill it within siX inches of the top. Fire is then applied to the end or side, at which the immersion orifice is situate until the metal is melted. The dross is then skimmed oft, and the immersion and emerging surfaces covered with a layer of sal-ammoniac or other flux, and in the trough-like space between the partitions a layer of several inches of sand or other suitable pulverulent matter is placed; as soon as the bath has reached the proper temperature, it is ready for the work of coating to commence by dipping the article to be covered, already prepared in the usual manner, into the hottest end or orifice of the bath, passing it beneath the surface of the melted metal, under the partition and out at the cooler end of the bath, as the flux is consumed with a degree of rapidity corresponding to the heat to which it is subjected, other things being equal, much 'more is used at the immersing than at the emerging orifice, the fresh flux however is first placed in the latter orifice until it begins to burn and get discolored, when it is transferred to the former orifice, and replaced by a quantity of the clean fresh material, in this way the partition enables me to produce coated articles of uniform and good color. In case of wire and a few other simi-. lar articles, the hot end only of the bath is fluxed, the opposite end being covered. by
the pulverulent matter alone, and this.
method of operation in all cases in which it will answer, effects a still further saving of tion of coating.
Sheets of iron are the only thing; coated so far that require the fiuxing of both orifices of the bath.
1 have flux'and consequent economy in the opera- What I claim as my invention and desire to secure by Letters Patent is Constructing the bath in such manner that the upper portion of the molten metal at which the article to be coated enters, is-
separated by a partition from that portion of the upper part of the molten metal at the surface of the molten metal, the remainder being covered by flux as herein set V forth.
In testimony whereof I have hereunto subscribed my name.
GEORGE ROGERS.
Witnesses WILLIAM EARNY, JOHN R. BARKER.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US10914A true US10914A (en) | 1854-05-16 |
Family
ID=2071244
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10914D Expired - Lifetime US10914A (en) | Coating metals |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US10914A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040164243A1 (en) * | 2002-04-23 | 2004-08-26 | Hitachi High Technologies Corporation | Shape measurement method and apparatus |
-
0
- US US10914D patent/US10914A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040164243A1 (en) * | 2002-04-23 | 2004-08-26 | Hitachi High Technologies Corporation | Shape measurement method and apparatus |
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