US1808363A - Production of preparations for oiling fibrous materials - Google Patents

Production of preparations for oiling fibrous materials Download PDF

Info

Publication number: US1808363A
Authority: US; United States
Prior art keywords: oiling; fibrous materials; preparations; production; alkaline agent
Prior art date: 1928-08-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

US376850A

Other languages

English (en)

Inventor

Luther Martin

Beller Hans

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

IG Farbenindustrie AG

Original Assignee

IG Farbenindustrie AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1928-08-06

Filing date

1929-07-08

Publication date

1931-06-02

1929-07-08 Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG

1931-06-02 Application granted granted Critical

1931-06-02 Publication of US1808363A publication Critical patent/US1808363A/en

1948-06-02 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000002360 preparation method Methods 0.000 title description 12
239000002657 fibrous material Substances 0.000 title description 10
238000004519 manufacturing process Methods 0.000 title description 5
239000002253 acid Substances 0.000 description 14
239000003795 chemical substances by application Substances 0.000 description 14
230000003647 oxidation Effects 0.000 description 14
238000007254 oxidation reaction Methods 0.000 description 14
239000000203 mixture Substances 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
150000007513 acids Chemical class 0.000 description 8
150000001735 carboxylic acids Chemical class 0.000 description 8
150000002894 organic compounds Chemical class 0.000 description 8
239000003921 oil Substances 0.000 description 7
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 6
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
239000005642 Oleic acid Substances 0.000 description 4
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
239000003208 petroleum Substances 0.000 description 4
239000004753 textile Substances 0.000 description 4
229910021529 ammonia Inorganic materials 0.000 description 3
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000004821 distillation Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
239000000463 material Substances 0.000 description 2
238000000034 method Methods 0.000 description 2
238000007127 saponification reaction Methods 0.000 description 2
239000000344 soap Substances 0.000 description 2
238000009987 spinning Methods 0.000 description 2
239000001993 wax Substances 0.000 description 2
210000002268 wool Anatomy 0.000 description 2
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
238000009960 carding Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
238000009963 fulling Methods 0.000 description 1
-1 hydroxy fatty acids Chemical class 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
239000008041 oiling agent Substances 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
238000003825 pressing Methods 0.000 description 1
238000007790 scraping Methods 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
239000010698 whale oil Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

the present invention relates to the propreparations for oiling fibrous materials.
1 Y 1 The preparations hitherto employed for oiling textile materials, such as in softening or oiling wool, oiling onspinning', in making shoddy, in fulling and similar textile processes, usually consist of, or contain, olein or crude oleic acid.
the products usually obtained by a simple saponification and distillation and consequently contain more or less of stearin which considerably reduces the resistance to cold and fluidity.
Such oils, and especially those which have been drying oils and the like also show to resinify so that, for example,
the said oils of lower viscosity are difficulty available, the only oil available in ample quantities being olein or oleic acid.
alkaline agent may vary depending on the desired application of the oiling agents. For use in making shoddy, for, example, a very small quantity only of alkaline agent may be employed or it may be dispensed with altogether.
the properties of these acids approximate to some degree to those of olein, they solidify however only at about 0 C. and they possess a lower viscosity than olein so that a very economical use is granted; they are of pale color and completely clear.
Atures they can be readily emulsified by means of very small quantities of basic agents and be easily dissolved with the aid of an about equivalent quantity of a basic agent, they exhibit no tendency to resinify or become sticky, and even when in a state of very fine distribution on the fibres they are not liable to catch fire.
the saponification value varies between 190 and 220, and the iodine value between 70 and 90, which, moreover, can be varied according to any special requirement by suitable Variations in the production of the unsaturated acids.
the said products can be produced in a continually constant quality and are particularly well adapted, for example, for various purposes of the textile industry, for the manufacture of softening oils, spinning oils and the like, for the manufacture of textile soaps and any similar preparations hitherto prepared by means of olein, oleic acid and the like
the aforesaid products can be employed also in conjunction with the aforesaid compounds or with the mixtures of carboxylic acids obtainable in the oxidation of hydrocarbons and the like.
Example I 300 C the hydroxy fatty acids produced by the oxidation of parafiin wax and separated by pressing, which said unsaturated acids are preferably employed in the form of an emulsion with water and a small quantity of ammonia.
the further working up of the threads, for example carding and scraping are considerably facilitated by this treatment.
the unsaturated acids which have been added can be removed from the wool yarn by passage through a soap bath at 40 C. which contains sodium carbonate and ammonia.
Vhat we claim is 1.
a preparation for oiling fibrous materials comprising a mixture of unsaturated carboxylic acids obtained by splitting ofiwater from an oxidation product of high molecular organic compounds, and an alkaline agent.
a preparation for oiling fibrous materials comprising a mixture of unsaturated carboxylic/acids obtained by splitting olf water from the acid portion of an oxidation product of high molecular organic compounds, and an alkaline agent;
a preparation for oiling fibrous materials comprising a mixture of unsaturated carboxylic acids obtained by splitting ofi water from the acid portion, insoluble in petroleum ether, of an oxidation product of high molecular organic compounds, and an' alkaline agent.
a preparation for oiling fibrous materials comprising a mixture of unsaturated carboxylic acids obtained by splitting off water from an oxidation product of high molecular organic compounds, and a very small quantity of an alkaline agent.
a preparation for oiling fibrousmatean alkaline rials comprising a mixture of unsaturated carboxylic acids obtained by splitting ofi water from the acid portion insoluble in petroleum ether, of an oxidation product of paraffin wax, and an alkaline agent.
a preparation for oiling fibrous materials comprising a mixture of unsaturated carboxylic acids obtained by splitting ofi water from the acid portion, insoluble in petroleum ether, of an oxidation product of high molecular organic compounds and a very small quantity of an alkaline agent.
a preparation for oiling fibrous materials comprising a mixture of unsaturated carboxylic acids obtained by splitting ofi'water from an oxidation product of high molecular organic compounds, an alkaline agent ,and water.
a preparation for oiling fibrous .materials comprising a mixture of unsaturated carboxylic acids obtained by s litting oif water from the acid portion 0 an oxidation product of high molecular organic compounds, an alkaline agent and water.
a preparation for oiling fibrous materials comprising a mixture of unsaturated carboxyiic acids obtained by splitting ofi Waof an oxidation product of high

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Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Fats And Perfumes (AREA)

US376850A 1928-08-06 1929-07-08 Production of preparations for oiling fibrous materials Expired - Lifetime US1808363A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE1808363X		1928-08-06

Publications (1)

Publication Number	Publication Date
US1808363A true US1808363A (en)	1931-06-02

Family

ID=7744168

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
US376850A Expired - Lifetime US1808363A (en)	1928-08-06	1929-07-08	Production of preparations for oiling fibrous materials

Country Status (2)

Country	Link
US (1)	US1808363A (fr)
FR (1)	FR677997A (fr)

1929
- 1929-07-08 FR FR677997D patent/FR677997A/fr not_active Expired
- 1929-07-08 US US376850A patent/US1808363A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
FR677997A (fr)	1930-03-17

Publication	Publication Date	Title
US2283602A (en)	1942-05-19	Grease and lubricant
US1808363A (en)	1931-06-02	Production of preparations for oiling fibrous materials
US1826900A (en)	1931-10-13	Process of producing emulsions
US2078886A (en)	1937-04-27	Mixed textile material and method of making same
US1989196A (en)	1935-01-29	Journal grease
US2371933A (en)	1945-03-20	Binders for glass fiber threads
US2176402A (en)	1939-10-17	Treatment of artificial silk
US2139343A (en)	1938-12-06	Method of surface treating fibrous rope or cordage
US2200298A (en)	1940-05-14	Modified fatty alcohol and process for producing same
US2978408A (en)	1961-04-04	Scorch resistant textile softening finish composition
US2132348A (en)	1938-10-04	Higher molecular alcohols
US2308355A (en)	1943-01-12	Lubricant for textiles and the like
US2049043A (en)	1936-07-28	Soluble oils
US2025989A (en)	1935-12-31	Method for soaking natural silk fibers
US2268141A (en)	1941-12-30	Composition and process for treating fibrous materials
US2012610A (en)	1935-08-27	Treatment process
US2008419A (en)	1935-07-16	Oil composition and method of making the same
US2225552A (en)	1940-12-17	Production of lubricants for textiles
DE640681C (de)	1937-01-09	Verfahren zur Gewinnung von gereinigten Schwefelsaeureestern der Fett- und Wachsalkohole
DE742523C (de)	1943-12-06	Verfahren zur Verbesserung der Spinnbarkeit von Cellulosehydratfasern
USRE20361E (en)	1937-05-11	Frocess of producing emulsions
US2672976A (en)	1954-03-23	Drawing lubricant compositions
DE942889C (de)	1956-05-09	Fettungsmittel fuer Materialien faseriger Struktur
DE585724C (de)	1933-10-10	Verfahren zum Glaetten, Schlichten, Appretieren und Schmaelzen von Textilfasern
US2258300A (en)	1941-10-07	Solid lubricant