US1818466A - Textile material containing organic esters of cellulose and method of preparing the same - Google Patents

Textile material containing organic esters of cellulose and method of preparing the same Download PDF

Info

Publication number
US1818466A
US1818466A US293781A US29378128A US1818466A US 1818466 A US1818466 A US 1818466A US 293781 A US293781 A US 293781A US 29378128 A US29378128 A US 29378128A US 1818466 A US1818466 A US 1818466A
Authority
US
United States
Prior art keywords
textile material
cellulose
fabric
bath
organic esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US293781A
Inventor
Dreyfus Camille
William R Blume
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Priority to US293781A priority Critical patent/US1818466A/en
Application granted granted Critical
Publication of US1818466A publication Critical patent/US1818466A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D06M11/385—Saponification of cellulose-acetate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92—Synthetic fiber dyeing
    • Y10S8/921—Cellulose ester or ether

Definitions

  • This invention relates to the treatment of fabrics or yarns containing organic esters of cellulose in such a manner that the fabrics or yarns may be safely ironed by means of irons or calenders that are at higher temperatures than may safely be employed with previously known textile materials.
  • An object of ourinvention is to produce textile material containing organic esters of cellulose that have higher safe ironing temperatures than prev1ously' known textile materials of this type.
  • Other objects of our invention will a pear from the following detailed description. 7
  • extile materials containing yarns of 'organic esters of cellulose may ordinarily not be ironed with an iron whose temperature is above about 230 0. since the organic esters of cellulose material tends to stick to the :0 iron above this temperature.
  • the so partially saponified material is then weighted with metallic salts or other weightin agents to the desired degree.
  • cordance with our invention may be a woven, knitted or netted fabric or it may be yarn in the form of hanks, or wound on bobbins, cones or other textile packages.
  • Thetextile' material to be treated may contain any suitable organic ester of cellulose such as cellulose acetate, cellulose formate, cellulose propionate or cellulose butyrate.
  • the textile material may consist wholly of one or more of these organic esters of cellulose, or may be a mixed fabric or yarn containing yarns of these organic esters of cellulose and yarns of cotton, silk or reconstituted cellulose (rayon).
  • the alkaline'bath used for partially saponifying the cellulose acetate contained in the fabric or yarn may be either of low concentration or of highconcentration dependin on the temperature of treatment. If an a alinesolution of low concentration is used, higher temperatures may be employed in the process, .whereas if alkaline solutions of high concentrations are used, low temperatures of treatment are employed. If a solution of intermediate concentration is employed, intermediate temperatures of treatment should .be used.
  • the saponifying bath may contain any suitable alkali or alkaline salt for producing hydroxyl ions in aqueous solutions.
  • alkalies sodium hydroxide, potassium hydroxide or ammonium ide may be mentioned.
  • alkaline salts are sodiumor potassium carbonates,- sodium or potassium henolate, sodium or potassium sulphite, sodium or potassium phosphate.
  • buffer salts or mo ifying agents such as soap, sodium acetate, borax or alcohol, etc. may be added to the saponifying hydroxyl ions in amounts corresponding to less than 0.2 grams of sodium hydroxide per liter.
  • the saponification may proceed to any desired extent, say 3% or- 5 to 10% or more. These percentages represent the percent of loss of weight the cellulose acetate has suffered through the saponification treatment.
  • the saponification of the fabric with alkaline solutions of low concentrations may be carried out in a tank, on the jig, on the winch or in any other suitable device. Often it is desirable to thoroughly wet out the fabric rior to subjecting it to the saponifiqation ath.
  • the addition of soap to the saponification bath is of great advantage in promoting level saponification of the organic esters of cellulose material, and also the presence of the soap in the saponifying bath tends to help to cause the saponification to be concentrated on the surface of the yarn containing the organic esters of celulose, which causes desirable increase in safe ironing point. While the proportions of soap to the solution may be varied within wide limits, it may be stated that the presence of 0.5 grams to 10 grams of soap per liter of solution produces satisfactory results.
  • the goods are scoured in an open'bath on strings or in any suitable machine such as a jig, with a bath containing olive oil soap for an hour or two.
  • the goods may then be removed from the bath and saponified in a separate bath containing fresh water and alkali, but'they are preferably saponified dire tly in the general scouring bath by the addition of a requisite amount of caustic soda.
  • the fabric ' is immersed in a bath of such large volume that it contains sufficient alkali to cause the desired degree of saponification-but which is not of such concentration to exceed the maximum permis- 54% acetyl value, we have found that a bath of up to 120 to 180 times the weight of the fabric can advantageously be used, and that such a bath should preferably contain an amount of caustic soda to the extent of 4 to 8% of the weight of the fabric, when a bath temperature of C. is used.
  • the proportions will be varied accordingly. Likewise it is apparent that when smaller amounts of alkaline material are used the volume of the saponification bath may be correspondingly decreased.
  • the fabric or yarn containing the yarns of cellulose acetate is treated in an alkaline bath of comparatively small volume and containing a relatively small amount of caustic soda.
  • the saponification proceeds, further quantities of caustic soda are added in small increments, until the desired degree of saponification has taken place.
  • the temperature of treatment is preferably room temperature and should not exceed 35 C. for obtaining the best results.
  • the textile material after saponification by any of the above-methods is then weighted by subjecting the same to a swelling agent and a weighting agent.
  • Thelswelling agent and the weighting agent may be applied in separate baths or they may be applied in the same bath.
  • the weighting agent may of itselfbe a swelling agent so that the use ofanother swelling agent may not be necessary. Examples of threeuarters of an hour.
  • swelling agents are comparatively concentrated aqueous solutions of acetic acid,-formic acid, lactic acid, or acetone.
  • weighting agents are aqueous solutions of stannic chloride or tannic acid, strong solutions of which are also swelling agents. After treating with the weighting agent, the fabric is subjected to the action of a fixing bath which contains alkaline phosphates or silicates.
  • the product formed by our process has a safe ironing point that is from 10 to 25 C. or more higher than the safe ironing point of the textile materials that have been saponified alone or have been weighted alone. Moreover, the fabric produced by our process has a softer hand than fabrics that have been subjected to the weighting process alone or to the partial saponification process alone.
  • the textile material should be first partially saponified and then weighted, rather than first weighted and then partially saponified, since a much higher safe ironing point. may be imparted to the textile material by the process that involves first partially saponifying and then weighting. While we do not limit our to this theory we believe that this is due to the fact that if the textile material is first weighted, the presence of the weighting agent causes saponification to proceed throughout the whole fabric, as against the intense surface saponification produced by the partial saponification of the unweighted textile material by the process above described.
  • Ewample A wovenfabric consisting wholly of cellulose acetate yarn is plaited and strung, and isthen immersed in a bath in which the ratio of water to fabric is between 130 and 160 to 1.
  • This bath contains soap to the extent .of 1 gram per liter of bath and the bath temperature is maintained at 80 C.
  • the fabric is treated in this soap bath for It is then raised out o the bath, and caustic soda in an amount equal to 6% of the weight of the fabric is added to the bath, and after the solution is homogeneous, the fabric is then immersed in the bath and is treated therein for approximately threehours while the bath temperature is maintained at 80 C.
  • the fabric is then lifted and washed off in water at C.
  • this fabric may be dyed or.
  • the safe ironing point is determined by measuring the maximum temperature of an iron that does not stick to, melt or scorch the fabric when said iron is permitted to rest upon the fabric for five seconds.
  • the safe ironing point of a cotton fabric when tested in 7 this manner is not appreciably over 260 C.
  • Method of increasing the safe ironing point of a textile material containing organic esters .of cellulose comprising subjecting the textile material to a solution of'alkali and then weighting the same with a tannic.
  • Method of increasing the safe ironing point of a textile material containing organic esters of cellulose comprisingsubjecting the textile material to a solution of alkali, then Weighting the same by treatment with a tin salt, and then 'fixing the tin by treatment with a precipitating agent, whereby a textile material having a safe ironing point above 270 C. is produced.
  • Met od of increasing the safe ironing point of a textile material: containing cellulose acetate comprising subjecting the textile material to a solution "of alkali and then weightin the same with a tin compound.
  • Met 0d of increasing the safe ironing point of a textile material containing cellulose acetate comprising subjecting the textile material to a solution of alkali, then weighting the same by treatment with a tin salt, and then fixing the tin by treatment with a precipitating agent, whereby a textile material having a safe ironing point above 270 C. is produced.
  • Method'of increasing the safe ironing point of a textile material containing cellu lose acetate comprising'subjectin the textile material to a solution of alkali, t en weight ing the same by treatment with a tannic acid solution, and then fixing thetannic acid compounds by treatment with a precipitating agent, whereby a textile material having a safe ironing point above 270 .C. is produced.
  • a textile material containing partially saponified cellulose acetate, -which" textile material is weighted with a tannic acid compound, said textile material having a safe ironing point above 270 C.
  • said textile material having a safe ironing point between 280 and 285 C.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Description

' Patented Aug. 11, 1931 UNITED STATES PATENT o FmE CAIILLE DBEY I'UB AND WILLIAM B. BLUME, OF NEW- YORK, N. Y., ASSIGNOBS IO WEBB GORIORATION OF AMERICA, A. CORPORATION OF DELAWARE .ZEEZ'I'ILE MATERIAL CGNTAIHIHG ORGANIC ESTERS OI CELLULOSE AND METHOD IBEPARING THE SAME no Drawing.
This invention relates to the treatment of fabrics or yarns containing organic esters of cellulose in such a manner that the fabrics or yarns may be safely ironed by means of irons or calenders that are at higher temperatures than may safely be employed with previously known textile materials.
An object of ourinvention is to produce textile material containing organic esters of cellulose that have higher safe ironing temperatures than prev1ously' known textile materials of this type. Other objects of our invention will a pear from the following detailed description. 7
extile materials containing yarns of 'organic esters of cellulose may ordinarily not be ironed with an iron whose temperature is above about 230 0. since the organic esters of cellulose material tends to stick to the :0 iron above this temperature. To increase the safe ironing point of such textile materials, it has been proposed to partially saponify the same, and it has also been proposed to weight these textile materials with 26 metallic salts. In either case, however,the
safe ironing point is raised to a predetermined amount, which, in the case of cellulose acetate textile material, does not generally exceed 260 C. We have made the so surprising discovery that'if textile materials -containing organic esters of cellulose are first partially saponified and then weighted with a metallic salt or other weightin agent the safe ironing oint of the materia is increased considerably, so that these materials may be ironed at temperatures above that at which even cotton or silk scorches. Thus, a fabric containing cellulose acetate yarn, when treated in accordance with our invention, has a safe ironing point of 27 5 to 285 C. or more. I
In accordance with our invention, we partially saponify the textile material, made of or containing organic esters of cellulose by means of an alkaline bath of suitable concentration and at suitable temperatures.
The so partially saponified material is then weighted with metallic salts or other weightin agents to the desired degree.
' he textile material to be treated in acsilicate, or tri-sodium Application filed July 18, 1928. Serial No. 293,781.
cordance with our invention may be a woven, knitted or netted fabric or it may be yarn in the form of hanks, or wound on bobbins, cones or other textile packages.
Thetextile' material to be treated may contain any suitable organic ester of cellulose such as cellulose acetate, cellulose formate, cellulose propionate or cellulose butyrate. The textile material may consist wholly of one or more of these organic esters of cellulose, or may be a mixed fabric or yarn containing yarns of these organic esters of cellulose and yarns of cotton, silk or reconstituted cellulose (rayon).
The alkaline'bath used for partially saponifying the cellulose acetate contained in the fabric or yarn may be either of low concentration or of highconcentration dependin on the temperature of treatment. If an a alinesolution of low concentration is used, higher temperatures may be employed in the process, .whereas if alkaline solutions of high concentrations are used, low temperatures of treatment are employed. If a solution of intermediate concentration is employed, intermediate temperatures of treatment should .be used.
The saponifying bath may contain any suitable alkali or alkaline salt for producing hydroxyl ions in aqueous solutions. Of the alkalies that are suitable, sodium hydroxide, potassium hydroxide or ammonium ide may be mentioned. Examples 0 alkaline salts. are sodiumor potassium carbonates,- sodium or potassium henolate, sodium or potassium sulphite, sodium or potassium phosphate. In order to promote intense sur ace saponification of the yarn containing the or anic ester of cellulose, buffer salts or mo ifying agents such as soap, sodium acetate, borax or alcohol, etc. may be added to the saponifying hydroxyl ions in amounts corresponding to less than 0.2 grams of sodium hydroxide per liter. The saponification may proceed to any desired extent, say 3% or- 5 to 10% or more. These percentages represent the percent of loss of weight the cellulose acetate has suffered through the saponification treatment.
.The saponification of the fabric with alkaline solutions of low concentrations may be carried out in a tank, on the jig, on the winch or in any other suitable device. Often it is desirable to thoroughly wet out the fabric rior to subjecting it to the saponifiqation ath. The addition of soap to the saponification bath is of great advantage in promoting level saponification of the organic esters of cellulose material, and also the presence of the soap in the saponifying bath tends to help to cause the saponification to be concentrated on the surface of the yarn containing the organic esters of celulose, which causes desirable increase in safe ironing point. While the proportions of soap to the solution may be varied within wide limits, it may be stated that the presence of 0.5 grams to 10 grams of soap per liter of solution produces satisfactory results.
In one mode of carrying out the partial saponification with the use of solutions contaming alkali in low concentrations, the goods are scoured in an open'bath on strings or in any suitable machine such as a jig, with a bath containing olive oil soap for an hour or two. The goods may then be removed from the bath and saponified in a separate bath containing fresh water and alkali, but'they are preferably saponified dire tly in the general scouring bath by the addition of a requisite amount of caustic soda. In one mode of partially saponifying the fabric containing the organic ester of cellulose with an alkaline solution of low concentration, the fabric 'is immersed in a bath of such large volume that it contains sufficient alkali to cause the desired degree of saponification-but which is not of such concentration to exceed the maximum permis- 54% acetyl value, we have found that a bath of up to 120 to 180 times the weight of the fabric can advantageously be used, and that such a bath should preferably contain an amount of caustic soda to the extent of 4 to 8% of the weight of the fabric, when a bath temperature of C. is used. Obviously,
if the fabric or yarn contains other organic esters of cellulose or an alkaline material other than caustic soda is used or if the temperature of the bath is other than 80 Q, the proportions will be varied accordingly. Likewise it is apparent that when smaller amounts of alkaline material are used the volume of the saponification bath may be correspondingly decreased.
In another mode of carrying out the saponification when alkaline-solutions of low concentrations are employed, the fabric or yarn containing the yarns of cellulose acetate is treated in an alkaline bath of comparatively small volume and containing a relatively small amount of caustic soda. As the saponification proceeds, further quantities of caustic soda are added in small increments, until the desired degree of saponification has taken place. Until the operator has gained sufficient experience, it is preferable to check up the amount of caustic soda in thebath by titration with sulphuric acid to insure that the amount of 9 caustic soda added is not sufiiclent to cause fabric containing the organic esters of cellulose in any suitable manner. However, we prefer to apply the caustic sodawhen ap-' plied in comparatively concentrated solution to the fabric by padding the caustic solution onto the fabric and then permitting the same to stand for an appreciable length of time. The temperature of treatment is preferably room temperature and should not exceed 35 C. for obtaining the best results.
The textile material after saponification by any of the above-methods, is then weighted by subjecting the same to a swelling agent and a weighting agent. Thelswelling agent and the weighting agent may be applied in separate baths or they may be applied in the same bath. Furthermore the weighting agent may of itselfbe a swelling agent so that the use ofanother swelling agent may not be necessary. Examples of threeuarters of an hour.
vsh
swelling agents are comparatively concentrated aqueous solutions of acetic acid,-formic acid, lactic acid, or acetone. Examples of weighting agents are aqueous solutions of stannic chloride or tannic acid, strong solutions of which are also swelling agents. After treating with the weighting agent, the fabric is subjected to the action of a fixing bath which contains alkaline phosphates or silicates.
The product formed by our process has a safe ironing point that is from 10 to 25 C. or more higher than the safe ironing point of the textile materials that have been saponified alone or have been weighted alone. Moreover, the fabric produced by our process has a softer hand than fabrics that have been subjected to the weighting process alone or to the partial saponification process alone.
For the best results, the textile material should be first partially saponified and then weighted, rather than first weighted and then partially saponified, since a much higher safe ironing point. may be imparted to the textile material by the process that involves first partially saponifying and then weighting. While we do not limit ourselves to this theory we believe that this is due to the fact that if the textile material is first weighted, the presence of the weighting agent causes saponification to proceed throughout the whole fabric, as against the intense surface saponification produced by the partial saponification of the unweighted textile material by the process above described.
In order to further illustrate our invention thefollowing detailed example is given, but this invention is not limited thereto.
Ewample A wovenfabric consisting wholly of cellulose acetate yarn is plaited and strung, and isthen immersed in a bath in which the ratio of water to fabric is between 130 and 160 to 1. This bath contains soap to the extent .of 1 gram per liter of bath and the bath temperature is maintained at 80 C. The fabric is treated in this soap bath for It is then raised out o the bath, and caustic soda in an amount equal to 6% of the weight of the fabric is added to the bath, and after the solution is homogeneous, the fabric is then immersed in the bath and is treated therein for approximately threehours while the bath temperature is maintained at 80 C. The fabric is then lifted and washed off in water at C.
- The so partially saponified fabric is thenv solution of stannic chloride for "one-halfoff in water and then treated with a 7 Tw.
solution of. sodium silicate. The fabric is then washed with or without soap, and is found to have increased in weight by 20%.
If desired, this fabric may be dyed or.
printed. The safe ironing point of the fabric has been increased by this process by 60 C.
or more, as is'indicated by the fact that the safe ironing point of the fabric, after it has been treated as above described, is increased to 280 'C. to 285 C. The safe ironing point is determined by measuring the maximum temperature of an iron that does not stick to, melt or scorch the fabric when said iron is permitted to rest upon the fabric for five seconds. The safe ironing point of a cotton fabric when tested in 7 this manner is not appreciably over 260 C.
It is to be understood that the foregoing detailed description is given merely by way of illustration and that many variations may be made therein without departing from the. spirit of this invention.
Having described our invention, what we lose acetate comprising both partially saponifying the cellulose acetate and weighting the textile material.
3. Method of increasing the safe ironing point of a textile material containing organic esters of cellulose comprising subjecting the textile material to a solution of alkali and thenweighting the same.
4. Method of increasing the safe ironing point of a textile material containing organic esters of cellulose-comprising subjecting the textile material to a solution of alkali and then weighting the same with a tin compound.
5. Method of increasing the safe ironing point of a textile material containing organic esters .of cellulose comprising subjecting the textile material to a solution of'alkali and then weighting the same with a tannic.
acid compound.
6. Method of increasing the safe ironing point of a textile material containing organic esters of cellulose comprisingsubjecting the textile material to a solution of alkali, then Weighting the same by treatment with a tin salt, and then 'fixing the tin by treatment with a precipitating agent, whereby a textile material having a safe ironing point above 270 C. is produced.
7. Method of increasing the safe ironing hour at 55 to 65 C. The fabric is rinsed point of a textile material containing celluloseacetate comprising subjecting the textile material to a solution of alkali and then weightin the same.
8. Met od of increasing the safe ironing point of a textile" material: containing cellulose acetate comprising subjecting the textile material to a solution "of alkali and then weightin the same with a tin compound.
9. Met 0d of increasing the safe ironing point of a textile material containing cellulose acetate comprising subjecting the textile material to a solution of alkali, then weighting the same by treatment with a tin salt, and then fixing the tin by treatment with a precipitating agent, whereby a textile material having a safe ironing point above 270 C. is produced. v
10. Method'of increasing the safe ironing point of a textile material containing cellu lose acetate comprising'subjectin the textile material to a solution of alkali, t en weight ing the same by treatment with a tannic acid solution, and then fixing thetannic acid compounds by treatment with a precipitating agent, whereby a textile material having a safe ironing point above 270 .C. is produced.
11. A textile material containing par-' tially saponified organic esters of cellulose, which'textile material is weighted with a weighting agent.
' 12.- A textile material'containing partially saponified cellu'lose acetate, which textile material is weighted 'with a weighting agent.
- 13. A textile material containing artially saponified organic estersof cell ose, which textile material is weighted with a tin compound.
14. A textile material containing partially saponified organic esters of cellulose, which textile materlal is weighted with a tannic acid compound.
15; A textile material containing partially saponified cellulose acetate, which textile material is weighted with a tin compound.
16. A textile material containing partially saponified cellulose acetate, which textile material isv weighted with a tin compound, saidtextile material having a safe ironing point above 270 C.
17. A textile material containing partially saponified cellulose acetate, -which" textile material is weighted with a tannic acid compound, said textile material having a safe ironing point above 270 C.
18. A textile material containing partially saponified cellulose acetate, which textile material is Weighted with a tin compound,
- said textile material having a safe ironing point between 280 and 285 C.
In testimony whereof, We have hereunto subscribed our names.
CAMILLE DREYFUS. WILLIAM R. BLUME.
US293781A 1928-07-18 1928-07-18 Textile material containing organic esters of cellulose and method of preparing the same Expired - Lifetime US1818466A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US293781A US1818466A (en) 1928-07-18 1928-07-18 Textile material containing organic esters of cellulose and method of preparing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US293781A US1818466A (en) 1928-07-18 1928-07-18 Textile material containing organic esters of cellulose and method of preparing the same

Publications (1)

Publication Number Publication Date
US1818466A true US1818466A (en) 1931-08-11

Family

ID=23130547

Family Applications (1)

Application Number Title Priority Date Filing Date
US293781A Expired - Lifetime US1818466A (en) 1928-07-18 1928-07-18 Textile material containing organic esters of cellulose and method of preparing the same

Country Status (1)

Country Link
US (1) US1818466A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3535141A (en) * 1967-04-17 1970-10-20 Deering Milliken Res Corp Process for making sail release synthetic textile
US3619251A (en) * 1969-05-22 1971-11-09 Norman S Stiles Sr Cleaning and polishing cloth and method of making it
US3649330A (en) * 1967-03-10 1972-03-14 Johnson & Johnson Composition containing metal salts and method of utilizing the same to control resin deposition

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3649330A (en) * 1967-03-10 1972-03-14 Johnson & Johnson Composition containing metal salts and method of utilizing the same to control resin deposition
US3535141A (en) * 1967-04-17 1970-10-20 Deering Milliken Res Corp Process for making sail release synthetic textile
US3619251A (en) * 1969-05-22 1971-11-09 Norman S Stiles Sr Cleaning and polishing cloth and method of making it

Similar Documents

Publication Publication Date Title
US2112499A (en) Treated artificial thread and method of producing same
US2173474A (en) Bleaching
US1736714A (en) Vegetable textile material and process for producing same
US2739034A (en) Permonosulfuric acid and sulphite treatment of wool and resulting product
US2205120A (en) Process for rendering cellulosecontaining material crease-resistant and products obtained thereby
US1818466A (en) Textile material containing organic esters of cellulose and method of preparing the same
US1998579A (en) Novel artificial silk effects and process of producing same
US2702737A (en) Wool chlorination process
US2144202A (en) Saponifying cellulose esters
US2860944A (en) Bleaching fibers of vegetable origin with formamidine sulfinate and alkaline peroxide
US2257716A (en) Method of bleaching fibers of vegetable origin
US2983568A (en) Bleaching peroxide impregnated cellulosic fabrics by contact with a dry heated body
US2497519A (en) Art of stabilizing rayon type fabric
US2903327A (en) Naoci-h2o2 cotton cloth bleaching
US2839353A (en) High speed peroxide textile bleaching process
US3056645A (en) Process of bleaching sized cotton fabrics
US1866153A (en) Partial saponification of cellulose ester material
US2189378A (en) Bleaching fibers and a composition therefor
US1897691A (en) Partial saponification of material containing organic esters of cellulose
US2469249A (en) Process of scouring cellulosic textiles using steam
US1802956A (en) Process of treating fabrics
US2505259A (en) Production of water-repellent textiles
US2220804A (en) Method of treating cellulosic fibrous materials
US3297399A (en) Process of mercerizing a cellulosic material while simultaneously depositing silica thereon
US2036862A (en) Textile process and product