US1936484A - Process for greasing textile fibers and fabrics - Google Patents
Process for greasing textile fibers and fabrics Download PDFInfo
- Publication number
- US1936484A US1936484A US609992A US60999232A US1936484A US 1936484 A US1936484 A US 1936484A US 609992 A US609992 A US 609992A US 60999232 A US60999232 A US 60999232A US 1936484 A US1936484 A US 1936484A
- Authority
- US
- United States
- Prior art keywords
- greasing
- materials
- carbon atoms
- fabrics
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 9
- 239000004744 fabric Substances 0.000 title description 3
- 239000004753 textile Substances 0.000 title description 3
- 239000000835 fiber Substances 0.000 title description 2
- 239000000463 material Substances 0.000 description 18
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- 150000002148 esters Chemical class 0.000 description 16
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 8
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 7
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- 239000002657 fibrous material Substances 0.000 description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- LSTDYDRCKUBPDI-UHFFFAOYSA-N palmityl acetate Chemical compound CCCCCCCCCCCCCCCCOC(C)=O LSTDYDRCKUBPDI-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 4
- 229910052740 iodine Inorganic materials 0.000 description 4
- 239000011630 iodine Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 229940049297 cetyl acetate Drugs 0.000 description 3
- 229960000541 cetyl alcohol Drugs 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 241000220438 Arachis Species 0.000 description 2
- 235000003911 Arachis Nutrition 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- -1 aliphatic alcohols Chemical class 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N alpha-n-hexadecene Natural products CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 235000019439 ethyl acetate Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/05—Organic amine, amide, or n-base containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
Definitions
- the present invention relates to the treatment of fibrous material and to improved greasing materials therefor.
- the principal object of the invention is to provide a fiber-greasing material which will have the desired lubricating and greasing effect and will have no deleterious effects upon the machinery and other apparatus used in working the 4 90 this purpose with varying success.
- Some greases used have been unsatisfactory in that they have not imparted satisfactory qualities to the yarn.
- Another of the difiiculties commonly encountered is that the greasing or lubricating materials attack the leather and metal parts of the machines used in the spinning, weaving and other processes.
- esters of practically saturated fatty alcohols of higher molecular weight and saturated fatty acids of low molecular weight have the necessary advantages without the disadvantages of materials previously used.
- These materials comprise the esters of the fatty acids having from 1 to 12 carbon atoms in the chain with aliphatic alcohols having 8 or more, usually 12 to 18 or 22 carbon atoms.
- the alcohols should be those of lowiodine value, the lower the better, preferably not exceeding 20. 4o Alcohols having from 12 to 18 carbon atoms are usually the most practical commercially, but those should be selected which are either saturated or at least have only one double bond in the carbon chain.
- esters eifectively grease and penetrate the fibers without causing damage to the machine parts. They are also easily removed especially if combined with emulsifying agents. These esters may be used alone but are preferably combined with emulsifying agents, especially such as alcohols of high molecular weight.
- soap materials including the sulphated and/or sulphonated derivatives of natural fats and oils easily soluble in the esters.
- a particularly effective emulsifying agent is produced by sulphating cetyl. alcohol and subsequently neutralizing the ester by triethanolamine or piperidine.
- Various other sulpho salts mentioned in co'-pending applications as constituting emulsifyin agents may be used as the emulsifying agents.
- the proportion of emulsifying material used may vary within wide limits. Usually it is added to the ester in a proportion of the order of ten percent, but as much as fifty per cent or even more is sometimes desirable.
- Example 1.100 kg. of worsted yarn are greased with 15 kg. of a mixture consisting of 90 parts of esters of propionic acid and lauryl alcohol and 10 parts of potassium soap of castor oil and then manufactured in the usual manner.
- Example 2.100 kg. of carded wool yarn are greased by 30 kg. .of a mixture consisting of parts of acetic esters of lauryl alcohol, 30 parts of cetyl acetate, and 5 parts of cetyl acid sulfate of piperidine, cwr-nzosoannmcmn.
- the goods 85 are greased thoroughly and well adapted for manufa'cturing.
- Example 325 kg. of a rag grease, consisting of 60 parts of cetyl acetate, 40 parts of arachis oil, and 10 parts of oleic acid triethanolamzine are added to 100 kg. of torn textile fabrics, and entirely torn by an opener.
- the method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 13 carbon atoms in the molecule and an aliphatic alcohol having 8 or more carbon atoms in the molecul and having an iodine value below 15.
- the method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule and having a low iodine value.
- the method of greasing fibrous materials which comprises treating the materials with an 110 ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule and having a low iodine value, and an emulsifying agent consisting of a mixture oi! a high molecular alcohol and a soap material easily soluble in the ester.
- the method of greasing flbrous materials which comprises treating the materials with an ester of a fatty acid of low molecular weight and an aliphatic alcohol 01 high molecular weight, above 8 carbon atoms, ahd an emulsifying agent obtained by suliating cetyl alcohol and neutralizing the product with triethanolam'inc onpiperidine.
- a composition of matter for treating flbrous materials comprising acetic esters of lauryl alcohol and cetyl alcohol and cetyl acid sulfate 8.
- a composition of matter for treating flbrous materials comprising cetyl acetate, arachis which comprises treating the materials with an ester of a fatty acid having lessthan 5 carbon atoms in the molecule and an aliphatic alcohol having 3 or more carbon-atoms in the molecule.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Patented Nov. 2 1, 1933 PROCESS FOR GREASING TEXTILE AND FABRICS Walther Schrauth, Berlin-Dahlem, Germany No Drawing. Application May 7, 1932, Serial No.
609,992, and in Germany May 3, 1930 12 Claims. (or. 19-66) The present invention relates to the treatment of fibrous material and to improved greasing materials therefor.
The principal object of the invention is to provide a fiber-greasing material which will have the desired lubricating and greasing effect and will have no deleterious effects upon the machinery and other apparatus used in working the 4 90 this purpose with varying success. Some greases used have been unsatisfactory in that they have not imparted satisfactory qualities to the yarn. Another of the difiiculties commonly encountered is that the greasing or lubricating materials attack the leather and metal parts of the machines used in the spinning, weaving and other processes.
According to the present invention it has been discovered that certain synthetic esters of practically saturated fatty alcohols of higher molecular weight and saturated fatty acids of low molecular weight have the necessary advantages without the disadvantages of materials previously used. These materials comprise the esters of the fatty acids having from 1 to 12 carbon atoms in the chain with aliphatic alcohols having 8 or more, usually 12 to 18 or 22 carbon atoms. The alcohols should be those of lowiodine value, the lower the better, preferably not exceeding 20. 4o Alcohols having from 12 to 18 carbon atoms are usually the most practical commercially, but those should be selected which are either saturated or at least have only one double bond in the carbon chain. Commercial alcohols, as for example the cetyl alcohol, which is a mixture of different alcohols, when esterified with acetic acid provide satisfactory products which can be economically produced. Commercially the acids having from 1 to 4' carbon atoms in the chain are preferable and more practicable. These esters eifectively grease and penetrate the fibers without causing damage to the machine parts. They are also easily removed especially if combined with emulsifying agents. These esters may be used alone but are preferably combined with emulsifying agents, especially such as alcohols of high molecular weight.
(preferably saturated) and soap materials including the sulphated and/or sulphonated derivatives of natural fats and oils easily soluble in the esters.
A particularly effective emulsifying agent is produced by sulphating cetyl. alcohol and subsequently neutralizing the ester by triethanolamine or piperidine. Various other sulpho salts mentioned in co'-pending applications as constituting emulsifyin agents may be used as the emulsifying agents.
The proportion of emulsifying material used may vary within wide limits. Usually it is added to the ester in a proportion of the order of ten percent, but as much as fifty per cent or even more is sometimes desirable.
The invention will be better understood from a consideration of specific examples.
Example 1.100 kg. of worsted yarn are greased with 15 kg. of a mixture consisting of 90 parts of esters of propionic acid and lauryl alcohol and 10 parts of potassium soap of castor oil and then manufactured in the usual manner.
Example 2.100 kg. of carded wool yarn are greased by 30 kg. .of a mixture consisting of parts of acetic esters of lauryl alcohol, 30 parts of cetyl acetate, and 5 parts of cetyl acid sulfate of piperidine, cwr-nzosoannmcmn. The goods 85 are greased thoroughly and well adapted for manufa'cturing.
1 Example 3.25 kg. of a rag grease, consisting of 60 parts of cetyl acetate, 40 parts of arachis oil, and 10 parts of oleic acid triethanolamzine are added to 100 kg. of torn textile fabrics, and entirely torn by an opener.
The foregoing particular description is illustrative merely and is not intended as defining the limits of the invention.
I claim:
1. The method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 13 carbon atoms in the molecule and an aliphatic alcohol having 8 or more carbon atoms in the molecul and having an iodine value below 15.
2. The method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule and having a low iodine value.
3. The method of greasing fibrous materials which comprises treating the materials with an 110 ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule and having a low iodine value, and an emulsifying agent consisting of a mixture oi! a high molecular alcohol and a soap material easily soluble in the ester.
4. The method of greasing flbrous materials which comprises treating the materials with an ester of a fatty acid of low molecular weight and an aliphatic alcohol 01 high molecular weight, above 8 carbon atoms, ahd an emulsifying agent obtained by suliating cetyl alcohol and neutralizing the product with triethanolam'inc onpiperidine.
5. The method or greasing fibrous materials which comprises treating the materials, with an ester oi a fatty acid of low molecular weight and an aliphatic alcohol 01' high molecular weight, above '8 carbon atoms, and potassium soap 0i castor oil- I 6. The method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule of piperidine.
and having a low iodine value, and potassium soapoi castor oil. 1
7. A composition of matter for treating flbrous materials comprising acetic esters of lauryl alcohol and cetyl alcohol and cetyl acid sulfate 8. A composition of matter for treating flbrous materials comprising cetyl acetate, arachis which comprises treating the materials with an ester of a fatty acid having lessthan 5 carbon atoms in the molecule and an aliphatic alcohol having 3 or more carbon-atoms in the molecule.
WALTEZER SCHIRAUTH, x
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE562921T | 1930-05-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1936484A true US1936484A (en) | 1933-11-21 |
Family
ID=34559076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US609992A Expired - Lifetime US1936484A (en) | 1930-05-04 | 1932-05-07 | Process for greasing textile fibers and fabrics |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US1936484A (en) |
| DE (1) | DE562921C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE767554C (en) * | 1939-03-25 | 1952-12-22 | Kurmaerkische Zellwolle | Process for achieving a permanent, crunchy grip and for simultaneous melting of fiber material made from regenerated cellulose |
| DE852389C (en) * | 1948-11-26 | 1952-10-13 | Herberts & Co Gmbh Dr Kurt | Preparations for treating textiles |
-
1930
- 1930-05-04 DE DE1930562921D patent/DE562921C/en not_active Expired
-
1932
- 1932-05-07 US US609992A patent/US1936484A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE562921C (en) | 1934-01-15 |
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