US1936484A - Process for greasing textile fibers and fabrics - Google Patents

Process for greasing textile fibers and fabrics Download PDF

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Publication number
US1936484A
US1936484A US609992A US60999232A US1936484A US 1936484 A US1936484 A US 1936484A US 609992 A US609992 A US 609992A US 60999232 A US60999232 A US 60999232A US 1936484 A US1936484 A US 1936484A
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Prior art keywords
greasing
materials
carbon atoms
fabrics
ester
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US609992A
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Schrauth Walther
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40Reduced friction resistance, lubricant properties; Sizing compositions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/03Organic sulfoxy compound containing
    • Y10S516/05Organic amine, amide, or n-base containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core

Definitions

  • the present invention relates to the treatment of fibrous material and to improved greasing materials therefor.
  • the principal object of the invention is to provide a fiber-greasing material which will have the desired lubricating and greasing effect and will have no deleterious effects upon the machinery and other apparatus used in working the 4 90 this purpose with varying success.
  • Some greases used have been unsatisfactory in that they have not imparted satisfactory qualities to the yarn.
  • Another of the difiiculties commonly encountered is that the greasing or lubricating materials attack the leather and metal parts of the machines used in the spinning, weaving and other processes.
  • esters of practically saturated fatty alcohols of higher molecular weight and saturated fatty acids of low molecular weight have the necessary advantages without the disadvantages of materials previously used.
  • These materials comprise the esters of the fatty acids having from 1 to 12 carbon atoms in the chain with aliphatic alcohols having 8 or more, usually 12 to 18 or 22 carbon atoms.
  • the alcohols should be those of lowiodine value, the lower the better, preferably not exceeding 20. 4o Alcohols having from 12 to 18 carbon atoms are usually the most practical commercially, but those should be selected which are either saturated or at least have only one double bond in the carbon chain.
  • esters eifectively grease and penetrate the fibers without causing damage to the machine parts. They are also easily removed especially if combined with emulsifying agents. These esters may be used alone but are preferably combined with emulsifying agents, especially such as alcohols of high molecular weight.
  • soap materials including the sulphated and/or sulphonated derivatives of natural fats and oils easily soluble in the esters.
  • a particularly effective emulsifying agent is produced by sulphating cetyl. alcohol and subsequently neutralizing the ester by triethanolamine or piperidine.
  • Various other sulpho salts mentioned in co'-pending applications as constituting emulsifyin agents may be used as the emulsifying agents.
  • the proportion of emulsifying material used may vary within wide limits. Usually it is added to the ester in a proportion of the order of ten percent, but as much as fifty per cent or even more is sometimes desirable.
  • Example 1.100 kg. of worsted yarn are greased with 15 kg. of a mixture consisting of 90 parts of esters of propionic acid and lauryl alcohol and 10 parts of potassium soap of castor oil and then manufactured in the usual manner.
  • Example 2.100 kg. of carded wool yarn are greased by 30 kg. .of a mixture consisting of parts of acetic esters of lauryl alcohol, 30 parts of cetyl acetate, and 5 parts of cetyl acid sulfate of piperidine, cwr-nzosoannmcmn.
  • the goods 85 are greased thoroughly and well adapted for manufa'cturing.
  • Example 325 kg. of a rag grease, consisting of 60 parts of cetyl acetate, 40 parts of arachis oil, and 10 parts of oleic acid triethanolamzine are added to 100 kg. of torn textile fabrics, and entirely torn by an opener.
  • the method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 13 carbon atoms in the molecule and an aliphatic alcohol having 8 or more carbon atoms in the molecul and having an iodine value below 15.
  • the method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule and having a low iodine value.
  • the method of greasing fibrous materials which comprises treating the materials with an 110 ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule and having a low iodine value, and an emulsifying agent consisting of a mixture oi! a high molecular alcohol and a soap material easily soluble in the ester.
  • the method of greasing flbrous materials which comprises treating the materials with an ester of a fatty acid of low molecular weight and an aliphatic alcohol 01 high molecular weight, above 8 carbon atoms, ahd an emulsifying agent obtained by suliating cetyl alcohol and neutralizing the product with triethanolam'inc onpiperidine.
  • a composition of matter for treating flbrous materials comprising acetic esters of lauryl alcohol and cetyl alcohol and cetyl acid sulfate 8.
  • a composition of matter for treating flbrous materials comprising cetyl acetate, arachis which comprises treating the materials with an ester of a fatty acid having lessthan 5 carbon atoms in the molecule and an aliphatic alcohol having 3 or more carbon-atoms in the molecule.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Patented Nov. 2 1, 1933 PROCESS FOR GREASING TEXTILE AND FABRICS Walther Schrauth, Berlin-Dahlem, Germany No Drawing. Application May 7, 1932, Serial No.
609,992, and in Germany May 3, 1930 12 Claims. (or. 19-66) The present invention relates to the treatment of fibrous material and to improved greasing materials therefor.
The principal object of the invention is to provide a fiber-greasing material which will have the desired lubricating and greasing effect and will have no deleterious effects upon the machinery and other apparatus used in working the 4 90 this purpose with varying success. Some greases used have been unsatisfactory in that they have not imparted satisfactory qualities to the yarn. Another of the difiiculties commonly encountered is that the greasing or lubricating materials attack the leather and metal parts of the machines used in the spinning, weaving and other processes.
According to the present invention it has been discovered that certain synthetic esters of practically saturated fatty alcohols of higher molecular weight and saturated fatty acids of low molecular weight have the necessary advantages without the disadvantages of materials previously used. These materials comprise the esters of the fatty acids having from 1 to 12 carbon atoms in the chain with aliphatic alcohols having 8 or more, usually 12 to 18 or 22 carbon atoms. The alcohols should be those of lowiodine value, the lower the better, preferably not exceeding 20. 4o Alcohols having from 12 to 18 carbon atoms are usually the most practical commercially, but those should be selected which are either saturated or at least have only one double bond in the carbon chain. Commercial alcohols, as for example the cetyl alcohol, which is a mixture of different alcohols, when esterified with acetic acid provide satisfactory products which can be economically produced. Commercially the acids having from 1 to 4' carbon atoms in the chain are preferable and more practicable. These esters eifectively grease and penetrate the fibers without causing damage to the machine parts. They are also easily removed especially if combined with emulsifying agents. These esters may be used alone but are preferably combined with emulsifying agents, especially such as alcohols of high molecular weight.
(preferably saturated) and soap materials including the sulphated and/or sulphonated derivatives of natural fats and oils easily soluble in the esters.
A particularly effective emulsifying agent is produced by sulphating cetyl. alcohol and subsequently neutralizing the ester by triethanolamine or piperidine. Various other sulpho salts mentioned in co'-pending applications as constituting emulsifyin agents may be used as the emulsifying agents.
The proportion of emulsifying material used may vary within wide limits. Usually it is added to the ester in a proportion of the order of ten percent, but as much as fifty per cent or even more is sometimes desirable.
The invention will be better understood from a consideration of specific examples.
Example 1.100 kg. of worsted yarn are greased with 15 kg. of a mixture consisting of 90 parts of esters of propionic acid and lauryl alcohol and 10 parts of potassium soap of castor oil and then manufactured in the usual manner.
Example 2.100 kg. of carded wool yarn are greased by 30 kg. .of a mixture consisting of parts of acetic esters of lauryl alcohol, 30 parts of cetyl acetate, and 5 parts of cetyl acid sulfate of piperidine, cwr-nzosoannmcmn. The goods 85 are greased thoroughly and well adapted for manufa'cturing.
1 Example 3.25 kg. of a rag grease, consisting of 60 parts of cetyl acetate, 40 parts of arachis oil, and 10 parts of oleic acid triethanolamzine are added to 100 kg. of torn textile fabrics, and entirely torn by an opener.
The foregoing particular description is illustrative merely and is not intended as defining the limits of the invention.
I claim:
1. The method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 13 carbon atoms in the molecule and an aliphatic alcohol having 8 or more carbon atoms in the molecul and having an iodine value below 15.
2. The method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule and having a low iodine value.
3. The method of greasing fibrous materials which comprises treating the materials with an 110 ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule and having a low iodine value, and an emulsifying agent consisting of a mixture oi! a high molecular alcohol and a soap material easily soluble in the ester.
4. The method of greasing flbrous materials which comprises treating the materials with an ester of a fatty acid of low molecular weight and an aliphatic alcohol 01 high molecular weight, above 8 carbon atoms, ahd an emulsifying agent obtained by suliating cetyl alcohol and neutralizing the product with triethanolam'inc onpiperidine.
5. The method or greasing fibrous materials which comprises treating the materials, with an ester oi a fatty acid of low molecular weight and an aliphatic alcohol 01' high molecular weight, above '8 carbon atoms, and potassium soap 0i castor oil- I 6. The method of greasing fibrous materials which comprises treating the materials with an ester of a fatty acid having less than 5 carbon atoms in the molecule and an aliphatic alcohol having 12 to 18 carbon atoms in the molecule of piperidine.
and having a low iodine value, and potassium soapoi castor oil. 1
7. A composition of matter for treating flbrous materials comprising acetic esters of lauryl alcohol and cetyl alcohol and cetyl acid sulfate 8. A composition of matter for treating flbrous materials comprising cetyl acetate, arachis which comprises treating the materials with an ester of a fatty acid having lessthan 5 carbon atoms in the molecule and an aliphatic alcohol having 3 or more carbon-atoms in the molecule.
WALTEZER SCHIRAUTH, x
US609992A 1930-05-04 1932-05-07 Process for greasing textile fibers and fabrics Expired - Lifetime US1936484A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE767554C (en) * 1939-03-25 1952-12-22 Kurmaerkische Zellwolle Process for achieving a permanent, crunchy grip and for simultaneous melting of fiber material made from regenerated cellulose
DE852389C (en) * 1948-11-26 1952-10-13 Herberts & Co Gmbh Dr Kurt Preparations for treating textiles

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