US20020006879A1 - Roller bearing - Google Patents
Roller bearing Download PDFInfo
- Publication number
- US20020006879A1 US20020006879A1 US09/199,447 US19944798A US2002006879A1 US 20020006879 A1 US20020006879 A1 US 20020006879A1 US 19944798 A US19944798 A US 19944798A US 2002006879 A1 US2002006879 A1 US 2002006879A1
- Authority
- US
- United States
- Prior art keywords
- acid
- oil
- rolling elements
- bearing
- fretting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000005096 rolling process Methods 0.000 claims abstract description 38
- 239000010687 lubricating oil Substances 0.000 claims abstract description 32
- 239000003921 oil Substances 0.000 claims abstract description 28
- 239000004519 grease Substances 0.000 claims abstract description 23
- 229910000831 Steel Inorganic materials 0.000 claims description 16
- 239000010959 steel Substances 0.000 claims description 16
- 229910045601 alloy Inorganic materials 0.000 claims description 7
- 239000000956 alloy Substances 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 7
- 230000002411 adverse Effects 0.000 abstract description 3
- 239000002253 acid Substances 0.000 description 24
- 239000003795 chemical substances by application Substances 0.000 description 24
- 230000007797 corrosion Effects 0.000 description 16
- 238000005260 corrosion Methods 0.000 description 16
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 230000036316 preload Effects 0.000 description 12
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 12
- -1 methyl acetyl Chemical group 0.000 description 11
- 230000002265 prevention Effects 0.000 description 11
- 230000001050 lubricating effect Effects 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000010696 ester oil Substances 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 229910052581 Si3N4 Inorganic materials 0.000 description 5
- 230000001133 acceleration Effects 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 5
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000002199 base oil Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- KHAVLLBUVKBTBG-UHFFFAOYSA-N dec-9-enoic acid Chemical compound OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 3
- 229940100539 dibutyl adipate Drugs 0.000 description 3
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 3
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
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- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- OAVQPLHPMFCMCD-UHFFFAOYSA-J C(N)([O-])=O.[W+4].C(N)([O-])=O.C(N)([O-])=O.C(N)([O-])=O Chemical compound C(N)([O-])=O.[W+4].C(N)([O-])=O.C(N)([O-])=O.C(N)([O-])=O OAVQPLHPMFCMCD-UHFFFAOYSA-J 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- UWHZIFQPPBDJPM-FPLPWBNLSA-M Vaccenic acid Natural products CCCCCC\C=C/CCCCCCCCCC([O-])=O UWHZIFQPPBDJPM-FPLPWBNLSA-M 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229940031769 diisobutyl adipate Drugs 0.000 description 2
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- GRPIQKZLNSCFTB-UHFFFAOYSA-N n-[bis(dimethylamino)-fluoroimino-$l^{5}-phosphanyl]-n-methylmethanamine Chemical compound CN(C)P(=NF)(N(C)C)N(C)C GRPIQKZLNSCFTB-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- NNBVENKHQFPYCW-UHFFFAOYSA-N 1-(3,5-ditert-butyl-4-hydroxyphenyl)-2-phenylethane-1,2-dione Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(C(=O)C(=O)C=2C=CC=CC=2)=C1 NNBVENKHQFPYCW-UHFFFAOYSA-N 0.000 description 1
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
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- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
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- LLLUKUXKUSKFLO-UHFFFAOYSA-N 2-[[2-hydroxy-5-methyl-3-(2,4,4-trimethylpentan-2-yl)phenyl]methyl]-4-methyl-6-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)CC(C)(C)C)O)=C1O LLLUKUXKUSKFLO-UHFFFAOYSA-N 0.000 description 1
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- DBOSBRHMHBENLP-UHFFFAOYSA-N 4-tert-Butylphenyl Salicylate Chemical compound C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC=CC=C1O DBOSBRHMHBENLP-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical group CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
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- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
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Images
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Definitions
- This invention relates to a roller bearing, and particularly to a roller bearing in a bearing for a spindle which is a portion of the constituent parts of various motors or the like and which is excellent in bearing characteristic and is greatly mitigated in fretting corrosion created by repeated shock and swing attributable to extraneous vibration as during conveyance.
- a bearing for a spindle directed to low torque may suffer from the possibility of creating fretting corrosion on the raceway surfaces of the outer race and inner race thereof and the contact surfaces of the rolling elements thereof because the quantity of grease is small and moreover the strength of oil film is low in lubricating oil of low dynamic viscosity.
- the present invention has been made in order to prevent the creation of fretting corrosion which may be created in a bearing for a spindle during the conveyance of various motors as noted above, and the object thereof is to provide a fretting-resisting roller bearing which is not adversely affected in its characteristics and achieves a higher temperature and a higher speed as well as a longer life.
- the roller bearing of the present invention is a roller bearing comprised of a plurality of rolling elements held between an inner race and an outer race with a cage interposed therebetween, characterized in that the oil film of lubricating oil of which the dynamic viscosity at 40° C. is 20 to 150 mm 2 /s is formed on the raceway surfaces of the inner and outer races, the cage and the rolling elements and grease is enclosed.
- the roller bearing of the present invention is heightened in the dynamic viscosity of the lubricating oil and the strength of the oil film with a view to improve the fretting-resisting property during the conveyance of various motors.
- the rolling elements are made of ceramics or a super-hard alloy of which the Vickers hardness is 1300 or greater, and the outer race and inner race are made of steel, and a material differing from that of the outer race and inner race is used as the material of the rolling elements and the hardness thereof is increased, whereby not only fretting corrosion can be suppressed by the prevention of the adhesion phenomenon between the members (the raceway surfaces of the outer and inner races and the rolling elements) and the decrease in Hertzian contact area due to the difference in Young's modulus, but also a good function is obtained even under use conditions of high temperature and high-speed rotation.
- FIG. 1 is a graph showing the acceleration signal execution values of each embodiment and each comparative example.
- FIG. 2 is a graph showing the rotation torques of each embodiment and each comparative example.
- the fretting-resisting roller bearing of the present invention is a roller bearing comprised of a plurality of rolling elements held between an inner race and an outer race with a cage interposed therebetween, wherein the oil film of lubricating oil of which the dynamic viscosity at 40° C. is 20 to 150 mm 2 /s is formed on the raceway surfaces of the inner and outer races, the cage and the rolling elements, and grease is enclosed.
- the dynamic viscosity of the lubricating oil at 40° C. is less than 20 mm 2 /s, the strength of the oil film is low and fretting corrosion is liable to be created by extraneous vibrations.
- the dynamic viscosity at 40° C. is higher than 150 mm 2 /s, rotation torque increases because the dynamic viscosity of the lubricating oil is high.
- the dynamic viscosity at 40° C. be 40 mm2/s or greater.
- the lubricant composition used as the lubricating oil is not particularly limited, it may be composed of base oil and various additives mentioned below, whereby there is formed lubricating oil film having a fretting-resisting property and a rust prevention property and suitable for use at a high temperatures and high speeds.
- the composition of the additives can be selected in accordance with using conditions of bearings if control of fretting corrosion is maintained and functions of anti-rust properties and additional properties can be combined in need.
- the lubricant oil may be anti-rust lubricant oil combined with the rust prevention agent, which has high anti-rust properties.
- ester oil use may preferably be made of diester oil obtained from the reaction of dibasic acid and branch alcohol, aromatic ester oil obtained from the reaction of aromatic tribasic acid and branch alcohol, or hindered ester oil obtained from the reaction of polyatomic alcohol and monobasic acid.
- diester oil mention may be made of dioctyl adipate (DOA), diisobutyl adipate (DIBA), dibutyl adipate (DBA), dioctyl azelate (DOZ), dibutyl sebacate (DBA), dioctyl sebacate (DOS), methyl acetyl recinolate (MAR-N) or the like.
- DOA dioctyl adipate
- DIBA diisobutyl adipate
- DBA dibutyl adipate
- DOZ dioctyl azelate
- DBA dioctyl sebacate
- DOS dioctyl sebacate
- MAR-N methyl acetyl recinolate
- aromatic ester oil mention may be made of trimellitic acid ester, trioctyl trimellitate (TOTM), tridecyl trimellitate, tetraoctyl pyromellitate or the like.
- hindered ester oil mention may be made of one obtained by polyatomic alcohol and monobasic acid shown below being suitably reacted with each other.
- Monobasic acid to be reacted with polyatomic alcohol may be single or plural. Further, it may be used as complex ester which is oligoester of polyatomic alcohol and mixed aliphatic acid of dibasic acid and monobasic acid.
- TMP trimethylol propane
- PE pentaerythritol
- DPE dipentaerythritol
- NPG neopentyl glycol
- MPPD 2-methyl-2-propyl-1,3-propane
- monobasic acid use is made chiefly of univalent aliphatic acid of C 4 to C 18 . Specifically, mention may be made of acetic acid, valerianic acid, caproic acid, caprylic acid, enanthic acid, pelargonic acid, capric acid, undecanic acid, laurylic acid, mistiric acid, palmitic acid, beef fatty acid, stearic acid, caproleic acid, undecylenic acid, linder acid, tudu acid, fiseterinic acid, milistolenic acid, palmitoleic acid, petroserine acid, oleic acid, elaiolic acid, asclepic acid, vaccenic acid, sorbic acid, linoleic acid, linolenic acid, sabineic acid, recinoleic acid, or the like.
- phenyl ether oil in which (di)alkyl chain of C 12 to C 20 of disphenyl, tripheyl and tetraphenyl was derived.
- ester oil be chosen from aromatic ester oil and hindered ester oil and be used singly or mixedly. Particularly TOTM is readily available and is excellent in a low evaporating property, a lubricating property, etc. Also, (di)alkyl polyphenyl ether oil is preferable as ether oil. Fluorophosphazene oil can also be suitably used.
- Organic sulfonic acid metal or ester is preferable as a rust prevention agent.
- organic sulfonic acid salt use is made, for example, of dinonyl naphthalene sulfonic acid and heavy alkyl benzene sulfonic acid, and as the metal salt thereof, there is calcium sulfonate, barium sulfonate, sodium sulfonate or the like.
- ester in sorbitan derivative, there is sorbitan monolaurate, sorbitan tristearate, sorbitan monooleate, sorbitan trioleate or the like as the partial ester of polybasic carboxylic acid and polyatomic alcohol.
- alkyl ester type there is polyoxyethylene laurate, polyoxyethylene oleate, polyoxyethylene stearate or the like.
- organic sulfonic acid metal salt and ester can be used singly or as a mixture.
- ester polyoxyethylene sorbitan laurate is high in dissolving property and is suitably used as sulfonic acid metallic salt such as calcium sulfonate, and fluorophosphazene oil.
- oxidation preventing agent a nitrogen containing compound oxidation preventing agent and a phenol oxidation preventing agent may preferably be used singly or as a mixture.
- the nitrogen containing compound oxidation preventing agent there is phenyl ⁇ naphthylamine, diphenylamine, phenylene diamine, oleyl amideamine, phenothiazine or the like.
- phenol oxidation preventing agent there is hindered phenol such as p-t-butyl-phenyl salicylate, 2,6-di-t-butyl-p-phenyl phenol, 2,2′-methylenebis-(4-methyl-6-t-octyl phenol), 4,4′-butyrydenbis-6-t-butyl-m-cresol, tetrakis[methylene-3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionate]methane, 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxylbenzil)benzene, n-octadecyl- ⁇ -(4′-hydroxy-3′,5′-di-t-butylphenyl)propionate, 2-n-octylthio-4,6-di(4′-hydroxy-3′,5′-di
- organic metallic salt such as molybdenum thiocarbamate, molybdenum dithio phosphate, zinc diocarbamate, zinc dithiophosphate or the like.
- phosphoric acid ester As a corrosion preventing agent, mention may be made of phosphoric acid ester, phosphorous acid ester or the like. Particularly, molybdenum dithiocarbamate and phosphorous acid ester exhibit an excellent effect in the fretting resisting property and can therefore be suitably used.
- a friction preventing agent, a viscosity index improving agent or the like may be contained in the lubricating oil. These may all be conventional agents.
- a thickness may be a conventional one such as metallic soap or urea resin, but from the viewpoint of the characteristic of the bearing for a spindle, lithium soap having an excellent characteristic in acoustic life is preferable.
- the contacting portions of the raceway surfaces of the outer and inner races and the rolling elements are the same material or different materials, and when different materials are used, they are steel and ceramics or steel and a super-hard alloy. If the lubricating oil in the present invention is used, the fretting corrosion will be greatly mitigated, and further, under an environment of severe vibration condition, different materials may be small in the frictional force acting on the contacting portions as compared with steel and steel, and in these contacting portions, it is more difficult for such an injury which will lead to fretting corrosion to occur.
- the material forming the rolling elements may be silicon nitride, zirconia, alumina or the like, and in the case of a super-high alloy, the material forming the rolling elements may be tungsten carbide or the like.
- the friction characteristic on the contacting portions of the raceways of the outer and inner races made of steel and the rolling surfaces of the rolling elements made of ceramics or a super-hard alloy is improved as compared with the friction characteristic when steel and steel contact with each other, even if the combination of different materials is steel and ceramics or steel and a super-hard alloy.
- the combination of bearing steel and silicon nitride, stainless steel and silicon nitride, bearing steel and zirconia, bearing steel and tungsten carbamate, or stainless steel and tungsten carbamate provides an excellent friction characteristic (a low friction characteristic) and is excellent in the fretting resisting property.
- a heretofore used bearing specification [Comparative Example 1] was subjected to a swing test, and comparison evaluation was effected with the bearing radial direction acceleration signal execution value after the test being 100%.
- test conditions of each embodiment and each comparative example are as follows:
- the oil film of lubricating oil having high dynamic viscosity is formed on the raceway surfaces of the inner and outer races, the cage and the rolling elements and therefore, there can be provided a fretting-resisting roller bearing in which the strength of the oil film is high and the fretting-resisting property during conveyance is improved and also the various characteristics of the bearing are not adversely affected and which achieves a higher temperature and a higher speed as well as a longer life.
- the material of the rolling elements is ceramics or a super-hard alloy of Vickers hardness 1300 or greater and the outer and inner races are made of steel and a material differing from the material of the outer and inner races is used as the material of the rolling elements, the hardness thereof is increased, whereby not only fretting corrosion can be suppressed by the prevention of the adhesion phenomenon between the members (the raceway surfaces of the outer and inner races and the rolling elements) and the decrease in the Hertzian contact area by the difference in Young's modulus, but also the bearing functions well even under the use conditions of high temperatures and high-speed rotation.
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Abstract
This invention relates to a fretting-resisting roller bearing of which the various characteristics are not adversely affected and which achieves a higher temperature and a higher speed as well as a longer life. In a roller bearing comprised of a plurality of rolling elements held between inner and outer races with a cage interposed therebetween, the oil film of lubricating oil of which the dynamic viscosity at 40° C. is 20 to 150 mm2/s is formed on the raceway surfaces of the inner and outer races, the cage and the rolling elements and grease is enclosed.
Description
- 1. Field of the Invention
- This invention relates to a roller bearing, and particularly to a roller bearing in a bearing for a spindle which is a portion of the constituent parts of various motors or the like and which is excellent in bearing characteristic and is greatly mitigated in fretting corrosion created by repeated shock and swing attributable to extraneous vibration as during conveyance.
- 2. Related Background Art
- The industry related to electrical instruments is high in the speed of technological innovation as compared with the other industrial fields. The available periods of types of machines are short and moreover, new types of machines having introduced new techniques (smaller electric power consumption, higher responsiveness, higher accuracy, compactness, etc.) are developed one after another.
- Now, the bearings for the spindles of various motors or the like have been made higher in speed with the development of the new types of machines as described above and lower torque has come to be required of them for the purpose of smaller electric power consumption. In the roller bearings used for the spindles according to the prior art, there have been adopted a lubricating system filled with grease, and a method of applying lubricating oil to the raceway surface or the like of the bearing and further enclose grease therein. At present, for the purpose of lower torque resulting from the requirement for smaller electric power consumption as described above, an amount of grease is less, and as lubricating oil applied to the raceway surface or the like of the bearing, many lubricating oils of low dynamic viscosity (dynamic viscosity of 5 to 15 mm 2/s at 40° C.) are used for rust prevention and in the low torque.
- Now, the inland conveyance of various motors often takes place on land, and they are transported under environment apt to be subjected to extraneous vibrations. By these extraneous vibrations, the bearings for the spindles suffer from axial excitation, or repeated circumferential swing depending on the way in which the instruments are placed.
- When such axial vibration or circumferential swinging movement is repeated, a bearing for a spindle directed to low torque may suffer from the possibility of creating fretting corrosion on the raceway surfaces of the outer race and inner race thereof and the contact surfaces of the rolling elements thereof because the quantity of grease is small and moreover the strength of oil film is low in lubricating oil of low dynamic viscosity.
- The creation of fretting corrosion may result in an increase in the sound and vibration of the bearing and may also pose a serious problem in a further improvement in required accuracy.
- So, the present invention has been made in order to prevent the creation of fretting corrosion which may be created in a bearing for a spindle during the conveyance of various motors as noted above, and the object thereof is to provide a fretting-resisting roller bearing which is not adversely affected in its characteristics and achieves a higher temperature and a higher speed as well as a longer life.
- To achieve the above object, the roller bearing of the present invention is a roller bearing comprised of a plurality of rolling elements held between an inner race and an outer race with a cage interposed therebetween, characterized in that the oil film of lubricating oil of which the dynamic viscosity at 40° C. is 20 to 150 mm 2/s is formed on the raceway surfaces of the inner and outer races, the cage and the rolling elements and grease is enclosed.
- The roller bearing of the present invention is heightened in the dynamic viscosity of the lubricating oil and the strength of the oil film with a view to improve the fretting-resisting property during the conveyance of various motors.
- Also, for example, the rolling elements are made of ceramics or a super-hard alloy of which the Vickers hardness is 1300 or greater, and the outer race and inner race are made of steel, and a material differing from that of the outer race and inner race is used as the material of the rolling elements and the hardness thereof is increased, whereby not only fretting corrosion can be suppressed by the prevention of the adhesion phenomenon between the members (the raceway surfaces of the outer and inner races and the rolling elements) and the decrease in Hertzian contact area due to the difference in Young's modulus, but also a good function is obtained even under use conditions of high temperature and high-speed rotation.
- FIG. 1 is a graph showing the acceleration signal execution values of each embodiment and each comparative example.
- FIG. 2 is a graph showing the rotation torques of each embodiment and each comparative example.
- Some embodiments of the fretting-resisting roller bearing of the present invention will hereinafter be described in detail.
- The fretting-resisting roller bearing of the present invention is a roller bearing comprised of a plurality of rolling elements held between an inner race and an outer race with a cage interposed therebetween, wherein the oil film of lubricating oil of which the dynamic viscosity at 40° C. is 20 to 150 mm 2/s is formed on the raceway surfaces of the inner and outer races, the cage and the rolling elements, and grease is enclosed.
- When the dynamic viscosity of the lubricating oil at 40° C. is less than 20 mm 2/s, the strength of the oil film is low and fretting corrosion is liable to be created by extraneous vibrations. When conversely, the dynamic viscosity at 40° C. is higher than 150 mm2/s, rotation torque increases because the dynamic viscosity of the lubricating oil is high. Further, to reduce fretting corrosion, it is preferable that the dynamic viscosity at 40° C. be 40 mm2/s or greater.
- While the lubricant composition used as the lubricating oil is not particularly limited, it may be composed of base oil and various additives mentioned below, whereby there is formed lubricating oil film having a fretting-resisting property and a rust prevention property and suitable for use at a high temperatures and high speeds. In the embodiments as described hereinafter, the composition of the additives can be selected in accordance with using conditions of bearings if control of fretting corrosion is maintained and functions of anti-rust properties and additional properties can be combined in need. Particularly, if the higher anti-rust properties are required under some using conditions, preferably the lubricant oil may be anti-rust lubricant oil combined with the rust prevention agent, which has high anti-rust properties.
- Regarding the base oil, as ester oil, use may preferably be made of diester oil obtained from the reaction of dibasic acid and branch alcohol, aromatic ester oil obtained from the reaction of aromatic tribasic acid and branch alcohol, or hindered ester oil obtained from the reaction of polyatomic alcohol and monobasic acid.
- As diester oil, mention may be made of dioctyl adipate (DOA), diisobutyl adipate (DIBA), dibutyl adipate (DBA), dioctyl azelate (DOZ), dibutyl sebacate (DBA), dioctyl sebacate (DOS), methyl acetyl recinolate (MAR-N) or the like.
- As aromatic ester oil, mention may be made of trimellitic acid ester, trioctyl trimellitate (TOTM), tridecyl trimellitate, tetraoctyl pyromellitate or the like.
- As hindered ester oil, mention may be made of one obtained by polyatomic alcohol and monobasic acid shown below being suitably reacted with each other. Monobasic acid to be reacted with polyatomic alcohol may be single or plural. Further, it may be used as complex ester which is oligoester of polyatomic alcohol and mixed aliphatic acid of dibasic acid and monobasic acid.
- As polyatomic alcohol, mention may be made of trimethylol propane (TMP), pentaerythritol (PE), dipentaerythritol (DPE), neopentyl glycol (NPG), 2-methyl-2-propyl-1,3-propane (MPPD) or the like.
- As monobasic acid, use is made chiefly of univalent aliphatic acid of C 4 to C18. Specifically, mention may be made of acetic acid, valerianic acid, caproic acid, caprylic acid, enanthic acid, pelargonic acid, capric acid, undecanic acid, laurylic acid, mistiric acid, palmitic acid, beef fatty acid, stearic acid, caproleic acid, undecylenic acid, linder acid, tudu acid, fiseterinic acid, milistolenic acid, palmitoleic acid, petroserine acid, oleic acid, elaiolic acid, asclepic acid, vaccenic acid, sorbic acid, linoleic acid, linolenic acid, sabineic acid, recinoleic acid, or the like.
- As synthetic hydrocarbon oil, there is phenyl ether oil in which (di)alkyl chain of C 12 to C20 of disphenyl, tripheyl and tetraphenyl was derived.
- Taking lower evaporation and longer life into account, it is preferable that ester oil be chosen from aromatic ester oil and hindered ester oil and be used singly or mixedly. Particularly TOTM is readily available and is excellent in a low evaporating property, a lubricating property, etc. Also, (di)alkyl polyphenyl ether oil is preferable as ether oil. Fluorophosphazene oil can also be suitably used.
- Also, by adding additives such as rust prevention agents, oily agents and oxidation preventing agents mentioned below, lubricating performance (fretting-resisting property or the like) and durable performance can be more improved.
- Organic sulfonic acid metal or ester is preferable as a rust prevention agent. As organic sulfonic acid salt, use is made, for example, of dinonyl naphthalene sulfonic acid and heavy alkyl benzene sulfonic acid, and as the metal salt thereof, there is calcium sulfonate, barium sulfonate, sodium sulfonate or the like.
- As ester, in sorbitan derivative, there is sorbitan monolaurate, sorbitan tristearate, sorbitan monooleate, sorbitan trioleate or the like as the partial ester of polybasic carboxylic acid and polyatomic alcohol. As alkyl ester type, there is polyoxyethylene laurate, polyoxyethylene oleate, polyoxyethylene stearate or the like.
- As these rust prevention agents, organic sulfonic acid metal salt and ester can be used singly or as a mixture. Taking it into account to improve the rust prevention property and suppress fretting corrosion, ester polyoxyethylene sorbitan laurate is high in dissolving property and is suitably used as sulfonic acid metallic salt such as calcium sulfonate, and fluorophosphazene oil.
- As an oil agent, oleic acid, stearic acid or the like as higher fatty acid, lauryl alcohol, oleyl alcohol or the like as higher alcohol, stearyl amine, cetyl amine or the like as amine—these can be used singly or mixedly.
- As an oxidation preventing agent, a nitrogen containing compound oxidation preventing agent and a phenol oxidation preventing agent may preferably be used singly or as a mixture.
- As the nitrogen containing compound oxidation preventing agent, there is phenyl α naphthylamine, diphenylamine, phenylene diamine, oleyl amideamine, phenothiazine or the like.
- As a phenol oxidation preventing agent, there is hindered phenol such as p-t-butyl-phenyl salicylate, 2,6-di-t-butyl-p-phenyl phenol, 2,2′-methylenebis-(4-methyl-6-t-octyl phenol), 4,4′-butyrydenbis-6-t-butyl-m-cresol, tetrakis[methylene-3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionate]methane, 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxylbenzil)benzene, n-octadecyl-β-(4′-hydroxy-3′,5′-di-t-butylphenyl)propionate, 2-n-octylthio-4,6-di(4′-hydroxy-3′,5′-di-t-butyl)phenoxy-1,3,5-triazine, 4,4′-thiobisu-[6-t-butyl-m-cresol], 2-(2′-hydroxy-3′-t-butyl-5′-methylphenyl)-5-chlorobenzotriazole or the like.
- As an extreme pressure agent, use can be made of organic metallic salt such as molybdenum thiocarbamate, molybdenum dithio phosphate, zinc diocarbamate, zinc dithiophosphate or the like.
- As a corrosion preventing agent, mention may be made of phosphoric acid ester, phosphorous acid ester or the like. Particularly, molybdenum dithiocarbamate and phosphorous acid ester exhibit an excellent effect in the fretting resisting property and can therefore be suitably used.
- In addition to the foregoing agents, a friction preventing agent, a viscosity index improving agent or the like may be contained in the lubricating oil. These may all be conventional agents.
- Regarding the base oil and additive of the grease enclosed in the above-described fretting-resisting roller bearing of the present invention, use may be made of ones similar to the above-described lubricating oil composition of the present invention. Also, a thickness may be a conventional one such as metallic soap or urea resin, but from the viewpoint of the characteristic of the bearing for a spindle, lithium soap having an excellent characteristic in acoustic life is preferable.
- In the case of the fretting-resisting roller bearing of the present invention, the contacting portions of the raceway surfaces of the outer and inner races and the rolling elements are the same material or different materials, and when different materials are used, they are steel and ceramics or steel and a super-hard alloy. If the lubricating oil in the present invention is used, the fretting corrosion will be greatly mitigated, and further, under an environment of severe vibration condition, different materials may be small in the frictional force acting on the contacting portions as compared with steel and steel, and in these contacting portions, it is more difficult for such an injury which will lead to fretting corrosion to occur.
- In the case of ceramics, the material forming the rolling elements may be silicon nitride, zirconia, alumina or the like, and in the case of a super-high alloy, the material forming the rolling elements may be tungsten carbide or the like.
- The friction characteristic on the contacting portions of the raceways of the outer and inner races made of steel and the rolling surfaces of the rolling elements made of ceramics or a super-hard alloy is improved as compared with the friction characteristic when steel and steel contact with each other, even if the combination of different materials is steel and ceramics or steel and a super-hard alloy. Above all, the combination of bearing steel and silicon nitride, stainless steel and silicon nitride, bearing steel and zirconia, bearing steel and tungsten carbamate, or stainless steel and tungsten carbamate provides an excellent friction characteristic (a low friction characteristic) and is excellent in the fretting resisting property. By combining these with the above-mentioned lubricating oil, a further effect is obtained against fretting corrosion and these combinations can be preferably be used.
- Description will now be made of the conditions and results of evaluation tests carried out to confirm the effect of the present invention.
- Tested bearing: 695
- Frequency: 27 Hz
- Angle of swing: 20
- Load (Fa): 14.7 N
- Frequency of swing: 1×10 5 times
- Enclosed grease: Lithium soap grease
- The above-mentioned swing test was carried out, and the acceleration of the bearing in the radial direction thereof after the test was measured and evaluation was effected.
- A heretofore used bearing specification [Comparative Example 1] was subjected to a swing test, and comparison evaluation was effected with the bearing radial direction acceleration signal execution value after the test being 100%.
- It is because the traces of minute fretting corrosion created on the inner and outer races and rolling elements of the bearing can be measured with good sensitivity that the bearing radial direction acceleration was used as a test evaluation item.
- Tested bearing: 695
- Load (Fa): 14.7 N
- Number of revolutions: 3600 rpm
- As regards the magnitude of torque, 1.2 gf·cm or less was regarded as being successful.
- The test conditions of each embodiment and each comparative example are as follows:
- A bearing in which lubricating oil C of which the dynamic viscosity at 40° C. was 90 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which rolling elements were made of silicon nitride and lubricating oil C of which the dynamic viscosity at 40° C. was 90 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which rolling elements were made of tungsten carbide of Vickers hardness 1300 and lubricating oil C of which the dynamic viscosity at 40° C. was 90 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which lubricating oil B of which the dynamic viscosity at 40° C. was 25 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which rolling elements were made of silicon nitride and lubricating oil B of which the dynamic viscosity at 40° C. was 25 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which rolling elements were made of tungsten carbide of Vickers hardness 1300 and lubricating oil B of which the dynamic viscosity at 40° C. was 25 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which lubricating oil E of which the dynamic viscosity at 40° C. was 150 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which lubricating oil F of which the dynamic viscosity at 40° C. was 25 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which lubricating oil G of which the dynamic viscosity at 40° C. was 90 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which lubricating oil H of which the dynamic viscosity at 40° C. was 120 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which lubricating oil A of which the dynamic viscosity at 40° C. was 11 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- A bearing in which lubricating oil D of which the dynamic viscosity at 40° C. was 160 mm 2/s was formed into film on the raceway surfaces of inner and outer races, a cage and rolling elements and grease was enclosed was tested in a pre-load state under the above-mentioned conditions.
- The compositions of the lubricating oils A to H used in the above-described embodiments and comparative examples are shown in Table 1 below.
TABLE 1 Lubricating Lubricating Lubricating Lubricating Lubricating Lubricating Lubricating Lubricating Oil A Oil B Oil C Oil D Oil E Oil F Oil G Oil H kind of DOS PAO TOTM ADE MO PET TOTM PAO oil dynamic 11 25 90 160 150 25 90 120 viscosity mm2/s (40° C.) rust calcium calcium calcium sodium sodium calcium barium calcium prevention sulfonate sulfonate sulfonate sulfonate sulfonate sulfonate sulfonate sulfonate agent additive — zinc molybdenum phosphorous phosphorous phosphorous zinc molybenum dithiophosphate dithiophosphate acid ester acid acid ester dithiophosphate dithiophosphate - The acceleration signal execution values and rotation torques in the above-described embodiments and comparative examples are shown in the graphs of FIGS. 1 and 2, respectively.
- According to the fretting-resisting roller bearing of the present invention described above, there are obtained the following effects:
- (1) The oil film of lubricating oil having high dynamic viscosity is formed on the raceway surfaces of the inner and outer races, the cage and the rolling elements and therefore, there can be provided a fretting-resisting roller bearing in which the strength of the oil film is high and the fretting-resisting property during conveyance is improved and also the various characteristics of the bearing are not adversely affected and which achieves a higher temperature and a higher speed as well as a longer life.
- (2) When the material of the rolling elements is ceramics or a super-hard alloy of Vickers hardness 1300 or greater and the outer and inner races are made of steel and a material differing from the material of the outer and inner races is used as the material of the rolling elements, the hardness thereof is increased, whereby not only fretting corrosion can be suppressed by the prevention of the adhesion phenomenon between the members (the raceway surfaces of the outer and inner races and the rolling elements) and the decrease in the Hertzian contact area by the difference in Young's modulus, but also the bearing functions well even under the use conditions of high temperatures and high-speed rotation.
Claims (3)
1. A fretting resisting roller bearing comprised of a plurality of rolling elements held between inner and outer races with a cage interposed therebetween, characterized in that the oil film of lubricating oil of which the dynamic viscosity at 40° C. is 20 to 150 mm2/2 is formed on the raceway surfaces of the inner and outer races, the cage and the rolling elements and grease is enclosed.
2. A fretting resisting roller bearing according to claim 1 , wherein said inner and outer races are made of steel and said roller element is made of ceramics.
3. A fretting resisting roller bearing according to claim 1 , wherein said inner and outer races are made of steel and said roller element is made of super-hard alloy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/030,077 US20050124511A1 (en) | 1997-11-26 | 2005-01-07 | Roller bearing |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9-324446 | 1997-11-26 | ||
| JP32444697 | 1997-11-26 | ||
| JP10332635A JP2000199526A (en) | 1997-11-26 | 1998-11-24 | Rolling bearing |
| JP10-332635 | 1998-11-24 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/030,077 Continuation US20050124511A1 (en) | 1997-11-26 | 2005-01-07 | Roller bearing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20020006879A1 true US20020006879A1 (en) | 2002-01-17 |
Family
ID=26571491
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US09/199,447 Abandoned US20020006879A1 (en) | 1997-11-26 | 1998-11-25 | Roller bearing |
| US11/030,077 Abandoned US20050124511A1 (en) | 1997-11-26 | 2005-01-07 | Roller bearing |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/030,077 Abandoned US20050124511A1 (en) | 1997-11-26 | 2005-01-07 | Roller bearing |
Country Status (1)
| Country | Link |
|---|---|
| US (2) | US20020006879A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080271967A1 (en) * | 2004-06-23 | 2008-11-06 | Nsk Ltd. | One-Way Clutch-Containing Rotation Transmission Apparatus |
| US20090136172A1 (en) * | 2005-06-09 | 2009-05-28 | Ntn Corporation | Grease for Hub Bearing and Hub Bearing |
| WO2013141959A1 (en) * | 2012-03-22 | 2013-09-26 | The Timken Company | Anti-fretting additives for non-lubricated contact surfaces |
| CN105062640A (en) * | 2015-08-11 | 2015-11-18 | 广西大学 | Environment-friendly heavy-load oil film bearing lubricating oil composition with wear resistance |
| CN105739027A (en) * | 2016-04-29 | 2016-07-06 | 宁波市樱铭电子科技有限公司 | Optical fiber splicing device |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5467723B2 (en) * | 2008-01-23 | 2014-04-09 | 協同油脂株式会社 | Lubricant composition and machine member |
| CN102226124B (en) * | 2011-05-12 | 2013-07-17 | 泉州市欧美润滑油制品有限公司 | Automobile oil with deep clean and antiwear properties |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2576898B2 (en) * | 1989-03-04 | 1997-01-29 | 日本石油株式会社 | Grease composition |
| US5462683A (en) * | 1991-03-07 | 1995-10-31 | Nippon Oil Co., Ltd. | Grease composition for constant velocity joint |
| US5401105A (en) * | 1992-12-28 | 1995-03-28 | Nsk Ltd. | Ball bearing and method for producing a cage of the ball bearing |
| US5729404A (en) * | 1993-09-30 | 1998-03-17 | Seagate Technology, Inc. | Disc drive spindle motor with rotor isolation and controlled resistance electrical pathway from disc to ground |
| GB2283758A (en) * | 1993-11-11 | 1995-05-17 | Nsk Ltd | Rust preventive lubricating oil |
| US5523009A (en) * | 1995-03-22 | 1996-06-04 | Witco Corporation | Fibrous polyurea grease |
| US5650380A (en) * | 1995-07-11 | 1997-07-22 | Shell Oil Company | Lubricating grease |
| US5807813A (en) * | 1995-07-20 | 1998-09-15 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
| DE19681044B4 (en) * | 1995-10-23 | 2008-08-28 | Nsk Ltd. | Lubricant composition and its use |
| SE514372C2 (en) * | 1996-03-07 | 2001-02-19 | Skf Nova Ab | Lubricated rolling contact device, method and composition for lubricating a rolling contact device and a ceramic roller body |
| JPH1182488A (en) * | 1996-10-25 | 1999-03-26 | Nippon Seiko Kk | Rolling bearing and spindle device |
-
1998
- 1998-11-25 US US09/199,447 patent/US20020006879A1/en not_active Abandoned
-
2005
- 2005-01-07 US US11/030,077 patent/US20050124511A1/en not_active Abandoned
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080271967A1 (en) * | 2004-06-23 | 2008-11-06 | Nsk Ltd. | One-Way Clutch-Containing Rotation Transmission Apparatus |
| US20090136172A1 (en) * | 2005-06-09 | 2009-05-28 | Ntn Corporation | Grease for Hub Bearing and Hub Bearing |
| WO2013141959A1 (en) * | 2012-03-22 | 2013-09-26 | The Timken Company | Anti-fretting additives for non-lubricated contact surfaces |
| CN105062640A (en) * | 2015-08-11 | 2015-11-18 | 广西大学 | Environment-friendly heavy-load oil film bearing lubricating oil composition with wear resistance |
| CN105739027A (en) * | 2016-04-29 | 2016-07-06 | 宁波市樱铭电子科技有限公司 | Optical fiber splicing device |
Also Published As
| Publication number | Publication date |
|---|---|
| US20050124511A1 (en) | 2005-06-09 |
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