US2002083A - Treatment of fabrics - Google Patents
Treatment of fabrics Download PDFInfo
- Publication number
- US2002083A US2002083A US470232A US47023230A US2002083A US 2002083 A US2002083 A US 2002083A US 470232 A US470232 A US 470232A US 47023230 A US47023230 A US 47023230A US 2002083 A US2002083 A US 2002083A
- Authority
- US
- United States
- Prior art keywords
- fibres
- fabrics
- cotton
- bath
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title description 26
- 229920000742 Cotton Polymers 0.000 description 17
- 229920002301 cellulose acetate Polymers 0.000 description 16
- 238000000034 method Methods 0.000 description 15
- 239000000463 material Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 239000002253 acid Substances 0.000 description 9
- 229920002678 cellulose Polymers 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 5
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229940003214 aluminium chloride Drugs 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 239000004627 regenerated cellulose Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002895 organic esters Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/02—Producing patterns by locally destroying or modifying the fibres of a web by chemical actions, e.g. making translucent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01C—CHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
- D01C5/00—Carbonising rags to recover animal fibres
Definitions
- This invention relates to improved; processes for the treatment of fabrics and in particular the treatment of fabrics made of cotton or other cellulosic fibresor containing cotton or other cellu- 5 losic fibres in association with cellulose derivatives, for example cellulose acetate or other cellulose esters or cellulose ethers or withanimal nbres, for instance wool or silk.
- cellulose derivatives for example cellulose acetate or other cellulose esters or cellulose ethers or withanimal nbres, for instance wool or silk.
- h m j m The object of the present invention isto proof the cotton or other cellulosic fibre partly or wholly from such fabrics, andmore particularly, the, invention is concerned with new processes for the production of ornamental. effects, for instance lace, brocade or raised figure effects, on such fabrics.
- the cellulosic threads 30 may be removed by treating the iabric in a hot bath containing aluminium chloride,
- the baths may contain the acidicsubstance in solution in water or in organic, liquids having no 4o deleterious effect upon the animal fibres or ,celluorganic solvent.
- the acidic substancesI may be employed in solution in organic acids, for example acetic acid.
- Local effects for example the localremoval oi pile or plush, may be obtained according 'tothe present invention by first applying tothe fabric consisting of or containing cotton or other cellulosic fibre'a suitable substance adapted to reserve the fibre against the action of the acidic substances.
- the fabric is thereafter treated in a hot bath containing the acidicvsubstance only the cellulosic fibres in the unreserved portions will be disintegrated and rendered removparticularly vide' newor improved processes for thereinoval delustering, if
- the acidic salts may be used. Moreoven with greater concentrations lower tem- 10 peratures or shorter timesmay be employed if desired.
- the 16 the bath in treating materials containing cellulose acetate may be below the delusteringtemperature, or alternatively substances may be added to the baths toprevent such delustering, for example, sodium sulphate, or other 20 neutral salts or other salts or sugars, (see for example United States Patents Nos. 1,7 56,581 and According to a modification of -the invention,
- the iabricsitreatedaccording to the present invention may be coloured in any desired man-
- suitable colouring matters may be incorporated in the reserve; or again the reserved portions may be subsequently coloured.
- Two. or 'multi-colour effects may be, obtained on mixed fabrics by taking advantage of thedifierent dyeing aillnities of the fibres used in association.
- mordant metalsalt such as alumin- 40 aluminium sulphate-or ferric chloride
- mordanting or the reserved fibres or of the fibres such as animal fibres or cellulose derivatives which are unattacked by themacidic'substances, then such mordanted flbresmay afterwards he coloured dyestufis, l i
- Example 1 a mixed natural wool-cotton fabric is boiled as in an aqueous solution of hydrochloric acid of 2-3 per cent. strength for 2-3 hours or until the cotton fibre is readily removable, as for example by washing, brushing or the like.
- Example 2 A mixed fabric containing cellulose acetate, natural wool and cotton is heated at C. in an aqueous solution of ferric chloride, containing 10 per cent. of Glaubers salt, of 3-5 per cent. concentration, for 2-3 hours or until the cotton is readily removable. After the removal of the cotton the fabric may be dyed with mordant dyestuffs .to fix therein an iron lake. 7
- Example 3 reference numerals refer to similar parts
- Figure 1 shows a fabric woven with natural silk yarns, I, in the warp and cotton or regenerated cellulose yarns, 2, in the weft.
- Figure 2 shows the fabric of Figure 1 after certain portions, A, of the cotton or regenerated cellulose yarns have been-removed by the'local application of the hot acid locally.
- Figure 3 shows a fabric woven with natural silk yarns, l, in the warp and cellulose acetate yarns, 3, in the weft.
- Figure 4 showsthe fabric of Figure 3 after a certain portion, B, of the cellulose acetate yarns has been saponified by the local application of a saponifying agent, the saponified portions of the cellulose acetate yarn being shown at 4.
- Figure 5 shows the fabric of Figure 4 with the saponified portion, B, of the cellulose acetate yarns removed by the hot acid treatment.
- Process for the production of effects upon fabrics which consists in subjecting mixed materials oontaining fibres comprising cellulose acetate at least in selected areas to the action of a reagent which will saponify the cellulose acetate, then treating the materials in a hot bath containing ferric chloride until the cellulosic fibres are rendered removable by the action of said bath and mechanically removing thesame.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB23809/29A GB339300A (en) | 1929-08-02 | 1929-08-02 | Improvements in the treatment of fabrics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2002083A true US2002083A (en) | 1935-05-21 |
Family
ID=10201655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US470232A Expired - Lifetime US2002083A (en) | 1929-08-02 | 1930-07-23 | Treatment of fabrics |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US2002083A (fr) |
| FR (1) | FR698418A (fr) |
| GB (1) | GB339300A (fr) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2417535A (en) * | 1942-12-07 | 1947-03-18 | British Celanese | Production of textile materials which are sensitive towards water |
| US2472238A (en) * | 1944-03-10 | 1949-06-07 | Celanese Corp | Recovery of wool from wool-acetate fabrics |
| US2530244A (en) * | 1946-11-21 | 1950-11-14 | Soren J F Jensen | Process of degumming and bleaching ramie |
| US2775584A (en) * | 1951-11-16 | 1956-12-25 | Celanese Corp | Preparation of organic acid esters of cellulose having an improved resistance to delustering |
| US2887366A (en) * | 1955-06-06 | 1959-05-19 | Du Pont | Resurfacing of fiber-reinforced resinous articles |
| US3108847A (en) * | 1958-03-24 | 1963-10-29 | Kvp Sutherland Paper Co | Parchmentized paper |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101122076B (zh) * | 2007-09-19 | 2011-04-06 | 顾志鹏 | 在真丝织锦画上刺绣的方法 |
-
1929
- 1929-08-02 GB GB23809/29A patent/GB339300A/en not_active Expired
-
1930
- 1930-07-05 FR FR698418D patent/FR698418A/fr not_active Expired
- 1930-07-23 US US470232A patent/US2002083A/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2417535A (en) * | 1942-12-07 | 1947-03-18 | British Celanese | Production of textile materials which are sensitive towards water |
| US2472238A (en) * | 1944-03-10 | 1949-06-07 | Celanese Corp | Recovery of wool from wool-acetate fabrics |
| US2530244A (en) * | 1946-11-21 | 1950-11-14 | Soren J F Jensen | Process of degumming and bleaching ramie |
| US2775584A (en) * | 1951-11-16 | 1956-12-25 | Celanese Corp | Preparation of organic acid esters of cellulose having an improved resistance to delustering |
| US2887366A (en) * | 1955-06-06 | 1959-05-19 | Du Pont | Resurfacing of fiber-reinforced resinous articles |
| US3108847A (en) * | 1958-03-24 | 1963-10-29 | Kvp Sutherland Paper Co | Parchmentized paper |
Also Published As
| Publication number | Publication date |
|---|---|
| FR698418A (fr) | 1931-01-30 |
| GB339300A (en) | 1930-12-02 |
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