US20040180801A1 - Highly anti-deodorizing cleansing and aiding agents for washing clothing articles - Google Patents

Highly anti-deodorizing cleansing and aiding agents for washing clothing articles Download PDF

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Publication number
US20040180801A1
US20040180801A1 US10/734,433 US73443303A US2004180801A1 US 20040180801 A1 US20040180801 A1 US 20040180801A1 US 73443303 A US73443303 A US 73443303A US 2004180801 A1 US2004180801 A1 US 2004180801A1
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United States
Prior art keywords
sodium
washing
agent
cleansing
substances
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Abandoned
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US10/734,433
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English (en)
Inventor
Maurizio Cuna
Laura Cuna
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Individual
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Individual
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Application filed by Individual filed Critical Individual
Publication of US20040180801A1 publication Critical patent/US20040180801A1/en
Priority to US12/012,599 priority Critical patent/US8048839B2/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0068—Deodorant compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates

Definitions

  • the present invention relates to highly anti-deodorizing cleansing and aiding agents for washing clothing articles.
  • the invention relates to the provision of washing cleansing and aiding agents which, after rinsing the cloth or clothing articles, allow a comparatively high amount or rate of their active substances to remain bound to the fiber material of the clothing articles.
  • the invention in particular, provides cleansing and/or aiding agents which can be made starting from active substances which can comprise short chain alpha and beta hydroxy acids and isomeric aliphatic alcohols, which are added to prevent generation of bad odors originated by human perspiration.
  • essential oils and aliphatic alcohols such as linear or branched chain undecanol
  • bacteriostatic and/or bactericide surface active agents including, for example, zinc and magnesium derivative compounds, such as Zinc Coceth Sulphates, also commercially known as Zetesol Les 3Zn, zinc ricinoleate, acylglutammate from C8-C10 fat acids, commercially called Protelan AG8, and other surface active agents obtained from octyl acid and glycerin of a Sensiva SC50 type, trichloro hydroxy diphenyl ethers and dichloro hydroxy diphenyl ethers.
  • the above mentioned cleansing and/or aiding agents can also include smell masking or covering agents, such as fragrances, for masking or covering body bad smells, fragrances preventing an enzymatic degeneration and adapted to mask smoke and kitchens odors, and domestic animal bad odors.
  • smell masking or covering agents such as fragrances, for masking or covering body bad smells, fragrances preventing an enzymatic degeneration and adapted to mask smoke and kitchens odors, and domestic animal bad odors.
  • odorous molecule inorganic sequestering agents such as complex silicates, in particular active bentonites and zeolites.
  • antioxidating materials such as tocopherol and propylgallate
  • anti-perspiring substances such as ammonium salts
  • the above mentioned substances provide cleansing and aiding agents adapted to provide processed articles of clothing with improved properties since, upon washing, their fabric material would acquire a lot of different useful properties, directly deriving from the active substances or principles held therein.
  • gland secretions in particular of perspiration and sebaceous glands.
  • Perspiration glands can be divided into eccrine glands, usually present in a comparatively high amount on the hand palms, foot backs, forehead and forearms, which however are devoid of any relationships with the pile-sebaceous apparatus, and have an apocryphal nature.
  • Said perspiration glands are essentially concentrated in the axillary, perianal and breast regions.
  • the sebaceous glands pertain to the pile-sebaceous system, are open in the pile follicles, and their sebaceous activity is affected by hormonal factors.
  • a bad odor is formed in a later time, because of a bacteric attack against the microflora present on the skin.
  • the microbic flora involved in the above mentioned degradation process is mainly constituted by the saprophyte microflora, substantially comprising gram positive bacteria, aerobic and anaerobic bacteria, and, in a less degree, gram negative bacteria, yeast and mycetes.
  • the lipid enzymatic activity of saprophyte bacteria causes a decomposition of the gland secretions, to produce free fat acids, i.e. substances having a characteristic rancid and pungent smell, such as: butyric acid, caprinic acid and isovalerianic acid.
  • the proposed mechanism which constitutes the subject matter of the present invention, provide that alpha and beta hydroxy acid ester molecules deposited on the cloth or fabric materials, and contacting the enzymes elaborated by the skin saprophyte microorganisms, are decomposed to aliphatic alcohols and odorless alpha hydroxy acids, thereby preventing enzymes from degrading perspiration, and generating the above mentioned short chain fat acids, which are responsible of the body bad smell.
  • bacteriostatic and/or bactericide surface active substances such as ethers obtained from octyl acid and glycerin, and having smell masking properties, fat substances including body smell masking fragrances, and fragrances adapted to prevent any enzymatic degeneration and mask or cover smoke and kitchen smells or domestic animal smells, odorous molecule inorganic sequestering substances, odorous molecule organic sequestering substances, anti-oxidating, anti-perspiring substances, such as ammonium salts, essential oils and aliphatic alcohols, in particular linear or branched chain undecanol.
  • bacteriostatic and/or bactericide surface active substances such as ethers obtained from octyl acid and glycerin, and having smell masking properties, fat substances including body smell masking fragrances, and fragrances adapted to prevent any enzymatic degeneration and mask or cover smoke and kitchen smells or domestic animal smells, odorous molecule inorganic sequestering substances, odorous molecule organic sequester
  • Clothing articles to be processed by the above mentioned cleansing and aiding agents can comprise natural proteic (proteinaceous) fibers (silk, wool fibers), natural polysaccharide fibers (cotton, flax fibers) and synthetic fibers (nylon, rayon, polyester, polyamide fibers) and any suitable combinations thereof.
  • the invention also provides to add the above mentioned specific active principles or substances, adapted to provide the above disclosed functions, to washing bases or washing and ironing aiding agents or substances.
  • the above mentioned active principles can be added to softening, stain removing agents, and sizing and whitening substances.
  • the latter products can be constituted by liquids, gels, powders, tablets and single-dose packets.
  • the active principles according to the present invention comprise one or more esters defined by the following formula:
  • R is an alkyl radical, either of a linear or branched configuration, with a C2-C34 chain and R′ being an alpha or beta hydroxy acid radical derived, for example, from glycolic, lactic, cictric, malic, tartaric, glugonic or mandelic acids.
  • esters can be mentioned:
  • the above active principles can be added to the washing bases or aiding bases, in a weight rate from 0.1 to 10%.
  • Other active principles or substances which can be also added comprise bacteriostatic and/or bactericide surface active agents, surface active substances such as ethers obtained from octyl acid and glycerin, smell masking substances, i.e. fragrances for covering body smells, fragrances preventing any enzymatic degeneration and fragrances for covering smoke or kitchen smells and domestic animal smells, odorous molecule inorganic sequestering substances, odorous molecule organic sequestering substances, anti-oxidating and anti-perspiring substances, such as ammonium salts, short chain isomeric aliphatic alcohols, for example: aliphatic alcohol, linear or branched chain undecanol.
  • surface active substances such as ethers obtained from octyl acid and glycerin
  • smell masking substances i.e. fragrances for covering body smells, fragrances preventing any enzymatic degeneration and fragrances for covering smoke or kitchen smells and domestic animal smells
  • the above mentioned active principles can be added to the washing or aiding bases in a weight rate from 0.1% to 10%.
  • This is a washing base comprising liquid, gel, suspension powder substances, single-dose packets containing one or more of the following materials:
  • anionic bases sodium, tea, ammonium laurylether sulphate, zinc laurylether sulphate; sodium, tea, ammonium lauryl sulphate; sodium, tea, ammonium alkylbenzenesulphonate; sodium, tea, ammonium alkanesulphonates; sodium, tea, ammonium sulphonated alpha-olefins
  • a weight rate dose from 0.1 to 50%;
  • non ionic bases ethoxylated alcohols having a linear or branched C3-C22 alkyl chain and an ethoxylation and propoxylation degree from 2 to 30 moles; fat acid amides; alkylpolyglucosides; amine oxides), with a dose, by a weight rate from 0.1 to 50%;
  • amphoteric bases alkylamidobetaine, alkylamidopropylbetaine, alkylamidosultaine
  • a dose by a weight rate from 0.1 to 50%;
  • cationic bases dialkylmethyl ammonium methasulphate; quaternized tert amines, imidazoline, with a dose, by a weight rate from 0.1 to 50%;
  • soaps fat acids salified by sodium, potassium, mea, tea, by a weight rate from 0.1 to 50%;
  • coformulating and coactive agents (phosphonates; ethylendiamine tetracetic acid derivatives; citric acid and sodium and potassium derivatives, ethylene, propylene, dipropylene glycols; ethyl and isopropyl alcohl; activated bentonites; calcium and sodium chlorides; amilolitic, lipolitic, proteolitic enzymes; polyvinyl pirrolidone and derivatives thereof; optic whitening agents derived from distirildiphenyl; polymeric styrene/acryl dispersions; polyacrylates; dymethylpolysiloxanes; isothiazolinones, benzoiso-thiazolinones, bronopol, N-formals; coloring agents), by a weight rate from 0.1 to 20%;
  • This washing base comprises powder substances, in a pressed form (tablets) and single-dose packets.
  • the formulation according to the present invention comprises one or more of the following substances:
  • anionic bases sodium, tea, ammonium alcansulphonates; sodium, tea, ammonium lauryl sulphate; sodium, tea, ammonium alkylbenzene sulphonate
  • non ionic bases ethoxylated alcohols with a linear or branched C3-C22 alkyl chain and an ethoxylation and propoxylation degree from 2 to 20 moles; fat acid amides; alkylpolyglucosides; amine oxides
  • amphoteric bases alkylamidobetaines, alkylamidopropylbetaines, alkylamidosultaines, by a weight rate of 0.1 to 50%;
  • soaps sodium salified fat acids, by a weight rate of 0.1 to 30%;
  • filling substances (powder and grained sodium sulphate, dense and light sodium carbonate, sodium silicate and disilicate), by a weight rate of 0.1 to 40%;
  • coformulating and coactive substances (zeolites; mono and tetrahydrate sodium perborate, sodium percarbonate, sodium persulphate; phosphonates; ethylendiamine tetracetic acid derivatives; citric acid and sodic derivatives; perborate and percarbonate activating substances, i.e.
  • tetracetylendiamine tetracetylendiamine
  • bentonites and activated bentonites carboxymethylcelluloses
  • amylolitic, lipolitic, proteolitic enzymes polyvinylpirrolidones and derivatives thereof
  • optic whitening substances of stilbene and distiryl diphenyl derivatives polyacrylates
  • dymethylpolyxyloxanes coloring agents
  • This Example is disclosed for showing a possible mode for using the above mentioned active principles, to be added to washing and ironing aiding substances and comprising softening, stain removing, sizing and whitening substances, liquid formulated substances, gel, powder, tablets and single-dose packets.
  • the formulation according to the present invention comprises one or more of the following components:
  • cationic bases dialkylmethylammonium metasulphate; quaternized tert-amines, dialkyl-dymethylammonioum chloride; imidazoline, by a weight rate of 0.1 to 50%;
  • amphoteric bases alkylamidobetaine, alkyl-amidopropylbetaine, alkylamidosultaine, by a weight rate of 0.1 to 20%;
  • -anionic bases sodium, tea, ammonium laurylether sulphate; sodium, tea, ammonium lauryl sulphate; sodium, tea, ammonium alkylbenzene-sulphonate
  • weight rate 0.1 to 50%
  • non ionic bases alkyl C3-C22 linear or branched ethoxylated alcohols and with an ethoxylation and propoxylation degree of 2 to 30 moles; fat acid amides; alkylpolyglucosides; amine oxides), with a weight rate dose from 0.1 to 50%;
  • active oxidating principles sodium hypochlorite, hydrogen peroxide, mono and tetrahydrate sodium perborate, sodium percarbonate, sodium persulphate, by a weight rate of 0.1 to 99%;
  • co-formulating and coactive substances (phosphonates; ethylendiamine tetracetic acid derivatives; citric acid and sodium and potassium derivatives, ethyl and isopropryl alcohol; calcium, sodium and ammonium chlorides; amylolitic, lypolitic, proteolitic enzymes, polyvinylpirrolidones and derivatives thereof; optic whitening substances derived from distiril dyphenil; polymeric styrene/acryl dispersions; dymethyl polysiloxanes; isothiazolinones, benzoisothiazolinones; bronopol, N-formals; coloring substances), by a weight rate of 0.1 to 20%;
  • Example No. 1 an exemplary formulation of the washing base No. 1.
  • a preferential formulation provides to use two or more of the following components, by the weight rates thereinbelow indicated: Sodium laurylethersulphate 8 Alkylbenzenesulphonate TEA 6 TEO C12-15 Alcohol 1.5 Alkylamidosultaine 1 Hydroxyacetyl hydroxyethyl 0.2 Ammonium chloride Potassium soap 3 Ethylene Diamine Tetra Acetic Acid 0.5 Amylasis enzyme 0.15 Proteasis enzyme 0.3 Lipasis enzyme 0.2 Preserving agents q.s. Perfume 0.3 Cosmacol ELI 0.8 Isalchem 11 0.5 Coloring or dyeing agents q.s. Water q.s.
  • Example No. 2 exemplary formulation of the washing basis No. 2.
  • a preferential formulation provides to use two or more of the following components in the indicated by weight rates: Sodium laurylsulphate 10 TEA alkylbenzesulphonate 5 TEO C12-15 alcohol 7 Alkylamidosultaine 0.5 Hydroxyacetyl hydroxyethyl 0.2 Ammonium chloride Potassium soap 5 Sodium percarbonate 10 Sodium carbonate 15 Sodium silicate 3 Ethylene Diamine Tetra Acetic Acid 0.5 Zeolite 15 Amilasis enzyme 0.15 Proteasis enzyme 0.3 Lipasis enzyme 0.2 Carboxymethylcellulose 1.5 Perfume 0.3 Cosmacol ELI 1.5 Isalchem 11 1 Sodium sulphate q.s.
  • Example No. 3 exemplary formulation of the washing basis No. 3.
  • a preferential formulation for a washing liquid aiding agents having a softening activity provides to use the following components in the indicated by weight rates: Alkylamidosultaine 1 Dialkylesterammoniummetha- 10 Sulphate Ethylene Diamine Tetra Acetic 0.5 Preserving agents q.s. Perfume 1.5 Ethoxylated C12-18 10 OE alcohol 1.5 Silicone 0.1 Isopropyl alcohol 1 Cosmacol ELI 0.8 Isalchem 11 0.5 Water q.s
  • the tests have been performed “in blind” on families including at least a member performing an intensive sports activity.
  • the invention provides a product comprising active principles, including alpha and beta hydroxy acid esters and aliphatic alcohols which can be added to cleansing agents and washing aiding agents for clothing articles, which product is very practical and functional and hinders any enzymatic activities of the skin microbic and bacteric microflora, which would be responsible of bad smells of clothing articles.
  • active principles including alpha and beta hydroxy acid esters and aliphatic alcohols which can be added to cleansing agents and washing aiding agents for clothing articles, which product is very practical and functional and hinders any enzymatic activities of the skin microbic and bacteric microflora, which would be responsible of bad smells of clothing articles.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US10/734,433 2003-02-06 2003-12-12 Highly anti-deodorizing cleansing and aiding agents for washing clothing articles Abandoned US20040180801A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/012,599 US8048839B2 (en) 2003-02-06 2008-02-04 Highly anti-deodorizing and aiding agents for washing clothing articles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT000202A ITMI20030202A1 (it) 2003-02-06 2003-02-06 Detergenti e coadiuvanti del lavaggio ad alto effetto antiodorante sui capi in uso per effetto del lavaggio
ITMI2003A000202 2003-02-06

Related Child Applications (1)

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US12/012,599 Continuation US8048839B2 (en) 2003-02-06 2008-02-04 Highly anti-deodorizing and aiding agents for washing clothing articles

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US20040180801A1 true US20040180801A1 (en) 2004-09-16

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US10/734,433 Abandoned US20040180801A1 (en) 2003-02-06 2003-12-12 Highly anti-deodorizing cleansing and aiding agents for washing clothing articles
US12/012,599 Expired - Fee Related US8048839B2 (en) 2003-02-06 2008-02-04 Highly anti-deodorizing and aiding agents for washing clothing articles

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US (2) US20040180801A1 (de)
EP (1) EP1449909B1 (de)
JP (1) JP4474170B2 (de)
AT (1) ATE416247T1 (de)
DE (1) DE60325012D1 (de)
ES (1) ES2318084T3 (de)
IT (1) ITMI20030202A1 (de)
PT (1) PT1449909E (de)

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JP2008533048A (ja) 2005-03-10 2008-08-21 スリーエム イノベイティブ プロパティズ カンパニー 耳の感染症の治療方法
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JP4712664B2 (ja) * 2005-10-14 2011-06-29 花王株式会社 繊維処理剤組成物及びその製造法
JP5019555B2 (ja) * 2005-11-30 2012-09-05 学校法人文化学園 新規洗浄剤
CN107267302B (zh) * 2010-02-08 2020-03-27 埃科莱布美国股份有限公司 减少烟气的纺织品护理去污剂
CN101993788B (zh) * 2010-11-05 2012-01-25 深圳市七叶红生物科技有限公司 一种健康零碳洗衣粉及其制备方法
KR101695483B1 (ko) * 2014-03-06 2017-01-13 (주)오성에버린 스프레이용 천연탈취제의 제조방법
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ITMI20030202A1 (it) 2004-08-07
ATE416247T1 (de) 2008-12-15
PT1449909E (pt) 2009-03-11
US8048839B2 (en) 2011-11-01
JP2004238620A (ja) 2004-08-26
ES2318084T3 (es) 2009-05-01
EP1449909B1 (de) 2008-12-03
US20080196169A1 (en) 2008-08-21
JP4474170B2 (ja) 2010-06-02
DE60325012D1 (de) 2009-01-15
EP1449909A1 (de) 2004-08-25

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