US20060185687A1 - Filter cigarette and method of making filter cigarette for an electrical smoking system - Google Patents

Filter cigarette and method of making filter cigarette for an electrical smoking system Download PDF

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Publication number
US20060185687A1
US20060185687A1 US11/300,583 US30058305A US2006185687A1 US 20060185687 A1 US20060185687 A1 US 20060185687A1 US 30058305 A US30058305 A US 30058305A US 2006185687 A1 US2006185687 A1 US 2006185687A1
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US
United States
Prior art keywords
cigarette
web
set forth
nanoparticles
filter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/300,583
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English (en)
Inventor
John Hearn
Wesley Sanderson
Barry Smith
Susan Wrenn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Philip Morris USA Inc
Original Assignee
Philip Morris USA Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Philip Morris USA Inc filed Critical Philip Morris USA Inc
Priority to US11/300,583 priority Critical patent/US20060185687A1/en
Assigned to PHILIP MORRIS USA INC. reassignment PHILIP MORRIS USA INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HEARN, JOHN R., SMITH, BARRY S., WRENN, SUSAN E., SANDERSON, WESLEY G.
Publication of US20060185687A1 publication Critical patent/US20060185687A1/en
Abandoned legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
    • A24B15/282—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by indirect addition of the chemical substances, e.g. in the wrapper, in the case
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/285—Treatment of tobacco products or tobacco substitutes by chemical substances characterised by structural features, e.g. particle shape or size
    • A24B15/286—Nanoparticles
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/287—Treatment of tobacco products or tobacco substitutes by chemical substances by inorganic substances only
    • A24B15/288—Catalysts or catalytic material, e.g. included in the wrapping material
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A24D1/20—Cigarettes specially adapted for simulated smoking devices
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/17—Filters specially adapted for simulated smoking devices

Definitions

  • a cigarette for an electrical smoking system includes a filter tipping including a web including added filtering material and a tubular wrapper around the web, and a tobacco rod portion adapted to generate a puff of smoke upon being heated by at least one heating element during smoking, the tobacco rod portion being attached to the filter tipping.
  • a method for making a cigarette for an electrical smoking system includes making a filter tipping by surrounding a web including added filtering material with a tubular wrapper, and attaching a tobacco rod portion adapted to generate a puff of smoke upon being heated by at least one heating element during smoking to the filter tipping.
  • FIGS. 1A-1C are cross-sectional side views of cigarettes according to various embodiments.
  • FIGS. 2A-2C show end views of a cigarette filter according to various embodiments.
  • FIG. 3 shows a web having a three-dimensional shape being compressed and surrounded by a wrapper according to an embodiment.
  • FIG. 4 shows a cigarette filter that uses multiple webs according to an embodiment.
  • Cigarettes 21 a - 21 c are shown in FIGS. 1A-1C .
  • the cigarettes all include a cigarette filter 23 including a web 25 including filtering material and a tubular wrapper 27 around the web.
  • the cigarette 21 includes a cylindrical member, e.g., a tobacco containing rod portion 37 a - 37 c , for generating smoke attached to the cigarette filter.
  • the cigarette 21 is of the type usable in an electrical smoking system such as is disclosed in commonly owned U.S. Pat. Nos. 5,388,594; 5,692,525; 6,209,547; 6,289,898; 6,615,840 and 6,888,313, and in U.S. Application Publication No. 20030131859, which patents and application publications are incorporated by reference in their entirety.
  • FIG. 1A shows a cigarette 21 a wherein a filter 23 is disposed in a filter tipping 33 a including the filter 23 positioned adjacent a filter plug 35 , which can be, for example, a conventional cellulose acetate tow filter.
  • a tobacco rod portion 37 a is attached to the tipping 33 a and includes a free flow filter 39 , a void 41 or open space, and a tobacco plug 43 wrapped in a wrapper 45 that may include a tobacco web, although other arrangements can also be used.
  • heat is applied to the wrapper 45 to heat tobacco (e.g., the tobacco web and the tobacco plug 43 ) during puffing of the cigarette to thereby generate smoke.
  • tobacco e.g., the tobacco web and the tobacco plug 43
  • using the filter 23 instead of or in addition to conventional tubular free-flow filters can facilitate adjustment of features of the cigarette such as resistance to draw (RTD) which can be useful in simulating the experience of smoking a traditional, lit-end cigarette.
  • RTD resistance to draw
  • FIG. 1B shows a cigarette 21 b with a tipping 33 b and tobacco rod portion 37 b wherein the free flow filter 39 from the cigarette 21 a is eliminated.
  • FIG. 1C shows a cigarette 21 c with a tobacco rod portion 37 c wherein the filter 23 is used together with a free flow filter 47 in the tipping 33 c between the filter 23 and the filter plug 35 .
  • the foregoing are only several illustrative ones of numerous possible variations. There may be voids, free flow filters, filter plugs, tobacco plugs, and any other desired structures in the cigarette.
  • the web 25 may include paper.
  • the web 25 may include a coated paper, an impregnated paper, carbon paper, a laminate, or a laminate including paper.
  • the web 25 may be formed into a non-planar shape, such as by folding or rolling or bending the web. As seen in FIG. 2A , the web 25 may be formed into an accordian shape. As seen in FIG. 2B , an accordian-shaped web 25 may be formed into a circular shape. As seen in FIG. 2C , the web 25 may be crimped and formed into any one of numerous possible shapes. As seen in FIG.
  • the web 25 may be formed into any desired three-dimensional shape by a suitable forming apparatus 101 and then swaged or otherwise processed by a suitable compressing apparatus 103 to compress the shape.
  • the web 25 may exert a force on the wrapper 27 to assist in maintaining a three-dimensional shape for the filter 23 .
  • the wrapper 27 may be made from a web but may be formed from any structure suited for providing an outer covering for the web 25 , such as a pre-formed tube.
  • the filtering material is any suitable material, such as a material that reacts with at least one constituent of cigarette smoke.
  • the filtering material can include an aminopropylsilyl group covalently bonded to a non-volatile inorganic substrate. See, for example, commonly-owned U.S. Pat. Nos. 6,209,547, 6,584,979, and 6,595,218, which are hereby incorporated by reference.
  • the aminopropylsilyl group is preferably a 3-aminopropylsilyl group.
  • the substrate is preferably silica gel or molecular sieve material.
  • the material may be provided on a web 25 of paper or other suitable material.
  • the physical and chemical properties of the filler material used to produce webs 25 of paper for making filters 23 are chosen and utilized to reduce the aldehyde content of the smoke produced during combustion/pyrolysis of the smoking article.
  • the paper filler includes an ammonium-containing compound, which when heated evolves ammonia, which may chemically react with aldehydes in tobacco smoke and/or modify the combustion/pyrolysis reactions thereby reducing the initial formation of aldehydes, thereby decreasing the delivery of such aldehydes to a smoker.
  • the filtering material can be an ammonium containing compound filler used in the web. See, for example, commonly-owned U.S. Pat. Nos. 6,289,898 and 6,615,840, which are incorporated by reference.
  • a suitable ammonium-containing compound is an inorganic ammonium metal salt, such as an ammonium-alkaline earth metal salt, such as MgNH 4 PO 4 .xH 2 O, wherein x ranges from 1 to 6 (AMP). It is preferred that the ammonium-containing compound have a low solubility in water so as to be compatible with conventional papermaking processes, e.g., the filler is substantially insoluble in an aqueous dispersion containing ingredients of the paper, such as flax, etc. That is, the ammonium-containing compound should be stable enough in a papermaking process to survive intact as filler in the final paper product. This includes sufficient thermal stability to survive the drying steps in the papermaking process.
  • an inorganic ammonium metal salt such as an ammonium-alkaline earth metal salt, such as MgNH 4 PO 4 .xH 2 O, wherein x ranges from 1 to 6 (AMP). It is preferred that the ammonium-containing compound have a low solubility in water so as to be compatible
  • Magnesium ammonium phosphate and its hydrates are well-suited to conventional papermaking processes, and evolve ammonia during the smoking process in a manner that greatly decreases the content of certain low molecular weight aldehydes in smoke.
  • Magnesium potassium phosphate is isostructural with magnesium ammonium phosphate and can form solid solutions therewith effective for reducing the aldehyde content in smoke.
  • An ammonium magnesium phosphate filler that consists essentially of the monohydrate form of magnesium ammonium phosphate is especially preferred.
  • the ammonium-containing compound filler can also comprise one or more of the following mineral phases: dittmarite, struvite, hannayite, schertelite, mundrabillaite and swaknoite.
  • Ammonium-containing compounds considered useful as filler materials have a range of surface areas, a range of particle sizes (mostly in the micron range), possess appropriate opacity, have low solubility in water (required for papermaking), and possess other properties that are considered desirable in fillers for papers used in cigarettes.
  • the filler preferably has a particle size below 25 ⁇ m, more preferably below 10 ⁇ m.
  • the filtering material can include nanoparticles. Some or all of the nanoparticles can be a filler used in the web and some or all of the nanoparticles can be disposed on a surface of the web.
  • the nanoparticles can be capable of acting as at least one of an oxidant for converting carbon monoxide to carbon dioxide and a catalyst for converting carbon monoxide to carbon dioxide, or both.
  • the nanoparticles can be selected from the group consisting of metals, metal compounds, metal oxides, doped metal oxides, and mixtures thereof.
  • Suitable nanoparticles are preferably selected from the group consisting of Fe 2 O 3 , CuO, TiO 2 , CeO 2 , Ce 2 O 3 , Al 2 O 3 , Y 2 O 3 doped with zirconium, Mn 2 O 3 doped with palladium, and mixtures thereof. See, for example, commonly-owned U.S. Pat. No. 6,769,437 and U.S. Published Patent Application Nos. 20030075193 and 20030131859.
  • the nanoparticles preferably have an average particle size less than about 500 nm, preferably an average particle size less than about 100 nm, more preferably an average particle size less than about 50 nm, and still more preferably an average particle size less than about 5 nm.
  • the nanoparticles preferably have a surface area of at least about 20 m 2 /g, and more preferably a surface area of at least about 200 m 2 /g.
  • the filter may be disposed in the tobacco rod portion or in the tobacco rod portion and the tipping. Where multiple webs are used, they may occupy substantially the same volume, such as where they are layered next to one another, or may be arranged at different axial locations along the length of the cigarette that may be next to one another or not, as desired or necessary.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Manufacturing Of Cigar And Cigarette Tobacco (AREA)
US11/300,583 2004-12-22 2005-12-15 Filter cigarette and method of making filter cigarette for an electrical smoking system Abandoned US20060185687A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/300,583 US20060185687A1 (en) 2004-12-22 2005-12-15 Filter cigarette and method of making filter cigarette for an electrical smoking system

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US63786204P 2004-12-22 2004-12-22
US11/300,583 US20060185687A1 (en) 2004-12-22 2005-12-15 Filter cigarette and method of making filter cigarette for an electrical smoking system

Publications (1)

Publication Number Publication Date
US20060185687A1 true US20060185687A1 (en) 2006-08-24

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US11/300,583 Abandoned US20060185687A1 (en) 2004-12-22 2005-12-15 Filter cigarette and method of making filter cigarette for an electrical smoking system

Country Status (15)

Country Link
US (1) US20060185687A1 (fr)
EP (1) EP1838175A1 (fr)
JP (1) JP2008525009A (fr)
KR (1) KR20070089849A (fr)
CN (1) CN101094599A (fr)
AU (1) AU2005317678A1 (fr)
BR (1) BRPI0518562A2 (fr)
CA (1) CA2592146A1 (fr)
EA (1) EA200701330A1 (fr)
IL (1) IL183632A0 (fr)
MA (1) MA29114B1 (fr)
MX (1) MX2007007559A (fr)
NO (1) NO20073817L (fr)
WO (1) WO2006067627A1 (fr)
ZA (1) ZA200704692B (fr)

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ZA200704692B (en) 2008-04-30
CN101094599A (zh) 2007-12-26
MX2007007559A (es) 2007-08-15
AU2005317678A1 (en) 2006-06-29
BRPI0518562A2 (pt) 2008-11-25
CA2592146A1 (fr) 2006-06-29
WO2006067627A8 (fr) 2007-08-02
IL183632A0 (en) 2007-09-20
EP1838175A1 (fr) 2007-10-03
EA200701330A1 (ru) 2007-10-26
MA29114B1 (fr) 2007-12-03

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