US20090051083A1 - Reduction furnace - Google Patents
Reduction furnace Download PDFInfo
- Publication number
- US20090051083A1 US20090051083A1 US11/918,921 US91892106A US2009051083A1 US 20090051083 A1 US20090051083 A1 US 20090051083A1 US 91892106 A US91892106 A US 91892106A US 2009051083 A1 US2009051083 A1 US 2009051083A1
- Authority
- US
- United States
- Prior art keywords
- reduction
- reduction furnace
- metallic iron
- iron
- furnace according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 230000009467 reduction Effects 0.000 title claims abstract description 51
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 64
- 229910052742 iron Inorganic materials 0.000 claims abstract description 31
- 239000007789 gas Substances 0.000 claims abstract description 15
- 238000009825 accumulation Methods 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 238000011946 reduction process Methods 0.000 claims abstract description 6
- 238000007789 sealing Methods 0.000 claims abstract description 3
- 238000001816 cooling Methods 0.000 claims description 18
- 230000001105 regulatory effect Effects 0.000 claims description 8
- 230000001276 controlling effect Effects 0.000 claims 1
- 230000001737 promoting effect Effects 0.000 claims 1
- 239000000463 material Substances 0.000 description 13
- 238000010891 electric arc Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 238000009628 steelmaking Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B19/00—Combinations of different kinds of furnaces that are not all covered by any single one of main groups F27B1/00 - F27B17/00
- F27B19/04—Combinations of different kinds of furnaces that are not all covered by any single one of main groups F27B1/00 - F27B17/00 arranged for associated working
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0086—Conditioning, transformation of reduced iron ores
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B1/00—Shaft or like vertical or substantially vertical furnaces
- F27B1/10—Details, accessories or equipment specially adapted for furnaces of these types
- F27B1/21—Arrangements of devices for discharging
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/0033—Charging; Discharging; Manipulation of charge charging of particulate material
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/52—Manufacture of steel in electric furnaces
- C21C5/527—Charging of the electric furnace
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the present invention relates to a reduction furnace, in particular a reduction furnace for the production of metallic iron by means of the direct reduction of iron ore, extracted from mines, at a temperature that is less than the melting point of the components.
- the product obtained as a result of a direct reduction process is known as DRI or “Direct Reduced Iron”.
- the direct reduction process converts iron ore into highly metallized iron, in the form of lump ore, pellets or a mixture of these components.
- the process produces reduced iron containing variable quantities of carbon in the form of Fe 3 C.
- This material is the ideal foodstock for electric arc furnaces used in the production of high-quality steel.
- Direct reduction systems can thus be made to integrate with systems upstream of electric steelmaking plants.
- the hot DRI from the furnace or reactor also known as a shaft furnace
- the hot DRI from the furnace or reactor is usually briquetted or cooled in specific vessels, as it is extremely reactive in air at the temperature at which it leaves the reduction furnace.
- cooling system is not necessarily always associated with an arc furnace.
- the cooling vessel can also be used to cool the DRI and render the plant independent of the end use.
- the presence of a seal leg means the reduction furnace must be placed even higher up if the electric arc furnace (EAF) is gravity-fed.
- EAF electric arc furnace
- the main purpose of this invention is to produce a reduction furnace that, by integrating the discharge, transfer and buffer functions in a sloping pipe directly connected to the reduction furnace and the hot off-gases from the process, is capable of reducing heat loss during the passage from the reduction furnace to the electric arc furnace to a minimum, thus reducing electric furnace cycle times, i.e. reducing so-called tap to tap time, and thus reducing energy consumption. Above all this guarantees increased steel plant productivity because a shorter tap to tap time means the same system can be used to produce more castings.
- the present invention therefore achieves the purposes described above with a reduction furnace, defining a longitudinal axis, for the production of metallic iron by means of the direct reduction of iron ore that, according to claim 1 , comprises an iron ore feed zone, an iron ore reduction zone, and a metallic iron discharge zone, characterised in that it comprises accumulation means communicating at an inlet end with said metallic iron discharge area and at an output end with gas sealing means, said accumulation means being suitable for accumulating said metallic iron together with the off-gases from the reduction process.
- the diameter and length of the pipe are functions of the volume of the buffer required to separate the reduction and steelmaking plants.
- the slope of the pipe which must have an angle steeper than the actual DRI repose angle, which is approximately 30°, is such to prevent bridging of the DRI in the pipe.
- the furnace according to the present invention advantageously reduces the amount of power required by the DRI cooling circuit in the reduction system and eliminates cold DRI handling and management costs.
- One advantage of the invention is the fact that the hot DRI, produced in the reduction furnace, is sent directly to the steelwork's electric furnace while being maintained at a temperature of approximately 700° C. Furthermore, the system allows the DRI discharge to be controlled and sent simultaneously or alternately through a cooling vessel, so as to obtain cold DRI in a known manner. The portions of DRI to be sent hot to the buffer or to the cooling vessel for cooling, can be metered as required.
- Another advantage consists of the maximization of the discharge height of the hot DRI, since by integrating the buffer in the reactor, the final discharge point can be placed at the maximum possible height, after the seal leg.
- the transfer pipe involves the use of one less element compared to the reduction systems known in the prior art, with the elimination of the gas seal leg, and relative inert gas injection device, which connects the reactor to the hot inert vessel.
- FIG. 1 is a front view of a system comprising the furnace according to the present invention
- FIG. 2 is a cross-section of a part of the furnace in FIG. 1 ;
- FIG. 3 is a cross-section, on a plane orthogonal to that in FIG. 1 , of a detail of the furnace according to the invention
- FIGS. 4 and 5 are cross-sections of the detail in FIG. 3 on the same plane as FIG. 1 .
- Said reduction shaft comprises:
- the furnace or reactor 1 produces hot DRI, starting from oxides in the form of pellets and/or lumps, which it discharges at a high temperature through a zone, preferably a conically-shaped zone, into the transfer pipe 6 .
- Said transfer pipe 6 through regulating means 3 that control the hot discharge from the reactor 1 , enables portions of DRI to be directed simultaneously or alternately to an electric arc furnace and to the cooling vessel 5 , and also acts as an accumulator, also referred to as a “buffer” in this description.
- a collecting duct 4 inserted into the pipe 6 and having a diameter larger than the base of the cone of the reactor 1 , is directly connected to the cooling vessel 5 and material passes through said duct at all times when the system is running. In the area 2 of the transfer pipe 6 a pile of material builds up according to the natural repose angle thereof.
- the cooling vessel 5 is in turn directly connected to a cold discharge device 10 via a dynamic gas seal leg 9 .
- a cold discharge device 10 via a dynamic gas seal leg 9 .
- the activation of the discharge device 10 generates a flow of material along the entire height of the reduction shaft, while the repose angles in the area 2 remain unchanged.
- the area 2 thus becomes an open point at which it is possible and easy to pick up portions of hot DRI which can be diverted, discharged or forced out of the collecting duct 4 and thus towards the pipe or buffer 6 .
- the hot discharge regulating means may comprise, for instance, a blade 3 arranged transversely in relation to the flow of material from the reactor 1 , controlled by a hydraulic cylinder. This blade 3 sweeps the pile of material in the area 2 with an oscillating movement, so that portions of hot DRI can be discharged outside the duct 4 towards the transfer pipe 6 and, at the same time, inside the duct 4 towards the cooling vessel 5 .
- the speed at which the blade 3 oscillates determines the control of the input flow both to the cooling vessel 5 and to the transfer pipe 6 .
- the blade 3 When in the home position the blade 3 is parked outside the pile of DRI and does not obstruct the flow towards the cooling vessel 5 .
- the blade 3 may be operated autonomously, or it may advantageously be joined to a “flow promoter” 8 the function of which is to prevent bridging in the end part of the discharge cone 1 ′ of the cone of the reactor 1 .
- This basically consists of through pipes with wear-proof protuberances that rotate by a few degrees about their own axis alternately in the two directions at very low frequency. This movement prevents bridging in the discharge cone 1 ′ and guarantees a good material flow.
- the flow promoters 8 are not metering systems. The alternating movement of these elements can be likened in terms of frequency to that of the blade 3 .
- the blade 3 can therefore advantageously be operated by appropriately connecting it to the actual axis H of the flow promoter 8 .
- the blade 3 regulates the amount of material that is discharged, while the flow promoter 8 promotes a correct and full supply.
- the blade 3 is autonomous or fixed to the axis of the flow promoter 8 , in the home position it is always parked outside the pile of DRI that builds up in the area 2 in the upper part of the transfer pipe 6 , and does not obstruct the flow of DRI towards the cooling vessel 5 .
- FIGS. 3 , 4 and 5 An advantageous alternative form of the regulating means, which allows the flow promoter 8 to remain active both when the blade 3 is in the home position and when acting as a meter, is illustrated in FIGS. 3 , 4 and 5 .
- the blade 3 In the home position the blade 3 continues to oscillate in an empty environment.
- there are two actuators 11 , 12 for instance hydraulic actuators, that drive two levers 13 , 14 that are integral with the axis H of the flow promoter.
- the blade 3 at work or in the home position only one of the two hydraulic actuators 11 , 12 is operational, while the hydraulic circuit of the other is short-circuited so as not to offer mechanical resistance.
- the reactor 1 can thus be discharged, simultaneously diverting a portion of the material to the transfer pipe 6 and a portion to the cooling vessel 5 , depending on the way in which the devices 3 and 10 are activated and controlled.
- the hot DRI that collects inside the transfer pipe 6 set at a slope and with an internal coating of refractory material, passes through the actual pipe together with the hot off-gases from the process.
- the pipe 6 thus simultaneously performs the following functions:
- the presence of the off-gases from the process in the transfer pipe 6 advantageously eliminates the problem of DRI re-oxidation and also promotes heat retention.
- the hot DRI that accumulates in the transfer pipe 6 is discharged towards the user, at fixed intervals of time, via a dynamic seal leg 7 , which has the function of maintaining the off-gases from the process inside the pipe 6 .
- the pipe/buffer is not thus inert.
- a second flow regulating device for instance a vibro-extractor, rotary valve, oscillating blade or the like.
- the hot DRI may be transported directly by gravity to the electric arc furnace, if the systems are arranged very close together, or transferred to the electric arc furnace by means of an inert conveyor system.
- the diameter and length of the transfer pipe 6 must be appropriately defined as a function of the volume of the buffer that is needed in order to separate the reduction furnace and the steelmaking plant.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacture Of Iron (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Furnace Details (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2005A000731 | 2005-04-22 | ||
| IT000731A ITMI20050731A1 (it) | 2005-04-22 | 2005-04-22 | Forno di riduzione |
| PCT/EP2006/061738 WO2006111574A1 (en) | 2005-04-22 | 2006-04-21 | Reduction furnace |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20090051083A1 true US20090051083A1 (en) | 2009-02-26 |
Family
ID=35670980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/918,921 Abandoned US20090051083A1 (en) | 2005-04-22 | 2006-04-21 | Reduction furnace |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20090051083A1 (pt) |
| EP (1) | EP1877714B1 (pt) |
| AT (1) | ATE458974T1 (pt) |
| BR (1) | BRPI0607534B1 (pt) |
| DE (1) | DE602006012474D1 (pt) |
| EG (1) | EG25071A (pt) |
| IT (1) | ITMI20050731A1 (pt) |
| MX (1) | MX2007013114A (pt) |
| WO (1) | WO2006111574A1 (pt) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102168185A (zh) * | 2011-03-20 | 2011-08-31 | 梁小军 | 立式还原炉 |
| US8518146B2 (en) | 2009-06-29 | 2013-08-27 | Gb Group Holdings Limited | Metal reduction processes, metallurgical processes and products and apparatus |
| US20130276584A1 (en) * | 2010-11-03 | 2013-10-24 | Technological Resources Pty. Limited | Production of iron |
| WO2020171079A1 (ja) * | 2019-02-19 | 2020-08-27 | 合同会社Kess | 直接還元鉄製造設備 |
| US20210301359A1 (en) * | 2020-03-24 | 2021-09-30 | Midrex Technologies, Inc. | Integration of dr plant and electric dri melting furnace for producing high performance iron |
| CN114921603A (zh) * | 2022-05-31 | 2022-08-19 | 中冶京诚工程技术有限公司 | 螺旋式热态直接还原铁输送装置及方法 |
| CN116516093A (zh) * | 2023-05-22 | 2023-08-01 | 河钢集团有限公司 | 一种直接还原铁的生产装置 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006062689B4 (de) * | 2006-12-21 | 2009-01-22 | Mines And Metals Engineering Gmbh (M.M.E.) | Schachtofen für die direkte Reduktion von Eisenoxid |
| AT509357B1 (de) * | 2010-01-15 | 2012-01-15 | Siemens Vai Metals Tech Gmbh | Verfahren und vorrichtung zur reduktion von eisenerzhältigen einsatzstoffen oder zur herstellung von roheisen oder flüssigen stahlvorprodukten |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4256290A (en) * | 1979-10-15 | 1981-03-17 | Pullman Incorporated | Bottom cooling arrangement for reduction apparatus |
| US4270739A (en) * | 1979-10-22 | 1981-06-02 | Midrex Corporation | Apparatus for direct reduction of iron using high sulfur gas |
| US4729786A (en) * | 1984-08-16 | 1988-03-08 | Voest-Alpine Aktiengesellschaft | Process for the direct reduction of iron-oxide-containing materials |
| US5676732A (en) * | 1995-09-15 | 1997-10-14 | Hylsa, S.A. De C.V. | Method for producing direct reduced iron utilizing a reducing gas with a high content of carbon monoxide |
| US6200363B1 (en) * | 1998-10-09 | 2001-03-13 | Midrex International B.V. Rotterdam Zurich Branch | Direct reduced iron hot/cold discharge system |
| US6214086B1 (en) * | 1999-08-20 | 2001-04-10 | Midrex International B.V. Rotterdam, Zurich Branch | Direct reduced iron discharge system and method |
-
2005
- 2005-04-22 IT IT000731A patent/ITMI20050731A1/it unknown
-
2006
- 2006-04-21 EP EP06743366A patent/EP1877714B1/en not_active Expired - Lifetime
- 2006-04-21 DE DE602006012474T patent/DE602006012474D1/de not_active Expired - Lifetime
- 2006-04-21 AT AT06743366T patent/ATE458974T1/de not_active IP Right Cessation
- 2006-04-21 BR BRPI0607534-7A patent/BRPI0607534B1/pt not_active IP Right Cessation
- 2006-04-21 WO PCT/EP2006/061738 patent/WO2006111574A1/en not_active Ceased
- 2006-04-21 US US11/918,921 patent/US20090051083A1/en not_active Abandoned
- 2006-04-21 MX MX2007013114A patent/MX2007013114A/es active IP Right Grant
-
2007
- 2007-10-22 EG EGNA2007001145 patent/EG25071A/xx active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4256290A (en) * | 1979-10-15 | 1981-03-17 | Pullman Incorporated | Bottom cooling arrangement for reduction apparatus |
| US4270739A (en) * | 1979-10-22 | 1981-06-02 | Midrex Corporation | Apparatus for direct reduction of iron using high sulfur gas |
| US4729786A (en) * | 1984-08-16 | 1988-03-08 | Voest-Alpine Aktiengesellschaft | Process for the direct reduction of iron-oxide-containing materials |
| US5676732A (en) * | 1995-09-15 | 1997-10-14 | Hylsa, S.A. De C.V. | Method for producing direct reduced iron utilizing a reducing gas with a high content of carbon monoxide |
| US6200363B1 (en) * | 1998-10-09 | 2001-03-13 | Midrex International B.V. Rotterdam Zurich Branch | Direct reduced iron hot/cold discharge system |
| US6214086B1 (en) * | 1999-08-20 | 2001-04-10 | Midrex International B.V. Rotterdam, Zurich Branch | Direct reduced iron discharge system and method |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8518146B2 (en) | 2009-06-29 | 2013-08-27 | Gb Group Holdings Limited | Metal reduction processes, metallurgical processes and products and apparatus |
| US20130276584A1 (en) * | 2010-11-03 | 2013-10-24 | Technological Resources Pty. Limited | Production of iron |
| US9376730B2 (en) * | 2010-11-03 | 2016-06-28 | Technological Resources Pty. Limited | Production of iron |
| CN102168185A (zh) * | 2011-03-20 | 2011-08-31 | 梁小军 | 立式还原炉 |
| WO2020171079A1 (ja) * | 2019-02-19 | 2020-08-27 | 合同会社Kess | 直接還元鉄製造設備 |
| US20210301359A1 (en) * | 2020-03-24 | 2021-09-30 | Midrex Technologies, Inc. | Integration of dr plant and electric dri melting furnace for producing high performance iron |
| US11788159B2 (en) * | 2020-03-24 | 2023-10-17 | Midrex Technologies, Inc. | Integration of DR plant and electric DRI melting furnace for producing high performance iron |
| CN114921603A (zh) * | 2022-05-31 | 2022-08-19 | 中冶京诚工程技术有限公司 | 螺旋式热态直接还原铁输送装置及方法 |
| CN116516093A (zh) * | 2023-05-22 | 2023-08-01 | 河钢集团有限公司 | 一种直接还原铁的生产装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| ITMI20050731A1 (it) | 2006-10-23 |
| EG25071A (en) | 2011-07-28 |
| BRPI0607534B1 (pt) | 2015-06-30 |
| BRPI0607534A2 (pt) | 2009-09-15 |
| WO2006111574A1 (en) | 2006-10-26 |
| MX2007013114A (es) | 2008-01-11 |
| ATE458974T1 (de) | 2010-03-15 |
| EP1877714A1 (en) | 2008-01-16 |
| EP1877714B1 (en) | 2010-02-24 |
| DE602006012474D1 (de) | 2010-04-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: DANIELI & C. OFFICINE MECCANICHE S.P.A., ITALY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:VRECH, ARBENO;MITOI, ILIE-FLORIAN;MARCONI, GIANFRANCO;REEL/FRAME:020043/0731 Effective date: 20060526 |
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