US20090077954A1 - Continuously regenerating particulate filter for internal combustion engine - Google Patents

Continuously regenerating particulate filter for internal combustion engine Download PDF

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Publication number
US20090077954A1
US20090077954A1 US11/859,936 US85993607A US2009077954A1 US 20090077954 A1 US20090077954 A1 US 20090077954A1 US 85993607 A US85993607 A US 85993607A US 2009077954 A1 US2009077954 A1 US 2009077954A1
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Prior art keywords
particulate filter
internal combustion
combustion engine
turbine
products
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Abandoned
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US11/859,936
Inventor
Richard E. Winsor
Kirby J. Baumgard
Ryan M. Nevin
Cuong T. Huynh
Craig W. Lohmann
Brian E. Holthaus
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Deere and Co
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Individual
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Priority to US11/859,936 priority Critical patent/US20090077954A1/en
Assigned to DEERE & COMPANY reassignment DEERE & COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BAUMGARD, KIRBY J., HOLTHAUS, BRIAN E., HUYNH, CUONG T., LOHMANN, CRAIG W., NEVIN, RYAN M., WINSOR, RICHARD E.
Priority to EP08162623A priority patent/EP2039898A1/en
Priority to CNA2008101472451A priority patent/CN101397926A/en
Priority to JP2008224447A priority patent/JP2009074543A/en
Priority to BRPI0804090-7A priority patent/BRPI0804090A2/en
Assigned to ENERGY, UNITED STATES DEPARTMENT OF reassignment ENERGY, UNITED STATES DEPARTMENT OF CONFIRMATORY LICENSE (SEE DOCUMENT FOR DETAILS). Assignors: DEERE & COMPANY
Publication of US20090077954A1 publication Critical patent/US20090077954A1/en
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/101Three-way catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0222Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • B01D2258/012Diesel engines and lean burn gasoline engines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2250/00Combinations of different methods of purification
    • F01N2250/02Combinations of different methods of purification filtering and catalytic conversion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2340/00Dimensional characteristics of the exhaust system, e.g. length, diameter or volume of the exhaust apparatus; Spatial arrangements of exhaust apparatuses
    • F01N2340/06Arrangement of the exhaust apparatus relative to the turbine of a turbocharger
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2430/00Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics
    • F01N2430/06Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics by varying fuel-air ratio, e.g. by enriching fuel-air mixture
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/14Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B37/00Engines characterised by provision of pumps driven at least for part of the time by exhaust
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/10Capture or disposal of greenhouse gases of nitrous oxide (N2O)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the present invention relates to the field of internal combustion engine systems, and more particularly to, engine systems having exhaust aftertreatment devices.
  • Internal combustion engines come in a number of forms, the most common of which are spark-ignited, gasoline-fueled engines and compression-ignition, diesel-fueled engines.
  • the spark-ignited, gasoline-fueled engine meters fuel into air, controlled by a throttle valve, to produce a mixture in the combustion chamber that is as close to stoichiometric as possible.
  • the stoichiometric air-fuel ratio is the mass ratio at which all the fuel and all the air are combined in the combustion process.
  • this air-fuel ratio is 14.7-1. Operation at this condition enables appropriate exhaust aftertreatment using a three-way catalyst to reduce oxides of nitrogen in the engine exhaust.
  • the compression-ignition, or diesel type engine is used in many commercial and industrial power applications because of outstanding durability and fuel economy superior to the spark-ignited, gasoline-fueled engine.
  • the diesel engine utilizes the heat of compression of intake air into which a timed and metered quantity of fuel is injected to produce combustion.
  • the nature of the diesel engine cycle is that it has a variable air-fuel ratio that can, under part power conditions, rise to levels significantly above stoichiometric. This results in enhanced part power fuel economy since only the quantity of fuel needed for particular power levels is supplied to the engine.
  • Stoichiometric diesel engines have been proposed to achieve this balance since they enable the use of automotive style catalysts to reduce oxides of nitrogen.
  • a three-way catalyst may be employed.
  • operation at this air fuel ratio causes a substantial increase in diesel particulates.
  • diesel particulate filters must be employed to filter out the particulates, but generation of particulates is significant enough that frequent regeneration of the filters through temporary heating or other means is necessary to remove the collected particulate matter.
  • the invention includes an internal combustion engine system having an internal combustion engine with an air intake and an exhaust for products of combustion, the products of combustion having an excess of oxygen and a temperature greater than approximately 600° C.
  • a non-catalyzed particulate filter receives products of combustion from the exhaust and a NO x reduction catalyst downstream from and receiving fluid from the particulate filter reduces the oxides of nitrogen.
  • the invention includes a method of operating an internal combustion engine system including the steps of operating an air breathing, fuel consuming, internal combustion engine to produce products of combustion in an exhaust with a temperature greater than approximately 600° C. and an excess of oxygen.
  • the products of combustion are passed over a non-catalyzed particulate filter and subsequently passed over a NO x reduction catalyst.
  • FIG. 1 is a schematic drawing of an internal combustion engine embodying the present invention
  • FIG. 2 is a schematic drawing of an alternate embodiment of the present invention.
  • FIG. 3 is still another alternative embodiment of the present invention.
  • FIG. 1 shows a power system having as its foundation an air breathing, fuel consuming, internal combustion engine 10 in which one or more pistons reciprocate within an engine block and are connected to a crankshaft for producing a rotary output.
  • Each piston forms part of a variable volume combustion chamber that receives air for combustion from an intake system 12 .
  • the products of combustion pass through an exhaust system 14 .
  • poppet valves are actuated by camshafts to open at the appropriate point in the cycle to permit intake of air or allow exhaust of the products of combustion.
  • the internal combustion engine is a compression ignition or diesel type.
  • This engine is usually characterized by having a significantly high compression ratio for intake air so that a hydrocarbon fuel will self-ignite upon injection into the air heated by the compression process.
  • a fuel system 13 delivers a metered quantity of fuel at the appropriate time interval to produce the desired power.
  • Fuel system 13 produces the fuel quantity and timing in response to selected engine operating parameters and command from a fuel system controller (not shown).
  • a turbocharger identified by reference character 16 may be employed.
  • Turbocharger 16 has a compressor 18 receiving intake air through conduit 20 and pressurizing it for delivery via conduit 17 to the intake system 12 . Consequently, the air entering the combustion chamber of the internal combustion engine 10 is at a higher density than obtainable from ambient air pressures and can produce greater power.
  • An intercooler 19 receives the air at an increased pressure and temperature from compressor 18 and cools it to increase the charge density and enable greater power output.
  • the compressor 18 is driven by a shaft 22 connected to a turbine 24 receiving the products of combustion from exhaust line 23 to be driven into rotation and thus drive compressor 18 .
  • the inlet to turbine 24 may employ variable geometry of different types to attempt to maintain gas velocity as high as possible for lower flow conditions experienced under part-power.
  • the exhaust gases that have passed over turbine 24 exit the system through exhaust line 26 where they may be subjected to exhaust aftertreatment, as described below, to reduce products in the exhaust system that are considered to be harmful to the environment.
  • a diesel particulate filter 28 is interposed in exhaust line 26 and a three-way NO x catalyst 30 is provided in exhaust line 26 downstream of diesel particulate filter 28 .
  • Internal combustion engine 10 is operated as a stoichiometric diesel engine in that the ratio of combustion air to fuel consumed by the engine 10 is approximately stoichiometric, which is usually about 14.7 to 1. The mixture is based on air mass to fuel mass flow in the exhaust. Stoichiometric means that the mixture contains only the proper amount of oxygen to consume all of the fuel in the combustion process. However, because combustion is not complete, the exhaust from a stoichiometric engine contains some oxygen which is typically 0.5 to 0.8% even though the overall fuel air ratio is stoichiometric.
  • the oxygen thus contained in the engine exhaust is balanced by a similar amount of carbon monoxide and hydrogen so that there is no excess oxygen since this would prevent the NO x reduction catalyst 30 from removing NO x in the engine exhaust.
  • its exhaust is very hot and is generally greater than approximately 600° C.
  • the diesel particulate filter 28 is absent a catalytic treatment and may be a wall-flow monolithic particulate filter. It should be apparent to those skilled in the art that other forms of uncatalyzed particulate filters may also be employed.
  • the most common particulate filter is made of cordierite (a ceramic material that is also used as catalytic converter support (core). Cordierite filters provide excellent filtration efficiency, are (relatively) inexpensive, and have thermal properties that simplifiy vehicle packaging.
  • the second most popular filter material is silicon carbide or SiC.
  • the small amount of oxygen present is able to continuously oxidize the collected particulate matter on the particulate filter 28 .
  • the NO x reduction catalyst 30 (or three-way catalyst, is employed to eliminate oxides of nitrogen and other harmful components, such as carbon monoxide and hydrocarbons in the exhaust. By placing the uncatalyzed particulate filter 28 ahead of the NO x reduction catalyst 30 , the temperature is sufficiently high to cause the accumulated carbon on the particulate filter 28 to oxidize.
  • the particulate filter 28 and the NO x catalyst 30 are placed downstream of the turbine in exhaust line 26 .
  • the particulate filter 28 is placed upstream of turbine 24 in exhaust line 23 and the NO x catalyst 30 placed downstream of turbine 24 . This may be done to place the diesel particulate filter in a fluid stream that is sufficiently hot to maintain a continuous oxidization of carbon particles collected on the particulate filter 28 .
  • the NO x catalyst 30 is downstream of the uncatalyzed particulate filter 28 .
  • FIG. 3 shows still another arrangement in which both the particulate filter 28 and NO x catalyst 30 are placed upstream of turbine 24 in exhaust line 23 . Again, it is noted that the uncatalyzed particulate filter 28 is upstream of NO x catalyst 30 to provide maximum temperature and oxygen for continuous oxidization of the carbon particles thus accumulated.
  • the engine system is shown incorporating a turbocharger 16 , it should be apparent to those skilled in the art that the engine 10 may also be operated without a turbocharger and still realize the benefits of the uncatalyzed particulate filter upstream of the NO x catalyst.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Filtering Materials (AREA)

Abstract

An internal combustion engine system having a non-catalyzed particulate filter receiving products of combustion at a temperature of frequently above 600° C. and an excess of oxygen of between 0.5 and 0.8% from a stoichiometric diesel engine. A NOx reduction catalyst is positioned downstream of the particulate filter. The engine system may include a turbocharger and the particulate filter and NOx reduction catalyst may be positioned either upstream of the turbine or downstream of the turbine or alternatively the particulate filter upstream of the turbine and the NOx reduction catalyst downstream of the turbine.

Description

    GOVERNMENT RIGHTS IN PATENT
  • This invention was made with Government support under contract DE-FC26-05NT42416 awarded by the Department of Energy. The U.S. government may have certain rights in this invention.
  • FIELD OF THE INVENTION
  • The present invention relates to the field of internal combustion engine systems, and more particularly to, engine systems having exhaust aftertreatment devices.
  • BACKGROUND OF THE INVENTION
  • Internal combustion engines come in a number of forms, the most common of which are spark-ignited, gasoline-fueled engines and compression-ignition, diesel-fueled engines. The spark-ignited, gasoline-fueled engine meters fuel into air, controlled by a throttle valve, to produce a mixture in the combustion chamber that is as close to stoichiometric as possible. The stoichiometric air-fuel ratio is the mass ratio at which all the fuel and all the air are combined in the combustion process. For gasoline-fueled, spark-ignited engines; this air-fuel ratio is 14.7-1. Operation at this condition enables appropriate exhaust aftertreatment using a three-way catalyst to reduce oxides of nitrogen in the engine exhaust.
  • The compression-ignition, or diesel type engine, is used in many commercial and industrial power applications because of outstanding durability and fuel economy superior to the spark-ignited, gasoline-fueled engine. The diesel engine utilizes the heat of compression of intake air into which a timed and metered quantity of fuel is injected to produce combustion. The nature of the diesel engine cycle is that it has a variable air-fuel ratio that can, under part power conditions, rise to levels significantly above stoichiometric. This results in enhanced part power fuel economy since only the quantity of fuel needed for particular power levels is supplied to the engine.
  • One of the issues with an engine of this type is the impact on emissions. In addition to generation of carbon monoxide and nitrous oxide, there is the generation of particulates in the form of soot. A number of approaches have been employed to reduce particulates while at the same time reducing oxides of nitrogen to evermore stringent levels mandated by the federal government.
  • Stoichiometric diesel engines have been proposed to achieve this balance since they enable the use of automotive style catalysts to reduce oxides of nitrogen. By operating the engine at or near stoichiometric, generally around 14.7 ratio of air to fuel, a three-way catalyst may be employed. However, operation at this air fuel ratio causes a substantial increase in diesel particulates. Accordingly, diesel particulate filters must be employed to filter out the particulates, but generation of particulates is significant enough that frequent regeneration of the filters through temporary heating or other means is necessary to remove the collected particulate matter.
  • Accordingly a need exists in the art to provide an engine system of this type having a superior ability to regenerate a diesel particulate filter.
  • SUMMARY OF THE INVENTION
  • In one form, the invention includes an internal combustion engine system having an internal combustion engine with an air intake and an exhaust for products of combustion, the products of combustion having an excess of oxygen and a temperature greater than approximately 600° C. A non-catalyzed particulate filter receives products of combustion from the exhaust and a NOx reduction catalyst downstream from and receiving fluid from the particulate filter reduces the oxides of nitrogen.
  • In another form, the invention includes a method of operating an internal combustion engine system including the steps of operating an air breathing, fuel consuming, internal combustion engine to produce products of combustion in an exhaust with a temperature greater than approximately 600° C. and an excess of oxygen. The products of combustion are passed over a non-catalyzed particulate filter and subsequently passed over a NOx reduction catalyst.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic drawing of an internal combustion engine embodying the present invention;
  • FIG. 2 is a schematic drawing of an alternate embodiment of the present invention; and
  • FIG. 3 is still another alternative embodiment of the present invention.
  • DETAILED DESCRIPTION OF THE INVENTION
  • FIG. 1 shows a power system having as its foundation an air breathing, fuel consuming, internal combustion engine 10 in which one or more pistons reciprocate within an engine block and are connected to a crankshaft for producing a rotary output. Each piston forms part of a variable volume combustion chamber that receives air for combustion from an intake system 12. The products of combustion pass through an exhaust system 14. In typical fashion, poppet valves (not shown to simplify the understanding of the invention) are actuated by camshafts to open at the appropriate point in the cycle to permit intake of air or allow exhaust of the products of combustion. As herein shown, the internal combustion engine is a compression ignition or diesel type. This engine is usually characterized by having a significantly high compression ratio for intake air so that a hydrocarbon fuel will self-ignite upon injection into the air heated by the compression process. In such an engine, a fuel system 13 delivers a metered quantity of fuel at the appropriate time interval to produce the desired power. Fuel system 13 produces the fuel quantity and timing in response to selected engine operating parameters and command from a fuel system controller (not shown).
  • In an attempt to further increase the efficiency of the engine 10, a turbocharger, identified by reference character 16 may be employed. Turbocharger 16 has a compressor 18 receiving intake air through conduit 20 and pressurizing it for delivery via conduit 17 to the intake system 12. Consequently, the air entering the combustion chamber of the internal combustion engine 10 is at a higher density than obtainable from ambient air pressures and can produce greater power. An intercooler 19 receives the air at an increased pressure and temperature from compressor 18 and cools it to increase the charge density and enable greater power output.
  • The compressor 18 is driven by a shaft 22 connected to a turbine 24 receiving the products of combustion from exhaust line 23 to be driven into rotation and thus drive compressor 18. The inlet to turbine 24 may employ variable geometry of different types to attempt to maintain gas velocity as high as possible for lower flow conditions experienced under part-power. The exhaust gases that have passed over turbine 24 exit the system through exhaust line 26 where they may be subjected to exhaust aftertreatment, as described below, to reduce products in the exhaust system that are considered to be harmful to the environment.
  • A diesel particulate filter 28 is interposed in exhaust line 26 and a three-way NOx catalyst 30 is provided in exhaust line 26 downstream of diesel particulate filter 28. Internal combustion engine 10 is operated as a stoichiometric diesel engine in that the ratio of combustion air to fuel consumed by the engine 10 is approximately stoichiometric, which is usually about 14.7 to 1. The mixture is based on air mass to fuel mass flow in the exhaust. Stoichiometric means that the mixture contains only the proper amount of oxygen to consume all of the fuel in the combustion process. However, because combustion is not complete, the exhaust from a stoichiometric engine contains some oxygen which is typically 0.5 to 0.8% even though the overall fuel air ratio is stoichiometric. The oxygen thus contained in the engine exhaust is balanced by a similar amount of carbon monoxide and hydrogen so that there is no excess oxygen since this would prevent the NOx reduction catalyst 30 from removing NOx in the engine exhaust. By operating the engine 10 in a stoichiometric manner, its exhaust is very hot and is generally greater than approximately 600° C.
  • The diesel particulate filter 28 is absent a catalytic treatment and may be a wall-flow monolithic particulate filter. It should be apparent to those skilled in the art that other forms of uncatalyzed particulate filters may also be employed. The most common particulate filter is made of cordierite (a ceramic material that is also used as catalytic converter support (core). Cordierite filters provide excellent filtration efficiency, are (relatively) inexpensive, and have thermal properties that simplifiy vehicle packaging. The second most popular filter material is silicon carbide or SiC.
  • Because the exhaust of the engine 10 is hot, the small amount of oxygen present is able to continuously oxidize the collected particulate matter on the particulate filter 28. This occurs because the particulate filter 28 has no catalytic treatment since the presence of the catalyst would cause the oxygen to preferentially react with carbon monoxide and hydrogen and leave the carbon collected by the filter unreacted. After the exhaust gas has passed through the particulate filter, the NOx reduction catalyst 30 (or three-way catalyst, is employed to eliminate oxides of nitrogen and other harmful components, such as carbon monoxide and hydrocarbons in the exhaust. By placing the uncatalyzed particulate filter 28 ahead of the NOx reduction catalyst 30, the temperature is sufficiently high to cause the accumulated carbon on the particulate filter 28 to oxidize.
  • As shown in FIG. 1, the particulate filter 28 and the NOx catalyst 30 are placed downstream of the turbine in exhaust line 26. In FIG. 2 however, the particulate filter 28 is placed upstream of turbine 24 in exhaust line 23 and the NOx catalyst 30 placed downstream of turbine 24. This may be done to place the diesel particulate filter in a fluid stream that is sufficiently hot to maintain a continuous oxidization of carbon particles collected on the particulate filter 28. It should be noted that in this embodiment also, the NOx catalyst 30 is downstream of the uncatalyzed particulate filter 28.
  • FIG. 3 shows still another arrangement in which both the particulate filter 28 and NOx catalyst 30 are placed upstream of turbine 24 in exhaust line 23. Again, it is noted that the uncatalyzed particulate filter 28 is upstream of NOx catalyst 30 to provide maximum temperature and oxygen for continuous oxidization of the carbon particles thus accumulated.
  • Although the engine system is shown incorporating a turbocharger 16, it should be apparent to those skilled in the art that the engine 10 may also be operated without a turbocharger and still realize the benefits of the uncatalyzed particulate filter upstream of the NOx catalyst.
  • Having described the preferred embodiment, it will become apparent that various modifications can be made without departing from the scope of the invention as defined in the accompanying claims.

Claims (20)

1. An internal combustion engine system comprising:
an internal combustion engine having an air intake and an exhaust for products of combustion, said products of combustion having an excess of oxygen and a temperature frequently greater than approximately 600° C.;
a non-catalyzed particulate filter receiving products of combustion from said exhaust; and
a NOx reduction catalyst downstream from and receiving fluid from said particulate filter.
2. An internal combustion engine system as claimed in claim 1, wherein said internal combustion engine is a stoichiometric diesel engine.
3. An internal combustion engine system as claimed in claim 2, wherein said excess oxygen is up to approximately 0.8%.
4. An internal combustion engine system as claimed in claim 3, wherein said excess oxygen is between approximately 0.5 and 0.8%.
5. An internal combustion engine system as claimed in claim 1, further comprising a pressurizing device including a turbine receiving the exhaust products of combustion to drive a compressor.
6. An internal combustion engine system as claimed in claim 5, wherein said particulate filter and NOx reduction catalyst are positioned downstream from and receiving fluid from said turbine.
7. An internal combustion engine system as claimed in claim 5, wherein said particulate filter is upstream of said turbine and said NOx reduction catalyst is downstream of said turbine.
8. An internal combustion engine system as claimed in claim 5, wherein said particulate filter and said NOx reduction catalyst are positioned upstream of said turbine.
9. An internal combustion engine system as claimed in claim 1, wherein said particulate filter is a ceramic filter.
10. An internal combustion engine system as claimed in claim 1, wherein said NOx reduction catalyst is a three-way catalyst.
11. A method of operating an internal combustion engine system comprising the steps of:
operating an air breathing, fuel consuming internal combustion engine to produce products of combustion on an exhaust with a temperature frequently greater than approximately 600° C. and an excess of oxygen;
passing said products of combustion through a non-catalyzed particulate filter; and subsequently passing said products of combustion over a NOx reduction catalyst.
12. A method as claimed in claim 11, wherein said internal combustion engine is a stoichiometric diesel.
13. A method as claimed in claim 11, wherein said excess of oxygen is up to approximately 0.8%.
14. A method as claimed in claim 13, wherein said excess oxygen is between approximately 0.5 and 0.8%.
15. A method as claimed in claim 11, wherein said engine is operated with a pressurizing device including a turbine receiving the products of combustion from said engine to drive a pressurizing device.
16. A method as claimed in claim 15, wherein said products of combustion are passed through said non-catalyzed particulate filter and said NOx reduction catalyst downstream of said turbine.
17. A method as claimed in claim 15, wherein said products of combustion are passed through said non-catalyzed particulate filter upstream of said turbine and said products of combustion are passed over said NOx reduction catalyst downstream of said turbine.
18. A method as claimed in claim 15, wherein said products of combustion are passed through said non-catalyzed particulate filter and said NOx reduction catalyst downstream of said turbine.
19. A method as claimed in claim 15, wherein said particulate filter is a ceramic filter.
20. A method as claimed in claim 15, wherein said NOx reduction catalyst is a three-way catalyst.
US11/859,936 2007-09-24 2007-09-24 Continuously regenerating particulate filter for internal combustion engine Abandoned US20090077954A1 (en)

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EP08162623A EP2039898A1 (en) 2007-09-24 2008-08-19 Continuously regenerating particulate filter for internal combustion engine
CNA2008101472451A CN101397926A (en) 2007-09-24 2008-08-25 Continuously regenerating particulate filter for internal combustion engine
JP2008224447A JP2009074543A (en) 2007-09-24 2008-09-02 Continuously regenerating particulate filter for internal combustion engine
BRPI0804090-7A BRPI0804090A2 (en) 2007-09-24 2008-09-10 internal combustion engine system and method of operating an internal combustion engine system

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