US2010423A - Method of manufacturing asphalt and product thereof - Google Patents
Method of manufacturing asphalt and product thereof Download PDFInfo
- Publication number
- US2010423A US2010423A US631369A US63136932A US2010423A US 2010423 A US2010423 A US 2010423A US 631369 A US631369 A US 631369A US 63136932 A US63136932 A US 63136932A US 2010423 A US2010423 A US 2010423A
- Authority
- US
- United States
- Prior art keywords
- asphalt
- oil
- product
- crude
- asphaltic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010426 asphalt Substances 0.000 title description 15
- 238000004519 manufacturing process Methods 0.000 title description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 6
- 239000010727 cylinder oil Substances 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 239000003518 caustics Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
- C10C3/005—Working-up pitch, asphalt, bitumen by mixing several fractions (also coaltar fractions with petroleum fractions)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
- C10C3/08—Working-up pitch, asphalt, bitumen by selective extraction
Definitions
- this invention relates to emulsifying fluxes, which are prepared according to this in- Patented Aug. 6, 19 35 METHOD OF MANUFACTURING ASPHALT AND PRODUCT THEREOF Alfred A. Wells, Roselle Park, N. J.,' assignor to Standard Oil Development Company, a corporation of Delaware No Drawing.
- This invention relates to a new and improved method in the art of manufacturing asphalt by blending heavy petroleum hydrocarbons. More vention by blending high melting point asphalt with an-extract derived from a cylinder oil fraction from the same crudefrom which the asphalt was derived or from another crude; the said extract being obtained by extracting with either phenol, sulfur dioxide, furfural or similar solvents.
- An object of this invention is to produce amaximum yield of a cylinder stock and of an asphalt of low melting point from the same crude.
- Another object of this invention is the production of a cylinder oil of low organic acidity.
- the cylinder oil fraction is then extracted with sulfur dioxide, phenol or furfural or similar selective solvents to give higher A. P. I. gravity, improved viscosity index and better stability, that is more resistant to oxidation, than other methods of treatment.
- the extracted material is separated from the solvent and incorporated with the asphaltic residue It is desirable in some cases to redistill the extracted oil so as to give a higher -viscositY blending stock; caustic such as sodium hydroxide may be incorporated during distillation if desired to remove any organic acids or solvent that may still be present in the oil.
- I finished asphalt will vary with proportions of extract and high melting asphalt.
- the mixture of asphalt and solvent extract may then be used as such or it may be used in making emulsions upon the addition of caustic soda and oleic acid.
- Other dis leu By this extracted material melting point asphalt in proper proportion so as to give a final product which is equivalent to or superior to the asphaltic product which would have been obtained on desired melting point. over other asphalts in ing asphalt with a better softening point penetration relationship and also a better softening point ductility relationship.
- the penetration characteristics vary with the melting point of the This method allows th trol so that he can vary cial requirements, which up required processing special special requirements. that material extracted from cylinder oil from one crude can be blende sources of a mixture. If desired, the asphalt may also be oxidized.
- Another advantage of this method is improving the maximum yield of cylinder stock from different crudes.
- An asphalt compris residues obtained from solvent extraction 0 of the same petroleum oil that .is liquid at atmospheric perature, of the group consisting of phenol and furfural.
- a method of manufac comprises subjectin separating the ligh fractions from an asphaltic residue, subjecting the higher boiling fractions to solvent extraction with an organic solvent pheric pressure and consisting of phenol and extracted material from the extracted material 3.
- a method comprises subjectin September 1, 1932, Serial No. 631,369 a 6 Claims. (Cl. 196-74) m oil containing idue'.
- tillation to separa emulsifying agents other than caustic soda and oleic acid may be substituted.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Working-Up Tar And Pitch (AREA)
- Lubricants (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US631369A US2010423A (en) | 1932-09-01 | 1932-09-01 | Method of manufacturing asphalt and product thereof |
| FR753036D FR753036A (fr) | 1932-09-01 | 1933-03-23 | Procédé de fabrication d'asphaltes |
| DEST51239D DE653646C (de) | 1932-09-01 | 1933-09-01 | Verfahren zur Gewinnung von niedrigschmelzenden Asphalten |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US631369A US2010423A (en) | 1932-09-01 | 1932-09-01 | Method of manufacturing asphalt and product thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2010423A true US2010423A (en) | 1935-08-06 |
Family
ID=24530907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US631369A Expired - Lifetime US2010423A (en) | 1932-09-01 | 1932-09-01 | Method of manufacturing asphalt and product thereof |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US2010423A (fr) |
| DE (1) | DE653646C (fr) |
| FR (1) | FR753036A (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2783162A (en) * | 1954-04-23 | 1957-02-26 | Gilman B Mollring | Method of producing a composite liquid bituminous binder |
| US2783163A (en) * | 1954-05-25 | 1957-02-26 | Gilman B Mollring | Road making and the like |
| US3476679A (en) * | 1966-08-19 | 1969-11-04 | Sinclair Research Inc | Asphalt blends of hydrocarbon precipitated asphalts with hydrocarbon aromatic extracts |
| US4462893A (en) * | 1981-09-24 | 1984-07-31 | Mitsubishi Oil Company, Ltd. | Process for producing pitch for using as raw material for carbon fibers |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1093283B (de) * | 1957-06-14 | 1960-11-17 | Deutsche Erdoel Ag | Verfahren zur Herstellung von synthetischem Bitumen |
| DE1125342B (de) * | 1958-12-29 | 1962-03-08 | Felix Hempel | Verfahren zur Herstellung von Bitumina mit ganz bestimmten rheologischen Eigenschaften |
-
1932
- 1932-09-01 US US631369A patent/US2010423A/en not_active Expired - Lifetime
-
1933
- 1933-03-23 FR FR753036D patent/FR753036A/fr not_active Expired
- 1933-09-01 DE DEST51239D patent/DE653646C/de not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2783162A (en) * | 1954-04-23 | 1957-02-26 | Gilman B Mollring | Method of producing a composite liquid bituminous binder |
| US2783163A (en) * | 1954-05-25 | 1957-02-26 | Gilman B Mollring | Road making and the like |
| US3476679A (en) * | 1966-08-19 | 1969-11-04 | Sinclair Research Inc | Asphalt blends of hydrocarbon precipitated asphalts with hydrocarbon aromatic extracts |
| US4462893A (en) * | 1981-09-24 | 1984-07-31 | Mitsubishi Oil Company, Ltd. | Process for producing pitch for using as raw material for carbon fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| DE653646C (de) | 1937-11-29 |
| FR753036A (fr) | 1933-10-05 |
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