US20110178203A1 - High strength glue formulation - Google Patents
High strength glue formulation Download PDFInfo
- Publication number
- US20110178203A1 US20110178203A1 US12/907,583 US90758310A US2011178203A1 US 20110178203 A1 US20110178203 A1 US 20110178203A1 US 90758310 A US90758310 A US 90758310A US 2011178203 A1 US2011178203 A1 US 2011178203A1
- Authority
- US
- United States
- Prior art keywords
- formulation
- urethane polymer
- operative
- compound
- sancure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000009472 formulation Methods 0.000 title claims abstract description 79
- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 239000003292 glue Substances 0.000 title claims abstract description 26
- 229920000642 polymer Polymers 0.000 claims abstract description 46
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 43
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000003115 biocidal effect Effects 0.000 claims abstract description 13
- 239000003139 biocide Substances 0.000 claims abstract description 13
- 150000002148 esters Chemical class 0.000 claims abstract description 12
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 11
- 239000013530 defoamer Substances 0.000 claims abstract description 11
- 239000004034 viscosity adjusting agent Substances 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 23
- 239000006254 rheological additive Substances 0.000 claims description 8
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims description 5
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical group CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 claims description 5
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical group [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- 229910000077 silane Inorganic materials 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- 244000005700 microbiome Species 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000005187 foaming Methods 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 239000004836 Glue Stick Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 240000002989 Euphorbia neriifolia Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000013500 performance material Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 235000019605 sweet taste sensations Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/80—Compositions for aqueous adhesives
Definitions
- the described invention relates in general to a glue or adhesive formulation, and more specifically to a two-part polyurethane, pourable glue formulation.
- glue products such as glue sticks typically include PVP (polyvinylpyrrolidone) or modified-PVOH (polyvinyl alcohol) polymers. These polymers provide such glue products with the strength required to adhere paper items to one another, but lack the adhesive capacity to join other more difficult materials such as wood, metal and plastic.
- PVP polyvinylpyrrolidone
- modified-PVOH polyvinyl alcohol
- current water-based wood glues utilize PVAc (polyvinyl acetate) for adhering wood substrates to one another. When adhesion is required for non-wood substrates, either a two-part epoxy or a one-part polyurethane adhesive is typically used.
- Waterborne urethane polymers are sometimes used as a base for products such as waterproof stains or clear shellacs.
- these polymers are not typically used for arts and crafts applications despite the fact that polyurethanes have a greater range of adhesion than many of the polymers used to formulate the glues and adhesives discussed above. Therefore, there is an ongoing need for a high-strength glue formulation for joining wood, metal and plastic, wherein the glue formulation includes waterborne polyurethanes.
- a pourable glue formulation includes a first urethane polymer, wherein the first urethane polymer is operative to provide adequate tensile strength to the formulation; a second urethane polymer, wherein the second urethane polymer is operative to provide adequate flexibility to the formulation; a compound operative to provide freeze-thaw stability to the formulation; a compound operative to confer film-forming properties to the formulation; a compound operative to limit the growth of microorganisms in the formulation; a compound operative to provide additional final strength to the formulation; a compound operative to provide a desirable final viscosity to the formulation; and a compound operative to prevent the formulation from foaming during mixing of the ingredients therein.
- a pourable glue formulation includes a first urethane polymer, wherein the first urethane polymer is operative to provide adequate tensile strength to the formulation; a second urethane polymer, wherein the second urethane polymer is operative to provide adequate flexibility to the formulation; a compound operative to provide freeze-thaw stability to the formulation; an ester alcohol; a biocide; a crosslinking agent; a viscosity modifier; and defoamer.
- a pourable glue formulation includes a first urethane polymer, wherein the first urethane polymer is Sancure 898; a second urethane polymer, wherein the second urethane polymer is Sancure 777F; a compound operative to provide freeze-thaw stability to the formulation such as propylene glycol; an ester alcohol, wherein the ester alcohol is Texanol; a biocide, wherein the biocide is Acticide LA; a crosslinking agent, wherein the crosslinking agent is CoatOsil 1770 silane; a rheology modifier, wherein the rheology modifier is Acrysol RM-825; and a defoamer, wherein the defoamer is Surfynol DF-58.
- a pourable glue formulation includes a first urethane polymer, wherein the first urethane polymer is operative to provide adequate tensile strength to the formulation; a second urethane polymer, wherein the second urethane polymer is operative to provide adequate flexibility to the formulation; propylene glycol for conferring freeze-thaw stability to the glue formulation; an ester alcohol for conferring film-forming properties to the formulation; a biocide for preventing or at least limiting the growth of microorganisms in the formulation; a crosslinking agent for providing additional final strength to the formulation; a rheology modifier for providing a desirable final viscosity to the formulation; and a defoamer preventing or at least reducing any tendency of the formulation to foam during mixing of the ingredients therein (i.e., during the manufacturing process.
- the first urethane polymer is Sancure® 898 (Lubrizol), which is an aliphatic waterborne urethane polymer that forms a very hard, flexible, clear, high gloss film upon drying, offers a high performance coating with very good stain, chemical and water resistance, and that provides good elongation at high tensile strength.
- the second urethane polymer is Sancure® 777F (Lubrizol), which is an aliphatic waterborne urethane polymer that offers very good abrasion resistance, provides high gloss and good shear stability, and that exhibits adhesion to a wide variety of substrates including nylon and polyester.
- Propylene glycol is used to confer freeze-thaw stability to the glue formulation, although other suitable stabilizers known to those of ordinary skill in the art are also compatible with this invention.
- Propylene glycol is an organic compound (a diol or double alcohol) with the formula C 3 H 8 O 2 and is a colorless, nearly odorless, clear, viscous liquid with a faintly sweet taste that is hygroscopic and miscible with water, acetone, and chloroform.
- the ester alcohol is TexonalTM (Eastman Chemical Company), which is a coalescent for latex paints typically used in the architectural, industrial, and maintenance markets. Texanol ester alcohol provides a high level of film integrity at low levels of coalescent.
- the biocide is Acticide® LA (Thor), which is a combination wet state biocide for water based products. Its active ingredients provide a wide spectrum of activity against both bacteria and fungi, including species that are difficult to control. This product is particularly effective against pre-existing contamination and is approved for use in craft products by the ACMI (Art & Creative Materials Institute, Inc.).
- the crosslinking agent is CoatOsil® 1770 silane (Momentive Performance Materials), which crosslinks under heat or at room temperature on alkaline substrates and that enhances waterborne coating performance, appearance and handling.
- the defoamer is Surfynol® DF-58 (Air Products), which is a silicone-based foam control agent useful in aqueous systems.
- the viscosity or rheology modifier is AcrysolTM RM-825 (Rohm and Haas), which is a non-ionic, medium shear viscosity builder that can be used as a co-thickener in many types of formulations for attaining a desired balance of low and high shear viscosities.
- the various ingredients are present in the following percentages (by weight):
- Sancure 898 (urethane polymer) 56.95 Sancure 777F (urethane polymer) 40.0 Propylene glycol 1.00 Texanol (ester alcohol) 0.25 Acticide LA (biocide) 0.10 Cotasil 1770 Silane 0.10 Surfynol DF-58 (defoamer) 0.10 Acrysol RM-825 (rheology modifier) 1.50 100.0
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
A pourable glue formulation is provided. The pourable glue formulation includes a first urethane polymer, wherein the first urethane polymer is operative to provide adequate tensile strength to the formulation; a second urethane polymer, wherein the second urethane polymer is operative to provide adequate flexibility to the formulation; propylene glycol; an ester alcohol; a biocide; a crosslinking agent; a defoamer; and a viscosity modifier.
Description
- This patent application claims the benefit of U.S. Provisional Patent Application Ser. No. 61/252,921 filed on Oct. 19, 2009, and entitled “High Strength Glue Stick”, the disclosure of which is hereby incorporated by reference herein in its entirety and made part of the present U.S. utility patent application for all purposes.
- The described invention relates in general to a glue or adhesive formulation, and more specifically to a two-part polyurethane, pourable glue formulation. Some commercially available glue products such as glue sticks typically include PVP (polyvinylpyrrolidone) or modified-PVOH (polyvinyl alcohol) polymers. These polymers provide such glue products with the strength required to adhere paper items to one another, but lack the adhesive capacity to join other more difficult materials such as wood, metal and plastic. With regard to pourable glue products, current water-based wood glues utilize PVAc (polyvinyl acetate) for adhering wood substrates to one another. When adhesion is required for non-wood substrates, either a two-part epoxy or a one-part polyurethane adhesive is typically used.
- Waterborne urethane polymers are sometimes used as a base for products such as waterproof stains or clear shellacs. However, these polymers are not typically used for arts and crafts applications despite the fact that polyurethanes have a greater range of adhesion than many of the polymers used to formulate the glues and adhesives discussed above. Therefore, there is an ongoing need for a high-strength glue formulation for joining wood, metal and plastic, wherein the glue formulation includes waterborne polyurethanes.
- The following provides a summary of certain exemplary embodiments of the present invention. This summary is not an extensive overview and is not intended to identify key or critical aspects or elements of the present invention or to delineate its scope.
- In accordance with one aspect of the present invention, a pourable glue formulation is provided. This pourable glue formulation includes a first urethane polymer, wherein the first urethane polymer is operative to provide adequate tensile strength to the formulation; a second urethane polymer, wherein the second urethane polymer is operative to provide adequate flexibility to the formulation; a compound operative to provide freeze-thaw stability to the formulation; a compound operative to confer film-forming properties to the formulation; a compound operative to limit the growth of microorganisms in the formulation; a compound operative to provide additional final strength to the formulation; a compound operative to provide a desirable final viscosity to the formulation; and a compound operative to prevent the formulation from foaming during mixing of the ingredients therein.
- In accordance with another aspect of the present invention, a pourable glue formulation is provided. This pourable glue formulation includes a first urethane polymer, wherein the first urethane polymer is operative to provide adequate tensile strength to the formulation; a second urethane polymer, wherein the second urethane polymer is operative to provide adequate flexibility to the formulation; a compound operative to provide freeze-thaw stability to the formulation; an ester alcohol; a biocide; a crosslinking agent; a viscosity modifier; and defoamer.
- In yet another aspect of this invention, a pourable glue formulation is provided. This pourable glue formulation includes a first urethane polymer, wherein the first urethane polymer is Sancure 898; a second urethane polymer, wherein the second urethane polymer is Sancure 777F; a compound operative to provide freeze-thaw stability to the formulation such as propylene glycol; an ester alcohol, wherein the ester alcohol is Texanol; a biocide, wherein the biocide is Acticide LA; a crosslinking agent, wherein the crosslinking agent is CoatOsil 1770 silane; a rheology modifier, wherein the rheology modifier is Acrysol RM-825; and a defoamer, wherein the defoamer is Surfynol DF-58.
- Additional features and aspects of the present invention will become apparent to those of ordinary skill in the art upon reading and understanding the following detailed description of the exemplary embodiments. As will be appreciated by the skilled artisan, further embodiments of the invention are possible without departing from the scope and spirit of the invention. Accordingly, the associated descriptions are to be regarded as illustrative and not restrictive in nature.
- Exemplary embodiments of the present invention are now described. Although the following detailed description contains many specifics for the purposes of illustration, a person of ordinary skill in the art will appreciate that many variations and alterations to the following details are within the scope of the invention. Accordingly, the following embodiments of the invention are set forth without any loss of generality to, and without imposing limitations upon, the claimed invention.
- The present invention relates to an adhesive or glue formulation. In an exemplary embodiment of the present invention, a pourable glue formulation is provided. This pourable glue formulation includes a first urethane polymer, wherein the first urethane polymer is operative to provide adequate tensile strength to the formulation; a second urethane polymer, wherein the second urethane polymer is operative to provide adequate flexibility to the formulation; propylene glycol for conferring freeze-thaw stability to the glue formulation; an ester alcohol for conferring film-forming properties to the formulation; a biocide for preventing or at least limiting the growth of microorganisms in the formulation; a crosslinking agent for providing additional final strength to the formulation; a rheology modifier for providing a desirable final viscosity to the formulation; and a defoamer preventing or at least reducing any tendency of the formulation to foam during mixing of the ingredients therein (i.e., during the manufacturing process.
- More specifically, in the exemplary embodiment, the first urethane polymer is Sancure® 898 (Lubrizol), which is an aliphatic waterborne urethane polymer that forms a very hard, flexible, clear, high gloss film upon drying, offers a high performance coating with very good stain, chemical and water resistance, and that provides good elongation at high tensile strength. The second urethane polymer is Sancure® 777F (Lubrizol), which is an aliphatic waterborne urethane polymer that offers very good abrasion resistance, provides high gloss and good shear stability, and that exhibits adhesion to a wide variety of substrates including nylon and polyester. Propylene glycol is used to confer freeze-thaw stability to the glue formulation, although other suitable stabilizers known to those of ordinary skill in the art are also compatible with this invention. Propylene glycol is an organic compound (a diol or double alcohol) with the formula C3H8O2 and is a colorless, nearly odorless, clear, viscous liquid with a faintly sweet taste that is hygroscopic and miscible with water, acetone, and chloroform. The ester alcohol is Texonal™ (Eastman Chemical Company), which is a coalescent for latex paints typically used in the architectural, industrial, and maintenance markets. Texanol ester alcohol provides a high level of film integrity at low levels of coalescent. The biocide is Acticide® LA (Thor), which is a combination wet state biocide for water based products. Its active ingredients provide a wide spectrum of activity against both bacteria and fungi, including species that are difficult to control. This product is particularly effective against pre-existing contamination and is approved for use in craft products by the ACMI (Art & Creative Materials Institute, Inc.). The crosslinking agent is CoatOsil® 1770 silane (Momentive Performance Materials), which crosslinks under heat or at room temperature on alkaline substrates and that enhances waterborne coating performance, appearance and handling. The defoamer is Surfynol® DF-58 (Air Products), which is a silicone-based foam control agent useful in aqueous systems. It has strong foam control and de-aeration performance in water-based formulations. The viscosity or rheology modifier is Acrysol™ RM-825 (Rohm and Haas), which is a non-ionic, medium shear viscosity builder that can be used as a co-thickener in many types of formulations for attaining a desired balance of low and high shear viscosities.
- Having generally described this invention, a further understanding can be obtained by reference to certain specific examples detailed below, which are provided for purposes of illustration only and are not intended to be all inclusive or limiting unless otherwise specified.
- In the exemplary embodiment, the various ingredients are present in the following percentages (by weight):
-
Sancure 898 (urethane polymer) 56.95 Sancure 777F (urethane polymer) 40.0 Propylene glycol 1.00 Texanol (ester alcohol) 0.25 Acticide LA (biocide) 0.10 Cotasil 1770 Silane 0.10 Surfynol DF-58 (defoamer) 0.10 Acrysol RM-825 (rheology modifier) 1.50 100.0 - While the present invention has been illustrated by the description of exemplary embodiments thereof, and while the embodiments have been described in certain detail, it is not the intention of the Applicant to restrict or in any way limit the scope of the appended claims to such detail. Additional advantages and modifications will readily appear to those skilled in the art. Therefore, the invention in its broader aspects is not limited to any of the specific details, representative devices and methods, and/or illustrative examples shown and described. Accordingly, departures may be made from such details without departing from the spirit or scope of the applicant's general inventive concept.
Claims (19)
1) A pourable glue formulation, comprising:
(a) a first urethane polymer, wherein the first urethane polymer is operative to provide adequate tensile strength to the formulation;
(b) a second urethane polymer, wherein the second urethane polymer is operative to provide adequate flexibility to the formulation;
(c) a compound operative to provide freeze-thaw stability to the formulation;
(d) a compound operative to confer film-forming properties to the formulation;
(e) a compound operative to limit the growth of microorganisms in the formulation;
(f) a compound operative to provide additional final strength to the formulation;
(g) a compound operative to provide a desirable final viscosity to the formulation; and
(h) a compound operative to prevent the formulation from foaming during mixing of the ingredients therein.
2) The formulation of claim 1 , wherein the first urethane polymer is SANCURE 898.
3) The formulation of claim 1 , wherein the second urethane polymer is SANCURE 777F.
4) The formulation of claim 1 , wherein the compound operative to provide freeze-thaw stability to the formulation is propylene glycol.
5) The formulation of claim 1 , wherein the compound operative to confer film-forming properties to the formulation is an ester alcohol.
6) The formulation of claim 1 , wherein the compound operative to limit the growth of microorganisms in the formulation is a biocide.
7) The formulation of claim 1 , wherein the compound operative to provide additional final strength to the formulation is a crosslinking agent.
8) The formulation of claim 1 , wherein the compound operative to provide a desirable final viscosity to the formulation is a rheology modifier.
9) A pourable glue formulation, comprising:
(a) a first urethane polymer, wherein the first urethane polymer is operative to provide adequate tensile strength to the formulation;
(b) a second urethane polymer, wherein the second urethane polymer is operative to provide adequate flexibility to the formulation;
(c) a compound operative to provide freeze-thaw stability to the formulation;
(d) an ester alcohol;
(e) a biocide;
(f) a crosslinking agent;
(g) a viscosity modifier; and
(h) a defoamer.
10) The formulation of claim 9 , wherein the compound operative to provide freeze-thaw stability to the formulation is propylene glycol.
11) The formulation of claim 9 , wherein the first urethane polymer is SANCURE 898.
12) The formulation of claim 9 , wherein the second urethane polymer is SANCURE 777F.
13) The formulation of claim 9 , wherein the ester alcohol is TEXANOL.
14) The formulation of claim 9 , wherein the biocide is ACTICIDE LA.
15) The formulation of claim 9 , wherein the crosslinking agent is COATOSIL 1770 silane.
16) The formulation of claim 9 , wherein the defoamer is SURFYNOL DF-58.
17) The formulation of claim 9 , wherein the viscosity modifier is ACRYSOL RM-825.
18) A pourable glue formulation, comprising:
(a) a first urethane polymer, wherein the first urethane polymer is SANCURE 898;
(b) a second urethane polymer, wherein the second urethane polymer is SANCURE 777F;
(c) a compound operative to provide freeze-thaw stability to the formulation;
(d) an ester alcohol, wherein the ester alcohol is TEXANOL;
(e) a biocide, wherein the biocide is ACTICIDE LA;
(f) a crosslinking agent, wherein the crosslinking agent is COATOSIL 1770 silane;
(g) a rheology modifier, wherein the rheology modifier is ACRYSOL RM-825; and
(h) a defoamer, wherein the defoamer is SURFYNOL DF-58.
19) The formulation of claim 18 , wherein the compound operative to provide freeze-thaw stability to the formulation is propylene glycol.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/907,583 US20110178203A1 (en) | 2009-10-19 | 2010-10-19 | High strength glue formulation |
| US14/059,075 US8871830B2 (en) | 2009-10-19 | 2013-10-21 | High-strength glue formulation |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25292109P | 2009-10-19 | 2009-10-19 | |
| US12/907,583 US20110178203A1 (en) | 2009-10-19 | 2010-10-19 | High strength glue formulation |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/059,075 Continuation US8871830B2 (en) | 2009-10-19 | 2013-10-21 | High-strength glue formulation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20110178203A1 true US20110178203A1 (en) | 2011-07-21 |
Family
ID=44278009
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US12/907,583 Abandoned US20110178203A1 (en) | 2009-10-19 | 2010-10-19 | High strength glue formulation |
| US14/059,075 Active US8871830B2 (en) | 2009-10-19 | 2013-10-21 | High-strength glue formulation |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/059,075 Active US8871830B2 (en) | 2009-10-19 | 2013-10-21 | High-strength glue formulation |
Country Status (1)
| Country | Link |
|---|---|
| US (2) | US20110178203A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105022432A (en) * | 2015-07-20 | 2015-11-04 | 南通凯迪自动机械有限公司 | Automatic glue viscosity detection and control system |
| US20190241714A1 (en) * | 2017-08-15 | 2019-08-08 | Sanford, L.P. | Glue slime activator and associated methods and kits |
| US20200061482A1 (en) * | 2017-08-15 | 2020-02-27 | Sanford, L.P. | Glue slime activator and associated methods and kits |
| CN111269682A (en) * | 2020-04-10 | 2020-06-12 | 珠海市泽涛粘合制品有限公司 | Water-based adhesive for spraying and preparation method and application thereof |
Citations (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4011311A (en) * | 1973-04-24 | 1977-03-08 | Akzo N.V. | Applicator stick |
| US4479840A (en) * | 1979-05-11 | 1984-10-30 | Sunstar Giken Kabushiki | Two-part adhesive and bonding method employing same |
| US4507430A (en) * | 1982-12-20 | 1985-03-26 | Hodogaya Chemical Co., Ltd. | Water-base polyurethane emulsion |
| US5156601A (en) * | 1991-03-20 | 1992-10-20 | Hydromer, Inc. | Tacky, hydrophilic gel dressings and products therefrom |
| US5334690A (en) * | 1992-07-09 | 1994-08-02 | Hoechst Aktiengesellschaft | Polyurethane dispersions |
| US5371131A (en) * | 1989-06-30 | 1994-12-06 | Henkel Kommanditgesellschaft Auf Aktien | Adhesive stick having improved adhesive strength |
| US5433775A (en) * | 1991-07-30 | 1995-07-18 | Henkel Kommanditgesellschaft Auf Aktien | Adhesive stick based on starch ethers |
| US5662960A (en) * | 1995-02-01 | 1997-09-02 | Schneider (Usa) Inc. | Process for producing slippery, tenaciously adhering hydrogel coatings containing a polyurethane-urea polymer hydrogel commingled with a poly (n-vinylpyrrolidone) polymer hydrogel |
| US5780542A (en) * | 1995-07-18 | 1998-07-14 | Basf Aktiengesellschaft | Water-emulsifiable polyisocyanates |
| US5945473A (en) * | 1995-06-07 | 1999-08-31 | National Starch And Chemical Investment Holding Corporation | Modified aqueous polyurethane dispersions and methods for making same |
| US6095996A (en) * | 1997-05-30 | 2000-08-01 | Bristol-Myers Squibb Company | Adhesive composition or structure |
| US6417261B1 (en) * | 1998-03-26 | 2002-07-09 | Henkel Kommanditgesellschaft Auf Aktien | Soap gel based glue stick |
| US20030092829A1 (en) * | 1993-10-20 | 2003-05-15 | Wolfgang Klauck | Binders based on oleochemical reaction products |
| US6590019B2 (en) * | 2000-05-05 | 2003-07-08 | National Starch And Chemical Investment Holding Corporation | Aqueous adhesive compositions useful as bottle labeling adhesives |
| US6706801B1 (en) * | 1998-12-21 | 2004-03-16 | Bayer Aktiengesellschaft | Aqueous reactive putty (I) |
| US6790903B1 (en) * | 1998-12-11 | 2004-09-14 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Dispersions of silyl-terminated polymers with a high solids content, their production and their use |
| US6797280B1 (en) * | 1998-07-29 | 2004-09-28 | Teijin Limited | Pressure-sensitive adhesive composition and moisture-permeable pressure-sensitive adhesive tape, pressure-sensitive adhesive drug composition, and pressure-sensitive adhesive tape preparation each containing the composition |
| US20050244442A1 (en) * | 2004-04-30 | 2005-11-03 | Sabino Michael C | Long-wearing cosmetic compositions |
| US20060183823A1 (en) * | 2005-02-16 | 2006-08-17 | Nordson Corporation | Adhesive composition |
| US7232858B2 (en) * | 2002-08-14 | 2007-06-19 | The Procter & Gamble Company | Thermoplastic hydrophilic adhesive compositions for attachment on dry and wet surfaces and with increased water adhesion stability |
| US7479520B2 (en) * | 2001-02-13 | 2009-01-20 | Basf Coatings Ag | Aqueous coating substance that is substantially or completely free of volatile organic substances, method for producing the same and the use thereof |
| US20090054579A1 (en) * | 2005-12-27 | 2009-02-26 | Kuraray Co., Ltd. | Adhesive composition |
| US20100233146A1 (en) * | 2002-09-09 | 2010-09-16 | Reactive Surfaces, Ltd. | Coatings and Surface Treatments Having Active Enzymes and Peptides |
-
2010
- 2010-10-19 US US12/907,583 patent/US20110178203A1/en not_active Abandoned
-
2013
- 2013-10-21 US US14/059,075 patent/US8871830B2/en active Active
Patent Citations (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4011311A (en) * | 1973-04-24 | 1977-03-08 | Akzo N.V. | Applicator stick |
| US4479840A (en) * | 1979-05-11 | 1984-10-30 | Sunstar Giken Kabushiki | Two-part adhesive and bonding method employing same |
| US4507430A (en) * | 1982-12-20 | 1985-03-26 | Hodogaya Chemical Co., Ltd. | Water-base polyurethane emulsion |
| US5371131A (en) * | 1989-06-30 | 1994-12-06 | Henkel Kommanditgesellschaft Auf Aktien | Adhesive stick having improved adhesive strength |
| US5156601A (en) * | 1991-03-20 | 1992-10-20 | Hydromer, Inc. | Tacky, hydrophilic gel dressings and products therefrom |
| US5433775A (en) * | 1991-07-30 | 1995-07-18 | Henkel Kommanditgesellschaft Auf Aktien | Adhesive stick based on starch ethers |
| US5334690A (en) * | 1992-07-09 | 1994-08-02 | Hoechst Aktiengesellschaft | Polyurethane dispersions |
| US20030092829A1 (en) * | 1993-10-20 | 2003-05-15 | Wolfgang Klauck | Binders based on oleochemical reaction products |
| US5662960A (en) * | 1995-02-01 | 1997-09-02 | Schneider (Usa) Inc. | Process for producing slippery, tenaciously adhering hydrogel coatings containing a polyurethane-urea polymer hydrogel commingled with a poly (n-vinylpyrrolidone) polymer hydrogel |
| US5945473A (en) * | 1995-06-07 | 1999-08-31 | National Starch And Chemical Investment Holding Corporation | Modified aqueous polyurethane dispersions and methods for making same |
| US5780542A (en) * | 1995-07-18 | 1998-07-14 | Basf Aktiengesellschaft | Water-emulsifiable polyisocyanates |
| US6095996A (en) * | 1997-05-30 | 2000-08-01 | Bristol-Myers Squibb Company | Adhesive composition or structure |
| US6417261B1 (en) * | 1998-03-26 | 2002-07-09 | Henkel Kommanditgesellschaft Auf Aktien | Soap gel based glue stick |
| US6797280B1 (en) * | 1998-07-29 | 2004-09-28 | Teijin Limited | Pressure-sensitive adhesive composition and moisture-permeable pressure-sensitive adhesive tape, pressure-sensitive adhesive drug composition, and pressure-sensitive adhesive tape preparation each containing the composition |
| US6790903B1 (en) * | 1998-12-11 | 2004-09-14 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Dispersions of silyl-terminated polymers with a high solids content, their production and their use |
| US6706801B1 (en) * | 1998-12-21 | 2004-03-16 | Bayer Aktiengesellschaft | Aqueous reactive putty (I) |
| US6590019B2 (en) * | 2000-05-05 | 2003-07-08 | National Starch And Chemical Investment Holding Corporation | Aqueous adhesive compositions useful as bottle labeling adhesives |
| US7479520B2 (en) * | 2001-02-13 | 2009-01-20 | Basf Coatings Ag | Aqueous coating substance that is substantially or completely free of volatile organic substances, method for producing the same and the use thereof |
| US7232858B2 (en) * | 2002-08-14 | 2007-06-19 | The Procter & Gamble Company | Thermoplastic hydrophilic adhesive compositions for attachment on dry and wet surfaces and with increased water adhesion stability |
| US20100233146A1 (en) * | 2002-09-09 | 2010-09-16 | Reactive Surfaces, Ltd. | Coatings and Surface Treatments Having Active Enzymes and Peptides |
| US20050244442A1 (en) * | 2004-04-30 | 2005-11-03 | Sabino Michael C | Long-wearing cosmetic compositions |
| US20060183823A1 (en) * | 2005-02-16 | 2006-08-17 | Nordson Corporation | Adhesive composition |
| US20090054579A1 (en) * | 2005-12-27 | 2009-02-26 | Kuraray Co., Ltd. | Adhesive composition |
Non-Patent Citations (7)
| Title |
|---|
| Air Products, "Surfynol DF-58 Defoamer", 1/2002. * |
| Eastman, "Product Data Sheet, Eastman Texanol Ester Alcohol", 10/14/2010, pp.1-3. * |
| Lubrizol Advanced Materials, Inc., "Sancure 777 Aliphatic Waterborne Urethane Polymer", Lubrizol Technical Data Sheet, June 4, 2007. * |
| Lubrizol Advanced Materials, Inc., "Sancure 898 Aliphatic Waterborne Urethane Polymer", Lubrizol Technical Data Sheet, June 4, 2007. * |
| Momentive Performance Materials, "CoatOSil* 1770 Silane, crosslinking additive for waterborne coatings", 3/2007. * |
| Rohm and Haas, "Acrysol RM-825 Rheology Modifier", 9/2005. * |
| Thor Specialties, Inc. "Thor Products, Biocides", 10/14/2010, pp1-2. * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105022432A (en) * | 2015-07-20 | 2015-11-04 | 南通凯迪自动机械有限公司 | Automatic glue viscosity detection and control system |
| US20190241714A1 (en) * | 2017-08-15 | 2019-08-08 | Sanford, L.P. | Glue slime activator and associated methods and kits |
| US20200061482A1 (en) * | 2017-08-15 | 2020-02-27 | Sanford, L.P. | Glue slime activator and associated methods and kits |
| US10738175B2 (en) * | 2017-08-15 | 2020-08-11 | Sanford, L.P. | Glue slime activator and associated methods and kits |
| US10974159B2 (en) * | 2017-08-15 | 2021-04-13 | Sanford, L.P. | Glue slime activator and associated methods and kits |
| US11499029B2 (en) * | 2017-08-15 | 2022-11-15 | Sanford, L.P. | Glue slime activator and associated methods and kits |
| CN111269682A (en) * | 2020-04-10 | 2020-06-12 | 珠海市泽涛粘合制品有限公司 | Water-based adhesive for spraying and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| US20140080939A1 (en) | 2014-03-20 |
| US8871830B2 (en) | 2014-10-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2601458C2 (en) | Monobenzoate suitable for use as plasticizer in adhesive compositions | |
| US8871830B2 (en) | High-strength glue formulation | |
| US11130869B2 (en) | Aqueous copolymer coating compositions for industrial and construction applications | |
| CN108966654B (en) | Adhesive composition, method for making the same, and adhesive product | |
| CN101472968B (en) | Water-based polyurethane floor coating composition | |
| US5326808A (en) | Odor free, air dry, aqueous emulsion paints | |
| CA2940732C (en) | Pigmented paint formulation with a phosphorus acid functionalized latex binder and an associative thickener | |
| CN103865365B (en) | paint system | |
| CN101878278A (en) | Thin film primers with improved adhesion | |
| KR101531569B1 (en) | Water-soluble paint composition and method for producing the same | |
| US20180016465A1 (en) | Aqueous based polyurethane/acrylate hybrid dispersions | |
| EP3533845A1 (en) | Coating composition for vehicle interior member, vehicle interior member, and method for manufacturing vehicle interior member | |
| WO2015188067A1 (en) | Polyurethane laminating adhesive composition | |
| RU2768711C1 (en) | Adhesive composition and method for production thereof | |
| KR20120108774A (en) | Water-soluble and antibiotic paint composition for plastics and method of manufacturing coating film using the same | |
| CN114213927B (en) | Water-based strippable coating, preparation method and application | |
| CN108779200A (en) | Water-based paint compositions | |
| RU2769812C1 (en) | Adhesive composition and method for production thereof | |
| KR101619771B1 (en) | Water-soluble antimicrobial paint composition and method for producing the same | |
| TW202016242A (en) | Adhesive composition, preparation method thereof, and adhesive product including the same | |
| WO2018079774A1 (en) | Aqueous paint for vehicle interior member, vehicle interior member, and method of manufacturing vehicle interior member | |
| CA2982663C (en) | Deep base paint formulation | |
| JP3982910B2 (en) | Aqueous resin composition | |
| WO2015146748A1 (en) | Room temperature-curable aqueous coating composition | |
| JP2019156970A (en) | Film for marking |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: ELMER'S PRODUCTS INC., OHIO Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KUKREJA, JOGINDER;PATEL, YOGESHBHAI B.;FOSTER, VAN R.;AND OTHERS;SIGNING DATES FROM 20101115 TO 20101116;REEL/FRAME:025370/0983 |
|
| STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |