US2081246A - Container closure and method of making same - Google Patents
Container closure and method of making same Download PDFInfo
- Publication number
- US2081246A US2081246A US663424A US66342433A US2081246A US 2081246 A US2081246 A US 2081246A US 663424 A US663424 A US 663424A US 66342433 A US66342433 A US 66342433A US 2081246 A US2081246 A US 2081246A
- Authority
- US
- United States
- Prior art keywords
- cushion
- cork
- liner
- rubber
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000463 material Substances 0.000 description 42
- 239000007799 cork Substances 0.000 description 20
- 229920001971 elastomer Polymers 0.000 description 16
- 239000002245 particle Substances 0.000 description 10
- 239000010410 layer Substances 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 230000001413 cellular effect Effects 0.000 description 8
- 239000011888 foil Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 239000004922 lacquer Substances 0.000 description 5
- 238000007789 sealing Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 229920000298 Cellophane Polymers 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- 229920001342 Bakelite® Polymers 0.000 description 1
- 239000000899 Gutta-Percha Substances 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 240000000342 Palaquium gutta Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000004637 bakelite Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- -1 collodium Substances 0.000 description 1
- 230000001447 compensatory effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 229920000588 gutta-percha Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
- B65D41/02—Caps or cap-like covers without lines of weakness, tearing strips, tags, or like opening or removal devices
- B65D41/10—Caps or cap-like covers adapted to be secured in position by permanent deformation of the wall-engaging parts
- B65D41/12—Caps or cap-like covers adapted to be secured in position by permanent deformation of the wall-engaging parts made of relatively stiff metallic materials, e.g. crown caps
Definitions
- This invention relates to closures, and particularly caps for containers having cushion liners associated therewith.
- a particular object of the invention is to pro- I vide a cap having a cushion or disc which will be (1) impervious to liquids and gases, (2) substantially unaffected by acids, alkalies and oils
- a further object of the invention is to provide a cap with a cushion disc having a suitable protective facing, which may be in the form of a film, an overall liner, or a center spot liner.
- the cushion liner material oi-the present invention is described in the co-pending application of William M. West, filed March 24, 1933, Serial No. 662,633, and I have found the same highly acceptableas a sealing means between the closure and the container to which 'it is ap- 30 plied.
- This material is in the formof a close network of expanded structure andvulcanized, having as its main body ingredients'comminuted cork ,and' cellular rubber with suitable plasticizers and softening'agents.
- the close network 5 providedis impervious ,to gases and liquids and will withstand pressures of one hundred. and fifty to two hundred poundsorabove the normal range necessary to be'considered inconnection with high pressure sealing operations.
- the material comprises "a retiform structure having asits 1 principal body materials comminuted' cork and rubber:' That is,'-'a'"close network; 'of expanded and vulcanized' material -in' block,
- panded material Theproduct is pnaracpenzee hav n he PPF F i here Pm i the bo y members available and in tact the rub-- 'berahd e rk coo emte .tdproduce an arrest which is the maximum resultant of the'combination of their several 1 qualities.
- cork particles are of a sizeto retain theirv 55 cellular nature, and the mass is expanded and Inicarrying out the methodlof the inventl Application March 29, 1933, Serial No. 663,424
- the rubber substantially enbases the cork particles, and is adherent to the faces thereof.
- the cork particles constitute a body material as dis- '5 tinguished from a filler, and the rubber, the cellular walls of which are united to the cork particle faces, acts to (1) bond the cork particles forming a cork and rubber network, and (2) resiliently and permanently fix or position the particles in spaced relation preventing compacting thereof.
- the product isfiexible and resistant to creasing and bending strains without cracking, elastic, tough, pressure resistant and impervious to water and gases, has an optimum of resilience, i. e;, compression and rebound, and the particle faces comprise a substantial. portion of the surface area.
- the discs and liners made from the material are free from any tendency to curl and do not warp or lose their shape, when wetted and subsequently dried. In other words, they will remain permanently flat and are not objectionably affected by conditions of temperature and moisture.
- the material is produced by a method of procedure wherein (a) molded products of any required shape will be-formed, and (b) continuous strip material will be produced.
- the method is carried out with. nice control of the ratio of cork and rubber and regulation of the chemical action whereby the cellular character of the rubber and of theexpanded ma. terial is determined.
- the method provides for expanding the 5 material and rendering the rubber cellular by means of a gas forming or blowing agentand in situ, that is in the form of the final product,
- Figure 1 is a sectional view through the cushion liner material
- Figure 2 is a view showing the cushion liner material provided with a film deposit or layer of a suitable acid and alkali resistant lacquer;
- Figure 3 is a view similar to Figure 2 showing the cushion material having united to its face a layer of paper or foil;
- Figure 4 is a view showing the cushion material having applied to one side thereof a layer of adhesive
- Figure 5 is a view showing a disc of the cushion material in position in a closure cap
- Figure 6 is a similar view showing the face of the cushion liner provided with a center spot liner
- Figure '7 is a bottom view showing the cap of Figure 6;
- Figure 8 is a top elevation of a sealing ring
- Figure 9 is a section on the line 9-9 of Figure 8.
- the cork and rubber are prepared as a retiform structure, that is to say, a close expanded network which is impervious to liquids and gases and which is pressure resistant.
- the material is characterized by numerous but non-communicating pores and interstices and the rubber is rendered cellular.
- the cork particles are encased in the rubber and the rubber adhesively unites the cork particles and fixes them in substantially permanent position.
- the material is characterized by a high degree of resiliency and since the cork particles are positioned by the rubber to have a compensatory movement, regardless of the sealing pressures, the cushion material will not be ruptured.
- the adhesive strata is shown at ii.
- I will form the material in the form of a tube or rod of suitable diameter and slice therefrom discs of the appropriate thickness.
- Such rod or tube may be extruded, and the material then expanded and vulcanized or the expansion and vulcanization take place in a suitable mold from which the rod will be withdrawn for slicing,
- the strip material of Figures 2, 3, and 4 will likewise be punched to produce a cushion disc having (1) a coextensive facing layer ll of lacquer, (2) a coextensive facing or overall liner l2 of paper, cellophane or tinfoil, and (3) a disc having applied to one surface thereof a layer of heat or pressure sensitive adhesive or heat coagulable adhesive I3. Also discs will be punched from a sheet having a facing as described, and the opposite surface provided with an adhesive layer.
- the adhesive layer will, in some cases, be applied to the sheet material shown in Figures 2 and 3, and the resultant composite structure punched to produce the discs.
- this may be either severed from a hollow tube of the material or punched from a suitable sheet.
- the lacquer or varnish facing l i for the cushion disc Ill, or liners l2 and It may comprise a suitable oil varnish, cellulose lacquers, collodium, synthetic resin lacquers, latex films, and in fact, any impervious deposit which will be acid and alkali and oil resistant.
- a facing film of a cellulose ester e. g. nitrocellulose will be employed.
- the adhesive bonding material I between the cushion and the cap is, in some cases, formed on the metal on the interior of the cap top, and in other cases, is provided as a fllm upon the cushion material.
- Such adhesive may consist of albumen, a synthetic resin of the glyptal type. a latex adhesive, 9. protein adhesive, such as casein, or a resin-copal-alcohol varnish.
- the cushion liner is useful in connection with lug caps, screw caps, divided thread caps, crown caps, and caps of molded form, as well as the disc type closures as shown and described in the With respect to synthetic resins of the adhesive type, while I have referred to glyptal resins, it will be understood thatI will use various of these resins such as bakelite and similar aldehyde condensation products.
- a cap comprising a metal shell and a liner disc therefor of an expanded body of comminuted cork and rubber forming a resilient and flexible 10 layer, the cork constituting a body material and body of comminuted cork and vulcanized rubber forming-a resilient and flexible layer, the cork constituting a body material and forming a substantial portion of the exposed face of the liner.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Closures For Containers (AREA)
Description
May 25, 1931. E MG AN 2,081,246
CONTAINER CLOSURE AND-METHOD "OF MAKING SAME Filed March 29, 1935 Patented May 25, 1937' UNITED STATES PATENT OFFICE Charles E. McManus, Baltimore, Md., assignor to Crown Cork & Seal Company, Inc., Baltimore, Md., a corporation of New York 2 Claims.
This invention relates to closures, and particularly caps for containers having cushion liners associated therewith.
A particular object of the invention is to pro- I vide a cap having a cushion or disc which will be (1) impervious to liquids and gases, (2) substantially unaffected by acids, alkalies and oils A further object of the invention is to provide a cap with a cushion disc having a suitable protective facing, which may be in the form of a film, an overall liner, or a center spot liner.
The cushion liner material oi-the present invention is described in the co-pending application of William M. West, filed March 24, 1933, Serial No. 662,633, and I have found the same highly acceptableas a sealing means between the closure and the container to which 'it is ap- 30 plied. This material, is in the formof a close network of expanded structure andvulcanized, having as its main body ingredients'comminuted cork ,and' cellular rubber with suitable plasticizers and softening'agents. The close network 5 providedis impervious ,to gases and liquids and will withstand pressures of one hundred. and fifty to two hundred poundsorabove the normal range necessary to be'considered inconnection with high pressure sealing operations. v
40 The material comprises "a retiform structure having asits 1 principal body materials comminuted' cork and rubber:' That is,'-'a'"close network; 'of expanded and vulcanized' material -in' block,
"rod or" strip, form having each" of"-the'*"m'ajor 45 compone ts substantially cellular. The cushion disc'sor liners are sliced'onf punched *rromthe ex;
panded material. Theproduct is pnaracpenzee hav n he PPF F i here Pm i the bo y members available and in tact the rub-- 'berahd e rk coo emte .tdproduce an arrest which is the maximum resultant of the'combination of their several 1 qualities. w
The cork particles are of a sizeto retain theirv 55 cellular nature, and the mass is expanded and Inicarrying out the methodlof the inventl Application March 29, 1933, Serial No. 663,424
the rubber rendered cellular in .situ and immediately vulcanized.
The rubber substantially enbases the cork particles, and is adherent to the faces thereof. The cork particles constitute a body material as dis- '5 tinguished from a filler, and the rubber, the cellular walls of which are united to the cork particle faces, acts to (1) bond the cork particles forming a cork and rubber network, and (2) resiliently and permanently fix or position the particles in spaced relation preventing compacting thereof.
The product isfiexible and resistant to creasing and bending strains without cracking, elastic, tough, pressure resistant and impervious to water and gases, has an optimum of resilience, i. e;, compression and rebound, and the particle faces comprise a substantial. portion of the surface area. Also, the discs and liners made from the material are free from any tendency to curl and do not warp or lose their shape, when wetted and subsequently dried. In other words, they will remain permanently flat and are not objectionably affected by conditions of temperature and moisture.
The material is produced by a method of procedure wherein (a) molded products of any required shape will be-formed, and (b) continuous strip material will be produced.
The method is carried out with. nice control of the ratio of cork and rubber and regulation of the chemical action whereby the cellular character of the rubber and of theexpanded ma. terial is determined. In connection with the latter, the method provides for expanding the 5 material and rendering the rubber cellular by means of a gas forming or blowing agentand in situ, that is in the form of the final product,
i. e., the block, rod, strip, or liner, and 'substan- I tially immediately, thereaiter vulcanizing'ffthe 40 mass. i
the inixturefoi cork and rubber and Ithe cnmi cal constituents; i. e., accelerators and: blowing and vulcanizin'g agents and[or plasticizers 'an'd-" softening agents, arefirst prepared inthe form ofa partiallyvulcanized or sfet mass This mass is placed in a mold of desired shape to form block's, sheets; rodsor'fliners, and in "ilil ,8 P-** tially set condition} is subjected to the blowing 5'0 operation whereby' the-materialfills the mold cavity, immediatelyiollo'wed by "vulcanization, both steps taking place'inthe moIdR -That is to say,'the mass is expanded simultaneously with the step ofrendering the rubbercellular and 56 immediately vulcanized whereby the product is obtained in its maximum blown or expanded and shaped condition. In the case of sheet material the mold is usually omitted, the strip material being passed in sheets through a heating chamber, and expanded and immediately vulcanized therein.
In the drawing:
Figure 1 is a sectional view through the cushion liner material;
Figure 2 is a view showing the cushion liner material provided with a film deposit or layer of a suitable acid and alkali resistant lacquer;
Figure 3 is a view similar to Figure 2 showing the cushion material having united to its face a layer of paper or foil;
Figure 4 is a view showing the cushion material having applied to one side thereof a layer of adhesive;
Figure 5 is a view showing a disc of the cushion material in position in a closure cap;
Figure 6 is a similar view showing the face of the cushion liner provided with a center spot liner;
Figure '7 is a bottom view showing the cap of Figure 6;
Figure 8 is a top elevation of a sealing ring; and
Figure 9 is a section on the line 9-9 of Figure 8.
Referring to Figure l, I have shown at ill a section of the improved cushion material. It is to be Observed that the cork and rubber are prepared as a retiform structure, that is to say, a close expanded network which is impervious to liquids and gases and which is pressure resistant. The material is characterized by numerous but non-communicating pores and interstices and the rubber is rendered cellular. The cork particles are encased in the rubber and the rubber adhesively unites the cork particles and fixes them in substantially permanent position.
The material is characterized by a high degree of resiliency and since the cork particles are positioned by the rubber to have a compensatory movement, regardless of the sealing pressures, the cushion material will not be ruptured.
In Figure 2 of the drawing, I have illustrated the cushion material provided with a surface facing ll of acid and alkali resistant varnish.
In Figure 3, I have illustrated the cushion material as having applied thereto a layer I2 of thin liner material such as varnished express paper, metal foil, as well as cellophane.
In Figure 4 of the drawing, I have shown the cushion material provided with a facing layer which may be pressure and heat sensitive, such.
as gutta percha, or heat coagulable, such as albumen. The adhesive strata is shown at ii.
In Figures 6 and 7, I- have shown the face of the cap provided with a center spot liner ii of varnished express paper or metallic foil such as tin foil and aluminum foil. This spot is united to the cushion material by means of a heat and/ or pressure sensitive adhesive or a heat coagulable adhesive, as just described.
Instead of using a center spot, I use, in some cases, an overall or coextensive liner of paper or metal foil, such as tin foil or aluminum foil, and unite the same to the cushion material as described.
In Figures 8 and 9, I have illustrated an ordinary ring gasket l1 constructed of the material shown in Figure 1.
In forming discs of the cushion material, I pro ceed in several ways. In order to form the cushion liner I of Figure 5, I will punch discs of suitable size from a strip of the material. In this connection, the strength of the material is such that even in the thinnest gauges, it may be suitably punched without fear of disruption or otherwise weakening the disc. For this reason cushion discs of very thin gauge, less than that of the usual cork composition discs, are employed, being both economical and assuring a better seal.
As an alternative process, I will form the material in the form of a tube or rod of suitable diameter and slice therefrom discs of the appropriate thickness. Such rod or tube may be extruded, and the material then expanded and vulcanized or the expansion and vulcanization take place in a suitable mold from which the rod will be withdrawn for slicing,
The strip material of Figures 2, 3, and 4 will likewise be punched to produce a cushion disc having (1) a coextensive facing layer ll of lacquer, (2) a coextensive facing or overall liner l2 of paper, cellophane or tinfoil, and (3) a disc having applied to one surface thereof a layer of heat or pressure sensitive adhesive or heat coagulable adhesive I3. Also discs will be punched from a sheet having a facing as described, and the opposite surface provided with an adhesive layer.
It will be understood that the adhesive layer will, in some cases, be applied to the sheet material shown in Figures 2 and 3, and the resultant composite structure punched to produce the discs.
With respect to the sealing rings shown in Figures 8 and 9, this may be either severed from a hollow tube of the material or punched from a suitable sheet.
The lacquer or varnish facing l i for the cushion disc Ill, or liners l2 and It, may comprise a suitable oil varnish, cellulose lacquers, collodium, synthetic resin lacquers, latex films, and in fact, any impervious deposit which will be acid and alkali and oil resistant.
In lieu of using a center spot of paper or foil or an over-all liner of this material, a facing film of a cellulose ester e. g. nitrocellulose will be employed.
I have stated that the adhesive bonding material I between the cushion and the cap is, in some cases, formed on the metal on the interior of the cap top, and in other cases, is provided as a fllm upon the cushion material. Such adhesive may consist of albumen, a synthetic resin of the glyptal type. a latex adhesive, 9. protein adhesive, such as casein, or a resin-copal-alcohol varnish.
The cushion liner is useful in connection with lug caps, screw caps, divided thread caps, crown caps, and caps of molded form, as well as the disc type closures as shown and described in the With respect to synthetic resins of the adhesive type, while I have referred to glyptal resins, it will be understood thatI will use various of these resins such as bakelite and similar aldehyde condensation products.
I claim:
1. A cap comprising a metal shell and a liner disc therefor of an expanded body of comminuted cork and rubber forming a resilient and flexible 10 layer, the cork constituting a body material and body of comminuted cork and vulcanized rubber forming-a resilient and flexible layer, the cork constituting a body material and forming a substantial portion of the exposed face of the liner.
CHARLES S. MCMANUS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US663424A US2081246A (en) | 1933-03-29 | 1933-03-29 | Container closure and method of making same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US663424A US2081246A (en) | 1933-03-29 | 1933-03-29 | Container closure and method of making same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2081246A true US2081246A (en) | 1937-05-25 |
Family
ID=24661748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US663424A Expired - Lifetime US2081246A (en) | 1933-03-29 | 1933-03-29 | Container closure and method of making same |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2081246A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1245498A1 (en) * | 2001-03-23 | 2002-10-02 | Crown Cork & Seal Technologies Corporation | Crown for secondary fermentation |
| EP1247751A1 (en) * | 2001-03-23 | 2002-10-09 | Crown Cork & Seal Technologies Corporation | Crown for secondary fermentation |
| US20180327601A1 (en) * | 2015-11-16 | 2018-11-15 | Arkema France | Polymer composition comprising a dispersed plant material |
-
1933
- 1933-03-29 US US663424A patent/US2081246A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1245498A1 (en) * | 2001-03-23 | 2002-10-02 | Crown Cork & Seal Technologies Corporation | Crown for secondary fermentation |
| EP1247751A1 (en) * | 2001-03-23 | 2002-10-09 | Crown Cork & Seal Technologies Corporation | Crown for secondary fermentation |
| US20180327601A1 (en) * | 2015-11-16 | 2018-11-15 | Arkema France | Polymer composition comprising a dispersed plant material |
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