US2086920A - Method and composition for preserving and curing hides and skins - Google Patents
Method and composition for preserving and curing hides and skins Download PDFInfo
- Publication number
- US2086920A US2086920A US61747A US6174736A US2086920A US 2086920 A US2086920 A US 2086920A US 61747 A US61747 A US 61747A US 6174736 A US6174736 A US 6174736A US 2086920 A US2086920 A US 2086920A
- Authority
- US
- United States
- Prior art keywords
- skins
- hides
- composition
- preserving
- barium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 15
- 238000000034 method Methods 0.000 title description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 22
- 235000011187 glycerol Nutrition 0.000 description 11
- 229910052788 barium Inorganic materials 0.000 description 8
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 6
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 5
- 229940045511 barium chloride Drugs 0.000 description 5
- 229910001626 barium chloride Inorganic materials 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 208000014674 injury Diseases 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000003230 hygroscopic agent Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 230000002311 subsequent effect Effects 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/02—Curing raw hides
Definitions
- This invention relates to a method and acomposition for preserving and curing green or raw hides or skins.
- V a salt, for example chloride of soda immediately after they have been removed from the animals, and then the hides and skins are folded and laid orpiled in a suitable storage place.
- the salt for example chloride of soda
- example chloride of soda is applied to the skins for the purpose of preserving them and, is more or less satisfactory in preserving thehides or skins for short periods of time.
- the skins are to be kept for longer periods than the -3 usual time permitted by this treatment, they are taken up and either subjected to sub-sequent operations such as tanning, or further cured, or put into cold storage plants.
- sub-sequent operations such as tanning, or further cured, or put into cold storage plants.
- the further curing or placing in cold storage of the hides or skins go adds great expense to the preserving and handling of the hides or skins, and moreover, they must be kept under constant supervision to avoid spoiling or destruction thereof.
- the preserving salt is usually technical sodium chloride which contains small percentages of hygroscopic substances which make the composi-, tion hygroscopic. This causes sweating of the hides or skins, and the composition is subject to changes with atmospheric conditions so that the :0 skins are frequently stained or a cloudy grain is developed thereon.
- the prime object of my invention is to provide a novel and improved method and composition for preserving and curing green hides and skins whereby the hides or skins may be preserved for indefinite periods of time and without the necessityof supervision or extra. curing or storing in cold storage plants or the like afterhaving once been treated according to my invention.
- the hides or skins are treated with an aqueous solution .offlchloride of barium.
- chloride of barium being substantially non-hygroscopic, I sometimes add to the solution of chloride of barium a small amount of glycerine to retain moisture in the hides or.skins.
- the composition may be applied to the skins in various ways, forexample, I may layout the hides or skins in flat condition with the flesh side up and sprinkle them with ,my composition, or the composition may be brushed into the hides or skins, or the hides or skins may be immersed in the composition in a suitable vat or receptacle. Thereafter .the hides or skins may be piled in a suitable storage place.
- 1 may employ a composition consisting of an aqueous solution of barium chloride which may vary from a 5% solution to a saturated solution at a room temperature of about 50 to F., although greater proportions of the barium chloride may be used without injury to the skins.
- the solution may or may not include one (1) to fifteen (15) per cent of glycerine depending upon the moisture conditions in the skins.
- the solution may be applied to the skins in either of the ways before mentioned, preferably at a room temperature of H about 50 to 60 F.
- the time of treatment may vary from a few hours up to a period of time required to completely saturate the hides or skins with the composition. Generally a treatment of about 12 hours is sufficient.
- the hides or skins may be piled in a suitable storage place, preferably cool, at a temperature of from 40 to F. and with the humidity of the atmosphere in the storage place at from 76 to 100.
- a suitable storage place preferably cool, at a temperature of from 40 to F. and with the humidity of the atmosphere in the storage place at from 76 to 100.
- glycerine may be omitted where sufficient moisture may be retainedin the skins without the glycerine.
- hides or skins treated ac-L cording to my invention can be stored indefinitely without any injury or deterioration of any kind.
- the natural fats and gelatinous matter of the hides-or skins are maintained intact and in substantially the same normal state in which they were at the time when they were removed from the animal.
- the hides or skins may be left in storage after a single treatment as above described without any supervision or' additional treatment or handling until it is desired to continue processing the skins in a tannery.
- All of the ingredients employed in my composition are readily soluble in water and may be completely removed from the hides or skins by the regular method employed by all users of such hides or skins, i. e. by soaking or washing the hides or skins,and therefore the'hides or skins may-be returned to the normal state in which they were at the timethey were removed from the animal, with no foreign substance or chemical which might interfere with subsequent processes such as liming or tanning.
- the proportions of the ingredients of the composition may be widely varied to suit different conditions, more or less or no glycerine being used according to the degree of moisture and flexibility desired in thehides or skins.
- the time of treatment and the amount of barium-chloride and glycerine may also be chloride as a preservative, it should be understood that I conte mplate the use of an alkaline earth, barium oxide, or any chemical equivalents of barium chloride suitable for the same purpose.
- hygroscopic agents other than glycerine may be used. Therefore, the following claims should be construed accordingly.
- a composition for preserving green hides and skins consisting of an aqueous solution of a soluble salt of barium and glycerine.
- a composition for preserving green hides and ,skins consisting of an aqueous solution of barium chloride and glycerine.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
UNITED STAT Patented July 13, 1931 METHOD AND COMPOSITION FOR PRE- SERVING AND CURING HIDES AND SKINS Arthur G. Moore, Maplewood, N. J.
No Drawing. Application January 31, 1936,
Serial No. 61,747
6 Claims.
This invention relates to a method and acomposition for preserving and curing green or raw hides or skins.
According to general practice of curing hides and skins it is customary to sprinkle them with V a salt, for example chloride of soda immediately after they have been removed from the animals, and then the hides and skins are folded and laid orpiled in a suitable storage place. The salt, for
10 example chloride of soda is applied to the skins for the purpose of preserving them and, is more or less satisfactory in preserving thehides or skins for short periods of time. However, if the skins are to be kept for longer periods than the -3 usual time permitted by this treatment, they are taken up and either subjected to sub-sequent operations such as tanning, or further cured, or put into cold storage plants. The further curing or placing in cold storage of the hides or skins go adds great expense to the preserving and handling of the hides or skins, and moreover, they must be kept under constant supervision to avoid spoiling or destruction thereof.
The preserving salt is usually technical sodium chloride which contains small percentages of hygroscopic substances which make the composi-, tion hygroscopic. This causes sweating of the hides or skins, and the composition is subject to changes with atmospheric conditions so that the :0 skins are frequently stained or a cloudy grain is developed thereon.
The prime object of my invention is to provide a novel and improved method and composition for preserving and curing green hides and skins whereby the hides or skins may be preserved for indefinite periods of time and without the necessityof supervision or extra. curing or storing in cold storage plants or the like afterhaving once been treated according to my invention.
Other objects are toprovide such a method and composition whereby the preserving and curing of hides and skins may be effected at a minimum cost, with aminimum of'handling .and without danger of injury to or destruction of the hides or skins over long periods of time; and to obtain other advantages and results which will be brought out by the following description.
In carrying out the preferredvform of my invention, the hides or skins are treated with an aqueous solution .offlchloride of barium. The
chloride of barium being substantially non-hygroscopic, I sometimes add to the solution of chloride of barium a small amount of glycerine to retain moisture in the hides or.skins.
The composition may be applied to the skins in various ways, forexample, I may layout the hides or skins in flat condition with the flesh side up and sprinkle them with ,my composition, or the composition may be brushed into the hides or skins, or the hides or skins may be immersed in the composition in a suitable vat or receptacle. Thereafter .the hides or skins may be piled in a suitable storage place.
As a specific example of my invention, 1 may employ a composition consisting of an aqueous solution of barium chloride which may vary from a 5% solution to a saturated solution at a room temperature of about 50 to F., although greater proportions of the barium chloride may be used without injury to the skins. The solution may or may not include one (1) to fifteen (15) per cent of glycerine depending upon the moisture conditions in the skins. I The solution may be applied to the skins in either of the ways before mentioned, preferably at a room temperature of H about 50 to 60 F. The time of treatment may vary from a few hours up to a period of time required to completely saturate the hides or skins with the composition. Generally a treatment of about 12 hours is sufficient.
' After this treatment, the hides or skins may be piled in a suitable storage place, preferably cool, at a temperature of from 40 to F. and with the humidity of the atmosphere in the storage place at from 76 to 100. As above indicated glycerine may be omitted where sufficient moisture may be retainedin the skins without the glycerine.
I have found that hides or skins treated ac-L cording to my invention can be stored indefinitely without any injury or deterioration of any kind. The natural fats and gelatinous matter of the hides-or skins are maintained intact and in substantially the same normal state in which they were at the time when they were removed from the animal. Furthermore, the hides or skins may be left in storage after a single treatment as above described without any supervision or' additional treatment or handling until it is desired to continue processing the skins in a tannery.
All of the ingredients employed in my composition are readily soluble in water and may be completely removed from the hides or skins by the regular method employed by all users of such hides or skins, i. e. by soaking or washing the hides or skins,and therefore the'hides or skins may-be returned to the normal state in which they were at the timethey were removed from the animal, with no foreign substance or chemical which might interfere with subsequent processes such as liming or tanning.
As above indicated the proportions of the ingredients of the composition may be widely varied to suit different conditions, more or less or no glycerine being used according to the degree of moisture and flexibility desired in thehides or skins. The time of treatment and the amount of barium-chloride and glycerine may also be chloride as a preservative, it should be understood that I conte mplate the use of an alkaline earth, barium oxide, or any chemical equivalents of barium chloride suitable for the same purpose.
Also, suitable hygroscopic agents other than glycerine may be used. Therefore, the following claims should be construed accordingly.
Having thus described my invention, what I claim is:
1. A composition for preserving green hides and skins consisting of an aqueous solution of a soluble salt of barium and glycerine.
2. A composition for preserving green hides and ,skins consisting of an aqueous solution of barium chloride and glycerine.
3. The step in the method of preserving green hides and skins consisting in impregnating them with a. water soluble salt of barium.
4. The step in the method of preserving green hides and skins consisting in impregnating them with a water soluble salt of barium and glycerine.
5.' The step in the method of preserving green hides and skins consisting in impregnating them with chloride of barium.
6. The step in the method of preserving green hides and skins consisting in impregnating them with chloride of barium and glycerine.
ARTHUR C. MOORE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61747A US2086920A (en) | 1936-01-31 | 1936-01-31 | Method and composition for preserving and curing hides and skins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61747A US2086920A (en) | 1936-01-31 | 1936-01-31 | Method and composition for preserving and curing hides and skins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2086920A true US2086920A (en) | 1937-07-13 |
Family
ID=22037865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US61747A Expired - Lifetime US2086920A (en) | 1936-01-31 | 1936-01-31 | Method and composition for preserving and curing hides and skins |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2086920A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4224029A (en) * | 1978-11-27 | 1980-09-23 | Heinz George G | Exotic leather, method of processing same, and method of processing domestic fowl |
-
1936
- 1936-01-31 US US61747A patent/US2086920A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4224029A (en) * | 1978-11-27 | 1980-09-23 | Heinz George G | Exotic leather, method of processing same, and method of processing domestic fowl |
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