US2132901A - Agent for and process of sizing textile fibers - Google Patents
Agent for and process of sizing textile fibers Download PDFInfo
- Publication number
- US2132901A US2132901A US415348A US41534829A US2132901A US 2132901 A US2132901 A US 2132901A US 415348 A US415348 A US 415348A US 41534829 A US41534829 A US 41534829A US 2132901 A US2132901 A US 2132901A
- Authority
- US
- United States
- Prior art keywords
- sizing
- polyvinyl alcohol
- textile fibers
- agent
- bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004513 sizing Methods 0.000 title description 18
- 239000000835 fiber Substances 0.000 title description 16
- 239000004753 textile Substances 0.000 title description 16
- 238000000034 method Methods 0.000 title description 11
- 230000008569 process Effects 0.000 title description 10
- 239000003795 chemical substances by application Substances 0.000 title description 9
- 229920002451 polyvinyl alcohol Polymers 0.000 description 19
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 19
- 239000004372 Polyvinyl alcohol Substances 0.000 description 18
- 239000000463 material Substances 0.000 description 15
- 239000003921 oil Substances 0.000 description 8
- 229920002472 Starch Polymers 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- 244000299507 Gossypium hirsutum Species 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229920002955 Art silk Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 241001226611 Allium textile Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 101100194706 Mus musculus Arhgap32 gene Proteins 0.000 description 1
- 101100194707 Xenopus laevis arhgap32 gene Proteins 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
Definitions
- This invention relates to agents for sizing tex tile fibers and process of preparing them. r
- the loose ends which project from a. textile thread canbe smoothly laid on the surface of the thread by treating the threads with sizing agents.
- sizing agents there are principally used starch (either alone or mixed with fat, wax or parafiin and the like), dextrin, glue or similar substances.
- starch either alone or mixed with fat, wax or parafiin and the like
- dextrin glue or similar substances.
- the textiles sized according to the processe hitherto known in most cases can be freed from size only by special operations; Thus, for in-y stance. the sizes containing starch must be treated with a ferment decomposing-starch or with an Y oxidizing agent or a substance of hydrolytic ac- .tion.
- the sizing agent which .is suitable for cotton cannot beapplied with the same good effect to other textile fibers. 1
- an excellently well sized material is'obtained by treating textile fibers with compounds of'high molecular weight of the type of polyvinyl alcohol.
- the size is absorbed by the fiber already after a short treatment and may be appliedequally well to'varlous textile fab-' rics; in each case there is obtained a perfectly well sized thread.
- the alcohol may be applied at temperatures of 10 CF90? C. v
- polyvinyl alcohols there may be used products of various lengths of chain and various chem- I ical constitution obtained by any of the usual methods. Processes of preparingthem are, for instance, described in Berichte .der Deutschen Chemischenmaschine, 19 27, pages 1658-1663. According to the desired effect of the products theymay also be prepared from polyvinyl este of various degrees of viscosity.
- the polyvinyl alcohol may be applied either invention but are not intended to limit it thereto, the parts beingby weight: a
- a sizing such as oil, fat wax or the like.
- additional material used for a sizing such as oil, fat wax or the like.
- the thread remains very pliable ifa sulfonated oil is added to the sizing bath.
- the material sized and dried according to the present process is free from dust, whereas this is generally not the case with material prepared with resin containing starch.
- the material can very well easily be"freed from the size, for instance by simply rinsing it in hot water, to which may be added a small'quantity of f soap, without applying any other auxiliary means.
- Material which is not at all or not entirely freed from the size can be dyed without any difli- .culty since the sizeand the fibrous material used are dyed equally.
- Cotton yarn is passed through a bath in which polyvinyl alcohol is dissolved in the pro- 15.
- the yam sized according-to (a) or (b) is introduced into a dyebath at about 45 C. without previousv washing and the bath is slowly heated to 20 80 C. The material is then dyed with the usual additions, rinsed and dried.
- the yam sized according to(a) or (b) is dyed by introducing it at about 40 C. into a dyebath and raising the temperature slowly to 60 C. it is dyed with the usual admixtures and then rinsed and dried;
- the yarn sized according to (a) or (b) is inout being washed previously and heated slowly to 80 C. It is dyed with the usual admixtures, then rinsed and dried.
- a process of sizing textile fibers which comprises treating the fiber with a solution of a polyvinyl alcohol. i i
- An agent for sizing textile fibers which comprises a polyvinyl alcohol and a sulfonated oil.
- a process of sizing textile fibers which comprises treating the fiber with a sizing composition comprising a' polyvinyl alcohol and material of the group consisting of oils, fats and waxes.
- a textile sizing composition comprising a polyvinyl alcohol and a material of the group consisting of oils, fats and waxes.
- a solution of a polyvinyl alcohol As a sizing agent for textile fibers, a solution of a polyvinyl alcohol.
- a process of sizing textile fibers which comprises treating the fiber with a textile sizing composition comprising an efiective amount of a polyvinyl alcohol.
- a textile sizing composition comprising an effective amount of a polyvinyl alcohol.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE345207X | 1928-12-24 | ||
| DE372599X | 1930-06-19 | ||
| DE664679T | 1930-11-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2132901A true US2132901A (en) | 1938-10-11 |
Family
ID=27192654
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US415348A Expired - Lifetime US2132901A (en) | 1928-12-24 | 1929-12-19 | Agent for and process of sizing textile fibers |
| US545364A Expired - Lifetime US2133125A (en) | 1928-12-24 | 1931-06-18 | Agent for sizing textile fibers and a process of applying it |
| US577158A Expired - Lifetime US1920564A (en) | 1928-12-24 | 1931-11-24 | Agent for sizing textile fibers and alpha process of sizing textile fibers |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US545364A Expired - Lifetime US2133125A (en) | 1928-12-24 | 1931-06-18 | Agent for sizing textile fibers and a process of applying it |
| US577158A Expired - Lifetime US1920564A (en) | 1928-12-24 | 1931-11-24 | Agent for sizing textile fibers and alpha process of sizing textile fibers |
Country Status (4)
| Country | Link |
|---|---|
| US (3) | US2132901A (fr) |
| DE (1) | DE664679C (fr) |
| FR (3) | FR687155A (fr) |
| GB (3) | GB345207A (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2451016A (en) * | 1945-10-18 | 1948-10-12 | Sterling W Alderfer | Elastic thread and process of making same |
| US2497536A (en) * | 1946-06-14 | 1950-02-14 | Du Pont | Yarn conditioning |
| US2638734A (en) * | 1947-11-14 | 1953-05-19 | American Viscose Corp | Method of making stable detwisted yarns and fabrics comprising the same |
| US2840442A (en) * | 1954-03-01 | 1958-06-24 | Goodrich Co B F | Treatment of cellulosic yarns by rubbery materials, and textiles thereof |
| US3630259A (en) * | 1969-11-24 | 1971-12-28 | Monsanto Co | Synthetic yarn coated with a spin finish and process for producing the same |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE745525C (de) * | 1937-01-09 | 1944-03-13 | Ig Farbenindustrie Ag | Verwendung von Geweben, Filzen, Vliesen oder losen Lagen von Kunstfaeden zu Filterzwecken |
| US2447578A (en) * | 1941-05-10 | 1948-08-24 | United Shoe Machinery Corp | Art of stiffening the uppers of shoes |
| US2439108A (en) * | 1943-09-11 | 1948-04-06 | Eastman Kodak Co | Coating with polyvinyl alcohol |
| US2743194A (en) * | 1949-10-21 | 1956-04-24 | Deering Milliken Res Corp | Sizing of textile yarn |
| US2808380A (en) * | 1953-02-27 | 1957-10-01 | Nat Starch Products Inc | Aqueous compositions containing polyvinyl alcohol and substituted starch, the substituent being a salt of a carboxyl radical |
| US2785146A (en) * | 1953-08-28 | 1957-03-12 | Celanese Corp | Improving the stability of polyvinyl alcohol |
| DE957336C (de) * | 1953-12-19 | 1957-01-31 | Hoechst Ag | Verfahren zum Behandeln von Stapelfasern und Faeden |
| US2935472A (en) * | 1954-08-16 | 1960-05-03 | Minnesota Mining & Mfg | Lost circulation materials |
| US3045317A (en) * | 1957-06-04 | 1962-07-24 | Stevens & Co Inc J P | Process for producing sized glass yarns |
| US3052652A (en) * | 1958-02-26 | 1962-09-04 | Borden Co | Alkoxylated polyvinyl alcohol |
| US3086963A (en) * | 1960-01-05 | 1963-04-23 | Kurashiki Rayon Co | Polyvinyl alcohol treatment |
| GB1036787A (en) * | 1962-08-09 | 1966-07-20 | Kurashiki Rayon Kk | Method of manufacturing synthetic fibres of acetalized polyvinyl alcohol |
| US3316336A (en) * | 1963-12-05 | 1967-04-25 | Dow Chemical Co | Process for preparing composite filamentary articles |
| JPS5173756A (en) * | 1974-12-20 | 1976-06-25 | Shikibo Ltd | Suiyoekikara horibiniruarukooruo bunrisuruhoho |
| DE3115163A1 (de) * | 1981-04-15 | 1982-11-11 | Hoechst Ag, 6000 Frankfurt | Waessrige polyvinylester-dispersion, verfahren zu ihrer herstellung und ihre verwendung |
| US4568726A (en) * | 1982-10-04 | 1986-02-04 | Petrolite Corporation | Ester-containing halopolyalkylenes |
| CN113549378A (zh) * | 2020-04-26 | 2021-10-26 | 合肥杰事杰新材料股份有限公司 | 一种乳胶涂料及其制备方法 |
-
1929
- 1929-12-10 GB GB37868/29A patent/GB345207A/en not_active Expired
- 1929-12-19 US US415348A patent/US2132901A/en not_active Expired - Lifetime
- 1929-12-23 FR FR687155D patent/FR687155A/fr not_active Expired
-
1930
- 1930-11-29 DE DE1930664679D patent/DE664679C/de not_active Expired
-
1931
- 1931-06-18 US US545364A patent/US2133125A/en not_active Expired - Lifetime
- 1931-06-19 FR FR40385D patent/FR40385E/fr not_active Expired
- 1931-06-19 GB GB17810/31A patent/GB372599A/en not_active Expired
- 1931-11-23 FR FR41010D patent/FR41010E/fr not_active Expired
- 1931-11-24 US US577158A patent/US1920564A/en not_active Expired - Lifetime
- 1931-11-30 GB GB33183/31A patent/GB382785A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2451016A (en) * | 1945-10-18 | 1948-10-12 | Sterling W Alderfer | Elastic thread and process of making same |
| US2497536A (en) * | 1946-06-14 | 1950-02-14 | Du Pont | Yarn conditioning |
| US2638734A (en) * | 1947-11-14 | 1953-05-19 | American Viscose Corp | Method of making stable detwisted yarns and fabrics comprising the same |
| US2840442A (en) * | 1954-03-01 | 1958-06-24 | Goodrich Co B F | Treatment of cellulosic yarns by rubbery materials, and textiles thereof |
| US3630259A (en) * | 1969-11-24 | 1971-12-28 | Monsanto Co | Synthetic yarn coated with a spin finish and process for producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| FR687155A (fr) | 1930-09-06 |
| GB345207A (en) | 1931-03-10 |
| FR40385E (fr) | 1932-06-09 |
| US2133125A (en) | 1938-10-11 |
| DE664679C (de) | 1938-08-18 |
| FR41010E (fr) | 1932-10-20 |
| GB372599A (en) | 1932-05-12 |
| US1920564A (en) | 1933-08-01 |
| GB382785A (en) | 1932-11-03 |
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