US2191338A - Stabilized mineral oil - Google Patents
Stabilized mineral oil Download PDFInfo
- Publication number
- US2191338A US2191338A US218039A US21803938A US2191338A US 2191338 A US2191338 A US 2191338A US 218039 A US218039 A US 218039A US 21803938 A US21803938 A US 21803938A US 2191338 A US2191338 A US 2191338A
- Authority
- US
- United States
- Prior art keywords
- mineral oil
- rosin
- oil
- per cent
- cables
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002480 mineral oil Substances 0.000 title description 19
- 235000010446 mineral oil Nutrition 0.000 title description 19
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 16
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 16
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 16
- 239000011347 resin Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000003921 oil Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 8
- 239000003990 capacitor Substances 0.000 description 7
- 239000002023 wood Substances 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 239000003989 dielectric material Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001717 carbocyclic compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/20—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils
- H01B3/22—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/14—Electric or magnetic purposes
- C10N2040/16—Dielectric; Insulating oil or insulators
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/14—Electric or magnetic purposes
- C10N2040/17—Electric or magnetic purposes for electric contacts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
- C10N2060/04—Oxidation, e.g. ozonisation
Definitions
- Mineral oil which consists substantially of aliphatic and carbocyclic compounds, has many advantageous properties, but even after subjection to the most approved refining treatment is subject to slow chemical changes under the environmental conditions occurring in electrical apparatus.
- mineral transformer oil is subject to the formation of a sludge which impedes the circulation of the oil.
- an increase of energy loss (rise of power factor) progressively occurs with elapsed time, the change being especially marked at elevated temperatures.
- compositions embodying my present invention should be distinguished from mineral oil compositions containing rosin, in which the content of rosin is relatively high, that is, in excess of 10 per cent by weight.
- the function of such relatively large rosin addition has been to increase the viscosity and tackiness of the oil, for special uses requiring viscous material.
- Such relatively large additions of rosin do not produce the advantageous properties characterizing the present compositions.
- Illustrative of the benefits of my invention is the improvement in power factor effected in high voltage' cables and capacitors containing paper spacers which are impregnated with mineral oil containing rosin, or other tree resin.
- the operation of such capacitors and cables when rosin is not present is accompanied by a rise in power factor, the rise being particularly marked when the capacitors or cables are elevated above ordinary room temperature under oxidizing conditions. when, however, about five-tenths per cent by weight of rosin, or equivalent tree resin, is dissolved in the mineral oil, capacitors or cables otherwise similar, impregnated with such solution, continue to operate without rise of power factor.
- compositions of mineral oil and less than three per cent rosin have substantially the same viscosity as the unmodified oil. No evidence of increased tackiness is observable. However, the formation of sludge, which will thicken oil in which it forms, is decreased by the presence of the rosin, or the like, in the specified small amounts.
- the mineral oil is stabilized, that is, made more resistant to chemical changes, and in particular is made less subject to sludge formation.
- mineral oil having the following physical properties, although I wish it to be understood that this oil is identified merely by way of illustration:
- Flash point Not less than 130 C. Burn point Not less than 140 C. Viscosity (37.8 C.) Not less than 50 seconds Saybolt Universal Specific gravity Approximately .875 Pour point -40 C., or lower Color Not greater than 2,
- a composition of matter comprising as essential ingredients mineral oil and a wood resin, the proportion of the wood resin by weight being within the limits of about one-tenth to three per cent of the mineral oil.
- a composition of matter comprising as essential ingredients mineral oil and a wood resin, the proportion of the wood resin by weight being about one-half per cent based on the weight of the mineral oil.
- a dielectric and insulating material consisting essentially of hydrocarbon oil and containing a fraction of one per cent by weight of rosin.
- a dielectric material for cables and capacitors comprising paper impregnated with mineral oil containing about one-tenth to three per cent by weight of a tree resin.
- a dielectric material for cables and capacitors comprising paper impregnated with mineral oil containing about five-tenths per cent. by weight of rosin.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Insulating Materials (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US218039A US2191338A (en) | 1938-07-07 | 1938-07-07 | Stabilized mineral oil |
| FR857431D FR857431A (fr) | 1938-07-07 | 1939-07-06 | Huiles minérales stabilisées et leurs applications |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US218039A US2191338A (en) | 1938-07-07 | 1938-07-07 | Stabilized mineral oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2191338A true US2191338A (en) | 1940-02-20 |
Family
ID=22813497
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US218039A Expired - Lifetime US2191338A (en) | 1938-07-07 | 1938-07-07 | Stabilized mineral oil |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2191338A (fr) |
| FR (1) | FR857431A (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2473242A (en) * | 1945-04-26 | 1949-06-14 | Gen Electric | Heat-resisting capacitor |
| US4402753A (en) * | 1981-07-30 | 1983-09-06 | Invictus Unlimited, Inc. | Composition and method for curing concrete |
| US4475952A (en) * | 1981-07-30 | 1984-10-09 | Invictus Unlimited, Inc. | Treating concrete |
-
1938
- 1938-07-07 US US218039A patent/US2191338A/en not_active Expired - Lifetime
-
1939
- 1939-07-06 FR FR857431D patent/FR857431A/fr not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2473242A (en) * | 1945-04-26 | 1949-06-14 | Gen Electric | Heat-resisting capacitor |
| US4402753A (en) * | 1981-07-30 | 1983-09-06 | Invictus Unlimited, Inc. | Composition and method for curing concrete |
| US4475952A (en) * | 1981-07-30 | 1984-10-09 | Invictus Unlimited, Inc. | Treating concrete |
Also Published As
| Publication number | Publication date |
|---|---|
| FR857431A (fr) | 1940-09-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2369090A (en) | Insulating oil compositions | |
| US2191338A (en) | Stabilized mineral oil | |
| US1935595A (en) | Liquid composition and electrical apparatus containing same | |
| US2195659A (en) | Stable mineral oil and method of preparing the same | |
| US3959162A (en) | Insulating oil | |
| US2081886A (en) | Oil composition | |
| US1856700A (en) | Insulating oil | |
| US2257870A (en) | Insulating oil | |
| US2198562A (en) | Method of making sulphurized | |
| US1793134A (en) | Refined viscous hydrocarbon oil | |
| US3573209A (en) | Insulating compositions and materials | |
| US1988299A (en) | Oil for transformers and the like | |
| US2892166A (en) | Additive for dielectric fluid of transformer assembly | |
| GB761363A (en) | Improvements in or relating to impregnating compositions for use in the manufacture of electric cables and condensers | |
| US1946322A (en) | Composition for the impregnation of cable insulation | |
| US2318373A (en) | Nonresinous condensation product | |
| GB715193A (en) | Improvements in electric cables and condensers | |
| US2257872A (en) | Insulating oil composition | |
| US1634054A (en) | Petroleum-oil composition | |
| US2000105A (en) | Mineral oil composition | |
| US1807060A (en) | Cable oil | |
| GB443340A (en) | Improvements in and relating to organic fluorine compounds | |
| US2229485A (en) | Method of increasing the sludge stability of a petroleum lubricating oil distillate | |
| US2214401A (en) | Process for treating mineral oils | |
| US1617826A (en) | Oil composition |