US2767111A - Method and compositions for use in treating and deforming metals - Google Patents
Method and compositions for use in treating and deforming metals Download PDFInfo
- Publication number
- US2767111A US2767111A US290336A US29033652A US2767111A US 2767111 A US2767111 A US 2767111A US 290336 A US290336 A US 290336A US 29033652 A US29033652 A US 29033652A US 2767111 A US2767111 A US 2767111A
- Authority
- US
- United States
- Prior art keywords
- acid
- treating
- metal
- compositions
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 20
- 239000002184 metal Substances 0.000 title claims description 20
- 239000000203 mixture Substances 0.000 title claims description 12
- 238000000034 method Methods 0.000 title description 16
- 150000002739 metals Chemical class 0.000 title description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- GQZXNSPRSGFJLY-UHFFFAOYSA-N hydroxyphosphanone Chemical compound OP=O GQZXNSPRSGFJLY-UHFFFAOYSA-N 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 235000011007 phosphoric acid Nutrition 0.000 claims description 4
- 235000015096 spirit Nutrition 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 229940046817 hypophosphorus acid Drugs 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- 125000005456 glyceride group Chemical group 0.000 description 3
- 125000005480 straight-chain fatty acid group Chemical group 0.000 description 3
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 2
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 2
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000010734 process oil Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010915 one-step procedure Methods 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/02—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
- C23C22/03—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions containing phosphorus compounds
Definitions
- This invention relates to the art of treating and deforming metal and is particularly concerned with the provision of an improved composition and method for treating the surface of the metal and mechanically working the same as by means of such operations as are involved in the drawing, rolling, stamping or other alteration of the physical shape of the metal.
- the invention is especially useful in the treating and working of ferriferous metal and will be specifically described with this field of usefulness in mind.
- the present invention is based upon the discovery that the advantages incident to the two stage procedure heretofore in use, i. e., first, the phosphatizing and, second, the lubrication of the phosphatized coating, can be obtained in a one-step procedure by subjecting the metal to be deformed to the action at room temperature of a non-aqeuous solution and then drying the metal.
- our improved solution is substantially non-aqueous and consists essentially of the following atent ice principal ingredients in approximately the proportions indicated, i. e., from 1 to 3% of an acid of phosphorus from the class consisting of ortho-phosphoric acid and hypo-phosphorous acid; from 5 to 30% of a saturated straight chain fatty acid or its glyceride having a chain length of at least 12 carbon atoms; from 20 to 30% of blending solvent; and at least 50% of mineral spirits, the latter constituting essentially the remainder of the composition. It is important also that the composition be further characterized by containing not over approximately 2% water.
- Typical examples of the saturated straight chain fatty acids useful with our invention are stearic acid, lauric acid, myristic acid and the glycerides of these acids are examples of suitable glycerides.
- suitable blending solvents are methyl isobutyl carbinol, butyl Cellosolve, butyl Carbitol, hexyl Cellosolve, etc.
- suitable mineral spirits are kerosene, Stoddard solvent, high flash naphtha from both petroleum and coal tar origin, hydrogenated petroleum solvent, etc. The main requirement is that the solvent evaporate at a reasonable rate so that it leaves a film of the other ingredients on the surface to be treated.
- composition for coating metal said c m osition including, as its essential and principal ingredients, from 1 to 3% of an acid of phosphorus from the class consisting of ortho-p'hqsphojric acid and hypo-phosphorous acid; from 5 to 30% of a material from the class consisting of saturated straight chain fatty acids and their glyeer'ides' characteriiedb'y having a chain length or at "least 12 carbon atoms; fr m '20 to 30% or blendingsolvent; and at least 50% of mineral spirits, the content of Which latter constituting essentially the remainder.
- composition of claim 1 which is further charact'e'i-iid By having a earliest of water of not over 2%. 3.
- steps which comprise treating the metal with the composition of claim 1 and drying the surface so treated prior to deformation 7 thereof.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Chemical Treatment Of Metals (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US290336A US2767111A (en) | 1952-05-27 | 1952-05-27 | Method and compositions for use in treating and deforming metals |
| FR1075889D FR1075889A (fr) | 1952-05-27 | 1953-04-15 | Perfectionnements apportés aux procédés et produits pour le traitement préalablede métaux pour leur déformation à froid |
| GB14701/53A GB738904A (en) | 1952-05-27 | 1953-05-26 | Methods of and compositions for phosphating and lubricating metals |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US738904XA | 1952-05-27 | 1952-05-27 | |
| US1075889XA | 1952-05-27 | 1952-05-27 | |
| US290336A US2767111A (en) | 1952-05-27 | 1952-05-27 | Method and compositions for use in treating and deforming metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2767111A true US2767111A (en) | 1956-10-16 |
Family
ID=61160938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US290336A Expired - Lifetime US2767111A (en) | 1952-05-27 | 1952-05-27 | Method and compositions for use in treating and deforming metals |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US2767111A (fr) |
| FR (1) | FR1075889A (fr) |
| GB (1) | GB738904A (fr) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2935432A (en) * | 1957-04-02 | 1960-05-03 | Reilly Whiteman Walton Company | Metal treatment |
| US3042558A (en) * | 1959-05-28 | 1962-07-03 | Aluminum Res Corp | Cold forming lubricant and method of applying same |
| US3129502A (en) * | 1954-04-21 | 1964-04-21 | Chrysler Corp | Process for joining metallic parts |
| US3262490A (en) * | 1954-04-21 | 1966-07-26 | Chrysler Corp | Process for joining metallic surfaces and products made thereby |
| US4027070A (en) * | 1974-03-08 | 1977-05-31 | Nippon Steel Corporation | Steel plate for preparing cans by ironing |
| US5851962A (en) * | 1992-08-18 | 1998-12-22 | Ethyl Japan Corporation | Lubricant composition for wet clutch or wet brake |
| US6251840B1 (en) * | 1995-09-12 | 2001-06-26 | The Lubrizol Corporation | Lubrication fluids for reduced air entrainment and improved gear protection |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE561643A (fr) * | 1957-01-30 | |||
| US4279946A (en) | 1977-09-07 | 1981-07-21 | Foseco International Limited | Coating compositions |
| IT1227716B (it) * | 1988-11-23 | 1991-05-06 | Pai Kor Srl | Fosfatazione organica in solventi non clorurati aventi flash point > 65 c ed impianto per la sua utilizzazione comprendente il recupero deisolventi |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2008939A (en) * | 1932-07-29 | 1935-07-23 | John L Tufts | Method of and material for treating metal |
| US2153811A (en) * | 1936-11-05 | 1939-04-11 | Harley A Montgomery | Process of treating sheet metal for drawing and the like |
| US2258309A (en) * | 1938-04-07 | 1941-10-07 | Standard Oil Dev Co | Lubricant |
| US2430400A (en) * | 1944-01-03 | 1947-11-04 | Carnegie Illinois Steel Corp | Lubricating and cooling compound for cold reducing mills |
| US2473614A (en) * | 1945-12-13 | 1949-06-21 | American Chem Paint Co | Method of and material for protecting and conditioning metal surfaces |
| US2522176A (en) * | 1947-10-14 | 1950-09-12 | Parker Rust Proof Co | Drawing ferrous wire and other metal-working processes |
-
1952
- 1952-05-27 US US290336A patent/US2767111A/en not_active Expired - Lifetime
-
1953
- 1953-04-15 FR FR1075889D patent/FR1075889A/fr not_active Expired
- 1953-05-26 GB GB14701/53A patent/GB738904A/en not_active Expired
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2008939A (en) * | 1932-07-29 | 1935-07-23 | John L Tufts | Method of and material for treating metal |
| US2153811A (en) * | 1936-11-05 | 1939-04-11 | Harley A Montgomery | Process of treating sheet metal for drawing and the like |
| US2258309A (en) * | 1938-04-07 | 1941-10-07 | Standard Oil Dev Co | Lubricant |
| US2430400A (en) * | 1944-01-03 | 1947-11-04 | Carnegie Illinois Steel Corp | Lubricating and cooling compound for cold reducing mills |
| US2473614A (en) * | 1945-12-13 | 1949-06-21 | American Chem Paint Co | Method of and material for protecting and conditioning metal surfaces |
| GB625297A (en) * | 1945-12-13 | 1949-06-24 | American Chem Paint Co | Method of and material for finishing metal surfaces |
| US2522176A (en) * | 1947-10-14 | 1950-09-12 | Parker Rust Proof Co | Drawing ferrous wire and other metal-working processes |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3129502A (en) * | 1954-04-21 | 1964-04-21 | Chrysler Corp | Process for joining metallic parts |
| US3262490A (en) * | 1954-04-21 | 1966-07-26 | Chrysler Corp | Process for joining metallic surfaces and products made thereby |
| US2935432A (en) * | 1957-04-02 | 1960-05-03 | Reilly Whiteman Walton Company | Metal treatment |
| US3042558A (en) * | 1959-05-28 | 1962-07-03 | Aluminum Res Corp | Cold forming lubricant and method of applying same |
| US4027070A (en) * | 1974-03-08 | 1977-05-31 | Nippon Steel Corporation | Steel plate for preparing cans by ironing |
| US5851962A (en) * | 1992-08-18 | 1998-12-22 | Ethyl Japan Corporation | Lubricant composition for wet clutch or wet brake |
| US6251840B1 (en) * | 1995-09-12 | 2001-06-26 | The Lubrizol Corporation | Lubrication fluids for reduced air entrainment and improved gear protection |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1075889A (fr) | 1954-10-20 |
| GB738904A (en) | 1955-10-19 |
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