US2871135A - Method for producing drying oils and the oil so produced - Google Patents

Method for producing drying oils and the oil so produced Download PDF

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Publication number
US2871135A
US2871135A US602439A US60243956A US2871135A US 2871135 A US2871135 A US 2871135A US 602439 A US602439 A US 602439A US 60243956 A US60243956 A US 60243956A US 2871135 A US2871135 A US 2871135A
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US
United States
Prior art keywords
oil
drying
raw
produced
synthetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US602439A
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English (en)
Inventor
Weiss Josef
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RICHARD NILSSON AB
Original Assignee
RICHARD NILSSON AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RICHARD NILSSON AB filed Critical RICHARD NILSSON AB
Application granted granted Critical
Publication of US2871135A publication Critical patent/US2871135A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C09D191/005—Drying oils

Definitions

  • the enolized aluminum-alcoholate then reacts with 2 moles of a fatty acid thus forming a drying oil the constitution of which is explained by the replacement of the 2 moles alcohol by 2 moles fatty acids while the enolic compound remains in its place bonded to the aluminum via the O-bridge.
  • the mixture of the natural and the synthetic oils is carried out either at room temperature or at an elevated temperature. Mixing may be elfected by agitating or stirring until the components are intimately mixed and from a homogenous composition. Driers such as lead-, cobaltand/or manganese salts, and/or pigments, may be added in known manner.
  • the action of the addition of the synthetic oils, for instance on linseed oil and other drying natural oils consists in a considerable acceleration of the drying process of the oils so that the duration of this process may be reduced to about /5-% of the drying time of the original drying oils used in the mixture.
  • the non drying oils will be converted into drying oils having shorter drying times than boiled linseed oil.
  • the water and weather resistance of the oil is considerably improved by the addition of said synthetic oil.
  • the films obtained from linseed oil and other drying oils swell in water and are spoiled after a few days.
  • the films of expensive isomerized linseed oils are dim already after having'been exposed to the influence of water for one day.
  • the films produced by oils according to the pres ent invention remain clear even after having been exposed to water for months and they do not swell in water.
  • the pigmentation properties, the adhesion, the flexibility etc. are excellent.
  • the oil composition according to the invention is compatible with all other raw materials conventionally used in producing lacquers and varnishes.
  • oils and their films can be attained by changing the ratio between the quantities of the natural oil and the synthetic oil.
  • range of viscosity of the oils which are produced may vary from a low viscosity oil like the known natural oils to the viscosity of standoils.
  • all films of oils produced according to the present invention are repellent to fungi.
  • Raw Soybean Oil Raw Soybean Oll,'sicActivted Raw Soybean Oil, with synthetic oil 4- feebIe -- excellent no Do.
  • Raw Herring Oil sicactivted Raw Herring Oil, with synthetic oil 0. Row lien-inn Oil, with synthetic oiland pigmen sozlgxol treated Herring Oil (Iodine Number Solexol treated Herring Oil (Iodine Number non drying 220); sicactivted. SoleIoI treated Herring -Oil (Iodine, Number 6 1 I10 0 110 D0.
  • Solezol treated Herring Oil (Iodine Number 5 6; about 1---. 0 "d n0 D0.
  • compositions include, according to the invention, a mixture of the respective oil with synthetic oils produced by a condensation improved properties in all respects.
  • the organicaluminium compound consists of. an cnolic compound, the: en-
  • olic component of which is i. e.-. aceto-acetic ester; malonio diethyl ester or acetonylacetom Any of these compounds may be used in the ,dilferentexamplcs.
  • the drying time of the mixture is /2 hour and .the viscosity (12) 40 kgs. raw Chinese Wood oil are'mixed'at 50 C. with 60 kgs. of a synthetic oil, produced by con densation of Whale oil fatty acid with an organic aluminium compound of the kind specified above.
  • the drying time of the mixture is less than /2 hour and the viscosity 230 sec.
  • the synthetic oil is producedin thehigher fatty acids and mixtures of unsaturated higher fatty acids with one mole of an organic aluminum compound in which two valences of the aluminum are bonded to alcohols while one valence of the aluminum is bonded to oxygen of an enolic compound selected from the group consisting of acetoacetic ester, malonic diethyl ester and acetonyl acetone to form a synthetic oil and mixing it with a higher fatty acid triglyceride.
  • a drying oil comprising a mixture of glyceride of a higher fatty acid and a synthetic oil obtained by condensing two moles of a fatty acid selected from the group consisting of unsaturated higher fatty acids and mixtures of unsaturated higher fatty acids with saturated higher fatty acids with one mole of an aluminum compound prepared by reacting one mole of aluminum alcoholate and one mole of an enolic compound selected from the group consisting of acetoacetic ester, malonic diethyl ester and acetonyl acetone.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Fats And Perfumes (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
US602439A 1955-08-24 1956-08-06 Method for producing drying oils and the oil so produced Expired - Lifetime US2871135A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE354879X 1955-08-24
SE71155X 1955-11-07

Publications (1)

Publication Number Publication Date
US2871135A true US2871135A (en) 1959-01-27

Family

ID=26654762

Family Applications (1)

Application Number Title Priority Date Filing Date
US602439A Expired - Lifetime US2871135A (en) 1955-08-24 1956-08-06 Method for producing drying oils and the oil so produced

Country Status (7)

Country Link
US (1) US2871135A (de)
BE (1) BE550505A (de)
CH (1) CH354879A (de)
DE (1) DE1076860B (de)
FR (1) FR1156062A (de)
GB (1) GB798351A (de)
NL (1) NL93693C (de)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3097957A (en) * 1959-06-18 1963-07-16 Exxon Research Engineering Co Coating composition with blocked alcoholates therein
US3258475A (en) * 1963-08-13 1966-06-28 Faulkner Raymond Noel Film-forming organometallic derivatives of fatty acids
US3287384A (en) * 1961-01-11 1966-11-22 Houghton & Co E F Ortho esters of aluminum, silicon or titanium with a metal soap of a hydroxy-fatty acid
US4090886A (en) * 1974-01-18 1978-05-23 Manchem Limited Aluminum based air drying compositions
US4264370A (en) * 1976-03-01 1981-04-28 Manchem Limited Method for preparing aluminum-based air drying compositions
US4529555A (en) * 1982-09-27 1985-07-16 Kawaken Fine Chemicals Co., Ltd. Surface modifier for powdery or granular substance having hydrophilic surface comprising an aluminum chelate compound
US4576647A (en) * 1982-09-27 1986-03-18 Kawaken Fine Chemicals Co., Ltd. Oleophilic composition comprising a powdery or granular substance having a hydrophilic surface and an aluminum chelate compound
US6887398B1 (en) * 1997-09-27 2005-05-03 Rwe-Dea Aktiengesellschaft Fur Mineraloel Und Chemie Aluminum acetoacetate compounds, the production and use thereof as printing ink additives

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1281610B (de) * 1959-06-08 1968-10-31 Glidden Co UEberzugsmittel fuer Metalle
FR2975836B1 (fr) 2011-05-24 2014-07-04 Schneider Electric Ind Sas Appareillage electrique a isolation gazeuse ayant des moyens de regulation de la pression de gaz

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE878826C (de) * 1951-01-13 1953-06-08 Albert Ag Chem Werke Verfahren zur Verbesserung von Bindemitteln fuer Lacke, Anstrichmittel, Kitte, Klebstoffe und plastische Massen auf der Grundlage von OElen, Naturharzen oder Kunstharzen

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3097957A (en) * 1959-06-18 1963-07-16 Exxon Research Engineering Co Coating composition with blocked alcoholates therein
US3287384A (en) * 1961-01-11 1966-11-22 Houghton & Co E F Ortho esters of aluminum, silicon or titanium with a metal soap of a hydroxy-fatty acid
US3258475A (en) * 1963-08-13 1966-06-28 Faulkner Raymond Noel Film-forming organometallic derivatives of fatty acids
US4090886A (en) * 1974-01-18 1978-05-23 Manchem Limited Aluminum based air drying compositions
US4264370A (en) * 1976-03-01 1981-04-28 Manchem Limited Method for preparing aluminum-based air drying compositions
US4529555A (en) * 1982-09-27 1985-07-16 Kawaken Fine Chemicals Co., Ltd. Surface modifier for powdery or granular substance having hydrophilic surface comprising an aluminum chelate compound
US4576647A (en) * 1982-09-27 1986-03-18 Kawaken Fine Chemicals Co., Ltd. Oleophilic composition comprising a powdery or granular substance having a hydrophilic surface and an aluminum chelate compound
US6887398B1 (en) * 1997-09-27 2005-05-03 Rwe-Dea Aktiengesellschaft Fur Mineraloel Und Chemie Aluminum acetoacetate compounds, the production and use thereof as printing ink additives

Also Published As

Publication number Publication date
GB798351A (en) 1958-07-16
FR1156062A (fr) 1958-05-12
CH354879A (de) 1961-06-15
DE1076860B (de) 1960-03-03
NL93693C (de)
BE550505A (de)

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