US2984473A - Furnace conveyor rolls and the like - Google Patents
Furnace conveyor rolls and the like Download PDFInfo
- Publication number
- US2984473A US2984473A US748320A US74832058A US2984473A US 2984473 A US2984473 A US 2984473A US 748320 A US748320 A US 748320A US 74832058 A US74832058 A US 74832058A US 2984473 A US2984473 A US 2984473A
- Authority
- US
- United States
- Prior art keywords
- roll
- furnace
- coating
- stabilized zirconia
- zirconia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 23
- 238000000576 coating method Methods 0.000 description 20
- 239000011248 coating agent Substances 0.000 description 17
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 16
- 239000010408 film Substances 0.000 description 11
- 229910001120 nichrome Inorganic materials 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 238000004901 spalling Methods 0.000 description 7
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/02—Skids or tracks for heavy objects
- F27D3/026—Skids or tracks for heavy objects transport or conveyor rolls for furnaces; roller rails
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/937—Sprayed metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12611—Oxide-containing component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12611—Oxide-containing component
- Y10T428/12618—Plural oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12778—Alternative base metals from diverse categories
Definitions
- This invention relates to furnace conveyor rolls and the like and particularly to furnace conveyor rolls over which metallic strip is passed and advanced through a heating furnace.
- the invention will be particularly illustrated and described as embodied in a furnace conveyor roll for passing steel strip through an annealing furnace. It is well known in the metal treating arts that difficulties are encountered by reasons of the collection of accretions of material from metal strip on the metallic conveyor in the heating furnace, e.g., metallic conveyor elements used in annealing strip with the strip passing over or around the rolls.
- the problem has been, particularly, acute in the treatment of high silicon steels and other steels which require high treatment or annealing temperatures. This problem appears to be influenced by a variety of factors including the tension of the strip, the composition of the strip, the temperature of the furnace atmosphere, as well as the characteristic of the roll surface.
- the conveyor roll of the present invention has a structural metal body with a stabilized zirconia work engaging surface.
- the body of the roll is of metal; a high temperature alloy of known composition desirably being employed.
- the zirconia used for the work engaging surface must be stabilized with calcium oxide or an equivalent stabilizing agent. Unstabilized zirconia has proven unsatisfactory and is subject to the spalling problem, previously mentioned.
- the metal roll is provided with a coating or film of Nichrome prior to the addition of the stabilized zirconia coating.
- the metal roll body may be a hollow body such as that commonly used in conveyor rolls or it may be of any other roll design.
- Figure 1 is a diagrammatic view of a heat treating chamber showing that a high strip can be supported on the furnace conveyor rolls of this invention
- Figure 4 is a diagrammatic fragmentary cross section to enlarged scale of apart of the roll body of Figure '2.
- a furnace chamber 10 through which strip 11 is adapted to be drawn, the strip passing over a series of rolls 12 at the top of the furnace and then passing over rolls 12 at the bottom of the furnace. It is desirable that the rolls be of uniform construction.
- the rolls 12 may be driven or turned idly as the strip passes through the chamber 10.
- the chamber 10 is heated internally by suitable heating methods not illustrated herein.
- the furnace conveyor roll 12 includes a metal body 13 made up of a barrel 14, two shaft ends 15, andtwo closure plates 16.
- the shaft ends 15 are filled with heat insulating material 17.
- the barrel 14 and shaft ends 15, and the closure plates 16 may be of any suitable alloy such as is used in the manufacture of furnace conveyor elements. Preferably we use a heat resistant alloy.
- the barrel 14 has a thin film of Nichrome 18 applied to its outer surface. This film may be applied by any conventional means, as for example, spraying.
- the outer Work engaging surface coating .20 of stabilized zirconia is then applied to the Nichrome.
- the coating may be applied by any known method which will provide a fused surface.
- the stabilized zirconia may be applied by high temperature spraying and to this end a metallizing gun 19 is provided tomelt and spray the stabilized zirconia.
- the shaft ends 15 have cylindrical portions 21 fitting within the ends of barrel 14,'tapered portions 22, cylindrical end portions 23 and trunnions 24 which may be mounted for rotation in a conventional manner.
- the ends of the barrel 14 are welded to the ends of the shaft ends 15 by weldments 25.
- the closure plates 17 are welded to the shaft ends 15 by weldments 26.
- the stabilized zirconia surface 20 constitutes the working engaging surface of the roll and is the only portion of the roll which comes in contact with the strip being carried over the roll.
- a ferrous roll body containing 25% chromium and 12% nickel was spray coated over /2 of its length with a film of -20 Nichrome (80% nickel and 20% chromium).
- a coating of stabilized zirconia (zirconia stabilized for example with CaO) was applied to /3 of the Nichrome coated length.
- a coating of alumina was applied to another third of the Nichrome coated length and a coating of zirconium silicate was applied to the remaining 6 of the Nichrome coated length.
- Identical coatings of stabilized zirconia alumina and zirconium silicate were applied to the portions of the roll which did not have the Nichrome coating.
- the roll was then subjected to cycles of temperature change such as would be encountered in heating and cooling a strip treating furnace.
- the alumina had spalled on both Nichrome coated and uncoated areas to an extent that it would be unsatisfactory for further use.
- the zirconium silicate showed signs of spalling in both cases but could still he used.
- the second cycle only the stabilized zirconia on the Nichnome film remained intact. After five cycles all of the coatings had spalled 01f except the stabilized zirconia which still remained unimpaired.
- the stabilized-zirconia coating must be applied to a roll jbodyfof proper composition and physical properties for the temperature in the particular'furnace involved.
- the zirconia coat maybe used in certain cases without an undercoat, however, where any difliculty with spalling is encountered a Nichrome film applied to the roll surface priorto the application of the stabilized zirconia will eliminate the spalling problem.
- a furnace conveyor roll and the like comprising a work supporting metal body and a coating of stabilized zirconia covering the work engaging portion of said body and being fixed thereto.
- a furnace conveyor element and the like comprising a work supporting metal body and a stabilized zirconia coating on the work engaging surface of said body, said stabilized zirconia covering the entire work engaging portion of the body and being fused thereto.
- a furnace conveyor roll and the like comprising a work supported metal body and a coating of zirconia stabilized with calcium oxide-covering the work engaging portion of said body and fused thereto.
- a furnace conveyor element and the like comprising a work supporting ferrous body and a zirconia coating stabilized with calcium oxide on the work engaging surface of said body, said stabilized zirconia covering the entire work engaging portion of the body and being fused thereto.
- a furnace conveyor element and the like comprising a ferrous body, a nickel chromium alloy film on the work engaging portion of said body and bonded thereto and an outer coating of zirconia stabilized with calcium oxide fused to the nickel chromium alloy film over the entire work engaging surface of the body.
- a furnace conveyor element and the like comprising ;a ferrous body, a nickel chromium alloy film consisting essentially ofbetween about %80% nickel and between 40%-20% chromium onthe work engaging portion of said body and bonded thereto and an outer coating of stabilized zirconia fixed to the nickel chromium alloy film over the entire work engaging surface of the body.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Coating By Spraying Or Casting (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US748320A US2984473A (en) | 1958-07-14 | 1958-07-14 | Furnace conveyor rolls and the like |
| BE591436A BE591436A (fr) | 1958-07-14 | 1960-06-01 | Rouleaux transporteurs et éléments analogues pour fours. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US748320A US2984473A (en) | 1958-07-14 | 1958-07-14 | Furnace conveyor rolls and the like |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2984473A true US2984473A (en) | 1961-05-16 |
Family
ID=25008967
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US748320A Expired - Lifetime US2984473A (en) | 1958-07-14 | 1958-07-14 | Furnace conveyor rolls and the like |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2984473A (fr) |
| BE (1) | BE591436A (fr) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3115335A (en) * | 1961-05-15 | 1963-12-24 | Blaw Knox Co | Furnace rolls |
| US3240414A (en) * | 1962-08-22 | 1966-03-15 | Continental Can Co | Forge rolls for fusion welding of aluminum |
| US3464681A (en) * | 1968-03-05 | 1969-09-02 | Vanfrido Olivotto | Charge conveying device for high temperature industrial ovens |
| US4056873A (en) * | 1975-12-19 | 1977-11-08 | Ugine Carbone | Composite guide roller for a rolling mill |
| US4060882A (en) * | 1975-01-27 | 1977-12-06 | Adamovske Strojirny, Narodni Podnik | Cylinders and rollers for printing machines |
| US4470802A (en) * | 1982-03-31 | 1984-09-11 | Nippon Steel Corporation | Highly buildup-resistant hearth roll for conveying a steel strip through a continuous annealing furnace and a method therefor |
| US4581073A (en) * | 1984-04-10 | 1986-04-08 | Allegheny Ludlum Steel Corporation | Method for descaling metal strip |
| US4876875A (en) * | 1987-12-04 | 1989-10-31 | Coors Porcelain Company | Supported ceramic guide roller |
| US4909485A (en) * | 1986-09-05 | 1990-03-20 | Kawasaki Steel Corp. | Apparatus for continuously annealing metal strip and hearth roll therefor |
| US5265332A (en) * | 1992-12-08 | 1993-11-30 | Norandal Usa, Inc. | Caster shell surface coating method |
| EP0707188A1 (fr) * | 1994-10-14 | 1996-04-17 | W. Haldenwanger Technische Keramik GmbH & Co. KG | Support en sic |
| WO1997043591A1 (fr) * | 1996-05-14 | 1997-11-20 | Bricmont, Inc. | Agencement de four comportant un rouleau a sec |
| US6709372B2 (en) * | 2001-03-06 | 2004-03-23 | Usinor | Roller for metal strip transfer in a continuous annealing furnace |
| US20220268521A1 (en) * | 2021-02-25 | 2022-08-25 | Benteler Maschinenbau Gmbh | Furnace roller and roller furnace |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1578254A (en) * | 1924-06-26 | 1926-03-30 | Thomas E Murray | Protection of metals against corrosion |
| US1861489A (en) * | 1930-02-17 | 1932-06-07 | William Swindell And Brothers | Conveying apparatus |
| US2151048A (en) * | 1937-05-01 | 1939-03-21 | Aluminum Co Of America | Drying roll |
| US2624097A (en) * | 1951-01-09 | 1953-01-06 | Norton Co | Method of making dense, hard, abrasion resistant ceramic articles |
| US2695248A (en) * | 1948-12-15 | 1954-11-23 | Blaw Knox Co | Furnace conveyer element and manufacture thereof |
| US2848349A (en) * | 1955-08-02 | 1958-08-19 | Armour Res Found | Flame spraying process |
-
1958
- 1958-07-14 US US748320A patent/US2984473A/en not_active Expired - Lifetime
-
1960
- 1960-06-01 BE BE591436A patent/BE591436A/fr unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1578254A (en) * | 1924-06-26 | 1926-03-30 | Thomas E Murray | Protection of metals against corrosion |
| US1861489A (en) * | 1930-02-17 | 1932-06-07 | William Swindell And Brothers | Conveying apparatus |
| US2151048A (en) * | 1937-05-01 | 1939-03-21 | Aluminum Co Of America | Drying roll |
| US2695248A (en) * | 1948-12-15 | 1954-11-23 | Blaw Knox Co | Furnace conveyer element and manufacture thereof |
| US2624097A (en) * | 1951-01-09 | 1953-01-06 | Norton Co | Method of making dense, hard, abrasion resistant ceramic articles |
| US2848349A (en) * | 1955-08-02 | 1958-08-19 | Armour Res Found | Flame spraying process |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3115335A (en) * | 1961-05-15 | 1963-12-24 | Blaw Knox Co | Furnace rolls |
| US3240414A (en) * | 1962-08-22 | 1966-03-15 | Continental Can Co | Forge rolls for fusion welding of aluminum |
| US3464681A (en) * | 1968-03-05 | 1969-09-02 | Vanfrido Olivotto | Charge conveying device for high temperature industrial ovens |
| US4060882A (en) * | 1975-01-27 | 1977-12-06 | Adamovske Strojirny, Narodni Podnik | Cylinders and rollers for printing machines |
| US4056873A (en) * | 1975-12-19 | 1977-11-08 | Ugine Carbone | Composite guide roller for a rolling mill |
| US4470802A (en) * | 1982-03-31 | 1984-09-11 | Nippon Steel Corporation | Highly buildup-resistant hearth roll for conveying a steel strip through a continuous annealing furnace and a method therefor |
| US4581073A (en) * | 1984-04-10 | 1986-04-08 | Allegheny Ludlum Steel Corporation | Method for descaling metal strip |
| EP0158474A3 (en) * | 1984-04-10 | 1986-10-01 | Allegheny Ludlum Steel Corporation | Method and apparatus for descaling metal strip |
| US4909485A (en) * | 1986-09-05 | 1990-03-20 | Kawasaki Steel Corp. | Apparatus for continuously annealing metal strip and hearth roll therefor |
| US4876875A (en) * | 1987-12-04 | 1989-10-31 | Coors Porcelain Company | Supported ceramic guide roller |
| US5265332A (en) * | 1992-12-08 | 1993-11-30 | Norandal Usa, Inc. | Caster shell surface coating method |
| EP0707188A1 (fr) * | 1994-10-14 | 1996-04-17 | W. Haldenwanger Technische Keramik GmbH & Co. KG | Support en sic |
| WO1997043591A1 (fr) * | 1996-05-14 | 1997-11-20 | Bricmont, Inc. | Agencement de four comportant un rouleau a sec |
| US5833455A (en) * | 1996-05-14 | 1998-11-10 | Bricmont, Inc. | Dry roll furnace arrangement |
| US6709372B2 (en) * | 2001-03-06 | 2004-03-23 | Usinor | Roller for metal strip transfer in a continuous annealing furnace |
| US20220268521A1 (en) * | 2021-02-25 | 2022-08-25 | Benteler Maschinenbau Gmbh | Furnace roller and roller furnace |
Also Published As
| Publication number | Publication date |
|---|---|
| BE591436A (fr) | 1960-10-03 |
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