US3024273A - Alkyl glyceryl ether sulfonate mixtures and processes for preparing the same - Google Patents

Alkyl glyceryl ether sulfonate mixtures and processes for preparing the same Download PDF

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Publication number
US3024273A
US3024273A US659038A US65903857A US3024273A US 3024273 A US3024273 A US 3024273A US 659038 A US659038 A US 659038A US 65903857 A US65903857 A US 65903857A US 3024273 A US3024273 A US 3024273A
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US
United States
Prior art keywords
alkyl
ethers
alcohol
ether
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US659038A
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English (en)
Inventor
David D Whyte
Edwin O Korpi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
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Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DENDAT1249434D priority Critical patent/DE1249434B/de
Priority to FR1139251D priority patent/FR1139251A/fr
Priority to BE538938A priority patent/BE538938A/xx
Priority to NL198118A priority patent/NL101525C/xx
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to US659038A priority patent/US3024273A/en
Application granted granted Critical
Publication of US3024273A publication Critical patent/US3024273A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C309/07—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton
    • C07C309/09—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing etherified hydroxy groups bound to the carbon skeleton
    • C07C309/10—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing etherified hydroxy groups bound to the carbon skeleton with the oxygen atom of at least one of the etherified hydroxy groups further bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/13—Saturated ethers containing hydroxy or O-metal groups
    • C07C43/137—Saturated ethers containing hydroxy or O-metal groups containing halogen

Definitions

  • FIGURE 1 is a graphical representation showing the composition of products which are obtained in accordance with the process of the invention in terms of the respective proportions of reactants, i.e.', epichlorohydrin and high molecular weight alcohol present; and
  • the miXture of chloroglyceryl ethers obtained from reacting the alcohols resulting from the reduction of hydrogenated or unhydrogenated tallow, for example, with an amount of epichlorohydrin at least in excess of the molar equivalent of the alcohol can be substituted for the coconut alkyl chloroglyceryl ethers of the example with comparable results.
  • compositions of claim 1 wherein the cation of the water-soluble sulfonic acid salt radical is selected from the group Consisting of sodium, potassium, animonium, calcium, magnesium, and alkylol-substituted ammonium in which the alltylol contains a whole number of carbon atoms from 2 to 3.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US659038A 1957-05-14 1957-05-14 Alkyl glyceryl ether sulfonate mixtures and processes for preparing the same Expired - Lifetime US3024273A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DENDAT1249434D DE1249434B (de) 1957-05-14 Waschmittel
FR1139251D FR1139251A (fr) 1957-05-14 1955-06-03 Compositions détersives et leur procédé de fabrication
BE538938A BE538938A (fr) 1957-05-14 1955-06-13
NL198118A NL101525C (fr) 1957-05-14 1955-06-16
US659038A US3024273A (en) 1957-05-14 1957-05-14 Alkyl glyceryl ether sulfonate mixtures and processes for preparing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US659038A US3024273A (en) 1957-05-14 1957-05-14 Alkyl glyceryl ether sulfonate mixtures and processes for preparing the same

Publications (1)

Publication Number Publication Date
US3024273A true US3024273A (en) 1962-03-06

Family

ID=24643775

Family Applications (1)

Application Number Title Priority Date Filing Date
US659038A Expired - Lifetime US3024273A (en) 1957-05-14 1957-05-14 Alkyl glyceryl ether sulfonate mixtures and processes for preparing the same

Country Status (5)

Country Link
US (1) US3024273A (fr)
BE (1) BE538938A (fr)
DE (1) DE1249434B (fr)
FR (1) FR1139251A (fr)
NL (1) NL101525C (fr)

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3243455A (en) * 1962-06-29 1966-03-29 Wyandotte Chemicals Corp Polyether hydroxysulfonate surface active agents
US3856534A (en) * 1970-09-03 1974-12-24 Nasa Anti-fog composition
US4217296A (en) * 1978-07-24 1980-08-12 Fmc Corporation Alkyl glyceryl ether sulfate salts and process for their preparation
US4269786A (en) * 1978-11-13 1981-05-26 Fmc Corporation Alkyl glyceryl ether sulfate salts and process for their preparation
DE3016544A1 (de) * 1980-04-29 1981-11-05 Lanko, Inc., Philadelphia, Pa. Emulsionen
FR2514780A1 (fr) * 1981-10-16 1983-04-22 Colgate Palmolive Co Detergent liquide ayant une grande aptitude a l'elimination des graisses et son procede de preparation
WO1991009923A1 (fr) * 1989-12-29 1991-07-11 The Procter & Gamble Company Agent tensio-actif tres doux comprenant un compose stimulant la mousse
US5108640A (en) * 1990-02-28 1992-04-28 The Procter & Gamble Company Personal cleansing synbar with improved rinsing
US5310508A (en) * 1992-07-15 1994-05-10 Colgate-Palmolive Company Mild personal cleansing compositions containing sodium alcohol ethoxy glyceryl sulfonate
US5322643A (en) * 1989-12-29 1994-06-21 The Procter & Gamble Company Ultra mild toilet bar and other personal cleansers
US5436366A (en) * 1993-10-15 1995-07-25 Colgate-Palmolive Company Process and composition
EP0717032A3 (fr) * 1994-10-18 1996-06-26 Colgate Palmolive Co
US5567359A (en) * 1989-12-29 1996-10-22 The Proctor & Gamble Company Ultra mild surfactant with good lather
US5672740A (en) * 1993-10-15 1997-09-30 Colgate-Palmolive Company Alkoxylated alkyl glyceryl ether sulfonates and method of preparing
WO1999001535A1 (fr) * 1997-07-02 1999-01-14 The Procter & Gamble Company Compositions de pain renfermant un tensioactif a base de sulfonate d'alkylglycerylether
EP0851783A4 (fr) * 1996-05-31 2004-01-02 Akzo Nobel Surface Chem Nouveaux sulfonates aromatiques et aliphatiques, leurs proprietes et leurs applications
WO2006041740A1 (fr) * 2004-10-08 2006-04-20 The Procter & Gamble Company Melange de tensioactifs oligomeres constitues de sulfonate et/ou de sulfate d'alkylglyceryle, et composition detergente comprenant ce melange
US20100041814A1 (en) * 2008-08-15 2010-02-18 Cvc Specialty Chemicals, Inc Methods for preparing toughened epoxy polymer composite systems
US20110015111A1 (en) * 2009-07-16 2011-01-20 Wanglin Yu Sulfonate surfactants and methods of preparation and use
US20110105787A1 (en) * 2009-11-02 2011-05-05 Neigel Dennis V Process for Producing Alkyl Glyceryl Sulfonates
EP2743337A1 (fr) * 2012-12-14 2014-06-18 Cognis IP Management GmbH Dérivés de polyglycérol tensioactifs
WO2020016025A1 (fr) 2018-07-09 2020-01-23 Rhodia Operations Formulations à base de cétones internes sulfonées pour la récupération assistée du pétrole
WO2021023633A1 (fr) 2019-08-05 2021-02-11 Rhodia Operations Formulations moussantes pour la recuperation assistee du petrole
US11708317B2 (en) 2017-06-16 2023-07-25 Rhodia Operations Process for the catalytic decarboxylative cross-ketonization of aryl and aliphatic carboxylic acid

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2469401A1 (fr) * 1979-11-13 1981-05-22 Rhone Poulenc Ind Procede de preparation de difluoromethane sulfonates alcalins

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2010726A (en) * 1935-08-06 B-o-cha-choh-cha-cl
US2094489A (en) * 1937-09-28 Wetting-out
US2260753A (en) * 1939-10-23 1941-10-28 Shell Dev Process for the production of derivatives of epihalohydrins
US2706207A (en) * 1955-04-12 Process for the production of

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2010726A (en) * 1935-08-06 B-o-cha-choh-cha-cl
US2094489A (en) * 1937-09-28 Wetting-out
US2706207A (en) * 1955-04-12 Process for the production of
US2260753A (en) * 1939-10-23 1941-10-28 Shell Dev Process for the production of derivatives of epihalohydrins

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3243455A (en) * 1962-06-29 1966-03-29 Wyandotte Chemicals Corp Polyether hydroxysulfonate surface active agents
US3856534A (en) * 1970-09-03 1974-12-24 Nasa Anti-fog composition
US4217296A (en) * 1978-07-24 1980-08-12 Fmc Corporation Alkyl glyceryl ether sulfate salts and process for their preparation
EP0011311A3 (en) * 1978-07-24 1981-02-11 Fmc Corporation Alkyl glyceryl ether sulfate salts, process for their preparation and composition of matter containing them
US4269786A (en) * 1978-11-13 1981-05-26 Fmc Corporation Alkyl glyceryl ether sulfate salts and process for their preparation
DE3016544A1 (de) * 1980-04-29 1981-11-05 Lanko, Inc., Philadelphia, Pa. Emulsionen
FR2514780A1 (fr) * 1981-10-16 1983-04-22 Colgate Palmolive Co Detergent liquide ayant une grande aptitude a l'elimination des graisses et son procede de preparation
US5084212A (en) * 1989-12-29 1992-01-28 The Procter & Gamble Company Ultra mild surfactant with foam enhancer
US5322643A (en) * 1989-12-29 1994-06-21 The Procter & Gamble Company Ultra mild toilet bar and other personal cleansers
WO1991009923A1 (fr) * 1989-12-29 1991-07-11 The Procter & Gamble Company Agent tensio-actif tres doux comprenant un compose stimulant la mousse
US5567359A (en) * 1989-12-29 1996-10-22 The Proctor & Gamble Company Ultra mild surfactant with good lather
US5108640A (en) * 1990-02-28 1992-04-28 The Procter & Gamble Company Personal cleansing synbar with improved rinsing
US5310508A (en) * 1992-07-15 1994-05-10 Colgate-Palmolive Company Mild personal cleansing compositions containing sodium alcohol ethoxy glyceryl sulfonate
US5672740A (en) * 1993-10-15 1997-09-30 Colgate-Palmolive Company Alkoxylated alkyl glyceryl ether sulfonates and method of preparing
US5436366A (en) * 1993-10-15 1995-07-25 Colgate-Palmolive Company Process and composition
US5516461A (en) * 1993-10-15 1996-05-14 Colgate-Palmolive Company Process and composition
EP0717032A3 (fr) * 1994-10-18 1996-06-26 Colgate Palmolive Co
US5621139A (en) * 1994-10-18 1997-04-15 Colgate-Palmolive Company Process for preparing alkoxylated alkyl glyceryl ether sulfonates
EP0851783A4 (fr) * 1996-05-31 2004-01-02 Akzo Nobel Surface Chem Nouveaux sulfonates aromatiques et aliphatiques, leurs proprietes et leurs applications
WO1999001535A1 (fr) * 1997-07-02 1999-01-14 The Procter & Gamble Company Compositions de pain renfermant un tensioactif a base de sulfonate d'alkylglycerylether
WO2006041740A1 (fr) * 2004-10-08 2006-04-20 The Procter & Gamble Company Melange de tensioactifs oligomeres constitues de sulfonate et/ou de sulfate d'alkylglyceryle, et composition detergente comprenant ce melange
US20100041814A1 (en) * 2008-08-15 2010-02-18 Cvc Specialty Chemicals, Inc Methods for preparing toughened epoxy polymer composite systems
US8304377B2 (en) 2009-07-16 2012-11-06 Dow Global Technologies Llc Sulfonate surfactants and methods of preparation and use
US20110015111A1 (en) * 2009-07-16 2011-01-20 Wanglin Yu Sulfonate surfactants and methods of preparation and use
US20110105787A1 (en) * 2009-11-02 2011-05-05 Neigel Dennis V Process for Producing Alkyl Glyceryl Sulfonates
US8053596B2 (en) 2009-11-02 2011-11-08 Third Stream Bioscience, Inc. Process for producing alxyl glyceryl sulfonates
EP2743337A1 (fr) * 2012-12-14 2014-06-18 Cognis IP Management GmbH Dérivés de polyglycérol tensioactifs
US11708317B2 (en) 2017-06-16 2023-07-25 Rhodia Operations Process for the catalytic decarboxylative cross-ketonization of aryl and aliphatic carboxylic acid
WO2020016025A1 (fr) 2018-07-09 2020-01-23 Rhodia Operations Formulations à base de cétones internes sulfonées pour la récupération assistée du pétrole
US12006470B2 (en) 2018-07-09 2024-06-11 Rhodia Operations Sulphonated internal ketone-based formulations for assisted recovery of oil
WO2021023633A1 (fr) 2019-08-05 2021-02-11 Rhodia Operations Formulations moussantes pour la recuperation assistee du petrole

Also Published As

Publication number Publication date
FR1139251A (fr) 1957-06-27
NL198118B (fr) 1962-01-15
BE538938A (fr) 1955-06-30
DE1249434B (de) 1968-03-28
NL101525C (fr) 1962-06-15

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