US3066383A - Finish for staple glass fibers and yarns manufactured thereof - Google Patents

Finish for staple glass fibers and yarns manufactured thereof Download PDF

Info

Publication number: US3066383A
Authority: US; United States
Prior art keywords: weight; glass fibers; percent; fibers; yarn
Prior art date: 1957-02-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

US640094A

Other languages

English (en)

Inventor

Marzocchi Alfred

Gerald E Rammel

Clarence W Charon

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Owens Corning

Original Assignee

Owens Corning Fiberglas Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1957-02-14

Filing date

1957-02-14

Publication date

1962-12-04

1957-02-14 Application filed by Owens Corning Fiberglas Corp filed Critical Owens Corning Fiberglas Corp

1957-02-14 Priority to US640094A priority Critical patent/US3066383A/en

1958-02-06 Priority to DEO5996A priority patent/DE1127321B/de

1958-02-07 Priority to FR1191203D priority patent/FR1191203A/fr

1958-02-10 Priority to CH358063D priority patent/CH358063A/de

1958-02-13 Priority to GB4789/58A priority patent/GB880909A/en

1962-12-04 Application granted granted Critical

1962-12-04 Publication of US3066383A publication Critical patent/US3066383A/en

1979-12-04 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000003365 glass fiber Substances 0.000 title claims description 44
239000003921 oil Substances 0.000 claims description 26
229920000180 alkyd Polymers 0.000 claims description 16
239000003995 emulsifying agent Substances 0.000 claims description 12
239000000463 material Substances 0.000 claims description 11
239000011248 coating agent Substances 0.000 claims description 4
238000000576 coating method Methods 0.000 claims description 4
239000003795 chemical substances by application Substances 0.000 claims 1
239000000203 mixture Substances 0.000 description 31
235000019198 oils Nutrition 0.000 description 25
239000000835 fiber Substances 0.000 description 14
230000015572 biosynthetic process Effects 0.000 description 10
239000004744 fabric Substances 0.000 description 10
239000002216 antistatic agent Substances 0.000 description 9
-1 fatty acid esters Chemical class 0.000 description 8
239000003906 humectant Substances 0.000 description 8
238000005299 abrasion Methods 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
239000002253 acid Substances 0.000 description 5
229920005989 resin Polymers 0.000 description 5
239000011347 resin Substances 0.000 description 5
235000014113 dietary fatty acids Nutrition 0.000 description 4
239000000194 fatty acid Substances 0.000 description 4
229930195729 fatty acid Natural products 0.000 description 4
238000009472 formulation Methods 0.000 description 4
238000000034 method Methods 0.000 description 4
150000005846 sugar alcohols Polymers 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
150000001408 amides Chemical class 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
230000014759 maintenance of location Effects 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
229920001225 polyester resin Polymers 0.000 description 3
239000004645 polyester resin Substances 0.000 description 3
239000012260 resinous material Substances 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
239000004753 textile Substances 0.000 description 3
ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
125000003710 aryl alkyl group Chemical group 0.000 description 2
238000006482 condensation reaction Methods 0.000 description 2
230000006378 damage Effects 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
239000003822 epoxy resin Substances 0.000 description 2
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
239000000944 linseed oil Substances 0.000 description 2
235000021388 linseed oil Nutrition 0.000 description 2
229920000647 polyepoxide Polymers 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
238000000926 separation method Methods 0.000 description 2
238000004513 sizing Methods 0.000 description 2
239000001593 sorbitan monooleate Substances 0.000 description 2
235000011069 sorbitan monooleate Nutrition 0.000 description 2
229940035049 sorbitan monooleate Drugs 0.000 description 2
239000001570 sorbitan monopalmitate Substances 0.000 description 2
235000011071 sorbitan monopalmitate Nutrition 0.000 description 2
229940031953 sorbitan monopalmitate Drugs 0.000 description 2
239000003549 soybean oil Substances 0.000 description 2
235000012424 soybean oil Nutrition 0.000 description 2
239000000126 substance Substances 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 2
IYLGZMTXKJYONK-ACLXAEORSA-N (12s,15r)-15-hydroxy-11,16-dioxo-15,20-dihydrosenecionan-12-yl acetate Chemical compound O1C(=O)[C@](CC)(O)C[C@@H](C)[C@](C)(OC(C)=O)C(=O)OCC2=CCN3[C@H]2[C@H]1CC3 IYLGZMTXKJYONK-ACLXAEORSA-N 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
244000068988 Glycine max Species 0.000 description 1
235000010469 Glycine max Nutrition 0.000 description 1
240000006240 Linum usitatissimum Species 0.000 description 1
235000004431 Linum usitatissimum Nutrition 0.000 description 1
235000004347 Perilla Nutrition 0.000 description 1
244000124853 Perilla frutescens Species 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
241000718541 Tetragastris balsamifera Species 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
238000009986 fabric formation Methods 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
235000004426 flaxseed Nutrition 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002483 hydrogen compounds Chemical class 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
238000012643 polycondensation polymerization Methods 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
150000007519 polyprotic acids Polymers 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
IYLGZMTXKJYONK-UHFFFAOYSA-N ruwenine Natural products O1C(=O)C(CC)(O)CC(C)C(C)(OC(C)=O)C(=O)OCC2=CCN3C2C1CC3 IYLGZMTXKJYONK-UHFFFAOYSA-N 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000001587 sorbitan monostearate Substances 0.000 description 1
235000011076 sorbitan monostearate Nutrition 0.000 description 1
229940035048 sorbitan monostearate Drugs 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000002383 tung oil Substances 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/323—Polyesters, e.g. alkyd resins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/08—Polyesters modified with higher fatty oils or their acids, or with resins or resin acids
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
- D06M15/51—Unsaturated polymerisable polyesters
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S260/00—Chemistry of carbon compounds
- Y10S260/15—Antistatic agents not otherwise provided for
- Y10S260/19—Non-high polymeric antistatic agents/n
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2904—Staple length fiber
- Y10T428/2907—Staple length fiber with coating or impregnation
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament

Definitions

composition applied to the glass fiber surfaces in yarn formation impart sufiicient bonding between the fibers to provide a desired mass integrity for holding the fibers together in the warn but without conflicting with the ability to draft the endless sliver in yarn formation.
the cure is so slow as to introduce further complications into the processing steps. Still further, the bodied oils have been found to be somewhat insufi icient from the standpoint of strength and abrasion resistance in the yarns that are formed.
the desired improvement in a treating composition embodying the characteristics of a size and of a finish for use as a single treating composition for staple glass fibers in the formation of twisted and plied yarns and fabrics formed thereof can be accomplished by the formulation of a composition which contains a curable, oil modified resinous material in an intermediate stage of polymeric growth.
a resin forming material in a bodied and intermediate stage of polymeric growth it is preferred to make use of an oil modified alkyd resin such as is formed by condensation reaction of a polybasic acid with a polyhydric alcohol but it is preferred to make use of the condensation polymerization product of a dibasic acid With a dihydric alcohol.
the dibasic acid may be selected of pythalic acid sebacic acid, maleic acid or fumaric acid
the dihydric alcohol can be selected of glycol, ethylene glycol, diethylene glycol, propylene glycol and the like.
the composition of the alkyd or polyester resin is formed of saturated dibasic acids and dihydric alcohols, cure will occur chiefly through the oil used to modify the alkyd or polyester resin.
an oil containing unsaturated ethylenic groups as represented by linseed oil, soybean oil, China-wood oil, isoline, perilla oil, oiticia oil, and the like.
oil modified alkyd or polyester resins which can be employed in the practice of this invention are such materials as are marketed by Archer-Daniels Midland Company under the tradename Aroplaz 1400 or Aroplaz 1271 which are glycol-phthalic acid or anhydride resins modified with soybean, linseed or cocoanut oil.
Epoxy resins, prefer- 53 ably similarly modified with oils and plasticizers, may be used.
the resinous component is not soluble in water and is therefore incorporated preferably as an emulsified phase in water in formulation of the treating composition. It will be understood, however, that solvent solutions of the oil modified resinous material may be employed. For application onto the staple glass fibers to provide the combination of a size and finish, it is desirable to formulate the treating composition with an amount of resin ranging from 4-25 percent by weight.
Use can be made of various surface active agents for emulsification and for producing a stable emulsion or dispersion of the oil modified resinous material in an aqueous system.
surface active agents as aryl alkyl polyether alcohols, fatty acid esters of polyhydric alcohols, or other comparable emulsifying agents, preferably of the nonionic type.
the surface active agent or emulsifying agent may be employed in a concentration within the range of 0.1-1.0 percent by weight.
the treating composition can be further modified by the addition of a humectant as represented by sorbitan mono-oleate, sorbitan mono-palmitate, sorbitan monostearate, or the polyoxyethylene derivatives thereof, as well as other equivalent humectants.
a humectant as represented by sorbitan mono-oleate, sorbitan mono-palmitate, sorbitan monostearate, or the polyoxyethylene derivatives thereof, as well as other equivalent humectants.
the humectant may be present in the treating composition in an amount within the range of 0.1-2.0 percent by weight.
Humectants including ethylene oxide condensates such as carbowaxes, combinations of ethylene and propylene oxide condensates such as the Ucon oils, and ethylene oxide condensates of amides, amines and other active hydrogen compounds are used.
an anti-static agent as represented by cationic amine or amide compounds preferably in the form of fatty acid amines or amides, as represented by the material marketed by Nopco Chemical Company under the tradename Konrite.
the anti-static agents when employed in the treating composition, can be present in an amount within the range of 0.1-2.0 percent by weight.
Anti-static agents which are used also include ethylene oxide condensates and modified urea and epoxy resins containing quaternary ammonium groups.
Example 1 10.0 percent by weight of a soybean oil modified phthalic acid-glycol resin 1.0 percent by weight of a cationic amide anti-static agent (Konrite A anti-static oil-marketed by Nopco Chemical Company) 0.5 percent by weight of an emulsifying agent (Triton 0.5 percent by weight sorbitan mono-oleate 88.0 percent by weight Water
Example 2 20.0 percent by Weight oil modified alkyd resin (Aroplaz 1400-Archer-Daniels Midland Company) 3.0 percent by Weight fatty acid ester of polyhydric alcohol emulsifying agent 77.0 percent by weight water
Example 3 5.0 percent by weight oil modified alkyd resin 0.5 percent by weight anionic emulsifying agent 3.0 percent by weight anti-static agent 91.5 percent by weight water
Example 4 10.0 percent by weight oil modified alkyd resin (Aroplaz l27lArcher-Daniels Midland Company) 1.0 percent by weight anti-static oil (Konrite A) 0.5 percent by weight aryl alkyl polyhydr
the drawn slivers should be air dried prior to twisting or plying to form yarns.
the resinous component of the size composition should be advanced to a cured stage by heating as to a temperature within the range of 250-400 F. for a time sufficient to advance the oil modified resin to the cured stage. Lower temperatures can be used and when a catalyst is employed, air curing may be utilized.
a yarn comprising staple glass fibers and a coating on the glass fiber surfaces embodying a resinous filmforming component consisting essentially of an unsaturated oil modified alkyd resin and containing an emulsifying agent and in which the materials are present in the ratio of 4-25 parts by weight of the alkyd resin to 0.1 to 1.0 part by weight of the emulsifying agent.
a glass fiber yarn comprising staple glass fibers and a size composition on the glass fiber surfaces comprising an aqueous system in which the resinous film-forming component consists essentially of an unsaturated oil modified alkyd resin present in an amount Within the range of 4-25 percent by weight of the size composition and which, contains an emulsifying agent present in an amount within the range of 0.1 to 1.0 percent by weight of the size composition, and an anti-static agent present in an amount within the range of 0.1 to 1.0 percent by weight.
a yarn comprising staple glass fibers and a coating on the glass fiber surfaces the resinous component of which consists essentially of an oil modifying alkyd resin and which contains an emulsifying agent, an anti-static agent and a humectant in which the materials are present in the ratio of 4-25 parts by weight of the alkyd resin, 0.1 to 1.0 part by weight of the emulsifying agent, 0.1 to 1.0 part by weight of the anti-static agent and 0.1 to 1.0 of the humectant.
a glass fiber yarn comprising staple glass fibers and a size composition on the glass fiber surfaces comprising an aqueous system in which the resinous filmforrning component consists essentially of an unsaturated oil modified alkyd resin present in an amount within the range of 4-25 percent by weight of the size composition and which contains an emulsifying agent present in an amount within the range of 0.1 to 1.0 percent by Weight of the size composition and a humectant present in an amount within the range of 0.1 to 1.0 percent by weight of the size composition.

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Life Sciences & Earth Sciences (AREA)
General Chemical & Material Sciences (AREA)
Geochemistry & Mineralogy (AREA)
Materials Engineering (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Surface Treatment Of Glass Fibres Or Filaments (AREA)

US640094A 1957-02-14 1957-02-14 Finish for staple glass fibers and yarns manufactured thereof Expired - Lifetime US3066383A (en)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
US640094A US3066383A (en)	1957-02-14	1957-02-14	Finish for staple glass fibers and yarns manufactured thereof
DEO5996A DE1127321B (de)	1957-02-14	1958-02-06	Verfahren zum Ausruesten von Textilien unter Verwendung von Polyesterharzen
FR1191203D FR1191203A (fr)	1957-02-14	1958-02-07	Fini pour fibres de verre discontinues et fils fabriqués à partir de ces dernières
CH358063D CH358063A (de)	1957-02-14	1958-02-10	Haltbares Appreturmittel zum Überziehen von Glasfasern
GB4789/58A GB880909A (en)	1957-02-14	1958-02-13	An improved finish for application to glass fibres and yarns formed thereof

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US640094A US3066383A (en)	1957-02-14	1957-02-14	Finish for staple glass fibers and yarns manufactured thereof

Publications (1)

Publication Number	Publication Date
US3066383A true US3066383A (en)	1962-12-04

Family

ID=24566815

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
US640094A Expired - Lifetime US3066383A (en)	1957-02-14	1957-02-14	Finish for staple glass fibers and yarns manufactured thereof

Country Status (5)

Country	Link
US (1)	US3066383A (de)
CH (1)	CH358063A (de)
DE (1)	DE1127321B (de)
FR (1)	FR1191203A (de)
GB (1)	GB880909A (de)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3249412A (en) *	1963-03-21	1966-05-03	Pittsburgh Plate Glass Co	Method of sizing glass fibers and epoxy resin emulsion therefor
US3348368A (en) *	1964-07-23	1967-10-24	Leesona Corp	Method and apparatus for processing glass yarn
US3395527A (en) *	1964-06-23	1968-08-06	Scandura Inc	Yarn and fabric made therefrom
US3446003A (en) *	1967-01-03	1969-05-27	Ppg Industries Inc	Glass fiber cord construction
US3771305A (en) *	1972-06-15	1973-11-13	Johns Manville	Fiber glass groove packing
US4086203A (en) *	1971-11-12	1978-04-25	Imperial Chemical Industries Limited	Fibers sized with polyester and polyurethane precursors
US5203900A (en) *	1989-12-06	1993-04-20	Isover Saint-Gobain. "Les Miroirs"	Method of producing discontinuous coated glass fibers
CN110927860A (zh) *	2018-09-19	2020-03-27	普睿司曼股份公司	具有交联二次涂层的光纤
CN111655646A (zh) *	2018-01-19	2020-09-11	普睿司曼股份公司	具有交联聚酯涂层的光纤
US11396476B2 (en)	2016-07-22	2022-07-26	Prysmian S.P.A.	Optical fibre coated with a polyester coating

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2655328B1 (de) *	1989-12-06	1993-07-16	Saint Gobain Isover
US5998029A (en) *	1997-06-30	1999-12-07	Owens Corning Fiberglas Technology, Inc.	Nonaqueous sizing system for glass fibers and injection moldable polymers
US6399198B1 (en)	1998-12-23	2002-06-04	Owens Corning Fiberglas Technology, Inc.	Nonaqueous sizing system for glass fibers and injection moldable polymers
WO2018046984A1 (en) *	2016-09-09	2018-03-15	Prysmian S.P.A.	Optical fibre coated with a polyester coating

Citations (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2168286A (en) *	1936-10-10	1939-08-01	Kendall & Co	Wettable material
US2245824A (en) *	1940-08-03	1941-06-17	Eraser Company Inc	Method of manufacturing glass rope
US2289222A (en) *	1941-02-14	1942-07-07	Du Pont	Yarn preparation
US2392805A (en) *	1943-10-11	1946-01-15	Owens Corning Fiberglass Corp	Glass fiber strand
US2504845A (en) *	1947-05-21	1950-04-18	Westinghouse Electric Corp	Method of making insulated electrical conductors
US2694021A (en) *	1951-03-30	1954-11-09	Atlas Powder Co	Textile bearing a starch size
US2712509A (en) *	1951-08-17	1955-07-05	Owens Corning Fiberglass Corp	Glass fiber filament strand and method of manufacturing glass fabric
US2780909A (en) *	1953-03-24	1957-02-12	Owens Corning Fiberglass Corp	Method of forming yarns from staple glass fibers
US2795926A (en) *	1954-02-23	1957-06-18	Owens Corning Fiberglass Corp	Method for producing a continuous roving
US2961821A (en) *	1956-12-07	1960-11-29	Owens Corning Fiberglass Corp	Apparatus for manufacturing bonded fibrous glass slivers

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2533270A (en) *	1946-11-26	1950-12-12	Interchem Corp	Alkyd resins

1957
- 1957-02-14 US US640094A patent/US3066383A/en not_active Expired - Lifetime
1958
- 1958-02-06 DE DEO5996A patent/DE1127321B/de active Pending
- 1958-02-07 FR FR1191203D patent/FR1191203A/fr not_active Expired
- 1958-02-10 CH CH358063D patent/CH358063A/de unknown
- 1958-02-13 GB GB4789/58A patent/GB880909A/en not_active Expired

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2168286A (en) *	1936-10-10	1939-08-01	Kendall & Co	Wettable material
US2245824A (en) *	1940-08-03	1941-06-17	Eraser Company Inc	Method of manufacturing glass rope
US2289222A (en) *	1941-02-14	1942-07-07	Du Pont	Yarn preparation
US2392805A (en) *	1943-10-11	1946-01-15	Owens Corning Fiberglass Corp	Glass fiber strand
US2504845A (en) *	1947-05-21	1950-04-18	Westinghouse Electric Corp	Method of making insulated electrical conductors
US2694021A (en) *	1951-03-30	1954-11-09	Atlas Powder Co	Textile bearing a starch size
US2712509A (en) *	1951-08-17	1955-07-05	Owens Corning Fiberglass Corp	Glass fiber filament strand and method of manufacturing glass fabric
US2780909A (en) *	1953-03-24	1957-02-12	Owens Corning Fiberglass Corp	Method of forming yarns from staple glass fibers
US2795926A (en) *	1954-02-23	1957-06-18	Owens Corning Fiberglass Corp	Method for producing a continuous roving
US2961821A (en) *	1956-12-07	1960-11-29	Owens Corning Fiberglass Corp	Apparatus for manufacturing bonded fibrous glass slivers

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3249412A (en) *	1963-03-21	1966-05-03	Pittsburgh Plate Glass Co	Method of sizing glass fibers and epoxy resin emulsion therefor
US3395527A (en) *	1964-06-23	1968-08-06	Scandura Inc	Yarn and fabric made therefrom
US3348368A (en) *	1964-07-23	1967-10-24	Leesona Corp	Method and apparatus for processing glass yarn
US3446003A (en) *	1967-01-03	1969-05-27	Ppg Industries Inc	Glass fiber cord construction
US4086203A (en) *	1971-11-12	1978-04-25	Imperial Chemical Industries Limited	Fibers sized with polyester and polyurethane precursors
US3771305A (en) *	1972-06-15	1973-11-13	Johns Manville	Fiber glass groove packing
US5203900A (en) *	1989-12-06	1993-04-20	Isover Saint-Gobain. "Les Miroirs"	Method of producing discontinuous coated glass fibers
US11396476B2 (en)	2016-07-22	2022-07-26	Prysmian S.P.A.	Optical fibre coated with a polyester coating
CN111655646A (zh) *	2018-01-19	2020-09-11	普睿司曼股份公司	具有交联聚酯涂层的光纤
CN111655646B (zh) *	2018-01-19	2022-08-12	普睿司曼股份公司	具有交联聚酯涂层的光纤
US11834367B2 (en)	2018-01-19	2023-12-05	Prysmian S.P.A.	Optical fibre having a crosslinked polyester coating
CN110927860A (zh) *	2018-09-19	2020-03-27	普睿司曼股份公司	具有交联二次涂层的光纤
US10775556B2 (en)	2018-09-19	2020-09-15	PEYSMIAN S.p.A.	Optical fibre having a crosslinked secondary coating
CN110927860B (zh) *	2018-09-19	2023-03-31	普睿司曼股份公司	具有交联二次涂层的光纤

Also Published As

Publication number	Publication date
DE1127321B (de)	1962-04-12
GB880909A (en)	1961-10-25
FR1191203A (fr)	1959-10-19
CH358063A (de)	1961-11-15

Publication	Publication Date	Title
US3066383A (en)	1962-12-04	Finish for staple glass fibers and yarns manufactured thereof
US2801189A (en)	1957-07-30	Glass fiber article and process of plural coated fiber and process of preparation
US3655420A (en)	1972-04-11	Synthetic organic textile fiber with improved, durable, soft, lubricated feel
US2842462A (en)	1958-07-08	Antistatic synthetic textile material
US2838455A (en)	1958-06-10	Textiles and conditioning compositions therefor
US2826514A (en)	1958-03-11	Treatment of textile materials and composition therefor
US3817898A (en)	1974-06-18	Sizing composition and glass fibers treated therewith
US2938812A (en)	1960-05-31	Treated glass fibers and compositions for use in same
US3488217A (en)	1970-01-06	Process for imparting a soft feel to textile fiber and the resulting fiber
US3207623A (en)	1965-09-21	Sized glass fiber
US2846337A (en)	1958-08-05	Magnesium chloride catalyst for modified urea resins
EP0002950B1 (de)	1981-09-09	Textilmaterialien mit dauerhaften Schmutzlöse- und Feuchtigkeitstransporteigenschaften und Verfahren zu deren Herstellung
US3888645A (en)	1975-06-10	Treatment of glass fibers
US3679507A (en)	1972-07-25	Method of producing a coated glass fiber strand
US3694257A (en)	1972-09-26	Polyester compositions and their use as textile assistants
US3341356A (en)	1967-09-12	Treated glass fibers and methods for treating glass fibers to improve the bonding relation with epoxy resins
US3498821A (en)	1970-03-03	Yarn sizing
US3040413A (en)	1962-06-26	Glass fiber yarns and compositions for use in the manufacture of same
US3329758A (en)	1967-07-04	Treating polyester filament with a surface active compound to permit lagging before drawing
US3355314A (en)	1967-11-28	Coating method for glass fabric and product thereof
US2295699A (en)	1942-09-15	Process of finishing textiles
US2671744A (en)	1954-03-09	Sized strands and method of making same
US3061554A (en)	1962-10-30	Water-dispersible emulsions of pinane hydroperoxide
DE1191330B (de)	1965-04-22	Verfahren zur Herstellung von UEberzuegen auf Glasfasern und Glasfasergeweben
US2436978A (en)	1948-03-02	Reinforcing cord and process of manufacture