US3085949A - Surface treatment of titanium or titanium base alloy - Google Patents

Surface treatment of titanium or titanium base alloy Download PDF

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Publication number
US3085949A
US3085949A US18884A US1888460A US3085949A US 3085949 A US3085949 A US 3085949A US 18884 A US18884 A US 18884A US 1888460 A US1888460 A US 1888460A US 3085949 A US3085949 A US 3085949A
Authority
US
United States
Prior art keywords
titanium
base alloy
surface treatment
articles
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US18884A
Other languages
English (en)
Inventor
Leech Harry Rowland
Riding Frank
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of US3085949A publication Critical patent/US3085949A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • C25D5/38Pretreatment of metallic surfaces to be electroplated of refractory metals or nickel
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents

Definitions

  • Said temperature may be 90-100 C. and the article may be pretreated with a standard pickling and de-scaling bath before treatment with the hydrochloric acid.
  • the method of surface treatment of titanium or titanium base alloy articles comprises treatment of the surface of the said articles with hydrogen at elevated temperatures, preferably at a temperature between 600 and 1000 0., followed by deposition of a coating of a metal thereon, for example platinum, rhodium or iridium or an alloy of two or more of these metals.
  • a metal for example platinum, rhodium or iridium or an alloy of two or more of these metals.
  • a suitable plating procedure comprises plating at a current density of about 0.8 amp./ sq. dm. from an aqueous solution of sodium hexahydroxy platinate containing 0.5 to 1% sodium hydroxide.
  • the process of the present invention permits surfaces of titanium or titanium base alloy articles to be conditioned quickly, without loss of titanium, and uniformly even in the presence of stresses and welds.
  • a method of surface treatment of an article selected from the group consisting of titanium and titanium base alloy articles which comprises treating the surface of the said articles with hydrogen at elevated temperatures and then depositing a coating of a metal thereon.
  • a method as claimed in claim 1 wherein the aforesaid metal is a metal selected from the group consisting of platinum, rhodium and iridium and alloys of at least two of these metals.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Chemically Coating (AREA)
US18884A 1959-04-17 1960-03-31 Surface treatment of titanium or titanium base alloy Expired - Lifetime US3085949A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB13185/59A GB871941A (en) 1959-04-17 1959-04-17 Improvements in or relating to the surface treatment of titanium or titanium base alloy

Publications (1)

Publication Number Publication Date
US3085949A true US3085949A (en) 1963-04-16

Family

ID=10018389

Family Applications (1)

Application Number Title Priority Date Filing Date
US18884A Expired - Lifetime US3085949A (en) 1959-04-17 1960-03-31 Surface treatment of titanium or titanium base alloy

Country Status (5)

Country Link
US (1) US3085949A (de)
CH (1) CH390655A (de)
DE (1) DE1196470B (de)
ES (1) ES257297A1 (de)
GB (1) GB871941A (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8204477A (nl) * 1982-11-18 1984-06-18 Bekaert Sa Nv Katalysator, alsmede werkwijze ter vervaardiging van deze katalysator en haar toepassing.

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2714566A (en) * 1952-05-28 1955-08-02 Rca Corp Method of treating a germanium junction rectifier
US2719797A (en) * 1950-05-23 1955-10-04 Baker & Co Inc Platinizing tantalum
GB758013A (en) * 1953-10-03 1956-09-26 Ici Ltd Improvements in or relating to the surface treatment of titanium or titanium base alloys
US2772227A (en) * 1953-06-29 1956-11-27 Westinghouse Electric Corp Protection of molybdenum and tungsten at high temperatures
US2835630A (en) * 1952-05-06 1958-05-20 Huddle Roy Alfred Ulfketel Treatment of metals prior to electro-plating
US2841477A (en) * 1957-03-04 1958-07-01 Pacific Semiconductors Inc Photochemically activated gaseous etching method
US2885826A (en) * 1954-12-21 1959-05-12 British Thomson Houston Co Ltd Glass-to-metal seals
US2929766A (en) * 1958-06-13 1960-03-22 Melpar Inc Plating of iridium

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2790738A (en) * 1955-04-14 1957-04-30 Du Pont Titanium descaling bath and process

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2719797A (en) * 1950-05-23 1955-10-04 Baker & Co Inc Platinizing tantalum
US2835630A (en) * 1952-05-06 1958-05-20 Huddle Roy Alfred Ulfketel Treatment of metals prior to electro-plating
US2714566A (en) * 1952-05-28 1955-08-02 Rca Corp Method of treating a germanium junction rectifier
US2772227A (en) * 1953-06-29 1956-11-27 Westinghouse Electric Corp Protection of molybdenum and tungsten at high temperatures
GB758013A (en) * 1953-10-03 1956-09-26 Ici Ltd Improvements in or relating to the surface treatment of titanium or titanium base alloys
US2885826A (en) * 1954-12-21 1959-05-12 British Thomson Houston Co Ltd Glass-to-metal seals
US2841477A (en) * 1957-03-04 1958-07-01 Pacific Semiconductors Inc Photochemically activated gaseous etching method
US2929766A (en) * 1958-06-13 1960-03-22 Melpar Inc Plating of iridium

Also Published As

Publication number Publication date
ES257297A1 (es) 1960-07-01
CH390655A (de) 1965-04-15
GB871941A (en) 1961-07-05
DE1196470B (de) 1965-07-08

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