Classifications

• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C21/00—Alloys based on aluminium
  • C22C21/10—Alloys based on aluminium with zinc as the next major constituent

Definitions

• This invention is concerned with improving the strength and resistance to corrosion of certain copper-free aluminum base alloy products by means of a novel sequence of thermal treatments.
• the invention more particularly relates to the thermal treatment of products of aluminum base alloys containing zinc and magnesium within limited ranges and which are free from copper except as an impurity.
• Aluminum base alloys containing substantial amounts of zinc and magnesium have been known for many years and it has also been recognized that these alloys can develop high strength when solution heat treated and age hardened. However, it has been observed that not all respond to the same treatment in the same way, and that the resistance to corrosion can be adversely affected by improper thermal treatment. Another factor which exerts a strong influence upon the properties of this type of alloy is the presence of other alloying elements. Among the elements frequently used in combination with zinc and magnesium is copper, this addition commonly being used to efiect an increase in strength. While the copper is beneficial in that respect, it alters the behavior of the alloys in a corrosive environment and special practices are often needed to offset any adverse effect.
• a particular object is to increase both the strength and resistance to stress corrosion cracking of the foregoing alloy products above that normally obtained by age hardening at but one temperature.
• Another object is to provide a method of treating hot worked products of certain copper-free aluminnm-zinc-magnesium alloys whereby both their strength and resistance to stress corrosion cracking are improved.
• Our invention is predicated upon the discovery that a copper-free aluminum base alloy consisting essentially of 3.5 to 6% by weight of zinc, 0.75 to 4.3% by weight of magnesium, 0.05 to 0.75% by weight of manganese, 0.05 to 0.3% by weight of chromium and balance aluminum plus impurities, wherein the zinc content is not less than the magnesium content, responds in a peculiar manner to a sequence of thermal treatments to yield a product having an unusual combination of properties.
• the strength developed as a result of the treat ments is greater than that produced by the conventional commercial single step aging treatments and the product ice is substantimly immune to stress corrosion cracking.
• the treatments consist of a solution heat treatment, that may be followed by a hot Working operation, performed within the solution heat treating temperature range, a retarded cooling to room temperature, storage at room temperature for at least '72 hours and finally age hardening in two steps.
• a solution heat treatment that may be followed by a hot Working operation, performed within the solution heat treating temperature range, a retarded cooling to room temperature, storage at room temperature for at least '72 hours and finally age hardening in two steps.
• Resistance to stress corrosion cracking has also been found to be superior to that of wrought commercial aluminum-zinc-magnesium-copper alloys of the past which have received the conventional solution heat treatment and age hardening treatment as well as being superior to that of products of the copper-free alloys which have received but a single aging treatment.
• the alloys employed in making the wrought products must have zinc and magnesium within the following limits in order to develop the desired properties through thermal treatment. At least,3.5% and not over 6% zinc must be present whilethe magnesium content must fall within the range of 0.75 to 4.3% by weight and the magnesium content should not exceed that of zinc. If smaller amounts of zinc and magnesium are present, the products fail to develop the strength or resistance to corrosion while on the other hand larger amounts introduce problems in fabrication as Well as a deficiency in one or more of the desired properties.
• T he usual impurities, iron and silicon, are found in the alloy products, but the total should not exceed 0.6%. Copper may be present as an impurity but the amount should not exceed 0.10%. For this reason the alloys are referred to as being copper-free.
• the alloys can be melted, cast and worked according to customary practices for aluminum base alloys of this type.
• the body can be given a solution heat treat ment immediately prior to the hot working operation, the body shaped at a temperature within the solution heat treating temperature range and the hot worked product then cooled to room temperature at a slow rate as defined hereinbelow.
• the wrought product is given a solution heat treatment and at the conclusion of the treatment cooled to room temperature at a rate below the maximum indicated below.
• the alloy body should be heated to a temperature between 700 and 970 F., but not above the temperature of incipient fusion of any of the alloy phases, and held within that temperature range for at least a long enough time to permit substantially complete solution of the zinc and magnesium components.
• the length of time required to effect solution will depend upon the thickness of the body, the size in respect to the properties of the final product.
• thisstorage period the proper condition does not exist for I of the load being treated and of course the temperature of treatment.
• the period may be as short as 3 or 4 minutes whereas the treatment of an ingot or large wrought product requires a longer time, usually a soaking at the desired temperature of 1 to 8 hours, which means that the stock to be worked is' held within the furnace or other heating means for a longer time.
• longer periods are required to treat alloy bodies in the lower portion of the temperature range than in the upper portion of the range.
• a solution heat treating temperature range of 750 to 870 F.
• the hot body can be transferred to the metal working apparatus and then worked, it being necessary to maintain the temperature above 700? F.,the minimum solution heat treating temperature.
• the solution heat treated alloy body can be cooled to room temeper'ature and later reheated for working within the.
• the product is obieu' to at least 250 F. at a relatively slow rate, not e'riceeding an average of 200 F. per second. This rate is slow with'respect to that which exists during quenching in coldwater, for example, where the average rate is 2000" F. per second.
• the product can be progressively cooled as it issues from the die orrolls.
• the worked article is cooled upon removel from the forging apparatus. Faster rates than 200 F. per second have been found to have an adverse effect upon the resistance to' stress corrosion cracking.
• the cooling is not to be retarded beyond a practicable tirne in the plant, usually a matter of minutes when haudliiig individual or small groups of products, but longer times may be required to cool a large batch of products or products of heavy cross 'section.
• the cooling medium used can vary according to the mass of the products being cooled. For light sections quenched directly from the solution heat treating temperature, hot or boiling water may be appropriate but for heavy sections a more drastic cooling medium can be used because of the slow' transfer of heat from the product. Where the hot worked product is being cooled, an air blast or water spray may be sufficienttoprovide the retarded cooling rate. Rates as slow as 4 F. per second have been found to give satisfactory results.
• the product Following the cooling to room temperature the product should be held at that temperature for a period of at least 72' hoursbefore proceeding with the two 'step treatment of age hardening.
• the products can be stored for longer periods of time to accommodate plant schedules or shipment but no benefitis gained by extending the time Without response to the two step treatment and unless the period extends for at least 72 hours, the desired strength is not attained in the final product.
• Some spontaneous age hardening seems to occur during this period as judged by an increase in strength which takes place. In any event the increase in strength falls far short of that of the finally treated product. From a theoretical viewpoint it can be assumed that any age hardening which occurs establishes a pattern of precipitate and that this controls or guides subsequent precipitation. Whether such an explanation is correct or not, we have found, nevertheless, that the storage at room temperature is a prerequisite to the next and last age hardening treatment.
• the two step age hardening treatment comprises heating the stored product to a temperature between 200 and 250 F. and holding for a period of 4 to 24 hours.
• the choice of a particular temperature and period of time is determined by factors akin to those which affect solution heat treatment. The range of temperature and time are important for at lower temperatures and shorter periods of time the necessary age hardening does not occur. On the other hand, higher temperatures and longer periods of time induce over-aging, a'condition which must be avoided.
• the product may be cooled. to room temperature and reheated for the second step or the product can be immediately heated to the higher temperature. In any case the product is heated to a temperature between 280 and 320 F. and held within that range for a period of 8 to 24'hours. These temperatures and times are critical with respect to attaining a high strength and substantial immunity to stress corrosion cracking without over-aging.
• the final properties are influenced by the type of working operation to which the alloy has been subjected and the direction within the product in which the properties are determined whether longitudinal, i.e., parallel to direction of working, or transverse thereto.
• the minimum tensile strength which characterizes the final product is on the order of 42,000 psi. and the minimum yield strength is 35,000 p.s.1.
• the treatment of the alloy products described above results in an improved resistance to stress corrosion cracking as compared to that of conventionally treated wrought products.
• This property is usually determined in an accelerated corrosion test where specimens are stressed while being exposed to a corroding medium.
• two methods of stressing were used to determine susceptibility to stress corrosion, in one, the specimen was placed under a stress equivalent to 75% of its yield strength and in the other sheet specimens in the form of i strips were bent around a mandrel to produce a U-shaped test without failure they are considered to possess substantial immunity'to stress corrosion cracking.
• Another accelerated corrosion test which has been successfully used to determine susceptibility to stress corrosion is one wherein the specimen is placed under a stress equivalent to of the yield strength and immersed in anaqueous solution containing 300 g. NaCl per liter and, 20 g. Na CrO per liter, the water used for making up the solution being distilled water. Also immersed in the solution is a suitable cathode, for example, one of platinum screen wire. An external current is impressed on the system whereby the stressed specimen is made anodic under a. potential of 100 mv. If the specimen survives a 24 hour exposure without cracking it is considered to be highly resistant to stress corrosion crackmg.
• the mechanical properties of the cold water quenched plate were found to be 57,500 p.s.i. tensile strength, 45,000 p.s.i. yield strength and 6% elongation.
• the other plate had a tensile strength of 60,000 p.s.i., a yield strength of 49,500 p.s.i. and 7% elongation.
• Specimens from the two plates were subjected to the electrolytic accelerated stress corrosion test. Those from the cold water quenched plate failed in 12 /2 hours whereas those from the other plate had not failed after a 24 hour exposure, thus demonstrating the benefit of the slow cooling and two step aging treatment.
• the method of improving the strength and resistance to stress corrosion of wrought products composed of a copper-free aluminum base alloy consisting essentially of 3.5 to 6% zinc, 0.75 to 4.3% magnesium, 0.05 to 0.75% manganese, 0.05 to 0.30% chromium and balance aluminum plus impurities comprising subjecting a body of said alloy to a solution heat treatment within the temperature range of 700 to 970 F., but below the temperature of incipient fusion of any alloy phase, and holding the body within said temperature range for at least a long enough period to permit substantially complete solution of the zinc and magnesium, cooling the solution treated product to room temperature at a rate not exceeding 200 F.
• the alloy also contains at least one grain refining element of the group composed of 0.01 to 0.15% titanium and 0.0005 to 0.02% boron.
• the alloy also contains at least one grain refining element of the group composed of 0.01 to 0.15% titanium and 0.0005 to 0.02% boron.

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Mechanical Engineering (AREA)
• Metallurgy (AREA)
• Organic Chemistry (AREA)
• Conductive Materials (AREA)
• Forging (AREA)

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Cited By (7)

Citations (6)

• 1963
  • 1963-04-29 US US276156A patent/US3171760A/en not_active Expired - Lifetime
• 1964
  • 1964-04-27 CH CH546364A patent/CH454473A/de unknown

Patent Citations (6)

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