US3298954A - Metal working lubricant - Google Patents

Metal working lubricant Download PDF

Info

Publication number
US3298954A
US3298954A US436269A US43626965A US3298954A US 3298954 A US3298954 A US 3298954A US 436269 A US436269 A US 436269A US 43626965 A US43626965 A US 43626965A US 3298954 A US3298954 A US 3298954A
Authority
US
United States
Prior art keywords
lubricants
lubricant
polybutene
steel
ssu
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US436269A
Other languages
English (en)
Inventor
John S Brown
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Priority to US436269A priority Critical patent/US3298954A/en
Priority to SE3451/65A priority patent/SE324423B/xx
Priority to FR10231A priority patent/FR1426791A/fr
Priority to GB12466/65A priority patent/GB1109304A/en
Priority to BE661651A priority patent/BE661651A/xx
Priority to NL6503934A priority patent/NL6503934A/xx
Priority to DE19651594626 priority patent/DE1594626C3/de
Priority to LU48283A priority patent/LU48283A1/xx
Priority to AT286565A priority patent/AT282787B/de
Application granted granted Critical
Publication of US3298954A publication Critical patent/US3298954A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES, PROFILES OR LIKE SEMI-MANUFACTURED PRODUCTS OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C23/00—Extruding metal; Impact extrusion
    • B21C23/32—Lubrication of metal being extruded or of dies, or the like, e.g. physical state of lubricant, location where lubricant is applied
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES, PROFILES OR LIKE SEMI-MANUFACTURED PRODUCTS OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C9/00—Cooling, heating or lubricating drawing material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES, PROFILES OR LIKE SEMI-MANUFACTURED PRODUCTS OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C9/00—Cooling, heating or lubricating drawing material
    • B21C9/02—Selection of compositions therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C23/00—Tools; Devices not mentioned before for moulding
    • B22C23/02—Devices for coating moulds or cores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/07—Lubricating the moulds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02—Petroleum fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C10M107/08—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation containing butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/56—Acids of unknown or incompletely defined constitution
    • C10M129/60—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M133/08—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/02—Natural products
    • C10M159/06—Waxes, e.g. ozocerite, ceresine, petrolatum, slack-wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/02—Natural products
    • C10M159/08—Fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C10M2205/0265—Butene used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/24—Epoxidised acids; Ester derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/04—Molecular weight; Molecular weight distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C10N2050/011—Oil-in-water

Definitions

  • This invention relates to metal working lubricants and particularly to non-staining metal working lubricants to avoid discoloration and/or contamination of the metal surfaces.
  • a lubricant In the cold rolling of hot-rolled ,strip steel to reduce the thickness of the steel strip, a lubricant, usually a mineral oil, is used to lubricate the surfaces of the steel and the rolls.
  • the lubricant in manycases, serves the dual function of both a lubricant and a coolant.
  • the lubricant can be applied in any suitable manner, such as by brushing or spraying ontothe metal and/or rolls.. Present practice is to apply. the lubricant to the hot-rolled steel strip at the up-coiler after the pickling operation.- The hot-rolled strip is thus provided with lubricant for subsequent cold rolling operations and also an anti-corrosion protective film.
  • Metal working lubricants for satisfactory reduction of strip steel by cold rolling must provide. good adherence prior to and during the rolling operation, and goodboundary lubrication; should not discolor the cold rolled strip on annealing or leave any residue on the surface which would interfere with further processing; and should be free from objectionable physiological features.
  • a superior non-staining metal working lubricant is obtained by the combination consisting essentially of (A) from about 50% to about 98% of liquid polybutenes having a viscosity at 210 F. of from about 30 to about 1100 SSU (Saybolt Seconds Universal); (B) from about ice 2% to about 50% fatty materials which provide lubricity and anti-friction properties to the lubricant; and (C) from about to about of an emulsifier.
  • the polybutenes providethe requisite load bearing properties to the. lubricant.
  • the lubricants of this invention provide the necessary adherence, boundary lubrication, and freedom from surface discoloration and contamination after annealing or casting that is required by various metal workingor fabricating processes.
  • liquid polybutenes suitable for use in the present invention are come'rcially available products and can be prepared by polymerizing butenes from a butane-butylene stream as described, for example, in US. Patents 2,407,- 873, and 2,677,000-l-2.
  • the polybutenes have a relatively narow molecular weight range of from about 300 to about 900 molecular weight, are substantially free from vegetable, and marine fats and oils; esters of such fatty acids and 'glycerides; oxidized oils, such as oxidized oil; sulfurized fatty acids and oils, such as sulfurized sperm oil and sulfurized fatty acids; halogenated materials, such as chlorinated paraflin waxes; and naturally occurring and synthetic waxes, such as sperm wax, montan wax, and beeswax.
  • the saturated fatty materials are preferred.
  • polybutenes used are identified as: Polybutene A-liquid polybutene having about 300 average molecular weight and a viscosity at 210 F. of about 40 SSU; Polybutene Bliquid polybutene having about 830 average molecular weight and a viscosity at 210 F. of about 1100 SSU; Polybutene Cliquid polybutene having about 460 average molecular weight and a viscosity at 210 F. of about 65 SSU.
  • the lubricated coils were passed thru the coldrolling mill without further lubrication; and the rolled strips annealed at about l000-1800 F. After annealing, the annealed sheets did not show any surface discoloration or surface blemishes. Rolling speeds were com parable to the roll speeds obtained with conventionally used mineral oil based lubricants.
  • the previously annealed cold rolled steel sheets are further reduced to the desired thickness.
  • the mechanical energy required to effect this reluction produces substantial heat in the strip. Therefore, water emulsions of the rolling lubricants are used for both lubrication and heat removal.
  • the novel metal working lubricants of this invention can be used to form the desired oil-in-Water emulsions containing from to about 60% lubricant depending on the type of emulsion used by the specific mill.
  • Quick breaking emulsions can be formed without the use of any emulsifier for single use service. For recirculatingtype mills, the addition of up to 5% emulsifier produces a stable emulsion suitable for extended service periods.
  • emulsifiers for the preparation of oil-inwater emulsions can be used.
  • the preferred emulsifiers are diethanolamine and di'glycolamine.
  • the following formulas illustrate lubricants that form either quick breaking or stable oil-in-water emulsions.
  • the non-staining rolling lubricant of this invention is unique in its ability to reduce the surface discoloration characteristics of mineral oil rolling lubricants. This is illustrated by the following formulations:
  • the present invention provides a nonstaining cold rolling lubricant that can be used perse, or to form oil-in-water lubricant emulsions, or for improving the non-staining characteristics of mineral oil rolling lubricants.
  • the lubricants are especially effective for metals that must be annealed because they are completely removed during annealing without discoloration of the metal and do not leave any residue. Quite unexpectedly, it has been further found that the lubricants are extremely effective in extending'the saw life, thereby reducing the number of times that the saw must be sharpened. Thus, use of the non-staining metal working lubricants of the present invention permit the fabrication of metal articles at reduced cost because waste is avoided and additional fabricating steps are no longer necessary.
  • lubricants prepared in accordance with this invention are suitable for use in such continuous casting processes; These lubricants having the requisite thermal stability, lubricity, non-reactivity and non-residue forming characteristics consist essentially of the herein defined liquid polybutenes and saturated fatty materials. Exemplary of such lubricants are the Formulas l3 formulations hereinbefore set forth.
  • a non-staining steel rolling lubricant consisting essentially of from about 50 to about 98% liquid polybutene having a viscosity at 210 F. of from about 30 SSU to about 1100 SSU; from about 2 to about 50% of fatty material which provides lubricity and anti-friction properties to the lubricant; and from 0 to about 5% of an emulsifier.
  • the non-staining steel rolling lubricant consisting essentially of a mixture of (A) about 65% liquid polybutene having a viscosity at 210 F. of about 40 SSU; (B) about 20% liquid polybutene having a viscosity at 210 F. of about 1100 SSU; and (C) about 15% hydrogenated tallow fatty acid.
  • the non-staining steel rolling lubricant consisting essentially of about 96% liquid polybutene having a viscosity at 210 F. of about 65 SSU; and about 4% hydrogenated tallow fatty acid.
  • the non-staining steel rolling lubricant consisting essentially of about 92% liquid polybutene having a viscosity at 210 F. of about 65 SSU; and about 8% hydrogenated tallow fatty acid.
  • the non-staining steel rolling lubricant consisting essentially of a mixture of about 60% liquid polybutene having a viscosity at 210 F. of about 40 SSU; about sperm oil wax; about 10% blown sperm oil; about hydrogenated tallow fatty acid; and about 5% triethanolamine.
  • the non-staining steel rolling lubricant consisting essentially of a mixture of about liquid polybutene having a viscosity at 210 F. of about 40 SSU; about 10% sperm oil wax; about 10% blown sperm oil; about 15% hydrogenated tallow fatty acid; and about 5% diglyc-olamine.
  • the non-staining steel rolling lubricant consisting essentially of a mixture of about liquid polybutene having a viscosity at 210 F. of about 40 SSU; about 10% sperm oil wax; about 10% blown sperm oil; and about 15 hydrogenated tallow fatty acid.
  • a water emulsifiable non-staining steel rolling lubricant consisting essentially of (A) about -100% of a mixture of substantially equal parts of liquid polybutene having a viscosity at 210 F. of about 1100 SSU, and hydrogenated tallow fatty acid; and (B) from 0 to about 5% of an emulsifier.
  • composition of claim 9 wherein said emulsifier is diglycolamine.
  • the non-staining steel rolling lubricant consisting essentially of (A) about 15% liquid polybutene having a viscosity at 210 F. of about 40 SSU; (B) about 20% liquid polybutene having a viscosity at 210 F. of about 1100 SSU; (C) about 50% mineral oil having a viscosity References Cited by the Examiner UNITED STATES PATENTS 2,276,453 3/1942 Bandur 25249.5 2,353,830 7/1944 Kaufman et al. 25249.5 X 2,899,390 8/1959 Plemich 25256 2,974,106 3/1961 Fronmuller et al. 252357 X 3,028,335 4/1962 Shamaiengar 252--49.5 X 3,071,544 1/1963 Rue 25249.5 X

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Lubricants (AREA)
US436269A 1964-03-27 1965-03-01 Metal working lubricant Expired - Lifetime US3298954A (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
US436269A US3298954A (en) 1964-03-27 1965-03-01 Metal working lubricant
SE3451/65A SE324423B (de) 1964-03-27 1965-03-17
FR10231A FR1426791A (fr) 1964-03-27 1965-03-22 Lubrifiant pour le travail de métaux, et procédés pour son utilisation
GB12466/65A GB1109304A (en) 1964-03-27 1965-03-24 Lubricants based on liquid polybutenes
BE661651A BE661651A (de) 1964-03-27 1965-03-25
NL6503934A NL6503934A (de) 1964-03-27 1965-03-26
DE19651594626 DE1594626C3 (de) 1964-03-27 1965-03-27 Polybutenhaltiges Schmiermittel zum Walzen von Stahl
LU48283A LU48283A1 (de) 1964-03-27 1965-03-29
AT286565A AT282787B (de) 1964-03-27 1965-03-29 Metallbearbeitungs-Schmiermittel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US35541964A 1964-03-27 1964-03-27
US436269A US3298954A (en) 1964-03-27 1965-03-01 Metal working lubricant

Publications (1)

Publication Number Publication Date
US3298954A true US3298954A (en) 1967-01-17

Family

ID=26998850

Family Applications (1)

Application Number Title Priority Date Filing Date
US436269A Expired - Lifetime US3298954A (en) 1964-03-27 1965-03-01 Metal working lubricant

Country Status (7)

Country Link
US (1) US3298954A (de)
AT (1) AT282787B (de)
BE (1) BE661651A (de)
GB (1) GB1109304A (de)
LU (1) LU48283A1 (de)
NL (1) NL6503934A (de)
SE (1) SE324423B (de)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3397734A (en) * 1966-05-31 1968-08-20 Standard Oil Co Polybutene continuous metal casting lubrication process
US3475338A (en) * 1966-10-13 1969-10-28 Sinclair Research Inc Process of cutting metals and cutting oil containing allylic hydroxyl-terminated unsaturated diene polymer
US3640856A (en) * 1969-01-27 1972-02-08 Chevron Res Polybutene containing soluble oils
US3657126A (en) * 1970-04-17 1972-04-18 Aluminum Co Of America Oil and water-base lubricant: that, as to improvements in oil and water-base lubricants
US3846319A (en) * 1973-03-27 1974-11-05 Chevron Res Dioxan-containing aluminum lubricant
US3899625A (en) * 1971-12-27 1975-08-12 Nippon Steel Corp Sheet metal treated with lubricant for press work
US3950975A (en) * 1972-10-11 1976-04-20 Kao Soap Co., Ltd. Process of cold plastic deformation of metals
US4027070A (en) * 1974-03-08 1977-05-31 Nippon Steel Corporation Steel plate for preparing cans by ironing
US4260502A (en) * 1979-06-07 1981-04-07 Nalco Chemical Company Synthetic drawing and ironing lubricant
WO1981003293A1 (en) * 1980-05-14 1981-11-26 Nat Can Corp Precoated stock material for containers and method of forming seamless container
US4483777A (en) * 1982-09-20 1984-11-20 Mobil Oil Corporation Stability improvers for water-in-oil emulsion
US4876017A (en) * 1988-01-19 1989-10-24 Trahan David O Use of polyalphalolefin in downhole drilling
JPH02199199A (ja) * 1989-01-27 1990-08-07 Yushiro Chem Ind Co Ltd 水溶性切削油剤組成物
US5001013A (en) * 1989-08-15 1991-03-19 Cincinnati-Vulcan Company Coating oil having improved electrocoat compatibility
US5045219A (en) * 1988-01-19 1991-09-03 Coastal Mud, Incorporated Use of polyalphalolefin in downhole drilling
JPH05255678A (ja) * 1992-12-24 1993-10-05 Idemitsu Kosan Co Ltd 切削・研削用潤滑油剤
US5340486A (en) * 1992-08-27 1994-08-23 Acheson Industries, Inc. Lubricant compositions for use in diecasting of metals and process
WO1998032818A1 (de) * 1997-01-29 1998-07-30 Henkel Kommanditgesellschaft Auf Aktien Kühlschmierstoffemulsion
US6194361B1 (en) 1998-05-14 2001-02-27 Larry W. Gatlin Lubricant composition
EP1245664A1 (de) * 2001-03-29 2002-10-02 Henkel Kommanditgesellschaft auf Aktien Schmierstoffmischung und ihre Verwendung
US9512381B2 (en) 2009-05-05 2016-12-06 Rhein Chemie Rheinau Gmbh Lubricity enhancing additives, a method for producing the same and use thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2276453A (en) * 1939-07-14 1942-03-17 Western Electric Co Lubricant composition
US2353830A (en) * 1940-08-13 1944-07-18 Texas Co Air pump lubricant
US2899390A (en) * 1959-08-11 Non-staining aluminum rolling
US2974106A (en) * 1955-12-02 1961-03-07 Comcolloid Inc Emulsifier-wax compositions
US3028335A (en) * 1958-10-20 1962-04-03 Waverly Oil Works Company Lubricating composition
US3071544A (en) * 1959-08-14 1963-01-01 Sun Oil Co Emulsifiable mixtures of mineral oil and esters

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2899390A (en) * 1959-08-11 Non-staining aluminum rolling
US2276453A (en) * 1939-07-14 1942-03-17 Western Electric Co Lubricant composition
US2353830A (en) * 1940-08-13 1944-07-18 Texas Co Air pump lubricant
US2974106A (en) * 1955-12-02 1961-03-07 Comcolloid Inc Emulsifier-wax compositions
US3028335A (en) * 1958-10-20 1962-04-03 Waverly Oil Works Company Lubricating composition
US3071544A (en) * 1959-08-14 1963-01-01 Sun Oil Co Emulsifiable mixtures of mineral oil and esters

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3397734A (en) * 1966-05-31 1968-08-20 Standard Oil Co Polybutene continuous metal casting lubrication process
US3475338A (en) * 1966-10-13 1969-10-28 Sinclair Research Inc Process of cutting metals and cutting oil containing allylic hydroxyl-terminated unsaturated diene polymer
US3640856A (en) * 1969-01-27 1972-02-08 Chevron Res Polybutene containing soluble oils
US3657126A (en) * 1970-04-17 1972-04-18 Aluminum Co Of America Oil and water-base lubricant: that, as to improvements in oil and water-base lubricants
US3899625A (en) * 1971-12-27 1975-08-12 Nippon Steel Corp Sheet metal treated with lubricant for press work
US3950975A (en) * 1972-10-11 1976-04-20 Kao Soap Co., Ltd. Process of cold plastic deformation of metals
US3846319A (en) * 1973-03-27 1974-11-05 Chevron Res Dioxan-containing aluminum lubricant
US4027070A (en) * 1974-03-08 1977-05-31 Nippon Steel Corporation Steel plate for preparing cans by ironing
US4260502A (en) * 1979-06-07 1981-04-07 Nalco Chemical Company Synthetic drawing and ironing lubricant
WO1981003293A1 (en) * 1980-05-14 1981-11-26 Nat Can Corp Precoated stock material for containers and method of forming seamless container
US4483777A (en) * 1982-09-20 1984-11-20 Mobil Oil Corporation Stability improvers for water-in-oil emulsion
US5045219A (en) * 1988-01-19 1991-09-03 Coastal Mud, Incorporated Use of polyalphalolefin in downhole drilling
US4876017A (en) * 1988-01-19 1989-10-24 Trahan David O Use of polyalphalolefin in downhole drilling
JPH02199199A (ja) * 1989-01-27 1990-08-07 Yushiro Chem Ind Co Ltd 水溶性切削油剤組成物
US5001013A (en) * 1989-08-15 1991-03-19 Cincinnati-Vulcan Company Coating oil having improved electrocoat compatibility
US5340486A (en) * 1992-08-27 1994-08-23 Acheson Industries, Inc. Lubricant compositions for use in diecasting of metals and process
JPH05255678A (ja) * 1992-12-24 1993-10-05 Idemitsu Kosan Co Ltd 切削・研削用潤滑油剤
WO1998032818A1 (de) * 1997-01-29 1998-07-30 Henkel Kommanditgesellschaft Auf Aktien Kühlschmierstoffemulsion
US6245723B1 (en) 1997-01-29 2001-06-12 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Cooling lubricant emulsion
US6194361B1 (en) 1998-05-14 2001-02-27 Larry W. Gatlin Lubricant composition
US6489272B2 (en) 1998-05-14 2002-12-03 Larry W. Gatlin Lubricant, solvent and emulsifier composition and method of manufacture
EP1245664A1 (de) * 2001-03-29 2002-10-02 Henkel Kommanditgesellschaft auf Aktien Schmierstoffmischung und ihre Verwendung
WO2002079360A1 (de) * 2001-03-29 2002-10-10 Henkel Kommanditgesellschaft Auf Aktien Schmierstoffmischung und ihre verwendung
US20040132628A1 (en) * 2001-03-29 2004-07-08 Jurgen Geke Lubricant blend and use of the same
US9512381B2 (en) 2009-05-05 2016-12-06 Rhein Chemie Rheinau Gmbh Lubricity enhancing additives, a method for producing the same and use thereof

Also Published As

Publication number Publication date
AT282787B (de) 1970-07-10
GB1109304A (en) 1968-04-10
DE1594626B2 (de) 1975-08-14
NL6503934A (de) 1965-09-28
BE661651A (de) 1965-07-16
SE324423B (de) 1970-06-01
DE1594626A1 (de) 1971-01-07
LU48283A1 (de) 1965-05-29

Similar Documents

Publication Publication Date Title
US3298954A (en) Metal working lubricant
US4452712A (en) Metalworking with an aqueous synthetic lubricant containing polyoxypropylene-polyoxyethylene-polyoxypropylene block copolymers
US4452711A (en) Aqueous metalworking lubricant containing polyoxypropylene-polyoxyethylene-polyoxypropylene block copolymers
JPH0317879B2 (de)
JPS62277495A (ja) 冷却潤滑剤の存在下におけるアルミニウムおよびアルミニウム合金の機械加工方法ならびに冷却潤滑剤の濃縮物
US2632734A (en) Emulsifiable metal-working lubricant
US5171903A (en) Lubricating oil composition
US3649538A (en) Diol-containing aluminum lubricant
US3124531A (en) Metal working lubricant
JPS62201994A (ja) 金属加工用潤滑油
KR970010855B1 (ko) 금속가공용 윤활유 조성물
US2962401A (en) Cold deformation of metals
US3835052A (en) Emulsion for hot rolling aluminum products
JP3251659B2 (ja) アルミニウム及びアルミニウム合金の冷間圧延油及びそれを用いる冷間圧延方法
US3390084A (en) Cold rolling lubrication
JPH08170090A (ja) アルミニウム用熱間圧延油および該圧延油を使用するアルミニウムの熱間圧延方法
US2981128A (en) Process and lubricant composition for rolling aluminum
JPH108077A (ja) 金属塑性加工用潤滑油剤
US3233442A (en) Method and compositions for rolling light metals
US2203507A (en) Lubricant and method of lubrication
US3770636A (en) Dispersion for hot rolling aluminum products
JPH0631391B2 (ja) 塑性加工用潤滑油剤
JP2791723B2 (ja) 水溶性冷間圧延油組成物
EP0115926A1 (de) Polyäthylenoxyd-Polypropylenoxyd-Polyäthylenoxyd-Blockcopolymere enthaltende Schmiermittel für die Metallbearbeitung
JPH0221437B2 (de)