US3342566A - Process for the electrodeposition of a decorative corrosion resistant nickel-chromium coating and products thereof - Google Patents

Process for the electrodeposition of a decorative corrosion resistant nickel-chromium coating and products thereof Download PDF

Info

Publication number: US3342566A
Authority: US; United States
Prior art keywords: nickel; coating; chromium; corrosion resistant; deposits
Prior art date: 1963-12-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

US416606A

Other languages

English (en)

Inventor

Adolf E Schwedhelm

Kull Friedrich Karl

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1963-12-24

Filing date

1964-12-07

Publication date

1967-09-19

1964-12-07 Application filed by Individual filed Critical Individual

1967-09-19 Application granted granted Critical

1967-09-19 Publication of US3342566A publication Critical patent/US3342566A/en

1984-09-19 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000576 coating method Methods 0.000 title claims description 35
239000011248 coating agent Substances 0.000 title claims description 32
238000005260 corrosion Methods 0.000 title claims description 27
230000007797 corrosion Effects 0.000 title claims description 27
238000000034 method Methods 0.000 title claims description 13
229910018487 Ni—Cr Inorganic materials 0.000 title description 15
VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 title description 15
238000004070 electrodeposition Methods 0.000 title description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 66
229910052759 nickel Inorganic materials 0.000 claims description 32
239000002245 particle Substances 0.000 claims description 28
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 16
229910052804 chromium Inorganic materials 0.000 claims description 16
239000011651 chromium Substances 0.000 claims description 16
229910052799 carbon Inorganic materials 0.000 claims description 12
239000010953 base metal Substances 0.000 claims description 4
239000007864 aqueous solution Substances 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 claims description 2
239000002184 metal Substances 0.000 claims description 2
238000013019 agitation Methods 0.000 description 6
238000007747 plating Methods 0.000 description 6
239000011148 porous material Substances 0.000 description 5
238000009713 electroplating Methods 0.000 description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
229910021586 Nickel(II) chloride Inorganic materials 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
239000004327 boric acid Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 2
LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 2
229910000363 nickel(II) sulfate Inorganic materials 0.000 description 2
239000000843 powder Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
YCMLQMDWSXFTIF-UHFFFAOYSA-N 2-methylbenzenesulfonimidic acid Chemical compound CC1=CC=CC=C1S(N)(=O)=O YCMLQMDWSXFTIF-UHFFFAOYSA-N 0.000 description 1
241000080590 Niso Species 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
229910052728 basic metal Inorganic materials 0.000 description 1
150000003818 basic metals Chemical class 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
150000001721 carbon Chemical class 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
229910010293 ceramic material Inorganic materials 0.000 description 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000000151 deposition Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
238000001962 electrophoresis Methods 0.000 description 1
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
RPNGVMQUMQOIJJ-UHFFFAOYSA-N hexa-2,4-diyne-1,1-diol Chemical compound CC#CC#CC(O)O RPNGVMQUMQOIJJ-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000011835 investigation Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
239000000203 mixture Substances 0.000 description 1
150000002815 nickel Chemical class 0.000 description 1
KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 description 1
SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
239000000047 product Substances 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
229940081974 saccharin Drugs 0.000 description 1
235000019204 saccharin Nutrition 0.000 description 1
239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000000243 solution Substances 0.000 description 1
FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
229940124530 sulfonamide Drugs 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
235000010215 titanium dioxide Nutrition 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
- C25D15/02—Combined electrolytic and electrophoretic processes with charged materials
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0016—Foam properties semi-rigid
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/934—Electrical process
- Y10S428/935—Electroplating
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12826—Group VIB metal-base component
- Y10T428/12847—Cr-base component
- Y10T428/12854—Next to Co-, Fe-, or Ni-base component
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12944—Ni-base component

Definitions

Nickel because of its corrosion resistant properties, is used extensively in the form of plating to protect other and more vulnerable materials from atmospheric corrosion. For decorative purposes, nickel deposits are frequently used for corrosion resistance and the thin covering of chromium provides additional tarnish resistance. However, the decorative covering of chromium adds little to the protective value of the nickel plating when the customarily very thin chromium deposits are used.
the corrosion of the resultant nickel-chromium coating generally proceeds at pores in the coating. These pores may exist originally because of imperfections in the electroplating process; the coating may be too thin, or the pores may develop as a result of local corrosion of the metallic coating itself. In any event, the corrosion causes the basic metal to suffer accelerated galvanic corrosion at the base of the pore, because of its small anodic area and the large cathodic area of the protective coating.

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electroplating And Plating Baths Therefor (AREA)
Electroplating Methods And Accessories (AREA)
Electrolytic Production Of Metals (AREA)
Paints Or Removers (AREA)

US416606A 1963-12-24 1964-12-07 Process for the electrodeposition of a decorative corrosion resistant nickel-chromium coating and products thereof Expired - Lifetime US3342566A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DEK0051724		1963-12-24

Publications (1)

Publication Number	Publication Date
US3342566A true US3342566A (en)	1967-09-19

Family

ID=7226100

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
US416606A Expired - Lifetime US3342566A (en)	1963-12-24	1964-12-07	Process for the electrodeposition of a decorative corrosion resistant nickel-chromium coating and products thereof

Country Status (10)

Country	Link
US (1)	US3342566A (de)
AT (1)	AT249464B (de)
BE (1)	BE655857A (de)
CH (1)	CH448668A (de)
DE (1)	DE1496856B2 (de)
DK (1)	DK107005C (de)
ES (1)	ES306536A1 (de)
GB (1)	GB1091418A (de)
NL (1)	NL6414795A (de)
SE (1)	SE307268B (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3926569A (en) *	1971-12-15	1975-12-16	Midwest Chrome Process Company	Multiple metallic layers including tin-cobalt-containing alloy layer
US4496442A (en) *	1980-08-14	1985-01-29	Toagosel Chemical Industry Co., Ltd.	Process for generating hydrogen gas

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4285783A (en) *	1979-07-06	1981-08-25	Metropolitan Wire Corporation	Coating for metal shelving and method of applying same
JPS5931187B2 (ja) *	1980-01-21	1984-07-31	株式会社日立製作所	触媒電極の製造方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE957677C (de) *		1957-01-17	Alfred Teves Maschinen- und Armaturenfabrik Kommandit-Gesellschaft, Frankfurt/M	Verfahren zur Herstellung von selbstschmierenden metallischen Gleitschichten
US2999798A (en) *	1955-12-09	1961-09-12	Daimler Benz Ag	Method of producing a wear-resisting surface on a metal element
US3057048A (en) *	1958-11-06	1962-10-09	Horizons Inc	Protection of niobium
US3061525A (en) *	1959-06-22	1962-10-30	Platecraft Of America Inc	Method for electroforming and coating
US3152973A (en) *	1960-07-26	1964-10-13	Udylite Corp	Electrodeposition of lustrous nickel

1963
- 1963-12-24 DE DE19631496856 patent/DE1496856B2/de active Pending
1964
- 1964-10-27 AT AT910564A patent/AT249464B/de active
- 1964-11-05 GB GB45103/64A patent/GB1091418A/en not_active Expired
- 1964-11-09 CH CH1444164A patent/CH448668A/de unknown
- 1964-11-17 BE BE655857D patent/BE655857A/xx unknown
- 1964-11-28 ES ES0306536A patent/ES306536A1/es not_active Expired
- 1964-12-07 US US416606A patent/US3342566A/en not_active Expired - Lifetime
- 1964-12-18 NL NL6414795A patent/NL6414795A/xx unknown
- 1964-12-21 DK DK628464AA patent/DK107005C/da active
- 1964-12-22 SE SE15557/64A patent/SE307268B/xx unknown

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE957677C (de) *		1957-01-17	Alfred Teves Maschinen- und Armaturenfabrik Kommandit-Gesellschaft, Frankfurt/M	Verfahren zur Herstellung von selbstschmierenden metallischen Gleitschichten
US2999798A (en) *	1955-12-09	1961-09-12	Daimler Benz Ag	Method of producing a wear-resisting surface on a metal element
US3057048A (en) *	1958-11-06	1962-10-09	Horizons Inc	Protection of niobium
US3061525A (en) *	1959-06-22	1962-10-30	Platecraft Of America Inc	Method for electroforming and coating
US3152973A (en) *	1960-07-26	1964-10-13	Udylite Corp	Electrodeposition of lustrous nickel
US3152972A (en) *	1960-07-26	1964-10-13	Udylite Corp	Electrodeposition of lustrous satin nickel
US3152971A (en) *	1960-07-26	1964-10-13	Udylite Corp	Electrodeposition of fine-grained lustrous nickel

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3926569A (en) *	1971-12-15	1975-12-16	Midwest Chrome Process Company	Multiple metallic layers including tin-cobalt-containing alloy layer
US4496442A (en) *	1980-08-14	1985-01-29	Toagosel Chemical Industry Co., Ltd.	Process for generating hydrogen gas

Also Published As

Publication number	Publication date
BE655857A (de)	1965-03-16
SE307268B (de)	1968-12-23
CH448668A (de)	1967-12-15
DK107005C (da)	1967-04-10
DE1496856B2 (de)	1971-06-24
ES306536A1 (es)	1965-04-01
GB1091418A (en)	1967-11-15
AT249464B (de)	1966-09-26
NL6414795A (de)	1965-06-25
DE1496856A1 (de)	1970-10-01

Publication	Publication Date	Title
US3268308A (en)	1966-08-23	Electrodeposition of a corrosion resistant decorative nickel-chromium coating and products thereof
US3354059A (en)	1967-11-21	Electrodeposition of nickel-iron magnetic alloy films
US4652349A (en)	1987-03-24	Baths for the electrodeposition of tin-graphite or tin/lead-graphite layers
US3591350A (en)	1971-07-06	Novel plating process
US4411961A (en)	1983-10-25	Composite electroplated article and process
US3697391A (en)	1972-10-10	Electroplating processes and compositions
US3920468A (en)	1975-11-18	Electrodeposition of films of particles on cathodes
US3500537A (en)	1970-03-17	Method of making palladium coated electrical contacts
US3691027A (en)	1972-09-12	Method of producing corrosion resistant chromium plated articles
US3528894A (en)	1970-09-15	Method of electrodepositing corrosion resistant coating
US3342566A (en)	1967-09-19	Process for the electrodeposition of a decorative corrosion resistant nickel-chromium coating and products thereof
US3793162A (en)	1974-02-19	Electrodeposition of ruthenium
US4767509A (en)	1988-08-30	Nickel-phosphorus electroplating and bath therefor
EP0892087A2 (de)	1999-01-20	Elektrobeschichtung von spannungsarmem Nickel
US3798137A (en)	1974-03-19	Direct current pigmenting of anodized aluminum
GB1265472A (de)	1972-03-01
US3687824A (en)	1972-08-29	Electrodeposition of films of particles on cathodes
US4479855A (en)	1984-10-30	Galvanic dispersion deposition bath
US3093556A (en)	1963-06-11	Electro-depositing stainless steel coatings on metal surfaces
US4297179A (en)	1981-10-27	Palladium electroplating bath and process
US3943040A (en)	1976-03-09	Microcracked chromium from a bath using an organic sulfur compound
US3920527A (en)	1975-11-18	Self-regulating plating bath and method for electrodepositing chromium
US2437612A (en)	1948-03-09	Process for electrolytically zinc plating magnesium and magnesium base alloys
US3474010A (en)	1969-10-21	Method of electroplating corrosion resistant coating
US3428441A (en)	1969-02-18	Article coated with a composite particulate,microporous chromium coating and method of producing said article

US3342566A - Process for the electrodeposition of a decorative corrosion resistant nickel-chromium coating and products thereof - Google Patents

Info

Links

Classifications

Definitions

Landscapes

Applications Claiming Priority (1)

Publications (1)

Family

ID=7226100

Family Applications (1)

Country Status (10)

Cited By (2)

Families Citing this family (2)

Citations (5)

Patent Citations (7)

Cited By (2)

Also Published As

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