US3372026A - Hot rolling nickel silver alloy - Google Patents

Hot rolling nickel silver alloy Download PDF

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Publication number
US3372026A
US3372026A US485954A US48595465A US3372026A US 3372026 A US3372026 A US 3372026A US 485954 A US485954 A US 485954A US 48595465 A US48595465 A US 48595465A US 3372026 A US3372026 A US 3372026A
Authority
US
United States
Prior art keywords
percent
nickel
weight
silver alloy
nickel silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US485954A
Other languages
English (en)
Inventor
Richard J Christine
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atlantic Richfield Co
Original Assignee
Anaconda American Brass Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anaconda American Brass Co filed Critical Anaconda American Brass Co
Priority to US485954A priority Critical patent/US3372026A/en
Priority to GB25471/66A priority patent/GB1073680A/en
Priority to FR65310A priority patent/FR1483262A/fr
Priority to DE19661533159D priority patent/DE1533159B1/de
Priority to CH1096966A priority patent/CH455296A/fr
Application granted granted Critical
Publication of US3372026A publication Critical patent/US3372026A/en
Assigned to ATLANTIC RICHFIELD COMPANY, A PA CORP. reassignment ATLANTIC RICHFIELD COMPANY, A PA CORP. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: ANACONDA COMPANY THE, A DE CORP
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/06Alloys based on copper with nickel or cobalt as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent

Definitions

  • This invention relates to a nickel silver alloy which has improved hot working properties, and more particularly, it relates to the addition of fractional amounts of titanium to a nickel silver alloy to form a nickel silver alloy that can be hot rolled.
  • Nickel silvers have poor hot working properties and cannot be reduced by hot rolling without severe cracking of the rolled metal.
  • Nickel silvers have essentially two phases, a single-phase alpha nickel silver and a two-phase alpha-beta nickel silver.
  • the alpha-beta nickel silver can be hot-worked but not with the results ordinarily achieved with brasses; the alpha nickel silvers have never been successfully hotworked without the cracking problem mentioned above, and therefore they are used in applications requiring ductility in the cold condition as they have good cold working properties.
  • the reduction of alpha nickels by cold rolling is an expensive process because they work-harden rapidly and require frequent anneals, and they are prone to fire cracking during annealing which causes considerable metal loss.
  • the nickel silver alloy of the invention is comprised of 45 to 75 percent by weight Cu, 7 to 30 percent by weight Ni, 5 to 43 percent by weight Zn and 0.003 to 0.3 percent Ti.
  • alpha nickel silvers which are comprised of 45 to percent by weight Cu, 7 to 25 percent by weight Ni, 5 to 32 percent by weight Zn, it is preferred to include from about 0.003 to 0.1 percent by weight Ti.
  • alpha nickel silvers is meant a copper-nickel-zinc alloy containing 45 to 75 percent by weight Cu, 7 to not more than about 25 percent by weight Ni, and 5 to not more than about 32 percent by weight Zn, which, under conditions of structural equilibrium comprise a single solid solution, isomorphous with copper; above about 32 percent Zn, the alpha-beta nickel silver phase appears.
  • Heat B Heat 0 Heat D The cakes were soaked at 900 C. for four hours prior to hot rolling. Hot rolling temperatures ranged from 860 C. to 900 C. All cakes were hot rolled to 0.500 gauge in 15 passes without evidence of cracking or other hot rolling defects.
  • a nickel silver alloy with improved hot working properties consisting essentially of 730% Ni, 543% 3 Zn, G.OO3O.3% Ti and the balance essentially Cu, said Cu being present in the range of 4575%.
  • a nickel silver alloy With improved hot Working properties consisting essentially of 7-30% Ni, 5-43% Zn, .O030.1% Ti and the balance essentially Cu, said Cu being present in the range of 45-75%.
  • An alpha nickel silver alloy with improved hot working properties consisting essentially of 725% Ni, 532% Zn, 0.003-0.3% Ti and the balance essentially Cu, said Cu being present in the range of 45-75%.
  • An alpha nickel silver alloy With improved hot Working properties consisting essentially of 725% Ni, 532% 4, p Zn, 0.003411% Ti and the balance essentially Cu, said Cu being present in the range of 45-75%.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Metal Rolling (AREA)
  • Conductive Materials (AREA)
US485954A 1965-09-08 1965-09-08 Hot rolling nickel silver alloy Expired - Lifetime US3372026A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US485954A US3372026A (en) 1965-09-08 1965-09-08 Hot rolling nickel silver alloy
GB25471/66A GB1073680A (en) 1965-09-08 1966-06-08 Improvements in a nickel silver alloy suitable for hot working
FR65310A FR1483262A (fr) 1965-09-08 1966-06-13 Alliage de nickel et d'argent perfectionné
DE19661533159D DE1533159B1 (de) 1965-09-08 1966-06-30 Neusilber-Legierung
CH1096966A CH455296A (fr) 1965-09-08 1966-07-28 Alliage de nickel blanc

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US485954A US3372026A (en) 1965-09-08 1965-09-08 Hot rolling nickel silver alloy

Publications (1)

Publication Number Publication Date
US3372026A true US3372026A (en) 1968-03-05

Family

ID=23930058

Family Applications (1)

Application Number Title Priority Date Filing Date
US485954A Expired - Lifetime US3372026A (en) 1965-09-08 1965-09-08 Hot rolling nickel silver alloy

Country Status (4)

Country Link
US (1) US3372026A (fr)
CH (1) CH455296A (fr)
DE (1) DE1533159B1 (fr)
GB (1) GB1073680A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5019335A (en) * 1989-07-10 1991-05-28 Daniel Davitz Gold colored metal alloy

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2035423A (en) * 1935-07-06 1936-03-24 Revere Copper & Brass Inc Welding rod and the like
US2752242A (en) * 1950-08-08 1956-06-26 Gen Motors Corp Copper-nickel-titanium alloy and process for making same
CA553142A (fr) * 1958-02-11 H. Waller Paul Alliages a base de cuivre et leur production
DE1050552B (de) * 1959-02-12 Wmified May Walkr geb CoIe und Paul Henry Waller Oxhey Watford Hertfordshire (Großbritannien) Kupfer Nickel Zmk-Legicrung

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB683122A (en) * 1949-03-09 1952-11-26 British Non Ferrous Metals Res Improvements in or relating to ª‰-brasses
GB672263A (en) * 1949-07-13 1952-05-21 Rolls Royce Aluminium bronze alloy
DE1026084B (de) * 1951-05-28 1958-03-13 Winifred May Waller Kupfer-Nickel-Zink-Legierung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA553142A (fr) * 1958-02-11 H. Waller Paul Alliages a base de cuivre et leur production
DE1050552B (de) * 1959-02-12 Wmified May Walkr geb CoIe und Paul Henry Waller Oxhey Watford Hertfordshire (Großbritannien) Kupfer Nickel Zmk-Legicrung
US2035423A (en) * 1935-07-06 1936-03-24 Revere Copper & Brass Inc Welding rod and the like
US2752242A (en) * 1950-08-08 1956-06-26 Gen Motors Corp Copper-nickel-titanium alloy and process for making same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5019335A (en) * 1989-07-10 1991-05-28 Daniel Davitz Gold colored metal alloy

Also Published As

Publication number Publication date
CH455296A (fr) 1968-06-28
GB1073680A (en) 1967-06-28
DE1533159B1 (de) 1972-01-20

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Legal Events

Date Code Title Description
AS Assignment

Owner name: ATLANTIC RICHFIELD COMPANY, A PA CORP.

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:ANACONDA COMPANY THE, A DE CORP;REEL/FRAME:003992/0218

Effective date: 19820115