US3377128A - Process for the production of colored cellulose triacetate material and blends thereof with polyacrylonitrile - Google Patents

Process for the production of colored cellulose triacetate material and blends thereof with polyacrylonitrile Download PDF

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US3377128A
US3377128A US417762A US41776264A US3377128A US 3377128 A US3377128 A US 3377128A US 417762 A US417762 A US 417762A US 41776264 A US41776264 A US 41776264A US 3377128 A US3377128 A US 3377128A
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acid
group
lower alkyl
member selected
cellulose triacetate
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US417762A
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Hans Rafael
Erhard Tutsch
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Novartis AG
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JR Geigy AG
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/647—Nitrogen-containing carboxylic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6536—Aromatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/40—Cellulose acetate
    • D06P3/401—Cellulose acetate using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/40—Cellulose acetate
    • D06P3/405—Cellulose acetate using metallisable or mordant dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/70—Material containing nitrile groups
    • D06P3/704—Material containing nitrile groups using metallisable or mordant dyes or dyeing by cupro-ionic method
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/70—Material containing nitrile groups
    • D06P3/74—Material containing nitrile groups using acid dyes

Definitions

  • a process for producing colored cellulose acetate fiber material, polyacry-lonitrile type fiber material and blended fabrics consisting essentially of these two types of fibers or blends of polyacrylonitrile type fibers with staple rayon.
  • Padding liquors or printing pastes are also provided.
  • the process comprises padding the fiber material with a thickened padding liquor or printing the material with a printing paste which contains at least one water-soluble acid wool dyestuif, at least one monoor poly-nuclear aromatic compound which is substituted at the aromatic ring by a functional group con-. taining oxygen, an amide of a thiocarbonderived acid, and thickener, as well as, if desired, other conventional additives, and steaming the resultant impregnated or printed goods.
  • the present invention concerns a process for the production of colored cellulose acetate fiber material, polyacrylonitrile type fiber material, and blended fabrics consisting essentially of the aforesaid two types of fibers or of blends of polyacrylonitrile type fibers with staple rayon, and the padding liquors or printing pastes used for this purpose as well as, as industrial product, the fabric so dyed or printed.
  • the present invention concerns a process for the pad-dyeing or printing of cellulose triacetate fiber materials.
  • the process according to the invention comprises padding the cellulose acetate fiber material or other abovelisted textile materials with a thickened padding liquor or printing the aforesaid material with a printing paste which contains at least one water-soluble acid wool dyestuff, at least one monoor poly-nuclear aromatic compound which is substituted at the aromatic ring by a functional group containing oxygen, an amide of a thiocarbon-derived acid as defined below, and thickener, as
  • the thickened padding liquor or printing paste contains, as aromatic functional oxygen compounds usable as defined, especially, in the preferred mode of carrying out the process according to the invention in practice, either a carbocyclic aryl compound with from one to two preferably unfused six-membered rings, exclusively substituted with at least one substituent, and preferably one to two substituents Y, each Y being, independently, -OH, or CHO, or --COOH, or a carbocyclic aryl compound with from one to two preferably unfuse'd sixmembered rings, exclusively substituted at the same time with at least one substituent defined as Y above, and at least one other substituent Z which is chlorine, bromine, amino, nitro or lower alkyl; for example, aromatic hydroxyl compounds, and more in particular, for use in the coloring of cellulose triacetate staple fibers or stretched filaments, and in the case of polyacrylonitrile fibers, phenols such as phenol, cresols, xylenols, resorcin
  • amide of a thiocarbon-derived acid as used h'e-rein means amides optionally substituted "at the aminonitrogen atom and, as the case may be, in several tau tomeric form-s, as wella s corresponding hydr'azides and imides of organic 'thio'carboxylic acids, furthermore the corresponding amide derivatives, and tautomers thereof,
  • the padding liquor or printing paste contains, for example, thioamides of carboxylic acids such as thioacetamides, N- methylor N-ethylor N-hydroxyethyl-thioacetamide, or amide-type derivatives of thiocarbonic acid such as thiourea or isothiourea which may be substituted at the nitrogen or sulfur atom, alkyl and hydroxyalkyl groups containing preferably not more than 4 carbonatoms being used in particular as nitrogen or sulfur substituents, or thiosemicarbazide, also optionally N-lower alkyl substituted thiuram monoand di-sulfides such as tetra-lower alkyl thiuram monoor di-sulfide or water-soluble salts, in particular alkali metal or ammonium salts and especially lower alkyl-ammonium salts of thiocyanic or thioisocyanic acids.
  • Thiouroamides of carboxylic acids such as thioace
  • Water-insoluble amides such as the above-mentioned tetra-alkyl-thiuram disulfides are preferably used finely Patented Apr. 9, 1968 dispersed, as a suspension or emulsion in an inorganic solvent such as ethanol.
  • the padding liquor or printing paste used according to the invention thus contains the aromatic functional oxygen compounds as defined and the amide of thiocarbonderived acid in amounts of, together, about 50 to 250 g., preferably in amounts of about 150 g. per kilogram liquor or paste.
  • padded or printed cellulose triacetate fabrics are produced by "(1) applying to at least a portion of the entire surface, i.e. either by printing or by padding, of a cellulose acetate material or polyacrylonitrile type fiber material, especially of cellulose triacetate fabric, a coloring mixture which consists essentially of q i (1) a water-soluble acid wool dyestuff, in amounts of 5 to 120 grams per kilogram (g./kg.) of the mixture;
  • thickener as defined hereinafter, in amounts of at least about 150 up to about 600 g./kg. of the mixture;
  • R is a member selected from the group consisting of lower alkyl and hydrazino
  • n is an integer ranging from to 1; and, preferably, thiourea, in amounts of about 40 to 120 g./kg. of the mixture;
  • a fixing component which is made up of the following:
  • the aromatic compound having a functional oxyv gen-containingsubstituent or substituents preferably a member selected from the group consisting of phenol, pyrocatechol, resorcinol, phloroglucinol, benzaldehyde substituted with a substituent Z, benzoic acid substituted by a substituent Z, and naphthoic acid substituted by a substituent Z, and phenol substituted with a substituent X, wherein X is a member selected from the group consisting of from one to three lower alkyl groups and phenyl, and
  • Z is a member selected from the group consisting of -OH, --C HO, Cl, Br, NO NH lower alkyl, but optimally resorcinol; (a) amounting to about onethird to one-half of the fixing component, by weight,
  • the resulting padded or printed products are then rinsed as described further below and dried.
  • the weight ratio of the aromatic functional oxygen compounds to that of the amides and other thio compounds mentioned is about 4:1 to 1:4 and preferably about 2:1 to 122, optimal results being obtained with a ratio of about 1:2. 7
  • the liquor or paste contains, for example, the disaggregated types of gum usual in the textile industry, for example the so-called crystal gum or thickeners based on cellulose such as carob bean flour, tragacanth, British gum or alkali metal alginates or cellulose derivatives such as methyl cellulose or soluble salts of carboxymethyl cellulose.
  • the so-called crystal gum or thickeners based on cellulose such as carob bean flour, tragacanth, British gum or alkali metal alginates or cellulose derivatives such as methyl cellulose or soluble salts of carboxymethyl cellulose.
  • the padding liquor or printing paste can contain, for example, acids, in particular, low fatty acids such as formic, and mainly acetic acid; or organic solvents such as alcohols, e.g. methanol, ethanol, benzyl alcohol, ethylene glycol, thiodiethylene glycol, glycerin; or mixtures of such compounds as further additives usual in the textile industry.
  • acids in particular, low fatty acids such as formic, and mainly acetic acid
  • organic solvents such as alcohols, e.g. methanol, ethanol, benzyl alcohol, ethylene glycol, thiodiethylene glycol, glycerin; or mixtures of such compounds as further additives usual in the textile industry.
  • Acid wool dyestuff as used in this specification and in the appended claims means dyestuffs, the colored anions of which draw on wool from hot, acid, aqueous solution and comprises also those of the aforesaid dyestuffs which do so already from their neutral solution.
  • the acid wool dyestuffs in the padding liquor or printing paste used according to the invention can be of the most varied classes of dyestuffs.
  • they are the technically proved dyestuff classes of the azo, anthraquinone, phthalocyanine, nitro, formazan or triphenylmethan dyestuffs which may also contain metals such as copper, nickel, chromium or cobalt.
  • azo dyestuffs mainly monoazo dyestuffs are used, eg.
  • benzene-azo-hydroxy-benzene those of the type benzene-azo-hydroxy-benzene, benzene azo-aminobem zene, benzene-azo-hydroxynaphthalene, naphthalene-azohydroxy-naphthalene, benzene-azo-aminc-naphthalene, benzene-azo-hydroxypyrazole, bcnzene-azo-aminopyrazole, benzene-azo-acyloacetylarylamide or those of the analogous naphthalene-azo and heterocycle-azo types.
  • heterocycle are meant those having five or six ring members, in particular containing nitrogen such as thiaz-oles, imidiazoles, triazoles, tetrazoles, oxdiazoles, thiadiazoles, pyridines, pyrimidines, benzthiazoles, benzimidazoles, benztriazoles, indazoles, quinolines.
  • Acid wool dyes from the class of polyazo dyestuffs can also be used.
  • the azo dyestuffs can be metallized, chiefly by chromium or cobalt, the formazan and phthalocyanine dyes preferably by copper or nickel.
  • heavy metal-containing azo dyestuffs preferably (--SO H)-free chromium or cobalt containing monoazo dyestuffs, which contain one metal atom bound to two molecules of azo dyestuffs.
  • the pH-value of the liquors and pastes according to the invention should be below 7, preferably in the range of 3.5 to 7, depending on the dyestuff used. This pH can be adjusted by adding a corresponding small amount (not more than 1% calculated on the weight of the liquor or bath) of benzoic acid.
  • cellulose triacetatc fabric which is therefore preferred, which very satisfactory dyeings and prints are also obtained on other cellulose acetate fibers such as cellulose diacetate or cellulose 2 /z-acetate, and also on polyacrylonitrile type fibers, by which term there are understood polyacrylonitrile fibers and fibers consisting of copolyrners obtained from acrylonitrile and up to 30% by weight of another monomer copolymerizable with acrylonitrile, examples of which other monomers are given, for instance in Canadian Patent 557,597, issued on May '20, 1958, to The Chemstrand Corporation, Decatur, Ala., and in US. Patents 2,837,500; 2,837,501 and 3,096,- 139. Moreover, blended fabrics as described hereinbefore can also be used with satisfactory results.
  • the cellulose triacetate material is treated with the padding liquor or printing paste by the usual methods.
  • the padded or printed goods are steamed in the known manner and then rinsed, e.g. with cold or warm water which can contain the additives usual in the textile industry, e.g. wetting or wash-active substances. Beautiful dyeings or prints of good color strength are attained.
  • Example 1 80 grams (g). of thiourea are stirred into 500 g. of crystal gum solution (e.g. NAFKAGUM 75, of Scholten, Foxhall, Netherlands) and the mixture is diluted with 260 ml. of water. A 60 warm solution of 50 g. of phenol in 80 g. of thiodiethylene glycol, 20g. of benzyl alcohol and g. of ethanol is added to this mixture.
  • crystal gum solution e.g. NAFKAGUM 75, of Scholten, Foxhall, Netherlands
  • a fabric made of cellulose triacetate staple fiber is printed with the paste so obtained in the then steamed and washed.
  • a strongly colored brilliant red pattern is obtained on the fabric.
  • Prints having similar properties are obtained when the above example is repeated but using, instead of the 80 g. of thiourea and the 50 g. of phenol, the combination of components given below (in amounts of g. per kg. of printing paste):
  • Example 1 When Example 1 is repeated, but instead of the dyestuff mentioned therein, the same amounts of the dyestuffs given in column II of the following table are used, then colored patterns of similar quality are obtained on cellulose triacetate fabric which have the shades given in column III below:
  • Example N TABLE-Continued I II III
  • Example N o. Dyestufi used Shade on cellulose triacetate 28
  • 31 4,4-bis-(o-diuzophenyl-sulphonyloxy)-diphenyl-methane l-phenyl-3-methyl-5-aminopyrazolc Yellow.
  • Acid Black 47 (N O. 56055) I. I. r. Acid Blue 127 (No. 61135) II Acid Orange 3 (No. '385) he monozao dyestuii: 2-diazo-benzoic acid-#142,5'-dichloro-3-sulfophcnyl .1. Acid Orange 7 (No. '510) Orange. Acid Red 52 (No. 45100) Brilliant red. Acid Violet 24 (N o. 44055)-.- Reddish blue. Acid Violet 15 (No. 43525) Blue. Acid Blue 47 (N0. 62'085) Do. Acid Blue 41 (No. 62130)... Do. Acid Blue 62 (No. 62045) Do. Acid Red 73 (No. 27290) Scarlet. Acid Blue 59 (N o. 50315) Blue.
  • Acid Blue 102 (No. 50320) Do. Acid Yellow 65 (No. 14170) Yellow.
  • Acid Red 88 (No. 15620).. Red. I Acid Brown 6 (No. 14625) Reddlsh brown. C. Acid Blue 9 (No. 42090) Blue.
  • Nickel phthalocyanine disulionic acid pyrezole Nickel phthalocyanine disulionic acid pyrezole.
  • Example 81 20 g. of the dyestuff 2:1 chromium complex of Z-amino- 1-hydroxybenzene-4-sulfonic acid amide- 1-(4-chlorophenyl)-3-methyl-5-pyrazolone are mixed with 10 g. of benzoic acid and 80 g. of thiourea; the mixture is pasted with 70 g. of a solution consisting of g. of thiodiethylene glycol, 14 g. of benzyl alcohol and 21 g. of ethanol. The mixture is then dissolved in 250 g. of hot water and then stirred into 350 g. of a ready-for-use 5%-alginate thickener prepared by dissolving g. of sodium alginate powder in 1 liter of Water. A solution of 50 g. rcsorcinol in 50 g. of water is then added to this paste and finally the whole is made up to 1000 g. with Water.
  • a fabric made from cellulose triacctatc stretched filathus prepared, dried at about 100 and then steamed with dry saturated steam in a continuous steaming apparatus of the Mather-Flatt type for 8 to 16 minutes or in a star steamer at 0.2 to 0.8 atmospheres gauge pressure for 10 to 15 minutes.
  • the fabric After steaming, the fabric is rinsed first in cold and then in hot water, then soaped at the boil with an aqueous solution of 1 to 2 g. liter of a nonionogcnic washing agent and finally dried.
  • a strongly colored golden yellow print is obtained which is fast to washing at the boil, sublimation and light.
  • Example 82 20 g. of the dycstulf 2:1 chromium complex of 2- ment is printed in a conventional manner with the paste amino 1 hydroxybcnzenc-S-ethyl sulfone 1-phcnyl-3- methyl-S-pyrazolone are thoroughly mixed with 8 g. of thiourea and 10 g. of benzoic acid and the mixture is pasted with 70 g. of a solution consisting of 35 g. of thiodiethylene glycol, 14 g. of benzyl alcohol and 21 g. of ethanol. The mixture is then dissolved in 250 g. of hot water and the solution is stirred into 350 g.
  • a fabric of cellulose tri-acetate staple fiber is printed in a conventional manner with the paste so prepared, dried at 100 and then steamed with dry saturated steam in a continuous steaming apparatus of the Mather-Flatt type for 8 to minutes.
  • the fabric After steaming, the fabric is rinsed first in cold and then in hot water, then soaped at 40 to 50 with an aqueous solution of 1 to 2 g./liter of a non-ionogenic washing agent and dried.
  • a strongly colored red print is obtained which is fast to washing and sublimation.
  • Example 83 30 g. of the dyestufi 4-(2',4'-dinitro-l-anilino)-1,l-diphenylamine-Z-sulfonic acid are mixed with 8 0 g. of thiourea and 10 g. of benzoicacid and the mixture is pasted with 70 g. of a solution consisting of 35 g. of thiodiethylene glycol, 14 g. of benzyl alcohol and 21 g. of ethanol. The mixture is then dissolved in 250 g. of :hot water and stirred into 350 g. of a previously prepared, ready-for-use 5%-sodium alginate thickener. A mixture of 50 g. of resorcinol in 50 g. of Water is then added to this paste which is finally made up to 1000 g. with water.
  • Polyacrylonitrile fabric is printed in the usual way With the paste so prepared, dried and then steamed with dry saturated steam in a continuous steaming apparatus of the Mather-Flatt type for 8 to 16 minutes or in a star steamer at'0.2 to 0.3 atmospheres gauge pressure for 10 to minutes. After steaming, the fabric is rinsed in cold and then in warm water, soaped at 60 with an aqueous solution of 1 to 2 g./liter of a non-ionogenic Washing agent and then dried.
  • a strongly colored dark golden yellow print is obtained which is fast to washing and sublimation.
  • a process for the production of a colored textile material comprising:
  • R is a member selected from the group consisting of lower alkyl and hydrazino
  • n is an integer ranging from 0 to l;
  • step II is carried out under an excess pressure of about 0.2 to 2 atmospheres.
  • a process for the production of a colored textile material comprising:
  • R is a member selected from the group consisting of lower alkyl and hydrazino
  • n is an integer ranging from to 1; and (d) a thickener;
  • a mixture for padding and printing fabrics consisting essentially of (a) an acid, water-soluble wool dyestuff;
  • Z is a member selected from the group consisting of -Cl, Br, -NO NH and lower alkyl;
  • R is a member selected from the group consisting of lower alkyl and hydrazino
  • n is an integer ranging from 0 to 1;
  • a mixture for padding and printing fabrics consisting essentially of, per kilogram of mixture,
  • Z is a member selected from the group consisting of -Cl, -Br, NO NH and lower alkyl,
  • each of R R R and R independently is a member selected from the group consisting of hydrogen, lower alkyl and hydroXy-lower alkyl,
  • R is a member selected from the group consisting of lower alkyl and hydrazino
  • n is an integer ranging from 0 to 1;
  • balance being aqueous solvent.
  • component (b) is resorcinol and component (0) is thiourea.
  • Z is a member selected from the group consisting of -Cl, Br, NO NH and lower alkyl,
  • (0) a member selected from the group consisting of a compound of the formula a compound of the formula Rt S H a compound of the formula NH Rr-S-C and thiourea, wherein each of R R R and R independently, is a member selected from the group consisting of hydrogen, lower alkyl and hydroxy-lower alkyl, R is a member selected from the group consisting of lower alkyl and hydrazine, and n is an integer ranging from 0 to 1; and (d) a thickener; and (II) steaming the resulting colored fabric. 14.
  • a mixture for padding and printing fabrics con- 7 sisting essentially of, per kilogram of mixture,

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Description

UnitedStates Patent H 3,377,128 PROCESS FOR THE PRODUCTION OF COLORED CELLULOSE TRIACETATE MATERIAL AND LIIIIJQDS THEREOF WITH POLYACRYLONI- R E Hans Rafael, Weil am Rhine, Germany, and Erhard Tutsch, Ashiya, Japan, assignors to J. R. Geigy A.G., Basel, Switzerland No Drawing. Continuation-impart of application Ser. No. 278,484, May 6, 1963. This application Dec. 11, 1964, Ser. No. 417,762 Claims priority, application Switzerland, Apr. 26, 1963,
, 5,296/63; May 2, 1963, 5,507/ 63 Claims. (Cl. 8-21) ABSTRACT OF THE DISCLOSURE A process is provided for producing colored cellulose acetate fiber material, polyacry-lonitrile type fiber material and blended fabrics consisting essentially of these two types of fibers or blends of polyacrylonitrile type fibers with staple rayon. Padding liquors or printing pastes are also provided. The process comprises padding the fiber material with a thickened padding liquor or printing the material with a printing paste which contains at least one water-soluble acid wool dyestuif, at least one monoor poly-nuclear aromatic compound which is substituted at the aromatic ring by a functional group con-. taining oxygen, an amide of a thiocarbonderived acid, and thickener, as well as, if desired, other conventional additives, and steaming the resultant impregnated or printed goods.
This is a continuation-in-part of our pending application Serial No. 278,484, filed May 6, 1963, now abandoned.
' The present invention concerns a process for the production of colored cellulose acetate fiber material, polyacrylonitrile type fiber material, and blended fabrics consisting essentially of the aforesaid two types of fibers or of blends of polyacrylonitrile type fibers with staple rayon, and the padding liquors or printing pastes used for this purpose as well as, as industrial product, the fabric so dyed or printed.
In a preferred aspect the present invention concerns a process for the pad-dyeing or printing of cellulose triacetate fiber materials.
We have found that hitherto known carriers used in the pad-dyeing and printing of cellulose acetate fibers by which fibers the art understands secondary cellulose acetate, more exactly 2 /z-acetate-with water-insoluble dispersion dyestuffs fail when applied to cellulose triacetate. I
' Up to the present it has been necessary to use waterinsolu-ble dispersion dyestuffs in order to obtain dyeings or prints on cellulose triacetate in sufiiciently strongly colored and level shades.
A process has now been found, whereby prints can be obtained on the above-listed textile materials with acid, water-soluble wool dyestuffs. This process has the advantage of giving a much greater choice of dyestuffs, as the class of wool dyestuffs is much more comprehensive than that of dispersion dyestulfs. In addition, the dyeings of prints obtained according to the invention are in no way inferior in their color strength and just as level as those obtained with dispersion dyestuffs. Ineed, some of their fastness properties exceed thoseof dyeings and prints obtained with dispersion dyestuffs. Among these fastness properties are especially wet fastnesses, i.e. to washing, perspiration, sea Water, alkaline media, more- ICC over fastness to sublimation, to many organic solvents and to gas fumes.
The process according to the invention comprises padding the cellulose acetate fiber material or other abovelisted textile materials with a thickened padding liquor or printing the aforesaid material with a printing paste which contains at least one water-soluble acid wool dyestuff, at least one monoor poly-nuclear aromatic compound which is substituted at the aromatic ring by a functional group containing oxygen, an amide of a thiocarbon-derived acid as defined below, and thickener, as
well as, if desired, other additives conventional in the textile industry, and steaming the resulting impregnated or printed goods.
The thickened padding liquor or printing paste contains, as aromatic functional oxygen compounds usable as defined, especially, in the preferred mode of carrying out the process according to the invention in practice, either a carbocyclic aryl compound with from one to two preferably unfused six-membered rings, exclusively substituted with at least one substituent, and preferably one to two substituents Y, each Y being, independently, -OH, or CHO, or --COOH, or a carbocyclic aryl compound with from one to two preferably unfuse'd sixmembered rings, exclusively substituted at the same time with at least one substituent defined as Y above, and at least one other substituent Z which is chlorine, bromine, amino, nitro or lower alkyl; for example, aromatic hydroxyl compounds, and more in particular, for use in the coloring of cellulose triacetate staple fibers or stretched filaments, and in the case of polyacrylonitrile fibers, phenols such as phenol, cresols, xylenols, resorcin or pphenylphenol; aroma-tic aldehydes, particularly those of the benzene series such as benzaldehyde, chlorobenzaldehyde, salicylaldehyde, cresotin-aldehyde or chloros'alicylic aldehyde; and preferably substituted aromatic carboxylic acids such as chlorobenzoic acid, bromo'benzoic acid, aminobenzoic acid, nitrobenzoic acid, salicylic acid or cres'otinic acid and in the case of cellulose tr-iacetate staple fibers als'o benzoic acid; or mixtures of these compounds, such mixtures, especially those of one of the above aromatic carbox'ylic acids with a phenol, especially resorcin, preferably in a ratio of 1:2 to 1: 10 affording particularly favorable results.
The term amide of a thiocarbon-derived acid as used h'e-rein means amides optionally substituted "at the aminonitrogen atom and, as the case may be, in several tau tomeric form-s, as wella s corresponding hydr'azides and imides of organic 'thio'carboxylic acids, furthermore the corresponding amide derivatives, and tautomers thereof,
of m'onoand di-thiocarbonic acids inclusive of imides and nitr'iles derived from hypothetical ortho-acids of this class,
in particular of ortho-thiocarbonic acids.
As such amides of a ithiocarbon-derived acid, the padding liquor or printing paste contains, for example, thioamides of carboxylic acids such as thioacetamides, N- methylor N-ethylor N-hydroxyethyl-thioacetamide, or amide-type derivatives of thiocarbonic acid such as thiourea or isothiourea which may be substituted at the nitrogen or sulfur atom, alkyl and hydroxyalkyl groups containing preferably not more than 4 carbonatoms being used in particular as nitrogen or sulfur substituents, or thiosemicarbazide, also optionally N-lower alkyl substituted thiuram monoand di-sulfides such as tetra-lower alkyl thiuram monoor di-sulfide or water-soluble salts, in particular alkali metal or ammonium salts and especially lower alkyl-ammonium salts of thiocyanic or thioisocyanic acids. Thiourea is preferred, since particularly deep dyeings or prints on cellulose triacetate are obtained therewith. y
Water-insoluble amides such as the above-mentioned tetra-alkyl-thiuram disulfides are preferably used finely Patented Apr. 9, 1968 dispersed, as a suspension or emulsion in an inorganic solvent such as ethanol.
The padding liquor or printing paste used according to the invention thus contains the aromatic functional oxygen compounds as defined and the amide of thiocarbonderived acid in amounts of, together, about 50 to 250 g., preferably in amounts of about 150 g. per kilogram liquor or paste.
In a preferred mode of carrying out the process according to the invention, padded or printed cellulose triacetate fabrics are produced by "(1) applying to at least a portion of the entire surface, i.e. either by printing or by padding, of a cellulose acetate material or polyacrylonitrile type fiber material, especially of cellulose triacetate fabric, a coloring mixture which consists essentially of q i (1) a water-soluble acid wool dyestuff, in amounts of 5 to 120 grams per kilogram (g./kg.) of the mixture;
(2) thickener as defined hereinafter, in amounts of at least about 150 up to about 600 g./kg. of the mixture;
(3) the amido-type compound derived from a thiocarbon-derived acid, namely a member selected from the group consisting of a compound of the formula /NCR x S a compound of the formula u Ncs s -o-N n v R: I R4 a compound of the formula NH' R1SC NH: wherein each of R R R and R independently, is a member selected from the group consisting of lower alkyl and hydroxy-lower alkyl,
R is a member selected from the group consisting of lower alkyl and hydrazino,
n is an integer ranging from to 1; and, preferably, thiourea, in amounts of about 40 to 120 g./kg. of the mixture;
(4) A fixing component which is made up of the following:
(a) the aromatic compound having a functional oxyv gen-containingsubstituent or substituents, preferably a member selected from the group consisting of phenol, pyrocatechol, resorcinol, phloroglucinol, benzaldehyde substituted with a substituent Z, benzoic acid substituted by a substituent Z, and naphthoic acid substituted by a substituent Z, and phenol substituted with a substituent X, wherein X is a member selected from the group consisting of from one to three lower alkyl groups and phenyl, and
Z is a member selected from the group consisting of -OH, --C HO, Cl, Br, NO NH lower alkyl, but optimally resorcinol; (a) amounting to about onethird to one-half of the fixing component, by weight,
(5) an organic solvent for the aforesaid components (1), (2), (3), and (4) (a), which is a mixed solvent comprising preferably a saturated aliphatic thio-alcohol such as thiodiethylene glycol, amounting to about one third of the fixing component, and the balance of the fixing component', which balance consists of a lower alkanol, preferably ethanol and/or benzyl alcohol, as solvent, the total fixing component amounting to from about 100 to 300 g./kg. of the mixture,
the balance of the coloring mixture consisting of water; and
(II) steaming the resulting colored fabric with saturated steam at 0.2 to'maximally about 2 atmospheres excess pressure and corresponding temperatures of about C. and higher for about 5 to 30, and preferably 10 to 20 minutes.
The resulting padded or printed products are then rinsed as described further below and dried.
Lowe'r' used in connection with an aliphatic radical means that the radical has maximally 4 carbon atoms.
The weight ratio of the aromatic functional oxygen compounds to that of the amides and other thio compounds mentioned is about 4:1 to 1:4 and preferably about 2:1 to 122, optimal results being obtained with a ratio of about 1:2. 7
As thickener, the liquor or paste contains, for example, the disaggregated types of gum usual in the textile industry, for example the so-called crystal gum or thickeners based on cellulose such as carob bean flour, tragacanth, British gum or alkali metal alginates or cellulose derivatives such as methyl cellulose or soluble salts of carboxymethyl cellulose.
The padding liquor or printing paste can contain, for example, acids, in particular, low fatty acids such as formic, and mainly acetic acid; or organic solvents such as alcohols, e.g. methanol, ethanol, benzyl alcohol, ethylene glycol, thiodiethylene glycol, glycerin; or mixtures of such compounds as further additives usual in the textile industry.
Acid wool dyestuff as used in this specification and in the appended claims means dyestuffs, the colored anions of which draw on wool from hot, acid, aqueous solution and comprises also those of the aforesaid dyestuffs which do so already from their neutral solution.
The acid wool dyestuffs in the padding liquor or printing paste used according to the invention can be of the most varied classes of dyestuffs. Advantageously they are the technically proved dyestuff classes of the azo, anthraquinone, phthalocyanine, nitro, formazan or triphenylmethan dyestuffs which may also contain metals such as copper, nickel, chromium or cobalt. As azo dyestuffs, mainly monoazo dyestuffs are used, eg. those of the type benzene-azo-hydroxy-benzene, benzene azo-aminobem zene, benzene-azo-hydroxynaphthalene, naphthalene-azohydroxy-naphthalene, benzene-azo-aminc-naphthalene, benzene-azo-hydroxypyrazole, bcnzene-azo-aminopyrazole, benzene-azo-acyloacetylarylamide or those of the analogous naphthalene-azo and heterocycle-azo types. By heterocycle are meant those having five or six ring members, in particular containing nitrogen such as thiaz-oles, imidiazoles, triazoles, tetrazoles, oxdiazoles, thiadiazoles, pyridines, pyrimidines, benzthiazoles, benzimidazoles, benztriazoles, indazoles, quinolines. Acid wool dyes from the class of polyazo dyestuffs can also be used. The azo dyestuffs can be metallized, chiefly by chromium or cobalt, the formazan and phthalocyanine dyes preferably by copper or nickel. Particularly favorable results are attained with heavy metal-containing azo dyestuffs, preferably (--SO H)-free chromium or cobalt containing monoazo dyestuffs, which contain one metal atom bound to two molecules of azo dyestuffs.
The pH-value of the liquors and pastes according to the invention should be below 7, preferably in the range of 3.5 to 7, depending on the dyestuff used. This pH can be adjusted by adding a corresponding small amount (not more than 1% calculated on the weight of the liquor or bath) of benzoic acid.
As textile materials which can be padded or printed by the process according to the invention, optimal results are obtained on cellulose triacetatc fabric which is therefore preferred, which very satisfactory dyeings and prints are also obtained on other cellulose acetate fibers such as cellulose diacetate or cellulose 2 /z-acetate, and also on polyacrylonitrile type fibers, by which term there are understood polyacrylonitrile fibers and fibers consisting of copolyrners obtained from acrylonitrile and up to 30% by weight of another monomer copolymerizable with acrylonitrile, examples of which other monomers are given, for instance in Canadian Patent 557,597, issued on May '20, 1958, to The Chemstrand Corporation, Decatur, Ala., and in US. Patents 2,837,500; 2,837,501 and 3,096,- 139. Moreover, blended fabrics as described hereinbefore can also be used with satisfactory results.
It should, however, be borne in mind that the process according to the invention is destined primarily for the dyeing and printing of cellulose triacetate. The strength of the fibers of normal cellulose acetate (2 /2 acetate) may suffer when such fibers are dyed or printed according to this process.
The cellulose triacetate material is treated with the padding liquor or printing paste by the usual methods. The padded or printed goods are steamed in the known manner and then rinsed, e.g. with cold or warm water which can contain the additives usual in the textile industry, e.g. wetting or wash-active substances. Beautiful dyeings or prints of good color strength are attained.
The following examples serve to illustrate the invention. The temperatures are given in degrees Centigrade. Where not otherwise expressly stated, parts and percentages are by weight. The relationship of parts by weight to parts by volume is as that of grams to cubic centimeters. C.I. means Colour Index, second edition, 1956, published by the Society of Dyers and Colourists, Bradford, England, and The American Association of Textile Chemists and Colorists, Lowell, Mass, USA.
Example 1 80 grams (g). of thiourea are stirred into 500 g. of crystal gum solution (e.g. NAFKAGUM 75, of Scholten, Foxhall, Netherlands) and the mixture is diluted with 260 ml. of water. A 60 warm solution of 50 g. of phenol in 80 g. of thiodiethylene glycol, 20g. of benzyl alcohol and g. of ethanol is added to this mixture.
30 g. of the dyestuff 2:1 chromium complex of 2-aminophenol-S-sulfonic acid amide 1-(4'-chlorophenyl)-3- methyl-S-pyrazolone are sprinkled into this so-called stock thickener while stirring well. The mixture'o-btained is made up to 1 000 g. with water.
A fabric made of cellulose triacetate staple fiber is printed with the paste so obtained in the then steamed and washed.
A strongly colored brilliant red pattern is obtained on the fabric.
5 By using in the above example instead of the cellulose triacetate staple fabric another fabric, for example, of cellulose triacetate filament, or an acrylic fiber containing a blend of copolymers comprising 88 parts of a copolymer of 94% by weight of acrylonitrile and 6% by weight of vinyl acetate blended with 12 parts of a copol mer of by weight of acrylonitrile and 50% by weight of methylvinylpyridine, similar satisfactory red prints are obtained.
Prints having similar properties are obtained when the above example is repeated but using, instead of the 80 g. of thiourea and the 50 g. of phenol, the combination of components given below (in amounts of g. per kg. of printing paste):
usual way and 20 Example Aromatic functional oxygen Amide of thiocarboncompound derived acid 2 50 g. resorcinol dissolved in 80 g. thiourea.
50 g. of water. 50 g. pyrocatechol 100 g. thiourea. 50 g. phloroglucinol Do. 50 g. p-chloro-benzoic acid Do. 50 g. o-amino-benzoic acid Do. 50 g. p-phenyl-phenol-. Do. 8 50 g. resorcinol dissolved 100 g. tetramethylthiuram- 50 g. water. disulfide. 9 do 100 g. thioacetamide. 10 g. o-nitro-benzoic acid- Do. 11 60 g. salicylic acid 100 g. thiourea. 30 12. 50 g. benzaldehyde. Do.
13 50 g. resorcinol dissolved in g. ethyl isothiourea 50 g. water. (for dyestufi see iollow- A I ing table). 14 d0 g. thiosemicarbazide (for dyestufi see following table). 35
When Example 1 is repeated, but instead of the dyestuff mentioned therein, the same amounts of the dyestuffs given in column II of the following table are used, then colored patterns of similar quality are obtained on cellulose triacetate fabric which have the shades given in column III below:
TAB LE 1 II III Example No. Dyestutr used Shade on cellulose triacetate The anthraquinone dyestufi described in Example 8 of German Patent 631,518 Blue. Tlae uifionoazoiyestufi: 2-diaz0-benzene-1-sulf0nic acid phenol ester 2-amin0-8-hydroxy-naphthalene- Red.
s omc aci 1 r The 2:1 chromium complex described in Example 2 of U.S. Patent 2,714,102. Yellow.
The 2:1 cobalt complex described in Example 2 oi-U.S. Patent. 2,738,345
The 2:1 chromium complex described in Example 2 0i U.S. Patent 2,730,522 Orange.
- The mixed 2:1 chromium complex described in Example 4 of U.S. Patent 2,826,572. Red.
The 2: 1 cobalt complex described in the Table N o. 14 of U.S. Patent 2,817,655. Rub
The 2 1 cobalt complex dyestufi 2-diazo-4-propylsulfouyl-phenol 2-hydroxy-naph Bordeaux.
The 2 1 chromium complex described in the Table N o 13 of U.S. Patent 2,817,655. Violet.
The 2:1 chromium complex described in Example 1 oi the U.S. Patent 2,723,263 Blue. 25 The 21;%h0{1r0mi11m complex dyestufi: 2-aminophen0l4-sulphonic acid amidel-hydroxy-QB Navy blue.
. nap a ene.
26 The 2:1 chromium complex described in Example 1 of the U.S. Patent 2,551,056 Golden yellow.
27 Green.
' Q-somm O: I l
TABLE-Continued I II III Example N o. Dyestufi used Shade on cellulose triacetate 28 The mixed 2:1 chromium complex described in Example 1 of the U.S. Patent 2,711,404 Brown. 29. The 2:1 chromium complex described in Example 1 of the U.S. Patent 2,829, 140 Dark brown. 30. The 2: 1 chromium complex described in Example 8 or the U.S. Patent 2,551,056 Grey. 31 4,4-bis-(o-diuzophenyl-sulphonyloxy)-diphenyl-methane l-phenyl-3-methyl-5-aminopyrazolc Yellow.
sulphonic acid (2 equivalents). 32 4,4-bi s-(adiagophenyl-sulphouyloxy)-diphenyl-methane- Z-aminonapthalene--sulpl1onic acid (2 Orange.
equiva en s 33 4,.4-bis-(o-diazophenyl-sulphonyloxy)-diphenyl-methane- 2-amino5-hydroxynaphthalene-(isulphonic Red.
acid (2 equivalents, acid coupling). 34 The 2:1 chromium complex described in Example 4 of the U.S. Patent 2,830,980. Yellowish red. 35. The 2 l chromium complex described in Example 1 of the English Patent 823,945.. Blue. 36. The 2 1 chromium complex described in Example 2 oi the Sw1ss Patent 330,129.. Green. 37. The 2:1 chromium complex described in Example 2 of the U.S. Patent 2,891,939. Dark green. 38 The 2:1 cobalt complex described in Example 2 of the U.S. Patent 2,820,140.-.. Reddish brown.
The 2:1 chromium complex described in Example 11 of U.S. Patent 2,551,056 The monoazo and disazo chromium mixed complex described in Example 5 of the Can The monoazo dyestufi described in Example 2 of the U.S. Patent 2,773,055
43 The disezo dyestufl described in Example 5 of the French Patent 1,150,719 44 Thegisazo dyestufi: 2,2-bis-diazo4,4-dichloro-diphenyl-sulfideZZ-aminoQ-hydro acl 45 0.1. Acid Yellow 117 (No. 24820)-- 46 (3.1. Acid Yellow 40 (N0. 18950) 47 The monoazo dyestufi:
cHi-C -soT-oC -N=N-ll-cm Do.
N S0 11 HO N k 48 0.1. Acid Red 155 (No. 18'l30). Red.
IIIH: SO3H 50 0. Acid Red 114 (N0. 23635)----- Red, Acid Blue 150 (No. 61' 130) Blue.
Brilliant blue.
Acid Black 47 (N O. 56055) I. I. r. Acid Blue 127 (No. 61135) II Acid Orange 3 (No. '385) he monozao dyestuii: 2-diazo-benzoic acid-#142,5'-dichloro-3-sulfophcnyl .1. Acid Orange 7 (No. '510) Orange. Acid Red 52 (No. 45100) Brilliant red. Acid Violet 24 (N o. 44055)-.- Reddish blue. Acid Violet 15 (No. 43525) Blue. Acid Blue 47 (N0. 62'085) Do. Acid Blue 41 (No. 62130)... Do. Acid Blue 62 (No. 62045) Do. Acid Red 73 (No. 27290) Scarlet. Acid Blue 59 (N o. 50315) Blue.
Acid Blue 102 (No. 50320) Do. Acid Yellow 65 (No. 14170) Yellow.
Acid Red 88 (No. 15620).. Red. I Acid Brown 6 (No. 14625) Reddlsh brown. C. Acid Blue 9 (No. 42090) Blue.
C.I. Acid Green 9 (No. 42/100) Green. The first cupriferous iormazane dye-stud described in Example 2 of Belgian Patent 603,740 Blue. The first cupriferous formazane dye-stufi described in Example 6 of Belgian Patent 603,740- Do. The fourth cuprilerous iormazane dye-stud described in Example 7 of Belgian Patent 603,740 Do. The nickeliferous iormazane dye-stud described in Table II, No. 4 of Belgian Patent 603,740..- Violet-brown. CLI. Acid Blue (No. 62055)... Bhw Copper phthalocyanine disulfonic acid Turquoise,
Nickel phthalocyanine disulionic acid pyrezole.
Turquoise blue.
The second 2:1 chromium complex dyestufl described in Example 5 of U.S. Patent 2,551,056. Bluish red. The monoazo dyestufi:2-diazo-d1phenyl-sulfone-3'-sulfonic acid 5-amino-3-methyl-l-(3-chlorophenyl)- Yellow.
0 The monoazo dyestuii:2-diazo-1-hydroxy-benzene-4,o-disulfonic acid+l,3-diamino benzene (after-treat d Bro with chromium).
Example 81 20 g. of the dyestuff 2:1 chromium complex of Z-amino- 1-hydroxybenzene-4-sulfonic acid amide- 1-(4-chlorophenyl)-3-methyl-5-pyrazolone are mixed with 10 g. of benzoic acid and 80 g. of thiourea; the mixture is pasted with 70 g. of a solution consisting of g. of thiodiethylene glycol, 14 g. of benzyl alcohol and 21 g. of ethanol. The mixture is then dissolved in 250 g. of hot water and then stirred into 350 g. of a ready-for-use 5%-alginate thickener prepared by dissolving g. of sodium alginate powder in 1 liter of Water. A solution of 50 g. rcsorcinol in 50 g. of water is then added to this paste and finally the whole is made up to 1000 g. with Water.
A fabric made from cellulose triacctatc stretched filathus prepared, dried at about 100 and then steamed with dry saturated steam in a continuous steaming apparatus of the Mather-Flatt type for 8 to 16 minutes or in a star steamer at 0.2 to 0.8 atmospheres gauge pressure for 10 to 15 minutes.
After steaming, the fabric is rinsed first in cold and then in hot water, then soaped at the boil with an aqueous solution of 1 to 2 g. liter of a nonionogcnic washing agent and finally dried.
A strongly colored golden yellow print is obtained which is fast to washing at the boil, sublimation and light.
Example 82 20 g. of the dycstulf 2:1 chromium complex of 2- ment is printed in a conventional manner with the paste amino 1 hydroxybcnzenc-S-ethyl sulfone 1-phcnyl-3- methyl-S-pyrazolone are thoroughly mixed with 8 g. of thiourea and 10 g. of benzoic acid and the mixture is pasted with 70 g. of a solution consisting of 35 g. of thiodiethylene glycol, 14 g. of benzyl alcohol and 21 g. of ethanol. The mixture is then dissolved in 250 g. of hot water and the solution is stirred into 350 g. of a previously prepared, ready-for-use %-sodium alginate thickener. A mixture of 35 g. of resorcinol in 35 g. of water is then added to this paste which is finally made up to 1000 g. with water while stirring.
A fabric of cellulose tri-acetate staple fiber is printed in a conventional manner with the paste so prepared, dried at 100 and then steamed with dry saturated steam in a continuous steaming apparatus of the Mather-Flatt type for 8 to minutes.
After steaming, the fabric is rinsed first in cold and then in hot water, then soaped at 40 to 50 with an aqueous solution of 1 to 2 g./liter of a non-ionogenic washing agent and dried.
A strongly colored red print is obtained which is fast to washing and sublimation.
Similarly good results are obtained when employing in the above example a blended fabric consisting of 50% by weight of the polyacrylonitrile type fibers used in the second part of Example I and 50% by weight of cellulose triacetate fibers.
Example 83 30 g. of the dyestufi 4-(2',4'-dinitro-l-anilino)-1,l-diphenylamine-Z-sulfonic acid are mixed with 8 0 g. of thiourea and 10 g. of benzoicacid and the mixture is pasted with 70 g. of a solution consisting of 35 g. of thiodiethylene glycol, 14 g. of benzyl alcohol and 21 g. of ethanol. The mixture is then dissolved in 250 g. of :hot water and stirred into 350 g. of a previously prepared, ready-for-use 5%-sodium alginate thickener. A mixture of 50 g. of resorcinol in 50 g. of Water is then added to this paste which is finally made up to 1000 g. with water.
Polyacrylonitrile fabric is printed in the usual way With the paste so prepared, dried and then steamed with dry saturated steam in a continuous steaming apparatus of the Mather-Flatt type for 8 to 16 minutes or in a star steamer at'0.2 to 0.3 atmospheres gauge pressure for 10 to minutes. After steaming, the fabric is rinsed in cold and then in warm water, soaped at 60 with an aqueous solution of 1 to 2 g./liter of a non-ionogenic Washing agent and then dried.
A strongly colored dark golden yellow print is obtained which is fast to washing and sublimation.
Similarly good results are obtained when employing in the above example a blended fabric consisting of 70% by weight of the polyacrylonitrile type fibers used in the second part of Example 1 and 30% by weight of staple rayon.
What we claim is:
1. A process for the production of a colored textile material comprising:
(I) applying to at least a portion of the entire surface of a fabric consisting essentially of a member of the group of cellulose triacetate stretched filament, cellulose triacetate staple fiber, a blend of cellulose triacetate fibers and polyacrylonitrile-type fibers, and a blend of staple rayon and polyacrylonitrile-type fibers, a mixture consisting essentially of (a) an acid, water-soluble wool dyestufi;
(b) a member selected from the group consisting of phenol, pyrocatechol, resorcinol, phloroglucinol, benzaldehyde, benzaldehyde substituted with a substituent Z, benzoic acid substituted by a substituent Z, naphthoic acid substituted by a substituent Z, and phenol substituted with a substituent X, wherein X is a member selected from the group consisting of from one to three lower alkyl groups and phenyl, and
a compound of the formula a compound of the formula Ri-s-c and thiourea; wherein each of R R R and R independently, is
a member selected from the group consisting of lower alkyl and hydroxy-lower alkyl,
R is a member selected from the group consisting of lower alkyl and hydrazino, and
n is an integer ranging from 0 to l; and
(d) a thickener; and
(II) steaming the resulting colored fabric.
2. A process as described in claim 1, wherein step II is carried out under an excess pressure of about 0.2 to 2 atmospheres.
'3. A process as described in claim 1, wherein steaming is carried out for from about 5 to 30 minutes.
4. A process as described in claim 1, wherein the entire surface of said fabric is colored by padding the same with said mixture. v
5. -A process as described in claim 1, whereina part of the surface of said fabric is colored by printing the same with said mixture in a pattern.
6. A process as described in claim 1, wherein the memher under (b) is p-chloro-benzoic acid.
7. A process as described in claim -1, wherein the memher under (c) is thiourea.
8. A process for the production of a colored textile material comprising:
(I) applying to at least a portion of the entire surface of a fabric consisting of a member of the group of cellulose triacetate stretched filament, cellulose triacetate staple fiber, a blendof cellulose triacetate fibers and polyacrylonitrile-type fibers,"and a blend of staple rayon and polyacrylonitrile-type fibers, a mixture consisting essentially of (a) an acid, water-soluble wool dyestutf, (b) a mixture of benzoic acid and'resorciuol in a weight ratio of about 1:2 to 1:5, the content of benzoic acid in said coloring mixture not exceeding substantially an amount of 1% by weight, (c) a member selected from the group consisting of a compound of the formula N-C-R 1.1 t
a compound ofthe formula a compound of the formula 1 1 and thiourea; wherein each of 1 R R and R independently, is
a member selected from the group consisting of lower alkyl and hydroXy-lower alkyl, R is a member selected from the group consisting of lower alkyl and hydrazino, and n is an integer ranging from to 1; and (d) a thickener; and
(II) steaming the resulting colored fabric.
9. A mixture for padding and printing fabrics consisting essentially of (a) an acid, water-soluble wool dyestuff;
(b) a member selected from the group consisting of phenol, pyrocatechol, resorcinol, phloroglucinol, benzaldehyde, benzaldehyde substituted with a substituent Z, benzoic acid substituted by a substituent Z and naphthoic acid substituted by a substituent Z, and phenol substituted with a substituent X, wherein X is a member selected from the group consisting of from one to three lower alkyl groups and phenyl, and
Z is a member selected from the group consisting of -Cl, Br, -NO NH and lower alkyl;
(c) a member selected from the group consisting of a compound of the formula Nfi-R Rf s r a compound of the formula thiourea and a compound of the formula Ri -'C wherein each of R R R and R independently, is a member selected from the group consisting of hydrogen, lower alkyl and hydroXy-lower alkyl,
R is a member selected from the group consisting of lower alkyl and hydrazino, and
n is an integer ranging from 0 to 1; and
, (d) athickener.
10. A mixture for padding and printing fabrics consisting essentially of, per kilogram of mixture,
(a) from about 5 to 120 grams of an acid, watersoluble wool dyestuff,
(b) from about to 150 grams of a member selected from the group consisting of phenol, pyrocatechol, resorcinol, phloroglucinol, benzaldehyde substituted with a substituent Z, benzoic acid substituted by a substituent Z and naphthoic acid substituted by a substituent Z, and phenol substituted with a substituent X, wherein X is a member selected from the group consisting of from one to three lower alkyl groups and phenyl, and
Z is a member selected from the group consisting of -Cl, -Br, NO NH and lower alkyl,
(c) from about 40 to 120 grams of a member selected from the group consisting of a compound of the formula i' R: S
thiourea,
1 2 a compound of the formula R1\ 3 /R3 N -sS- -N A R2 R4 and a compound of the formula NlI R1SC
wherein each of R R R and R independently, is a member selected from the group consisting of hydrogen, lower alkyl and hydroXy-lower alkyl,
R is a member selected from the group consisting of lower alkyl and hydrazino, and
n is an integer ranging from 0 to 1; and
(d) from about to 600 grams of a thickener, the
balance being aqueous solvent.
11. A composition as defined in claim 10, wherein component (b) is resorcinol and component (0) is thiourea.
12. Colored fabric of cellulose triacetate produced by the process defined in claim 1.
13. A process for the production of a colored textile material selected from the group consisting of a padded and a printed polyacrylonitrile type fiber material, comprising:
(I) applying to at least a portion of the entire surface of a polyacrylonitrile fabric a mixture consisting essentially of (a) an acid, water-soluble wool dyestutl,
(b) a member selected from the group consisting of phenol, pyrocatechol, resorcinol, phloroglucinol, benzaldehyde substituted with a substituent Z, benzoic acid substituted by a substituent Z and naphthoic acid substituted by a substituent Z, and phenol substituted with a substituent X, wherein X is a member selected from the group consisting of from one to three lower alkyl groups and phenyl, and
Z is a member selected from the group consisting of -Cl, Br, NO NH and lower alkyl,
(0) a member selected from the group consisting of a compound of the formula a compound of the formula Rt S H a compound of the formula NH Rr-S-C and thiourea, wherein each of R R R and R independently, is a member selected from the group consisting of hydrogen, lower alkyl and hydroxy-lower alkyl, R is a member selected from the group consisting of lower alkyl and hydrazine, and n is an integer ranging from 0 to 1; and (d) a thickener; and (II) steaming the resulting colored fabric. 14. A mixture for padding and printing fabrics con- 7 sisting essentially of, per kilogram of mixture,
13 (a) from about 5 to 120 grams of an acid, watersoluble wool dyestuff, (b) from about 30 to 150 grams of a mixture of (i) a phenol selected from the group of phenol, pyrocatechol, resorcinol, phloroglucinol, and phenol substituted with a substituent X, wherein X is a member selected from the group consisting of from one to three lower alkyl groups and phenyl and (ii) an aromatic carboxylic acid selected from benzoic acid, chlorobenzoic acid, bromobenzoic acid, aminobenzoic acid, nitrobenzoic acid, salicylic acid and cresotinic acid, the Weight ratio of said phenol to said aromatic carboxylic acid ranging from 1:2 to 1:10, (c) from about 40 to 120 grams of a member selected from the group consisting of a compound of the thiourea, a compound of the formula and a compound of the formula phenol is resorcinol, said aromatic carboxylic acid is benzoic acid, and the component (c) is thiourea.
References Cited UNITED STATES PATENTS 2,291,052 7/1942 Miller 8 63 2,901,311 8/1959 Nusslein et al. 259
FGREIGN PATENTS 285,942 2/1928 Great Britain.
NORMAN G. TORCHIN, Primary Examiner. T. I. HERBERT, Examiner.
US417762A 1963-04-26 1964-12-11 Process for the production of colored cellulose triacetate material and blends thereof with polyacrylonitrile Expired - Lifetime US3377128A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3961883A (en) * 1972-11-24 1976-06-08 American Cyanamid Company Process for printing a fiber product containing acrylic fibers and cellulosic fibers

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB285942A (en) *
US2291052A (en) * 1940-07-09 1942-07-28 Du Pont Printing cellulose acetate
US2901311A (en) * 1955-03-04 1959-08-25 Hoechst Ag Process for the printing of fibrous textile material made of polyester fibres

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB285942A (en) *
US2291052A (en) * 1940-07-09 1942-07-28 Du Pont Printing cellulose acetate
US2901311A (en) * 1955-03-04 1959-08-25 Hoechst Ag Process for the printing of fibrous textile material made of polyester fibres

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3961883A (en) * 1972-11-24 1976-06-08 American Cyanamid Company Process for printing a fiber product containing acrylic fibers and cellulosic fibers

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