US3473610A - Process for obtaining bitumens from underground deposits - Google Patents
Process for obtaining bitumens from underground deposits Download PDFInfo
- Publication number
- US3473610A US3473610A US658522A US3473610DA US3473610A US 3473610 A US3473610 A US 3473610A US 658522 A US658522 A US 658522A US 3473610D A US3473610D A US 3473610DA US 3473610 A US3473610 A US 3473610A
- Authority
- US
- United States
- Prior art keywords
- combustion
- boring
- treatment
- bitumens
- packer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 20
- 230000008569 process Effects 0.000 title description 16
- 238000002485 combustion reaction Methods 0.000 description 56
- 239000007789 gas Substances 0.000 description 39
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 22
- 239000001301 oxygen Substances 0.000 description 22
- 229910052760 oxygen Inorganic materials 0.000 description 22
- 239000003921 oil Substances 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 238000011065 in-situ storage Methods 0.000 description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 description 11
- 239000008246 gaseous mixture Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000007788 liquid Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000001569 carbon dioxide Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 238000004880 explosion Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000004576 sand Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 230000000977 initiatory effect Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 239000012476 oxidizable substance Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
- E21B43/243—Combustion in situ
Definitions
- the title of the copending application is Process for the Extraction of Liquid and Solid Bitumens From Underground Deposits, and the application relates to a continuous method of extracting liquid and solid bitumens from underground deposits where injection and produc- @Aw Patented Oct. 2l, 1969 rice tion borings are inserted into an underground stratum of the bitumens, combustion gases are fed to the underground deposit and ignited, the bitumens are brought to the surface in liquid and gaseous phases, a portion of the bitumens are recovered, another portion of the bitumens is recirculated into the stratum to be burned by the heat in the reaction zone and a continuous process is provided.
- the field of the invention is processes for supplying input and output to Wells wherein the input includes heating.
- a particular eld of the invention is processes for heating wells which includes the introduction of heated uid.
- Another object of the present invention is to provide a preliminary preparation of a treatment boring prior to the commencement of an in situ combustion.
- Still another object of the present invention is an improved apparatus for insertion in the treatment boring of a process for obtaining bitumens from underground deposits.
- the production of bitumens from deposits containing liquid bitumens by the in situ combustion process disclosed in U.S. Patent No. 3,344,856 supra is improved by a process and apparatus for the preliminary preparation of the treatment boring and the commencement of the in situ combustion.
- the present process and apparatus is characterized in that when the space above the packer located above the injection or treatment borings contains traces of oil, the space is filled with water or gaseous nitrogen under high pressure and through this treatment boring the gaseous mixture consisting mainly of carbon dioxide and steam is injected.
- the gaseous mixture is heated to above 200 C., depending on the pressure and saturation temperature of the steam.
- the gaseous mixture is gradually enriched with oxygen from at the beginning to 21% by volume.
- This gaseous mixture is injected into the restricted space in the boring below the packer and into the immediate neighborhood thereof, to displace and oxidize whatever oil may be present.
- the temperature of the oxygen containing gaseous mixture is gradually increased and ignition is effected by contacting the gaseous mixture containing oxygen with catalysts or readily oxidizable substances located in the bottom of the treatment boring.
- FIGURE 1 shows in cross section a treatment or injection boring inserted into an underground bituminous deposit from the surface of the ground;
- FIGURE 2 shows a modified embodiment of FIGURE 1
- FIGURE 3 is a detailed showing of a modified embodiment of the check valve of FIGURES l and 2.
- the treatment or injection boring is shown having a casing 1 provided with a perforated liner 20a that extends into the oil -bearing sand 26.
- the casing is held rmly in place in the surrounding rock 3 by cement 2.
- a cage 15 is positioned in the casing 1 at the level of the perforated liner 20a adjacent the oil bearing sand.
- the cage is in the form of a tubular structure with outer and inner jackets of perforated non-corrosive iron.
- the space between the outer and inner jackets is completely filled with coarse sand while the space inside the inner jacket is partly iilled therewith.
- a vessel 16 with a fusible bottom 17 is positioned upon the sand in the inner jacket.
- the vessel is filled to level 19 with a covering liquid such as water containing pieces of the substance such as phosphorus which gnites in the presence of oxygen.
- a packer 7 with a peripheral seal 9 is set in the casing 1 above the liner 20a in cage 15.
- the packer is initially tightly sealed with closure caps 5 and 8 to a horizontal position.
- a tubing 4 is shown lowered through the pivoted closure caps 5 and 8 and central opening 14 of the packer down to almost the level of the cage 15.
- the lowermost section of the tube 4 contains an upwardly floating check valve in the form of a ball valve 10, a sealing member 11 and a valve closing spring 12.
- the tubing 4 carries elastic or resilient centering devices 6 at about 10 meter intervals. Besides their centering function, the devices u also divide the space above the packer into separate compartments 27 to provide better heat insulation for the tube 4.
- the free space above the packer 7 between the casing 1 and tubing 4 is filled with nitrogen under pressure or with water, introduced through valve 24.
- the packer 7 is shown through which is passed a second tubing 28 with a valve 24 at its upper end.
- This second tubing 28 permits the introduction of hydrocarbons for combustion and the insertion of a pressure gauge 29 which is lowered by a supporting cable 30 into the cage 15.
- a plurality of packers 21 are shown located in the liner 20a for the purpose of controlling the uids introduced into the oil bearing sand 26.
- Casing 1 is closed at the top by a cover 23 which is equipped with a valve 24.
- Tubings 4 and 28 carry valves 25 and 24 at their upper ends.
- perforated liners of smaller diameters than casing 1 Such a smaller perforated liner is shown at 20h.
- the solvent or emulsion is circulated until the casing has been thoroughly cleaned.
- This temporary tubing is then removed and substituted by the permanent tubing 4 which is lowered into the casing 1 through the central opening 14 of the packer by pivoting the closure caps S and 8 to their vertical positions.
- the permanent tubing 4 is lowered to almost the level of the cage 15.
- Nitrogen under a pressure of about 5 to 10 atmospheres above deposit pressure or water is introduced through the valve 24 into the free space above the packer 7 between the casing 1 and the tubing 4. Heated modified gases of combustion at a temperature of about 200 to 295 C. are now forced through the tubing 4 and through the boring into the oil deposit. After about 48 hours the gases of combustion are gradually enriched with oxygen. This enrichment is continued for another 48 hours until the oxygen content is increased to 21% for the purpose of oxidizing the oil or bituminous residues.
- the temperature of the activated gases of combustion is slowly increased to about 275 to 475 C.
- These activated gases of combustion consist of carbon dioxide, oxygen and steam.
- the readily fusible bottom 17, formed for example from tin having a melting point of 232 C., of vessel 16 melts so as to lose the protective liquid therein and the pieces of phosphorus 18 are ignited by the oxygen.
- vessel 16 also contains a catalytic agent such as platinum to initiate in situ combustion with the formation of a burning front between two specially prepared borings.
- a catalytic agent such as platinum to initiate in situ combustion with the formation of a burning front between two specially prepared borings.
- the second tubing 28 facilitates the introduction of hydrocarbons for combustion until the oil content of the burning space is adequately high to support combustion.
- a pressure gauge 29 is lowered by the supporting cable 30 into the cage 15. Fluid pressure readings are transmitted by the cable to above ground.
- the flow resistance encountered by gas and steam, e.g. by the activated gases of combustion, in the regions of combustion is usually very slight. This flow resistance has to be kept practically constant in the regions between the treatment and leading borings. Increased flow resistance can result, for example, from the penetration of flooding water into the path of combustion.
- an increased pressure reading on the pressure gauge activates an increase in the amount of oxygen that is added to the gases of combustion so as to increase the underground permeability to gases.
- the cage or basket when activated gases of combustion of different compositions are introduced at different levels of the deposit, the cage or basket is perforated only below the level of the uppermost packer 21.
- the activated gases of combustion having different compositions are introduced separately from above ground through tubing 28 to the upper strata and through tubing 4 to the lower strata.
- This modified gas of combustion comprises S51-20% steam, 41.5il5 CO2 and 3.5111067?) nitrogen.
- the condensation temperature is about 295 C. so that at the foot of the boring this temperature builds up with the displacement of large amounts of mineral oil.
- the fusible bottom 17 of vessel 16 now releases the ignition material.
- the modified gas of combustion is changed by continually increasing the oxygen content to 21% from its initial composition of 53 t20% steam, 39il5% CO2,
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED50833A DE1247238B (de) | 1966-08-12 | 1966-08-12 | Verfahren zum Foerdern von Bitumina aus Lagerstaetten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3473610A true US3473610A (en) | 1969-10-21 |
Family
ID=7052948
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US658522A Expired - Lifetime US3473610A (en) | 1966-08-12 | 1967-08-04 | Process for obtaining bitumens from underground deposits |
| US810057*A Expired - Lifetime US3512584A (en) | 1966-08-12 | 1969-01-06 | Apparatus for obtaining bitumens from underground deposits |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US810057*A Expired - Lifetime US3512584A (en) | 1966-08-12 | 1969-01-06 | Apparatus for obtaining bitumens from underground deposits |
Country Status (3)
| Country | Link |
|---|---|
| US (2) | US3473610A (de) |
| AT (1) | AT280188B (de) |
| DE (1) | DE1247238B (de) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4063416A (en) * | 1975-12-03 | 1977-12-20 | Cooper Jack M | Steam generator |
| FR2548207A1 (fr) * | 1983-06-30 | 1985-01-04 | Air Liquide | Procede d'oxydation de couches sedimentaires souterraines contenant des matieres hydrocarbonees |
| US4509595A (en) * | 1981-01-28 | 1985-04-09 | Canadian Liquid Air Ltd/Air Liquide | In situ combustion for oil recovery |
| WO2015164930A3 (en) * | 2014-04-30 | 2016-04-28 | Kovachki Hristo Atanasov | Method and device for underground gasification of fuels using a single wellbore for directing gases |
| US10858928B2 (en) | 2018-08-21 | 2020-12-08 | Baker Hughes, A Ge Company, Llc | Gauge assembly and method of delivering a gauge assembly into a wellbore |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2804146A (en) * | 1955-04-20 | 1957-08-27 | Paul B Crawford | Recovery of petroleum oil from partially depleted subterranean reservoirs |
| US2839141A (en) * | 1956-01-30 | 1958-06-17 | Worthington Corp | Method for oil recovery with "in situ" combustion |
| US3024841A (en) * | 1958-07-30 | 1962-03-13 | Jersey Prod Res Co | Method of oil recovery by in situ combustion |
| US3127935A (en) * | 1960-04-08 | 1964-04-07 | Marathon Oil Co | In situ combustion for oil recovery in tar sands, oil shales and conventional petroleum reservoirs |
| US3276518A (en) * | 1961-08-08 | 1966-10-04 | Deutsche Erdoel Ag | Process for extracting liquid bitumens from an underground deposit |
| US3316962A (en) * | 1965-04-13 | 1967-05-02 | Deutsche Erdoel Ag | In situ combustion method for residualoil recovery from petroleum deposits |
| US3344856A (en) * | 1964-03-26 | 1967-10-03 | Deutsche Erdoel Ag | Process for the extraction of liquid and solid bitumens from underground deposits |
| US3360044A (en) * | 1963-03-21 | 1967-12-26 | Deutsche Erdoel Ag | Process and apparatus for the recovery of liquid bitumen from underground deposits |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2913050A (en) * | 1955-05-12 | 1959-11-17 | Phillips Petroleum Co | Preventing explosions in bore holes during underground combustion operations for oil recovery |
| US2895555A (en) * | 1956-10-02 | 1959-07-21 | California Research Corp | Gas-air burner with check valve |
| US3072188A (en) * | 1958-12-30 | 1963-01-08 | Gulf Research Development Co | Method of heating underground formations around the borehole of a well |
| US3109482A (en) * | 1961-03-02 | 1963-11-05 | Pure Oil Co | Well-bore gas burner |
| US3087545A (en) * | 1961-08-09 | 1963-04-30 | Pure Oil Co | Method of heating and producing oil wells |
| US3298439A (en) * | 1964-07-29 | 1967-01-17 | Texaco Inc | Bottom hole burner |
-
1966
- 1966-08-12 DE DED50833A patent/DE1247238B/de active Pending
-
1967
- 1967-08-04 AT AT728567A patent/AT280188B/de active
- 1967-08-04 US US658522A patent/US3473610A/en not_active Expired - Lifetime
-
1969
- 1969-01-06 US US810057*A patent/US3512584A/en not_active Expired - Lifetime
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2804146A (en) * | 1955-04-20 | 1957-08-27 | Paul B Crawford | Recovery of petroleum oil from partially depleted subterranean reservoirs |
| US2839141A (en) * | 1956-01-30 | 1958-06-17 | Worthington Corp | Method for oil recovery with "in situ" combustion |
| US3024841A (en) * | 1958-07-30 | 1962-03-13 | Jersey Prod Res Co | Method of oil recovery by in situ combustion |
| US3127935A (en) * | 1960-04-08 | 1964-04-07 | Marathon Oil Co | In situ combustion for oil recovery in tar sands, oil shales and conventional petroleum reservoirs |
| US3276518A (en) * | 1961-08-08 | 1966-10-04 | Deutsche Erdoel Ag | Process for extracting liquid bitumens from an underground deposit |
| US3360044A (en) * | 1963-03-21 | 1967-12-26 | Deutsche Erdoel Ag | Process and apparatus for the recovery of liquid bitumen from underground deposits |
| US3344856A (en) * | 1964-03-26 | 1967-10-03 | Deutsche Erdoel Ag | Process for the extraction of liquid and solid bitumens from underground deposits |
| US3316962A (en) * | 1965-04-13 | 1967-05-02 | Deutsche Erdoel Ag | In situ combustion method for residualoil recovery from petroleum deposits |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4063416A (en) * | 1975-12-03 | 1977-12-20 | Cooper Jack M | Steam generator |
| US4509595A (en) * | 1981-01-28 | 1985-04-09 | Canadian Liquid Air Ltd/Air Liquide | In situ combustion for oil recovery |
| FR2548207A1 (fr) * | 1983-06-30 | 1985-01-04 | Air Liquide | Procede d'oxydation de couches sedimentaires souterraines contenant des matieres hydrocarbonees |
| EP0131499A1 (de) * | 1983-06-30 | 1985-01-16 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Verfahren zur Oxydation von kohlenwasserstoffhaltigen untertägigen sedimentären Lagerstätten |
| WO2015164930A3 (en) * | 2014-04-30 | 2016-04-28 | Kovachki Hristo Atanasov | Method and device for underground gasification of fuels using a single wellbore for directing gases |
| US10858928B2 (en) | 2018-08-21 | 2020-12-08 | Baker Hughes, A Ge Company, Llc | Gauge assembly and method of delivering a gauge assembly into a wellbore |
Also Published As
| Publication number | Publication date |
|---|---|
| AT280188B (de) | 1970-04-10 |
| US3512584A (en) | 1970-05-19 |
| DE1247238B (de) | 1967-08-17 |
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